JPH0513585Y2 - - Google Patents
Info
- Publication number
- JPH0513585Y2 JPH0513585Y2 JP1985098901U JP9890185U JPH0513585Y2 JP H0513585 Y2 JPH0513585 Y2 JP H0513585Y2 JP 1985098901 U JP1985098901 U JP 1985098901U JP 9890185 U JP9890185 U JP 9890185U JP H0513585 Y2 JPH0513585 Y2 JP H0513585Y2
- Authority
- JP
- Japan
- Prior art keywords
- sensitive
- heat
- transfer recording
- thermal transfer
- pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 claims description 11
- 239000001993 wax Substances 0.000 claims description 9
- 239000003086 colorant Substances 0.000 claims description 5
- 239000000976 ink Substances 0.000 description 16
- 239000000123 paper Substances 0.000 description 15
- 238000000034 method Methods 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 239000003094 microcapsule Substances 0.000 description 5
- 239000000049 pigment Substances 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- -1 malachite green lactone Chemical class 0.000 description 3
- 238000001454 recorded image Methods 0.000 description 3
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- YXVFYQXJAXKLAK-UHFFFAOYSA-N biphenyl-4-ol Chemical compound C1=CC(O)=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 229940100445 wheat starch Drugs 0.000 description 2
- LIZLYZVAYZQVPG-UHFFFAOYSA-N (3-bromo-2-fluorophenyl)methanol Chemical compound OCC1=CC=CC(Br)=C1F LIZLYZVAYZQVPG-UHFFFAOYSA-N 0.000 description 1
- HUOKHAMXPNSWBJ-UHFFFAOYSA-N 2'-chloro-6'-(diethylamino)-3'-methylspiro[2-benzofuran-3,9'-xanthene]-1-one Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC(Cl)=C(C)C=C1OC1=CC(N(CC)CC)=CC=C21 HUOKHAMXPNSWBJ-UHFFFAOYSA-N 0.000 description 1
- ZJWUEJOPKFYFQD-UHFFFAOYSA-N 2-hydroxy-3-phenylbenzoic acid Chemical compound OC(=O)C1=CC=CC(C=2C=CC=CC=2)=C1O ZJWUEJOPKFYFQD-UHFFFAOYSA-N 0.000 description 1
- DLGBEGBHXSAQOC-UHFFFAOYSA-N 2-hydroxy-5-methylbenzoic acid Chemical compound CC1=CC=C(O)C(C(O)=O)=C1 DLGBEGBHXSAQOC-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- ZDRSNHRWLQQICP-UHFFFAOYSA-N 2-tert-butyl-4-[2-(3-tert-butyl-4-hydroxyphenyl)propan-2-yl]phenol Chemical compound C1=C(O)C(C(C)(C)C)=CC(C(C)(C)C=2C=C(C(O)=CC=2)C(C)(C)C)=C1 ZDRSNHRWLQQICP-UHFFFAOYSA-N 0.000 description 1
- ZWQBZEFLFSFEOS-UHFFFAOYSA-N 3,5-ditert-butyl-2-hydroxybenzoic acid Chemical compound CC(C)(C)C1=CC(C(O)=O)=C(O)C(C(C)(C)C)=C1 ZWQBZEFLFSFEOS-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- HTVITOHKHWFJKO-UHFFFAOYSA-N Bisphenol B Chemical compound C=1C=C(O)C=CC=1C(C)(CC)C1=CC=C(O)C=C1 HTVITOHKHWFJKO-UHFFFAOYSA-N 0.000 description 1
- SDDLEVPIDBLVHC-UHFFFAOYSA-N Bisphenol Z Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCCC1 SDDLEVPIDBLVHC-UHFFFAOYSA-N 0.000 description 1
- 241000272165 Charadriidae Species 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- 238000012695 Interfacial polymerization Methods 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000004163 Spermaceti wax Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000012296 anti-solvent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000005354 coacervation Methods 0.000 description 1
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 1
- 239000011086 glassine Substances 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- HSEMFIZWXHQJAE-UHFFFAOYSA-N hexadecanamide Chemical compound CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229940107698 malachite green Drugs 0.000 description 1
