JPH05255626A - Ink for ink jet printing - Google Patents
Ink for ink jet printingInfo
- Publication number
- JPH05255626A JPH05255626A JP8806992A JP8806992A JPH05255626A JP H05255626 A JPH05255626 A JP H05255626A JP 8806992 A JP8806992 A JP 8806992A JP 8806992 A JP8806992 A JP 8806992A JP H05255626 A JPH05255626 A JP H05255626A
- Authority
- JP
- Japan
- Prior art keywords
- ink
- disperse dye
- weight
- water
- jet printing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、インクジェット捺染用
インクに係わり、さらに詳細にはポリエステル系繊維か
らなる布帛の印捺に適したインクジェット捺染用インク
に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an ink jet printing ink, and more particularly to an ink jet printing ink suitable for printing a cloth made of polyester fiber.
【０００２】[0002]
【従来の技術】従来、布帛に図柄を印捺する方法として
は、スクリーン捺染法，ローラ捺染法，ロータリースク
リーン捺染法，転写捺染法等が用いられてきたが、図柄
の変更毎にスクリーン枠，彫刻ローラ，転写紙等を用意
する必要があり、これらスクリーン枠，彫刻ローラ，転
写紙の作成はかなり高価であるため、かなりのロットを
生産しないと経済的な面で合わない点のみならず、ファ
ッションの多様化に迅速に対応出来ないという欠点を有
する。2. Description of the Related Art Conventionally, as a method for printing a pattern on a cloth, a screen printing method, a roller printing method, a rotary screen printing method, a transfer printing method, etc. have been used. It is necessary to prepare engraving rollers, transfer paper, etc., and since the production of these screen frames, engraving rollers, transfer paper is quite expensive, not only is it economically incompatible unless a large lot is produced, It has the drawback of not being able to quickly respond to the diversification of fashion.
【０００３】これ等の欠点を解消するために、スキャナ
ーで見本を読み取り、コンピュータで画像処理を行な
い、その結果をインクジェット方式で印捺する技術が開
発されてきており、これ等のインクジェット方式に用い
るインクとしては、各種水溶性染料を有機溶剤や水に溶
解させたものが知られている。In order to solve these drawbacks, a technique has been developed in which a sample is read by a scanner, image processing is performed by a computer, and the result is printed by an inkjet method, which is used for these inkjet methods. Known inks are those prepared by dissolving various water-soluble dyes in an organic solvent or water.
【０００４】そして、水溶性染料としては、直接染料，
酸性染料，反応性染料等が用いられてきたが、かかる染
料はポリエステル系繊維に応用できないという問題があ
った。As the water-soluble dye, a direct dye,
Acid dyes and reactive dyes have been used, but there is a problem that such dyes cannot be applied to polyester fibers.
【０００５】そこで、分散染料を用いたインクジェット
捺染用のインク開発がなされ、例えば特開昭５０−５９
１０８号公報には有機溶媒に分散染料を溶解させた分散
型のものが、また特開昭５４−１８９７４号公報には水
に分散染料を溶解させた分散型のものが提案されてい
る。Therefore, an ink for ink-jet printing using a disperse dye has been developed, for example, JP-A-50-59.
No. 108 discloses a dispersion type in which a disperse dye is dissolved in an organic solvent, and JP-A-54-18974 proposes a dispersion type in which a disperse dye is dissolved in water.
【０００６】[0006]
【発明が解決しようとする課題】しかしながら溶解型の
インクジェット捺染用のインクは分散染料の溶解度が低
く高濃度の捺染製品が得られないという問題があり、一
方分散型のインクジェット捺染用のインクは高濃度の捺
染製品は得られるものの分散染料の粒子が凝集し巨大粒
子になったり、分散性が完全でないためノズルに目詰ま
りが発生し、長時間にわたって安定した印捺ができない
という問題があった。However, the solution type ink jet printing ink has a problem that the solubility of the disperse dye is low and a high-concentration print product cannot be obtained, while the dispersion type ink jet printing ink has a high problem. Although a printing product having a high density can be obtained, there is a problem in that particles of the disperse dye aggregate to form huge particles, or the nozzles are clogged due to incomplete dispersibility, and stable printing cannot be performed for a long time.
