JPH0631388B2 - Water-soluble cutting oil composition - Google Patents
Water-soluble cutting oil compositionInfo
- Publication number
- JPH0631388B2 JPH0631388B2 JP61026724A JP2672486A JPH0631388B2 JP H0631388 B2 JPH0631388 B2 JP H0631388B2 JP 61026724 A JP61026724 A JP 61026724A JP 2672486 A JP2672486 A JP 2672486A JP H0631388 B2 JPH0631388 B2 JP H0631388B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- ethylene oxide
- cutting
- test
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title description 18
- 239000010730 cutting oil Substances 0.000 title description 13
- -1 alcohol ester Chemical class 0.000 claims description 17
- 239000002199 base oil Substances 0.000 claims description 13
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 10
- 239000000194 fatty acid Substances 0.000 claims description 10
- 229930195729 fatty acid Natural products 0.000 claims description 10
- 150000004665 fatty acids Chemical class 0.000 claims description 10
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 6
- 125000002723 alicyclic group Chemical group 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 27
- 238000012360 testing method Methods 0.000 description 14
- 239000000839 emulsion Substances 0.000 description 13
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 10
- 235000019441 ethanol Nutrition 0.000 description 9
- 239000002480 mineral oil Substances 0.000 description 9
- 239000012190 activator Substances 0.000 description 8
- 230000001804 emulsifying effect Effects 0.000 description 8
- 235000010446 mineral oil Nutrition 0.000 description 8
- 239000003899 bactericide agent Substances 0.000 description 7
- 125000002091 cationic group Chemical group 0.000 description 7
- 238000005520 cutting process Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 239000002173 cutting fluid Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- 238000010998 test method Methods 0.000 description 6
- 241000894006 Bacteria Species 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 238000011160 research Methods 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- 229910001018 Cast iron Inorganic materials 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 230000001050 lubricating effect Effects 0.000 description 3
- 238000005461 lubrication Methods 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
- 239000011550 stock solution Substances 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000005069 Extreme pressure additive Substances 0.000 description 2
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 2
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 description 1
- OYWRDHBGMCXGFY-UHFFFAOYSA-N 1,2,3-triazinane Chemical compound C1CNNNC1 OYWRDHBGMCXGFY-UHFFFAOYSA-N 0.000 description 1
- DYBIGIADVHIODH-UHFFFAOYSA-N 2-nonylphenol;oxirane Chemical compound C1CO1.CCCCCCCCCC1=CC=CC=C1O DYBIGIADVHIODH-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 241001574381 Bactra Species 0.000 description 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical group C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000012136 culture method Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- NJIMZDGGLTUCPX-UHFFFAOYSA-N docosyl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCCCCCC NJIMZDGGLTUCPX-UHFFFAOYSA-N 0.000 description 1
- FRFMHEKZBITLOK-UHFFFAOYSA-N docosyl tetracosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCCCCCCCC FRFMHEKZBITLOK-UHFFFAOYSA-N 0.000 description 1
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 239000006479 glucose peptone medium Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 125000002819 montanyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- AYTIAPQIRMHXML-KVVVOXFISA-N n-cyclohexylcyclohexanamine;(z)-octadec-9-enoic acid Chemical compound C1CCCCC1NC1CCCCC1.CCCCCCCC\C=C/CCCCCCCC(O)=O AYTIAPQIRMHXML-KVVVOXFISA-N 0.000 description 1
- DGEHCTZOEREOTM-UHFFFAOYSA-N n-cyclohexylcyclohexanamine;oxirane Chemical compound C1CO1.C1CCCCC1NC1CCCCC1 DGEHCTZOEREOTM-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- 229940113162 oleylamide Drugs 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 102200082816 rs34868397 Human genes 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- VLAQWJMMSTXOEI-UHFFFAOYSA-N tetracosyl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCCCCCC VLAQWJMMSTXOEI-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Landscapes
- Lubricants (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Description
【発明の詳細な説明】 （産業上の利用分野） 本発明は金属材料の切削研削に使用する水溶性切削油剤
であってエマルジョン型であるが、特に優れた抗菌性を
有し腐敗し難いことを特徴とする水溶性切削油剤に関す
るものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial field of application) The present invention is a water-soluble cutting fluid used for cutting and grinding metal materials and is of an emulsion type, but it has particularly excellent antibacterial properties and is resistant to decay. And a water-soluble cutting fluid.