- ZSYJMXLJNPEAGP-UHFFFAOYSA-N methyl n-cyanocarbamate Chemical compound COC(=O)NC#N ZSYJMXLJNPEAGP-UHFFFAOYSA-N 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- JHOKTNSTUVKGJC-UHFFFAOYSA-N n-(hydroxymethyl)octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCO JHOKTNSTUVKGJC-UHFFFAOYSA-N 0.000 description 1
- FTQWRYSLUYAIRQ-UHFFFAOYSA-N n-[(octadecanoylamino)methyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCNC(=O)CCCCCCCCCCCCCCCCC FTQWRYSLUYAIRQ-UHFFFAOYSA-N 0.000 description 1
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000019385 spermaceti wax Nutrition 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 229940037312 stearamide Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Description
【考案の詳細な説明】
本考案は熱転写記録層の上に部分的に感圧性イ
ンク層を設けた感熱熱転写記録シートに関するも
ので、感熱記録及び普通紙への熱転写記録に加え
て、感圧記録を備えた記録シートに関するもので
ある。[Detailed description of the invention] The present invention relates to a heat-sensitive thermal transfer recording sheet in which a pressure-sensitive ink layer is partially provided on a thermal transfer recording layer. The present invention relates to a recording sheet equipped with.
感熱熱転写記録シートは、一般に基材の片面に
無色の電子供与性の発色剤及び電子受容性の顕色
剤からなる発色材料に、増感剤、結合剤、その他
の添加物を加えた、いわゆる感熱記録紙と同じ感
熱記録成分を塗設し、その反対面には染顔料、ワ
ツクス類、接着剤を主成分とする着色の熱溶融性
インクを塗設し、熱溶融性インク層側と普通紙と
を重ね合わせてサーマルヘツドを用いて記録する
もので基材上の感熱記録と同時に普通紙にも記録
できるものである。該記録シートには染顔料を用
いた熱溶融性インクの代りに感熱記録成分と同じ
発色材料からなる無色の熱溶融性インクを用いた
ものがある。 Heat-sensitive thermal transfer recording sheets are generally made of a color-forming material consisting of a colorless electron-donating color-forming agent and an electron-accepting color-developing agent on one side of a base material, in addition to a sensitizer, a binder, and other additives. The same heat-sensitive recording component as that of heat-sensitive recording paper is coated, and the opposite side is coated with a colored heat-melt ink whose main components are dyes, pigments, waxes, and adhesives, and the heat-melt ink layer side and normal This is a method in which recording is performed using a thermal head by overlapping sheets of paper, and it is possible to record on plain paper at the same time as thermal recording on the base material. Some of the recording sheets use a colorless heat-melt ink made of the same coloring material as the heat-sensitive recording component instead of a heat-melt ink using dyes and pigments.
上述の感熱転写記録シートは、サーマルヘツド
を用いた１回の記録で該記録シートと普通紙に同
時に記録ができることから近年になつて多く用い
られている。 The above-mentioned thermal transfer recording sheet has been widely used in recent years because it allows simultaneous recording on the recording sheet and plain paper in one recording using a thermal head.
特に、該記録シートは、持ち運びが容易な熱記
録装置に用いられる伝票類としての用途が多い。
しかし、上述の染顔料のインクからなるタイプは
該記録シートが着色していることから外観上好ま
しくないこと、取り扱い時の圧力カブリや摩擦汚
れが生じることといつた欠点を有するため、無色
のインクのタイプが好まれるようになつてきてい
る。このように、伝票類として用いるとき、サー
マルヘツドからの記録に加えて筆圧など圧力によ
る署名ができるような感圧性を付与することも要
望されてきている。 In particular, the recording sheet is often used as slips used in thermal recording devices that are easy to carry.
However, the above-mentioned types made of dye and pigment inks have drawbacks such as the unfavorable appearance of the recording sheet due to its color, and the occurrence of pressure fog and friction stains during handling. These types are becoming more popular. As described above, when used as slips, there is a demand for pressure sensitivity so that in addition to recording from a thermal head, signatures can be made using pressure such as pen pressure.
