JPH051350A - Roll external layer material for rolling - Google Patents

Roll external layer material for rolling

Info

Publication number
JPH051350A
JPH051350A JP30383291A JP30383291A JPH051350A JP H051350 A JPH051350 A JP H051350A JP 30383291 A JP30383291 A JP 30383291A JP 30383291 A JP30383291 A JP 30383291A JP H051350 A JPH051350 A JP H051350A
Authority
JP
Japan
Prior art keywords
rolling
outer layer
roll
layer material
external layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP30383291A
Other languages
Japanese (ja)
Other versions
JP2715205B2 (en
Inventor
Yoshihiro Kataoka
義弘 片岡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Priority to DE69227504T priority Critical patent/DE69227504T2/en
Priority to US08/050,394 priority patent/US5316596A/en
Priority to KR1019930701420A priority patent/KR960005598B1/en
Priority to PCT/JP1992/000400 priority patent/WO1993005192A1/en
Priority to EP92907591A priority patent/EP0562114B1/en
Priority to EP92909738A priority patent/EP0559899B1/en
Priority to ES92909738T priority patent/ES2124728T3/en
Priority to PCT/JP1992/000625 priority patent/WO1993005193A1/en
Priority to CN 92103692 priority patent/CN1032262C/en
Publication of JPH051350A publication Critical patent/JPH051350A/en
Application granted granted Critical
Publication of JP2715205B2 publication Critical patent/JP2715205B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Abstract

PURPOSE:To provide a roll external layer material for rolling free from the generation of segregation or the like and having uniform wear resistance and cracking resistance even if a centrifugal force casting method excellent in productivity and economicity is applied by optimizing alloy components forming an external layer and limiting the compsn. of carbide. CONSTITUTION:This roll external layer material for rolling contains 1.5 to 3.5% C, <=1.5% Si, <=1.2% Mn, 5.5 to 12.0% Cr, 2.0 to 8.0% Mo, 3.0 to 10.0% V and 0.6 to 7.0% Nb as well as satisfies the following inequalities (1) and (2), i.e., V+1.8Nb<=7.5C-6.0(%)...(1) and 0.2<=Nb/V<=0.8...(2) and the balance Fe with inevitable impurities.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、耐摩耗性と耐クラック
性を兼備した圧延用ロール外層材に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a rolling roll outer layer material having both wear resistance and crack resistance.

【0002】[0002]

【従来の技術】従来、耐摩耗性が要求される熱間圧延用
ロールは、外層と内層からなる複合ロールとされ、外層
材をセメンタイト系の炭化物が晶出した高Cr鋳鉄、ま
たはNi−グレン鋳鉄、内層材を靱性の良いねずみ鋳
鉄、またはダクタイル鋳鉄として、遠心力鋳造法によっ
て製造されている。然るに、圧延条件の苛酷化及び圧延
における生産性向上の要求等から、より一層の耐摩耗性
と耐クラック性を備えた圧延用ロールの提供が要求され
ている。
2. Description of the Related Art Conventionally, a hot rolling roll required to have wear resistance is a composite roll consisting of an outer layer and an inner layer, and the outer layer material is a high Cr cast iron crystallized with cementite type carbide or Ni-grain. It is manufactured by the centrifugal force casting method using cast iron, the inner layer material as gray cast iron having good toughness, or ductile cast iron. However, due to stricter rolling conditions and demand for improved productivity in rolling, it is required to provide rolling rolls having further wear resistance and crack resistance.

【0003】このような状況から、例えば特開昭60-124
407 号、特開昭61-177355 号には、従来の遠心力鋳造ロ
ールの外層材として高V鋳鉄を用いることが提案されて
いる。
Under such circumstances, for example, Japanese Patent Laid-Open No. 60-124
No. 407 and Japanese Patent Laid-Open No. 61-177355 propose to use high V cast iron as an outer layer material of a conventional centrifugal casting roll.

