JPH0534151B2 - - Google Patents
Info
- Publication number
- JPH0534151B2 JPH0534151B2 JP2140012A JP14001290A JPH0534151B2 JP H0534151 B2 JPH0534151 B2 JP H0534151B2 JP 2140012 A JP2140012 A JP 2140012A JP 14001290 A JP14001290 A JP 14001290A JP H0534151 B2 JPH0534151 B2 JP H0534151B2
- Authority
- JP
- Japan
- Prior art keywords
- heat
- wax
- transfer layer
- weight
- sensitive transfer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000576 coating method Methods 0.000 claims description 18
- 239000011248 coating agent Substances 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 9
- 238000002844 melting Methods 0.000 claims description 9
- 230000008018 melting Effects 0.000 claims description 8
- 230000035515 penetration Effects 0.000 claims description 6
- 238000004040 coloring Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- 239000003085 diluting agent Substances 0.000 claims 2
- 239000000123 paper Substances 0.000 description 24
- 239000000976 ink Substances 0.000 description 23
- 239000010410 layer Substances 0.000 description 23
- 239000001993 wax Substances 0.000 description 23
- 239000011230 binding agent Substances 0.000 description 16
- 238000000034 method Methods 0.000 description 16
- 239000002904 solvent Substances 0.000 description 16
- 238000010438 heat treatment Methods 0.000 description 11
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 8
- 239000008096 xylene Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 5
- 239000006229 carbon black Substances 0.000 description 4
- 238000007757 hot melt coating Methods 0.000 description 4
- 239000002480 mineral oil Substances 0.000 description 4
- 235000010446 mineral oil Nutrition 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- 230000009182 swimming Effects 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 229920006267 polyester film Polymers 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- -1 and specifically Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000003990 capacitor Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- IIEWJVIFRVWJOD-UHFFFAOYSA-N ethylcyclohexane Chemical compound CCC1CCCCC1 IIEWJVIFRVWJOD-UHFFFAOYSA-N 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011086 glassine Substances 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Description
【発明の詳細な説明】
本発明は感熱転写記録紙の改良された製造方法
に関し、特に感熱転写層形成用インキの塗工時に
特別の加熱手段を用いない感熱転写記録紙の製造
方法に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an improved method for manufacturing thermal transfer recording paper, and particularly to a method for manufacturing thermal transfer recording paper that does not use special heating means during application of ink for forming a thermal transfer layer.
近年、コンピユーターやフアクシミリ等の各種
出力端末の出力方式として、低騒音、メンテナン
スフリー性、装置の簡便性、小型軽量化が可能で
ある事等の理由で感熱転写型記録法の開発が進め
られている。 In recent years, thermal transfer recording methods have been developed as an output method for various output terminals such as computers and facsimile machines due to their low noise, maintenance-free nature, simplicity of equipment, and ability to be made smaller and lighter. There is.
感熱転写記録紙は、熱良導性の基体の表面に、
加熱時に軟化或いは溶融するワツクスや他の低融
点物質をバインダーとし、着色剤等を混合したも
のを塗設したものであつて、被記録媒体と転写紙
の転写層とを合せ、感熱ヘツドでパターン状に印
字することにより被記録媒体上に印字するもので
ある。 Thermal transfer recording paper has a thermally conductive substrate with
It is coated with a binder made of wax or other low-melting point substance that softens or melts when heated, mixed with a coloring agent, etc., and the recording medium and the transfer layer of the transfer paper are combined and patterned with a heat-sensitive head. The image is printed on the recording medium by printing on the recording medium.
これらの感熱転写記録紙の製造法としては、従
来、ホツトメルトコーテイング法や、溶剤中に上
記インキバインダー分を通常40℃以上に加熱溶解
して塗布するホツトラツカーコーテイング法が使
用されている。 As methods for producing these thermal transfer recording papers, conventionally used are hot melt coating method and hot liquid coating method in which the above-mentioned ink binder is dissolved in a solvent by heating to usually 40° C. or higher and applied.
ホツトメルトコーテイング法は、バインダー自
体が常温では固体であるので、バインダーの融点
以上に加熱して塗布を行うものである。 In the hot melt coating method, since the binder itself is solid at room temperature, coating is performed by heating the binder to a temperature higher than its melting point.