（従来の技術） エマルジョン型水溶性切削油剤は金属材料の切削、切削
に広く使用されているが、腐敗し易い欠点を有すること
が認められている。それはこの型の切削油剤は鉱油、動
植物油、エステル油等の基油に界面活性剤を添加しさら
に極圧添加剤として硫黄化合物、塩素化合物、燐化合物
等を添加しその他防錆剤等を添加し原液をつくりこれを
水中に分散乳化してエマルジョンとしての切削、研削に
使用するものであって、これらの成分はすべて細菌やカ
ビの好適な栄養源になる材料であるからこのエマルジョ
ン中に多種の微生物が増殖するのは当然の結果である。
かかる微生物の作用によってエマルジョンが破壊されpH
が低下し防錆性が劣化し遂には悪臭を発するようになり
更油せざるを得なくなることになる。(Prior Art) Emulsion-type water-soluble cutting fluid is widely used for cutting and cutting metal materials, but it is recognized that it has a drawback that it easily rots. This type of cutting fluid contains mineral oil, animal and vegetable oils, ester oils, and other base oils with surfactants added, and extreme pressure additives with sulfur compounds, chlorine compounds, phosphorus compounds, and other rust inhibitors. It is used for cutting and grinding as an emulsion by making an undiluted solution and dispersing and emulsifying it in water.Since all of these ingredients are suitable nutrient sources for bacteria and mold, it is possible to use various types in this emulsion. It is a natural result that the above microorganisms grow.
The action of such microorganisms destroys the emulsion and
Deteriorates, the rust preventive property deteriorates, and finally a bad odor is emitted, and oil must be changed.
この防止策として従来は各種防腐剤の添加による方法が
行われている。例えば特公昭58-5960号公報には殺菌剤
としてカチオン界面活性剤のヤシアルキルジメチルベン
ジルアンモニウムクロライドを抗腐敗剤、殺菌剤として
添加したものが記載されており、また特公昭58-51039号
公報には重金属の金属コバルトを殺菌剤として添加した
ものが開示されている。しかしこれらの殺菌剤は切削油
に繁殖する各種の微生物、中でも殺菌剤に抵抗性の弱い
シュードモナス・エアルギノーザ(Pseudomonas Aerugin
osa)菌には通常の添加量で完全に抑制し得ず、完全に抑
制し得る量を添加すると刺戟性の増大、防錆性の悪化等
の副作用があり好ましくないことになる。As a countermeasure for this, conventionally, a method by adding various preservatives has been used. For example, Japanese Examined Patent Publication No. 58-5960 discloses that a cation surfactant, palm alkyl dimethyl benzyl ammonium chloride, is added as an antiseptic and a bactericidal agent as a bactericidal agent, and in Japanese Examined Patent Publication No. 58-51039. Discloses the addition of heavy metal metal cobalt as a bactericide. However, these fungicides are Pseudomonas aeruginosa (Pseudomonas aeruginosa), which are resistant to fungicides, among which various microbes that propagate in cutting oils.
The osa) bacterium cannot be completely suppressed by a usual addition amount, and if it is added in an amount that can be completely suppressed, side effects such as increased stimulating property and deterioration of rust preventive property are not preferable.
（発明が解決しようとする問題点） 従来の技術である殺菌剤の添加によって切削油の腐敗を
抑制する方法においては殺菌剤として重金属を使用する
とその種類及び添加量によっては人体に対して刺戟性の
強い場合があり、あたカチオン界面活性剤を使用する
と、その種類及び添加量によっては防錆性、乳化安定性
を阻害する場合があり殺菌剤の種類及び添加量の選択が
難しく副作用のために有効な腐敗抑制方法となり得ない
場合が多く、これが解決を要する問題点であった。(Problems to be Solved by the Invention) In the conventional method of suppressing decay of cutting oil by adding a bactericide, when a heavy metal is used as a bactericide, depending on the type and amount of the sterilizer, the stimulability to the human body is increased. If you use a cationic surfactant, it may hinder rust resistance and emulsion stability depending on the type and amount added, and it is difficult to select the type and amount added of bactericide, which causes side effects. In many cases, it cannot be an effective method for suppressing corruption, and this is a problem that needs to be solved.
（問題点を解決するための手段） かような問題点を解決するための手段として本発明者等
は切削油を構成する成分のすべてにおいて抗菌性を持た
せ、それらを組合わせて油剤を構成し殺菌剤の添加に頼
らずに抗菌性を持ったエマルジョン水溶性切削油剤を得
ることを着想した。(Means for Solving Problems) As means for solving such problems, the inventors of the present invention have antibacterial properties in all components constituting cutting oil, and combine them to form an oil agent. The idea was to obtain an emulsion water-soluble cutting fluid with antibacterial properties without relying on the addition of bactericides.
