JPH0511499A - Developing device - Google Patents

Developing device

Info

Publication number
JPH0511499A
JPH0511499A JP3012392A JP1239291A JPH0511499A JP H0511499 A JPH0511499 A JP H0511499A JP 3012392 A JP3012392 A JP 3012392A JP 1239291 A JP1239291 A JP 1239291A JP H0511499 A JPH0511499 A JP H0511499A
Authority
JP
Japan
Prior art keywords
toner
conveying member
image
sheets
charge amount
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3012392A
Other languages
Japanese (ja)
Inventor
Toshiki Minamitani
俊樹 南谷
Chiharu Mochizuki
千春 望月
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ricoh Co Ltd
Original Assignee
Ricoh Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ricoh Co Ltd filed Critical Ricoh Co Ltd
Priority to JP3012392A priority Critical patent/JPH0511499A/en
Publication of JPH0511499A publication Critical patent/JPH0511499A/en
Pending legal-status Critical Current

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  • Dry Development In Electrophotography (AREA)
  • Developing Agents For Electrophotography (AREA)

Abstract

PURPOSE:To make an image free from abnormality even after continuous copying and to obtain image quality comparable to that in the early stage of copying by impressing bias on a toner feeding member surfacecoated with a specified fluorine compd. so that the member has higher positive potential than a toner conveying member. CONSTITUTION:A developing device is fitted with a toner conveying member, a toner layer thickness regulating member and a toner feeding member freely rotatably supported while in contact with the toner conveying member and used for feeding a toner onto the conveying member. The surface of the toner feeding member is coated with at least one kind of arom. fluorine compd. selected among compds. represented by formulae I, II, etc., and bias is impressed on the toner feeding member so that the member has higher positive potential than the toner conveying member by 0-500V. In the formulae I, II each of R1-R4 is H, Cl, etc., Rf is CnF2n+1 or OCnF2n+1 and n is a positive integer. In the case of negative potential, the toner is not satisfactorily shifted onto the conveying member. In the case of >=+500V, toner filming is caused on the conveying member and ground fog is caused on an image.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、一成分系現像装置に関
する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a one-component developing device.

【0002】[0002]

【従来の技術】電子写真や静電記録などで採用される乾
式現像方式には、トナー及びキャリアからなる二成分系
現像剤を用いる方式と、キャリアを含まない一成分系現
像剤を用いる方式がある。前者の方式には、比較的安定
して良好な画像が得られるが、キャリアの劣化並びにト
ナーとキャリアとの混合比の変動が発生しやすいことか
ら長期間に亘って一定の品質が得られにくく、また、装
置の維持管理性やコンパクト化に難点がある。そこで、
こうした欠点を有しない後者の一成分系現像剤を用いる
方式が注目されるようになっている。ところで、この方
式においては、通常少なくとも一つのトナー搬送部材に
よってトナー(現像剤)を搬送し、かつ搬送されたトナ
ーによって潜像担持体に形成された静電潜像を可視像化
する手段がとられているが、その際、トナー搬送部材表
面を搬送されるトナーの層厚は極力薄くしなければなら
ないとされている。このことは二成分系現像剤であって
もキャリアが非常に小径なものを用いる場合にも当ては
まることであり、また、特に、一成分系現像剤を使用し
そのトナーとして電気抵抗の高いものを用いたときは、
現像装置によってこのトナーを帯電させる必要があるた
め、トナー層厚は著しく薄くされなければならない。こ
の層厚が厚いとトナー層の表面近くだけが帯電し、トナ
ー層全体が均一に帯電しにくくなるからである。
2. Description of the Related Art Dry developing methods used in electrophotography and electrostatic recording include a method using a two-component developer composed of toner and carrier and a method using a one-component developer containing no carrier. is there. The former method can obtain a relatively stable and good image, but it is difficult to obtain a constant quality for a long period of time because carrier deterioration and variation in the mixing ratio of toner and carrier are likely to occur. Moreover, there is a problem in maintenance and compactness of the device. Therefore,
The latter method using a one-component developer, which does not have such drawbacks, has been receiving attention. By the way, in this system, there is usually a means for carrying toner (developer) by at least one toner carrying member and for visualizing the electrostatic latent image formed on the latent image carrier by the carried toner. However, at that time, it is said that the layer thickness of the toner conveyed on the surface of the toner conveying member must be made as thin as possible. This is true even when using a two-component developer whose carrier has a very small diameter. In particular, when a one-component developer is used and its toner has high electric resistance, When used,
Since this toner needs to be charged by the developing device, the toner layer thickness must be made extremely thin. This is because if the layer is thick, only the surface of the toner layer is charged, and it becomes difficult to uniformly charge the entire toner layer.

