JPH0513064A - Manufacture of electrode plate for alkaline storage battery - Google Patents
Manufacture of electrode plate for alkaline storage batteryInfo
- Publication number
- JPH0513064A JPH0513064A JP3161778A JP16177891A JPH0513064A JP H0513064 A JPH0513064 A JP H0513064A JP 3161778 A JP3161778 A JP 3161778A JP 16177891 A JP16177891 A JP 16177891A JP H0513064 A JPH0513064 A JP H0513064A
- Authority
- JP
- Japan
- Prior art keywords
- electrode plate
- conductive core
- active material
- core body
- collector terminal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Connection Of Batteries Or Terminals (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、アルカリ蓄電池用電極
板の製造方法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing an electrode plate for alkaline storage batteries.
【0002】[0002]
【従来の技術】従来、ニッケル−カドミウム蓄電池など
のアルカリ蓄電池に用いられる電極には、パンチングメ
タルなどを導電芯体として、ニッケル粉末を焼結して得
られる多孔性焼結基板にニッケル塩、カドミウム塩など
の溶液を含浸し、アルカリ処理することによって活物質
化する焼結式製法がある。また一方、導電芯体や金属繊
維焼結体、発砲ニッケルなどの三次元多孔金属板にペー
スト状の活物質を直接保持させる非焼結式製法がある。2. Description of the Related Art Conventionally, for electrodes used in alkaline storage batteries such as nickel-cadmium storage batteries, nickel salts and cadmium are deposited on a porous sintered substrate obtained by sintering nickel powder using a punching metal as a conductive core. There is a sintering method in which a solution such as salt is impregnated and treated with an alkali to make it an active material. On the other hand, there is a non-sintering manufacturing method in which a paste-like active material is directly held on a three-dimensional porous metal plate such as a conductive core, a metal fiber sintered body, or foamed nickel.
【0003】ところで、各電極への集電端子の取付方法
としては、図2に示すように電極の芯体1に予め集電端
子部2を設けて打ち抜く方法がある。しかし、この方法
によると集電端子部2を除いた芯体の一部3が不要とな
るため材料ロスであるとともに、集電端子部2を予め形
成して打ち抜く工程が、機種切り替えなどにより煩雑で
あり、生産性が低下するという欠点を有していた。Incidentally, as a method of attaching the collector terminal to each electrode, there is a method in which the collector terminal portion 2 is provided in advance on the core body 1 of the electrode as shown in FIG. However, according to this method, the part 3 of the core body excluding the collector terminal portion 2 is not required, which is a material loss, and the step of forming the collector terminal portion 2 in advance and punching it out is complicated by changing the model. Therefore, there is a drawback that productivity is lowered.
【0004】また、材料ロスをなくし、生産性を向上す
るために、電極板を所望の寸法に切断した後に、電極板
の活物質層の一部を剥離し、導電芯体面を露出させ、該
露出面に集電端子を載置し、集電端子の上面と集電端子
を載置した反対面とからなる一対の溶接極により電気溶
接で集電端子を溶接する方法がある。Further, in order to eliminate material loss and improve productivity, after cutting the electrode plate into a desired size, a part of the active material layer of the electrode plate is peeled off to expose the surface of the conductive core. There is a method of mounting a current collecting terminal on the exposed surface and welding the current collecting terminal by electric welding with a pair of welding electrodes composed of an upper surface of the current collecting terminal and an opposite surface on which the current collecting terminal is mounted.
【0005】しかし、この方法では、活物質層の剥離は
不十分になり、溶接極間に異物が残っている場合、水酸
化ニッケル、水酸化カドミウムなどの活物質及び、結着
剤などは、導電性が極めて乏しいので溶接極間に充分な
導通が得られず、スパークなどを起こし易いため溶接が
困難になる。そのため、生産効率及び溶接の信頼性が低
下するという欠点を有する。However, in this method, the peeling of the active material layer becomes insufficient, and when foreign matter remains between the welding electrodes, the active materials such as nickel hydroxide and cadmium hydroxide and the binder are Since the conductivity is extremely poor, sufficient conduction cannot be obtained between the welding electrodes, and sparks are likely to occur, which makes welding difficult. Therefore, there is a drawback that the production efficiency and the reliability of welding are reduced.
