JPH0544134Y2 - - Google Patents
Info
- Publication number
- JPH0544134Y2 JPH0544134Y2 JP1985141583U JP14158385U JPH0544134Y2 JP H0544134 Y2 JPH0544134 Y2 JP H0544134Y2 JP 1985141583 U JP1985141583 U JP 1985141583U JP 14158385 U JP14158385 U JP 14158385U JP H0544134 Y2 JPH0544134 Y2 JP H0544134Y2
- Authority
- JP
- Japan
- Prior art keywords
- fragrance
- thermoplastic resin
- layer
- interior material
- substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003205 fragrance Substances 0.000 claims description 62
- 239000000463 material Substances 0.000 claims description 40
- 229920005992 thermoplastic resin Polymers 0.000 claims description 33
- 239000000758 substrate Substances 0.000 claims description 19
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 14
- 229920001038 ethylene copolymer Polymers 0.000 claims description 13
- 230000004888 barrier function Effects 0.000 claims description 8
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 6
- 229920005672 polyolefin resin Polymers 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 32
- 229920005989 resin Polymers 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- 229920001577 copolymer Polymers 0.000 description 6
- -1 polyethylene terephthalate Polymers 0.000 description 6
- 239000002023 wood Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 230000002688 persistence Effects 0.000 description 5
- 239000008188 pellet Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 description 2
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 2
- LBUJPTNKIBCYBY-UHFFFAOYSA-N 1,2,3,4-tetrahydroquinoline Chemical compound C1=CC=C2CCCNC2=C1 LBUJPTNKIBCYBY-UHFFFAOYSA-N 0.000 description 2
- GRWFGVWFFZKLTI-IUCAKERBSA-N 1S,5S-(-)-alpha-Pinene Natural products CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- GNKZMNRKLCTJAY-UHFFFAOYSA-N 4'-Methylacetophenone Chemical compound CC(=O)C1=CC=C(C)C=C1 GNKZMNRKLCTJAY-UHFFFAOYSA-N 0.000 description 2
- OALYTRUKMRCXNH-UHFFFAOYSA-N 5-pentyloxolan-2-one Chemical compound CCCCCC1CCC(=O)O1 OALYTRUKMRCXNH-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- ZOJBYZNEUISWFT-UHFFFAOYSA-N allyl isothiocyanate Chemical compound C=CCN=C=S ZOJBYZNEUISWFT-UHFFFAOYSA-N 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229930016911 cinnamic acid Natural products 0.000 description 2
- 235000013985 cinnamic acid Nutrition 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 2
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 2
- DTUQWGWMVIHBKE-UHFFFAOYSA-N phenylacetaldehyde Chemical compound O=CCC1=CC=CC=C1 DTUQWGWMVIHBKE-UHFFFAOYSA-N 0.000 description 2
- 239000011120 plywood Substances 0.000 description 2
- 229920006122 polyamide resin Polymers 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 2
- RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 2
- PHXATPHONSXBIL-UHFFFAOYSA-N xi-gamma-Undecalactone Chemical compound CCCCCCCC1CCC(=O)O1 PHXATPHONSXBIL-UHFFFAOYSA-N 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 description 1
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 description 1
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- 239000001306 (7E,9E,11E,13E)-pentadeca-7,9,11,13-tetraen-1-ol Substances 0.000 description 1
- 239000001211 (E)-4-phenylbut-3-en-2-one Substances 0.000 description 1
- KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- FACFHHMQICTXFZ-UHFFFAOYSA-N 2-(2-phenylimidazo[1,2-a]pyridin-3-yl)ethanamine Chemical compound N1=C2C=CC=CN2C(CCN)=C1C1=CC=CC=C1 FACFHHMQICTXFZ-UHFFFAOYSA-N 0.000 description 1
- LUZDYPLAQQGJEA-UHFFFAOYSA-N 2-Methoxynaphthalene Chemical compound C1=CC=CC2=CC(OC)=CC=C21 LUZDYPLAQQGJEA-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- PRNCMAKCNVRZFX-UHFFFAOYSA-N 3,7-dimethyloctan-1-ol Chemical compound CC(C)CCCC(C)CCO PRNCMAKCNVRZFX-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- 241000271309 Aquilaria crassna Species 0.000 description 1
- 241000218645 Cedrus Species 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- 244000301850 Cupressus sempervirens Species 0.000 description 1
- 240000006497 Dianthus caryophyllus Species 0.000 description 1