【0004】[0004]

【発明が解決しようとする課題】然しながら、遠心力鋳
造ロールの外層材として高V鋳鉄を用いる圧延用ロール
では、比重の小さいV炭化物が遠心分離し、ロール外層
内の特性が肉厚方向で不均一になる。この傾向は大型ロ
ールで外層肉厚が大なるほど著しく、実用ロールとして
の使用に耐えることができないという問題点がある。
However, in a rolling roll using high V cast iron as the outer layer material of a centrifugal casting roll, V carbide having a small specific gravity is centrifugally separated, and the characteristics in the outer layer of the roll are not uniform in the thickness direction. Be uniform. This tendency is remarkable as the outer layer thickness of the large roll increases, and there is a problem that it cannot withstand use as a practical roll.

【0005】尚、特開昭58-87249号公報、特開平1-9635
5号公報には、高速度鋼なみに高合金化した鋳鋼、鋳鉄
を適用したロール材が提案されている。然しながら、特
開昭58-87249号公報には焼嵌めまたは組立ロールを対象
としたものであり、圧延中に生ずる外層と軸材間の滑り
が問題となる。また、特開平1-96355 号公報は特殊な鋳
かけ肉盛法等、遠心力鋳造法以外の特殊な製造手法しか
適用できず、生産性、経済性の面で問題がある。
Incidentally, Japanese Patent Laid-Open Nos. 58-87249 and 1-9635.
Japanese Unexamined Patent Application Publication No. 5 proposes a roll material to which cast steel and cast iron that are highly alloyed like high speed steel are applied. However, JP-A-58-87249 deals with shrink fitting or assembling rolls, and slippage between the outer layer and the shaft material during rolling poses a problem. Further, Japanese Patent Application Laid-Open No. 1-96355 can only be applied to a special manufacturing method other than the centrifugal force casting method such as a special cast overlay method, which causes problems in productivity and economy.

【0006】即ち、圧延用ロールの製造に際し、ロール
外層にVを多量に含有させることにより、耐摩耗性を著
しく向上させることは可能であるが、複合ロール製造時
に生産性、経済性が最も優れているとして一般に実施さ
れている遠心力鋳造法を採用した場合には、炭化物の遠
心分離を生じ所定の特性を均一に得られないという問題
点がある。
That is, when a rolling roll is manufactured, it is possible to remarkably improve the wear resistance by adding a large amount of V to the outer layer of the rolling roll, but the productivity and the economical efficiency are most excellent at the time of manufacturing the composite roll. However, when the centrifugal casting method which is generally carried out is adopted, there is a problem in that carbides are centrifugally separated and predetermined characteristics cannot be obtained uniformly.

【0007】本発明は、外層を形成する合金成分を適正
化し、炭化物組成を限定することにより、生産性、経済
性の優れた遠心力鋳造法を適用しても、偏析等の生じな
い耐摩耗性と耐クラック性の均一な圧延用ロール外層材
を提供することを目的とする。
The present invention optimizes the alloy components forming the outer layer and limits the carbide composition, so that even if the centrifugal casting method, which is excellent in productivity and economy, is applied, segregation does not occur. An object of the present invention is to provide a roll outer layer material for rolling, which has uniform properties and crack resistance.

【0008】[0008]

【課題を解決するための手段】本発明の圧延用ロール外
層材は、C:1.5 〜 3.5%,Si:1.5 %以下, Mn:
1.2%以下, Cr:5.5 〜12.0%,Mo:2.0 〜8.0
%,V:3.0 〜10.0%,Nb:0.6 〜7.0 %を含有し、
且つ下記(1) 式と(2) 式を満足し、 V+ 1.8Nb ≦ 7.5 C−6.0(%)…(1) 0.2 ≦ Nb/V ≦ 0.8 …(2) 残部Fe及び不可避的不純物よりなるようにしたもので
ある。
The outer layer material for rolling of the present invention is C: 1.5 to 3.5%, Si: 1.5% or less, Mn:
1.2% or less, Cr: 5.5 to 12.0%, Mo: 2.0 to 8.0
%, V: 3.0 to 10.0%, Nb: 0.6 to 7.0%,
Further, the following formulas (1) and (2) are satisfied, and V + 1.8Nb ≤ 7.5 C-6.0 (%) ... (1) 0.2 ≤ Nb / V ≤ 0.8 ... (2) The balance is Fe and inevitable impurities. It is the one.

