JPH06279239A - Manicuring agent - Google Patents
Manicuring agentInfo
- Publication number
- JPH06279239A JPH06279239A JP9255893A JP9255893A JPH06279239A JP H06279239 A JPH06279239 A JP H06279239A JP 9255893 A JP9255893 A JP 9255893A JP 9255893 A JP9255893 A JP 9255893A JP H06279239 A JPH06279239 A JP H06279239A
- Authority
- JP
- Japan
- Prior art keywords
- acrylic acid
- nail enamel
- methyl methacrylate
- nail
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、特定のスチレン及び／
またはメタクリル酸メチル・アクリル酸エステル・アク
リル酸共重合体を皮膜形成剤として用いる美爪料に関す
る。BACKGROUND OF THE INVENTION The present invention is directed to specific styrene and / or
Alternatively, the present invention relates to a nail enamel which uses a methyl methacrylate / acrylic acid ester / acrylic acid copolymer as a film forming agent.
【０００２】[0002]
【従来の技術及び発明が解決しようとする課題】従来、
美爪料の皮膜形成剤としてはニトロセルロースが最も汎
用されており、光沢性、接着性、収縮性及び可塑性等を
改良する目的で、アルキド樹脂、アリルスルホンアミド
ホルムアルデヒド樹脂、エポキシ樹脂及びロジン変性樹
脂等が併用されてきた。2. Description of the Related Art Conventionally, the problems to be solved by the invention
Nitrocellulose is most commonly used as a film-forming agent for nail enamel, and for the purpose of improving gloss, adhesion, shrinkage, plasticity, etc., alkyd resin, allyl sulfonamide formaldehyde resin, epoxy resin and rosin-modified resin. Etc. have been used together.
【０００３】近年、美爪料の連用により、爪の黄変（爪
が黄色に着色する）が問題視されている。爪の黄変は美
爪料の主成分であるニトロセルロースが分解されて生成
する硝酸イオンや亜硝酸イオンが爪の構成成分であるタ
ンパク質と結合するいわゆるキサントプロテイン反応が
原因の一つと考えられる。また、ニトロセルロースは非
常に引火性が強く、爆発性があることから、貯蔵、運搬
及び製造過程において取扱いに注意する必要があり、美
爪料組成の改良が望まれていた。In recent years, yellowing of the nails (coloring the nails yellow) has been regarded as a problem due to continuous use of beauty nail materials. The yellowing of nails is considered to be one of the causes of so-called xanthoprotein reaction in which nitrate ions and nitrite ions produced by decomposition of nitrocellulose, which is the main ingredient of beauty nail materials, are bound to proteins that are components of nails. . Further, since nitrocellulose is extremely flammable and explosive, it is necessary to pay attention to handling during storage, transportation and manufacturing processes, and improvement of nail composition has been desired.
【０００４】この問題を解決するために、ニトロセルロ
ースを用いずにアルキド樹脂、アリルスルホンアミドホ
ルムアルデヒド樹脂、エポキシ樹脂及びロジン変性樹脂
のみで美爪料を処方した場合、皮膜強度が弱く、また耐
水性、乾燥速度及び光沢性の点でも好ましい美爪料が得
られない。In order to solve this problem, when the nail enamel was formulated only with an alkyd resin, an allyl sulfonamide formaldehyde resin, an epoxy resin and a rosin-modified resin without using nitrocellulose, the film strength was weak and the water resistance was low. In addition, it is impossible to obtain a nail enamel which is preferable in terms of drying speed and gloss.
【０００５】そこで、特開昭５４−１２９１３７号公報
にはメタクリル酸エステル共重合体及びメタクリル酸エ
ステル・アクリル酸エステル共重合体を皮膜形成剤とし
て含有することを特徴とする新規ネイルエナメルが提案
されている。しかし、これも皮膜強度、密着性、乾燥速
度及び光沢性が充分なものではでなかった。Therefore, Japanese Patent Application Laid-Open No. 54-129137 proposes a new nail enamel containing a methacrylic acid ester copolymer and a methacrylic acid ester / acrylic acid ester copolymer as a film forming agent. ing. However, this is also not sufficient in film strength, adhesion, drying speed and gloss.
