JPH05194110A - Repellent-containing body - Google Patents
Repellent-containing bodyInfo
- Publication number
- JPH05194110A JPH05194110A JP926292A JP926292A JPH05194110A JP H05194110 A JPH05194110 A JP H05194110A JP 926292 A JP926292 A JP 926292A JP 926292 A JP926292 A JP 926292A JP H05194110 A JPH05194110 A JP H05194110A
- Authority
- JP
- Japan
- Prior art keywords
- repellent
- carrier
- layer
- polyester
- containing body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000002940 repellent Effects 0.000 title claims abstract description 32
- 239000005871 repellent Substances 0.000 title claims abstract description 32
- 239000000077 insect repellent Substances 0.000 claims abstract description 25
- 229920000728 polyester Polymers 0.000 claims abstract description 22
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229920000298 Cellophane Polymers 0.000 claims abstract description 10
- 239000005022 packaging material Substances 0.000 claims description 18
- 239000004677 Nylon Substances 0.000 claims description 6
- 229920001778 nylon Polymers 0.000 claims description 6
- 239000000470 constituent Substances 0.000 claims description 5
- 238000004806 packaging method and process Methods 0.000 claims description 5
- WGRPQCFFBRDZFV-UHFFFAOYSA-N 3-methylbenzamide Chemical compound CC1=CC=CC(C(N)=O)=C1 WGRPQCFFBRDZFV-UHFFFAOYSA-N 0.000 claims 1
- MMOXZBCLCQITDF-UHFFFAOYSA-N N,N-diethyl-m-toluamide Chemical compound CCN(CC)C(=O)C1=CC=CC(C)=C1 MMOXZBCLCQITDF-UHFFFAOYSA-N 0.000 abstract description 16
- 239000011230 binding agent Substances 0.000 abstract description 3
- 239000003094 microcapsule Substances 0.000 abstract description 2
- 238000007598 dipping method Methods 0.000 abstract 1
- 239000002648 laminated material Substances 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 31
- -1 2-butenylene Chemical group 0.000 description 21
- 238000000034 method Methods 0.000 description 15
- 239000004698 Polyethylene Substances 0.000 description 13
- 229920000573 polyethylene Polymers 0.000 description 13
- 229960001673 diethyltoluamide Drugs 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 239000004744 fabric Substances 0.000 description 9
- 239000004952 Polyamide Substances 0.000 description 7
- 229920002647 polyamide Polymers 0.000 description 7
- 238000003860 storage Methods 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- 241000255925 Diptera Species 0.000 description 6
- 241000607479 Yersinia pestis Species 0.000 description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 description 6
- 239000005020 polyethylene terephthalate Substances 0.000 description 6
- 239000002952 polymeric resin Substances 0.000 description 6
- 229920003002 synthetic resin Polymers 0.000 description 6
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229940079593 drug Drugs 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920005594 polymer fiber Polymers 0.000 description 4
- RWLALWYNXFYRGW-UHFFFAOYSA-N 2-Ethyl-1,3-hexanediol Chemical compound CCCC(O)C(CC)CO RWLALWYNXFYRGW-UHFFFAOYSA-N 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 241001674044 Blattodea Species 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- 241000257303 Hymenoptera Species 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 2
- 229960001826 dimethylphthalate Drugs 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- UXDAWVUDZLBBAM-UHFFFAOYSA-N n,n-diethylbenzeneacetamide Chemical compound CCN(CC)C(=O)CC1=CC=CC=C1 UXDAWVUDZLBBAM-UHFFFAOYSA-N 0.000 description 2
- 244000052769 pathogen Species 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000005033 polyvinylidene chloride Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 1
- OBDKTQFLFFCZBN-UHFFFAOYSA-N 1-(cyclohepten-1-yl)-2-octylcycloheptene Chemical compound C1CCCCC(CCCCCCCC)=C1C1=CCCCCC1 OBDKTQFLFFCZBN-UHFFFAOYSA-N 0.000 description 1
- NZVZVGPYTICZBZ-UHFFFAOYSA-N 1-benzylpiperidine Chemical compound C=1C=CC=CC=1CN1CCCCC1 NZVZVGPYTICZBZ-UHFFFAOYSA-N 0.000 description 1