【０００７】本発明者等は、分散染料インクのインクジ
ェット方式での布帛への捺染法について鋭意研究を続け
た結果上記問題点が解消された新規インクを見出し本発
明を完成したものである。The present inventors have conducted intensive studies on a method of printing a disperse dye ink on a cloth by an ink jet system, and as a result, have found a new ink in which the above problems are solved and completed the present invention.
【０００８】本発明の目的は、ノズル目詰まり等を生じ
ることがなく、かつ高濃度の捺染を可能にするインクジ
ェット捺染用インクを提供するにある。An object of the present invention is to provide an ink for ink jet printing which does not cause nozzle clogging and enables high density printing.
【０００９】[0009]
【課題を解決するための手段】上記の目的は、水に不溶
または難溶性の分散染料，分散剤，乾燥防止剤及び水か
ら成り、上記分散染料が粒径０．１〜５μｍで分散され
ており、かつ上記分散剤が分散染料に対して５０〜１５
０重量％含有されていると共に、上記乾燥防止剤がイン
ク全体に対して２０〜７０重量％含有されていることを
特徴とするインクジェット捺染用インクにより達成され
る。The above-mentioned object comprises a disperse dye which is insoluble or hardly soluble in water, a dispersant, an anti-drying agent and water, and the disperse dye is dispersed in a particle size of 0.1 to 5 μm. And the dispersant is 50 to 15 relative to the disperse dye.
It is achieved by an ink for ink jet textile printing, characterized in that the anti-drying agent is contained in an amount of 20 to 70% by weight based on the total weight of the ink in addition to 0% by weight.
【００１０】以下、本発明を詳細に説明する。The present invention will be described in detail below.
【００１１】本発明に用いられる分散染料としては、ア
ントラキノン系，アゾ系，ニトロジフェニルアミン系，
メチン系，アミノケトン系，ケトイミン系等が挙げられ
る。これらの分散染料の好ましい含有量はインク全体に
対して１〜２０重量％であり、更に好適には３〜１５重
量％である。The disperse dyes used in the present invention include anthraquinone type, azo type, nitrodiphenylamine type,
Examples include methine type, aminoketone type and ketoimine type. The content of these disperse dyes is preferably 1 to 20% by weight, more preferably 3 to 15% by weight, based on the whole ink.
【００１２】本発明に用いる分散剤としてはリグニンス
ルホン酸，ナフタレンスルホン酸ホルムアルデヒド縮合
物，シエファー酸・クレゾール・重亜硫酸ナトリウム・
ホルムアルデヒド縮合物等が挙げられる。これらの分散
剤の好ましい含有量は上記分散染料に対して５０〜１５
０重量％であり、更に好適には７５〜１２５重量％であ
る。分散剤が５０重量％未満であると分散染料の分散性
が悪くノズルに目詰まりが発生し、一方分散剤が１５０
重量％より多くなると布帛への滲み量が多くなるので好
ましくない。As the dispersant used in the present invention, lignin sulfonic acid, naphthalene sulfonic acid formaldehyde condensate, syferic acid / cresol / sodium bisulfite /
Formaldehyde condensate and the like can be mentioned. The preferred content of these dispersants is 50 to 15 relative to the above disperse dye.
It is 0% by weight, and more preferably 75 to 125% by weight. When the dispersant is less than 50% by weight, the dispersibility of the disperse dye is poor and the nozzle is clogged.
When it is more than the weight%, the amount of bleeding on the fabric increases, which is not preferable.
【００１３】そして、上記の分散染料は粒径０．１〜５
μｍ、好ましくは０．２〜２μｍで分散されていること
が必要である。分散染料の粒径が５μｍを越すとノズル
の目詰まりが発生しやすく好ましくない。一方、０．１
μｍ未満に細微粒子化するのは効果の割りに経済的でな
い。そして、分散染料の粒径を０．１〜５μｍにするた
めには、分散染料を分散剤に分散させた分散液をサウン
ドミル，サウンドグラインダー，アトライター等により
微粒子化し、次いでフィルターでロ過すること等を実施
すれば良い。The above disperse dye has a particle size of 0.1 to 5
It is necessary that the particles are dispersed in a size of μm, preferably 0.2 to 2 μm. If the particle size of the disperse dye exceeds 5 μm, the nozzle may be clogged, which is not preferable. On the other hand, 0.1
It is not economical for the effect to make fine particles smaller than μm. Then, in order to make the particle size of the disperse dye 0.1 to 5 μm, the dispersion liquid in which the disperse dye is dispersed in a dispersant is made into fine particles by a sound mill, sound grinder, attritor, etc., and then filtered by a filter. You just have to do things.