【0003】かかる要請からトナー搬送部材上のトナー
層厚を規制する手段(トナー層厚規制手段)にいろいろ
な方法が提案されており、代表例としては、ドクターブ
レードを用い、このブレードをトナー搬送部材に対置さ
せ、これによりトナー搬送部材表面の搬送されるトナー
を押圧部材(ドクターブレード)で押さえつけてトナー
層厚を制御するものである。しかしながら、これだけで
はトナーがトナー搬送部材に均一に搬送されにくい。そ
のため、トナー搬送部材に接触しつつ自在に回転可能に
支持されており、トナーをトナー搬送部材上に供給する
トナー供給手段を有する現像装置が提案されているが、
現像を連続して行うと、トナーをトナー搬送部材へ供給
する能力が低下し、画像濃度の低下を招くようになる。
その原因としては、トナーホッパー内からトナー供給部
材へのトナー補給性の低下、さらにはトナー供給部材か
らトナー搬送部材へのトナー補給性の低下の2つがあげ
られる。上記欠点の解決のために、トナーに界面活性物
質及び流動性改質剤などの添加を試みたが、まだ十分に
解決されていない。
In response to such a request, various methods have been proposed as means for controlling the toner layer thickness on the toner carrying member (toner layer thickness controlling means). As a typical example, a doctor blade is used, and this blade is used for carrying toner. The toner layer thickness is controlled by placing the toner on the surface of the toner conveying member and pressing the conveyed toner on the surface of the toner conveying member with a pressing member (doctor blade). However, with this alone, it is difficult to uniformly convey the toner to the toner conveying member. Therefore, there has been proposed a developing device that is rotatably supported while being in contact with the toner conveying member and has a toner supply unit that supplies the toner onto the toner conveying member.
When the development is continuously performed, the ability to supply the toner to the toner conveying member is lowered, and the image density is lowered.
There are two causes for this: deterioration of the toner replenishment property from the toner hopper to the toner supply member, and further deterioration of the toner replenishment property from the toner supply member to the toner transport member. Attempts have been made to add a surface-active substance and a fluidity modifier to the toner in order to solve the above-mentioned drawbacks, but they have not been sufficiently solved yet.

【0004】[0004]

【発明が解決しようとする課題】本発明の目的は、トナ
ー搬送部材上にトナー薄層を形成させ現像を行い、良質
な画像を得るようにした電子写真における一成分現像方
式において、連続複写後も画像に異常がみられず、初期
と同等の画像品質が得られる現像方式を提供することで
ある。
SUMMARY OF THE INVENTION It is an object of the present invention to form a thin toner layer on a toner conveying member for development to obtain a high quality image in a one-component developing system in electrophotography, after continuous copying. Is to provide a developing method in which no image abnormality is observed and the image quality equivalent to the initial stage is obtained.

【0005】[0005]