- 235000009355 Dianthus caryophyllus Nutrition 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- WEEGYLXZBRQIMU-UHFFFAOYSA-N Eucalyptol Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- 241000282375 Herpestidae Species 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- 235000019501 Lemon oil Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 235000019502 Orange oil Nutrition 0.000 description 1
- 235000019082 Osmanthus Nutrition 0.000 description 1
- 241000333181 Osmanthus Species 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 description 1
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005844 Thymol Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 235000016720 allyl isothiocyanate Nutrition 0.000 description 1
- OOCCDEMITAIZTP-UHFFFAOYSA-N allylic benzylic alcohol Natural products OCC=CC1=CC=CC=C1 OOCCDEMITAIZTP-UHFFFAOYSA-N 0.000 description 1
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 1
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 1
- 229940011037 anethole Drugs 0.000 description 1
- 229940095076 benzaldehyde Drugs 0.000 description 1
- 229930008407 benzylideneacetone Natural products 0.000 description 1
- 229930006722 beta-pinene Natural products 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010624 camphor oil Substances 0.000 description 1
- 229960000411 camphor oil Drugs 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229930007050 cineol Natural products 0.000 description 1
- 229960005233 cineole Drugs 0.000 description 1
- KJPRLNWUNMBNBZ-UHFFFAOYSA-N cinnamic aldehyde Natural products O=CC=CC1=CC=CC=C1 KJPRLNWUNMBNBZ-UHFFFAOYSA-N 0.000 description 1
- 229940117916 cinnamic aldehyde Drugs 0.000 description 1
- 239000001279 citrus aurantifolia swingle expressed oil Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000010639 cypress oil Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 1
- OALYTRUKMRCXNH-QMMMGPOBSA-N gamma-Nonalactone Natural products CCCCC[C@H]1CCC(=O)O1 OALYTRUKMRCXNH-QMMMGPOBSA-N 0.000 description 1
- PHXATPHONSXBIL-JTQLQIEISA-N gamma-Undecalactone Natural products CCCCCCC[C@H]1CCC(=O)O1 PHXATPHONSXBIL-JTQLQIEISA-N 0.000 description 1
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 description 1
- 229940020436 gamma-undecalactone Drugs 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 1
- 229940095102 methyl benzoate Drugs 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229960001047 methyl salicylate Drugs 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229940067137 musk ketone Drugs 0.000 description 1
- XMWRWTSZNLOZFN-UHFFFAOYSA-N musk xylene Chemical compound CC1=C(N(=O)=O)C(C)=C(N(=O)=O)C(C(C)(C)C)=C1N(=O)=O XMWRWTSZNLOZFN-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 description 1
- 235000019477 peppermint oil Nutrition 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 229940100595 phenylacetaldehyde Drugs 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000010666 rose oil Substances 0.000 description 1
- 235000019719 rose oil Nutrition 0.000 description 1
- 239000010671 sandalwood oil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- BWHOZHOGCMHOBV-BQYQJAHWSA-N trans-benzylideneacetone Chemical compound CC(=O)\C=C\C1=CC=CC=C1 BWHOZHOGCMHOBV-BQYQJAHWSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
Landscapes
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Laminated Bodies (AREA)
- Building Environments (AREA)
Description
【考案の詳細な説明】 ［産業上の利用分野］ 本考案は賦香内装材に関するものである。[Detailed explanation of the idea] [Industrial application field] The present invention relates to scented interior materials.
更に詳しくは、本考案は、保管中は芳香を無駄
に放散せず、かつ運搬時や施工時には外的損傷を
受け難く、内装材を装着した後任意のときに芳香
を発生させることができ、しかもその芳香が長期
に持続することを特徴とする優れた賦香内装材を
提供するものである。 More specifically, the present invention does not wastefully dissipate fragrance during storage, is less susceptible to external damage during transportation or construction, and can generate fragrance at any time after interior material is installed. In addition, the present invention provides an excellent scented interior material whose aroma lasts for a long period of time.
