JPH0557507A - Coating tool and manufacture thereof - Google Patents

Coating tool and manufacture thereof

Info

Publication number
JPH0557507A
JPH0557507A JP21838391A JP21838391A JPH0557507A JP H0557507 A JPH0557507 A JP H0557507A JP 21838391 A JP21838391 A JP 21838391A JP 21838391 A JP21838391 A JP 21838391A JP H0557507 A JPH0557507 A JP H0557507A
Authority
JP
Japan
Prior art keywords
film
cutting edge
tool
outermost layer
tin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP21838391A
Other languages
Japanese (ja)
Other versions
JP2825693B2 (en
Inventor
Toshihiko Ogino
俊彦 荻野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kyocera Corp
Original Assignee
Kyocera Corp
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Filing date
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  • Cutting Tools, Boring Holders, And Turrets (AREA)
  • Chemical Vapour Deposition (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

PURPOSE:To prevent the lowering of impact resistance by constituting the outermost layer of the cutting edge part of a tool with Al2O3,, and the outermost layer of the parts other than the cutting edge with either TiN or TiCN. CONSTITUTION:On the surface of the base material of a tool consisting of a hard material such as Wc-Co cemented carbide, a single or a plurality of hard layer or layers 2 consisting of at least a kind of compound selected out of the carbide, nitride, and carbonitride of the metal in the 4a to 6b groups of the periodic table of the elements, and Al2O3 are coated. And the outermost layer 4 of the cutting edge part 3 of the tool is made up of Al2O3 by means of the chemical vapor-phase growth method, and the outermost layer 6 other than the cutting edge part 3 is made up of TiN or TiNC. And, the surface roughness of the cutting edge part 3 is set to be 0.4mum or less.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の利用分野】本発明は、コーティング工具および
その製造方法に関し、詳細には、耐衝撃性を改良した切
削工具に関する。
FIELD OF THE INVENTION The present invention relates to a coated tool and a method for manufacturing the same, and more particularly to a cutting tool having improved impact resistance.

【0002】[0002]

【従来技術】従来、切削工具としてはWCを主成分とし
て、Co等の金属を配合してなる超硬合金が主流であっ
たが、最近では、切削時の耐摩耗性を向上させることを
目的としてこの超硬合金やサーメットからなる母材の表
面にTiC,TiCN,TiNあるいはAl2 3 等の
硬質材料を化学気相成長法(CVD法)等により被覆し
た、コーティング工具が多く用いられている。
2. Description of the Related Art Conventionally, as a cutting tool, a cemented carbide containing WC as a main component and a metal such as Co is mainly used, but recently, an object thereof is to improve wear resistance during cutting. As a coating tool in which a hard material such as TiC, TiCN, TiN or Al 2 O 3 is coated on the surface of the base material made of cemented carbide or cermet by chemical vapor deposition (CVD method) There is.

【0003】このコーティング工具の表面に形成される
被覆層は、工具の耐摩耗性を左右する大きな要因である
ことから各種の改善がなされているが、具体的には、母
材表面に高硬度のTiC層を形成して耐摩耗性を改善し
たもの、あるいはこのTiC膜の表面にさらにAl2
3 からなる外層を形成し耐摩耗性および耐酸化性を改善
したもの等が主流であったが、最近ではこれらの被覆槽
の最外層としてTiNやTiCNを被覆することも提案
されている。これは、TiNやTiCNが靱性に優れる
とともに摩擦係数が小さいことから切屑との摩擦抵抗が
低減されるために切削温度を低くできるという長所を有
する。
The coating layer formed on the surface of the coated tool has been variously improved because it is a major factor affecting the wear resistance of the tool. Specifically, the base material surface has a high hardness. A TiC layer of which the wear resistance has been improved, or the surface of this TiC film is further treated with Al 2 O.
The mainstream of these is an outer layer composed of 3 to improve wear resistance and oxidation resistance, but recently, it has been proposed to coat TiN or TiCN as the outermost layer of these coating tanks. This has the advantage that the cutting temperature can be lowered because TiN and TiCN are excellent in toughness and have a small friction coefficient, so that the friction resistance with chips is reduced.