一方、ホツトラツカーコーテイング法は、ソル
ベントコーテイング法とも称され、バインダーを
加熱下に溶剤中に溶解して塗布する方式であり、
この方式ではバインダーと溶剤とを混合し、バイ
ンダーの融点よりも低い温度に加熱してバインダ
ーを溶剤中に溶解して塗工するが、この場合にも
従来使用しているワツクスは40℃以下では溶剤中
に溶解しないので、40℃以下の常温ではインキの
塗布が困難で、何等かの加熱手段を用いなければ
良好な塗布はできない。 On the other hand, the hottrusker coating method, also called the solvent coating method, is a method in which the binder is dissolved in a solvent under heating and applied.
In this method, a binder and a solvent are mixed, heated to a temperature lower than the melting point of the binder, and the binder is dissolved in the solvent before being applied. Since it does not dissolve in solvents, it is difficult to apply ink at room temperatures below 40°C, and good application cannot be achieved unless some heating means is used.
勿論、上記バインダーを溶剤中に単に微分散さ
せただけ（いわゆるエマルジヨン）でも見掛上塗
布はできるが、塗布面にはいわゆる「泳ぎ」等の
ムラが発生していしまい、転写時には印字ムラが
生じて良好な転写印字品質が得られない。即ち、
溶解したバインダー成分が無い為、基体表面に均
一な被膜を作らない為である。従つて塗工時に加
熱手段を用いてバインダーを溶剤中に溶解するこ
とにより、塗布適性を保持する必要がる。 Of course, it is possible to apply the binder by simply finely dispersing it in a solvent (so-called emulsion), but this will cause unevenness such as so-called "swimming" on the coated surface, resulting in uneven printing during transfer. Good transfer print quality cannot be obtained. That is,
This is because there is no dissolved binder component, so a uniform film cannot be formed on the substrate surface. Therefore, it is necessary to maintain coating suitability by dissolving the binder in a solvent using heating means during coating.
本発明者は各種の化合物について、感熱転写層
用インキとしてのバインダー適性を検討した結
果、或る特定の化合物が、常温、例えば、０℃〜
40℃の温度で一般的な低沸点有機溶剤に少なくと
も一部溶解し、且つ感熱転写形成用インキのバイ
ンダーとして適当であることを見い出して本発明
に至つたものである。 As a result of examining the suitability of various compounds as binders as inks for heat-sensitive transfer layers, the present inventor found that certain compounds
The present invention was achieved by discovering that it is at least partially soluble in general low-boiling point organic solvents at a temperature of 40°C and is suitable as a binder for thermal transfer forming inks.
かかるバインダーとしては、ビニル基、エーテ
ル基等の極性基が導入されており、40℃以下で溶
剤に10重量％以上溶解するワツクスが好ましく、
キシレンに溶解する例につき示すと、ヘキスト社
製エステル系ワツクスWAX Ｅ、WAX Ｆ、
WAX KPS及びWAX BJ等や、部分鹸化エステ
ル系ワツクスとして、WAX OP、WAX OM、
WAX Ｖ及びWAX GL3（いずれもヘキスト社
製）が挙げられる。 As such a binder, a wax that has a polar group such as a vinyl group or an ether group introduced therein and that dissolves at least 10% by weight in a solvent at 40°C or lower is preferable.
Examples of ester waxes that dissolve in xylene include Hoechst's ester waxes WAX E, WAX F,
WAX KPS and WAX BJ, as well as partially saponified ester waxes such as WAX OP, WAX OM,
Examples include WAX V and WAX GL3 (both manufactured by Hoechst).
これらのワツクスはいずれもグラビアインキ用
溶剤として広く使用されている溶剤に対して常温
（０〜40℃）で10重量％以上の溶解度を有し且つ
優れたバインダー適性を有している。 All of these waxes have a solubility of 10% by weight or more at room temperature (0 to 40°C) in a solvent widely used as a solvent for gravure inks, and have excellent binder suitability.
以上は単なる具体例であり、40℃以下で溶剤に
10重量％以上溶解するワツクスであれば上記例に
限定されない。 The above is just a specific example.
The wax is not limited to the above examples as long as it dissolves 10% by weight or more.