【0006】これらの欠点を解消するために、集電端子
の取付方法として特公昭54−31575号公報では、
陰、陽極板とこれら極板間にセパレーターを介挿してな
る電極体の上下の各端面にそれぞれ各所定極板の端縁を
突出させ、該端縁上に載置した表面に無数の凸部を有す
る有孔金属板からなる集電端子を、集電端子上に当接し
た一対の溶接極で電気溶接により固着する方法が提案さ
れている。In order to solve these drawbacks, Japanese Patent Publication No. 54-31575 discloses a method of attaching a collector terminal.
An edge of each predetermined electrode plate is projected on each of the upper and lower end faces of an electrode body formed by inserting a separator between the negative electrode plate and these electrode plates, and a myriad of convex portions are formed on the surface mounted on the edge. A method has been proposed in which a current collecting terminal made of a perforated metal plate having a hole is fixed by electric welding with a pair of welding electrodes abutting on the current collecting terminal.
【0007】しかしながら、この方法では集電端子の凸
部を極板端縁にくい込ませるので、陰、陽極板の短絡を
防止するために、1mm程度幅の活物質層を形成してい
ない端縁を設け、陰、陽極板をずらして捲回しなければ
ならない。そのため極板の体積エネルギー密度が低下す
るという欠点を有している。However, in this method, since the convex portion of the current collector terminal is hard to be embedded in the edge of the electrode plate, in order to prevent a short circuit between the shade and the anode plate, the edge without the active material layer having a width of about 1 mm is formed. And the negative and positive plates must be displaced and wound. Therefore, it has a drawback that the volume energy density of the electrode plate is lowered.
【0008】さらに、陰、陽極板をずらして捲回するこ
とにより、極板の端部に対極板と対向していない部分が
生じ、この部分の活物質が充分に反応しないという欠点
を有している。Further, when the negative and positive plates are shifted and wound, a part not facing the counter plate is formed at the end of the electrode plate, and the active material in this part does not react sufficiently. ing.
【0009】[0009]
【発明が解決しようとする課題】本発明は、上述の如き
問題点を解決し、コーティングした活物質の一部を除去
してその部分のエネルギー密度の低下を最小限にするこ
とによって、信頼性の高い溶接法を提供するものであ
る。SUMMARY OF THE INVENTION The present invention solves the problems as described above and removes a part of the coated active material to minimize the decrease in energy density of the part, thereby improving reliability. It provides a high welding method.
【0010】[0010]
【課題を解決するための手段】本発明によるアルカリ蓄
電池用電極板の製造方法は、導電芯体に活物質層を形成
した電極板の活物質層を導電芯体面に対して垂直方向の
超音波振動を加えて剥離し、導電芯体面を露出させ、前
記電極板の活物質層を剥離した部分に集電端子を載置
し、上部から超音波ホーンを押圧し、導電芯体面に対し
て水平方向の超音波振動を加えて集電端子を溶接するこ
とを特徴とするものである。A method for manufacturing an electrode plate for an alkaline storage battery according to the present invention is a method in which an active material layer of an electrode plate having an active material layer formed on a conductive core is subjected to ultrasonic waves in a direction perpendicular to the surface of the conductive core. Peel by applying vibration to expose the surface of the conductive core, place the collector terminal on the part of the electrode plate from which the active material layer has been separated, press the ultrasonic horn from the top, and place it horizontally against the surface of the conductive core. It is characterized in that the current collecting terminal is welded by applying ultrasonic vibration in the direction.
【0011】ここで、前記溶接時の超音波ホーンの押圧
が1.0×104Pa以上7.0×104Pa以下の加圧
力であることが好ましい。Here, it is preferable that the pressing force of the ultrasonic horn at the time of welding is from 1.0 × 10 4 Pa to 7.0 × 10 4 Pa.
【0012】さらに、前記集電端子を溶接した電極板の
反対面に耐アルカリ性の樹脂性粘着テープを貼り付ける
ことが好ましい。Further, it is preferable that an alkali resistant resin adhesive tape is attached to the opposite surface of the electrode plate to which the current collecting terminal is welded.