［従来技術］
合板、石膏ボード、発泡プラスチツクボード等
の板材に木目やその他の模様を印刷した装飾紙を
貼付した材料は、天井材、壁材、車輌内装材など
（以下単に「内装材」という）として広く使用さ
れている。しかし、これらの材料は、従来の檜材
や杉材のような木香はない。また、ボードや装飾
紙に香料を単に含浸させたり、あるいは香料含有
インキで印刷を施すこともできるが、その場合に
は芳香の寿命が短く、また材料の保管中や施工時
に香料の大部分が発散するという欠点がある。ま
た、装飾用印刷紙を表面に貼付した内装材では、
表面が損傷されることを防ぐために保護層をコー
トしたものもあるが、単なる薄いコーテイングで
は内装材に傷が付き易いという欠点が有る。[Prior art] Materials such as plywood, gypsum board, foamed plastic board, etc. with decorative paper printed with wood grain or other patterns pasted are used in ceiling materials, wall materials, vehicle interior materials, etc. (hereinafter simply referred to as "interior materials"). ) is widely used as However, these materials do not have the wood scent of traditional cypress or cedar wood. Boards and decorative papers can also be simply impregnated with fragrance or printed with fragrance-containing ink, but in this case the fragrance has a short lifespan and most of the fragrance is lost during storage and application of the material. It has the disadvantage of divergence. In addition, for interior materials with decorative printing paper pasted on the surface,
Some products are coated with a protective layer to prevent the surface from being damaged, but a mere thin coating has the disadvantage that the interior material is easily scratched.
［考案が解決しようとする問題点］
本考案は、このような種々の問題点を解消する
ためになされてもので、内装材の保管中には香気
を放散せず、取扱いおよび施工時には損傷され難
く、内装材を装着した後に初めて香気を放散させ
ることができ、かつ長期に芳香を持続することの
できる内装材を提供するものである。[Problems to be solved by the invention] The present invention has been made in order to solve these various problems, and is designed to prevent interior materials from emitting fragrance during storage and to avoid damage during handling and construction. To provide an interior material that is difficult to dissipate, can diffuse fragrance only after the interior material is attached, and can maintain the aroma for a long period of time.
［問題点を解決するための手段］
本考案の賦香内装材は、香料含有熱可塑性樹脂
層を有する多層体を基板に積層したものである。
前記多層体は、香料含有熱可塑性樹脂層および剥
離層の順に前記基板の側から積層したものであ
る。また、前記多層体の基板側には透明なバリア
層を付与して基板の木目を生かし、かつ基板側か
らの芳香の散逸を防止し、更に装飾層を付与する
こともできる。[Means for Solving the Problems] The scented interior material of the present invention is obtained by laminating a multilayer body having a scented thermoplastic resin layer on a substrate.
The multilayer body has a fragrance-containing thermoplastic resin layer and a release layer laminated in this order from the substrate side. Further, a transparent barrier layer may be provided on the substrate side of the multilayer body to make use of the wood grain of the substrate and prevent aroma from dissipating from the substrate side, and a decorative layer may also be provided.
すなわち、本考案においては、基板の上に必要
により印刷紙などの装飾層を貼付するのみでな
く、基板の上に直接あるいは基板の上に貼付した
装飾層の上に香料含有熱可塑性樹脂層を積層し、
更にその上に香気不透過性の剥離層を貼付する。
このような構成にすることによつて、板材に芳香
性を付与することができ、かつ芳香の無駄な散逸
を防ぎ、更に外部からの損傷を防ぐことができ
る。 That is, in the present invention, in addition to pasting a decorative layer such as printed paper on the substrate as necessary, a fragrance-containing thermoplastic resin layer is applied directly onto the substrate or on the decorative layer pasted on the substrate. Laminated,
Furthermore, a fragrance-impermeable release layer is attached thereon.
With such a configuration, it is possible to impart aromatic properties to the plate material, prevent unnecessary dissipation of the aroma, and further prevent damage from the outside.
また、基板や装飾層が香気を透過するような場
合には、更に装飾層と香料含有熱可塑性樹脂層と
の間に透明な罵詈や層を挟むことにより、香気の
無駄な散逸を一層効果的に防止することができ
る。 In addition, if the substrate or decorative layer allows fragrance to pass through, a transparent layer may be sandwiched between the decorative layer and the fragrance-containing thermoplastic resin layer to further effectively prevent wasteful dissipation of the fragrance. can be prevented.
更に、本考案においては、香料含有熱塑性樹脂
として、後述の特定の熱可塑性樹脂配合物を使用
することにより、芳香の強さや持続性を任意に調
整することができる。 Furthermore, in the present invention, by using a specific thermoplastic resin compound described below as the fragrance-containing thermoplastic resin, the intensity and persistence of the fragrance can be adjusted as desired.