- FWKYRPILDKFAHM-UHFFFAOYSA-N 2-chloro-3,4-dimethylbenzamide Chemical compound CC1=CC=C(C(N)=O)C(Cl)=C1C FWKYRPILDKFAHM-UHFFFAOYSA-N 0.000 description 1
- MZJHBUKIOBJCAW-UHFFFAOYSA-N 2-chloro-n,n-diethylbenzamide Chemical compound CCN(CC)C(=O)C1=CC=CC=C1Cl MZJHBUKIOBJCAW-UHFFFAOYSA-N 0.000 description 1
- AAIBYZBZXNWTPP-UHFFFAOYSA-N 2-phenylcyclohexan-1-ol Chemical compound OC1CCCCC1C1=CC=CC=C1 AAIBYZBZXNWTPP-UHFFFAOYSA-N 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- 241000209495 Acorus Species 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- OKIJSNGRQAOIGZ-UHFFFAOYSA-N Butopyronoxyl Chemical compound CCCCOC(=O)C1=CC(=O)CC(C)(C)O1 OKIJSNGRQAOIGZ-UHFFFAOYSA-N 0.000 description 1
- MDJQQKAZQNDZQE-UHFFFAOYSA-N C(C)(=O)N.C(CC(C)C)C(CO)O Chemical compound C(C)(=O)N.C(CC(C)C)C(CO)O MDJQQKAZQNDZQE-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 241000238366 Cephalopoda Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- YUXIBTJKHLUKBD-UHFFFAOYSA-N Dibutyl succinate Chemical compound CCCCOC(=O)CCC(=O)OCCCC YUXIBTJKHLUKBD-UHFFFAOYSA-N 0.000 description 1
- 235000010254 Jasminum officinale Nutrition 0.000 description 1
- 240000005385 Jasminum sambac Species 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 241000606651 Rickettsiales Species 0.000 description 1
- 241000258242 Siphonaptera Species 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229960002903 benzyl benzoate Drugs 0.000 description 1
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 235000000484 citronellol Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 229960002097 dibutylsuccinate Drugs 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229960004118 dimethylcarbate Drugs 0.000 description 1
- VGQLNJWOULYVFV-SPJNRGJMSA-N dimethylcarbate Chemical compound C1[C@H]2C=C[C@@H]1[C@H](C(=O)OC)[C@@H]2C(=O)OC VGQLNJWOULYVFV-SPJNRGJMSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000008029 eradication Effects 0.000 description 1
- 239000010647 garlic oil Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 230000003100 immobilizing effect Effects 0.000 description 1
- LVPMIMZXDYBCDF-UHFFFAOYSA-N isocinchomeronic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)N=C1 LVPMIMZXDYBCDF-UHFFFAOYSA-N 0.000 description 1
- 230000005722 itchiness Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- ZWDZJRRQSXLOQR-UHFFFAOYSA-N n-butyl-n-phenylacetamide Chemical compound CCCCN(C(C)=O)C1=CC=CC=C1 ZWDZJRRQSXLOQR-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- BBNYLDSWVXSNOQ-UHFFFAOYSA-N oxolane-2-carbaldehyde Chemical compound O=CC1CCCO1 BBNYLDSWVXSNOQ-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- UZCDZCKZKAMXMC-UHFFFAOYSA-N propyl 4-(diethylamino)-4-oxobutanoate Chemical compound CCCOC(=O)CCC(=O)N(CC)CC UZCDZCKZKAMXMC-UHFFFAOYSA-N 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 206010039766 scrub typhus Diseases 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、忌避剤含有体に関す
る。更に詳細には、含有せしめられた揮発性防虫剤を長
期間安定して保持することのできる忌避剤含有体に関す
る。TECHNICAL FIELD The present invention relates to a repellent-containing body. More specifically, the present invention relates to a repellent-containing body capable of stably holding the volatile insect repellent contained therein for a long period of time.
【０００２】[0002]
【従来技術と発明が解決しようとする課題】人間の生活
環境において有害とみなされる、いわゆる有害昆虫（害
虫）として、蚊、ハエ、ゴキブリ、ノミ、ダニ、蟻、ハ
チ、ブユ、ツツガムシ幼虫等が挙げられ、文明が発達し
た現在でもその根絶は非常に困難と思われる。これらの
害虫は刺咬によって、カユミ、疼痛等の不快な症状を惹
起するのみでなく、ウイルス、リケッチア等の病原体を
媒介し、生命に重篤な影響を与えるものが多い。BACKGROUND OF THE INVENTION Mosquitoes, flies, cockroaches, fleas, mites, ants, bees, gnats, and tsutsugamushi larvae are so-called harmful insects (pests) that are considered harmful in the human living environment. The eradication of civilization seems to be extremely difficult even today. Many of these pests not only cause unpleasant symptoms such as itchiness and pain due to bites, but also mediate pathogens such as viruses and rickettsias and seriously affect their lives.
