JPH06113474A - Charging method for nonaqueous secondary battery - Google Patents

Charging method for nonaqueous secondary battery

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Publication number
JPH06113474A
JPH06113474A JP26011592A JP26011592A JPH06113474A JP H06113474 A JPH06113474 A JP H06113474A JP 26011592 A JP26011592 A JP 26011592A JP 26011592 A JP26011592 A JP 26011592A JP H06113474 A JPH06113474 A JP H06113474A
Authority
JP
Japan
Prior art keywords
charging
voltage
battery
current
constant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP26011592A
Other languages
Japanese (ja)
Other versions
JP3213401B2 (en
Inventor
Mikitaka Tamai
幹隆 玉井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanyo Electric Co Ltd
Original Assignee
Sanyo Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sanyo Electric Co Ltd filed Critical Sanyo Electric Co Ltd
Priority to JP26011592A priority Critical patent/JP3213401B2/en
Priority to TW82106452A priority patent/TW228616B/en
Priority to US08/111,976 priority patent/US5442274A/en
Publication of JPH06113474A publication Critical patent/JPH06113474A/en
Application granted granted Critical
Publication of JP3213401B2 publication Critical patent/JP3213401B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PURPOSE:To shorten charging time by considerably reducing degrading in battery performance due to overcharging. CONSTITUTION:Constant-current charging is performed until a first voltage V1 and thereafter pulse charging is started in conformity with the first voltage V1. After the pulse charging, constant-voltage charging is performed with the second voltage V2 which is lower than the first voltage V1. By doing this, the pulse charging is performed in conformity with the first voltage V1, so that a decrease in battery performance can be prevented by charging at a large current. because of this, a drop in the performance of a battery weak against overcharging can be prevented and quick charging can be made in a short time.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、主として非水系二次電
池の充電に使用される充電方法に関し、とくに、充電時
間を短縮して過充電による電池性能の低下を防止できる
急速充電方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a charging method mainly used for charging non-aqueous secondary batteries, and more particularly to a rapid charging method capable of shortening charging time and preventing deterioration of battery performance due to overcharging.

【0002】[0002]

【従来の技術】二次電池の急速充電方法として、定電流
充電した後、定電圧電流に切り換える方法が開発されて
いる(特開平3−251054号公報)。この公報に記
載される充電方法は、電池電圧が設定値になるまでは定
電流充電し、電圧が設定値に上昇した後は、電池の電圧
が異常に上昇して電池性能が低下しないように、定電圧
充電に切り換えるものである。この方法は、定電流充電
するときの充電電流を大きくすることによって満充電す
るまでの時間を短くできる。しかしながら、大電流で充
電するためには、充電装置を大型化する必要があり、装
置がコストアップする。また、電池の最大充電電流は、
電池性能を低下させないように設計する必要がある。電
池の最大充電電流は、電池を満充電する時間を制限す
る。このため、充電電流を大きくする方法では、満充電
時間に制約を受ける。
2. Description of the Related Art As a method of rapidly charging a secondary battery, a method of switching to a constant voltage current after constant current charging has been developed (JP-A-3-251054). The charging method described in this publication performs constant current charging until the battery voltage reaches a set value, and after the voltage rises to the set value, the battery voltage does not rise abnormally and battery performance is not degraded. , To switch to constant voltage charging. In this method, the time until full charge can be shortened by increasing the charging current during constant current charging. However, in order to charge with a large current, it is necessary to upsize the charging device, which increases the cost of the device. Also, the maximum charging current of the battery is
It must be designed so as not to reduce battery performance. The maximum battery charging current limits the time to fully charge the battery. Therefore, in the method of increasing the charging current, the full charging time is restricted.

【0003】この欠点を解消する充電方法が特開平2−
119539号公報に記載されている。この公報に記載
される充電方法は、鉛蓄電池を急速充電するものであ
る。この方法は、電池電圧と充電電流とを図1に示すよ
うに設定している。すなわち、第2の電圧V2よりも多
少高く設定される第1の電圧V1まで定電流充電し、そ
の後に、第2の電圧V2の電圧で定電圧充電するもので
ある。この充電方法は、定電流充電するときの電池の最
終電圧である第1の電圧V1を、定電圧充電する設定電
圧である第2の電圧V2よりも高く設定することによっ
て、鉛蓄電池を満充電する時間を短くするものである。
A charging method that solves this drawback is disclosed in Japanese Patent Application Laid-Open No. HEI 2-
It is described in Japanese Patent Publication No. 119539. The charging method described in this publication is for rapidly charging a lead storage battery. In this method, the battery voltage and the charging current are set as shown in FIG. That is, constant current charging is performed up to the first voltage V1 that is set to be slightly higher than the second voltage V2, and then constant voltage charging is performed with the second voltage V2. In this charging method, the lead-acid battery is fully charged by setting the first voltage V1 which is the final voltage of the battery for constant current charging higher than the second voltage V2 which is the set voltage for constant voltage charging. The time to do is shortened.

【0004】[0004]

【発明が解決しようとする課題】この公報に記載される
方法は、最初から定電圧充電する方法に比較して充電時
間を短くできる。それは、最初から最後まで定電圧充電
すると、次第に電流が減少するのに対し、最初に、第1
の電圧V1までは定電流充電すると、定電流充電によっ
て充電量を多くできるからである。したがって、この方
法は、トータルの充電時間を短縮することができる。さ
らに、この方式の充電方法は、定電流充電における最終
の電池電圧である第1の電圧V1を高くすることによっ
て、充電時間を短くできる。しかしながら、第1の電圧
V1を高くすると、副反応によって、非水系二次電池の
電池としての性能を低下させる。
The method described in this publication can shorten the charging time compared to the method of constant voltage charging from the beginning. When the constant voltage charge is applied from the beginning to the end, the current gradually decreases.
This is because when the constant current charging is performed up to the voltage V1, the charging amount can be increased by the constant current charging. Therefore, this method can reduce the total charging time. Further, in this type of charging method, the charging time can be shortened by increasing the first voltage V1 which is the final battery voltage in constant current charging. However, when the first voltage V1 is increased, a side reaction reduces the performance of the non-aqueous secondary battery as a battery.