かようにして研究を進め、切削油を構成する成分すべて
について抗菌性の観点から新たに検討し直し抗菌性のす
ぐれ材料のみを選択して抗菌性切削油剤として新たに設
計したものが本発明の組成物であって、従来の殺菌剤を
適当に選択して添加した切削油とは全く観点を異にする
ものである。In this way, we proceeded with the research and newly re-examined all the components that make up the cutting oil from the viewpoint of antibacterial properties, and selected only materials with excellent antibacterial properties and newly designed them as antibacterial cutting fluids. The composition is completely different from the conventional cutting oil in which a sterilizing agent is appropriately selected and added.
もちろん切削油に基本的に必要な性能すなわち潤滑性、
極圧性、防錆性、衛生性等を具備するものであるが、第
１の設計要因として抗菌性を考えた点が本発明の特徴で
ある。Of course, the basic performance required for cutting oil, namely lubricity,
Although it has extreme pressure properties, rust prevention properties, hygiene properties, etc., it is a feature of the present invention that antibacterial properties are considered as the first design factor.
かような観点から研究の結果得られた本発明の組成物の
構成は基油と界面活性剤と防錆剤とを必須成分とし、そ
の他乳化剤、防腐剤等の添加剤を任意成分として含有し
得るものである。The composition of the composition of the present invention obtained as a result of research from such a viewpoint contains a base oil, a surfactant and a rust inhibitor as essential components, and further contains additives such as an emulsifier and a preservative as optional components. I will get it.
基油としては鉱油、油脂、エステル油等の合成油が一般
に使用されているが、この内脂肪酸と低級アルコールと
のエステルである油脂および脂肪酸低級アルコールエス
テルは加水分解し易く本発明において主成分とするのは
好ましくない。本発明においては鉱油を主成分とし、潤
滑性が優れ加水分解性の比較的少ない脂肪酸高級アルコ
ールエステルを少量添加する方法が適当であることが判
った。ここで、鉱油については本質的には精製鉱油すべ
て使用し得るものであるが、本発明者等は研究の結果、
硫黄分が1.0％以上の精製鉱油は抗菌性が劣るので、硫
黄分1.0％以下の精製鉱油が基油として好ましく、更に
硫黄分0.5％以下の精製鉱油は抗菌性が最も優れ本発明
の基油として最も好ましいことを見出した。As the base oil, mineral oil, fats and oils, and synthetic oils such as ester oils are generally used. Among them, fats and oils and fatty acid lower alcohol esters which are esters of fatty acids and lower alcohols are easily hydrolyzed and are the main components in the present invention. It is not preferable to do. In the present invention, it has been found that a method of adding a small amount of a fatty acid higher alcohol ester having mineral oil as a main component and having excellent lubricity and relatively little hydrolyzability is suitable. Here, for mineral oil, essentially all refined mineral oils can be used, but as a result of research by the present inventors,
Since refined mineral oil having a sulfur content of 1.0% or more has poor antibacterial properties, refined mineral oil having a sulfur content of 1.0% or less is preferable as a base oil, and refined mineral oil having a sulfur content of 0.5% or less has the best antibacterial property and is the base oil of the present invention. Was found to be the most preferable.
界面活性剤としては非イオン活性剤、アニオン活性剤、
カチオン活性剤が一般に使用されているが、非イオン活
性剤、アニオン活性剤は乳化性および潤滑性が良好であ
るが、抗菌性が一般に悪い。カチオン活性剤は抗菌性は
良いが、乳化性および潤滑性が一般に悪い。As the surfactant, nonionic surfactant, anionic surfactant,
Cationic activators are generally used. Nonionic and anionic activators have good emulsifying properties and lubricity, but generally have poor antibacterial properties. Cationic activators have good antibacterial properties, but generally have poor emulsifying and lubricating properties.
本発明者等は研究の結果、特定のカチオン活性剤の組合
せが抗菌性のみならず乳化性、潤滑性も共に優れている
ことを見出したのである。As a result of research, the present inventors have found that a combination of specific cationic active agents is excellent not only in antibacterial property but also in emulsifying property and lubricating property.
すなわちそれは脂環式アミンエチレンオキサイド付加物
とアルキルアミンエチレンオキサイド付加物との組合せ
であって、特に前者がジシクロヘキシルアミンエチレン
オキサイド付加物である場合に上記目的に最も適当であ
る。That is, it is a combination of an alicyclic amine ethylene oxide adduct and an alkyl amine ethylene oxide adduct, and is most suitable for the above purpose, especially when the former is a dicyclohexyl amine ethylene oxide adduct.
この両者はいずれも一般にカチオン活性剤に分類されて
いるものであるが、非イオン活性剤としての性質も有す
るものであって従って、カチオン活性剤としての抗菌性
があり、また非イオン活性剤としての乳化性、潤滑性も
有する。Both of these are generally classified as cationic activators, but they also have properties as nonionic activators and therefore have antibacterial properties as cationic activators and also as nonionic activators. It also has emulsifying and lubricating properties.