【0013】[0013]
【作用】活物質層を剥離した芯体面に集電端子を載置し
て抵抗溶接で集電端子を溶接する時、芯体面と集電端子
の間に異物が残っているとスパークなどを起こして溶接
不良となる場合がある。[Operation] When a current collector terminal is placed on the core body surface from which the active material layer has been peeled off and the current collector terminal is welded by resistance welding, if foreign matter remains between the core body surface and the current collector terminal, sparks or the like will occur. May result in poor welding.
【0014】発明者の種々の実験によれば、水平方向の
超音波振動による溶接法では溶接面に多少の夾雑物が残
っていても信頼性の高い溶接状態が得られることがわか
った。また、芯体裏面の活物質の剥離は不要なこと、そ
して、溶接面は出来るだけ高い活物質除去率とする事
が、良好な溶接状態を得るための要因であることがわか
った。この結果をうけて、溶接部の剥離方法を種々検討
した結果、垂直方向の超音波振動による活物質除去方法
が上述の条件を満足していることを見出した。According to various experiments conducted by the inventor, it has been found that the welding method using ultrasonic vibration in the horizontal direction can provide a highly reliable welding state even if some impurities remain on the welding surface. Further, it was found that the peeling of the active material on the back surface of the core body is not necessary and the removal rate of the active material on the welded surface is as high as possible, which is a factor for obtaining a good welded state. Based on these results, as a result of various studies on the peeling method of the welded portion, it was found that the active material removing method by ultrasonic vibration in the vertical direction satisfies the above conditions.
【0015】また、前記集電端子を溶接した電極板の反
対面に耐アルカリ性の樹脂製粘着テープを貼り付ける
と、粗れた活物質面がセパレーターを貫通したり、活物
質が脱落したりする事がないので、捲回の際の内部短絡
を防止する事が出来る。When an alkali-resistant resin adhesive tape is attached to the opposite surface of the electrode plate to which the current collecting terminal is welded, the rough active material surface may penetrate the separator or the active material may fall off. Since nothing happens, it is possible to prevent an internal short circuit during winding.
【0016】さらに、集電端子を押圧する超音波ホーン
の先端の加圧面(以下チップと省略する)の面積を集電
端子の面積よりも大きくすると、集電端子の端部が反り
返り、セパレーターを貫通して内部短絡を起こす恐れが
ない。Further, when the area of the pressing surface (hereinafter abbreviated as a chip) at the tip of the ultrasonic horn that presses the current collecting terminal is made larger than the area of the current collecting terminal, the end of the current collecting terminal warps and the separator is removed. There is no danger of penetrating and causing an internal short circuit.
【0017】[0017]
〔実験1〕酸化カドミウムを主成分とする活物質ペース
トをニッケルメッキを施した厚さ80μのパンチングメ
タルに塗着後、乾燥して公知の非焼結式カドミウム電極
板を得た。[Experiment 1] A known non-sintered cadmium electrode plate was obtained by applying an active material paste containing cadmium oxide as a main component to a nickel-plated punching metal having a thickness of 80 μm and drying it.
【0018】この電極板の片面の活物質層を剥離する方
法として、以下の方法を行った。
1.電極板に対して垂直方向の超音波振動を加える
2.電極板に対して水平方向の超音波振動を加える
3.先端を刃状にしたカギ型の専用治具で削る
4.サンドブラスト
これらの方法によって電極板の活物質層を剥離した部分
に集電端子を載置し、上部から超音波ホーンを押圧し、
該導電芯体面に対し水平方向の超音波振動を加える事に
より集電端子を溶接した時の結果を表1に示す。As a method for peeling the active material layer on one side of this electrode plate, the following method was performed. 1. 1. Apply ultrasonic vibration in the vertical direction to the electrode plate 2. Horizontal ultrasonic vibration is applied to the electrode plate. 3. Use a key-shaped special jig with a blade-shaped tip to cut it. SandblastingThe current collector terminal is placed on the part where the active material layer of the electrode plate is peeled off by these methods, and the ultrasonic horn is pressed from above,
Table 1 shows the results of welding the current collector terminal by applying ultrasonic vibration in the horizontal direction to the surface of the conductive core.