【0005】最初から第2の電圧V2で定電圧充電する
と、副反応による弊害を防止できる。しかしながら、ト
ータルの充電時間が長くなる欠点がある。したがって、
この充電方法も、充電時間を短縮することと、電池性能
の低下を防止するとこととは互いに相反する性質であっ
て両者を満足することができない。
If the constant voltage charging is performed with the second voltage V2 from the beginning, the adverse effects due to side reactions can be prevented. However, there is a drawback that the total charging time becomes long. Therefore,
Also in this charging method, shortening the charging time and preventing the deterioration of the battery performance are contradictory properties, and both cannot be satisfied.

【0006】本発明は、さらにこの欠点を解決すること
を目的に開発されたもので、本発明の重要な目的は、過
充電による電池性能の低下を極減して、充電時間を短縮
できる電池の充電方法を提供することにある。
The present invention was developed with the object of further solving this drawback, and an important object of the present invention is to reduce the deterioration of battery performance due to overcharging to a minimum and to shorten the charging time. Is to provide a charging method.

【0007】[0007]

【課題を解決するための手段】本発明の電池の充電方法
は、前述の目的を達成するために、下記の方法で電池を
充電する。すなわち、本発明の方法は、第1の電圧V1
まで定電流充電または準定電流充電した後に、第2の電
圧V2で定電圧充電する充電方法であって、定電流充電
の後に、第1の電圧V1で規制されたパルス充電に移行
し、下記の〜の工程を終了した後に、第1の電圧V
1よりも低い第2の電圧V2で定電圧充電することを特徴
とする。 オン時間に充電電流が設定値以下に達したとき オフ時間の電池電圧が設定値以上に達したとき 一定時間パルス充電した後
In order to achieve the above-mentioned object, the battery charging method of the present invention charges the battery by the following method. That is, the method of the present invention uses the first voltage V1
Is a constant voltage charge or a quasi-constant current charge, and then a constant voltage charge with a second voltage V2. After the constant current charge, a transition is made to a pulse charge regulated with a first voltage V1, After completing steps 1 to 3, the first voltage V
It is characterized by performing constant voltage charging with a second voltage V2 lower than 1. When the charging current reaches the set value or less during the on time When the battery voltage reaches the set value during the off time After pulse charging for a certain period

【0008】[0008]

【作用】本発明の電池の充電方法は、最初に第1の電圧
V1まで定電流充電し、その後、第1の電圧V1に規制し
てパルス充電し、パルス充電の後に第2の電圧V2で定
電圧充電する。すなわち、本発明の充電方法は、最初
に、電池の電圧が第1の電圧V1に上昇するまでは定電
流充電して、短い時間で充電量を多くする。その後、パ
ルス充電して、電池をさらに充電する。この充電工程に
おいて、電池の電圧は第1の電圧V1に規制される。パ
ルス充電の工程において、電池の電圧を第1の電圧V1
に規制して充電するが、充電と休止とを繰り返すので、
副反応による電池性能の低下を防止できる。また、第2
の電圧V2よりも高い電圧である第1の電圧V1に規制し
て充電するので、充電時間を短くできる。パルス充電し
た後、電池の設定電圧を低くして第2の電圧V2で定電
圧充電する。
According to the battery charging method of the present invention, first, constant current charging up to the first voltage V1 is performed, then pulse charging is performed by regulating the voltage to the first voltage V1, and then pulse charging is performed at the second voltage V2. Charge at a constant voltage. That is, in the charging method of the present invention, first, constant current charging is performed until the battery voltage rises to the first voltage V1, and the charging amount is increased in a short time. After that, pulse charging is performed to further charge the battery. In this charging process, the voltage of the battery is regulated to the first voltage V1. In the pulse charging process, the battery voltage is set to the first voltage V1.
It is regulated to charge, but since charging and rest are repeated,
It is possible to prevent deterioration of battery performance due to side reactions. Also, the second
Since the charging is restricted to the first voltage V1 which is higher than the voltage V2, the charging time can be shortened. After pulse charging, the set voltage of the battery is lowered and constant voltage charging is performed with the second voltage V2.

【0009】[0009]

【実施例】以下、本発明の実施例を図面に基づいて説明
する。ただし、以下に示す実施例は、本発明の技術思想
を具体化するための充電方法を例示するものであって、
本発明の充電方法は、充電条件、充電回路、充電装置の
フローチャート、設定電圧等を下記に特定するものでな
い。本発明の電池の充電方法は、特許請求の範囲におい
て、種々の変更を加えることができる。
Embodiments of the present invention will be described below with reference to the drawings. However, the following examples illustrate a charging method for embodying the technical idea of the present invention,
The charging method of the present invention does not specify the charging conditions, the charging circuit, the flowchart of the charging device, the set voltage, etc. below. The battery charging method of the present invention can be modified in various ways within the scope of the claims.