【課題を解決するための手段】本発明者等が鋭意検討し
たところ、前記現像装置に正帯電性トナーを使用する場
合、前記欠点は、特定のフッ素化合物で少なくともトナ
ー供給部材表面を被覆し、前記トナー供給部材に前記ト
ナー搬送部材より0〜500V正電位のバイアスを印加
させた現像装置を使用することで解決し得ることを見出
し、本発明に至った。すなわち、本発明は、少なくとも
トナー搬送部材、トナー層厚規制部材を有し、トナー搬
送部材に接触しつつ自在に回転可能に支持されトナーを
前記搬送部材上に供給するトナー供給部材とを有する現
像装置において、少なくとも前記トナー供給部材の表面
を前記[化1]〜[化5]の一般式で表わされる化合物
の群から選択された少なくとも一種の芳香族フッ素化合
物で被覆し、前記トナー供給部材に前記トナー搬送部材
よりも0〜500V正電位のバイアスを印加することを
特徴とする正帯電性トナー用現像装置である。前記解決
の原因は定かではないが、トナー供給部材を上記化合物
で被覆することにより、現像部のトナータンク内の正帯
電性トナーがトナー供給部材に円滑に補給され、さらに
該トナー供給部材に前記のトナー搬送部材より0〜50
0V正電位のバイアスを印加させることにより、トナー
供給部材上のトナーが滞留することなく、円滑にトナー
搬送部材上に供給され、現像装置内のトナーの流れがス
ムーズになり、トナー搬送部材上のトナー層厚が常に均
一に保てるようになるためと考えられる。本発明で使用
される前記一般式で表わされる芳香族フッ素化合物とし
ては、以下のようなものがある。
Means for Solving the Problems The inventors of the present invention have made extensive studies and found that when a positively chargeable toner is used in the developing device, at least the surface of the toner supply member is coated with a specific fluorine compound. The inventors have found that the problem can be solved by using a developing device in which a bias of 0 to 500 V positive potential is applied to the toner supply member from the toner transport member, and have reached the present invention. That is, the present invention is a developing device including at least a toner transport member and a toner layer thickness regulating member, and a toner supply member that is rotatably supported while being in contact with the toner transport member and that supplies toner onto the transport member. In the apparatus, at least the surface of the toner supply member is coated with at least one aromatic fluorine compound selected from the group of compounds represented by the general formulas [Chem. The positive charging toner developing device is characterized in that a bias of 0 to 500 V positive potential is applied to the toner conveying member. Although the cause of the solution is not clear, by coating the toner supply member with the above compound, the positively chargeable toner in the toner tank of the developing section is smoothly replenished to the toner supply member, and the toner supply member is 0 to 50 from the toner transport member
By applying a bias of 0 V positive potential, the toner on the toner supply member is smoothly accumulated on the toner conveying member without accumulating, the toner flow in the developing device becomes smooth, and the toner on the toner conveying member is smoothed. It is considered that this is because the toner layer thickness can always be kept uniform. Examples of the aromatic fluorine compound represented by the above general formula used in the present invention are as follows.

【0006】[0006]

【化7】 [Chemical 7]

【0007】[0007]

【化8】 [Chemical 8]

【0008】[0008]

【化9】 [Chemical 9]

【0009】[0009]

【化10】 [Chemical 10]

【化11】 [Chemical 11]

【化12】 [Chemical 12]

【0010】 [0010]

【0011】 [0011]