【0019】[0019]
【表1】 [Table 1]
【0020】尚、ワークタイムは、上記1〜4の方法で
活物質層を剥離した時の活物質除去率がそれぞれ99,
70,90及び85%になるまでの時間である。しか
し、サンドブラストによるものでは0.5秒以上行うと
芯体に用いたパンチングメタルが著しく破損されてしま
う。The work time is such that the removal rate of the active material when the active material layer is peeled off by the above methods 1 to 4 is 99, respectively.
Time to reach 70, 90 and 85%. However, when sand blasting is performed for 0.5 seconds or more, the punching metal used for the core body is significantly damaged.
【0021】以上の結果より明らかなように、活物質層
や芯体を破損すること無しに効率よく剥離するには、電
極板に対して垂直方向の超音波振動を加えることが効果
的であるとわかる。As is clear from the above results, it is effective to apply ultrasonic vibration in the vertical direction to the electrode plate in order to efficiently separate the active material layer and the core without damaging them. I understand.
【0022】〔実験2〕前記の非焼結式カドミウム電極
板に導電芯体に対して垂直方向の周波数20kHz、振
幅100μの超音波振動を0.2秒間加え、活物質層を
片面のみ剥離した。尚、活物質層を剥離した面積は4m
m×8mmであった。[Experiment 2] Ultrasonic vibration having a frequency of 20 kHz and an amplitude of 100 μ in the direction perpendicular to the conductive core was applied to the non-sintered cadmium electrode plate for 0.2 seconds to peel off the active material layer on only one side. . The area where the active material layer is peeled off is 4 m
It was m × 8 mm.
【0023】次に3mm×20mmのニッケルメッキし
た厚さ200μの平板である集電端子を活物質層を一部
剥離した電極板の上に載置し、3.5mm×7mmのチ
ップにより0.5×104Pa〜9.0×104Paの間
で圧力を変化させて、導電芯体に対して水平方向の周波
数20kHz、振幅60μの超音波振動を0.5秒間加
え、前記の集電端子を溶接した。この時の溶接部の引っ
張り強度を調べた結果を図1に示す。尚、図中の値は1
00個の平均値である。Next, a current collecting terminal, which is a nickel-plated flat plate having a thickness of 200 μ and having a size of 3 mm × 20 mm, is placed on the electrode plate from which a part of the active material layer has been peeled off. The pressure was changed between 5 × 10 4 Pa and 9.0 × 10 4 Pa, and ultrasonic vibration with a horizontal frequency of 20 kHz and an amplitude of 60 μ was applied to the conductive core for 0.5 seconds, and the above-mentioned collection was performed. Welded the electrical terminals. The results of examining the tensile strength of the welded portion at this time are shown in FIG. The value in the figure is 1
It is an average value of 00 pieces.
【0024】図1より明らかなように、1.0×104
Pa未満の加圧力では溶接面間の結着力が弱く、1N以
上の引っ張り強度が得られない。また、7.0×104
Paより大きな加圧力では、芯体であるパンチングメタ
ルが破壊されるため急激に引っ張り強度が低下する。し
たがって、集電端子を溶接する際の加圧力は、1.0×
104Pa以上7.0×104Pa以下が望ましい。As is clear from FIG. 1, 1.0 × 10 4
If the applied pressure is less than Pa, the binding force between the welding surfaces is weak and a tensile strength of 1 N or more cannot be obtained. In addition, 7.0 × 10 4
When the applied pressure is larger than Pa, the punching metal that is the core body is broken, so that the tensile strength is rapidly reduced. Therefore, the welding pressure when welding the current collector terminal is 1.0 ×
It is desirable that the pressure is 10 4 Pa or more and 7.0 × 10 4 Pa or less.
【0025】〔実験3〕前記の非焼結式陰極板に垂直方
向の周波数20kHz、振幅100μの超音波振動を
0.2秒間加え、活物質層を片面のみ剥離した。尚、活
物質層を剥離した面積は4mm×8mmである。[Experiment 3] Ultrasonic vibration with a vertical frequency of 20 kHz and an amplitude of 100 μ was applied to the non-sintered cathode plate for 0.2 seconds to peel off the active material layer on only one side. The area where the active material layer was peeled off was 4 mm × 8 mm.