本発明者らは、先に特願昭59−25329号で出願
している。同号では、無色の熱転写記録層に感圧
性を備えたものであるが、熱転写層自体が感圧性
をもつものであり、感圧性を必要とする部分以外
は摩擦汚れの原因となること、経済的に高価であ
ることから改善が望まれている。 The present inventors previously filed Japanese Patent Application No. 59-25329. In the same issue, the colorless thermal transfer recording layer is pressure-sensitive, but the thermal transfer layer itself is pressure-sensitive, and areas other than those that require pressure-sensitivity may cause friction stains, and there are economic concerns. Since it is expensive, improvements are desired.
本考案は、これら熱転写記録層自体の感圧性付
与による欠点を改善し、摩擦汚れのない安価な感
熱熱転写記録シートを提供するものであり、熱転
写記録層上に感圧性インク層を設けた構成を特徴
とするものである。 The present invention improves these drawbacks caused by imparting pressure sensitivity to the thermal transfer recording layer itself, and provides an inexpensive thermal transfer recording sheet that is free from friction stains. This is a characteristic feature.
図面に従つて、本考案を説明すると、第１図〜
第３図は本考案の感熱熱転写記録シートの構造の
１例を示すものである。 The present invention will be explained according to the drawings.
FIG. 3 shows an example of the structure of the thermosensitive thermal transfer recording sheet of the present invention.
第１図は感熱熱転写記録シート１の断面図であ
り、基材５の片面に感熱記録層４、その反対面に
熱転写記録層３を、さらに熱転写記録層の上に本
考案の感圧性インク層２を設けたものである。 FIG. 1 is a cross-sectional view of a heat-sensitive thermal transfer recording sheet 1, which has a heat-sensitive recording layer 4 on one side of a base material 5, a heat-transfer recording layer 3 on the opposite side, and a pressure-sensitive ink layer of the present invention on the heat-transfer recording layer. 2.
第２図は、感熱熱転写記録シート１の熱転写記
録層側からみた平面図であり、感圧性インク層２
が熱転写記録層３の上に部分的に設けられてい
る。 FIG. 2 is a plan view of the heat-sensitive thermal transfer recording sheet 1 viewed from the thermal transfer recording layer side, and shows the pressure-sensitive ink layer 2.
is partially provided on the thermal transfer recording layer 3.
第３図は、感熱熱転写記録シート１と普通紙か
らなる受像紙７とを組み合せたものであり、筆記
具１０を用いて感熱記録層側より筆圧を加えたと
き、感熱記録層４の上に筆記具による記録像９が
同時に感熱熱転写記録シート１に筆圧が加わり、
感圧性インク層２の筆圧部８のマイクロカプセル
が破壊され、受像紙７の面に筆圧による転写像６
が記録される。筆記具１０は通常加圧可能なもの
であればよく、ペン先に発熱体を持つペンであつ
てもよい。 FIG. 3 shows a combination of a heat-sensitive thermal transfer recording sheet 1 and an image-receiving paper 7 made of plain paper. At the same time, writing pressure is applied to the recording image 9 by the writing instrument on the thermosensitive thermal transfer recording sheet 1,
The microcapsules in the pen pressure section 8 of the pressure-sensitive ink layer 2 are destroyed, and a transferred image 6 is formed on the surface of the image receiving paper 7 by the pen pressure.
is recorded. The writing instrument 10 generally only needs to be pressable, and may be a pen having a heating element at the tip.
基材５としては転写特性の面で薄いものが良
く、10〜30μmのコンデンサー紙、グラシン紙な
どの紙類、あるいはポリエステル、ポリイミド、
ポリカーボネート、テフロンなどの樹脂フイルム
類が用いられる。 The base material 5 is preferably thin in terms of transfer characteristics, such as paper such as 10 to 30 μm capacitor paper, glassine paper, or polyester, polyimide,
Resin films such as polycarbonate and Teflon are used.
感熱記録層４は、通常感熱記録紙用の素材をそ
のまま用いて塗設すれば良い。 The heat-sensitive recording layer 4 may be coated using a material for normal heat-sensitive recording paper as it is.