【００１４】本発明に用いる乾燥防止剤としてはエチレ
ングリコール，ジエチレングリコール，トリエチレング
リコール，チオジエチレングリコール，ジエチレングリ
コールジメチルエーテル，トリエチレングリコールジメ
チルエーテル，ポリエチレングリコールジメチルエーテ
ル等のグリコール類及び尿素等が挙げられる。これらの
乾燥防止剤の好ましい含有量はインク全体に対して２０
〜７０重量％、更に好適には２５〜５０重量％である。
乾燥防止剤が２０重量％未満であるとインクの蒸発防止
が不充分であり、一方７０重量％より多くなると布帛へ
の滲み量が多くなるので好ましくない。Examples of the anti-drying agent used in the present invention include glycols such as ethylene glycol, diethylene glycol, triethylene glycol, thiodiethylene glycol, diethylene glycol dimethyl ether, triethylene glycol dimethyl ether and polyethylene glycol dimethyl ether, and urea. The preferred content of these anti-drying agents is 20 based on the total ink.
˜70 wt%, and more preferably 25 to 50 wt%.
If the anti-drying agent is less than 20% by weight, the evaporation of the ink is insufficiently prevented. On the other hand, if it exceeds 70% by weight, the amount of bleeding on the fabric increases, which is not preferable.
【００１５】このような組成から成るインクジェット捺
染用インクの適用はノズル内に発熱抵抗素子を埋め込
み、その発熱によりインクを沸騰させ、その泡の圧力に
よりインクを吐出させるバブルジェット方式，圧電素子
に電気信号を加えて変形させインク室の体積変化を励起
してインク粒子を飛ばすパルスジェット方式，超音波振
動しているノズルからインクを加圧連続噴射させて粒子
化し、粒子を荷電量に制御一定電界中を通過偏向させ、
記録，非記録粒子に分けて記録する荷電制御方式等によ
り実施される。The ink-jet printing ink having such a composition is applied by embedding a heating resistance element in the nozzle, boiling the ink by its heat generation, and ejecting the ink by the pressure of the bubble. A pulse jet method that applies a signal to deform and excites the volume change of the ink chamber to fly ink particles, ink is continuously jetted under pressure from a nozzle that is vibrating ultrasonically to form particles, and the particles are controlled to a constant charge electric field Deflected through
It is carried out by a charge control method or the like in which recording and non-recording particles are separately recorded.
【００１６】本発明のインクジェット捺染用インクをポ
リエステル系繊維に印捺する場合、布帛にデンプン類
（デンプン，可溶性デンプン，水溶性デンプン誘導体
等）、水溶性のセルロース誘導体（カルボキシメチルセ
ルロース，ヒドロキシエチルセルロース，メチルセルロ
ース等）、アルギン酸ナトリウム，アラビアゴム，ガム
類（ローカストビーンガム，グアーガム等）、水溶性タ
ンパク（ゼラチン，にかわ等）、水溶性の合成高分子化
合物（ポリアクリル酸ナトリウム，ポリビニルアルコー
ル，ポリエチレンオキシド，ポリビニルピロリドン，ポ
リアクリルアミド，ポリエチレンイミン，４級化水溶性
カチオンポリマー等）等の捺染用糊剤を付与し、滲みを
防止するようにすることが好ましい。そしてかかる布帛
を用いて上記のインクジェット方式にて，印捺した後、
布帛を熱処理することにより分散染料が繊維に固着する
ようになる。When the ink-jet printing ink of the present invention is printed on polyester fibers, starch (starch, soluble starch, water-soluble starch derivative, etc.) and water-soluble cellulose derivative (carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose) are applied to the cloth. Etc.), sodium alginate, gum arabic, gums (locust bean gum, guar gum, etc.), water-soluble proteins (gelatin, glue, etc.), water-soluble synthetic polymer compounds (sodium polyacrylate, polyvinyl alcohol, polyethylene oxide, polyvinyl) A sizing agent such as pyrrolidone, polyacrylamide, polyethyleneimine, quaternized water-soluble cationic polymer, etc.) is preferably added to prevent bleeding. And after printing with the above inkjet method using such a cloth,
The heat treatment of the fabric causes the disperse dye to stick to the fibers.