また両者を比較すると前者は抗菌性がより優れ後者は乳
化性、潤滑性がより優れる。よって両者併用した場合に
長短相補って抗菌性、乳化性、潤滑性の共に優れる結果
となる。When the two are compared, the former is more excellent in antibacterial property and the latter is more excellent in emulsifying property and lubricity. Therefore, when both are used in combination, the results are excellent in antibacterial property, emulsifying property and lubricity by complementing each other.
かようにして基油と脂肪酸高級アルコールエステルと脂
環式アミンエチレンオキサイド付加物とアルキルアミン
エチレンオキサイド付加物を含有する組成物により、抗
菌性、潤滑性の優れるエマルジョン組成物が得られるこ
とを知り得たが、更に研究の結果、本発明の界面活性剤
成分のカチオン活性の持続性すなわち該成分の抗菌性の
持続性および上記の各成分の相溶性に難点があることが
判った。そこでこの点についても改良を進めたが、図ら
ずも式(1)の化合物を添加し、更に成分の配合比を整え
バランスをよくすることによってかような欠点が改良さ
れ長期の使用にも抗菌性が持続し、また相溶性が向上し
切削油組成物の長期保存時の安定性が著しく改良させる
ことが判明し、ここに於いて本発明が完成したのであ
る。Thus, it was found that a composition containing a base oil, a fatty acid higher alcohol ester, an alicyclic amine ethylene oxide adduct and an alkylamine ethylene oxide adduct can provide an emulsion composition having excellent antibacterial properties and lubricity. However, as a result of further research, it was found that there are problems in the persistence of the cationic activity of the surfactant component of the present invention, that is, the sustainability of the antibacterial property of the component and the compatibility of the above components. Therefore, we have made improvements in this respect as well, but by unintentionally adding the compound of formula (1) and adjusting the compounding ratio of the components to improve the balance, such drawbacks have been improved and antibacterial properties for long-term use have been improved. It has been found that the stability of the cutting oil composition is improved and the compatibility of the cutting oil composition is remarkably improved during long-term storage, and the present invention was completed here.
従って、本発明は基油25〜96重量％、脂肪酸高級アルコ
ールエステル１〜20重量％、脂環式アミンエチレンオキ
サイド付加物１〜20重量％、アルキルアミンエチレンオ
キサイド付加物１〜５重量％および次の一般式 （式中のＲはＣ１２〜２０のアルキル基を表わす） で示される化合物１〜５重量％とを含有することを特徴
とする水溶性切削油組成物である。Therefore, the present invention is based on 25-96% by weight of base oil, 1-20% by weight of fatty acid higher alcohol ester, 1-20% by weight of alicyclic amine ethylene oxide adduct, 1-5% by weight of alkylamine ethylene oxide adduct and General formula of (R in the formula represents a C 12-20 alkyl group) 1 to 5% by weight of a compound represented by the formula (1) is a water-soluble cutting oil composition.
（作用） 本発明は上記各成分を混和し均一な液状組成物となした
もので、使用時に水で稀釈したエマルジョンとなし金属
の切削、研削作業において工具刃先に供給し潤滑、冷
却、洗浄等の役割を果たすものである。基油は各成分を
溶液分散し潤滑性、防錆性の基礎となる成分である。基
油は精製鉱油で動粘度1.98cst以上135cst未満（40℃）
の範囲のものであって硫黄分1.0％以下のものが好まし
く、硫黄分0.5以下のものが最も好ましい。(Function) The present invention is a uniform liquid composition obtained by mixing the above components, and it is supplied to the tool edge during cutting and grinding of an emulsion and a metal diluted with water when used, and lubrication, cooling, cleaning, etc. Plays the role of. Base oil is a component that is a solution dispersion of each component and is the basis of lubricity and rust prevention. The base oil is refined mineral oil with a kinematic viscosity of 1.98 cst or more and less than 135 cst (40 ° C)
And a sulfur content of 1.0% or less is preferable, and a sulfur content of 0.5 or less is most preferable.
脂肪酸高級アルコールエステルは炭素数20〜30の脂肪酸
と炭素数20〜30の高級アルコールより合成したエステル
であって基油の潤滑性を向上する作用を有ししかも加水
分解性が少なく、細菌、カビの作用に対して安定性があ
る。脂肪酸高級アルコールエステルの具体例をあげれば
ベヘン酸ドコシル、ベヘン酸テトラコシル、リグノセリ
ン酸ドコシル、セラコレイン酸オクタコシル等がある。The fatty acid higher alcohol ester is an ester synthesized from a fatty acid having 20 to 30 carbon atoms and a higher alcohol having 20 to 30 carbon atoms, has the action of improving the lubricity of the base oil, and has a low hydrolyzability, and can prevent bacteria and mold. It is stable against the action of. Specific examples of the fatty acid higher alcohol ester include docosyl behenate, tetracosyl behenate, docosyl lignocerate, octacosyl ceracoleate and the like.