感熱熱転写記録層３は無色の電子供与性の発色
剤、電子受容性の顕色剤、ワツクス類を主成分と
するものを塗設する。 The heat-sensitive thermal transfer recording layer 3 is coated with a material whose main components are a colorless electron-donating coloring agent, an electron-accepting color developer, and waxes.
本考案の感圧性インク層２の成分は少なくとも
一方がマイクロカプセル化された電子供与性の発
色剤、電子受容性の顕色剤、ワツクス類からなる
ものであり、具体的には以下のとおりである。 The components of the pressure-sensitive ink layer 2 of the present invention include an electron-donating coloring agent, an electron-accepting color developer, and waxes, at least one of which is microencapsulated.Specifically, they are as follows. be.
本考案に用いられる電子供与性の無色の発色剤
について、例えば、クリスタルバイオレツトラク
トン、マラカイトグリーンラクトン、３−ジエチ
ルアミノ−７−メチルフルオラン、３−ジエチル
アミノ−６−メチル−７−クロロフルオラン、３
−ジエチルアミノ−７−ジベンジルアミノフルオ
ラン、３−ジエチルアミノ−７−アニリノフルオ
ラン、３−（Ｎ−メチルアニリノ）−７−アニリノ
フルオラン、３−ジエチルアミノ−７−（ｍ−ト
リフルオロメチルアニリノ）フルオラン、３−ジ
エチルアミノ−６−メチル−７−アニリノフルオ
ラン、３−（Ｎ−メチルシクロヘキシルアミノ）−
６−メチル−７−アニリノフルオラン、３−ピロ
リジノ−６−メチル−７−アニリノフルオラン、
３−ピペリジノ−６−メチル−７−アニリノフル
オラン、３−（Ｎ−メチル−Ｐ−トルイジノ）−６
−メチル−７−アニリノフルオラン、ベンゾ−β
−ナフトスピロピラン、などを挙げることができ
る。 Examples of the electron-donating color former used in the present invention include crystal violet lactone, malachite green lactone, 3-diethylamino-7-methylfluoran, 3-diethylamino-6-methyl-7-chlorofluoran, 3
-diethylamino-7-dibenzylaminofluorane, 3-diethylamino-7-anilinofluorane, 3-(N-methylanilino)-7-anilinofluorane, 3-diethylamino-7-(m-trifluoromethylaniline) Lino)fluorane, 3-diethylamino-6-methyl-7-anilinofluorane, 3-(N-methylcyclohexylamino)-
6-methyl-7-anilinofluorane, 3-pyrrolidino-6-methyl-7-anilinofluorane,
3-piperidino-6-methyl-7-anilinofluorane, 3-(N-methyl-P-toluidino)-6
-Methyl-7-anilinofluorane, benzo-β
-naphthospiropyran, etc.
本考案に用いられる電子受容性の無色の顕色剤
について、例えば、フエノール、パラ−tert−ブ
チルフエノール、パラフエニルフエノール、α−
ナフトール、β−ナフトール、４，4′−イソプロ
ビリデンジフエノール、４，4′−sec−ブチリデ
ンジフエノール、４，4′−イソプロピリデンビス
−（２−tert−ブチルフエノール）、４，4′−シク
ロヘキシリデンジフエノール、フエニル−４−ヒ
ドロキシベンゾエート、ノボラツク型フエノール
樹脂、サリチル酸、３−フエニルサリチル酸、５
−メチルサリチル酸、３，５−ジ−tert−ブチル
サリチル酸などを挙げることができる。 Examples of the electron-accepting colorless developer used in the present invention include phenol, para-tert-butylphenol, paraphenylphenol, α-
Naphthol, β-naphthol, 4,4'-isopropylidene diphenol, 4,4'-sec-butylidene diphenol, 4,4'-isopropylidene bis-(2-tert-butylphenol), 4,4'- Cyclohexylidene diphenol, phenyl-4-hydroxybenzoate, novolak type phenolic resin, salicylic acid, 3-phenylsalicylic acid, 5
-methylsalicylic acid, 3,5-di-tert-butylsalicylic acid, and the like.