【０００６】また、特開平４−３４５１４号公報にはセ
レン化合物を単独または抗酸化剤と共に美爪料に配合し
た、爪の黄変を起こすことのない美爪料が提案されてい
る。しかし、セレン化合物を配合することは、原因を取
り除くものではなく、その効果も充分ではない。Further, Japanese Patent Application Laid-Open No. 4-34514 proposes a nail enamel containing a selenium compound alone or in combination with an antioxidant in the nail enamel without causing yellowing of the nail. However, compounding a selenium compound does not eliminate the cause, and its effect is not sufficient.
【０００７】[0007]
【課題を解決するための手段】係る状況に鑑み鋭意研究
を行った結果、特定のスチレン及び／またはメタクリル
酸メチル・アクリル酸エステル・アクリル酸共重合体を
皮膜形成剤として用いることで、爪の黄変を来すことな
く、皮膜強度、乾燥性及び光沢性に優れた美爪料を見い
だし、本発明を完成するに至った。[Means for Solving the Problems] As a result of earnest research in view of such a situation, by using a specific styrene and / or methyl methacrylate / acrylic acid ester / acrylic acid copolymer as a film-forming agent, The present inventors have found a nail enamel excellent in film strength, drying property and glossiness without causing yellowing, and completed the present invention.
【０００８】すなわち、本発明は、特定のスチレン及び
／またはメタクリル酸メチル・アクリル酸エステル・ア
クリル酸共重合体を皮膜形成剤として用いることを特徴
とする美爪料である。That is, the present invention is a nail enamel characterized by using a specific styrene and / or methyl methacrylate / acrylic acid ester / acrylic acid copolymer as a film forming agent.
【０００９】本発明に用いられる特定のスチレン及び／
またはメタクリル酸メチル・アクリル酸エステル・アク
リル酸共重合体は、スチレン及び／またはメタクリル酸
メチル２０〜８５重量％、アクリル酸アルキルエステル
（アルキル鎖長が１〜８）５〜６０重量％及びアクリル
酸７〜３０重量％よりなり、分子量が１００００〜７０
０００である。尚、以下の本文中で、％は特に規定しな
い場合重量％を意味する。Specific styrene and / or
Alternatively, the methyl methacrylate / acrylic acid ester / acrylic acid copolymer is 20 to 85% by weight of styrene and / or methyl methacrylate, 5 to 60% by weight of alkyl acrylate (alkyl chain length is 1 to 8) and acrylic acid. 7 to 30% by weight and a molecular weight of 10,000 to 70
It is 000. In the text below,% means% by weight unless otherwise specified.
【００１０】スチレン及び／またはメタクリル酸メチル
が８５％を超えると、皮膜に柔軟性がなくなり、乾燥時
に剥離し易くなる。スチレン及び／またはメタクリル酸
メチルが２０％未満では、皮膜強度が弱く、耐水性も悪
くなる。スチレンとメタクリル酸メチルの合計量は、２
０〜８５％であるが、どちらか一方を全く含有しなくて
も差し支えない。When the content of styrene and / or methyl methacrylate exceeds 85%, the film loses flexibility and is easily peeled off during drying. If the content of styrene and / or methyl methacrylate is less than 20%, the film strength will be weak and the water resistance will be poor. The total amount of styrene and methyl methacrylate is 2
It is 0 to 85%, but it does not matter if either of them is not contained at all.
【００１１】アクリル酸エステルが６０％を超えると、
皮膜強度が弱く、乾燥速度が遅くなる。アクリル酸エス
テルが５％未満では、皮膜に柔軟性がなく、乾燥すると
剥離しやすくなる。アクリル酸エステルのうち、アルキ
ル鎖長が９以上のエステルを用いると溶剤に溶けにくく
なり、出来た皮膜も白化し易く、美爪料として好ましく
ない。If the acrylic ester exceeds 60%,
The film strength is weak and the drying speed is slow. If the amount of acrylic acid ester is less than 5%, the film has no flexibility and is easily peeled off when dried. Among the acrylic acid esters, if an ester having an alkyl chain length of 9 or more is used, it becomes difficult to dissolve in a solvent and the resulting film is liable to be whitened, which is not preferable as a nail polish.
【００１２】アクリル酸が３０％を超えると、耐水性が
悪い。アクリル酸が７％未満では、皮膜強度が弱く、乾
燥速度が遅くなる。If the acrylic acid content exceeds 30%, the water resistance is poor. If the acrylic acid content is less than 7%, the film strength will be weak and the drying speed will be slow.
