JPH0598553A - Fiber structure and corrugated board - Google Patents

Fiber structure and corrugated board

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Publication number
JPH0598553A
JPH0598553A JP3874292A JP3874292A JPH0598553A JP H0598553 A JPH0598553 A JP H0598553A JP 3874292 A JP3874292 A JP 3874292A JP 3874292 A JP3874292 A JP 3874292A JP H0598553 A JPH0598553 A JP H0598553A
Authority
JP
Japan
Prior art keywords
fiber
thermoplastic polymer
warp
yarn
yarns
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP3874292A
Other languages
Japanese (ja)
Other versions
JP3027469B2 (en
Inventor
Kenji Yamamoto
賢二 山本
Akimitsu Ouchi
章光 大内
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kanebo Ltd
Original Assignee
Kanebo Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kanebo Ltd filed Critical Kanebo Ltd
Priority to JP3874292A priority Critical patent/JP3027469B2/en
Publication of JPH0598553A publication Critical patent/JPH0598553A/en
Application granted granted Critical
Publication of JP3027469B2 publication Critical patent/JP3027469B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PURPOSE:To obtain a fiber structure having excellent properties such as high strength and high elastic modulus by arranging high modulus yarns in lateral and longitudinal directions and hot melt bonding the crossing points with a thermoplastic polymer. CONSTITUTION:High modulus yarns 1, 3 such as glass fiber or alumina fiber are arranged in lateral and longitudinal directions and the crossing points of the yarns are hot melt bonded with a thermoplastic polymer 2 such as nylon or polyester to obtain the objective structure. A corrugated board is produced by using the structure as a reinforcing material.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、繊維構造物に係り、更
に詳しくは、各種ラミネート・コーティング用基布,繊
維強化樹脂(FRP),繊維強化金属(FRM),繊維
強化セラミックス(FRC)等に用いられる補強材料と
して好適な、繊維構造物,及びそれを補強材として用い
た波板に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fiber structure, and more specifically, various laminating / coating base fabrics, fiber reinforced resin (FRP), fiber reinforced metal (FRM), fiber reinforced ceramics (FRC), etc. The present invention relates to a fibrous structure suitable as a reinforcing material used for a sheet, and a corrugated sheet using the same as a reinforcing material.

【0002】[0002]

【従来の技術】補強材料としては、補強繊維を用いたか
らみ織物がよく知られている。しかし、通常のからみ織
組織では、二本で一組の経糸が絡むと、経糸が屈曲する
ため、補強繊維が本来有する高強度,高弾性率等の優れ
た特性を、充分に活用できないという欠点があった。ま
た、からみ織物は容易に目ずれを起こす為、補強繊維の
配列が乱れやすく、この目ずれを防止するには、織物を
製造した後、更に樹脂加工を施すという工程を設けなけ
ればならなかった。
2. Description of the Related Art A woven fabric using reinforcing fibers is well known as a reinforcing material. However, in an ordinary entangled weave design, when two sets of warp are entangled, the warp is bent, so that the excellent properties such as high strength and high elastic modulus originally possessed by the reinforcing fiber cannot be fully utilized. was there. Further, since the entangled woven fabric easily causes misalignment, the arrangement of the reinforcing fibers is apt to be disturbed, and in order to prevent this misalignment, it was necessary to provide a step of further processing the resin after manufacturing the woven fabric. .

【0003】また、これらのからみ織物で補強した波板
は、熱により、波がへたってくるという問題があった。
Further, the corrugated sheet reinforced with these entangled fabrics has a problem that the waves are eroded by heat.

【0004】[0004]

【発明が解決しようとする課題】従って、本発明の目的
とするところは、補強繊維が本来有する高強度,高弾性
率等の優れた特性を最大限に活用した特段の補強効果を
備えた繊維構造物,及び熱によるへたりの少ない波板を
提供するにある。他の本発明の目的及び効果は以下の説
明から明らかにされよう。
SUMMARY OF THE INVENTION Therefore, the object of the present invention is to provide a fiber having a particular reinforcing effect by making the most of the excellent properties originally possessed by the reinforcing fiber such as high strength and high elastic modulus. It is to provide a structure and a corrugated sheet with little settling due to heat. Other objects and effects of the present invention will be apparent from the following description.