【0004】[0004]

【発明が解決しようとする問題点】しかしながら、これ
までのように化学気相成長法(CVD法)等によって、
Al2 3 膜を形成すると、Al2 3 膜の結晶粒径が
大きいことから膜表面の凹凸が大きい傾向にある。その
ために、このようなAl2 3 膜の表面にTiNやTi
CN膜を形成すると、Al2 3 膜の凹凸が反映される
ために、TiNやTiCN膜自体にも凹凸が存在するた
めに、工具刃先部における切削時の耐衝撃性が低下し刃
先の欠損を生じる等の問題があった。
[Problems to be Solved by the Invention] However, the chemical vapor deposition method (CVD method) or the like has been used as in the past.
When the Al 2 O 3 film is formed, since the crystal grain size of the Al 2 O 3 film is large, the unevenness of the film surface tends to be large. Therefore, the surface of such an Al 2 O 3 film is not covered with TiN or Ti.
When the CN film is formed, the unevenness of the Al 2 O 3 film is reflected, and therefore the TiN or TiCN film itself also has unevenness, so the impact resistance at the time of cutting at the tool cutting edge is reduced and the cutting edge is broken. There was a problem such as causing.

【0005】[0005]

【問題点を解決するための手段】本発明者等は、上記の
問題点に対して検討を加えた結果、Al2 3 膜とTi
NあるいはTiCN膜を順次形成し、切削加工において
最も衝撃の加わる刃先表面において、機械的に刃先部の
みを研磨加工し、工具母材の刃先部にAl2 3 を露出
させることにより、上記目的が解決できることを知見し
た。
[Means for Solving the Problems] As a result of studying the above problems, the present inventors have found that Al 2 O 3 film and Ti
By sequentially forming N or TiCN films and mechanically polishing only the cutting edge portion on the cutting edge surface to which the greatest impact is applied during cutting, and exposing Al 2 O 3 to the cutting edge portion of the tool base material, We found that can be solved.

【0006】即ち、本発明のコーティング工具は、硬質
材料からなる工具母材の表面に周期律表第4a,5a,
6a族金属の炭化物、窒化物、炭窒化物およびAl2
3 から選ばれる少なくとも1種の化合物を単層あるいは
複数層からなる硬質層を被覆してなるコーティング工具
において、工具の刃先部の最外層がAl2 3 から構成
され、刃先以外の部分の最外層がTiN,TiCNのい
ずれかにより構成したことを特徴とするものであり、か
かる製造方法としては、硬質材料からなる工具母材の表
面に、化学気相成長法によって最外層としてTiN、T
iCNのいずれかの膜を、最外層に隣接する内層として
Al2 3 膜を形成した後、工具刃先部を研磨処理し、
Al2 3 膜を露出したことを特徴とするものである。
That is, in the coated tool of the present invention, the periodic table 4a, 5a,
Carbides, nitrides, carbonitrides and Al 2 O of Group 6a metals
In a coating tool formed by coating a hard layer composed of a single layer or a plurality of layers with at least one compound selected from 3, the outermost layer of the cutting edge of the tool is composed of Al 2 O 3, and the outermost layer of the portion other than the cutting edge is The outer layer is composed of either TiN or TiCN. As such a manufacturing method, TiN, T as the outermost layer is formed on the surface of the tool base material made of a hard material by chemical vapor deposition.
After forming an Al 2 O 3 film as an inner layer adjacent to the outermost layer using any film of iCN, the tool edge portion is subjected to polishing treatment,
The feature is that the Al 2 O 3 film is exposed.

【0007】以下、本発明を図1を参照し説明する。図
1によれば、1が工具母材、2が硬質層である。本発明
において硬質材料からなる工具母材1表面に被覆される
硬質層2は、周期律表第4a,5a,6a族金属の炭化
物、窒化物、炭窒化物およびAl2 3 から選ばれる少
なくとも1種から選ばれる化合物より構成される。
The present invention will be described below with reference to FIG. According to FIG. 1, 1 is a tool base material and 2 is a hard layer. In the present invention, the hard layer 2 coated on the surface of the tool base material 1 made of a hard material is at least selected from carbides, nitrides, carbonitrides and Al 2 O 3 of metals of Groups 4a, 5a and 6a of the periodic table. It is composed of a compound selected from one kind.