【0010】本発明の充電方法は、図2に示す電圧、電
流カーブで下記のようにして非水系二次電池を充電す
る。 一定の電流で電池の定電流充電を開始する。電池の
電圧が、第2の電圧V2よりも高い第1の電圧V1となる
まで、定電流または準定電流充電する。第1の電圧V1
は、一時的に非水系二次電池の電圧を上昇させても、電
池性能が低下しない電圧に設計される。 電池の電圧が第1の電圧V1に上昇すると、定電流
充電を中止して、パルス充電に切り換える。パルス充電
は、電池の電圧を第1の電圧V1に規制し、電池電圧が
第1の電圧V1よりも高くならないように充電電流を調
整する。パルス充電は、充電と休止とを繰り返すが、そ
の周期は、例えば1msec〜1secの範囲に調整さ
れる。また、パルス充電のデューティーサイクルは、例
えば、10%〜70%、好ましくは30%〜70%の範
囲に設計される。 パルス充電するに従って、電池の開放電圧は上昇
し、また、充電電流も減少する。充電電流が設定値より
も小さくなると、パルス充電を停止して、電池の電圧
を、第1の電圧V1よりも低い第2の電圧V2として定電
圧充電する。第2の電圧V2は、非水系二次電池を過充
電することなく満充電できる電圧に設定される。
In the charging method of the present invention, the non-aqueous secondary battery is charged by the voltage and current curves shown in FIG. 2 as follows. Start constant current charging of battery with constant current. The battery is charged with a constant current or a quasi-constant current until the voltage of the battery becomes a first voltage V1 which is higher than the second voltage V2. First voltage V1
Is designed to a voltage at which the battery performance does not deteriorate even if the voltage of the non-aqueous secondary battery is temporarily increased. When the battery voltage rises to the first voltage V1, constant current charging is stopped and pulse charging is switched to. The pulse charge regulates the battery voltage to the first voltage V1 and adjusts the charging current so that the battery voltage does not become higher than the first voltage V1. In pulse charging, charging and rest are repeated, but the cycle thereof is adjusted within the range of 1 msec to 1 sec, for example. Further, the duty cycle of pulse charging is designed in the range of, for example, 10% to 70%, preferably 30% to 70%. With pulse charging, the open circuit voltage of the battery rises and the charging current also decreases. When the charging current becomes smaller than the set value, the pulse charging is stopped and the voltage of the battery is constant-voltage charged as the second voltage V2 lower than the first voltage V1. The second voltage V2 is set to a voltage at which the non-aqueous secondary battery can be fully charged without overcharging.

【0011】図2の波線は、参考のために、従来の方法
で電池を充電する状態を示している。波線で示す方法
は、最初は第2の電圧V2まで定電流充電した後、第2
の電圧V2に規制して定電圧充電する。
For reference, the wavy line in FIG. 2 shows the state of charging the battery by the conventional method. The method shown by the wavy line is that the constant current charge is first performed up to the second voltage V2, and then the second
The voltage V2 is regulated to a constant voltage.

【0012】さらに、図3は、別の方法で非水系二次電
池を充電するときの電池の電圧、充電電流の特性を示し
ている。このグラフに示す充電方法は、下記の工程で非
水系二次電池を満充電する。この図において波線は従来
の方法で電池を充電する状態を示している。とは、
前述の図2に示す方法と同じとする。 パルス充電するに従って、電池の開放電圧は上昇
し、また、充電電流も減少する。電池の開放電圧が設定
値よりも高くなると、パルス充電を停止して、電池の電
圧を、第1の電圧V1よりも低い第2の電圧V2にとして
定電圧充電する。
Further, FIG. 3 shows the characteristics of the voltage and charging current of the battery when the non-aqueous secondary battery is charged by another method. The charging method shown in this graph fully charges the non-aqueous secondary battery in the following steps. In this figure, the wavy line indicates the state of charging the battery by the conventional method. Is
The method is the same as the method shown in FIG. With pulse charging, the open circuit voltage of the battery rises and the charging current also decreases. When the open circuit voltage of the battery becomes higher than the set value, the pulse charging is stopped and the voltage of the battery is constant voltage charged as the second voltage V2 lower than the first voltage V1.

【0013】さらに、図4は、別の方法で非水系二次電
池を充電するときの電池の電圧、充電電流の特性を示し
ている。このグラフに示す充電方法は、下記の工程で非
水系二次電池を満充電する。この図も波線は従来の方法
で電池を充電する状態を示している。 この工程は、前述の図2に示す方法と同じとする。 電池の電圧が第1の電圧V1に上昇すると、定電流
充電を中止して、パルス充電に切り換える。パルス充電
は、電池の電圧を第1の電圧V1に規制し、電池電圧が
第1の電圧V1よりも高くならないように充電電流を調
整する。パルス充電を開始すると、タイマーがカウント
を開始する。 一定時間パルス充電して、タイマーがタイムアップ
すると、電池の電圧を、第1の電圧V1よりも低い第2
の電圧V2にとして定電圧充電する。
Further, FIG. 4 shows the characteristics of the battery voltage and charging current when the non-aqueous secondary battery is charged by another method. The charging method shown in this graph fully charges the non-aqueous secondary battery in the following steps. Also in this figure, the wavy line shows the state of charging the battery by the conventional method. This step is the same as the method shown in FIG. When the battery voltage rises to the first voltage V1, constant current charging is stopped and pulse charging is switched to. The pulse charge regulates the battery voltage to the first voltage V1 and adjusts the charging current so that the battery voltage does not become higher than the first voltage V1. When pulse charging is started, the timer starts counting. When the timer is timed up by pulse charging for a certain period of time, the battery voltage is changed to the second voltage lower than the first voltage V1.
A constant voltage is charged to the voltage V2.