脂環式アミンエチレンオキサイド付加物はアルキルアミ
ンエチレンオキサイド付加物と共に、抗菌性ある乳化剤
として基油を乳化分散させるものであって、前者はエチ
レンオキサイド付加量１〜10モルの範囲が好ましく、１
モルより少ないと乳化性が劣り、10モルより多いと非イ
オン活性剤としての特性が顕著に表れて、抗菌性が劣り
好ましくない。後者のアルキルアミンエチレンオキサイ
ド付加物はアルキルの炭素数12〜20の範囲でエチレンオ
キサイド付加量１〜10モルの範囲ものが好ましく、これ
以外は乳化性、抗菌性が劣り好ましくない。The alicyclic amine ethylene oxide adduct emulsifies and disperses a base oil as an antibacterial emulsifier together with an alkyl amine ethylene oxide adduct, and the former preferably has an ethylene oxide addition amount of 1 to 10 mol.
If it is less than 10 moles, the emulsifying property is inferior, and if it is more than 10 moles, the properties as a nonionic activator are remarkably exhibited, and the antibacterial property is inferior. The latter alkylamine-ethylene oxide adduct is preferably one having an alkyl carbon number of 12 to 20 and an ethylene oxide addition amount of 1 to 10 mol.
式(1)の化合物は界面活性剤成分のカチオン活性の持続
および各成分の相溶性の維持の作用をするものでアルキ
ルアミンアミドの構造を有し、アルキル基は炭素数12〜
20であることが必要である。この範囲以外のものは上記
の作用を示さない。式(1)の化合物の具体例を示せば、
Ｎ−（２−オキシエチル），Ｎ−（２−（N,N−ビス
（２−オキシエチル））−アミノエチル）ラウリルアミ
ド、Ｎ−（２−オキシエチル）、Ｎ−（２−（N,N−ビ
ス（２−オキシエチル））−アミノエチル）オレイルア
ミド等を挙げることが出来る。The compound of formula (1) acts to maintain the cationic activity of the surfactant component and maintain the compatibility of each component, and has a structure of alkylamine amide, and the alkyl group has 12 to 12 carbon atoms.
Must be 20. Anything outside this range does not exhibit the above effects. If a specific example of the compound of formula (1) is shown,
N- (2-oxyethyl), N- (2- (N, N-bis (2-oxyethyl))-aminoethyl) laurylamide, N- (2-oxyethyl), N- (2- (N, N- Examples thereof include bis (2-oxyethyl))-aminoethyl) oleylamide.
以上の５成分の他に必要に応じて乳化剤、防腐剤、極圧
添加剤等の添加剤を含有させることができる。乳化剤と
しては、例えば石油スルホン酸ナトリウム塩、ノニルフ
ェノールエチレンオキサイド９モル付加物、オレイン酸
ジシクロヘキシルアミン塩、オレイン酸トリエタノール
アミン塩、４−（Ｎ−テトラデカンスルホニウム）−ア
ミノブタン酸ナトリウム等、防腐剤としては1,3,5−ヘ
キサヒドロトリアジン等が好ましく使用される。In addition to the above-mentioned 5 components, additives such as an emulsifier, a preservative, and an extreme pressure additive can be added if necessary. Examples of the emulsifier include petroleum sulfonic acid sodium salt, nonylphenol ethylene oxide 9 mol adduct, oleic acid dicyclohexylamine salt, oleic acid triethanolamine salt, 4- (N-tetradecanesulfonium) -aminobutanoic acid sodium salt, and the like as preservatives. 1,3,5-hexahydrotriazine and the like are preferably used.
これらの成分の配合量は基油25〜96重量％、脂肪酸高級
アルコールエステル１〜20重量％、ジシクロヘキシルア
ミンエチレンオキサイド付加物１〜20重量％、アルキル
アミンエチレンオキサイド付加物１〜５重量％、式(1)
の化合物１〜５重量％、がそれぞれ適当な範囲であっ
て、いずれも下限より少なくては前述の効果がなく、上
限より多くてはバランスを失い組成物が不安定となる
外、界面活性剤が多すぎると防錆性が悪くなりいずれも
好ましくない。The amount of these components blended is 25 to 96% by weight of base oil, 1 to 20% by weight of fatty acid higher alcohol ester, 1 to 20% by weight of dicyclohexylamine ethylene oxide adduct, 1 to 5% by weight of alkylamine ethylene oxide adduct, and formula. (1)
1 to 5% by weight of each of the compounds is in an appropriate range, and if the amount is less than the lower limit in any case, the above effect does not occur, and if the amount is more than the upper limit, the composition becomes unstable and the composition becomes unstable. If the amount is too large, the rust preventive property is deteriorated, which is not preferable.