本考案に用いられるワツクス類について、例え
ば、パラフインワツクス、マイクロクリスタルワ
ツクス、みつろう、鯨ろう、セラツクろう、カル
ナウバワツクス、キヤンデリラワツクス、モンタ
ンワツクス、低分子ポリエチレンワツクス、ステ
アリン酸アマイド、パルミチン酸アマイド、オレ
イン酸アマイド、ラウリン酸アマイド、エチレン
ビスステアロアマイド、メチレンビスステアロア
マイド、メチロールステアロアマイド、などを挙
げることができる。 The waxes used in the present invention include, for example, paraffin wax, microcrystal wax, beeswax, spermaceti wax, ceramic wax, carnauba wax, candelilla wax, montan wax, low-molecular polyethylene wax, and stearic acid wax. amide, palmitic acid amide, oleic acid amide, lauric acid amide, ethylene bis stearamide, methylene bis stearamide, methylol stearamide, and the like.
本考案に用いられる少なくとも一方がマイクロ
カプセル化された該発色剤及び該顕色剤はいずれ
も不揮発制溶剤に溶解した溶液としてマイクロカ
プセルに内包されているものであるが、該発色剤
及び該顕色剤を溶解させる不揮発性溶剤について
は、例えば、アルキルナフタレン系、塩素化パラ
フイン系、ジアリールエタン系、アルキルジフエ
ニル系、芳香族エステル系、脂肪族エステル系な
どを挙げることができる。 The color former and the color developer used in the present invention, at least one of which is microencapsulated, are both encapsulated in microcapsules as a solution dissolved in a nonvolatile antisolvent. Examples of nonvolatile solvents for dissolving coloring agents include alkylnaphthalenes, chlorinated paraffins, diarylethanes, alkyldiphenyls, aromatic esters, and aliphatic esters.
また、マイクロカプセル化法については、業界
公知の方法でよいが、例えばコンプレツクス・コ
アセルベーシヨン法、インサイチユー法、界面重
合法、スプレードライ法など挙げることができ
る。 Further, as for the microencapsulation method, any method known in the industry may be used, and examples thereof include a complex coacervation method, an in-situ method, an interfacial polymerization method, and a spray drying method.
その他、マイクロカプセルに対するスチルト材
として、小麦デンプン、ポリオレフインなどの球
状粒子、ポリビニルアルコール、でん粉、スチレ
ン−無水マレイン酸共重合体のナトリウム塩ある
いはアンモニウム塩、スチレン−ブタジエン共重
合体ラテツクスなどの接着剤。必要によつては、
二酸化チタン、炭酸カルシウム、カオリン、焼成
カリオン、水酸化アルミなどの顔料を加えても良
い。本考案の感圧性インク層を熱転写記録層の上
に塗設する方法は、水性塗液又は溶剤塗液として
フレキソ印刷機、グラビア印刷機、ロールコータ
ーなどを用いて部分塗工又はストライプ塗工する
方法を挙げることができる。 Other stilt materials for microcapsules include adhesives such as spherical particles such as wheat starch and polyolefin, polyvinyl alcohol, starch, sodium salt or ammonium salt of styrene-maleic anhydride copolymer, and styrene-butadiene copolymer latex. If necessary,
Pigments such as titanium dioxide, calcium carbonate, kaolin, calcined carrion, and aluminum hydroxide may also be added. The method of coating the pressure-sensitive ink layer of the present invention on the thermal transfer recording layer is partial coating or stripe coating using a flexographic printing machine, gravure printing machine, roll coater, etc. as an aqueous coating liquid or a solvent coating liquid. Here are some methods.
以下に本考案の実施例を示すが、これらに限定
されるものではない。 Examples of the present invention are shown below, but the present invention is not limited thereto.
実施例
16μmポリエステルフイルムの片面に感熱記録
層を、その反対面に熱転写記録層を塗設した感熱
熱転写記録シートを用意する。該記録シートの熱
転写記録層上に感圧性インクを塗工するが、その
配合は次のとおりである。Example A thermosensitive thermal transfer recording sheet is prepared by coating a 16 μm polyester film with a thermosensitive recording layer on one side and a thermal transfer recording layer on the opposite side. A pressure-sensitive ink is coated on the thermal transfer recording layer of the recording sheet, and its formulation is as follows.