本考案の内装材とは、建築物や車輌等の内張り
に使用する通例の内装材としての用途の他、家具
什器等の外張材としても使用できるものであり、
それらの板状材料をも包含する。 The interior material of the present invention can be used not only as a customary interior material for lining buildings and vehicles, but also as an exterior material for furniture fixtures, etc.
These plate-like materials are also included.
前記基板は、合板、石膏ボード、ソリツドプラ
スチツクボード、発泡プラスチツクボード等の板
状材料である。 The substrate is a plate-like material such as plywood, gypsum board, solid plastic board, or foamed plastic board.
装飾層は、内装材としての美観を調えるために
基板の上に付与するもので、木目、花模様、雲紋
その他の模様を付した印刷紙あるいは透明または
不透明のコーテイング層でもよい。 The decorative layer is provided on the substrate to enhance the aesthetic appearance of the interior material, and may be printed paper with wood grain, flower patterns, cloud patterns, or other patterns, or a transparent or opaque coating layer.
また、前記バリア層は透明なガスバリアフイル
ムであり、例えば、アクリロニトリル高含有共重
合体、エチレン−酢酸ビニル共重合体のケン化
物、ポリ塩化ビニリデン系樹脂、ポリエチレンテ
レフタレートなどのポリエステル系樹脂、ポリア
ミド系樹脂、ポリカーボネート樹脂などの熱可塑
性樹脂およびセロフアンなどからなるものであ
る。 The barrier layer is a transparent gas barrier film, and is made of, for example, a high-containing acrylonitrile copolymer, a saponified ethylene-vinyl acetate copolymer, a polyvinylidene chloride resin, a polyester resin such as polyethylene terephthalate, or a polyamide resin. , thermoplastic resin such as polycarbonate resin, and cellophane.
また、前記の剥離層はやはりガス不透過性のフ
イルム状の材料であり、上記の透明なガスバリア
フイルムの他、剥離剤をコーテイングした不透明
な材料も使用することができる。 Further, the above-mentioned release layer is also a gas-impermeable film-like material, and in addition to the above-mentioned transparent gas barrier film, an opaque material coated with a release agent can also be used.
本考案における前記香料含有熱可塑性樹脂は、
香料を直接熱可塑性樹脂に含浸させたもの自体で
もよいが、芳香の強さや持続性を調整したり、成
形性を向上させるなどの要請から、香料と相溶性
を有する軟質性樹脂Ａと香料と非相溶性の熱可塑
性樹脂Ｂとからなり、かつ前記軟質性樹脂Ａおよ
び熱可塑性樹脂Ｂは互いに相溶性を有するような
熱可塑性樹脂ＡおよびＢの配合物からなるものが
特に好ましい。 The fragrance-containing thermoplastic resin in the present invention is
Although it is possible to directly impregnate a thermoplastic resin with a fragrance, it is necessary to adjust the intensity and persistence of the fragrance, improve moldability, etc. Particularly preferred is a mixture of thermoplastic resins A and B, in which the soft resin A and the thermoplastic resin B are compatible with each other.
前記の軟質性樹脂Ａとしては、石油樹脂、ポリ
ブテン、ポリ塩化ビニル樹脂、天然ゴムまたは合
成ゴムの未加硫ゴム、カルボキシル基含有エチレ
ン共重合体などがある。これらの内、特にエチレ
ン−酢酸ビニル共重合体やエチレン−アクリル酸
エチル共重合体などのカルボキシル基含有エチレ
ン共重合体は、香料および後記の熱可塑性樹脂Ｂ
に対して良好な相溶性を有するので好ましく、特
にエチレン−酢酸ビニル共重合体が好適である。 Examples of the soft resin A include petroleum resin, polybutene, polyvinyl chloride resin, unvulcanized natural or synthetic rubber, and carboxyl group-containing ethylene copolymer. Among these, carboxyl group-containing ethylene copolymers such as ethylene-vinyl acetate copolymer and ethylene-ethyl acrylate copolymer are particularly suitable for use in fragrances and thermoplastic resin B described below.
Ethylene-vinyl acetate copolymers are particularly preferred because they have good compatibility with.
