JPH06199633A - Makeup cosmetic - Google Patents
Makeup cosmeticInfo
- Publication number
- JPH06199633A JPH06199633A JP36035092A JP36035092A JPH06199633A JP H06199633 A JPH06199633 A JP H06199633A JP 36035092 A JP36035092 A JP 36035092A JP 36035092 A JP36035092 A JP 36035092A JP H06199633 A JPH06199633 A JP H06199633A
- Authority
- JP
- Japan
- Prior art keywords
- titanium oxide
- plate
- present
- transparency
- makeup cosmetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、透明感に優れ、青白さ
のない、自然な感触を持つ化粧料に関する。さらに詳し
くは、チタンテトライソプロポキシドの気相加水分解法
によって得られる平均粒径１０〜２５ｎｍのアモルファ
ス型超微粒子酸化チタンと板状酸化チタンおよび／また
は板状酸化亜鉛とを配合したメイクアップ化粧料に関す
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cosmetic composition which is excellent in transparency, has no bluishness, and has a natural feel. More specifically, makeup cosmetics containing amorphous ultrafine particle titanium oxide having an average particle size of 10 to 25 nm obtained by a gas phase hydrolysis method of titanium tetraisopropoxide and plate titanium oxide and / or plate zinc oxide are blended. Regarding fees.
【０００２】[0002]
【従来の技術及び発明が解決しようとする課題】従来、
メイクアップ化粧料において、隠蔽力を出すためにサブ
ミクロン領域の球状酸化チタンが用いられることが多
い。しかし、これらの酸化チタンは青味のかかった色調
を出してしまう傾向にあった。最近、酸化チタンの形状
を球状から板状に変化させることで、青みが少ない優れ
た光学特性が得られることが判ったた。また、酸化亜鉛
についても形状を球状から板状に変化させることで光学
特性が改善されることが判った。2. Description of the Related Art Conventionally, the problems to be solved by the invention
In make-up cosmetics, spherical titanium oxide in the submicron region is often used to provide hiding power. However, these titanium oxides tended to give a bluish color tone. Recently, it has been found that by changing the shape of titanium oxide from a spherical shape to a plate shape, excellent optical characteristics with less blue tint can be obtained. It was also found that the optical characteristics of zinc oxide were improved by changing the shape from spherical to plate-like.
【０００３】一方、超微粒子酸化チタンは従来、青白さ
が強く示されることから、メイクアップ化粧料の色味の
悪化を生じる原因として問題があった。この青白さは、
従来の超微粒子酸化チタンが凝集した結果、青白さを示
す短波長側の可視光線を散乱するために生じている。そ
こで、凝集が極めて少ない超微粒子酸化チタンを、チタ
ンテトライソプロポキシドの気相加水分解法によって得
ることで、透明性が高く、青白さを示さない、アモルフ
ァス超微粒子酸化チタンを開発することに成功した。On the other hand, since ultra-fine titanium oxide has conventionally been strongly bluish, it has been a problem as a cause of deterioration of the tint of makeup cosmetics. This paleness is
As a result of agglomeration of conventional ultrafine particle titanium oxide, it is caused by scattering visible light on the short wavelength side showing bluishness. Therefore, we succeeded in developing amorphous ultrafine particle titanium oxide with high transparency and no bluish white by obtaining ultrafine particle titanium oxide with extremely low aggregation by the gas phase hydrolysis method of titanium tetraisopropoxide. did.
【０００４】そこで、本発明者らは、このアモルファス
型超微粒子酸化チタンと板状酸化チタンおよび／または
板状酸化亜鉛とを組み合わせて配合することで、より透
明感に優れ、青白さのない優れたメイクアップ化粧料が
得られることを見いだした。Therefore, the inventors of the present invention blended the amorphous ultrafine particle titanium oxide with a plate-shaped titanium oxide and / or a plate-shaped zinc oxide in combination, so that they were more transparent and had no bluish whiteness. I found that I could get makeup cosmetics.
【０００５】すなわち、本発明は透明感に優れ、青白さ
のないメイクアップ化粧料を提供することを目的とす
る。That is, an object of the present invention is to provide a makeup cosmetic which is excellent in transparency and has no paleness.
【０００６】[0006]
【課題を解決するための手段】本発明は、チタンテトラ
イソプロポキシドの気相加水分解法によって得られる平
均粒径１０〜２５ｎｍのアモルファス型超微粒子酸化チ
タンと板状酸化チタンおよび／または板状酸化亜鉛とを
配合することを特徴とするメイクアップ化粧料に関す
る。DISCLOSURE OF THE INVENTION The present invention is directed to amorphous ultrafine particle titanium oxide having an average particle diameter of 10 to 25 nm obtained by a gas phase hydrolysis method of titanium tetraisopropoxide, and plate-shaped titanium oxide and / or plate-shaped titanium oxide. The present invention relates to a makeup cosmetic composition characterized by being blended with zinc oxide.