【0012】次に本発明で使用する前記[化6]の単量
体の重合体及び共重合体の代表的合成例を記す。なお、
この合計例に記載の平均分子量(Mw)はゲル・パーメ
ーション・クロマトグラフィー法によって測定した値で
ある。即ち、これらの各値はすべてゲル・パーメーショ
ン・クロマトグラフィーによって以下に記す条件で測定
された値である。温度25℃において、溶媒(テトラヒ
ドロフラン)を毎分1mlの流速で流し、濃度0.4g
/dlのテトラヒドロフラン試料溶液を試料重量として
8mg注入し、測定を行う。試料の分子量測定にあたっ
ては、該試料の有する分子量分布が、数種の単分散ポリ
スチレン標準試料により、作成された検量線の分子量の
対数とカウント数が直線となる範囲内に包含される測定
条件を選択する。また、本測定にあたり信頼性は上述の
測定条件で行ったNBS706ポリスチレン標準試料
(Mw=28.8×104、Mn=13.7×104、M
w/Mn=2.11)のMw/Mn=2.11±0.1
0となることにより確認する。 [合成例1] 例示化合物[化6]−(1)の合成 容量21の4つ口フラスコに温度計、撹拌機、冷却管を
取り付け、オイルバスで温度制御する重合装置にトルエ
ン500gをとり、85℃に加温した。下記の構造式で
示されるアクリル酸フルオロイソフタロニトリルのモノ
マー500gとアゾビスブチロニトリル(AIBN)8
gを混合溶解させたモノマーを滴下ロートにより1.5
時間にわたり滴下した。モノマー滴下終了後85℃で6
時間撹拌し重合を終了した。次に重合物をエタノール/
ヘキサン(1/2)溶液で生成後乾燥し、重合物を作製
した。重合率92%、重量平均分子量Mw14000で
あった。
Next, typical synthesis examples of polymers and copolymers of the above-mentioned [Chemical Formula 6] used in the present invention will be described. In addition,
The average molecular weight (Mw) described in this total example is a value measured by the gel permeation chromatography method. That is, each of these values is a value measured by gel permeation chromatography under the conditions described below. At a temperature of 25 ° C., a solvent (tetrahydrofuran) is caused to flow at a flow rate of 1 ml / min to give a concentration of 0.4 g.
8 mg of a tetrahydrofuran sample solution of / dl is injected as a sample weight, and measurement is performed. In measuring the molecular weight of a sample, the molecular weight distribution possessed by the sample should be set within a range in which the logarithm of the molecular weight and the count number of the calibration curve made by several kinds of monodisperse polystyrene standard samples fall within a linear range. select. In addition, in this measurement, the reliability was determined by the NBS706 polystyrene standard sample (Mw = 28.8 × 10 4 , Mn = 13.7 × 10 4 , M
Mw / Mn = 2.11 ± 0.1 of w / Mn = 2.11)
Confirm by setting to 0. [Synthesis Example 1] A thermometer, a stirrer, and a cooling pipe were attached to a four-necked flask having a synthesis capacity of 21 for exemplified compound [Chemical Formula 6]-(1), and 500 g of toluene was placed in a polymerization apparatus whose temperature was controlled by an oil bath. Warmed to 85 ° C. 500 g of a monomer of fluoroisophthalonitrile acrylate represented by the following structural formula and azobisbutyronitrile (AIBN) 8
1.5 g of the mixed and dissolved monomer was added by a dropping funnel to 1.5.
Dropped over time. 6 at 85 ° C after completion of monomer dropping
Polymerization was completed by stirring for a period of time. Next, the polymer is ethanol /
After being formed with a hexane (1/2) solution, it was dried to prepare a polymer. The polymerization rate was 92%, and the weight average molecular weight was Mw 14,000.

【0013】[0013]