【０００３】また、刺咬しない害虫であるハエ、ゴキブ
リ等も病原体を媒介し、衛生環境上に好ましくない影響
を与えてきている。これ等害虫の駆除は、上下水道の整
備、排水溝の整備、発生源となるゴミ処理の整備等の社
会環境の整備／及び害虫駆除に有効な薬剤の利用にとも
なって、大きな進歩を遂げてきた。しかしながらその反
面で冷暖房の完備、住宅構造の気密化等により、害虫に
とっても生育に好適な環境が現出され、従来は特定な季
節のみ発生し生育していたものが年間を通じて生育する
ようになった。また、駆除に有効であった薬剤が、一方
で環境汚染の問題となり、使用が制限されるようになっ
てきた。そのため、害虫駆除／忌避効果に優れ、かつ環
境汚染やヒト・動物への副作用の問題が少ない日常生活
に使用されても安全な忌避剤として、例えばＮ，Ｎ―ジ
エチル―ｍ―トルアミド、フタル酸ジメチル、２―エチ
ル―１，３―ヘキサンジオール等の種々の揮発性防虫剤
が軟膏、クリーム、スプレー、加熱気化等の方法で従来
から使用されてきた。[0003] In addition, harmful insects such as flies and cockroaches that do not bite also transmit pathogens and have an unfavorable effect on the sanitary environment. The control of these pests has made great progress with the improvement of the social environment such as the maintenance of water and sewage systems, the maintenance of drainage channels, the maintenance of waste disposal as the source, and the use of effective chemicals for the control of pests. It was On the other hand, however, due to the complete air-conditioning and air-tightness of the housing structure, an environment suitable for growth of pests has emerged, and what had previously been generated only during a specific season grows throughout the year. It was On the other hand, drugs that have been effective for extermination have become a problem of environmental pollution, and their use has come to be restricted. Therefore, N, N-diethyl-m-toluamide, phthalic acid, which is a safe repellent that has excellent pest control / repellency effects and is safe to use in daily life with little problem of environmental pollution and side effects on humans / animals. Various volatile insect repellents such as dimethyl, 2-ethyl-1,3-hexanediol have been conventionally used by methods such as ointments, creams, sprays, and heat vaporization.
【０００４】しかしながら、これら揮発性薬剤の作用効
果の持続時間が一般的に数時間から十数時間であること
からも明らかなように、これらの揮発性薬剤を通常の開
放状態で長期間保存する場合には、徐々に薬剤が放散し
て使用時には所望の駆除／忌避効果が得られなくなると
いう問題がある。However, as is clear from the fact that the duration of action and effect of these volatile drugs is generally several hours to ten and several hours, these volatile drugs are stored for a long period of time in a normally open state. In this case, there is a problem that the drug gradually diffuses and the desired exterminating / repelling effect cannot be obtained at the time of use.
【０００５】すなわち、本発明の目的は、忌避剤を長期
間に亘って安定して保存すること、特に消費者が使用す
る前の段階、すなわち、流通在庫期間中の保存安定性を
向上せしめた忌避剤含有体を提供することにある。That is, an object of the present invention is to stably store the repellent for a long period of time, and particularly to improve the storage stability before the consumer uses it, that is, during the distribution inventory period. To provide a repellent-containing body.
【０００６】[0006]
【課題を解決するための具体的手段】すなわち本発明
は、揮発性防虫剤を含有せしめた担体と、該担体を包装
する、構成層の少なくとも一部分にアルミニウム層、ポ
リエステル層、及び／又はセロファン層を含む包装材と
からなる忌避剤含有体である。Specifically, the present invention provides a carrier containing a volatile insect repellent, and an aluminum layer, a polyester layer, and / or a cellophane layer for packaging the carrier, the aluminum layer being at least a part of the constituent layers. A repellent-containing body comprising a packaging material containing.
【０００７】本発明の揮発性防虫剤とは、例えばＮ，Ｎ
―ジエチル―ｍ―トルアミド、フタル酸ジメチル、２―
エチル―１，３―ヘキサンジオール、Ｎ，Ｎ―ジエチル
フェニルアセトアミド、フタル酸ジブチル、ブチル―
３，４―ジヒドロ―２，２―ジメチル―４―オキソ―２
―Ｈ―ピラン―６―カルボキシレイト、ブトキシポリプ
ロピレングリコール、２―フェニルシクロヘキサノー
ル、ブチル―３―メチシンコニネイト、ジメチルカーベ
イト、ジブチルサクシネイト、ベンジルベンゾエイト、
ブチルアセトアニリド、イソアミル―エチレングリコー
ルアセトアミド、シクロヘキサン―アルカノイック―カ
ルボキシアミド、ベメチルベンズアミド、ジメチルアセ
トアミド、ジメチル―２―クロロベンズアミド、ｎ―プ
ロピル―Ｎ，Ｎ―ジエチル―サクシナメイト、２―クロ
ロ―Ｎ，Ｎ―ジエチルベンズアミド、Ｎ―ベンジルピペ
リジン、ピレスロイド、シネリン、ジャスミン、シトロ
ネロール、アコラスオイル、テフロシア抽出物、ガーリ
ックオイル、オレンジ果皮抽出物、Ｎ―オクチル―ビシ
クロヘプテン・ジカルボキシイミド、イソシンコメロン
酸ジノルマルプロピル、２，３，４，５ビス（２―ブテ
ニレン）テトラヒドロフルフラール等をいう。The volatile insect repellent of the present invention is, for example, N, N
-Diethyl-m-toluamide, dimethyl phthalate, 2-
Ethyl-1,3-hexanediol, N, N-diethylphenylacetamide, dibutyl phthalate, butyl-
3,4-dihydro-2,2-dimethyl-4-oxo-2
-H-pyran-6-carboxylate, butoxy polypropylene glycol, 2-phenylcyclohexanol, butyl-3-methicine conineate, dimethyl carbate, dibutyl succinate, benzyl benzoate,
Butyl acetanilide, isoamyl-ethylene glycol acetamide, cyclohexane-alkanoic-carboxamide, bemethylbenzamide, dimethylacetamide, dimethyl-2-chlorobenzamide, n-propyl-N, N-diethyl-succinamate, 2-chloro-N, N- Diethylbenzamide, N-benzylpiperidine, pyrethroid, cinerine, jasmine, citronellol, acorus oil, tefrussia extract, garlic oil, orange peel extract, N-octyl-bicycloheptene dicarboximide, isocinchomeronate dinormalpropyl, 2, It means 3,4,5 bis (2-butenylene) tetrahydrofurfural and the like.