【００１３】分子量が１００００未満の場合、皮膜強度
が弱く乾燥速度も遅くなる。分子量が７００００を超え
ると、粘度が高すぎるため爪に塗りにくい。When the molecular weight is less than 10,000, the film strength is weak and the drying speed is slow. When the molecular weight exceeds 70,000, the viscosity is too high and it is difficult to apply to the nail.
【００１４】本発明には、特定のスチレン及び／または
メタクリル酸メチル・アクリル酸エステル・及びアクリ
ル酸共重合体を一種又は二種以上を併せて用いることが
でき、その配合量は美爪料の重量を基準に、５〜５０重
量％の範囲で用いることが好ましい。In the present invention, the specific styrene and / or methyl methacrylate / acrylic acid ester / acrylic acid copolymer can be used alone or in combination of two or more, and the blending amount thereof is the same as that of the nail enamel. It is preferably used in the range of 5 to 50% by weight based on the weight.
【００１５】本発明の美爪料には、特定のスチレン及び
／またはメタクリル酸メチル・アクリル酸エステル・ア
クリル酸共重合体の他には、皮膜形成剤を必要としない
が、粘度調整や顔料分散性向上等の目的で、アルキッド
樹脂、アリルスルホンアミドホルムアルデヒド樹脂、エ
ポキシ樹脂及びロジン変性樹脂等を用いることが出来
る。The nail enamel of the present invention does not require a film-forming agent other than the specific styrene and / or methyl methacrylate / acrylic acid ester / acrylic acid copolymer, but it does not require viscosity adjustment or pigment dispersion. For the purpose of improving the properties, alkyd resin, allyl sulfonamide formaldehyde resin, epoxy resin and rosin-modified resin can be used.
【００１６】また、本発明の美爪料には通常の美爪料に
用いられる可塑剤、顔料、色素、香料、ゲル化剤、紫外
線吸収剤、酸化防止剤、有効成分及び溶剤等の添加物を
適宜配合することが出来る。Further, the nail enamel of the present invention includes additives such as plasticizers, pigments, dyes, fragrances, gelling agents, ultraviolet absorbers, antioxidants, active ingredients and solvents which are used in ordinary nail enamel. Can be appropriately mixed.
【００１７】可塑剤として、例えば、クエン酸エステル
類、フタル酸エステル類及びリン酸エステル類等を挙げ
ることが出来る。顔料としては、例えば、酸化チタン、
酸化鉄、マイカ、雲母チタン及び魚リン箔等を挙げるこ
とが出来る。色素としては、例えば、赤色２０１号、赤
色２０２号、青色１号、黄色２０３号及びそれらのレー
キ類等を挙げることが出来る。ゲル化剤としては、例え
ば、有機変性ベントナイト類等を挙げることが出来る。
紫外線吸収剤としては、例えば、オキシベンゾン、ジベ
ンゾイルフェノン及びＰＡＢＡ誘導体等を挙げることが
出来る。溶剤としては、例えば、酢酸エチル、酢酸ブチ
ル等の酢酸エステル類、ｎ−ブチルアルコール、イソプ
ロピルアルコール（以下、ＩＰＡと略記）等の低級アル
コール、トルエン等の炭化水素類、アセトン等のケトン
類が挙げられる。Examples of the plasticizer include citric acid esters, phthalic acid esters and phosphoric acid esters. Examples of the pigment include titanium oxide,
Examples thereof include iron oxide, mica, titanium mica, and fish phosphorus foil. Examples of the dyes include Red No. 201, Red No. 202, Blue No. 1, Yellow No. 203, and lakes thereof. Examples of the gelling agent include organic modified bentonites.
Examples of ultraviolet absorbers include oxybenzone, dibenzoylphenone, and PABA derivatives. Examples of the solvent include acetic acid esters such as ethyl acetate and butyl acetate, lower alcohols such as n-butyl alcohol and isopropyl alcohol (hereinafter abbreviated as IPA), hydrocarbons such as toluene, and ketones such as acetone. To be
【００１８】[0018]
【実施例】以下、実施例及び比較例によって本発明を詳
細に説明する。本発明は実施例に限定されるものではな
い。尚、実施例中の％は特に指定しない場合重量％を意
味する。EXAMPLES The present invention will be described in detail below with reference to examples and comparative examples. The invention is not limited to the examples. Incidentally,% in the examples means% by weight unless otherwise specified.