【0009】[0009]

【作用】本発明における各合金元素の含有量の限定理由
及びV、Nb、C量の限定式について説明する。
The reason for limiting the content of each alloying element and the limiting formula for the amounts of V, Nb, and C in the present invention will be described.

【0010】C:1.5 %〜3.5 % Cはロール外層材の耐摩耗性を向上する硬い炭化物を形
成するための必須元素で1.5 %以上必要であるが、3.5
%を越えると耐クラック性が著しく低下するため上限を
3.5 %とする。
C: 1.5% to 3.5% C is an essential element for forming a hard carbide which improves the wear resistance of the outer layer material of the roll and is required to be 1.5% or more.
%, The crack resistance will drop significantly, so the upper limit is
3.5%

【0011】Si:1.5 %以下 Siは脱酸剤及び鋳造性の確保のために添加するが、1.
5 %を越えると耐クラック性を低下するため上限を1.5
%とする。
Si: 1.5% or less Si is added to secure a deoxidizing agent and castability, but 1.
If it exceeds 5%, the crack resistance decreases, so the upper limit is 1.5.
%.

【0012】Mn:1.2 %以下 Mnも上記Siと同様の目的で添加するが、1.2 %を越
えると耐クラック性が低下するため好ましくなく上限を
1.2 %とする。
Mn: 1.2% or less Mn is also added for the same purpose as the above Si, but if it exceeds 1.2%, the crack resistance is deteriorated and the upper limit is not preferable.
1.2%

【0013】Cr:5.5 〜12.0% Crは炭化物を形成し、耐摩耗性を向上するために必要
な元素で5.5 %以上添加するが、12.0%を越えると本発
明が対象とするV、Nbを添加した場合には耐摩耗性が
劣化するため上限を12.0%とする。
Cr: 5.5 to 12.0% Cr forms a carbide and is an element necessary for improving wear resistance, and is added in an amount of 5.5% or more. If it exceeds 12.0%, V and Nb targeted by the present invention are added. If added, the wear resistance deteriorates, so the upper limit is made 12.0%.

【0014】Mo:2.0 〜8.0 % MoはCrと同様に炭化物を形成して耐摩耗性の向上に
有効であるとともに、基地の焼入性、焼もどし軟化抵抗
を向上し、基地組織の強化に有効であるため2.0 %以上
必要であるが、8.0 %を越えると耐クラック性が低下す
るため、上限を8.0 %とする。
Mo: 2.0 to 8.0% Mo forms a carbide similarly to Cr and is effective in improving wear resistance, and also improves the hardenability and temper softening resistance of the matrix and strengthens the matrix structure. Since it is effective, 2.0% or more is required, but if it exceeds 8.0%, crack resistance deteriorates, so the upper limit is made 8.0%.

【0015】V:3.0 〜10.0%、Nb:0.6 〜7.0 % V、Nbは本発明における最も重要な必須元素であり、
これらの複合添加と含有量制限条件が本発明の最大の特
徴である。
V: 3.0 to 10.0%, Nb: 0.6 to 7.0% V, Nb is the most important essential element in the present invention,
These combined additions and content limiting conditions are the greatest features of the present invention.

【0016】Vは耐摩耗性の向上に最も有効な硬いMC
またはM43 炭化物を形成するための必須元素で、そ
の効果を発揮するためには3.0 %以上必要であるが、1
0.0%を越えると耐クラック性の低下、製造上の問題を
生じるため上限を10.0%とする。
V is a hard MC that is most effective in improving wear resistance.
Or, it is an essential element for forming M 4 C 3 carbide, and 3.0% or more is necessary to exert its effect.
If it exceeds 0.0%, the crack resistance lowers and manufacturing problems occur, so the upper limit is made 10.0%.

【0017】NbもV同様耐摩耗性に有効な硬いMC炭
化物を形成するが単独添加では粗大な塊状炭化物となり
その効果が得られないだけでなく耐クラック性が問題と
なる。
Nb, like V, forms hard MC carbides that are effective in wear resistance, but when added alone, it becomes coarse lump carbides, and this effect cannot be obtained, and crack resistance becomes a problem.