【００１７】[0017]
【実施例】以下、本発明を実施例に基づき詳細に説明す
る。EXAMPLES The present invention will be described in detail below based on examples.
【００１８】尚、実施例および比較例中の数値の基本と
なる試験方法は次の通りである。 （１）測色 マクベス分光光度計Ｍ−２０２０型
（最大吸収波長におけるＫ／Ｓ値） （２）粒径の測度 測定機器 ：島津製作所ＳＡＬＤ−
１１００ 測定方法 ：レーザ散乱による方法（ミー散乱） セルの種類：フローセル 測定温度 ：２０℃ 測定間隔 ：１秒 測定回数 ：５回The test methods on which the numerical values in Examples and Comparative Examples are based are as follows. (1) Color measurement Macbeth spectrophotometer M-2020 type (K / S value at the maximum absorption wavelength) (2) Particle size measurement device: Shimadzu SALD-
1100 Measurement method: Method by laser scattering (Mie scattering) Cell type: Flow cell Measurement temperature: 20 ° C Measurement interval: 1 second Number of measurements: 5 times
【００１９】実施例１ ポリエチレンテレフタレート５０ｄ／１８ｆを経糸に、
ポリエチレンテレフタレート５０ｄ／１８ｆを緯糸に用
い、経糸密度１１０本／インチ、緯糸密度８５本／イン
チで織成した平織物を準備し、この織物を公知の方法で
糊抜，精錬，ヒートセット加工した。その後、この織物
にｐＨ調整剤としてウルトラＭＴ（御幣島化学（株）
製）０．５重量％，アルギン酸ナトリウムとしてダック
アルギンＮＳＰＨ（紀文（株）製）０．５重量％，水９
９重量％からなる処理液をパッディングし、マングルで
絞り率３５％に絞った後、１２０℃にて２分間乾燥し
た。Example 1 Polyethylene terephthalate 50d / 18f was used as a warp,
Using polyethylene terephthalate 50d / 18f as the weft, a plain woven fabric having a warp density of 110 yarns / inch and a weft yarn density of 85 yarns / inch was prepared, and the woven fabric was desizing, refined and heat set by known methods. Then, as a pH adjuster for this fabric, Ultra MT (Minnajima Chemical Co., Ltd.)
0.5% by weight, duck algin NSPH as sodium alginate (manufactured by Kibun Co., Ltd.) 0.5% by weight, water 9
The treatment liquid consisting of 9 wt% was padded, squeezed with a mangle to a squeezing ratio of 35%, and then dried at 120 ° C. for 2 minutes.
【００２０】別に、分散染料（イエロー：Ｃ．Ｉ．Ｄｉ
ｓｐｅｒｓｅ Ｙｅｌｌｏｗ ８８，マゼンタ：Ｃ．
Ｉ．Ｄｉｓｐｅｒｓｅ Ｒｅｄ ３４９，シアン：Ｃ．
Ｉ．Ｄｉｓｐｅｒｓｅ Ｂｌｕｅ １６０，ブラック：
Ｃ．Ｉ．Ｄｉｓｐｅｒｓｅ Ｂｌａｃｋ １）５０重量
％、分散剤としてリグニンスルホン酸５０重量％を配合
し、サンドミルにて粒度分布が０．１〜５．０μｍにな
る様に微粒子化を行ない、その後１０μｍのフィルター
（日本ミリポール工業（株）製，ミリポールフィルター
ＬＣ１０．０μｍ）にてロ過し、分散染料の微粒子化物
を得た。Separately, a disperse dye (yellow: CI Di
sperse Yellow 88, magenta: C.I.