発色剤（３−ジエチルアミノ−６−メチル−７−
フエニルアミノフルオラン）含有マイクロカプセ
ル（黒発色） 10重量部
顕色剤（パラ−フエニルフエノール）含有マイク
ロカプセル 20 〃
ステアリン酸アマイド 30 〃
SBRラテツクス 30 〃
小麦デンプン 10 〃
上記の配合からなる40％水性塗液をフレキソ印
刷機により熱転写記録上に部分塗工して本考案の
地肌の白い感熱熱転写記録シートを作製した。Color former (3-diethylamino-6-methyl-7-
Phenylaminofluorane)-containing microcapsules (black coloring) Microcapsules containing 10 parts by weight of color developer (para-phenylphenol) 20 〃 Stearamide 30 〃 SBR latex 30 〃 Wheat starch 10 〃 Consisting of the above formulation 40 % aqueous coating liquid was partially coated on a thermal transfer recording sheet using a flexo printing machine to prepare a thermosensitive thermal transfer recording sheet with a white background according to the present invention.
作製した該記録シートを受像紙（三菱製紙製、
商品名TTR−PW）と重ねて感圧性インク層の
塗設した部分の反対面（感熱記録層）より筆圧を
加えたところ、受像紙上に鮮明なる黒色の記録像
を得た。又、感圧性インク層塗設部以外は、サマ
ールヘツドの熱により該記録シート上には感熱記
録像を、受像紙上には熱転写記録像を得ることが
できた。 The produced recording sheet was coated with image receiving paper (manufactured by Mitsubishi Paper Mills,
When pressure was applied from the opposite side (heat-sensitive recording layer) of the area coated with the pressure-sensitive ink layer (trade name TTR-PW), a clear black recorded image was obtained on the receiver paper. In addition, except for the area where the pressure-sensitive ink layer was applied, a heat-sensitive recorded image could be obtained on the recording sheet and a thermally transferred recorded image could be obtained on the image-receiving paper by the heat of the Samal head.
第１図は本考案の感熱転写記録シートの断面図
である。第２図はその平面図である。第３図は該
記録シート１と受像紙７とを重ねて筆圧を加えた
ときの断面図である。
図中１は、感熱熱転写記録シート、２は感圧性
インク層、３は熱転写記録層、４感熱記録層、５
は基材、６は転写像、７は受像紙、８は感圧性イ
ンク層の筆圧後の部分、９は感熱記録層の筆記具
による記録像、１０は筆記具を示す。
FIG. 1 is a sectional view of the thermal transfer recording sheet of the present invention. FIG. 2 is a plan view thereof. FIG. 3 is a cross-sectional view when the recording sheet 1 and the image receiving paper 7 are stacked and writing pressure is applied. In the figure, 1 is a heat-sensitive thermal transfer recording sheet, 2 is a pressure-sensitive ink layer, 3 is a thermal transfer recording layer, 4 is a heat-sensitive recording layer, and 5 is a heat-sensitive thermal transfer recording sheet.
Reference numeral indicates a base material, 6 indicates a transferred image, 7 indicates an image receiving paper, 8 indicates a portion of the pressure-sensitive ink layer after writing pressure, 9 indicates an image recorded by a writing instrument on the heat-sensitive recording layer, and 10 indicates a writing instrument.