（実施例） 第１表の組成欄に示す配合（重量％）により実施例１〜
６、比較１〜４の各例の試料原液を作成し、次の試験方
法により各種試験を行い第２表〜第５表に示す試験結果
を得た。(Example) Examples 1 to 1 according to the composition (% by weight) shown in the composition column of Table 1.
The sample stock solutions of Examples 6 and Comparative Examples 1 to 4 were prepared and various tests were carried out by the following test methods to obtain the test results shown in Tables 2 to 5.
試験方法 (A)抗菌性試験 1)実験室試験 各例の５重量％エマルジョンを試料とし、各試料の100m
lを200mlエレンマイヤーフラスコに採り、これに活性化
腐敗液（別の切削油エマルジョン腐敗液50％、トリプト
ソイ培地25％、ブドウ糖ペプトン培地25％の割合でフラ
スコに採り混和し綿栓をして25℃で24時間、エアレーシ
ョンし活性化した腐敗液）（生菌数１×108個／ml）を
３ml、潤滑油（モービル社製商品名バクトラNO.２）３m
l、鋳鉄切屑10ｇを加えて綿栓をして25℃で21日間振盪
培養した。その間７日目、14日目に活性化腐敗液のみを
３ｍづつ追加した。Test method (A) Antibacterial test 1) Laboratory test The 5 wt% emulsion of each example was used as a sample, and 100 m of each sample was used.
Take l of this in a 200 ml Erlenmeyer flask and add to it the activated putrefaction solution (50% of another cutting oil emulsion putrefaction solution, 25% tryptosome medium, 25% glucose peptone medium) in a flask, mix and cover with a cotton plug. Aged spoiler liquid aerated and activated at 24 ° C for 24 hours (viable cell count: 1 x 10 8 cells / ml), 3 ml, lubricating oil (trade name: Bactra NO.2 manufactured by Mobil) 3 m
l, 10 g of cast iron chips were added, a cotton plug was attached, and the mixture was shake-cultured at 25 ° C. for 21 days. Meanwhile, on the 7th day and the 14th day, only the activated septic solution was added in 3 m increments.
この培養液各試料について１，３，７，14，21日目にそ
の一部を採り平板培養法により菌数を測定し同時に外
観、臭気、pHを観察、測定した。A portion of each sample of this culture solution was sampled on the 1st, 3rd, 7th, 14th and 21st days, and the number of bacteria was measured by the plate culture method. At the same time, the appearance, odor and pH were observed and measured.
その結果を第２表に示す。The results are shown in Table 2.
2)現場試験 実施例１および比較例４の30倍（3.3重量％）エマルジ
ョンについて自動車工場現場において下記条件で部品の
切削加工に実用した。2) On-site test About 30 times (3.3% by weight) emulsion of Example 1 and Comparative Example 4 was practically used for cutting parts under the following conditions at an automobile factory site.
実施例１については１年間使用してもpHの低下、悪臭の
発生は認められず、正常に使用された。Regarding Example 1, even if it was used for one year, the pH was not lowered and no foul odor was generated, and it was used normally.
比較例４については２か月間使用してpHの低下、悪臭の
発生が認められ、液を交換した。Regarding Comparative Example 4, the pH was lowered and the offensive odor was generated after two months of use, and the liquid was replaced.
使用機械 トランスフアーマシン 加工部品 シリンダーヘッド 部品材質 アルミニウム合金、AC-4B 加工法 ドリル、リーマー、タップ他 タンク容量 ４万、集中クーラントタンク (B)切削性試験 各例の５重量％エマルジョンを試料として各試料につい
て下記試験条件で溝なしタップによる切削性試験を行
い、溝なしタップの損傷するまでの加工個数で試料の切
削性を評価した。Machines used Transfer machine Machined parts Cylinder head Parts material Aluminum alloy, AC-4B processing method Drill, reamer, tap, etc. Tank capacity 40,000, central coolant tank (B) Machinability test 5% by weight emulsion of each example is used as a sample The sample was subjected to a machinability test with a grooveless tap under the following test conditions, and the machinability of the sample was evaluated based on the number of cuts before the grooveless tap was damaged.