【0008】本発明のコーティング工具によれば、硬質
層2が、刃先部3の最外層4がAl2 3 膜より構成さ
れ、刃先部以外の表面3の最外層6がTiN膜あるいは
TiCN膜より構成される。なお、各部位の内層7は、
それ自体存在しなくてもよいが、形成する場合には、そ
の材質は特定されるものでなく、前記硬質材料より選択
されるいずれの物質により形成してもよい。この硬質膜
2は、母材1表面に5〜15μmの厚みで形成される
が、上記構成においてTiN膜あるいはTiCN膜6は
1.0μm以下の厚み、Al2 3 膜4は1〜4μmの
厚みで形成されることが望ましい。
According to the coating tool of the present invention, in the hard layer 2, the outermost layer 4 of the cutting edge portion 3 is composed of an Al 2 O 3 film, and the outermost layer 6 of the surface 3 other than the cutting edge portion is a TiN film or a TiCN film. It is composed of The inner layer 7 of each part is
Although it does not have to exist as such, when it is formed, its material is not specified, and it may be formed of any substance selected from the above hard materials. The hard film 2 is formed on the surface of the base material 1 with a thickness of 5 to 15 μm. In the above structure, the TiN film or the TiCN film 6 has a thickness of 1.0 μm or less, and the Al 2 O 3 film 4 has a thickness of 1 to 4 μm. It is desirable that it is formed with a thickness.

【0009】また、本発明によれば、刃先部の最外層で
あるAl2 3 膜はその表面粗さ(Ra)が0.4μm
以下であることが望ましい。これは、表面粗さが0.4
μmより大きいと被削材との接触において膜に応力が生
じ膜の剥離を生じ、膜に発生する亀裂を増大するためで
ある。
According to the present invention, the surface roughness (Ra) of the Al 2 O 3 film which is the outermost layer of the cutting edge portion is 0.4 μm.
The following is desirable. This has a surface roughness of 0.4.
This is because if the thickness is larger than μm, stress is applied to the film when it comes into contact with the work material, peeling of the film occurs, and cracks generated in the film increase.

【0010】本発明のコーティング工具の製造方法によ
れば、まず、WC−Co系超硬合金やサーメット等の硬
質材料を母材として準備する。母材を構成する成分とし
ては公知の超硬合金、あるいはTiC基、TiCN基サ
ーメットが使用できる。具体的には、超硬合金として
は、WC−Coを主成分とし、さらに周期律表第4a:
5a、6a族金属の炭化物、窒化物、炭窒化物を添加し
たもの、サーメットとしてはTiCあるいはTiNを主
成分とし、これに周期律表第4a、5a、6a族金属の
炭化物、窒化物、炭窒化物を添加したもの等が使用でき
る。これらの母材はいずれも相対密度99%以上の高強
度、高靱性材料であることが望まれる。
According to the method for manufacturing a coated tool of the present invention, first, a hard material such as a WC-Co type cemented carbide or cermet is prepared as a base material. A known cemented carbide, or a TiC-based or TiCN-based cermet can be used as a constituent of the base material. Specifically, as the cemented carbide, WC-Co is the main component, and further, Periodic Table 4a:
Carbide, nitride, or carbonitride of group 5a or 6a metal, cermet containing TiC or TiN as a main component, and carbide, nitride, or charcoal of group 4a, 5a, or 6a metal of the periodic table A material to which a nitride is added can be used. All of these base materials are desired to be high strength and high toughness materials having a relative density of 99% or more.

【0011】本発明によれば、上記母材表面に化学気相
成長法(CVD法)により硬質膜を形成する。CVD法
によれば、例えばTiN膜を形成する場合には反応ガス
としてTiCl4 、N2 およびキャリアガスとして水素
等の不活性ガス等を用いて反応炉に導入し、母材を65
0〜1050℃に加熱することにより母材表面にTiC
膜が形成される。また、上記反応ガスの構成に加え、C
4 等の炭素含有ガスを混入させることによりTiCN
膜を形成することができる。さらに、反応ガスとしてA
lCl3 、H2 、CO2 等を用いることによりAl2
3膜を生成させることができる。
According to the present invention, a hard film is formed on the surface of the base material by the chemical vapor deposition method (CVD method). According to the CVD method, for example, when forming a TiN film, TiCl 4 , N 2 as a reaction gas and an inert gas such as hydrogen as a carrier gas are introduced into the reaction furnace, and the base material is made into 65
TiC on the surface of the base material by heating to 0-1050 ° C
A film is formed. In addition to the composition of the above reaction gas, C
By mixing carbon-containing gas such as H 4, TiCN
A film can be formed. Furthermore, as a reaction gas, A
Al 2 O by using lCl 3 , H 2 , CO 2 etc.
3 membranes can be generated.