【００１９】実施例中に示す、皮膜強度試験、耐水性試
験、乾燥速度及び官能試験は以下の通り実施した。The film strength test, water resistance test, drying rate and sensory test shown in the examples were carried out as follows.
【００２０】（皮膜強度試験）アプリケーターを用いて
硝子板に８０μｍの厚さで試料を塗布し、３０℃にて４
時間乾燥後、鉛筆引っかき試験機を用い、荷重３００
ｇ、接触角４５度の条件で塗膜に傷をつけ得る鉛筆硬度
を測定した。(Film Strength Test) A glass plate was coated with a sample having a thickness of 80 μm using an applicator, and the coating was applied at 30 ° C. for 4 hours.
After drying for 3 hours, use a pencil scratch tester and load 300
The pencil hardness capable of scratching the coating film was measured under the conditions of g and contact angle of 45 degrees.
【００２１】（耐水性試験）アプリケーターを用いて硝
子板に８０μｍの厚さで試料を塗布し、３０℃にて４時
間乾燥後、４０℃の温水に１時間浸漬し白化の度合いを
観察し、 不可逆的な白化及び／または剥離を生じたもの × 白化するが放置すると元に戻るもの △ 変化しないもの ○ とした。(Water resistance test) A glass plate was coated with a sample to a thickness of 80 μm using an applicator, dried at 30 ° C. for 4 hours, and immersed in warm water at 40 ° C. for 1 hour to observe the degree of whitening. Irreversible whitening and / or peeling occurred × Whitening but returning to its original state after standing △ No change ○
【００２２】（乾燥速度）アプリケーターを用いて硝子
板に８０μｍの厚さで試料を塗布し、２５℃、湿度７０
％の恒温室中で触診にて跡が残らなくなった時間で測定
した。(Drying speed) A glass plate was coated with a sample having a thickness of 80 μm using an applicator, and the temperature was 25 ° C. and the humidity was 70 ° C.
% It was measured by palpation in a thermostatic chamber at the time when no trace remained.
【００２３】（官能試験）２０人の女性パネラーによる
３か月の連用試験を行い、「爪の黄色変化のあるな
し」、「塗り易さ」及び「美爪料を塗布した際の仕上が
り」について評価し、「黄変なし」、「塗り易い」及び
「仕上り良い」と回答したパネラーの人数を示した。(Sensory test) A 20-month panel test was carried out by three female panelists for three months, and the results were as follows: "With or without change in yellow color of nails", "Ease of application", and "Finish when applying nail enamel". The number of panelists who answered "No yellowing", "Easy to apply" and "Good finish" was shown.
【００２４】実施例で用いた特定のスチレン及び／また
はメタクリル酸メチル・アクリル酸エステル・アクリル
酸共重合体のモノマー組成（％）及び分子量を表１に示
す。Table 1 shows the monomer composition (%) and molecular weight of the specific styrene and / or methyl methacrylate / acrylic acid ester / acrylic acid copolymer used in the examples.
【００２５】[0025]
【表１】 [Table 1]
【００２６】実施例１〜３ 表２に示した組成の如く本発明の美爪料を調製し、各種
試験を実施した。Examples 1 to 3 The nail enamel of the present invention having the composition shown in Table 2 was prepared and various tests were conducted.
【００２７】[0027]
【表２】 [Table 2]
【００２８】（製法）表２の成分を均一に混合分散し本
発明の美爪料を調製した。(Manufacturing Method) The ingredients of Table 2 were uniformly mixed and dispersed to prepare the nail enamel of the present invention.
【００２９】比較例１ （組成） ニトロセルロース ２０．０ アルキッド樹脂 ５．０ クエン酸アセチル ５．０ トリブチル 酢酸ブチル ３０．０ 酢酸エチル ３０．０ ＩＰＡ １０．０ （製法）上記の成分を均一に混合分散し比較用の美爪料
を調製した。Comparative Example 1 (Composition) Nitrocellulose 20.0 Alkyd resin 5.0 Acetyl citrate 5.0 Tributyl butyl acetate 30.0 Ethyl acetate 30.0 IPA 10.0 (Production method) The above components are uniformly mixed. Dispersion was performed to prepare a nail enamel for comparison.
【００３０】実施例１〜４及び比較例１の皮膜強度試
験、耐水性試験、乾燥速度及び官能試験の結果を表３に
示す。Table 3 shows the results of the film strength test, the water resistance test, the drying rate and the sensory test of Examples 1 to 4 and Comparative Example 1.