使用機械 吉田鉄工所製直立ボール盤 YD3-94CT型 工具 溝なしタップ直径６mm 材質SKH9田野井（株）製 被削剤 AC-4B（150L×150W×30Hmm） 高度HRB45 切削条件 タッピングスピード5.1m/min（270rpm） めねじ深さ15mm盲孔 下孔寸法 直径5.2mm×深さ25mm盲孔 給油量 ３／minポンプ給油 実験回数 ３回 試験結果は第３表に示す。Machine used Yoshida Iron Works upright drilling machine YD3-94CT type tool No groove tap diameter 6mm Material SKH9 Tanoi Co., Ltd. Work material AC-4B (150L x 150W x 30Hmm) Advanced HRB45 Cutting conditions Tapping speed 5.1m / min (270rpm) ) Female screw depth 15mm blind hole pilot hole size 5.2mm diameter x 25mm depth blind hole Lubrication amount 3 / min Pump lubrication test frequency 3 times The test results are shown in Table 3.
(C)防錆試験法 各例の５重量％および2.5重量％エマルジョンを試料と
し、各試料につき次に示す方法の軟鋼板重ね板試験法、
鋳鉄切屑浸漬法により試験を行って判定した。(C) Rust prevention test method Using 5% by weight and 2.5% by weight emulsion of each example as a sample, the following method is applied to each sample for the mild steel plate laminate test method,
A test was conducted by the cast iron chip dipping method to make a judgment.
1)軟鋼板重ね板試験法 直径40mm、厚さ10mmのS45C鋼円板の２枚をそれぞれ片面
を研磨しエチルアルコール、エチルエーテルの順で洗浄
し、ついでその一枚の研磨面に試料を１滴、滴下し他の
一枚の研磨面を合わせて重ね25℃恒温槽中に24時間放置
しその後の発錆状態を観察した。1) Mild steel plate test method Two S45C steel discs with a diameter of 40 mm and a thickness of 10 mm were each polished on one side and washed with ethyl alcohol and ethyl ether in this order, and then one sample was applied to the polished side. Drops were dropped and the other polishing surface was put together and piled up and left in a constant temperature bath at 25 ° C for 24 hours, after which the rusting state was observed.
2)鋳鉄切屑浸漬試験法 乾切削したFC20鋳鉄切屑20ｇを直径60mmのガラスシャー
レに採り、これに試料を完全に浸漬するまで加え５分間
放置しついで試料を傾瀉して除去しふたをして25℃恒温
度槽中に24時間放置し発錆状態を観察した。試験結果は
第４表に示す。2) Cast iron chip immersion test method 20 g of dry-cut FC20 cast iron chips is taken in a glass dish with a diameter of 60 mm, and the sample is added until it is completely immersed and left for 5 minutes, then the sample is decanted and removed. It was left in a constant temperature bath at ℃ for 24 hours and the rusting state was observed. The test results are shown in Table 4.
(D)原液安定度試験（相溶性試験） 各例の原液を量試料とし、各試料の100ｍを150ｍガ
ラス試料壜に採り、−５℃および50℃の恒温槽中に30日
間保管し、その間１日１回試料壜を観察して濁りの有無
を検した。(D) Stock solution stability test (compatibility test) The stock solution of each example was used as a volume sample, 100 m of each sample was put into a 150 m glass sample bottle, and stored in a constant temperature bath at -5 ° C and 50 ° C for 30 days, during which time The sample bottle was observed once a day to check for turbidity.
試験結果は第５表に示す。The test results are shown in Table 5.
（発明の効果） 第１表に示される組成の本発明の水溶性切削油組成物は
特許請求の範囲に示される５成分を必須成分として特定
量含有することにより第２表に示される様に長期の腐敗
試験において、しかも期間中次々と新たな活性化腐敗菌
を追加投入する条件においても、他の切削油と比較して
抗菌性が著しく優れている結果が得られた。 (Effects of the Invention) The water-soluble cutting oil composition of the present invention having the composition shown in Table 1 contains the five components shown in the claims as specific components in the specified amounts, as shown in Table 2. In the long-term spoilage test, and even under the condition that new activated spoilage bacteria were added one after another during the period, the antibacterial property was remarkably excellent as compared with other cutting oils.