【0018】そこでVとNbを複合添加した場合の母材
硬さに及ぼすC量との関係、及び遠心力鋳造したリング
材の炭化物分布に起因する外層、内層間の熱間摩耗比、
熱衝撃試験におけるクラックの最大深さとNb、Vの含
有量比Nb/Vとの関係を調べた結果をそれぞれ図1及
び図2に示す。
Therefore, the relationship between the C content and the hardness of the base metal when V and Nb are added in combination, and the hot wear ratio between the outer layer and the inner layer due to the carbide distribution of the centrifugally cast ring material,
The results of examining the relationship between the maximum crack depth and the Nb / V content ratio Nb / V in the thermal shock test are shown in FIGS. 1 and 2, respectively.

【0019】図1から耐摩耗熱間圧延用ロールとして必
要な硬さHs 75以上を得るためには V+1.8 Nb≦7.5 C−6.0 (%) を満足する必要があることが明らかとなった。
From FIG. 1, it has been clarified that V + 1.8 Nb ≦ 7.5 C-6.0 (%) must be satisfied in order to obtain hardness Hs 75 or more required for the wear-resistant hot rolling roll. ..

【0020】尚、図1の実験は、Si:0.5 %,Mn:
0.5 %,Cr:6.8 %,Mo:3.2%を含有し、C、N
b、Vを変化した溶湯を鋳造した25mmYブロックについ
て、1000℃焼ならし処理、550 ℃焼もどし処理を施した
試料を用いた。
In the experiment of FIG. 1, Si: 0.5%, Mn:
Contains 0.5%, Cr: 6.8%, Mo: 3.2%, C, N
A 25 mm Y block obtained by casting a molten metal having different b and V was subjected to a normalizing treatment at 1000 ° C and a tempering treatment at 550 ° C.

【0021】また、図2から遠心力鋳造法で製造した場
合にも均一な外層材を得ることができ、かつ耐クラック
性も損なわないためには 0.2 ≦Nb/V≦0.8 を満足する必要があることが明らかとなった。
In addition, it is necessary to satisfy 0.2 ≤ Nb / V ≤ 0.8 in order to obtain a uniform outer layer material even when manufactured by the centrifugal casting method from Fig. 2 and not to impair the crack resistance. It became clear.

【0022】尚、図2において、「摩耗比(内層/外
層)」は、リング材の内層側から採取した試験片の摩耗
量(Iw )と外層側から採取した試験片の摩耗量(Ow
)との比(Iw /Ow )であり、「熱衝撃クラック最
大深さ」は、熱衝撃試験で発生したクラックの最大深さ
である。
In FIG. 2, "wear ratio (inner layer / outer layer)" means the wear amount (Iw) of the test piece taken from the inner layer side of the ring material and the wear amount (Ow of the test piece taken from the outer layer side).
)), And the "maximum depth of thermal shock cracks" is the maximum depth of cracks generated in the thermal shock test.

【0023】また、図2の実験は、C:2.5 %,Si:
0.5 %,Mn:0.5 %,Cr:6.5%,Mo:3.5 %,
V:5.4 %,Nb:0 〜8.0 %を含有する溶湯を遠心力
鋳造(140 G)して得た肉厚100mm のリングサンプルに
ついて、1000℃焼ならし処理、550 ℃焼もどし処理を施
した試料を用いた。
In the experiment of FIG. 2, C: 2.5%, Si:
0.5%, Mn: 0.5%, Cr: 6.5%, Mo: 3.5%,
A ring sample with a wall thickness of 100 mm obtained by centrifugal casting (140 G) of a molten metal containing V: 5.4% and Nb: 0 to 8.0% was subjected to normalizing treatment at 1000 ° C and tempering treatment at 550 ° C. A sample was used.

【0024】そして、摩耗試験は、φ190 ×15の相手材
とφ50×10の試験材の2円盤のすべり摩耗方式で相手材
を800 ℃に加熱し、荷重100Kgfで圧接した状態で試験材
を800rpmで回転させ、すべり率3.9 %として120 分後の
摩耗減量を測定して行なった。
A wear test was conducted by heating the mating material to 800 ° C. by the sliding wear method of a 2 disk of φ190 × 15 mating material and φ50 × 10 test material, and pressing the test material at 800 rpm under a pressure of 100 Kgf. Rotation was performed at a slip rate of 3.9%, and the wear loss after 120 minutes was measured.