【0005】[0005]

【課題を解決するための手段】上述の目的は、高弾性糸
を縦横に引きそろえて、その交点を、熱可塑性ポリマー
で融着してなる繊維構造物,及び、波板の補強材とし
て、高弾性糸を縦横に引きそろえて、その交点を、熱可
塑性ポリマーで融着してなる繊維構造物を使用したこと
を特徴とする波板により達成される。
Means for Solving the Problems The above-mentioned object is to arrange high-elasticity yarns in the longitudinal and transverse directions and to fuse the intersections thereof with a thermoplastic polymer, and as a reinforcing material for corrugated sheets, This is achieved by a corrugated sheet characterized by using a fiber structure in which high-elasticity yarns are aligned in the lengthwise and crosswise directions and the intersections thereof are fused with a thermoplastic polymer.

【0006】本発明に用いられる高弾性糸としては、ガ
ラス繊維,有機高弾性繊維(例えば、アラミド繊維,液
晶繊維,超高分子量ポリエチレン繊維),シリコンカー
バイド繊維,炭素繊維,黒鉛繊維,アルミナ繊維,アル
ミナ−シリカ繊維などの高強度,高弾性率繊維のマルチ
フィラメントまたは紡績糸等があり、補強材料の用途に
よって選択して使用する。このうち、ガラス繊維,アル
ミナ繊維等、不燃性のものが、耐火性の点で好ましい。
Examples of the highly elastic yarn used in the present invention include glass fiber, organic highly elastic fiber (for example, aramid fiber, liquid crystal fiber, ultra high molecular weight polyethylene fiber), silicon carbide fiber, carbon fiber, graphite fiber, alumina fiber, There are multifilaments or spun yarns of high-strength, high-modulus fibers such as alumina-silica fibers, which are selected and used depending on the use of the reinforcing material. Of these, nonflammable materials such as glass fiber and alumina fiber are preferable in terms of fire resistance.

【0007】本発明に用いられる熱可塑性ポリマーとし
ては、例えばナイロン,共重合ナイロン,ポリエステ
ル,共重合ポリエステル,塩化ビニリデン,塩化ビニ
ル,ポリウレタン,ポリプロピレン,ポリエチレンなど
からなるモノフィラメント,複合繊維,マルチフィラメ
ント,スリットヤーンの様な繊維状のものが挙げられ
る。
As the thermoplastic polymer used in the present invention, for example, nylon, copolymerized nylon, polyester, copolymerized polyester, vinylidene chloride, vinyl chloride, polyurethane, polypropylene, polyethylene, etc. monofilament, composite fiber, multifilament, slit A fibrous material such as yarn can be used.

【0008】本発明の繊維構造物は、次のようにして製
造することができる。
The fiber structure of the present invention can be manufactured as follows.

【0009】経糸のうちの一本に熱可塑性ポリマー糸
を、残る経糸及び緯糸に高弾性糸を用い、熱可塑性ポリ
マー糸の送り出し量を、高弾性糸の送り出し量よりも多
くし、しかも高弾性糸からなる経糸が、織物の同一側面
にくるようにして、通常のからみ織りを行う。また熱可
塑性のポリマー糸を二本として、三本からみ織りとして
も良い。
A thermoplastic polymer yarn is used for one of the warp yarns, and a high elastic yarn is used for the remaining warp yarns and weft yarns. Normal leno weaving is performed so that the warp yarns are on the same side of the fabric. Further, two thermoplastic polymer threads may be used, and a three-entangled weave may be used.

【0010】送り出し量を多くする手段としては、高弾
性糸の経糸と熱可塑性のポリマー糸の経糸ビームを別々
に用意して二重ビームとなし、高弾性糸のビームを緯糸
密度(打ち込み数)により規定される量となる様に積極
送りとする一方で、熱可塑性のポリマー糸のビームを消
極送りで低張力にて送り出す事により、高弾性糸の送り
出し量より多くする方法,ダイレクトクリールを用い
て、高弾性糸及び熱可塑性のポリマー糸のボビンより、
直接織機に経糸を供給する時に、高弾性糸のみを積極駆
動のロールを通して送り、緯糸密度に見合う量とするの
に対し、熱可塑性のポリマー糸は、フリーテンションで
織機に送り出す事により、送り出し量を多くする方法,
或いは経糸である高弾性糸が直線性を保ち得る様に,即
ち熱可塑性のポリマー糸が緯糸を把持しながら対となる
高弾性糸の周囲を旋回するのに必要な量だけ、高弾性糸
より多く送り出す様にそれぞれの糸条を積極送りとする
方法等により行う事ができる。
As means for increasing the delivery amount, a high elastic yarn warp yarn and a thermoplastic polymer yarn warp beam are separately prepared to form a double beam, and the high elastic yarn beam is used as a weft density (number of hammers). By using the direct creel method, the amount of the thermoplastic polymer thread is increased by depolarizing the beam of the thermoplastic polymer thread to lower the tension than that of the highly elastic thread. From a bobbin of high elasticity yarn and thermoplastic polymer yarn,
When directly supplying the warp yarn to the loom, only the high elastic yarn is fed through the rolls driven positively to make the amount commensurate with the weft density, whereas the thermoplastic polymer yarn is fed to the loom with free tension, so How to increase
Alternatively, in order that the high elastic yarn which is the warp can maintain the linearity, that is, the thermoplastic polymer yarn grips the weft and turns around the pair of high elastic yarns by an amount necessary for the high elastic yarn to be more than the high elastic yarn. This can be done by a method of positively feeding each yarn so that many yarns are sent.