【０００７】以下に本発明の構成を詳説する。本発明で
用いられる超微粒子酸化チタンは、チタンテトライソプ
ロポキシドの気相加水分解法（H.SHIMAKAWA et al.,Cer
amic Powder science IV, ２２巻、１１５頁〜１２０
頁、１９９１年）により製造された、平均粒径１０〜２
５ｎｍのアモルファス型超微粒子酸化チタンである。平
均粒径の測定は、電子顕微鏡（ＴＥＭ）観察により一次
粒子径の平均として求めている。本発明に適用されるア
モルファス型超微粒子酸化チタンの例としては、出光興
産（株）製の出光チタニアシリーズ品等が挙げられる。The structure of the present invention will be described in detail below. The ultrafine titanium oxide used in the present invention is obtained by gas phase hydrolysis of titanium tetraisopropoxide (H.SHIMAKAWA et al., Cer.
amic Powder science IV, Volume 22, pages 115-120
Page, 1991), average particle size 10-2.
It is a 5 nm amorphous type ultrafine particle titanium oxide. The average particle size is measured by observing with an electron microscope (TEM) as an average of primary particle sizes. Examples of amorphous ultrafine titanium oxide particles applicable to the present invention include Idemitsu titania series products manufactured by Idemitsu Kosan Co., Ltd.
【０００８】また、本発明で用いる超微粒子酸化チタン
には、全体の１５重量％以下の範囲で、シリカ、アルミ
ナ、ジルコニア、鉄から選ばれる元素が混合されていて
も良い。The ultrafine titanium oxide particles used in the present invention may contain an element selected from silica, alumina, zirconia, and iron in an amount of 15% by weight or less based on the total weight.
【０００９】本発明で用いられる超微粒子酸化チタンの
配合量は、化粧料１００重量部に対して、０．５〜１２
重量部であり、さらに好ましくは１〜７重量部である。The amount of ultrafine titanium oxide used in the present invention is 0.5 to 12 with respect to 100 parts by weight of the cosmetic.
Parts by weight, and more preferably 1 to 7 parts by weight.
【００１０】本発明で用いられる板状酸化チタン、板状
酸化亜鉛は、長径０．１〜１０μｍ、短径０．１〜１０
μｍ、厚さ０．０３〜３μｍの大きさを持ち、形状が板
状であるものを指す。The plate-like titanium oxide and plate-like zinc oxide used in the present invention have a major axis of 0.1 to 10 μm and a minor axis of 0.1 to 10.
It has a size of μm and a thickness of 0.03 to 3 μm, and has a plate shape.
【００１１】本発明で用いられる板状酸化チタン、板状
酸化亜鉛の配合量は、化粧料１００重量部に対して、
０．５〜３０重量部であり、さらに好ましくは３〜１５
重量部である。The amount of the plate-shaped titanium oxide or plate-shaped zinc oxide used in the present invention is 100 parts by weight of the cosmetic.
0.5 to 30 parts by weight, more preferably 3 to 15
Parts by weight.
【００１２】本発明のメイクアップ化粧料には、上記の
各成分以外に、通常化粧料に用いられる粉体類、繊維、
樹脂、油剤、シリコーン油、界面活性剤、香料、防腐
剤、殺菌剤、溶剤、水等を同時に配合することができ
る。In addition to the above-mentioned components, the makeup cosmetics of the present invention include powders, fibers, which are usually used in cosmetics,
A resin, an oil agent, a silicone oil, a surfactant, a fragrance, an antiseptic agent, a bactericide, a solvent, water and the like can be simultaneously mixed.
【００１３】また、本発明のファンデーションに配合さ
れる粉体類は、シリコーン処理、フッ素化合物処理、脂
肪酸処理、アミノ酸処理、カップリング剤処理等の表面
処理が行ってあっても構わない。The powders incorporated in the foundation of the present invention may be subjected to surface treatment such as silicone treatment, fluorine compound treatment, fatty acid treatment, amino acid treatment and coupling agent treatment.
【００１４】本発明のメイクアップ化粧料の種類として
は、ファンデーション、白粉、頬紅、プレストパウダ
ー、チークカラー、口紅、アイシャドウ、アイライナ
ー、ネイルカラー、ベースファンデーション等が挙げら
れる。The types of makeup cosmetics of the present invention include foundation, white powder, blusher, pressed powder, cheek color, lipstick, eye shadow, eyeliner, nail color, base foundation and the like.