本発明において使用する溶剤は、従来のグラビ
アインキ用に使用されている比較的低沸点の溶剤
であり、具体的にはトルエン、キシレン、トリク
レン、ホワイトスピリツト、酢酸エチル、酢酸ｎ
−ブチル、イソプロパノール、ｎ−ブタノール、
エチルシクロヘキサン等であり、前記ワツクスが
10重量％以上の溶解度を有するものを選択して１
種又は混合物として使用する。 The solvent used in the present invention is a relatively low boiling point solvent used for conventional gravure inks, and specifically, toluene, xylene, trichlene, white spirit, ethyl acetate, acetic acid n
-butyl, isopropanol, n-butanol,
ethylcyclohexane, etc., and the wax is
Select one with a solubility of 10% by weight or more.1
Use as seeds or mixtures.
本発明で使用する色材としては任意の有機及び
無機の顔料若しくは染料の中から耐熱性、耐候性
等を考慮して選択して用い、又、必要に応じて使
用する添加剤としては鉱物油、菜種油等の油類が
用いられる。 The coloring material used in the present invention is selected from arbitrary organic and inorganic pigments or dyes in consideration of heat resistance, weather resistance, etc., and the additive used as necessary is mineral oil. , rapeseed oil, and other oils are used.
以上の如き各成分の相対的使用量はいずれも従
来公知の感熱転写層形成用インキと同様でよく、
又、インキの塗布方法も常温で塗布することを除
けば従来技術と同様でよい。 The relative amounts of each component used as described above may be the same as in conventionally known inks for forming a heat-sensitive transfer layer,
Further, the ink application method may be the same as that of the prior art except that the ink is applied at room temperature.
以上の如くして形成される感熱転写層の物性
は、融点が41〜200℃、好ましくは50〜90℃、90
℃における粘度が10〜3000c.p.、好ましくは15〜
2000c.p.、針入度が0.1〜60、好ましくは0.1〜30
である。 The physical properties of the heat-sensitive transfer layer formed as described above include a melting point of 41 to 200°C, preferably 50 to 90°C,
Viscosity at °C is 10-3000c.p., preferably 15-3000c.p.
2000c.p., penetration 0.1~60, preferably 0.1~30
It is.
上記の感熱転写層を支持する基体シートは、使
用時に伸びたり破れたりしない強度を有し、記録
用熱ヘツドの熱により変形若しくは部分的溶融し
ないものであればいずれのものでもよく、具体的
には、例えば、ポリエステル、ポリプロピレン、
ポリスチレン、ポリカーボネート、ポリイミド及
びその他のプラスチツクフイルム、グラシン紙、
コンデンサ紙、帳票用紙、インデイアン紙及びそ
の他の紙、金属箔並びに以上の様な各材料の複合
体であるアルミニウム−紙複合シート、金属蒸着
紙若しくは金属蒸着フイルム等が挙げられる。 The base sheet supporting the above-mentioned heat-sensitive transfer layer may be any material as long as it has a strength that will not stretch or tear during use, and will not be deformed or partially melted by the heat of the recording thermal head. For example, polyester, polypropylene,
Polystyrene, polycarbonate, polyimide and other plastic films, glassine paper,
Examples include capacitor paper, ledger paper, Indian paper and other papers, metal foil, aluminum-paper composite sheets that are composites of the above-mentioned materials, metal-deposited paper, metal-deposited film, and the like.
上記感熱転写記録紙を用いて記録する際に使用
する被転写体は何等制限されないが、表面が平滑
性の高いものが好ましい。例えば、プラスチツク
フイルム、紙、金属、木材、ガラス、繊維等が使
用される。 There are no particular restrictions on the material to be transferred when recording with the above-mentioned thermal transfer recording paper, but it is preferable that the material has a highly smooth surface. For example, plastic film, paper, metal, wood, glass, fiber, etc. are used.
以上の様な本発明の方法によれば、感熱転写層
の形成に際し、使用するインキを何等加熱する必
要なく、例えば、０℃〜40℃の常温、好ましくは
室温で基体シート上に塗布し、満足できる感熱転
写層を形成することができる。又、インキの粘度
調整や塗工機の保温に加熱を行うにしても40℃以
下の温度で十分に粘度調整や保温が可能である。 According to the method of the present invention as described above, when forming a heat-sensitive transfer layer, the ink used is coated onto the base sheet at room temperature, for example, 0°C to 40°C, preferably at room temperature, without any need for heating, A satisfactory thermal transfer layer can be formed. Furthermore, even if heating is used to adjust the viscosity of the ink or to keep the coating machine warm, it is possible to sufficiently adjust the viscosity and keep the coating machine warm at a temperature of 40°C or less.