前記の熱可塑性樹脂Ｂとしては、高、中、低密
度のエチレン単独重合体、あるいはエチレン−ブ
テン−１共重合体、エチレン−ヘキセン−１共重
合体、エチレン−オクテン−１共重合体などのエ
チレンを主成分とするα−オレフインとの共重合
体、またはポリプロピレン、プロピレンを主成分
とる他のα−オレフインとの共重合体、ポリブテ
ン−１、ポリ−４−メチルペンテン−１などのポ
リオレフイン系樹脂、およびそれらと少量のアク
リル酸、マレイン酸などの不飽和カルボン酸また
はその誘導体などの極性モノマーとのグラフト変
性物、ナイロン−６、ナイロン−６，６、ナイロ
ン−12などのポリアミド系樹脂、ポリビニルアル
コール系樹脂、ポリエステル系樹脂、ポリスチレ
ン系樹脂、エチレン−酢酸ビニル共重合体のケン
化物およびそれらの混合物などがあり、比較的結
晶性が良好で、かつ製膜性などの加工性の良い樹
脂を使用する。これらの樹脂のうち汎用性を有
し、かつ安価であり、加工性も良好であるなどの
観点からポリオレフイン系樹脂が好適である。 Examples of the thermoplastic resin B include high, medium, and low density ethylene homopolymers, ethylene-butene-1 copolymers, ethylene-hexene-1 copolymers, ethylene-octene-1 copolymers, and the like. Copolymers with α-olefins mainly composed of ethylene, copolymers with other α-olefins mainly composed of polypropylene, propylene, polyolefins such as polybutene-1, poly-4-methylpentene-1, etc. resins, and graft-modified products of them with small amounts of polar monomers such as acrylic acid, unsaturated carboxylic acids such as maleic acid, or derivatives thereof, polyamide resins such as nylon-6, nylon-6,6, and nylon-12; These resins include polyvinyl alcohol resins, polyester resins, polystyrene resins, saponified products of ethylene-vinyl acetate copolymers, and mixtures thereof, and have relatively good crystallinity and good processability such as film-forming properties. use. Among these resins, polyolefin resins are preferred because they are versatile, inexpensive, and have good processability.
本考案において使用する香料は、天然香料、合
成香料および調合香料などの何れでもよい。 The fragrance used in the present invention may be any natural fragrance, synthetic fragrance, or blended fragrance.
例えば、天然香料としては、ジヤ香、シベツ
ト、カストル、アンバーグリスなどの動物性香
料、ラベンダー油、ハツカ油、レモン油、オレン
ジ油、ローズ油、シヨウノウ油、ビヤクダン油、
ヒノキ油、テレビン油、ライム油、沈香などの植
物精油からなる植物性香料がある。 For example, natural fragrances include animal fragrances such as jia incense, civet, castor, ambergris, lavender oil, peppermint oil, lemon oil, orange oil, rose oil, camphor oil, sandalwood oil,
There are botanical fragrances made from plant essential oils such as cypress oil, turpentine oil, lime oil, and agarwood.
合成香料としては、リモネンおよびα−または
β−ピネンのような炭化水素類、ジメチルオクタ
ノール、リナロール、サンタロール、ベンジルア
ルコール、β−フエニルエチルアルコールおよび
シンナミルアルコールなどのアルコール類、シネ
オールなどのエーテル類、ジフエニルオキサイ
ド、チモール、アネトールおよびβ−ナフチルメ
チルエーテルなどのフエノール類またはフエニル
エーテル類、ベンズアルデヒド、フエニルアセト
アルデヒド、ケイヒアルデヒドなどのアルデヒド
類、アセトフエノン、ｐ−メチルアセトフエノ
ン、ベンジリデンアセトンなどのケン類、ケイヒ
酸、フエニル酢酸などの酸類、γ−ノナラクト
ン、γ−ウンデカラクトンおよびクマリンなどの
ラクトン類、酩酸エチル、安息香酸メチル、安息
香酸エチル、酢酸エチル、サルチル酸メチル、ケ
イヒ酸メチルなどのエステル類、インドール、テ
トラヒドロキノリン、ムスクキシロール、ムスク
ケトンなどの窒素含有化合物ならびにアリルイソ
チオシアネートのようなイオウ含有化合物などあ
る。 Synthetic fragrances include hydrocarbons such as limonene and α- or β-pinene, alcohols such as dimethyloctanol, linalool, santalol, benzyl alcohol, β-phenylethyl alcohol and cinnamyl alcohol, and ethers such as cineol. phenols or phenyl ethers such as diphenyl oxide, thymol, anethole and β-naphthyl methyl ether, aldehydes such as benzaldehyde, phenylacetaldehyde, cinnamaldehyde, acetophenone, p-methylacetophenone, benzylidene acetone, etc. Acids such as cinnamic acid and phenylacetic acid, lactones such as γ-nonalactone, γ-undecalactone and coumarin, ethyl oxate, methyl benzoate, ethyl benzoate, ethyl acetate, methyl salicylate, cinnamic acid These include esters such as methyl, nitrogen-containing compounds such as indole, tetrahydroquinoline, musk xylol, musk ketone, and sulfur-containing compounds such as allyl isothiocyanate.