また第３表、第４表に示される様に切削性、防錆性も優
れ、更に第５表に示される様に原液安定度も低温時、高
温時共優れた結果が得られ、ここに本発明により当初の
目的を達成し得たことが確認された。Further, as shown in Tables 3 and 4, excellent machinability and rust resistance are obtained. Further, as shown in Table 5, excellent stability of the undiluted solution is obtained at both low temperature and high temperature. It was confirmed that the present invention could achieve the original purpose.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｃ１０Ｍ 133:08 133:16） Ｃ１０Ｎ 30:16 40:22 (72)発明者 丹羽 栄次 神奈川県茅ヶ崎市美住町18−53 (72)発明者 佐々木 芳雄 愛知県豊田市トヨタ町１番地 トヨタ自動 車株式会社内 (72)発明者 川村 輝夫 愛知県豊田市トヨタ町１番地 トヨタ自動 車株式会社内 (72)発明者 加藤 泰男 愛知県豊田市トヨタ町１番地 トヨタ自動 車株式会社内 (72)発明者 有馬 和彦 愛知県豊田市トヨタ町１番地 トヨタ自動 車株式会社内─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Internal reference number FI Technical display location C10M 133: 08 133: 16) C10N 30:16 40:22 (72) Inventor Eiji Niwa Chigasaki, Kanagawa Prefecture 18-53, Misumi, Ichi (72) Inventor Yoshio Sasaki 1 Toyota Town, Toyota City, Aichi Prefecture, Toyota Motor Corporation (72) Inventor Teruo Kawamura 1, Toyota Town, Aichi Prefecture, Toyota Motor Corporation ( 72) Inventor Yasuo Kato 1 Toyota Town, Toyota City, Aichi Prefecture, Toyota Motor Co., Ltd. (72) Inventor, Kazuhiko Arima, 1 Toyota Town, Toyota City, Aichi Prefecture Toyota Motor Co., Ltd.
Claims (1)
エステル１〜20重量％、脂環式アミンエチレンオキサイ
ド付加物１〜20重量％、アルキルアミンエチレンオキサ
イド付加物１〜５重量％、および次の一般式 （式中のＲはＣ１２〜２０のアルキル基を表わす） で示される化合物１〜５重量％とを含有することを特徴
とする水溶性切削油組成物。1. A base oil 25-96% by weight, a fatty acid higher alcohol ester 1-20% by weight, an alicyclic amine ethylene oxide adduct 1-20% by weight, an alkylamine ethylene oxide adduct 1-5% by weight, and The following general formula (Wherein R represents a C12-20 alkyl group) 1 to 5% by weight of a compound represented by the formula:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61026724A JPH0631388B2 (en) | 1986-02-12 | 1986-02-12 | Water-soluble cutting oil composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61026724A JPH0631388B2 (en) | 1986-02-12 | 1986-02-12 | Water-soluble cutting oil composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62185793A JPS62185793A (en) | 1987-08-14 |
| JPH0631388B2 true JPH0631388B2 (en) | 1994-04-27 |
Family
ID=12201273
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61026724A Expired - Lifetime JPH0631388B2 (en) | 1986-02-12 | 1986-02-12 | Water-soluble cutting oil composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0631388B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006129747A1 (en) | 2005-06-01 | 2006-12-07 | Kyodo Yushi Co., Ltd. | Metalworking fluid composition and metalworking process |
| WO2008093844A1 (en) | 2007-02-01 | 2008-08-07 | Kyodo Yushi Co., Ltd. | Metalworking fluid and metalworking method |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0481497A (en) * | 1990-07-25 | 1992-03-16 | Yushiro Chem Ind Co Ltd | Water-soluble metal working oiling agent composition |
| JP5089179B2 (en) * | 2007-01-19 | 2012-12-05 | Ｊｘ日鉱日石エネルギー株式会社 | Cutting / grinding method with ultra-trace oil supply |
| JP5074466B2 (en) * | 2009-08-20 | 2012-11-14 | ヤナセ製油株式会社 | Biodegradable lubricating oil composition with excellent rust prevention and low friction properties |
| JP6371687B2 (en) * | 2014-11-21 | 2018-08-08 | 日本油化工業株式会社 | Composition for improving mold resistance and lubricity of fuel oil |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5269081A (en) * | 1975-12-05 | 1977-06-08 | Standard Oil Co | Fluid and coolant for use in high speed manufacturing cutting |
| JPS59118098A (en) * | 1982-12-22 | 1984-07-07 | Kankyo Bunseki Center:Kk | Determination of inosine and/or hypoxanthine and test paper for determination thereof |
| JPS59227987A (en) * | 1983-06-10 | 1984-12-21 | Kao Corp | Metal working oil composition |
-
1986
- 1986-02-12 JP JP61026724A patent/JPH0631388B2/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5269081A (en) * | 1975-12-05 | 1977-06-08 | Standard Oil Co | Fluid and coolant for use in high speed manufacturing cutting |
| JPS59118098A (en) * | 1982-12-22 | 1984-07-07 | Kankyo Bunseki Center:Kk | Determination of inosine and/or hypoxanthine and test paper for determination thereof |
| JPS59227987A (en) * | 1983-06-10 | 1984-12-21 | Kao Corp | Metal working oil composition |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006129747A1 (en) | 2005-06-01 | 2006-12-07 | Kyodo Yushi Co., Ltd. | Metalworking fluid composition and metalworking process |
| WO2008093844A1 (en) | 2007-02-01 | 2008-08-07 | Kyodo Yushi Co., Ltd. | Metalworking fluid and metalworking method |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62185793A (en) | 1987-08-14 |
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