【0026】次に3mm×20mmのニッケルメッキし
た厚さ200μの平板である集電端子を活物質層を一部
剥離した電極板の上に載置し、3.5mm×7mmのチ
ップにより3.5×104Paの圧力で加圧しながら、
電極板に対して水平方向の周波数20kHz、振幅60
μの超音波振動を0.5秒間加え、前記集電端子を溶接
した。Next, a 3 mm × 20 mm nickel-plated 200 μm-thick flat collector terminal was placed on the electrode plate from which the active material layer had been partially peeled off, and a 3.5 mm × 7 mm chip was used to make a 3. While pressurizing with a pressure of 5 × 10 4 Pa,
Horizontal frequency of 20 kHz to electrode plate, amplitude 60
Ultrasonic vibration of μ was applied for 0.5 seconds to weld the current collecting terminal.
【0027】このようにして得られた電極板の集電端子
の溶接した反対面に耐アルカリ性の樹脂製粘着テープを
貼り付け、公知のニッケル極板と、ナイロン不織布セパ
レーターと共に捲回し、電池Aを得た。The electrode plate thus obtained was attached with an alkali-resistant resin adhesive tape on the opposite side of the current collector terminal to which it was welded, and was wound together with a known nickel electrode plate and a nylon non-woven fabric separator to form a battery A. Obtained.
【0028】また比較として、樹脂製粘着テープを貼り
付けていない電極板を用いる以外は上記方法と同様にし
て、電池Bを得た。For comparison, a battery B was obtained in the same manner as above except that an electrode plate without a resin adhesive tape was used.
【0029】この電池A及びBの内部短絡発生率の結果
を表2に示す。尚、サンプル数は各500個行った。Table 2 shows the results of the internal short circuit occurrence rates of the batteries A and B. The number of samples was 500 each.
【0030】[0030]
【表2】 [Table 2]
【0031】表2の結果より明らかなように、電極板の
集電端子を溶接した反対面に耐アルカリ性の樹脂製粘着
テープを貼り付けた電極板を用いて作製した電池Aは、
電池Bよりも内部短絡発生率が抑えられ一層の効果があ
ることが判る。As is clear from the results shown in Table 2, the battery A produced by using the electrode plate having the alkali-resistant resin adhesive tape adhered to the opposite surface of the electrode plate to which the collector terminal was welded was
It can be seen that the internal short-circuit occurrence rate is suppressed more than that of the battery B, which is more effective.
【0032】[0032]
【発明の効果】本発明の製造方法では、垂直方向の超音
波振動による活物質除去により、集電端子の溶接が充分
にでき、また溶接強度にも優れた電極板が得られる。ま
た、生産性が高く、不良発生率の減少したアルカリ蓄電
池用電極板を提供する事ができ、その工業的価値は極め
て大である。According to the manufacturing method of the present invention, by removing the active material by ultrasonic vibration in the vertical direction, the current collector terminal can be sufficiently welded and an electrode plate excellent in welding strength can be obtained. Further, it is possible to provide an electrode plate for an alkaline storage battery, which has high productivity and a reduced incidence of defects, and its industrial value is extremely large.
【図1】集電端子の溶接時の加圧力と引っ張り強度の関
係を示す図である。FIG. 1 is a diagram showing a relationship between a pressing force and a tensile strength during welding of a collector terminal.
【図2】従来方法による電極板の打ち抜き図である。FIG. 2 is a punched view of an electrode plate according to a conventional method.