調合香料は、前記の天然香料、合成香料、その
他の薬剤を調合したもので、例えば、ローズ、ジ
ヤスミン、リラ、モクセイ、カーネーシヨンなど
の単一花香調のものや、それらを複合した種々の
香料がある。 Compound fragrances are mixtures of the above-mentioned natural fragrances, synthetic fragrances, and other agents, such as single-flower fragrances such as rose, diasmine, lilla, osmanthus, and carnation, and various fragrances that combine these fragrances. There is.
前記香料含有熱可塑性樹脂である軟質性樹脂Ａ
としてのカルボキシル基含有エチレン共重合体お
よび香料と相溶性のない熱可塑性樹脂Ｂ（以下に
「第２の熱可塑性樹脂」というの混合物を調整す
る方法は、特に限定されるものではないが、例え
ば、カルボキシル基含有エチレン共重合体に香料
を含浸させて、通常の混練機または押出機内で第
２の熱可塑性樹脂と溶融混合してペレツト化する
方法、あるいは、あらかじめ溶融したカルボキシ
ル基含有エチレン共重合体に香料を混合してペレ
ツト化し、得られたペレツトと第２の熱可塑性樹
脂のペレツトとをドライブレンドまたは溶融ブレ
ンドする方法、更に押出機によつて一段階でブレ
ンドおよび製膜を行なう方法などいずれの方法で
もよい。 Soft resin A which is the fragrance-containing thermoplastic resin
The method for preparing the mixture of the carboxyl group-containing ethylene copolymer and the thermoplastic resin B (hereinafter referred to as "second thermoplastic resin") that is incompatible with the carboxyl group-containing ethylene copolymer and fragrance is not particularly limited, but for example, , a method in which a carboxyl group-containing ethylene copolymer is impregnated with a fragrance and then melt-mixed with a second thermoplastic resin in a conventional kneader or extruder to form pellets, or a pre-melted carboxyl group-containing ethylene copolymer A method in which a fragrance is mixed with the mixture and made into pellets, and the obtained pellets are dry-blended or melt-blended with pellets of a second thermoplastic resin, and a method in which blending and film formation are performed in one step using an extruder, etc. Either method may be used.
本考案における香料の含有量は、香料の種類や
使用の態様、カルボキシル基含有エチレン共重合
体や第２の熱可塑性樹脂の種類などに従つて適宜
に選択することができる。 The content of the fragrance in the present invention can be appropriately selected depending on the type of fragrance, the mode of use, the type of carboxyl group-containing ethylene copolymer, the second thermoplastic resin, etc.
また、芳香持続性も、香料の種類、カルボキシ
ル基含有エチレン共重合体の種類やカルボキシル
基の含有量、第２の熱可塑性樹脂の種類、香料含
有熱可塑性樹脂の厚さ、積層の態様などによつて
相違するが、使用目的や用途などに応じて適宜に
選択することができる。 Fragrance persistence also depends on the type of fragrance, the type and carboxyl group content of the carboxyl group-containing ethylene copolymer, the type of second thermoplastic resin, the thickness of the fragrance-containing thermoplastic resin, the lamination mode, etc. Although they are different, they can be selected as appropriate depending on the purpose and use.