【０００８】本発明の揮発性防虫剤としては、これらの
なかでもＮ，Ｎ―ジエチル―ｍ―トルアミド、フタル酸
ジメチル、２―エチル―１，３―ヘキサンジオール、
Ｎ，Ｎ―ジエチルフェニルアセトアミドが好ましく、な
かでもＮ，Ｎ―ジエチル―ｍ―トルアミドが特に好まし
い。Among the volatile insect repellents of the present invention, among these, N, N-diethyl-m-toluamide, dimethyl phthalate, 2-ethyl-1,3-hexanediol,
N, N-diethylphenylacetamide is preferable, and N, N-diethyl-m-toluamide is particularly preferable.
【０００９】本発明の担体としては、高分子樹脂からな
る担体、繊維状担体等があげられる。高分子樹脂からな
る担体としては、例えばポリ塩化ビニル、ポリエチレ
ン、ポリエチレンテレフタレート、ポリプロピレン、ポ
リアミド、ポリ塩化ビニリデン、ポリウレタン等が挙げ
られる。また繊維状担体としては、例えばポリエステ
ル、ナイロン、アクリル等の合成繊維からなる布帛、織
物、編物等が挙げられる。これらのなかでも本発明の担
体としては繊維状担体が好ましく、なかでも特に繊維の
種類としてはポリエステル、ナイロン、形状としては織
物、編物が好ましい。具体的にはパンティストッキン
グ、靴下、織編物生地、衣服等が挙げられる。Examples of the carrier of the present invention include a carrier made of a polymer resin and a fibrous carrier. Examples of the carrier made of a polymer resin include polyvinyl chloride, polyethylene, polyethylene terephthalate, polypropylene, polyamide, polyvinylidene chloride, polyurethane and the like. Examples of the fibrous carrier include cloth, woven fabric, and knitted fabric made of synthetic fibers such as polyester, nylon, and acrylic. Of these, fibrous carriers are preferable as the carrier of the present invention, and among these, polyester and nylon are particularly preferable as the type of fiber, and woven and knitted are preferable as the shape. Specific examples include pantyhose, socks, woven and knitted cloth, clothes and the like.
【００１０】ここで、ポリエステルとしては、例えばポ
リエチレンテレフタレート等を、ナイロンとしては、例
えばナイロン６、ナイロン６６等のポリアミド等を、ア
クリルとしては、例えばアクリル酸エステル、アクリロ
ニトリル、アクリルアミド等からなるポリアクリロニト
リル等をいうが、これら合成繊維に限らず、木綿、麻、
絹等の天然繊維も本発明の繊維状担体に含まれる。Here, as the polyester, for example, polyethylene terephthalate or the like is used, as the nylon, for example, polyamides such as nylon 6, nylon 66 or the like is used, and as the acryl, polyacrylonitrile or the like made of acrylic acid ester, acrylonitrile, acrylamide or the like is used. , But not limited to these synthetic fibers, cotton, hemp,
Natural fibers such as silk are also included in the fibrous carrier of the present invention.
【００１１】かかる担体に揮発性防虫剤を含有させる方
法としては、高分子樹脂や繊維自体に防虫剤を混練する
方法、あるいは防虫剤を含有する溶液中に高分子樹脂や
繊維を含浸させる方法、防虫剤をその蒸気雰囲気中で高
分子樹脂や繊維に含浸させる方法、防虫剤を適当な剤皮
で包んでマイクロカプセル化した後に、適当なバインダ
ーで高分子樹脂や繊維に固着させる方法等がある。本発
明においては、以上の方法に加えて従来防虫剤等を担体
に含有せしめるのに用いられている公知の方法を用いる
ことができ、用いる防虫剤、担体の種類に応じた方法を
用いることができる。As a method of incorporating a volatile insect repellent into such a carrier, a method of kneading the polymer resin or fiber itself with the insect repellent, or a method of impregnating the polymer resin or fiber in a solution containing the repellent, There is a method of impregnating a polymer resin or fiber in the vapor atmosphere with the insect repellent, a method of encapsulating the insect repellent in a suitable coating and microencapsulating it, and then fixing it to the polymer resin or fiber with a suitable binder. .. In the present invention, in addition to the above methods, it is possible to use a known method conventionally used for incorporating an insect repellent or the like into a carrier, and an insect repellent to be used or a method depending on the type of the carrier may be used. it can.