フロントページの続き (72)発明者 樋口 正樹 守口市京阪本通2丁目18番地 三洋電機株 式会社内Continued front page (72) Inventor Masaki Higuchi 2-18 Keihanhondori, Moriguchi-shi Sanyo Electric Co., Ltd. Inside the company
Claims (3)
製造方法において、活物質層を導電芯体面に対して垂直
方向の超音波振動を加えて剥離し、導電芯体面を露出さ
せ、前記電極板の活物質層を剥離した部分に集電端子を
載置し、上部から超音波ホーンを押圧し、導電芯体面に
対して水平方向の超音波振動を加えて集電端子を溶接す
ることを特徴とするアルカリ蓄電池用電極板の製造方
法。1. A method of manufacturing an electrode plate for forming an active material layer on a conductive core body, wherein the active material layer is peeled by applying ultrasonic vibration in a direction perpendicular to the conductive core body surface to expose the conductive core body surface. , Place the collector terminal on the part of the electrode plate where the active material layer has been peeled off, press the ultrasonic horn from the top, and apply ultrasonic vibration in the horizontal direction to the conductive core surface to weld the collector terminal. A method of manufacturing an electrode plate for an alkaline storage battery, comprising:
0×104Pa以上7.0×104Pa以下の加圧力であ
ることを特徴とする請求項1記載のアルカリ蓄電池用電
極板の製造方法。2. The pressing force of the ultrasonic horn during the welding is 1.
The method for producing an electrode plate for an alkaline storage battery according to claim 1, wherein the applied pressure is 0 × 10 4 Pa or more and 7.0 × 10 4 Pa or less.
に耐アルカリ性の樹脂性粘着テープを貼り付けることを
特徴とする請求項1記載のアルカリ蓄電池用電極板の製
造方法。3. The method for manufacturing an electrode plate for an alkaline storage battery according to claim 1, wherein an alkali resistant resin adhesive tape is attached to the opposite surface of the electrode plate to which the current collecting terminal is welded.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3161778A JPH0513064A (en) | 1991-07-02 | 1991-07-02 | Manufacture of electrode plate for alkaline storage battery |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3161778A JPH0513064A (en) | 1991-07-02 | 1991-07-02 | Manufacture of electrode plate for alkaline storage battery |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH0513064A true JPH0513064A (en) | 1993-01-22 |
Family
ID=15741731
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP3161778A Pending JPH0513064A (en) | 1991-07-02 | 1991-07-02 | Manufacture of electrode plate for alkaline storage battery |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0513064A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6298530B1 (en) | 1997-08-08 | 2001-10-09 | Duracell Inc. | Reinforced coiled electrode assemblies and methods of producing same |
WO2009133689A1 (en) * | 2008-04-28 | 2009-11-05 | 株式会社フジクラ | Manufacturing method for photoelectric transducer, photoelectric transducer manufactured thereby, manufacturing method for photoelectric transducer module, and photoelectric transducer module manufactured thereby |
US8530084B2 (en) | 2008-06-25 | 2013-09-10 | Panasonic Corporation | Electrode structure for non-aqueous electrolyte secondary battery, method for producing the same, and non-aqueous electrolyte secondary battery |
US11923498B2 (en) | 2014-01-17 | 2024-03-05 | Ningde Amperex Technology Limited | Lithium-ion battery having desirable safety performance |
US12009483B2 (en) | 2015-08-31 | 2024-06-11 | Ningde Amperex Technology Limited | Secondary battery cell and winding formation system thereof |
-
1991
- 1991-07-02 JP JP3161778A patent/JPH0513064A/en active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6298530B1 (en) | 1997-08-08 | 2001-10-09 | Duracell Inc. | Reinforced coiled electrode assemblies and methods of producing same |
WO2009133689A1 (en) * | 2008-04-28 | 2009-11-05 | 株式会社フジクラ | Manufacturing method for photoelectric transducer, photoelectric transducer manufactured thereby, manufacturing method for photoelectric transducer module, and photoelectric transducer module manufactured thereby |
JP2009289736A (en) * | 2008-04-28 | 2009-12-10 | Fujikura Ltd | Manufacturing method for photoelectric transducer, photoelectric transducer manufactured thereby, manufacturing method for photoelectric transducer module, and photoelectric transducer module manufactured thereby |
US8530084B2 (en) | 2008-06-25 | 2013-09-10 | Panasonic Corporation | Electrode structure for non-aqueous electrolyte secondary battery, method for producing the same, and non-aqueous electrolyte secondary battery |
US11923498B2 (en) | 2014-01-17 | 2024-03-05 | Ningde Amperex Technology Limited | Lithium-ion battery having desirable safety performance |
US12009483B2 (en) | 2015-08-31 | 2024-06-11 | Ningde Amperex Technology Limited | Secondary battery cell and winding formation system thereof |
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