【化13】 [合成例2] 例示化合物[化6]−(2)の合成 容量2lの4つ口フラスコに温度計、撹拌機、冷却管を
取り付け、オイルバスで温度制御する重合装置にトルエ
ン500gをとり、85℃に加温した。合成例1のアク
リル酸フルオロイソフタロニトリルのモノマー150g
と2エチルヘキシルアクリレート(2EHA)350g
とアゾビスブチロニトリル(AIBN)10gを混合溶
解させたモノマーを滴下ロートにより1.5時間にわた
り滴下した。モノマー滴下終了後85℃で6時間撹拌し
重合を終了した。次に重合物をエタノール/ヘキサン
(1/2)溶液で精製後乾燥し、重合物を作製した。重
合率90%、重量平均分子量Mwは12000であっ
た。 [合成例3] 例示化合物[化6]−(3)の合成 容量2lの4つ口フラスコに温度計、撹拌機、冷却管を
取り付け、オイルバスで温度制御する重合装置にトルエ
ン500gをとり、85℃に加温した。合成例1のアク
リル酸フルオロイソフタロニトリルのモノマー100g
とスチレン400gとアゾビスブチロニトリル(AIB
N)10gを混合溶解させたモノマーを滴下ロートによ
り1.5時間にわたり滴下した。モノマー滴下終了後8
5℃で6時間撹拌し重合を終了した。次に重合物をエタ
ノール/ヘキサン(1/2)溶液で精製後乾燥し、重合
物を作製した。重合率94%、重量平均分子量Mw15
000であった。 [合成例4] 例示化合物[化6]−(6)の合成 容量2lの4つ口フラスコに温度計、撹拌機、冷却管を
取り付け、オイルバスで温度制御する重合装置にトルエ
ン500gをとり、85℃に加温した。下記の構造式で
示されるメタクリル酸フルオロイソフタロニトリルのモ
ノマー500gとアゾビスブチロニトリル(AIBN)
8gを混合溶解させたモノマーを滴下ロートにより1.
5時間にわたり滴下した。モノマー滴下終了後85℃で
6時間撹拌し重合を終了した。次に重合物をエタノール
/ヘキサン(1/2)溶液で精製後乾燥し、重合物を作
製した。重合率92%、重量平均分子量Mw16500
であった。
[Chemical 13] [Synthesis Example 2] Synthesis of Exemplified Compound [Chemical Formula 6]-(2) A thermometer, a stirrer, and a cooling pipe were attached to a four-necked flask having a capacity of 2 liters, and 500 g of toluene was placed in a polymerization apparatus whose temperature was controlled by an oil bath. Warmed to 85 ° C. 150 g of fluoroisophthalonitrile acrylate monomer of Synthesis Example 1
And 2 ethylhexyl acrylate (2EHA) 350g
And 10 g of azobisbutyronitrile (AIBN) were mixed and dissolved, and the monomer was added dropwise by a dropping funnel over 1.5 hours. After completion of dropping the monomer, the mixture was stirred at 85 ° C. for 6 hours to complete the polymerization. Next, the polymer was purified with an ethanol / hexane (1/2) solution and then dried to prepare a polymer. The polymerization rate was 90%, and the weight average molecular weight Mw was 12,000. [Synthesis Example 3] Synthesis of Exemplified Compound [Chemical Formula 6]-(3) A thermometer, a stirrer, and a cooling pipe were attached to a four-necked flask having a capacity of 2 liters, and 500 g of toluene was placed in a polymerization apparatus whose temperature was controlled by an oil bath. Warmed to 85 ° C. 100 g of fluoroisophthalonitrile acrylate monomer of Synthesis Example 1
And styrene 400 g and azobisbutyronitrile (AIB
N) 10 g of a mixed and dissolved monomer was added dropwise using a dropping funnel over 1.5 hours. 8 after completion of monomer dropping
Polymerization was completed by stirring at 5 ° C. for 6 hours. Next, the polymer was purified with an ethanol / hexane (1/2) solution and then dried to prepare a polymer. Polymerization rate 94%, weight average molecular weight Mw15
It was 000. [Synthesis Example 4] Synthesis of Exemplified Compound [Chemical Formula 6]-(6) A thermometer, a stirrer, and a cooling pipe were attached to a four-necked flask having a capacity of 2 l, and 500 g of toluene was placed in a polymerization apparatus whose temperature was controlled by an oil bath. Warmed to 85 ° C. 500 g of fluoroisophthalonitrile methacrylate monomer represented by the following structural formula and azobisbutyronitrile (AIBN)
The monomer obtained by mixing and dissolving 8 g was added with a dropping funnel to 1.
It was added dropwise over 5 hours. After completion of dropping the monomer, the mixture was stirred at 85 ° C. for 6 hours to complete the polymerization. Next, the polymer was purified with an ethanol / hexane (1/2) solution and then dried to prepare a polymer. Polymerization rate 92%, weight average molecular weight Mw16500
Met.

【0014】[0014]