Claims (1)
熱転写記録層を塗設し、さらに、該熱転写記録層
上に、少なくとも一方がマイクロカプセル化され
た電子供与性の発色剤、電子受容性の顕色剤及び
ワツクス類を主成分とした感圧性インクの層を部
分的に設けた伝票用感熱熱転写記録シート。 A heat-sensitive recording layer is coated on one side of the base material, and a colorless heat transfer recording layer is coated on the opposite side, and an electron-donating coloring agent, at least one of which is microencapsulated, and an electron-accepting coloring agent are coated on the heat transfer recording layer. A heat-sensitive thermal transfer recording sheet for slips partially provided with a layer of pressure-sensitive ink containing a color developer and waxes as main components.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1985098901U JPH0513585Y2 (en) | 1985-06-27 | 1985-06-27 | |
| DE19863601525 DE3601525A1 (en) | 1985-01-21 | 1986-01-20 | HEAT SENSITIVE AND HEAT TRANSFERABLE RECORD SHEET |
| US06/820,305 US4703335A (en) | 1985-01-21 | 1986-01-21 | Heat-sensitive and heat-transferable recording sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1985098901U JPH0513585Y2 (en) | 1985-06-27 | 1985-06-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS625958U JPS625958U (en) | 1987-01-14 |
| JPH0513585Y2 true JPH0513585Y2 (en) | 1993-04-09 |
Family
ID=30967287
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1985098901U Expired - Lifetime JPH0513585Y2 (en) | 1985-01-21 | 1985-06-27 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0513585Y2 (en) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5312845A (en) * | 1976-07-22 | 1978-02-04 | Bayer Ag | Tetraalkylated bisscyclohexyl amine derivatives |
| JPS53106210A (en) * | 1977-02-28 | 1978-09-16 | Toppan Moore Kk | Pressure sensitive copy sheet |
| JPS5483842A (en) * | 1977-12-17 | 1979-07-04 | Nippon Telegr & Teleph Corp <Ntt> | Thermal recording medium |
| JPS5515316A (en) * | 1978-07-15 | 1980-02-02 | Michimoto Sakai | Moisture preventing method for backmirror |
| JPS5627396A (en) * | 1979-08-15 | 1981-03-17 | Dainippon Printing Co Ltd | Transferring method for thermorecording |
| JPS5675894A (en) * | 1979-11-26 | 1981-06-23 | Nippon Telegr & Teleph Corp <Ntt> | Thermal recording medium |
| JPS5639268B2 (en) * | 1976-02-19 | 1981-09-11 | ||
| JPS57191085A (en) * | 1981-05-20 | 1982-11-24 | Mitsubishi Paper Mills Ltd | Ordinary paper transfer type pressure sensitive copying paper |
| JPS6018946U (en) * | 1982-05-10 | 1985-02-08 | 株式会社資生堂 | laundry bag |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5122727Y2 (en) * | 1971-10-29 | 1976-06-11 | ||
| JPS5639268U (en) * | 1979-09-03 | 1981-04-13 | ||
| JPS5669463U (en) * | 1979-10-31 | 1981-06-09 | ||
| JPS5669462U (en) * | 1979-10-31 | 1981-06-09 | ||
| JPS635898Y2 (en) * | 1979-11-09 | 1988-02-18 | ||
| JPS58160175U (en) * | 1982-04-20 | 1983-10-25 | 凸版印刷株式会社 | pressure sensitive copy slip |
-
1985
- 1985-06-27 JP JP1985098901U patent/JPH0513585Y2/ja not_active Expired - Lifetime
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5639268B2 (en) * | 1976-02-19 | 1981-09-11 | ||
| JPS5312845A (en) * | 1976-07-22 | 1978-02-04 | Bayer Ag | Tetraalkylated bisscyclohexyl amine derivatives |
| JPS53106210A (en) * | 1977-02-28 | 1978-09-16 | Toppan Moore Kk | Pressure sensitive copy sheet |
| JPS5483842A (en) * | 1977-12-17 | 1979-07-04 | Nippon Telegr & Teleph Corp <Ntt> | Thermal recording medium |
| JPS5515316A (en) * | 1978-07-15 | 1980-02-02 | Michimoto Sakai | Moisture preventing method for backmirror |
| JPS5627396A (en) * | 1979-08-15 | 1981-03-17 | Dainippon Printing Co Ltd | Transferring method for thermorecording |
| JPS5675894A (en) * | 1979-11-26 | 1981-06-23 | Nippon Telegr & Teleph Corp <Ntt> | Thermal recording medium |
| JPS57191085A (en) * | 1981-05-20 | 1982-11-24 | Mitsubishi Paper Mills Ltd | Ordinary paper transfer type pressure sensitive copying paper |
| JPS6018946U (en) * | 1982-05-10 | 1985-02-08 | 株式会社資生堂 | laundry bag |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS625958U (en) | 1987-01-14 |
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