【００１２】なかでも、防虫剤を適当な皮膜で被覆した
マイクロカプセルを適当なバインダーで固定化する方法
が、揮発性防虫剤を含有する担体の表面上に防虫剤を十
分な忌避効果を発現するために必要とされる有効濃度を
保持することが可能となるので好ましい。Among them, the method of immobilizing microcapsules coated with a suitable film of an insect repellent with a suitable binder exhibits a sufficient repellent effect of the insect repellent on the surface of a carrier containing a volatile insect repellent. Therefore, it is possible to maintain the effective concentration required, which is preferable.
【００１３】揮発性防虫剤の量としては、例えばＮ，Ｎ
―ジエチル―ｍ―トルアミドの場合には処理担体表面上
に０．１mg／ｇ以上存在することが望ましく、最適量は
０．２〜１．０mg／ｇである。The amount of volatile insect repellent is, for example, N, N
In the case of -diethyl-m-toluamide, it is desirable that 0.1 mg / g or more is present on the surface of the treated carrier, and the optimum amount is 0.2 to 1.0 mg / g.
【００１４】本発明の包装材は、上述のようにして得ら
れた担体を包装する、構成層の少なくとも一部分にアル
ミニウム層、ポリエステル層、及び／又はセロファン層
を含むものをいう。かかる包装材を構成する他の層とし
ては、例えばポリエチレン層、ポリプロピレン層、ポリ
ウレタン層、ポリ塩化ビニリデン層などが挙げられる
が、なかでもポリエチレン層が好ましい。本発明におい
てその構成層の少なくとも一部分にアルミニウム層等を
含むとは、包装材の一部分ではなく、その全体を構成す
る層の少なくとも一つの層としてアルミニウム層等が存
在せしめられていることをいい、場合によっては単独で
構成することもできる。例えばアルミニウム層を含む包
装材としては、ポリエチレンシート―酸化アルミニウム
―ポリエチレンシートの３層から構成されるものが、ま
た、ポリエステル層を含む包装材としては、ポリエステ
ルシート―ポリエチレンシートの２層から構成されるも
のが、セロファン層を含む包装材としては、セロファン
シート―ポリエチレンシートの２層から構成されるもの
等、２層、あるいは３層以上の複層、さらにサンドイッ
チ状等の層により構成されるものを例示することができ
る。The packaging material of the present invention is a packaging material for packaging the carrier obtained as described above, which contains an aluminum layer, a polyester layer, and / or a cellophane layer in at least a part of its constituent layers. Examples of other layers constituting such a packaging material include a polyethylene layer, a polypropylene layer, a polyurethane layer, a polyvinylidene chloride layer, and the like. Among them, the polyethylene layer is preferable. In the present invention to include an aluminum layer or the like in at least a part of its constituent layers means that an aluminum layer or the like is present as at least one layer of the layers constituting the whole, not a part of the packaging material, In some cases, it may be configured alone. For example, a packaging material containing an aluminum layer is composed of three layers of polyethylene sheet-aluminum oxide-polyethylene sheet, and a packaging material containing a polyester layer is composed of two layers of polyester sheet-polyethylene sheet. However, the packaging material containing the cellophane layer is composed of two layers of cellophane sheet-polyethylene sheet, etc., or is composed of two layers, or three or more layers of layers, and sandwich-like layers. Can be illustrated.
【００１５】かかるアルミニウム層等の厚みは特に制限
はないが、揮発性防虫剤の放散を防止して長期間に亘っ
て防虫剤を安定に保存せしめる本発明の目的から及び製
造上や保存時の取扱性の点から、アルミニウム層の場合
には約５〜２０μｍの厚みが好ましく、なかでも約７〜
１５μｍの厚みであることが好ましい。また、ポリエス
テル層の場合には、約５〜２０μｍの厚みが好ましく、
なかでも約１０〜１５μｍの厚みが好ましく、セロファ
ン層の場合には、約１０〜６０μｍの厚みが好ましく、
なかでも２０〜４０μｍの厚みが好ましい。さらに、包
装材を構成する他の層の厚みとしては、例えばポリエチ
レン層の場合には、約２０〜４０μｍの厚みが好ましい
ものとして挙げられる。The thickness of the aluminum layer or the like is not particularly limited, but for the purpose of the present invention to prevent the emission of the volatile insect repellent and to keep the repellent stable for a long period of time, and during production and storage. From the viewpoint of handleability, the thickness of the aluminum layer is preferably about 5 to 20 μm, and particularly about 7 to 20 μm.
The thickness is preferably 15 μm. Further, in the case of the polyester layer, a thickness of about 5 to 20 μm is preferable,
Above all, a thickness of about 10 to 15 μm is preferable, and in the case of a cellophane layer, a thickness of about 10 to 60 μm is preferable,
Above all, a thickness of 20 to 40 μm is preferable. Further, as the thickness of the other layers constituting the packaging material, for example, in the case of a polyethylene layer, a preferable thickness is about 20 to 40 μm.
【００１６】ここで、ポリエステル層のポリエステルと
しては、例えばポリエチレンテレフタレート等が挙げら
れる。Here, examples of the polyester of the polyester layer include polyethylene terephthalate.