【0025】また、熱衝撃試験は、1200rpm で回転して
いるローラーに55×40×15の板状試験片を圧接する方式
で、荷重150kgf、接触時間15sの条件で行ない、試験片
に発生したクラック長さを測定した。
The thermal shock test was carried out by pressing a 55 × 40 × 15 plate test piece against a roller rotating at 1200 rpm under the conditions of a load of 150 kgf and a contact time of 15 s, and the test piece was generated. The crack length was measured.

【0026】[0026]

【実施例】表1に示す化学組成の溶湯(本発明材:B〜
F、R、S、比較材:A、G〜Q)を遠心力鋳造法(14
0G)により鋳造し、肉厚100mm のリングサンプルを試作
し、ショアー硬さ、熱間摩耗及び熱衝撃試験を行なっ
た。
EXAMPLE A molten metal having the chemical composition shown in Table 1 (material of the present invention: B to
F, R, S, comparative materials: A, G to Q) are centrifugally cast (14
A ring sample with a wall thickness of 100 mm was cast as a prototype and subjected to Shore hardness, hot wear and thermal shock tests.

【0027】[0027]

【表1】 [Table 1]

【0028】尚、摩耗試験は、リング材の内層側と外層
側からそれぞれφ50×10の試験片を採取し、前記条件と
同一の方法で行なった。
The wear test was carried out by the same method as the above conditions by taking test pieces of φ50 × 10 from the inner layer side and the outer layer side of the ring material.

【0029】また、熱衝撃試験は、リング材の外層側よ
り前記した板状試験片を採取し、同一の条件で行なっ
た。
The thermal shock test was conducted under the same conditions by collecting the above-mentioned plate-shaped test piece from the outer layer side of the ring material.

【0030】それら摩耗試験と熱衝撃試験の結果を表2
に示す。表2によれば、本発明材は従来のNi−グレン
材(A材)と比べ、硬さは同程度であるが、耐摩耗性、
耐クラック性ともに著しく向上していることが認められ
る。
The results of the wear test and the thermal shock test are shown in Table 2.
Shown in. According to Table 2, the material of the present invention has the same hardness as the conventional Ni-Glen material (A material), but the wear resistance,
It is recognized that the crack resistance is significantly improved.

【0031】[0031]

【表2】 [Table 2]

【0032】また、比較材G〜Q材は本発明の限定をは
ずれているため、G材は炭化物の偏析で外層の耐摩耗性
が低下し、H材については硬さが不足しているとともに
耐クラック性が低下し、I材については硬さの不足とと
もに炭化物の偏析で外層の耐摩耗性が低下し、J材につ
いては硬さが不足している。また、K材はC量が過多で
あるため耐クラック性が低下し、L材はSi量が過多で
あるため耐クラック性が低下し、M材はMn量が過多で
あるため耐クラック性が低下し、N材はCr量が過多で
あるため耐摩耗性、耐クラック性が低下し、O材はMo
量が過多であるため耐クラック性が低下し、P材はV量
が不足しているため耐摩耗性、耐クラック性が低下し、
Q材はV量が過多であるため耐クラック性が低下してい
る。
Further, since the comparative materials G to Q deviate from the limitation of the present invention, segregation of the carbide causes the wear resistance of the outer layer of the G material to be deteriorated, and the hardness of the H material is insufficient. The crack resistance is lowered, the hardness of I material is insufficient, and the wear resistance of the outer layer is reduced due to the segregation of carbides, and the hardness of J material is insufficient. In addition, the K material has an excessive amount of C and thus has low crack resistance, the L material has an excessive amount of Si, and therefore has poor crack resistance, and the M material has an excessive amount of Mn and therefore has an excellent crack resistance. When the N material has an excessive amount of Cr, the wear resistance and crack resistance are reduced, and the O material is Mo.
Since the amount is too large, the crack resistance is reduced, and the P material is insufficient in the V amount, so the wear resistance and crack resistance are reduced.
Since the V material has an excessive V content, the crack resistance is deteriorated.