【0012】本発明によれば、硬質膜を形成する際、図
1に示す通り、場合により内層7として各種の硬質膜を
形成した後、Al2 3 膜4を形成し、その後TiN膜
6を順次形成する。これらの膜はAl2 3 膜4が1〜
4μm、TiN膜6が1μm以下の厚みで形成する。そ
の後、この硬質膜のうち、刃先部3のみをホーニング等
の手段により研磨加工し、刃先部3のみAl2 3 膜が
露出させる。この時の研磨量は、刃先部のAl2 3
4の厚みが0.5μmより薄くならないように制御す
る。また、研磨により刃先部3の表面粗さ(Ra)が
0.4μm以下になるように研磨することが望ましい。
According to the present invention, when forming a hard film, as shown in FIG. 1, optionally, various hard films are formed as the inner layer 7, then the Al 2 O 3 film 4 is formed, and then the TiN film 6 is formed. Are sequentially formed. These films are Al 2 O 3 films 1 to 1
The TiN film 6 having a thickness of 4 μm is formed with a thickness of 1 μm or less. After that, of this hard film, only the cutting edge portion 3 is polished by means such as honing to expose the Al 2 O 3 film only in the cutting edge portion 3. The polishing amount at this time is controlled so that the thickness of the Al 2 O 3 film 4 at the cutting edge portion does not become thinner than 0.5 μm. Further, it is desirable to polish the blade edge portion 3 so that the surface roughness (Ra) thereof is 0.4 μm or less.

【0013】これにより、刃先部3の最外層はAl2
3 膜より構成され、刃先部以外の表面5の最外層はTi
N膜により構成することができる。
As a result, the outermost layer of the cutting edge portion 3 is Al 2 O.
It is composed of 3 films and the outermost layer of the surface 5 other than the cutting edge is Ti
It can be composed of an N film.

【0014】[0014]

【作用】本発明のコーティング工具によれば、刃先部3
の最外層はAl2 3 膜より構成され、刃先部以外の表
面5の最外層はTiN膜により構成することにより、刃
先部が耐酸化性の優れたAl2 3膜であることにより
耐溶着性を向上させることができ、また、刃先以外の表
面においては、靱性に優れ、摩擦係数の小さいTiN膜
であることにより切屑により受ける衝撃を減じることが
できる。
According to the coating tool of the present invention, the cutting edge portion 3
The outermost layer of is composed of an Al 2 O 3 film, and the outermost layer of the surface 5 other than the cutting edge portion is formed of a TiN film, so that the cutting edge portion is an Al 2 O 3 film having excellent oxidation resistance. The weldability can be improved, and the TiN film having excellent toughness and a small friction coefficient on the surface other than the cutting edge can reduce the impact received by the chips.

【0015】また、刃先部の表面粗さ(Ra)を0.4
μm以下に制御することにより膜の耐剥離性と耐衝撃性
を向上することができる。
The surface roughness (Ra) of the cutting edge is 0.4.
By controlling the thickness to be not more than μm, the peeling resistance and impact resistance of the film can be improved.

【0016】[0016]

【実施例】【Example】

実施例1 超硬合金母材をCVD反応炉内に設置し、反応ガスとし
てTiCl4 、N2 、CH4 を導入しTiC膜とTiN
膜を総膜厚6μmの厚みで形成した後、反応ガスとして
AlCl3 、H2 、CO2 を導入してAl2 3 膜を2
μmの厚みで形成した。その後Al2 3 膜の上にTi
Cl4、N2 の反応ガスを導入しTiN膜を0.5μm
の厚みで形成した。
Example 1 A cemented carbide base material was placed in a CVD reactor, and TiCl 4 , N 2 , and CH 4 were introduced as reaction gases to introduce a TiC film and TiN.
After forming the film to a total film thickness of 6 μm, AlCl 3 , H 2 and CO 2 are introduced as reaction gases to form an Al 2 O 3 film.
It was formed with a thickness of μm. After that, on the Al 2 O 3 film, Ti
The reaction gas of Cl 4 and N 2 was introduced to form a TiN film with a thickness of 0.5 μm.
It was formed with a thickness of.