［作用］
本考案の香料含有内装材は前記のような構成を
有するので、芳香の放散開始時期を選択し、かつ
その持続性を高めることができると共に、表面強
度が優れている。また、香料含有熱可塑性樹脂層
の成分であるカルボキシル基含有エチレン共重合
体、例えば、エチレン−酢酸ビニル共重合体
（EVA）に含有される香料の含有量により芳香の
効果を適当に調節することができるが、これをポ
リエチレンなどの第２の熱可塑性樹脂に溶融混合
するので、芳香効果が一層発揮され、かつ芳香の
持続性をも調節できる。また前記の樹脂混合物
は、製膜性や成形性がよく、積層し易いなど利点
を有する。これらの理由は明確ではないが香料の
拡散速度や脱着速度がより遅いEVAなどのカル
ボキシル基含有エチレン共重合体の部分から、よ
り速いポリエチレンなどの第２の熱可塑性樹脂の
部分へと香料が移行して香料が効果的に大気中へ
放散されるものと考えられる。[Function] Since the fragrance-containing interior material of the present invention has the above-described configuration, it is possible to select the timing at which the fragrance starts to diffuse, increase its sustainability, and has excellent surface strength. In addition, the aromatic effect can be appropriately adjusted by the content of the fragrance contained in the carboxyl group-containing ethylene copolymer, such as ethylene-vinyl acetate copolymer (EVA), which is a component of the fragrance-containing thermoplastic resin layer. However, since this is melt-mixed with a second thermoplastic resin such as polyethylene, the aromatic effect is further exhibited, and the persistence of the aroma can also be adjusted. Further, the above-mentioned resin mixture has advantages such as good film formability and moldability, and easy lamination. The reasons for this are not clear, but the fragrance migrates from the carboxyl group-containing ethylene copolymer part such as EVA, which has a slower diffusion and desorption rate, to the second thermoplastic resin part, such as polyethylene, which has a faster diffusion rate and desorption rate. It is thought that the fragrance is effectively dissipated into the atmosphere.
また、本考案においては、香気不透過性のフイ
ルムを剥離層として賦香内装材の外面に貼付し、
内装材を装着した後に剥離層を剥がす。また、必
要に応じてバリア−層を設けることができる。従
つて、使用時まで徒に芳香を散逸させることがな
く、内装材を長期間保管しても芳香を保持するこ
とができるばかりでなく、作業場や倉庫の空間を
不必要な芳香で充満汚染することがない。 In addition, in the present invention, an aroma-impermeable film is attached to the outer surface of the scented interior material as a release layer,
Peel off the release layer after installing the interior material. Further, a barrier layer can be provided as necessary. Therefore, the fragrance does not dissipate unnecessarily until the time of use, and the fragrance can be retained even when the interior material is stored for a long period of time, and the space in the workplace or warehouse is not filled with unnecessary fragrance and polluted. Never.
［実施例］
以下に本考案の図示の実施例によつて更に説明
する。[Examples] The present invention will be further explained below with reference to illustrated embodiments.
第１図は本考案の賦香内装材の実施例の斜視図
である。第２図は本考案の第１実施例の部分拡大
断面図であり、第３図は本考案の第２実施例の部
分拡大断面図である。 FIG. 1 is a perspective view of an embodiment of the scented interior material of the present invention. FIG. 2 is a partially enlarged sectional view of the first embodiment of the present invention, and FIG. 3 is a partially enlarged sectional view of the second embodiment of the present invention.
本考案の賦香内装材１は、第２図示すように、
基板２およびその表面に積層した多層体３からな
る。この多層体３は、装飾層４、香料含有熱可塑
性樹脂層５および剥離層６を前記基板２の側から
順に積層したものである。なお、基板２の木目を
生かす場合などには前記装飾層４を省略すること
もできる。これらの部材の材質は前述の通りであ
り、各種の組合せにより実施することができる。 The scented interior material 1 of the present invention, as shown in Figure 2,
It consists of a substrate 2 and a multilayer body 3 laminated on its surface. This multilayer body 3 has a decorative layer 4, a fragrance-containing thermoplastic resin layer 5, and a release layer 6 laminated in this order from the substrate 2 side. Note that the decorative layer 4 may be omitted if the wood grain of the substrate 2 is to be utilized. The materials of these members are as described above, and various combinations can be used.
更に、本考案の第２実施例においては、前記装
飾層４および香料含有熱可塑性樹脂層５の間に透
明なバリア層７を積層したものであり、装飾層４
および基板２からの芳香の散逸を防止することが
できる。 Furthermore, in the second embodiment of the present invention, a transparent barrier layer 7 is laminated between the decorative layer 4 and the fragrance-containing thermoplastic resin layer 5.
Also, it is possible to prevent aroma from dissipating from the substrate 2.
［考案の効果］
上記のように本考案に賦香内装材は、芳香の放
散開始時期を任意に選択することができ、また芳
香の強さや持続性などの機能を調節することがで
きると共に、従来のこの種の内装材よりも表面強
度が優れている。[Effects of the invention] As described above, the scented interior material of the present invention allows the time to start dispersing the fragrance to be arbitrarily selected, and functions such as the strength and persistence of the fragrance can be adjusted. It has better surface strength than conventional interior materials of this type.