【0033】[0033]

【発明の効果】以上のように本発明によれば、生産性、
経済性の優れた遠心力鋳造法を適用しても、偏析等の生
じない耐摩耗性と耐クラック性に優れた圧延用ロール外
層材を得ることができる。
As described above, according to the present invention, productivity,
Even if the centrifugal casting method which is excellent in economic efficiency is applied, it is possible to obtain a rolling roll outer layer material which is free from segregation and has excellent wear resistance and crack resistance.

【図面の簡単な説明】[Brief description of drawings]

【図1】図1はVとNbの複合添加量とC量とが母材硬
さに及ぼす影響を示す線図である。
FIG. 1 is a diagram showing the effect of the combined addition amount of V and Nb and the C amount on the hardness of a base material.

【図2】図2は遠心力鋳造したリング材の炭化物分布に
起因する外層と内層間の熱間摩耗比と、熱衝撃試験にお
けるクラック最大深さに及ぼすNbとVの含有量比Nb
/Vの影響を示す線図である。
FIG. 2 is a hot wear ratio between an outer layer and an inner layer due to a carbide distribution of a centrifugally cast ring material, and a Nb and V content ratio Nb which affects the maximum crack depth in a thermal shock test.
It is a diagram which shows the influence of / V.

Claims (1)

【特許請求の範囲】 【請求項1】 C:1.5 〜 3.5%,Si:1.5 %以下,
Mn: 1.2%以下,Cr:5.5 〜12.0%,Mo:2.0 〜
8.0 %,V:3.0 〜10.0%,Nb:0.6 〜7.0 %を含有
し、且つ下記(1) 式と(2) 式を満足し、 V+ 1.8Nb ≦ 7.5 C−6.0(%)…(1) 0.2 ≦ Nb/V ≦ 0.8 …(2) 残部Fe及び不可避的不純物よりなる圧延用ロール外層
材。
[Claims] [Claim 1] C: 1.5 to 3.5%, Si: 1.5% or less,
Mn: 1.2% or less, Cr: 5.5 to 12.0%, Mo: 2.0 to
It contains 8.0%, V: 3.0 to 10.0%, Nb: 0.6 to 7.0%, and satisfies the following formulas (1) and (2), V + 1.8Nb ≤ 7.5 C-6.0 (%) ... (1) 0.2 ≤ Nb / V ≤ 0.8 (2) An outer layer material for a rolling roll comprising the balance Fe and unavoidable impurities.
JP30383291A 1990-11-21 1991-10-24 Roll outer layer material for rolling Expired - Lifetime JP2715205B2 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
US08/050,394 US5316596A (en) 1991-09-12 1992-03-31 Roll shell material and centrifugal cast composite roll
KR1019930701420A KR960005598B1 (en) 1991-09-12 1992-03-31 Roll shell material and centrifugal cast composite roll
PCT/JP1992/000400 WO1993005192A1 (en) 1991-09-12 1992-03-31 Material of outer layer of roll for rolling and compound roll manufactured by centrifugal casting
EP92907591A EP0562114B1 (en) 1991-09-12 1992-03-31 Material of outer layer of roll for rolling and compound roll manufactured by centrifugal casting
DE69227504T DE69227504T2 (en) 1991-09-12 1992-03-31 MATERIAL FOR EXTERNAL LAYER OF A FORMING ROLLER AND COMPOSITE ROLLER PRODUCED BY SPINNING
ES92909738T ES2124728T3 (en) 1991-09-12 1992-05-14 MATERIAL FOR THE OUTER LAYER OF A LAMINATION CYLINDER AND COMPOSITE CYLINDER MANUFACTURED BY CENTRIFUGA FOUNDRY.
EP92909738A EP0559899B1 (en) 1991-09-12 1992-05-14 Material of outer layer of roll for rolling and compound roll manufactured by centrifugal casting
PCT/JP1992/000625 WO1993005193A1 (en) 1991-09-12 1992-05-14 Material of outer layer of roll for rolling and compound roll manufactured by centrifugal casting
CN 92103692 CN1032262C (en) 1991-09-12 1992-05-16 Outer material of roll and composite roll of centrifugal casting

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP31420790 1990-11-21
JP2-314207 1990-11-21

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JPH051350A true JPH051350A (en) 1993-01-08
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