又、上記本発明方法により形成される感熱転写
層は、使用するインキが常温であつても溶剤中に
少なくとも一部のワツクスが溶解しているため、
塗布層にいわゆる「泳ぎ」等な現象が無く、塗布
ムラのない表面平滑な感熱転写層となつており、
従つてこれにより転写される印字も鮮明且つ解像
度の優れたものである。 Furthermore, in the heat-sensitive transfer layer formed by the method of the present invention, at least a portion of the wax is dissolved in the solvent even when the ink used is at room temperature.
There is no phenomenon such as so-called "swimming" in the coating layer, and the heat-sensitive transfer layer has a smooth surface with no uneven coating.
Therefore, the printed characters transferred by this method are also clear and have excellent resolution.
これに対して、従来のホツトラツカーコーテイ
ング法及びホツトメルトコーテイング法では、加
熱手段及びその温度管理が必要であり、温度管理
が不調であると塗布が困難になつたり、塗布ムラ
や厚みの不均一が発生するという問題があるが、
本発明では塗布時に加熱を要しないのでこの様な
問題も解決されている。 On the other hand, the conventional hot tracker coating method and hot melt coating method require a heating means and its temperature control, and if temperature control is inadequate, coating may become difficult, and uneven coating or thickness problems may occur. There is a problem that uniformity occurs, but
In the present invention, this problem is solved because heating is not required during coating.
更に塗布時に加熱を要する従来の塗布方法で
は、重ね刷りによる多色の感熱転写層の形成は困
難であるが、本発明方法によれば、一旦形成した
感熱転写層を軟化させたり侵したりすることがな
いので重ね刷りが可能であり、多色模様、ストラ
イプ状の感熱転写層等の形成も容易である。 Furthermore, with conventional coating methods that require heating during coating, it is difficult to form a multicolor heat-sensitive transfer layer by overprinting, but according to the method of the present invention, the heat-sensitive transfer layer once formed can be softened or eroded. Since there are no layers, overprinting is possible, and it is easy to form multicolor patterns, striped heat-sensitive transfer layers, etc.
更に常温で行う従来のソルベントコーテイング
方法では、バインダーが溶剤中に溶解していない
ため、いわゆる「泳ぎ」が生じて不均一な感熱転
写層となるが、本発明ではこのような不都合も解
決されている。 Furthermore, in the conventional solvent coating method, which is carried out at room temperature, the binder is not dissolved in the solvent, so so-called "swimming" occurs, resulting in an uneven heat-sensitive transfer layer, but the present invention solves this problem. There is.
本発明は以上の様な利点を有するので、例え
ば、用紙の流れ方向に黄、赤、藍、墨の各色の区
域を順に繰返し設けておき、１個の熱ヘツドで多
色の印字が可能な転写型の多色感熱転写記録紙等
も容易に提供することができ、従来のホツトメル
トコーテイング法における如く各色の印刷若しく
は塗布ユニツト毎に加熱したり、一旦転移したイ
ンキの版への付着といつた不都合も生じない。 Since the present invention has the above-mentioned advantages, for example, it is possible to repeatedly provide yellow, red, indigo, and ink color areas in the paper flow direction, and print in multiple colors with one thermal head. Transfer-type multicolor thermal transfer recording paper can also be easily provided, and as in the conventional hot melt coating method, each color printing or coating unit is heated, and once the ink has been transferred, it is difficult to adhere to the plate. No other inconvenience will occur.
次に実施例を挙げて本発明を更に具体的に説明
する。 Next, the present invention will be explained in more detail with reference to Examples.
実施例 １
12μｍの厚みのポリエステルフイルムに以下の
転写インキ組成物を常温（25℃）でロールコータ
ー装置で乾燥時基準で３ｇ／m2の割合で塗布した
ところ、平滑な表面を有する感熱転写層が形成さ
れた。Example 1 When the following transfer ink composition was applied to a 12 μm thick polyester film using a roll coater at room temperature (25°C) at a rate of 3 g/m 2 on a dry basis, a thermal transfer layer with a smooth surface was obtained. was formed.
ヘキスト社製WAX BJ 15重量部
カーボンブラツク ２重量部
鉱物油 １重量部
キシレン 82重量部
尚、上記ワツクスは25℃において100ｇのキシ
レン中に約20ｇが溶解する。WAX BJ manufactured by Hoechst 15 parts by weight Carbon black 2 parts by weight Mineral oil 1 part by weight Xylene 82 parts by weight Approximately 20 g of the above wax is dissolved in 100 g of xylene at 25°C.