I. Disperse Red 349, cyan: C.I.
I. Disperse Blue 160, black:
C. I. Disperse Black 1) 50% by weight and lignin sulfonic acid 50% by weight as a dispersant are blended, and finely divided by a sand mill so that the particle size distribution becomes 0.1 to 5.0 μm, and then a 10 μm filter (Japan Millipol). It was filtered with Millipol Filter LC 10.0 μm manufactured by Kogyo Co., Ltd. to obtain fine particles of disperse dye.
【００２１】次に、上記の分散染料の微粒子化物１０重
量％，乾燥防止剤としてジエチレングリコール４０重量
％，水５０重量％からなるインクをパルスジェット方式
のインクジェットプリンターに搭載し、８ドット／ｍｍ
の連続プリントを上記前処理織物に実施した。Next, an ink containing 10% by weight of the above disperse dye fine particles, 40% by weight of diethylene glycol as a drying inhibitor, and 50% by weight of water was mounted on a pulse jet type ink jet printer, and 8 dots / mm.
Was continuously printed on the pretreated fabric.
【００２２】次に、このようにして得た捺染織物を、２
１０℃にて６０秒間熱処理し、ハイドロサルファイト２
ｇ／ｌ，ソーダ灰２ｇ／ｌの水溶液にて９０℃で５分還
元洗浄をし、しかる後洗浄，乾燥を行ない実施例１の製
品を得た。Next, the printing fabric thus obtained is
Heat treated at 10 ° C for 60 seconds, and hydrosulfite 2
The product of Example 1 was obtained by reducing and washing with an aqueous solution of g / l and 2 g / l of soda ash at 90 ° C. for 5 minutes, followed by washing and drying.
【００２３】比較例１ 実施例１において分散染料を９０重量％，分散剤として
リグニンスルホン酸を１０重量％を配合した以外は、実
施例１と同様の処理を行ない、比較例１の製品を得た。Comparative Example 1 A product of Comparative Example 1 was obtained by carrying out the same treatment as in Example 1 except that 90% by weight of the disperse dye and 10% by weight of ligninsulfonic acid were added as the dispersant. It was
【００２４】比較例２ 実施例１において分散染料の微粒子化物１０重量％，水
９０重量％を配合してインクとした以外は、実施例１と
同様の処理を行ない、比較例２の製品を得た。Comparative Example 2 A product of Comparative Example 2 was obtained by carrying out the same treatment as in Example 1 except that 10% by weight of fine particles of the disperse dye and 90% by weight of water were mixed to prepare an ink. It was
【００２５】比較例３ 実施例１において微粒子化及びロ過を行なわなかった以
外は、実施例１と同様の処理を行ない、比較例３の製品
を得た。Comparative Example 3 A product of Comparative Example 3 was obtained by performing the same treatment as in Example 1 except that the atomization and filtration were not performed in Example 1.
【００２６】実施例１及び比較例１〜３のインクを用い
てインクジェット捺染した時のノズルが目詰まりするま
での時間を測定した。また実施例１及び比較例１〜３で
得た製品の最大吸収波長におけるＫ／Ｓ値を測定した。
インク組成とその結果を表１，表２に示す。The time until the nozzle was clogged when ink-jet printing was performed using the inks of Example 1 and Comparative Examples 1 to 3 was measured. The K / S value at the maximum absorption wavelength of the products obtained in Example 1 and Comparative Examples 1 to 3 was measured.
The ink compositions and the results are shown in Tables 1 and 2.
【００２７】[0027]
【表１】 [Table 1]
【００２８】[0028]
【表２】 [Table 2]
【００２９】表１，表２から明らかなように、実施例１
のインクを用いてインクジェット捺染を行なった時にノ
ズルの目詰まりはなく、実施例１のインクは良好な吐出
性を示すことがわかる。また、実施例１で得られた製品
は高濃度の捺染布帛であることがわかる。As is clear from Table 1 and Table 2, Example 1
It can be seen that when ink-jet printing is performed using the ink of No. 1, the nozzle is not clogged, and the ink of Example 1 exhibits good ejection properties. Further, it can be seen that the product obtained in Example 1 is a high density textile printing fabric.