【化14】 [合成例5] 例示化合物[化6]−(7)の合成 容量2lの4つ口フラスコに温度計、撹拌機、冷却管を
取り付け、オイルバスで温度制御する重合装置にトルエ
ン500gをとり、85℃に加温した。合成例4のメタ
クリル酸フルオロイソフタロニトリルのモノマー150
gと2エチルヘキシルアクリレート(2EHA)350
gとアゾビスブチロニトリル(AIBN)10gを混合
溶解させたモノマーを滴下ロートにより1.5時間にわ
たり滴下した。モノマー滴下終了後85℃で6時間撹拌
し重合を終了した。次に重合物をタノール/ヘキサン
(1/2)溶液で精製後乾燥し、重合物を作製した。重
合率88%、重量平均分子量Mwは13500であっ
た。本発明において荷電制御剤として使用される前記一
般式で示される単量体の重合体または該単量体とビニル
系単量体との共重合体を含有することを特徴とするもの
で、樹脂分として上記のものを単独で使用してもよい
が、他の相溶性を有する樹脂と併用してよい。例えば、
ポリスチレン、ポリp−クロロスチレン、ポリビニルト
ルエンなどのスチレン及びその置換体の単重合体;スチ
レン−p−クロロスチレン共重合体、スチレン−プロピ
レン共重合体、スチレン−ビニルトルエン共重合体、ス
チレン−ビニルナフタリン共重合体、スチレン−アクリ
ル酸メチル共重合体、スチレン−アクリル酸エチル共重
合体、スチレン−アクリル酸ブチル共重合体、スチレン
−アクリル酸オクチル共重合体、スチレン−メタクリル
酸メチル共重合体、スチレン−メタクリル酸エチル共重
合体、スチレン−メタクリル酸ブチル共重合体、スチレ
ン−α−クロルメタクリル酸メチル共重合体、スチレン
−アクリロニトリル共重合体、スチレン−ビニルメチル
エーテル共重合体、スチレン−ビニルエーテル共重合
体、スチレン−ビニルメチルケトン共重合体、スチレン
−ブタジエン共重合体、スチレン−イソプレン共重合
体、スチレン−アクリロニトリル−インデン共重合体、
スチレン−マレイン酸共重合体、スチレン−マレイン酸
エステル共重合体などのスチレン系共重合体;ポリメチ
ルメタクリレート、ポリブチルメタクリレート、ポリ塩
化ビニル、ポリ酢酸ビニル、ポリエチレン、ポリプロピ
レン、ポリエステル、ポリウレタン、ポリアミド、エポ
キシ樹脂、ポリビニルブチラール、ポリアクリル酸樹
脂、ロジン、変性ロジン、テルペン樹脂、フェノール樹
脂、脂肪族又は脂環族炭化水素樹脂、芳香族系石油樹
脂、塩素化パラフィン、パラフィンワックスなどが挙げ
られ、単独あるいは混合して使用できる。
[Chemical 14] [Synthesis Example 5] Synthesis of Exemplified Compound [Chemical Formula 6]-(7) A thermometer, a stirrer, and a cooling pipe were attached to a four-necked flask having a capacity of 2 l, and 500 g of toluene was placed in a polymerization apparatus whose temperature was controlled by an oil bath. Warmed to 85 ° C. Monomer 150 of Fluoroisophthalonitrile Methacrylate of Synthesis Example 4
g and 2 ethylhexyl acrylate (2EHA) 350
and 10 g of azobisbutyronitrile (AIBN) were mixed and dissolved, and a monomer was added dropwise with the dropping funnel over 1.5 hours. After completion of dropping the monomer, the mixture was stirred at 85 ° C. for 6 hours to complete the polymerization. Next, the polymer was purified with a tanol / hexane (1/2) solution and then dried to prepare a polymer. The polymerization rate was 88% and the weight average molecular weight Mw was 13,500. A resin characterized by containing a polymer of a monomer represented by the above general formula or a copolymer of the monomer and a vinyl monomer used as a charge control agent in the present invention. The above may be used alone as a component, but may be used in combination with another resin having compatibility. For example,
Polystyrene, homopolymers of styrene such as poly (p-chlorostyrene) and polyvinyltoluene, and their substitution products; styrene-p-chlorostyrene copolymers, styrene-propylene copolymers, styrene-vinyltoluene copolymers, styrene-vinyl. Naphthalene copolymer, styrene-methyl acrylate copolymer, styrene-ethyl acrylate copolymer, styrene-butyl acrylate copolymer, styrene-octyl acrylate copolymer, styrene-methyl methacrylate copolymer, Styrene-ethyl methacrylate copolymer, styrene-butyl methacrylate copolymer, styrene-α-chloromethyl methacrylate copolymer, styrene-acrylonitrile copolymer, styrene-vinyl methyl ether copolymer, styrene-vinyl ether copolymer Polymer, styrene-vinyl Methyl ketone copolymer, styrene - butadiene copolymer, styrene - isoprene copolymer, styrene - acrylonitrile - indene copolymer,
Styrene-maleic acid copolymers, styrene-based copolymers such as styrene-maleic acid ester copolymers; polymethyl methacrylate, polybutyl methacrylate, polyvinyl chloride, polyvinyl acetate, polyethylene, polypropylene, polyester, polyurethane, polyamide, Epoxy resin, polyvinyl butyral, polyacrylic acid resin, rosin, modified rosin, terpene resin, phenol resin, aliphatic or alicyclic hydrocarbon resin, aromatic petroleum resin, chlorinated paraffin, paraffin wax, etc. Alternatively, they can be mixed and used.