第１図は本考案の実施例の斜視図であり、第２
図は同実施例の層構成を示す部分拡大縦断面図、
および第３図は他の実施例の部分拡大縦断面図で
ある。
１……賦香内装材、２……基板、３……多層
体、４……装飾層、５……香料含有熱可塑性樹脂
層、６……剥離層、７……バリア層。
FIG. 1 is a perspective view of an embodiment of the present invention;
The figure is a partially enlarged vertical cross-sectional view showing the layer structure of the same example.
and FIG. 3 is a partially enlarged vertical sectional view of another embodiment. DESCRIPTION OF SYMBOLS 1...Fragranced interior material, 2...Substrate, 3...Multilayer body, 4...Decoration layer, 5...Fragrance-containing thermoplastic resin layer, 6...Peeling layer, 7...Barrier layer.
Claims (1)
り、かつ前記多層体が、香料含有熱可塑性樹脂
層および剥離層を前記基板の側から順に積層し
たものであり、更に前記香料含有熱可塑性樹脂
層が、香料を配合したカルボキシル基含有エチ
レン共重合体と、該香料と非相溶性であり、か
つ該カルボキシル基含有エチレン共重合体と相
溶性を有する第２の熱可塑性樹脂との混合物か
らなることを特徴とする賦香内装材。 (2) 前記多層体の香料含有熱可塑性樹脂層の基板
側に装飾層を設けてなる実用新案登録請求の範
囲第１に項記載の賦香内装材。 (3) 前記多層体の装飾層および香料含有熱可塑性
樹脂層の間に、更にバリア層を積層してなる実
用新案登録請求の範囲第２項に記載の賦香内装
材。 (4) 前記カルボキシル基含有エチレン共重合体が
エチレン−酢酸ビニル共重合体である実用新案
登録請求の範囲第１項に記載の賦香内装材。 (5) 前記第２の熱可塑性樹脂がポリオレフイン系
樹脂である実用新案登録請求の範囲第１項から
第４項のいずれかに記載の賦香内装材。[Claims for Utility Model Registration] (1) Consisting of a substrate and a multilayer body laminated on the surface thereof, and the multilayer body is one in which a fragrance-containing thermoplastic resin layer and a release layer are laminated in order from the side of the substrate. , the fragrance-containing thermoplastic resin layer further comprises a carboxyl group-containing ethylene copolymer blended with a fragrance, and a second layer that is incompatible with the fragrance and compatible with the carboxyl group-containing ethylene copolymer. A scented interior material characterized by being made of a mixture with a thermoplastic resin. (2) The scented interior material according to claim 1, wherein a decorative layer is provided on the substrate side of the fragrance-containing thermoplastic resin layer of the multilayer body. (3) The scented interior material according to claim 2, which further comprises a barrier layer laminated between the decorative layer and the fragrance-containing thermoplastic resin layer of the multilayer body. (4) The perfumed interior material according to claim 1, wherein the carboxyl group-containing ethylene copolymer is an ethylene-vinyl acetate copolymer. (5) The scented interior material according to any one of claims 1 to 4, wherein the second thermoplastic resin is a polyolefin resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1985141583U JPH0544134Y2 (en) | 1985-09-17 | 1985-09-17 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1985141583U JPH0544134Y2 (en) | 1985-09-17 | 1985-09-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6250930U JPS6250930U (en) | 1987-03-30 |
| JPH0544134Y2 true JPH0544134Y2 (en) | 1993-11-09 |
Family
ID=31049502
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1985141583U Expired - Lifetime JPH0544134Y2 (en) | 1985-09-17 | 1985-09-17 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0544134Y2 (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57140153A (en) * | 1981-02-26 | 1982-08-30 | Lonseal Kogyo Kk | Conductive interior finish material having granite-like external appearance |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59120139U (en) * | 1983-01-31 | 1984-08-13 | 昭和ラミネ−ト印刷株式会社 | Fragrance sheet |
| JPS61108395U (en) * | 1984-12-20 | 1986-07-09 |
-
1985
- 1985-09-17 JP JP1985141583U patent/JPH0544134Y2/ja not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57140153A (en) * | 1981-02-26 | 1982-08-30 | Lonseal Kogyo Kk | Conductive interior finish material having granite-like external appearance |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6250930U (en) | 1987-03-30 |
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