【0017】その後、ラバー砥石を用いて、刃先部を研
磨し、刃先部の最外層のTiN膜を除去しAl2 3
を露出させた。この時の刃先部のAl2 3 膜の最大表
面粗さは0.27μmであった。
After that, the blade tip portion was polished with a rubber grindstone to remove the outermost TiN film of the blade tip portion to expose the Al 2 O 3 film. At this time, the maximum surface roughness of the Al 2 O 3 film at the cutting edge was 0.27 μm.

【0018】このようにして得られたコーティング工具
を用いて、被削材としてSCM440(5mm幅の溝4
本入り)を用いて周速60m/min、切り込み2m
m、送り0.51mm/rev、切削時間10秒、乾式
切削で5コーナー加工し、耐欠損性について評価した。
比較のために研磨加工を施さなかった工具を用いて同様
に評価した。
Using the coating tool thus obtained, SCM440 (5 mm wide groove 4
Perimeter speed 60m / min, 2m cut using
m, feed 0.51 mm / rev, cutting time 10 seconds, 5 corners were processed by dry cutting, and fracture resistance was evaluated.
For comparison, the same evaluation was performed using a tool that was not subjected to polishing.

【0019】その結果、本発明品は、5コーナーすべて
について欠損が認められず、これに対して比較品は、5
コーナーの内、1コーナーに欠損が認められ、本発明品
に比較して劣るものであった。
As a result, in the product of the present invention, no defects were observed in all of the 5 corners, whereas in the comparative product, 5 defects were observed.
One of the corners had a defect, which was inferior to the product of the present invention.

【0020】実施例2 超硬合金母材をCVD反応炉内に設置し、反応ガスとし
てTiCl4 、N2 、CH4 を導入しTiC膜とTiN
膜を総膜厚6μmの厚みで形成した後、反応ガスとして
AlCl3 、H2 、CO2 を導入してAl2 3 膜を2
μmの厚みで形成した。その後Al2 3 膜の上にTi
Cl4、N2 、CH4 の反応ガスを導入しTiCN膜を
0.5μmの厚みで形成した。
Example 2 A cemented carbide base material was placed in a CVD reaction furnace, and TiCl 4 , N 2 and CH 4 were introduced as reaction gases to introduce a TiC film and a TiN film.
After forming a film with a total film thickness of 6 μm, AlCl 3 , H 2 , and CO 2 are introduced as reaction gases to form an Al 2 O 3 film.
It was formed with a thickness of μm. After that, on the Al 2 O 3 film, Ti
A TiCN film having a thickness of 0.5 μm was formed by introducing a reaction gas of Cl 4 , N 2 and CH 4 .

【0021】その後、ラバー砥石を用いて、刃先部を研
磨し、刃先部の最外層のTiCN膜を除去しAl2 3
膜を露出させた。この時の刃先部のAl2 3 膜の最大
表面粗さは0.28μmであった。
After that, the edge of the blade was polished with a rubber grindstone to remove the TiCN film, which is the outermost layer of the edge of the blade, to remove Al 2 O 3.
The membrane was exposed. At this time, the maximum surface roughness of the Al 2 O 3 film at the cutting edge was 0.28 μm.

【0022】このようにして得られたコーティング工具
を用いて、実施例1と同様な条件で切削テストを行い、
耐欠損性を評価した。なお、比較のために研磨加工を施
さなかった工具を用いて同様に評価した。
Using the coating tool thus obtained, a cutting test was conducted under the same conditions as in Example 1,
The fracture resistance was evaluated. For comparison, the same evaluation was performed using a tool that was not polished.

【0023】その結果、本発明品は、5コーナーすべて
について欠損が認められず、比較品は、5コーナーの
内、2コーナーに欠損が認められ、本発明品に比較して
劣るものであった。
As a result, the product of the present invention showed no defects at all five corners, and the comparative product had defects at two of the five corners, which was inferior to the product of the present invention. ..