【0011】熱可塑性のポリマー糸条の送り出し量は、
使用する経糸・緯糸の各糸条の断面積,緯糸の密度に比
例して増やす必要があるが、必要以上に増やすと、経糸
と緯糸の交点の把持力が低下し、目ずれを起こし易くな
るため、織物のハンドリング性を悪化させる事になる。
従って、熱可塑性のポリマー糸の送り出し量は、ハンド
リング性と、補強繊維の直線性の要求度に応じ調整する
必要がある。
The delivery amount of the thermoplastic polymer yarn is
It is necessary to increase it in proportion to the cross-sectional area of each warp and weft thread to be used and the density of the weft, but if it is increased more than necessary, the gripping force at the intersection of the warp and the weft will decrease, and misalignment will occur easily. Therefore, the handleability of the fabric is deteriorated.
Therefore, it is necessary to adjust the delivery amount of the thermoplastic polymer yarn according to the handling property and the linearity requirement of the reinforcing fiber.

【0012】上述の様にして織成した織物は、図1
(a)の如く、熱可塑性ポリマー糸が高弾性糸の周りを
まとわりつくようにからんでおり、高弾性糸の経糸・緯
糸は図1(b)に示す様に屈曲していない。
The woven fabric woven as described above is shown in FIG.
As shown in (a), the thermoplastic polymer yarn is entangled around the high elastic yarn, and the warp and weft yarns of the high elastic yarn are not bent as shown in FIG. 1 (b).

【0013】この織物を加熱して熱可塑性のポリマー糸
を溶融し、高弾性糸の経糸及び緯糸同士を接着すること
によって、本発明の繊維構造物を製造する事ができる。
The fibrous structure of the present invention can be manufactured by heating this woven fabric to melt the thermoplastic polymer yarn and adhering the warp yarn and the weft yarn of the high elastic yarn to each other.

【0014】この様にして製造された本発明の繊維構造
物は、図1(a)及び図1(b)に示されるように、経
糸は織物に対して全て同一側面に亘って接着されてお
り、からみ織に見られる経糸の屈曲(図2(b)参照)
が起きていない。
In the fiber structure of the present invention thus produced, as shown in FIGS. 1 (a) and 1 (b), the warp yarns are adhered to the woven fabric all over the same side surface. Bending of warp seen in a cage and leno cloth (see Fig. 2 (b))
Is not happening.

【0015】本発明の波板は、上述のようにして得られ
た繊維構造物を中間層とし、その両側に塩化ビニル等の
シートを形成させ、波形を付与する常法によって製造す
ることができる。
The corrugated sheet of the present invention can be manufactured by a conventional method in which the fibrous structure obtained as described above is used as an intermediate layer, sheets of vinyl chloride or the like are formed on both sides thereof, and corrugation is applied. .

【0016】[0016]

【発明の効果】本発明の繊維構造物は、従来の高弾性糸
使用からみ織物よりも経糸の高弾性糸部分及び緯糸の直
線性に優れる為、繊維補強材料として利用する際、繊維
自身の高強度・高弾性率をより効果的に利用する事がで
きる。
EFFECTS OF THE INVENTION The fiber structure of the present invention is superior in linearity of the high elastic yarn portion of the warp and the weft as compared with the conventional woven fabric using the high elastic yarn. The strength and high elastic modulus can be used more effectively.

【0017】さらに熱可塑性のポリマー糸を用いている
ために、織機上にて簡単な装置で加熱する事により、目
ずれを起こす事の無い繊維構造物を製造できる。
Further, since the thermoplastic polymer yarn is used, it is possible to manufacture a fibrous structure free from misalignment by heating with a simple device on the loom.