【００３０】[0030]
【発明の効果】以上詳述したように、本発明のインクジ
ェット捺染用インクを用いると、分散染料の特性を生か
した色を高濃度に得ることができ、ファッションの多様
化に対応できる捺染が可能であり、非常に有用である。
また長時間にわたって目詰まり等を生ずる事がなく、生
産性の向上，品質の向上という効果を奏する。As described in detail above, when the ink for ink-jet printing of the present invention is used, it is possible to obtain a high density of color by making use of the characteristics of the disperse dye, and it is possible to print in response to diversification of fashion. And is very useful.
In addition, clogging or the like does not occur for a long time, and the effect of improving productivity and quality is achieved.
Claims (1)
剤，乾燥防止剤及び水から成り、上記分散染料が粒径
０．１〜５μｍで分散されており、かつ上記分散剤が分
散染料に対して５０〜１５０重量％含有されていると共
に、上記乾燥防止剤がインク全体に対して２０〜７０重
量％含有されていることを特徴とするインクジェット捺
染用インク。1. A disperse dye which is insoluble or sparingly soluble in water, a dispersant, an anti-drying agent and water, wherein the disperse dye is dispersed in a particle size of 0.1 to 5 μm, and the dispersant is a disperse dye. In addition to 50 to 150% by weight, the anti-drying agent is contained in an amount of 20 to 70% by weight based on the total weight of the ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8806992A JPH05255626A (en) | 1992-03-11 | 1992-03-11 | Ink for ink jet printing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8806992A JPH05255626A (en) | 1992-03-11 | 1992-03-11 | Ink for ink jet printing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH05255626A true JPH05255626A (en) | 1993-10-05 |
Family
ID=13932568
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8806992A Pending JPH05255626A (en) | 1992-03-11 | 1992-03-11 | Ink for ink jet printing |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH05255626A (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07207205A (en) * | 1993-11-30 | 1995-08-08 | Seiren Co Ltd | Ink for ink jet dyeing |
| EP0778798A1 (en) * | 1994-09-01 | 1997-06-18 | Sawgrass Systems, Inc. | Permanent heat activated transfer printing process and composition |
| WO1997046623A1 (en) * | 1996-06-05 | 1997-12-11 | Basf Aktiengesellschaft | Dye preparations |
| WO1998024850A1 (en) * | 1996-12-02 | 1998-06-11 | Basf Aktiengesellschaft | Dye preparations containing methine dyes |
| US5782965A (en) * | 1993-11-30 | 1998-07-21 | Seiren Co., Ltd. | Ink for ink-jet dyeing and method of forming mixing color |
| WO1998042787A1 (en) * | 1997-03-25 | 1998-10-01 | Seiko Epson Corporation | Inks for ink-jet recording |
| WO1999028397A1 (en) * | 1997-11-26 | 1999-06-10 | Basf Aktiengesellschaft | Colorant preparations |
| EP0924335A1 (en) * | 1997-12-17 | 1999-06-23 | Ciba SC Holding AG | Process for printing textile fibres materials according to the ink-jet printing process |
| WO2002018504A3 (en) * | 2000-08-31 | 2002-05-23 | Basf Ag | Aqueous dye preparation for ink jet printing |
| WO2004033560A1 (en) * | 2002-10-04 | 2004-04-22 | Basf Aktiengesellschaft | Dyestuff preparations |
| JP2005089498A (en) * | 2003-09-12 | 2005-04-07 | Konica Minolta Holdings Inc | Inkjet printing ink and inkjet recording method |
| USRE38952E1 (en) | 1994-03-08 | 2006-01-31 | Hale Nathan S | Heat activated ink jet ink |
| US7265164B2 (en) | 1998-02-23 | 2007-09-04 | Seiko Epson Corporation | Ink composition containing cationic water-soluble polymer |
| EP2837665B1 (en) | 2009-07-10 | 2017-01-25 | Sawgrass Technologies, Inc. | High viscosity heat sensitive ink |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60133076A (en) * | 1983-12-21 | 1985-07-16 | Mitsubishi Chem Ind Ltd | Ink for ink jet printing |