【0014】以上の方法で電池を充電する回路のブロッ
ク図を図5に、配線図を図6に示している。これ等の図
に示す充電回路は、リチウムイオン二次電池等の非水系
二次電池を充電するものである。この充電回路は、充電
用の電源1と、電源1の出力を制御して電池の充電状態
を制御する充電制御手段2とを備える。
A block diagram of a circuit for charging the battery by the above method is shown in FIG. 5, and a wiring diagram is shown in FIG. The charging circuit shown in these figures charges a non-aqueous secondary battery such as a lithium ion secondary battery. This charging circuit includes a power source 1 for charging and a charge control unit 2 that controls the output of the power source 1 to control the charging state of the battery.

【0015】電源1は、AC100Vの商用電源に含ま
れる雑音を除去する入力フィルター3と、入力された交
流を直流に変換する整流回路4と、整流回路4の直流を
高周波の交流に変換するスイッチング部5であるトラン
ジスター6と、交流を所定の電圧に変換する変換トラン
ス7と、変換トランス7の交流出力を整流して平滑な直
流に変換する整流平滑回路8と、スイッチング部5を制
御して直流出力を制御するPWM制御回路9と、充電制
御手段2からの信号を、電気的に絶縁してPWM制御回
路9に入力するフォトカプラ10とを備えている。
The power supply 1 includes an input filter 3 for removing noise contained in a commercial power supply of 100 VAC, a rectifier circuit 4 for converting the input alternating current into direct current, and a switching for converting the direct current of the rectifier circuit 4 into high frequency alternating current. The transistor 6, which is the unit 5, the conversion transformer 7 that converts alternating current into a predetermined voltage, the rectifying and smoothing circuit 8 that rectifies the alternating current output of the converting transformer 7 into smooth DC, and controls the switching unit 5. A PWM control circuit 9 that controls a DC output and a photocoupler 10 that electrically insulates a signal from the charging control unit 2 and inputs the signal to the PWM control circuit 9 are provided.

【0016】充電制御手段2は、スイッチング素子11
と、スイッチング素子11のオンオフを制御する発振回
路19と、出力調整回路12と、演算回路13と、電圧
検出回路14と、電流検出回路15とを備える。
The charging control means 2 includes a switching element 11
An oscillation circuit 19 for controlling ON / OFF of the switching element 11, an output adjustment circuit 12, an arithmetic circuit 13, a voltage detection circuit 14, and a current detection circuit 15.

【0017】スイッチング素子11は、演算回路13の
出力でオンオフに切り換えられる。スイッチング素子1
1は、オンの状態で、電池を電源の出力に接続して充電
する。オフになると、電池を電源から分離して充電を休
止する。
The switching element 11 is turned on / off by the output of the arithmetic circuit 13. Switching element 1
1 is in the on state and connects the battery to the output of the power supply to charge. When turned off, it disconnects the battery from the power source and suspends charging.

【0018】発振回路19は、パルス充電するときに、
スイッチング素子11を一定の周期でオンオフする。発
振回路19は、好ましくは、1msec〜1secの周
期で”H”と”L”とを繰り返す矩形波を発振する。矩
形波のデューティーサイクルは、通常は10%〜70
%、好ましくは30%〜70%に設計される。発振回路
19の出力波形が”H”のときスイッチング素子11を
オンとし、”L”のときには、スイッチング素子11を
オフとする。
The oscillator circuit 19, when pulse charging,
The switching element 11 is turned on / off at a constant cycle. The oscillator circuit 19 preferably oscillates a rectangular wave that repeats "H" and "L" in a cycle of 1 msec to 1 sec. The duty cycle of square wave is usually 10% to 70
%, Preferably 30% to 70%. When the output waveform of the oscillation circuit 19 is "H", the switching element 11 is turned on, and when it is "L", the switching element 11 is turned off.

【0019】出力調整回路12は、定電圧充電回路16
と、定電流充電回路17とを備える。定電圧充電回路1
6と定電流充電回路17は作動アンプ16A、17Aを
備える。
The output adjusting circuit 12 is a constant voltage charging circuit 16
And a constant current charging circuit 17. Constant voltage charging circuit 1
6 and the constant current charging circuit 17 include operation amplifiers 16A and 17A.

【0020】定電圧充電回路16の作動アンプ16A
は、+側入力端子を、分圧抵抗を介して電池に接続して
いる。−側入力端子は、切換スイッチ18を介して基準
電源E1、E2に接続される。作動アンプ16A、17A
の出力はダイオードを介してフォトカプラ10に接続さ
れている。
Operation amplifier 16A of constant voltage charging circuit 16
Connects the + side input terminal to the battery via a voltage dividing resistor. The-side input terminal is connected to the reference power sources E1 and E2 via the changeover switch 18. Operation amplifier 16A, 17A
Is connected to the photocoupler 10 via a diode.

【0021】この定電圧充電回路16は、作動アンプ1
6Aの+側入力端子の電圧、すなわち電池の分圧電圧
を、−側に接続された基準電圧に比較して、作動アンプ
16Aの出力を+−に反転させる。電池の電圧が設定電
圧よりも高くなると、+側の電圧が−側の基準電圧より
も高くなる。そうすると、作動アンプ16Aの出力は+
となり、ダイオードに電流が流れなくなってフォトカプ
ラ10の発光ダイオードは発光しなくなる。この状態に
なると、PWM制御回路9はスイッチング部5であるト
ランジスター6を制御して出力を低下させる。定電圧充
電回路16の基準電圧E1は、電池の第1の電圧V1を決
定する。基準電圧E2は、電池の第2の電圧V2を決定す
る。
This constant-voltage charging circuit 16 includes an operational amplifier 1
The voltage of the + input terminal of 6A, that is, the divided voltage of the battery is compared with the reference voltage connected to the-side, and the output of the operational amplifier 16A is inverted to +-. When the battery voltage becomes higher than the set voltage, the + side voltage becomes higher than the − side reference voltage. Then, the output of the operational amplifier 16A is +
Therefore, no current flows through the diode, and the light emitting diode of the photocoupler 10 does not emit light. In this state, the PWM control circuit 9 controls the transistor 6 which is the switching unit 5 to reduce the output. The reference voltage E1 of the constant voltage charging circuit 16 determines the first voltage V1 of the battery. The reference voltage E2 determines the second voltage V2 of the battery.