【0018】また本発明の波板は、通常のからみ織物で
補強した波板に比べて、熱による波のへたりが少ない。
Further, the corrugated sheet of the present invention is less susceptible to thermal fatigue due to heat, as compared with a corrugated sheet reinforced with a normal entangled fabric.

【0019】[0019]

【実施例】以下実施例を挙げて本発明を具体的に説明す
る。
The present invention will be specifically described with reference to the following examples.

【0020】実施例1 高弾性糸として日本板硝子株式会社製ガラス繊維“EC
G37 1/0”と、熱可塑性のポリマー糸として、チ
ッソ株式会社製複合モノフィラメント“ライトロン”
(650d)を経糸とし、25mmあたりの密度をそれ
ぞれ2.5本として別々にビームを用意した。
Example 1 Glass fiber “EC manufactured by Nippon Sheet Glass Co., Ltd.
G37 1/0 "and a composite polymer filament" Lytron "manufactured by Chisso Corporation as a thermoplastic polymer yarn.
(650d) was used as a warp, and the density was set to 2.5 per 25 mm, and beams were prepared separately.

【0021】ECG37 1/0とライトロン(650
d)を一対にしてからませるに際し、それぞれのビーム
の送り出し量を調節し、緯糸にECG37 1/0を用
い、2.5本/25mmの密度にして、からみ織りに
て、経糸ECG371/0が緯糸との交点において、必
ず織物の同一側面となるように製織した。
ECG37 1/0 and Literon (650
When d) is paired and twisted, the amount of each beam is adjusted, ECG37 1/0 is used for the weft, and the density is 2.5 threads / 25 mm, and the warp ECG371 / 0 is Weaving was carried out so that the intersections with the wefts were always on the same side of the fabric.

【0022】次に、上記織物を織機上に取り付けた加熱
装置で150℃に加熱し、熱可塑性のポリマー糸を溶融
して経糸と緯糸のガラス繊維同士を接着した。
Next, the above woven fabric was heated to 150 ° C. by a heating device mounted on a loom to melt the thermoplastic polymer yarn and bond the glass fibers of the warp and the weft.

【0023】このようにして得た繊維構造物は、経糸と
緯糸の直線性に優れ、強い力で引っ張っても容易に目ズ
レしなかった。
The fibrous structure thus obtained was excellent in the linearity of the warp and the weft, and did not easily misalign even when pulled with a strong force.

【0024】実施例2 実施例1におけるECG37 1/0の代わりに、デュ
ポン・東レ・ケブラー株式会社製のアラミド繊維“ケブ
ラー49”(1420d)を用いた以外は、実施例1と
同様にして繊維構造物を得た。
Example 2 A fiber was prepared in the same manner as in Example 1 except that the aramid fiber "Kevlar 49" (1420d) manufactured by DuPont Toray Kevlar Co., Ltd. was used in place of the ECG37 1/0 used in Example 1. The structure was obtained.

【0025】実施例3 実施例1におけるECG 37 1/0の代わりに、新
旭化成カーボンファイバー株式会社製の炭素繊維“ハイ
・カーボロン”(フィラメント数:3000、1800
d)を用いた以外は、実施例1と同様にして繊維構造物
を得た。
Example 3 Instead of ECG 37 1/0 in Example 1, carbon fiber "High Carboron" manufactured by Shin-Asahi Kasei Carbon Fiber Co., Ltd. (filament number: 3000, 1800) was used.
A fiber structure was obtained in the same manner as in Example 1 except that d) was used.

【0026】実施例4 実施例1におけるECG37 1/0の代わりに、EC
G75 1/0を,ライトロン650dの代わりに、ラ
イトロン250dを用い、経糸及び緯糸の密度を7本/
25mmにする以外は、実施例1と同様にして繊維構造
物を得た。
Example 4 Instead of ECG37 1/0 in Example 1, EC
G75 1/0, Literon 250d was used instead of Literon 650d, and the warp and weft densities were 7 /
A fiber structure was obtained in the same manner as in Example 1 except that the fiber structure was 25 mm.

【0027】得られた繊維構造物を中間層とし、両側に
0.4mmの塩化ビニルシートを150℃で成形し、波
形を付与し、波板を製造した。
Using the obtained fiber structure as an intermediate layer, 0.4 mm vinyl chloride sheets were molded on both sides at 150 ° C. and corrugated to give corrugated sheets.