上記感熱転写記録紙を上質紙と合せて神鋼電機
(株)製サーマルプリンタSP3050中に通して印字し
たところ黒色の高画質の印字ができた。 Shinko Electric Co., Ltd. combined the above thermal transfer recording paper with high-quality paper.
When printed through a thermal printer SP3050 manufactured by Co., Ltd., a black high-quality print was obtained.
上記感熱転写層の融点は55℃、90℃における粘
度は100c.p.及び針入度が４であつた。 The heat-sensitive transfer layer had a melting point of 55°C, a viscosity of 100 c.p. at 90°C, and a penetration of 4.
実施例 ２
12μｍの厚みのポリエステルフイルムに以下の
転写インキ組成物を常温（25℃）でロールコータ
ー装置で乾燥時基準で３ｇ／m2の割合で塗布した
ところ、平滑な表面を有する感熱転写層が形成さ
れた。Example 2 When the following transfer ink composition was applied to a 12 μm thick polyester film using a roll coater at room temperature (25°C) at a dry rate of 3 g/m 2 , a thermal transfer layer with a smooth surface was obtained. was formed.
キヤンデリラワツクス 15重量部
カーボンブラツク ２重量部
鉱物油 １重量部
キシレン 82重量部
尚、上記ワツクスは40℃において100ｇのキシ
レン中に約15ｇが溶解する。Candelilla wax 15 parts by weight Carbon black 2 parts by weight Mineral oil 1 part by weight Xylene 82 parts by weight Approximately 15 g of the above wax dissolves in 100 g of xylene at 40°C.
上記感熱転写記録紙を上質紙と合せて神鋼電機
(株)製サーマルプリンタSP3050中に通して印字し
たところ黒色の高画質の印字ができた。 Shinko Electric Co., Ltd. combined the above thermal transfer recording paper with high-quality paper.
When printed through a thermal printer SP3050 manufactured by Co., Ltd., a black high-quality print was obtained.
上記感熱転写層の融点は80℃、90℃における粘
度は50c.p.及び針入度が２であつた。 The heat-sensitive transfer layer had a melting point of 80° C., a viscosity of 50 c.p. at 90° C., and a penetration of 2.
実施例 ３
12μｍの厚みのポリエステルフイルムに以下の
転写インキ組成物を常温（25℃）でロールコータ
ー装置で乾燥時基準で３ｇ／m2の割合で塗布した
ところ、平滑な表面を有する感熱転写層が形成さ
れた。Example 3 When the following transfer ink composition was applied to a 12 μm thick polyester film using a roll coater at room temperature (25°C) at a dry rate of 3 g/m 2 , a thermal transfer layer with a smooth surface was obtained. was formed.
ライスラワツクス 15重量部
カーボンブラツク ２重量部
鉱物油 １重量部
キシレン 82重量部
尚、上記ワツクスは40℃において100ｇのキシ
レン中に約15ｇが溶解する。Rice la wax 15 parts by weight Carbon black 2 parts by weight Mineral oil 1 part by weight Xylene 82 parts by weight Approximately 15 g of the above wax dissolves in 100 g of xylene at 40°C.
上記感熱転写記録紙を上質紙と合せて神鋼電機
(株)製サーマルプリンタSP3050中に通して印字し
たところ黒色の高画質の印字ができた。 Shinko Electric Co., Ltd. combined the above thermal transfer recording paper with high-quality paper.
When printed through a thermal printer SP3050 manufactured by Co., Ltd., a black high-quality print was obtained.
上記感熱転写層の融点は80℃、90℃における粘
度は50c.p.及び針入度が２であつた。 The heat-sensitive transfer layer had a melting point of 80° C., a viscosity of 50 c.p. at 90° C., and a penetration of 2.
実施例 ４
10μｍの厚みのコンデンサ紙に以下の各色の転
写インキ組成物を常温（20℃）でグラビア印刷機
で乾燥時基準で５ｇ／m2の割合で塗布したとこ
ろ、「泳ぎ」が無く、美麗且つ平滑な表面を有す
る感熱転写層が形成された。Example 4 When the following transfer ink compositions of each color were applied to a 10 μm thick capacitor paper using a gravure printing machine at room temperature (20°C) at a dry rate of 5 g/m 2 , there was no “swimming”. A heat-sensitive transfer layer with a beautiful and smooth surface was formed.