【0022】定電流充電回路17は、作動アンプ17A
の+側入力端子を電流検出抵抗に接続し、−側を基準電
源に接続している。この回路は、電池の充電電流が設定
値よりも大きくなると、作動アンプ17Aの+側入力端
子の電圧が−側の基準電圧より高くなる。この状態で作
動アンプ17Aは出力電圧を+とし、ダイオードを逆バ
イアスとしてフォトカプラ10の発光ダイオードを発光
させなくする。この状態で、PWM制御回路9はトラン
ジスター6を制御して出力を低く制御して、電池の充電
電流を少なくする。したがって、定電流充電回路17
は、電池の充電電流が設定値よりも大きくなるのを防止
して、定電流充電する。
The constant current charging circuit 17 includes an operational amplifier 17A.
The + input terminal of is connected to the current detection resistor and the-side is connected to the reference power supply. In this circuit, when the charging current of the battery becomes larger than the set value, the voltage at the + side input terminal of the operational amplifier 17A becomes higher than the − side reference voltage. In this state, the operational amplifier 17A sets the output voltage to +, and the diode is reverse biased so that the light emitting diode of the photocoupler 10 does not emit light. In this state, the PWM control circuit 9 controls the transistor 6 to control the output to be low to reduce the charging current of the battery. Therefore, the constant current charging circuit 17
Will prevent the charging current of the battery from becoming larger than the set value and perform constant current charging.

【0023】演算回路13は、電圧検出回路14と電流
検出回路15の出力信号を演算処理して、発振回路19
と、切換スイッチ18とを切り換える。演算回路13は
充電をスタートするときに発振回路19の出力を強制的
に”H”として、スイッチング素子11をオンとし、充
電を完了すると発振回路19の出力を”L”としてスイ
ッチング素子11をオフにする。また、演算回路13
は、定電圧充電の設定電圧をE1とE2に切り換えるとき
に、切換スイッチ18を制御する。さらに、演算回路1
3はタイマー(図示せず)を内蔵しており、タイマー
と、電圧検出回路14と、電流検出回路15とから入力
される信号を処理して、発振回路19を介してスイッチ
ング素子11を制御し、さらに、切換スイッチ18も切
り換える。
The arithmetic circuit 13 arithmetically processes the output signals of the voltage detection circuit 14 and the current detection circuit 15 to generate an oscillation circuit 19
And the changeover switch 18 are switched. The arithmetic circuit 13 forcibly sets the output of the oscillation circuit 19 to "H" to turn on the switching element 11 when starting charging, and when the charging is completed, sets the output of the oscillation circuit 19 to "L" to turn off the switching element 11. To In addition, the arithmetic circuit 13
Controls the changeover switch 18 when the set voltage for constant voltage charging is switched between E1 and E2. Furthermore, the arithmetic circuit 1
3 includes a timer (not shown), processes a signal input from the timer, the voltage detection circuit 14, and the current detection circuit 15, and controls the switching element 11 via the oscillation circuit 19. Further, the changeover switch 18 is also changed over.

【0024】演算回路13は、電池電圧が第1の電圧V
1に上昇するまでは、定電圧充電回路16の設定電圧を
E1とする。電池電圧が第1の電圧V1に上昇すると、発
振回路19を発振状態として、スイッチング素子を一定
の周期でオンオフして、電池をパルス充電する。電池の
充電電流が設定値以下となり、あるいは、電池の開放電
圧が設定値なり、あるいはまた、タイマーがカウントを
終了すると、切換スイッチ18を制御して、設定電圧を
E1からE2に低下させる。
In the arithmetic circuit 13, the battery voltage is the first voltage V
Until it rises to 1, the set voltage of the constant voltage charging circuit 16 is E1. When the battery voltage rises to the first voltage V1, the oscillating circuit 19 is put into an oscillating state, the switching element is turned on and off at a constant cycle, and the battery is pulse-charged. When the charging current of the battery becomes equal to or less than the set value, the open voltage of the battery becomes the set value, or when the timer finishes counting, the changeover switch 18 is controlled to decrease the set voltage from E1 to E2.

【0025】さらに、演算回路13は、電流検出回路1
5から電池の充電電流を検出し、電池の充電電流が小さ
くなって電池が満充電になると、発振回路19の出力
を”L”として、スイッチング素子11をオフにして充
電を停止する。また、演算回路13は、パルス充電から
定電圧充電に切り換えた後、一定時間充電してスイッチ
ング素子11をオフにすることもできる。
Further, the arithmetic circuit 13 is the current detection circuit 1
When the battery charging current is detected from 5 and the battery charging current becomes small and the battery is fully charged, the output of the oscillation circuit 19 is set to "L" and the switching element 11 is turned off to stop charging. Further, the arithmetic circuit 13 can also turn off the switching element 11 by charging for a certain period of time after switching from pulse charging to constant voltage charging.