【0024】比較例 超硬合金母材をCVD反応炉内に設置し、反応ガスとし
てTiCl4 、N2 、CH4 を導入しTiC膜とTiN
膜を総膜厚6μmの厚みで形成した後、反応ガスとして
AlCl3 、H2 、CO2 を導入してAl2 3 膜を2
μmの厚みで形成した。
Comparative Example A cemented carbide base material is placed in a CVD reactor, and TiCl 4 , N 2 and CH 4 are introduced as reaction gases to introduce a TiC film and TiN.
After forming a film with a total film thickness of 6 μm, AlCl 3 , H 2 , and CO 2 are introduced as reaction gases to form an Al 2 O 3 film.
It was formed with a thickness of μm.

【0025】その後、刃先部において研磨加工を行い表
面粗さ(Ra)0.3μmに研磨した。このコーティン
グ工具を用いて実施例1と同様な方法で切削テストを行
ったところ、5コーナーのうち3コーナーに欠損が認め
られた。
Thereafter, the cutting edge portion was ground to a surface roughness (Ra) of 0.3 μm. When a cutting test was performed using this coated tool in the same manner as in Example 1, defects were found in 3 out of 5 corners.

【0026】[0026]

【発明の効果】本発明のコーティング工具によれば、刃
先部の最外層をAl2 3 膜、刃先以外の表面の最外層
をTiNあるいはTiCN膜により構成することによ
り、切屑の耐溶着性と切削加工時の耐衝撃性を向上する
ことができ、工具の長寿命化を図ることができる。
According to the coated tool of the present invention, by forming the outermost layer of the cutting edge portion with an Al 2 O 3 film and the outermost layer of the surface other than the cutting edge with a TiN or TiCN film, chip welding resistance and Impact resistance during cutting can be improved, and the tool life can be extended.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明のコーティング工具を説明するための要
部断面図である。
FIG. 1 is a sectional view of relevant parts for explaining a coating tool of the present invention.

【符号の説明】[Explanation of symbols]

1 工具母材 2 硬質層 3 刃先部 1 Tool base material 2 Hard layer 3 Cutting edge part

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】硬質材料からなる工具母材の表面に周期律
表第4a,5a,6a族金属の炭化物、窒化物、炭窒化
物およびAl2 3 から選ばれる少なくとも1種の化合
物を単層あるいは複数層として被覆してなるコーティン
グ工具において、工具の刃先部の最外層がAl2 3
ら構成され、刃先以外の部分の最外層がTiN,TiC
Nのいずれかにより構成されることを特徴とするコーテ
ィング工具。
1. A surface of a tool base material made of a hard material is coated with at least one compound selected from carbides, nitrides, carbonitrides of groups 4a, 5a and 6a of the periodic table and Al 2 O 3. In a coating tool formed by coating as a layer or a plurality of layers, the outermost layer of the cutting edge of the tool is made of Al 2 O 3, and the outermost layer of the portion other than the cutting edge is made of TiN, TiC.
A coating tool characterized by comprising any of N.
【請求項2】刃先部の表面荒さ(Ra)が0.4μm以
下である請求項1記載のコーティング工具。
2. The coating tool according to claim 1, wherein the surface roughness (Ra) of the cutting edge portion is 0.4 μm or less.
【請求項3】硬質材料からなる工具母材の表面に、化学
気相成長法によって最外層としてTiN、TiCNのい
ずれかの膜を、最外層に隣接する内層としてAl2 3
膜を形成した後、工具刃先部のみを研磨処理し、Al2
3 膜を露出したことを特徴とするコーティング工具の
製造方法。
3. A tool base material made of a hard material, on the surface of which is formed by chemical vapor deposition, a film of TiN or TiCN as an outermost layer and Al 2 O 3 as an inner layer adjacent to the outermost layer.
After forming the film, only the cutting edge of the tool is polished to remove Al 2
A method for manufacturing a coating tool, which comprises exposing an O 3 film.
JP21838391A 1991-08-29 1991-08-29 Coating tool and method of manufacturing the same Expired - Lifetime JP2825693B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP21838391A JP2825693B2 (en) 1991-08-29 1991-08-29 Coating tool and method of manufacturing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP21838391A JP2825693B2 (en) 1991-08-29 1991-08-29 Coating tool and method of manufacturing the same

Publications (2)

Publication Number Publication Date
JPH0557507A true JPH0557507A (en) 1993-03-09
JP2825693B2 JP2825693B2 (en) 1998-11-18

Family

ID=16719044

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JP2825693B2 (en)

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