【００１７】本発明においては、前述の揮発性防虫剤を
含有する担体を上述の包装材で包装して、本発明の忌避
剤含有体を得る。本発明においてかかる包装とは、担体
に含有せしめられた揮発性防虫剤が、長期間の保存によ
って外部に放散しないような包装をいい、用いられる包
装材の種類に応じて例えば被包装物の大きさに応じた袋
状の包装材をヒートシーラー等の加熱圧着法で溶融接着
する等の方法によるものを挙げることができる。In the present invention, the carrier containing the above-mentioned volatile insect repellent is wrapped with the above-mentioned packaging material to obtain the repellent-containing body of the present invention. In the present invention, such a packaging means a packaging in which the volatile insect repellent contained in the carrier does not release to the outside by long-term storage, and, for example, the size of the packaged material depends on the type of packaging material used. Examples of the method include a method of melt-bonding a bag-shaped packaging material corresponding to the size by a heat compression method such as a heat sealer.
【００１８】かかる際に、揮発性防虫剤を含有する担体
以外に、酸素吸収剤、水分吸収剤等を同時に存在せしめ
ることができる。At this time, in addition to the carrier containing the volatile insect repellent, an oxygen absorbent, a water absorbent and the like can be simultaneously present.
【００１９】かくして本発明の忌避剤含有体を得ること
ができる。Thus, the repellent-containing body of the present invention can be obtained.
【００２０】[0020]
【参考例１】忌避剤含有ポリエステル編物の製造 Ｎ，Ｎ―ジエチル―ｍ―トルアミド（以下ＤＥＥＴと称
する）５部にノニオン系界面活性剤（ポリオキシエチレ
ン（５〜１０７）ノニルフェニルエーテル）５部を加
え、更に水９０部を加えて加工浴とした。この加工浴２
５部に対し１部の比率でポリエステル（ポリエチレンテ
レフタレート）繊維（ウーリー１５０／４８）を浸漬
し、９０℃×１２０分間処理した。処理後の繊維中に含
有されているＤＥＥＴ量は２５mg／ｇであった。この繊
維をメリヤス編みした編物を抜毛したラット背部に固着
し、羽化後２週間のアカイエカ（雌）３００匹を入れた
ケージ（７０cm×３０cm×５０cm）に５時間放置した。
その後ラットをケージから取り出して、背部の吸血痕を
倍率２０倍の拡大鏡で観察した。別に、無処理のポリエ
ステル繊維（ウーリー１５０／４８）を用いて編物を
得、これを対照として同様にテストした。その結果、対
照（無処理繊維）に比較して処理繊維は顕著な忌避効果
を示した。[Reference Example 1] Manufacture of polyester knitted fabric containing repellent 5 parts of N, N-diethyl-m-toluamide (hereinafter referred to as DEET) and 5 parts of nonionic surfactant (polyoxyethylene (5-107) nonylphenyl ether) Was added, and 90 parts of water was further added to form a processing bath. This processing bath 2
Polyester (polyethylene terephthalate) fiber (Woolie 150/48) was immersed in a ratio of 1 part to 5 parts and treated at 90 ° C. for 120 minutes. The amount of DEET contained in the treated fiber was 25 mg / g. This fiber was fixed to the back of a rat from which a knitted knit fabric had been plucked, and left for 5 hours in a cage (70 cm × 30 cm × 50 cm) containing 300 squid (female) for 2 weeks after emergence.
After that, the rat was taken out of the cage, and the blood-sucking mark on the back was observed with a magnifying glass at a magnification of 20 times. Separately, an untreated polyester fiber (Woolie 150/48) was used to obtain a knit, which was similarly tested as a control. As a result, the treated fiber showed a remarkable repellent effect as compared with the control (untreated fiber).
【００２１】また、別にこの処理繊維をＪＩＳ Ｌ０２
１７の洗い方１０３に規定する方法で洗濯し、ＤＥＥＴ
含量を測定した。その結果、洗濯３０回後も洗濯前の含
量の８０％を保持し、充分な洗濯耐久性を示した。In addition, this treated fiber is separately specified in JIS L02.
17 Washing method specified in Washing method 103, and DEET
The content was measured. As a result, 80% of the content before washing was retained even after 30 times of washing, showing sufficient washing durability.
【００２２】[0022]
【参考例２】忌避剤含有ポリアミド編物の製造 ＤＥＥＴをメラミン系樹脂でマイクロカプセル化し、ア
クリル系高分子エマルジョン接着剤で繊維状担体として
のナイロンパンティストッキング（編物）に固着した。
この時のＤＥＥＴ含量は３０mg／ｇ編物であった。対照
としては無処理の編物を用い、参考例１と同様に蚊に対
する忌避効果をテストした結果充分な効果が得られた。
また参考例１と同様な洗濯を行った結果、洗濯５回後の
ＤＥＥＴ残存含量は２０mg／ｇ編物であった。Reference Example 2 Production of Repellent-Containing Polyamide Knitted DEET was microencapsulated with a melamine resin and fixed to a nylon pantyhose (knitted fabric) as a fibrous carrier with an acrylic polymer emulsion adhesive.