【0028】比較例1 図2の様な構造を持つ、ガラス織物〔鐘紡(株)製KS
5207:経糸ECG1501/0×2,経糸密度7本
/25mm,緯糸ECG751/0,緯糸密度7本/2
5mmのからみ織〕を、メラミン−ホルマリン系樹脂
〔住友化学工業(株)製 SUMITEX RESIN
M−3〕350g/l水溶液に浸漬し、絞液・乾燥し
て、目止め処理を行った。
Comparative Example 1 A glass fabric having a structure as shown in FIG. 2 [KS manufactured by Kanebo Co., Ltd.
5207: warp ECG1501 / 0 × 2, warp density 7 threads / 25 mm, weft ECG 751/0, weft density 7 threads / 2
5 mm entangled weave] is a melamine-formalin resin [SUMITEX RESIN manufactured by Sumitomo Chemical Co., Ltd.]
M-3] Immersed in 350 g / l aqueous solution, squeezed and dried, and sealing treatment was performed.

【0029】得られたガラス織物を用い、実施例4と同
様にして波板を製造した。
A corrugated sheet was produced in the same manner as in Example 4 using the obtained glass fabric.

【0030】実施例4及び比較例1で製造した波板の、
75℃1時間加熱前後の波の高さと戻り率を測定し、結
果を表1に示す。
Of the corrugated sheet produced in Example 4 and Comparative Example 1,
The wave height and the return rate before and after heating at 75 ° C. for 1 hour were measured, and the results are shown in Table 1.

【0031】また、波板の波がへたってくる様子を、図
3に示す。
Further, FIG. 3 shows how the waves of the corrugated plate are bent.

【0032】[0032]

【表1】 [Table 1]

【図面の簡単な説明】[Brief description of drawings]

【図1】(a)及び(b)は、本発明にかかるからみ織
物の一例の、平面図及び断面図である。
1A and 1B are a plan view and a cross-sectional view of an example of a woven fabric according to the present invention.

【図2】(a)及び(b)は、従来のからみ織物の平面
図及び断面図である。
2A and 2B are a plan view and a cross-sectional view of a conventional leno cloth.

【図3】熱処理前と熱処理後の波板の断面を表す図であ
る。
FIG. 3 is a diagram showing a cross section of a corrugated sheet before and after heat treatment.

【符号の説明】 1,1’ 高弾性糸の経糸 2 熱可塑性のポリマー糸の経糸 3 高弾性糸の緯糸 4 熱処理前の波板 5 熱処理後の波板 D0 波の高さ D1 波の高さ[Explanation of symbols] 1,1 'Warp of highly elastic yarn 2 Warp of thermoplastic polymer yarn 3 Weft of highly elastic yarn 4 Corrugated sheet before heat treatment 5 Corrugated sheet after heat treatment D 0 Wave height D 1 Wave height

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 高弾性糸を縦横に引きそろえて、その交
点を、熱可塑性ポリマーで融着してなる繊維構造物。
1. A fibrous structure in which high-elasticity yarns are aligned vertically and horizontally, and the intersections thereof are fused with a thermoplastic polymer.
【請求項2】 波板の補強材として、高弾性糸を縦横に
引きそろえて、その交点を、熱可塑性ポリマーで融着し
てなる繊維構造物を使用したことを特徴とする波板。
2. A corrugated sheet comprising a fibrous structure obtained by aligning high-elasticity yarns lengthwise and crosswise and fusing the intersections with a thermoplastic polymer as a reinforcing material for the corrugated sheet.
JP3874292A 1991-04-24 1992-01-28 Corrugated sheet using fiber structure Expired - Fee Related JP3027469B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3874292A JP3027469B2 (en) 1991-04-24 1992-01-28 Corrugated sheet using fiber structure

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP3-122775 1991-04-24
JP12277591 1991-04-24
JP3874292A JP3027469B2 (en) 1991-04-24 1992-01-28 Corrugated sheet using fiber structure

Publications (2)

Publication Number Publication Date
JPH0598553A true JPH0598553A (en) 1993-04-20
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103114490A (en) * 2013-01-18 2013-05-22 浙江绍兴希望包装有限公司 Processing method of fiber strengthening composite corrugated board
JP2021524545A (en) * 2018-05-16 2021-09-13 リンテック オブ アメリカ インクLintec Of America, Inc. Nanofiber fabric

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103114490A (en) * 2013-01-18 2013-05-22 浙江绍兴希望包装有限公司 Processing method of fiber strengthening composite corrugated board
CN103114490B (en) * 2013-01-18 2015-07-08 浙江希望包装有限公司 Processing method of fiber strengthening composite corrugated board
JP2021524545A (en) * 2018-05-16 2021-09-13 リンテック オブ アメリカ インクLintec Of America, Inc. Nanofiber fabric

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