【００１５】[0015]
【実施例】以下、実施例及び比較例によって本発明を詳
細に説明する。尚、実施例に先立ち透明感及び青白さの
評価方法を述べる。２５〜３８歳の男女計８名のパネラ
ーを用い、化粧料を実際に塗布した時の状態を目視観察
し、実施例及び比較例の透明感及び青白さの評価をし
た。その評価はアンケートにて回答してもらった。その
回答の集計結果を表６に示す。EXAMPLES The present invention will be described in detail below with reference to examples and comparative examples. Prior to the examples, a method for evaluating transparency and bluishness will be described. Using eight panelists, a total of eight men and women aged 25 to 38, the state when the cosmetic was actually applied was visually observed, and the transparency and bluishness of the examples and comparative examples were evaluated. The evaluation was answered by a questionnaire. Table 6 shows the result of tabulation of the answers.
【００１６】実施例１ 下記の処方にて、ファンデーションを作成した。Example 1 A foundation was prepared with the following formulation.
【００１７】[0017]
【表１】 [Table 1]
【００１８】粉体成分をヘンシェルミキサーにて混合し
た後、予め混合しておいた液体成分を加え、さらに撹
拌、混合した。ついで、アトマイザーを用いて粉砕を行
った後、金型を用いて打型し、製品とした。After mixing the powder components with a Henschel mixer, the previously mixed liquid components were added and further stirred and mixed. Then, after pulverizing with an atomizer, it was punched with a die to obtain a product.
【００１９】比較例１ 実施例１のアモルファス型超微粒子酸化チタン（一次粒
子径 １２ｎｍ）をルチル型超微粒子酸化チタン（一次
粒子径 ３６ｎｍ）に代えた他は同じ処方でファンデー
ションを作成した。Comparative Example 1 A foundation was prepared with the same formulation except that the amorphous ultrafine particle titanium oxide (primary particle diameter 12 nm) of Example 1 was replaced with rutile type ultrafine titanium oxide (primary particle diameter 36 nm).
【００２０】比較例２ 下記の処方にて、ファンデーションを作成した。Comparative Example 2 A foundation was prepared according to the following formulation.
【００２１】[0021]
【表２】 [Table 2]
【００２２】粉体成分をヘンシェルミキサーにて混合し
た後、予め混合しておいた液体成分を加え、さらに撹
拌、混合した。ついで、アトマイザーを用いて粉砕を行
った後、金型を用いて打型し、製品とした。After the powder components were mixed with a Henschel mixer, the liquid components that had been mixed in advance were added, and the mixture was further stirred and mixed. Then, after pulverizing with an atomizer, it was punched with a die to obtain a product.
【００２３】実施例２ 下記の処方にて、液体化粧料を作成した。Example 2 A liquid cosmetic composition was prepared according to the following formulation.
【００２４】[0024]
【表３】 [Table 3]
【００２５】成分Ａの混合液に成分Ｂを加え６０℃に加
熱した。これに加熱溶解した成分Ｃを加え、冷却した。
得られた化粧料を、容器に充填して製品とした。Component B was added to the mixture of component A and heated to 60 ° C. The component C heated and dissolved was added to this and cooled.
The obtained cosmetic was filled into a container to obtain a product.
【００２６】比較例３ 実施例２の板状酸化チタン（長径６μｍ、短径２．８μ
ｍ、厚さ０．８μｍ）を球状酸化チタン（粒径４μｍ）
に代えた他は同じ処方で液体化粧料を作成した。Comparative Example 3 The plate-shaped titanium oxide of Example 2 (long diameter 6 μm, short diameter 2.8 μ)
m, thickness 0.8 μm) spherical titanium oxide (particle size 4 μm)
Liquid cosmetics were prepared with the same formulation except that
【００２７】実施例３ 下記の処方にて、クリーム状化粧料を作成した。Example 3 A creamy cosmetic was prepared according to the following formulation.
【００２８】[0028]
【表４】 [Table 4]
【００２９】加熱溶解した成分Ａ中に、予め混合した成
分Ｂを加え、撹拌混合した後、冷却した。そして容器に
充填し、製品とした。Ingredient B, which had been preliminarily mixed, was added to ingredient A that had been heated and dissolved, and the mixture was stirred and mixed, and then cooled. Then, it was filled in a container to obtain a product.
【００３０】比較例４ 下記の処方にて、クリーム状化粧料を作成した。Comparative Example 4 A creamy cosmetic composition was prepared according to the following formulation.
【００３１】[0031]
【表５】 [Table 5]
【００３２】加熱溶解した成分Ａ中に、予め混合した成
分Ｂを加え、撹拌混合した後、冷却した。そして容器に
充填し、製品とした。The component B mixed in advance was added to the component A heated and dissolved, and the mixture was stirred and mixed, and then cooled. Then, it was filled in a container to obtain a product.
【００３３】[0033]
【表６】 [Table 6]
【００３４】表６より実施例と比較例を比較すると、実
施例の方が透明感に優れ、青白さが少ないことが判る。From Table 6, a comparison between the examples and the comparative examples shows that the examples are superior in transparency and have less bluish white.