The DEET content at this time was 30 mg / g knitted fabric. As a control, an untreated knitted fabric was used, and a repellent effect against mosquitoes was tested in the same manner as in Reference Example 1, and a sufficient effect was obtained.
As a result of performing the same washing as in Reference Example 1, the residual content of DEET after 5 washings was 20 mg / g knitted fabric.
【００２３】この時の、蚊に対する忌避効果は、無処理
に比較して顕著に有効であった。At this time, the repellent effect against mosquitoes was remarkably effective as compared with the untreated case.
【００２４】[0024]
【実施例１及び２】参考例１で処理した繊維（ＤＥＥＴ
含有量２５mg／ｇポリエステル編物）及び参考例２で処
理した繊維（ＤＥＥＴ含有量３０mg／ｇナイロン編物）
をアルミ箔―ポリエチレンラミネートからなる包装材で
密封包装し、本発明の忌避剤含有包装体（実施例１，
２）を得た。具体的にはポリエチレン（１５μｍ）―酸
化アルミニウム（９μｍ）―ポリエチレン（２０μｍ）
からなるシート材をヒートシールで袋状とし、上記の処
理された繊維を袋内に密封した。Examples 1 and 2 Fibers treated in Reference Example 1 (DEET
Content 25 mg / g polyester knit) and fibers treated in Reference Example 2 (DEET content 30 mg / g nylon knit)
Is hermetically sealed with a packaging material composed of aluminum foil-polyethylene laminate, and the repellent-containing package of the present invention (Example 1,
2) was obtained. Specifically, polyethylene (15 μm) -aluminum oxide (9 μm) -polyethylene (20 μm)
The sheet material consisting of the above was heat-sealed into a bag shape, and the treated fiber was sealed in the bag.
【００２５】得られた２種の忌避剤含有体と未包装で開
放状態にある前記２種の処理繊維（比較例（ポリエステ
ル繊維）、比較例（ポリアミド繊維））とについて、保
存前及びそれぞれ８℃、室温、３７℃、６０℃で１年間
保存した時の処理繊維中ＤＥＥＴ含量を測定した。その
結果を表１及び表２に示した。With respect to the obtained two kinds of repellent-containing bodies and the above-mentioned two kinds of treated fibers (comparative example (polyester fiber) and comparative example (polyamide fiber)) which are not packaged and are in an open state, before storage and respectively 8 The DEET content in the treated fiber when stored for 1 year at 37 ° C, 60 ° C, 37 ° C, room temperature was measured. The results are shown in Tables 1 and 2.
【００２６】[0026]
【表１】 [Table 1]
【００２７】表１から、本願発明の忌避剤含有体は６０
℃、１年保存でも防虫剤が安全に保持されていることが
判る。From Table 1, the repellent-containing body of the present invention is 60
It can be seen that the insect repellent is retained safely even at 1 ° C for 1 year.
【００２８】[0028]
【表２】 [Table 2]
【００２９】表２から、本願発明の忌避剤含有体は６０
℃、１年保存でも揮発性防虫剤が安全に保持されている
ことが判る。From Table 2, the repellent-containing body of the present invention is 60
It can be seen that the volatile insect repellent is retained safely even after storage at ℃ for 1 year.
【００３０】[0030]
【実施例３〜６】実施例１及び２と同様に、参考例１で
処理した繊維及び参考例２で処理した繊維をそれぞれ、
ポリエチレンテレフタレート（厚み１２μｍ）、ポリエ
チレン（厚み４０μｍ）からなるシート材をヒートシー
ルして袋状となした包装材に密封包装し、本発明の忌避
剤含有体（実施例３―ポリエステル繊維、実施例４―ポ
リアミド繊維）を製造した。Examples 3 to 6 As in Examples 1 and 2, the fibers treated in Reference Example 1 and the fibers treated in Reference Example 2, respectively,
A sheet material made of polyethylene terephthalate (thickness 12 μm) and polyethylene (thickness 40 μm) is heat-sealed and hermetically packaged in a bag-shaped packaging material, and the repellent-containing body of the present invention (Example 3-polyester fiber, Example). 4-polyamide fiber) was produced.
【００３１】更に同様にセロファン（厚み２０μｍ）と
ポリエチレン（厚み４０μｍ）からなるシート材をヒー
トシールして袋状となした包装材に、各繊維を密封包装
して、本発明の忌避剤含有体（実施例５―ポリエステル
繊維、実施例６―ポリアミド繊維）を得た。得られた４
種類の忌避剤含有体（実施例３〜６）と未包装で開放状
態にある２種類の処理繊維（比較例（ポリエステル繊
維）、比較例（ポリアミド繊維））とについて、保存前
及びそれぞれ８℃、室温、３７℃、６０℃で１年間保存
した時の処理繊維中のＤＥＥＴ含量を測定した。その結
果を表３〜表６に示した。Similarly, a sheet material made of cellophane (thickness: 20 μm) and polyethylene (thickness: 40 μm) is heat-sealed to form a bag, and each fiber is hermetically sealed in a packaging material, and the repellent-containing body according to the present invention. (Example 5-polyester fiber, Example 6-polyamide fiber) were obtained. Obtained 4
About 8 kinds of repellent-containing bodies (Examples 3 to 6) and two types of treated fibers (comparative example (polyester fiber) and comparative example (polyamide fiber)) that are unpackaged and open before storage and at 8 ° C. The DEET content in the treated fiber when stored at room temperature, 37 ° C. and 60 ° C. for 1 year was measured. The results are shown in Tables 3 to 6.