【００３１】[0031]
【表３】 [Table 3]
【００３２】表３に示した如く、本発明の美爪料はニト
ロセルロースを用いた比較例１と同等の塗膜特性を有
し、官能試験において爪の黄変が認められなかった。ま
た、ニトロセルロースを用いた比較例１に比べ仕上がり
が良いとの評価を得た。As shown in Table 3, the nail enamel of the present invention has the same coating characteristics as Comparative Example 1 using nitrocellulose, and no yellowing of the nail was observed in the sensory test. In addition, it was evaluated that the finished product was better than that of Comparative Example 1 using nitrocellulose.
【００３３】比較例２〜１０Comparative Examples 2-10
【００３４】[0034]
【表４】 [Table 4]
【００３５】表４に示したモノマー組成の樹脂を用い
て、表５に示す組成にて比較用の美爪料を調製し、各種
試験を実施した。Using the resins having the monomer compositions shown in Table 4, comparative nail preparations having the compositions shown in Table 5 were prepared and various tests were carried out.
【００３６】[0036]
【表５】 [Table 5]
【００３７】（製法）表５の成分を均一に混合分散し比
較用の美爪料を調製した。(Production method) The ingredients shown in Table 5 were uniformly mixed and dispersed to prepare a nail enamel for comparison.
【００３８】比較例２〜１０の皮膜強度試験、耐水性試
験、乾燥速度及び官能試験の結果を表６に示す。Table 6 shows the results of the coating strength test, the water resistance test, the drying rate and the sensory test of Comparative Examples 2 to 10.
【００３９】[0039]
【表６】 [Table 6]
【００４０】表６に示した如く、分子量が小さい樹脂を
用いた比較例２は、皮膜強度が弱く乾燥速度も遅くな
る。分子量が大きすぎる樹脂を用いた比較例３は、粘度
が高すぎるため塗りにくい。アクリル酸エステルが多す
ぎる樹脂を用いた比較例４は、皮膜強度が弱く、乾燥速
度も遅くなる。アクリル酸エステルが少なすぎる樹脂を
用いた比較例５は、乾燥すると皮膜が剥離してしまい皮
膜強度試験及び耐水性試験を実施出来きず、仕上がりが
著しく劣っていた。アクリル酸が多すぎる樹脂を用いた
比較例６は、耐水性が悪かった。アクリル酸が少ない樹
脂を用いた比較例７は、皮膜強度及び乾燥速度の点でや
や劣り、仕上がり状態も好ましくなかった。スチレン及
び／またはメタクリル酸メチルが多すぎる樹脂を用いた
比較例８は、比較例５と同様に乾燥時に剥離してしまい
皮膜強度及び耐水性試験を実施できず仕上がりも好まし
くなかった。スチレン及び／またはメタクリル酸メチル
が少ない樹脂を用いた比較例９は、皮膜強度が弱く、耐
水性もやや悪かった。As shown in Table 6, in Comparative Example 2 in which the resin having a small molecular weight was used, the film strength was weak and the drying speed was slow. Comparative Example 3 using a resin having a too high molecular weight has a too high viscosity and is difficult to apply. Comparative Example 4 using a resin having too much acrylic ester has a weak film strength and a slow drying rate. In Comparative Example 5 using a resin having too little acrylate ester, the film peeled off when dried, and the film strength test and water resistance test could not be carried out, resulting in a markedly poor finish. Comparative Example 6 using a resin having too much acrylic acid had poor water resistance. Comparative Example 7, which used a resin with a small amount of acrylic acid, was slightly inferior in terms of film strength and drying rate, and the finished state was also unfavorable. Comparative Example 8, which used a resin containing too much styrene and / or methyl methacrylate, peeled off during drying as in Comparative Example 5 and could not be subjected to film strength and water resistance tests, and the finish was also unfavorable. Comparative Example 9 using a resin containing a small amount of styrene and / or methyl methacrylate had a weak film strength and a slightly poor water resistance.