| JPS61118474A (en) * | 1984-11-14 | 1986-06-05 | Canon Inc | Ink composition for ink jet recording |
| JPS63159484A (en) * | 1986-12-23 | 1988-07-02 | Mitsubishi Kasei Corp | Production of ink for ink jet textile printing |
| JPH02189373A (en) * | 1989-01-19 | 1990-07-25 | Seiren Co Ltd | Jet printing ink composition for dyeing cloth |
-
1992
- 1992-03-11 JP JP8806992A patent/JPH05255626A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60133076A (en) * | 1983-12-21 | 1985-07-16 | Mitsubishi Chem Ind Ltd | Ink for ink jet printing |
| JPS61118474A (en) * | 1984-11-14 | 1986-06-05 | Canon Inc | Ink composition for ink jet recording |
| JPS63159484A (en) * | 1986-12-23 | 1988-07-02 | Mitsubishi Kasei Corp | Production of ink for ink jet textile printing |
| JPH02189373A (en) * | 1989-01-19 | 1990-07-25 | Seiren Co Ltd | Jet printing ink composition for dyeing cloth |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5782965A (en) * | 1993-11-30 | 1998-07-21 | Seiren Co., Ltd. | Ink for ink-jet dyeing and method of forming mixing color |
| JPH07207205A (en) * | 1993-11-30 | 1995-08-08 | Seiren Co Ltd | Ink for ink jet dyeing |
| USRE38952E1 (en) | 1994-03-08 | 2006-01-31 | Hale Nathan S | Heat activated ink jet ink |
| EP0778798A1 (en) * | 1994-09-01 | 1997-06-18 | Sawgrass Systems, Inc. | Permanent heat activated transfer printing process and composition |
| EP0778798B1 (en) * | 1994-09-01 | 2001-12-05 | Sawgrass Systems, Inc. | Permanent heat activated transfer printing process and composition |
| US6117224A (en) * | 1996-06-05 | 2000-09-12 | Basf Aktiengesellschaft | Dye preparations |
| WO1997046623A1 (en) * | 1996-06-05 | 1997-12-11 | Basf Aktiengesellschaft | Dye preparations |
| WO1998024850A1 (en) * | 1996-12-02 | 1998-06-11 | Basf Aktiengesellschaft | Dye preparations containing methine dyes |
| WO1998042787A1 (en) * | 1997-03-25 | 1998-10-01 | Seiko Epson Corporation | Inks for ink-jet recording |
| US6100315A (en) * | 1997-03-25 | 2000-08-08 | Seiko Epson Corporation | Ink for ink jet recording |
| WO1999028397A1 (en) * | 1997-11-26 | 1999-06-10 | Basf Aktiengesellschaft | Colorant preparations |
| SG79243A1 (en) * | 1997-12-17 | 2001-03-20 | Ciba Sc Holding Ag | Process for ink-jet printing textile fibre materials |
| EP0924335A1 (en) * | 1997-12-17 | 1999-06-23 | Ciba SC Holding AG | Process for printing textile fibres materials according to the ink-jet printing process |
| KR100562793B1 (en) * | 1997-12-17 | 2007-04-25 | 시바 스페셜티 케미칼스 홀딩 인크. | Ink-jet printing method of textile fiber material |
| US7265164B2 (en) | 1998-02-23 | 2007-09-04 | Seiko Epson Corporation | Ink composition containing cationic water-soluble polymer |
| WO2002018504A3 (en) * | 2000-08-31 | 2002-05-23 | Basf Ag | Aqueous dye preparation for ink jet printing |
| WO2004033560A1 (en) * | 2002-10-04 | 2004-04-22 | Basf Aktiengesellschaft | Dyestuff preparations |
| CN100352864C (en) * | 2002-10-04 | 2007-12-05 | 巴斯福股份公司 | Dyestuff preparations |
| JP2005089498A (en) * | 2003-09-12 | 2005-04-07 | Konica Minolta Holdings Inc | Inkjet printing ink and inkjet recording method |
| EP2837665B1 (en) | 2009-07-10 | 2017-01-25 | Sawgrass Technologies, Inc. | High viscosity heat sensitive ink |
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