【0026】この充電回路は、図7に示すフローチャー
トでリチウムイオン二次電池等の非水系二次電池を充電
する。このフローチャートは、図2に示す電圧、電流特
性で非水系二次電池を充電する。
This charging circuit charges a non-aqueous secondary battery such as a lithium ion secondary battery according to the flow chart shown in FIG. This flowchart charges the non-aqueous secondary battery with the voltage-current characteristics shown in FIG.

【0027】(1) 充電を開始する(n1)。 (2) 電池電圧Vをサンプリングする(n2)。 (3) 電池電圧Vを第1の電圧V1に比較する。電池電圧
Vが第1の電圧V1よりも低いと、(2)の工程にループす
る(n3)。 (4) 電池電圧Vが第1の電圧V1を電圧以上であると、
パルス充電を開始する(n4)。 (5) パルス充電するときに、充電時における電流Iを
サンプリングする(n5)。 (6) 充電電流Iが設定電流IAよりも大きいと、(5)に
ループする(n6)。 (7) 充電電流Iが設定電流IA以下になると、パルス充
電を中止する(n7)。 (8) 演算回路で切換スイッチ18を制御して、設定電
圧を第1の電圧V1から第2の電圧V2に切り換える(n
8)。 (9) 電池電圧を第2の電圧V2に規制して、定電圧充電
する(n9)。 この工程でいつまでも定電圧充電することもできるが、
図7に示すように、充電電流が一定以下になったことを
検出し、あるいは、一定時間定電圧充電した後に充電を
停止することもできる。
(1) Start charging (n1). (2) The battery voltage V is sampled (n2). (3) Compare the battery voltage V with the first voltage V1. When the battery voltage V is lower than the first voltage V1, the process loops to the step (2) (n3). (4) When the battery voltage V is equal to or higher than the first voltage V1,
Pulse charging is started (n4). (5) During pulse charging, the current I during charging is sampled (n5). (6) If the charging current I is larger than the set current IA, the process loops to (5) (n6). (7) When the charging current I becomes equal to or less than the set current IA, the pulse charging is stopped (n7). (8) The changeover switch 18 is controlled by the arithmetic circuit to change the set voltage from the first voltage V1 to the second voltage V2 (n
8). (9) The battery voltage is regulated to the second voltage V2, and constant voltage charging is performed (n9). In this process, you can charge the battery at a constant voltage forever,
As shown in FIG. 7, it is also possible to detect that the charging current has dropped below a certain level or stop the charging after performing constant voltage charging for a certain period of time.

【0028】さらに図8に示すフローチャートでリチウ
ムイオン二次電池等の非水系二次電池を充電する。この
フローチャートは、図3に示す電圧、電流特性、すなわ
ち、パルス充電する時に電池の開放電圧が設定電圧VA
よりも高くなると、パルス充電を停止して非水系二次電
池を充電する。
Further, a non-aqueous secondary battery such as a lithium ion secondary battery is charged according to the flow chart shown in FIG. This flow chart shows the voltage and current characteristics shown in FIG. 3, that is, the open circuit voltage of the battery during pulse charging is the set voltage VA.
When it becomes higher than that, pulse charging is stopped and the non-aqueous secondary battery is charged.

【0029】(1) 充電を開始する(n1)。 (2) 電池電圧Vをサンプリングする(n2)。 (3) 電池電圧Vを第1の電圧V1に比較する。電池電圧
Vが第1の電圧V1よりも低いと、(2)の工程にループす
る(n3)。 (4) 電池電圧Vが第1の電圧V1を電圧以上であると、
パルス充電を開始する(n4)。 (5) パルス充電するときに、充電時における電池の開
放電圧VOFF、すなわち、電池を充電しない時の電圧を
サンプリングする(n5)。 (6) 電池の開放電圧VOFFが設定電圧VAよりも小さい
と、(5)にループする(n6)。 (7) 開放電圧VOFFが設定電圧VA以上になると、パル
ス充電を中止する(n7)。 (8) 演算回路で切換スイッチを制御して、設定電圧を
第1の電圧V1から第2の電圧V2に切り換える(n
8)。 (9) 電池電圧を第2の電圧V2に規制して、定電圧充電
する(n9)。 この場合においても、図7に示す先の実施例と同様に、
充電電流が一定以下になったことを検出し、あるいは、
一定時間定電圧充電した後に充電を停止することもでき
る。
(1) Start charging (n1). (2) The battery voltage V is sampled (n2). (3) Compare the battery voltage V with the first voltage V1. When the battery voltage V is lower than the first voltage V1, the process loops to the step (2) (n3). (4) When the battery voltage V is equal to or higher than the first voltage V1,
Pulse charging is started (n4). (5) During pulse charging, the open circuit voltage VOFF of the battery during charging, that is, the voltage when the battery is not charged is sampled (n5). (6) If the open circuit voltage VOFF of the battery is smaller than the set voltage VA, the loop loops to (5) (n6). (7) When the open circuit voltage VOFF becomes equal to or higher than the set voltage VA, the pulse charging is stopped (n7). (8) The arithmetic circuit controls the changeover switch to change the set voltage from the first voltage V1 to the second voltage V2 (n
8). (9) The battery voltage is regulated to the second voltage V2, and constant voltage charging is performed (n9). Also in this case, similarly to the previous embodiment shown in FIG.
Detects that the charging current has dropped below a certain level, or
It is also possible to stop charging after constant-voltage charging for a certain period of time.