ヘキスト社製WAX Ｖ 30重量部 色 材 ３重量部 トルエン 67重量部 色材としては下記の物を使用した。Hoechst WAX V 30 parts by weight Color Material 3 parts by weight Toluene 67 parts by weight The following materials were used as coloring materials.
黄インキ；CI21090
赤インキ；CI15850
藍インキ；CI74160
墨インキ；カーボンブラツク
尚、上記ワツクスは20℃において100ｇのトル
エン中に約40ｇが溶解する。Yellow ink; CI21090 Red ink; CI15850 Blue ink; CI74160 Black ink; Carbon black Approximately 40 g of the above wax is dissolved in 100 g of toluene at 20°C.
上記感熱転写記録紙を上質紙を合せて東芝サー
マルヘツドを装着した印字機に、印加電圧12V及
び印加時間２ｍsec.の条件で通したところ印字品
質の良い多色の画像が得られた。 When the above thermal transfer recording paper was combined with high-quality paper and passed through a printing machine equipped with a Toshiba thermal head under conditions of an applied voltage of 12 V and an application time of 2 msec., a multicolor image with good print quality was obtained.
尚、上記各感熱転写層の融点は55℃、90℃にお
ける粘度は150c.p.及び針入度が10であつた。 The melting point of each heat-sensitive transfer layer was 55°C, the viscosity at 90°C was 150 c.p., and the penetration was 10.
Claims (1)
なくとも10重量％以上溶解するワツクスと、色材
とを含む感熱転写層形成用インキを用いて、基体
上に０℃以上40℃以下で、融点が41〜200℃、90
℃における粘度が10〜3000c.p.及び針入度が0.1〜
60である感熱転写層を塗設することを特徴とする
感熱転写記録紙の製造方法。1. Using a heat-sensitive transfer layer forming ink containing a diluent, a wax that dissolves in the diluent by at least 10% by weight at a temperature of 0°C to 40°C, and a coloring material, a heat-sensitive transfer layer forming ink is applied onto a substrate at a temperature of 0°C to 40°C. and the melting point is 41-200℃, 90
Viscosity at °C is 10~3000c.p. and penetration is 0.1~
A method for producing a heat-sensitive transfer recording paper, characterized by coating a heat-sensitive transfer layer of 60%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2140012A JPH0396390A (en) | 1990-05-31 | 1990-05-31 | Production of thermal transfer recording paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2140012A JPH0396390A (en) | 1990-05-31 | 1990-05-31 | Production of thermal transfer recording paper |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57011272A Division JPS58128897A (en) | 1982-01-27 | 1982-01-27 | Production of heat-sensitive transfer recording paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0396390A JPH0396390A (en) | 1991-04-22 |
| JPH0534151B2 true JPH0534151B2 (en) | 1993-05-21 |
Family
ID=15258882
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2140012A Granted JPH0396390A (en) | 1990-05-31 | 1990-05-31 | Production of thermal transfer recording paper |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0396390A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05201458A (en) * | 1992-01-20 | 1993-08-10 | Toyo Glass Co Ltd | Glass container internal plug |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4241916A1 (en) * | 1992-12-11 | 1994-06-16 | Huber Fa Michael Muenchen | Additive for reducing the residual toluene content of prints produced by gravure and / or flexographic printing and printing inks containing the additive |
| JP3720396B2 (en) * | 1994-10-17 | 2005-11-24 | 富士写真フイルム株式会社 | Thermal transfer recording material |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53144751A (en) * | 1977-05-23 | 1978-12-16 | Riso Kagaku Corp | Thermosensitive transfer sheet |
| JPS5698190A (en) * | 1980-01-07 | 1981-08-07 | Fuji Kagakushi Kogyo Co Ltd | Ribbon for color thermotranscription |
-
1990
- 1990-05-31 JP JP2140012A patent/JPH0396390A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53144751A (en) * | 1977-05-23 | 1978-12-16 | Riso Kagaku Corp | Thermosensitive transfer sheet |
| JPS5698190A (en) * | 1980-01-07 | 1981-08-07 | Fuji Kagakushi Kogyo Co Ltd | Ribbon for color thermotranscription |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05201458A (en) * | 1992-01-20 | 1993-08-10 | Toyo Glass Co Ltd | Glass container internal plug |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0396390A (en) | 1991-04-22 |
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