【００３５】[0035]
【発明の効果】以上のことから、本発明は、チタンテト
ライソプロポキシドの気相加水分解法によって得られる
平均粒径１０〜２５ｎｍのアモルファス型超微粒子酸化
チタンと板状酸化チタンおよび／または板状酸化亜鉛と
を配合することで、透明感に優れ、青白さのないメイク
アップ化粧料を提供することは明かである。From the above, the present invention provides an amorphous ultrafine particle titanium oxide having an average particle diameter of 10 to 25 nm and a plate-like titanium oxide and / or a plate obtained by a gas phase hydrolysis method of titanium tetraisopropoxide. It is clear that by adding the particulate zinc oxide, a make-up cosmetic having excellent transparency and no bluishness can be provided.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 土田 幸宏 千葉県袖ヶ浦市長浦駅前６−20−２ ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Yukihiro Tsuchida 6-20-2 Nagaura Station, Sodegaura City, Chiba Prefecture
Claims (1)
水分解法によって得られる平均粒径１０〜２５ｎｍのア
モルファス型超微粒子酸化チタンと、板状酸化チタンお
よび／または板状酸化亜鉛とを配合することを特徴とす
るメイクアップ化粧料。1. Blending amorphous ultrafine particulate titanium oxide having an average particle size of 10 to 25 nm obtained by a gas phase hydrolysis method of titanium tetraisopropoxide with plate titanium oxide and / or plate zinc oxide. Makeup cosmetics characterized by.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP36035092A JPH06199633A (en) | 1992-12-28 | 1992-12-28 | Makeup cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP36035092A JPH06199633A (en) | 1992-12-28 | 1992-12-28 | Makeup cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH06199633A true JPH06199633A (en) | 1994-07-19 |
Family
ID=18469026
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP36035092A Pending JPH06199633A (en) | 1992-12-28 | 1992-12-28 | Makeup cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH06199633A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1142830A1 (en) * | 2000-04-03 | 2001-10-10 | Degussa AG | Nano-sized pyrogenic oxides, process for their preparation and their use |
| US7465431B2 (en) | 2001-08-06 | 2008-12-16 | Degussa Ag | Nanoscalar pyrogenically produced yttrium-zirconium mixed oxide |
-
1992
- 1992-12-28 JP JP36035092A patent/JPH06199633A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1142830A1 (en) * | 2000-04-03 | 2001-10-10 | Degussa AG | Nano-sized pyrogenic oxides, process for their preparation and their use |
| JP2001342011A (en) * | 2000-04-03 | 2001-12-11 | Degussa Ag | Nano size oxide and/or oxide composition obtained through thermo-decomposition of metal and/or metalloid, its manufacturing method, and usage of the oxide and/or oxide composition |
| US7465431B2 (en) | 2001-08-06 | 2008-12-16 | Degussa Ag | Nanoscalar pyrogenically produced yttrium-zirconium mixed oxide |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5968531A (en) | Particulate composite, method of producing thereof, and cosmetic containing particulate composite | |
| US6309627B1 (en) | Cosmetic compositions with agglomerated substrates | |
| WO1988005453A1 (en) | Synthetic mica powder, process for its production, and cosmetics containing said synthetic mica powder | |
| JPH03176411A (en) | Oily solid cosmetic | |
| JP2544200B2 (en) | Cosmetics | |
| JPH09255528A (en) | Solid powder make-up cosmetic | |
| JPS62187405A (en) | Cosmetic | |
| JPH06199633A (en) | Makeup cosmetic | |
| JPH09221411A (en) | Titanium dioxide and composition containing the same | |
| JP2001335410A (en) | Powder cosmetic | |
| JP2000302625A (en) | Solid powder cosmetic | |
| JP3483231B2 (en) | Powder solid makeup cosmetics | |
| JP2880084B2 (en) | Powder cosmetics | |
| JPS63183962A (en) | Synthetic mica powder, production thereof and cosmetic compounded with said synthetic mica powder | |
| JPH08113514A (en) | Composite particles and cosmetic containing the same | |
| JP4516729B2 (en) | Iron phosphate-containing composite and cosmetic containing the same | |
| JP3508031B2 (en) | Composite pigment and cosmetic containing the same | |
| JP2000226316A (en) | Makeup cosmetic | |
| JPS6185309A (en) | Solid powder cosmetic | |
| JPH02311409A (en) | Powdery cosmetic | |
| JPH0848614A (en) | Make-up cosmetic | |
| JP5173424B2 (en) | Cosmetics | |
| JPH06199634A (en) | Cosmetic | |
| JP3454453B2 (en) | Pressed makeup cosmetics | |
| JPH0892030A (en) | Cosmetic |