【００３２】これらの結果に示す通り、ポリエチレンテ
レフタレート及びセロファンを構成層とする包装材はい
ずれも良好な保存安定性を示した。As shown in these results, the packaging materials containing polyethylene terephthalate and cellophane as the constituent layers exhibited good storage stability.
【００３３】[0033]
【表３】 [Table 3]
【００３４】[0034]
【表４】 [Table 4]
【００３５】[0035]
【表５】 [Table 5]
【００３６】[0036]
【表６】 [Table 6]
Claims (4)
担体を包装する、構成層の少なくとも一部分にアルミニ
ウム層、ポリエステル層、及び／又はセロファン層を含
む包装材とからなる忌避剤含有体。1. A repellent-containing body comprising a carrier containing a volatile insect repellent and a packaging material for packaging the carrier, the packaging material including an aluminum layer, a polyester layer, and / or a cellophane layer in at least a part of its constituent layers. ..
ｍ―トルアミドである請求項１記載の忌避剤含有体。2. The volatile insect repellent is N, N-diethyl-
The repellent-containing body according to claim 1, which is m-toluamide.
の忌避剤含有体。3. The repellent-containing body according to claim 1, wherein the carrier is a fibrous carrier.
イロン編物である請求項３記載の忌避剤含有体。4. The repellent-containing body according to claim 3, wherein the fibrous carrier is a polyester knit or a nylon knit.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP926292A JPH05194110A (en) | 1992-01-22 | 1992-01-22 | Repellent-containing body |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP926292A JPH05194110A (en) | 1992-01-22 | 1992-01-22 | Repellent-containing body |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH05194110A true JPH05194110A (en) | 1993-08-03 |
Family
ID=11715522
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP926292A Pending JPH05194110A (en) | 1992-01-22 | 1992-01-22 | Repellent-containing body |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH05194110A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006273742A (en) * | 2005-03-29 | 2006-10-12 | Sumitomo Chemical Co Ltd | Method of preserving insect pest controlling agent |
| JP2006327938A (en) * | 2005-05-23 | 2006-12-07 | Sumitomo Chemical Co Ltd | Method for preserving noxious insect-controlling agent |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6456548A (en) * | 1987-05-14 | 1989-03-03 | Puresuto Prod Inc | Non-oriented polyester film for sealing blank |
| JPH01156901A (en) * | 1988-11-04 | 1989-06-20 | Dainippon Jochugiku Co Ltd | Repellent for cockroach |
| JPH02142702A (en) * | 1988-08-17 | 1990-05-31 | Clive St John Rumble | Vermin-proof device |
| JPH02305637A (en) * | 1989-03-10 | 1990-12-19 | Showa Denko Kk | Laminate |
| JPH0327938A (en) * | 1988-10-14 | 1991-02-06 | Reynolds Consumer Prod Inc | Non-orientation polyester film for lid material with modified heat-seal layer |
| JPH03138145A (en) * | 1989-09-22 | 1991-06-12 | Hercules Inc | Elongated laminated film |
| JP3109830B2 (en) * | 1990-12-14 | 2000-11-20 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチェン | Riogel, its preparation and use in sealing |
-
1992
- 1992-01-22 JP JP926292A patent/JPH05194110A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6456548A (en) * | 1987-05-14 | 1989-03-03 | Puresuto Prod Inc | Non-oriented polyester film for sealing blank |
| JPH02142702A (en) * | 1988-08-17 | 1990-05-31 | Clive St John Rumble | Vermin-proof device |
| JPH0327938A (en) * | 1988-10-14 | 1991-02-06 | Reynolds Consumer Prod Inc | Non-orientation polyester film for lid material with modified heat-seal layer |
| JPH01156901A (en) * | 1988-11-04 | 1989-06-20 | Dainippon Jochugiku Co Ltd | Repellent for cockroach |
| JPH02305637A (en) * | 1989-03-10 | 1990-12-19 | Showa Denko Kk | Laminate |
| JPH03138145A (en) * | 1989-09-22 | 1991-06-12 | Hercules Inc | Elongated laminated film |
| JP3109830B2 (en) * | 1990-12-14 | 2000-11-20 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチェン | Riogel, its preparation and use in sealing |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006273742A (en) * | 2005-03-29 | 2006-10-12 | Sumitomo Chemical Co Ltd | Method of preserving insect pest controlling agent |
| JP2006327938A (en) * | 2005-05-23 | 2006-12-07 | Sumitomo Chemical Co Ltd | Method for preserving noxious insect-controlling agent |
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