【0030】さらまた、パルス充電する時間をタイマー
でセットして、パルス充電をストップすることもでき
る。この場合、図7および図8に示すフローチャートに
おいて、(5)〜(7)の工程(n5〜n7)を下記のように
してパルス充電をストップする。 (5) タイマーのカウントを開始させる。 (6) タイマーが設定経過したかどうかを判定し、設定
時間経過していないと、(5)にループする。 (7) タイマーが設定時間経過すると、パルス充電をス
トップする。 この工程は、(1)〜(4)と、(8)および(9)のフローチャー
トは図7と図8と同様にする。
Furthermore, the time for pulse charging can be set by a timer to stop the pulse charging. In this case, in the flowcharts shown in FIGS. 7 and 8, the pulse charging is stopped in the steps (5) to (7) (n5 to n7) as described below. (5) Start timer counting. (6) Judges whether the timer has passed the setting. If the set time has not passed, loops to (5). (7) When the timer has passed the set time, pulse charging is stopped. In this step, the flowcharts of (1) to (4) and (8) and (9) are the same as those in FIGS. 7 and 8.

【0031】[0031]

【発明の効果】本発明の電池の充電方法は、電池の過充
電を防止して、短時間に急速充電できる優れた特長を実
現する。とくに、本発明の充電方法は、非水系二次電池
のように過充電すると電池性能が低下しやすい電池を、
過充電によって電池性能を低下させることなく、短時間
で急速充電できる特長がある。それは、本発明の充電方
法が、一時的には超過電圧となる第1の電圧V1まで定
電流充電をした後、第1の電圧V1に規制して充電と休
止とを繰り返すパルス充電をし、その後の第1の電圧V
1よりも低い設定電圧である第2の電圧V2に規制して定
電圧充電するからである。超過電圧である第1の電圧V
1に規制してパルス充電する工程は、電池の電圧を高く
設定して大電流で充電するので、短時間に急速充電でき
るが、充電と休止とを繰り返すので、副反応等によって
非水系二次電池の性能が低下するのを効果的に防止でき
る。本発明の電池の充電方法は、電池の過充電を防止で
きることに加えて、充電時間を短縮できるという、互い
に相反する特長を実現することができる。
The battery charging method of the present invention prevents battery overcharging and realizes an excellent feature that allows rapid charging in a short time. In particular, the charging method of the present invention uses a battery whose battery performance is likely to deteriorate when overcharged, such as a non-aqueous secondary battery,
It has the feature that it can be charged rapidly in a short time without degrading the battery performance due to overcharging. This is because the charging method of the present invention performs constant-current charging up to a first voltage V1 which is temporarily an overvoltage, then regulates the voltage to the first voltage V1 and repeats pulse charging and rest, After that, the first voltage V
This is because the second voltage V2, which is a set voltage lower than 1, is regulated and the constant voltage charging is performed. First voltage V that is an overvoltage
In the process of controlling the pulse charging to 1 and pulse charging, the battery voltage is set high and charging is performed with a large current, so quick charging can be performed in a short time, but since charging and rest are repeated, non-aqueous secondary It is possible to effectively prevent deterioration of the battery performance. INDUSTRIAL APPLICABILITY The battery charging method of the present invention can prevent the battery from being overcharged, and can realize the contradictory features that the charging time can be shortened.

【図面の簡単な説明】[Brief description of drawings]

【図1】従来の充電方法の電圧、電流特性を示すグラフFIG. 1 is a graph showing voltage and current characteristics of a conventional charging method.

【図2】本発明の実施例にかかる充電方法の電圧、電流
特性を示すグラフ
FIG. 2 is a graph showing voltage-current characteristics of the charging method according to the example of the present invention.

【図3】本発明の実施例にかかる充電方法の電圧、電流
特性を示すグラフ
FIG. 3 is a graph showing voltage-current characteristics of the charging method according to the example of the present invention.

【図4】本発明の実施例にかかる充電方法の電圧、電流
特性を示すグラフ
FIG. 4 is a graph showing voltage-current characteristics of a charging method according to an example of the present invention.

【図5】本発明の充電方法に使用する充電回路のブロッ
ク線図
FIG. 5 is a block diagram of a charging circuit used in the charging method of the present invention.

【図6】本発明の充電方法に使用する充電回路のブロッ
ク線図
FIG. 6 is a block diagram of a charging circuit used in the charging method of the present invention.

【図7】図2に示す電圧、電流特性で電池を充電するフ
ローチャート
FIG. 7 is a flowchart for charging a battery with the voltage-current characteristics shown in FIG.

【図8】図3に示す電圧、電流特性で電池を充電するフ
ローチャート
FIG. 8 is a flowchart for charging a battery with the voltage-current characteristics shown in FIG.

【符号の説明】[Explanation of symbols]

1…電源 2…充電制御手段 3…入力フィルター 4…整流回路 5…スイッチング部 6…トランジスター 7…変換トランス 8…整流平滑回路 9…PWM制御回路 10…フォトカプラ 11…スイッチング素子 12…出力調整回路 13…演算回路 14…電圧検出回路 15…電流検出回路 16…定電圧充電回路 16A…作動アンプ 17…定電流充電回路 17A…作動アンプ 18…切換スイッチ 19…発振回路 DESCRIPTION OF SYMBOLS 1 ... Power supply 2 ... Charge control means 3 ... Input filter 4 ... Rectifier circuit 5 ... Switching part 6 ... Transistor 7 ... Conversion transformer 8 ... Rectification smoothing circuit 9 ... PWM control circuit 10 ... Photo coupler 11 ... Switching element 12 ... Output adjustment circuit 13 ... Arithmetic circuit 14 ... Voltage detection circuit 15 ... Current detection circuit 16 ... Constant voltage charging circuit 16A ... Operation amplifier 17 ... Constant current charging circuit 17A ... Operation amplifier 18 ... Changeover switch 19 ... Oscillation circuit