【００４１】実施例５ 下記組成の如く本発明の美爪料を調製した。 （組成） 樹脂２ ２５．０ 有機変性ベントナイト １．０ フタル酸ジブチル ８．０ トルエン １０．０ 酢酸エチル ３５．０ 酢酸ブチル １５．０ ＩＰＡ ５．０ 酸化チタン ０．９ 赤色２０２号 ０．１ （製法）上記の成分を均一に混合分散し本発明の美爪料
を調製した。Example 5 A nail enamel of the present invention having the following composition was prepared. (Composition) Resin 2 25.0 Organically modified bentonite 1.0 Dibutyl phthalate 8.0 Toluene 10.0 Ethyl acetate 35.0 Butyl acetate 15.0 IPA 5.0 Titanium oxide 0.9 Red No. 202 0.1 ( Manufacturing method) The above ingredients were uniformly mixed and dispersed to prepare the nail enamel of the present invention.
【００４２】本発明の実施例５について、皮膜強度試
験、耐水性試験、乾燥速度及び官能試験を実施した結
果、何れも優れていた。As a result of conducting a film strength test, a water resistance test, a drying rate and a sensory test on Example 5 of the present invention, all were excellent.
【００４３】[0043]
【発明の効果】以上記載の如く、本発明の特定のスチレ
ン及び／またはメタクリル酸メチル・アクリル酸エステ
ル・アクリル酸共重合体を皮膜形成剤として用いる美爪
料が従来の美爪料と同等の塗膜物性を有し、連続使用に
よっても、爪の黄色変化を来さない優れた美爪料である
ことは明かである。As described above, the nail enamel using the specific styrene and / or methyl methacrylate / acrylic acid ester / acrylic acid copolymer of the present invention as a film-forming agent is equivalent to conventional nail enamel. It is clear that it is an excellent nail enamel that has coating film physical properties and does not cause yellowing of the nail even after continuous use.
Claims (1)
ル２０〜８５重量％、アクリル酸アルキルエステル（ア
ルキル鎖長が１〜８）５〜６０重量％及びアクリル酸７
〜３０重量％からなる共重合体のうち分子量が１０００
０〜７００００のものを皮膜形成剤として用いることを
特徴とする美爪料。1. Styrene and / or methyl methacrylate 20 to 85% by weight, acrylic acid alkyl ester (alkyl chain length 1 to 8) 5 to 60% by weight, and acrylic acid 7
The molecular weight of the copolymer consisting of 30 to 30% by weight is 1000
A nail enamel characterized by using 0 to 70,000 as a film forming agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP09255893A JP3178937B2 (en) | 1993-03-26 | 1993-03-26 | Nail polish |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP09255893A JP3178937B2 (en) | 1993-03-26 | 1993-03-26 | Nail polish |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06279239A true JPH06279239A (en) | 1994-10-04 |
| JP3178937B2 JP3178937B2 (en) | 2001-06-25 |
Family
ID=14057754
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP09255893A Expired - Fee Related JP3178937B2 (en) | 1993-03-26 | 1993-03-26 | Nail polish |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3178937B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5772988A (en) * | 1996-05-10 | 1998-06-30 | Revlon Consumer Products Corporation | Nail enamel compositions from acetoacetoxy methacrylate copolymer |
| US5798426A (en) * | 1996-05-10 | 1998-08-25 | E. I. Du Pont De Nemours And Company | Acrylic polymer compounds |
| US5922334A (en) * | 1998-05-06 | 1999-07-13 | Rohm And Haas Company | Aqueous nail coating composition |
| US6982076B2 (en) | 2000-11-29 | 2006-01-03 | Shiseido Co., Ltd. | Nail care products |
| US9603786B1 (en) | 2016-01-22 | 2017-03-28 | Mycone Dental Supply Co., Inc. | Low haze film formers for top coat nail polish |
-
1993
- 1993-03-26 JP JP09255893A patent/JP3178937B2/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5772988A (en) * | 1996-05-10 | 1998-06-30 | Revlon Consumer Products Corporation | Nail enamel compositions from acetoacetoxy methacrylate copolymer |
| US5798426A (en) * | 1996-05-10 | 1998-08-25 | E. I. Du Pont De Nemours And Company | Acrylic polymer compounds |
| US5922334A (en) * | 1998-05-06 | 1999-07-13 | Rohm And Haas Company | Aqueous nail coating composition |
| US6982076B2 (en) | 2000-11-29 | 2006-01-03 | Shiseido Co., Ltd. | Nail care products |
| US9603786B1 (en) | 2016-01-22 | 2017-03-28 | Mycone Dental Supply Co., Inc. | Low haze film formers for top coat nail polish |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3178937B2 (en) | 2001-06-25 |
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