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 非水系二次電池の充電方法において、第
1の電圧まで定電流または準定電流充電し、第1の電圧
で規制されたパルス充電に移行し、オン時間に充電電流
が設定値以下に達したときにパルス充電を終了し、第1
の電圧よりも低い第2の電圧で定電圧充電することを特
徴とする非水系二次電池の充電方法。
1. A method for charging a non-aqueous secondary battery, wherein constant-current or quasi-constant-current charging is performed up to a first voltage, pulse charging regulated by the first voltage is performed, and a charging current is set at an on-time. When it reaches below the threshold value, pulse charging is terminated and the first
A method for charging a non-aqueous secondary battery, which comprises performing constant voltage charging at a second voltage lower than the above voltage.
【請求項2】 非水系二次電池の充電方法において、第
1の電圧まで定電流または準定電流充電し、第1の電圧
で規制されたパルス充電に移行し、オフ時間の電池電圧
が設定値以上に達したときにパルス充電を終了し、第1
の電圧よりも低い第2の電圧で定電圧充電することを特
徴とする非水系二次電池の充電方法。
2. A method of charging a non-aqueous secondary battery, wherein constant-current or quasi-constant-current charging is performed up to a first voltage, pulse charging regulated by the first voltage is performed, and a battery voltage for an off time is set. When it reaches or exceeds the value, pulse charging is terminated and the first
A method for charging a non-aqueous secondary battery, which comprises performing constant voltage charging at a second voltage lower than the above voltage.
【請求項3】 非水系二次電池の充電方法において、第
1の電圧まで定電流または準定電流充電し、第1の電圧
で規制されたパルス充電に移行し、一定時間充電した後
パルス充電を終了し、第1の電圧よりも低い第2の電圧
で定電圧充電することを特徴とする非水系二次電池の充
電方法。
3. A method of charging a non-aqueous secondary battery, wherein constant-current or quasi-constant-current charging is performed up to a first voltage, pulse charging regulated by the first voltage is performed, and charging is performed for a certain period of time and then pulse charging is performed. And charging at a constant voltage with a second voltage lower than the first voltage, the method for charging a non-aqueous secondary battery.
JP26011592A 1992-08-27 1992-09-29 Charging method for non-aqueous secondary batteries Expired - Fee Related JP3213401B2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP26011592A JP3213401B2 (en) 1992-09-29 1992-09-29 Charging method for non-aqueous secondary batteries
TW82106452A TW228616B (en) 1992-08-27 1993-08-12 Method for charging a secondary cell
US08/111,976 US5442274A (en) 1992-08-27 1993-08-26 Rechargeable battery charging method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP26011592A JP3213401B2 (en) 1992-09-29 1992-09-29 Charging method for non-aqueous secondary batteries

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US5654622A (en) * 1995-02-16 1997-08-05 Sanyo Electric Co., Ltd. Secondary battery charging method and apparatus which controls protecting voltage level of battery protecting circuit
US5684386A (en) * 1994-10-20 1997-11-04 Sanyo Electric Co. Ltd. Charging method of a secondary battery
US5747969A (en) * 1995-11-21 1998-05-05 Sanyo Electric Co., Ltd. Method of charging a rechargeable battery with pulses of a predetermined amount of charge
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US5808447A (en) * 1996-02-29 1998-09-15 Sanyo Electric Co., Ltd. Pulse charging method for rechargeable batteries
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US6087810A (en) * 1995-10-24 2000-07-11 Matsushita Electric Industrial Co., Ltd. Constant current and constant voltage battery charger
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US5808447A (en) * 1996-02-29 1998-09-15 Sanyo Electric Co., Ltd. Pulse charging method for rechargeable batteries
US5828202A (en) * 1996-02-29 1998-10-27 Sanyo Electric Co., Ltd. Battery apparatus
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US6313612B1 (en) 1999-03-18 2001-11-06 Seiko Epson Corporation Electronic device, electronic device to be charged and method of controlling electronic devices
JP2003087990A (en) * 2001-09-14 2003-03-20 Ricoh Co Ltd Charging circuit for secondary battery
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US7205748B2 (en) 2001-09-14 2007-04-17 Ricoh Company, Ltd. Charging circuit for secondary battery
US7274171B2 (en) 2001-09-14 2007-09-25 Ricoh Company, Ltd. Charging circuit for secondary battery
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JP2003092843A (en) * 2001-09-20 2003-03-28 Ricoh Co Ltd Charging circuit of secondary battery
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JP2007311107A (en) * 2006-05-17 2007-11-29 Toshiba Corp Method for charging secondary cell
JP2007325324A (en) * 2006-05-30 2007-12-13 Matsushita Electric Ind Co Ltd Charging system, battery pack and its charging method
US8193777B2 (en) 2006-12-26 2012-06-05 Panasonic Corporation Non-aqueous electrolyte secondary battery charging method, electronic device, battery pack, and charging device
KR20160063526A (en) * 2014-11-26 2016-06-07 주식회사 엘란기어스 Multistage charging method for Rechargeable Batteries and multistage charging device for rechargeable Batteries
WO2016116437A1 (en) * 2015-01-19 2016-07-28 Leopold Schoeller Battery charging method
KR20170142055A (en) * 2016-06-16 2017-12-27 주식회사 엘지화학 Apparatus and method for charging battery
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US11327119B2 (en) 2016-07-21 2022-05-10 Petalite Limited Battery charging circuit and method
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