【0015】なお、本発明のトナー供給部材としては、
スポンジ状材質、ファーブラシ状材質などのものが考え
られるが、これらに限定されるものではない。また、本
発明の物質をトナー供給部材表面に被覆する方法として
は、必要に応じて溶剤あるいは分散媒中に溶解ないし分
散させて得た塗布液中にトナー供給部材を浸漬、スプレ
ー、刷毛塗り等により塗布することが可能である。本発
明において重要なことは、トナー供給部材がトナーに対
して、負帯電性を示す物質で表面処理されていることで
あり、負帯電性を示さない物質の場合は、トナーがトナ
ー供給部材によって負に十分摩擦帯電されず供給部材に
十分トナーが補給されず、さらにトナー搬送部材へもト
ナーの供給が不十分となり均一に帯電した均一なトナー
薄層が得られない。またさらに重要なことは、トナー供
給部材表面の被覆材料としては、長期間使用しても、熱
的にも経時的にも変質せず安定にトナーに対して正に帯
電しなければならないことである。また、トナー供給部
材にトナー搬送部材より0〜+500Vのバイアスを印
加することにより、トナー供給部材からトナー搬送部材
上へトナーの補給が速やかに行われる。該印加バイアス
が負電位であると、トナーの搬送部材上への移行が不十
分となり、+500Vより正に大きいと、トナー搬送部
材上へのトナーフィルミングが発生し、ランニングによ
り地かぶり等が画像上に生じる。本発明の現像装置に用
いられるトナーとしては、従来から知られている静電荷
現像用正帯電性トナーとして使用されているものの実質
的にすべてが有効に用いられる。即ち、トナーは非磁
性、磁性のいずれもが用いられる。さらに、トナーは結
着樹脂中に着色剤を分散させた着色粒子であり、また、
帯電付与するために染料・顔料、あるいは、いわゆる荷
電制御剤を含有してもよい。また、コロイダルシリカの
ような流動性向上剤、酸化セリウム、炭化珪素等の研磨
剤、ステアリン酸金属塩などの滑剤、酸化錫のような導
電性付与剤等を必要に応じて含有させてもよい。
As the toner supply member of the present invention,
A sponge-like material, a fur brush-like material, and the like are conceivable, but the material is not limited to these. Further, as a method for coating the surface of the toner supply member with the substance of the present invention, the toner supply member may be immersed, sprayed or brushed in a coating solution obtained by dissolving or dispersing it in a solvent or a dispersion medium as required. Can be applied. What is important in the present invention is that the toner supply member is surface-treated with a substance having a negative charging property with respect to the toner. In the case of a substance having no negative charging property, the toner is supplied by the toner supply member. The toner is not sufficiently negatively charged negatively, the toner is not replenished to the supply member sufficiently, and the toner is not sufficiently supplied to the toner conveying member, so that a uniformly thin toner layer that is uniformly charged cannot be obtained. More importantly, as a coating material for the surface of the toner supply member, it should be stable and positively charged to the toner without being deteriorated by heat or with time even after long-term use. is there. Further, by applying a bias of 0 to +500 V to the toner supplying member from the toner conveying member, the toner is rapidly replenished from the toner supplying member onto the toner conveying member. If the applied bias is a negative potential, the transfer of the toner onto the conveying member becomes insufficient, and if it is more than + 500V, the toner filming on the toner conveying member occurs, and the background fog or the like is generated by running. Occurs on. As the toner used in the developing device of the present invention, substantially all of the conventionally known toners used as positively charging toner for electrostatic charge development can be effectively used. That is, both non-magnetic and magnetic toners are used. Further, the toner is colored particles in which a colorant is dispersed in a binder resin, and
A dye / pigment or a so-called charge control agent may be contained in order to impart an electric charge. Further, a fluidity improver such as colloidal silica, an abrasive such as cerium oxide or silicon carbide, a lubricant such as metal stearate, a conductivity-imparting agent such as tin oxide and the like may be contained as necessary. .

【0016】[0016]

【実施例】以下実施例により本発明を説明する。 実施例1 スチレン系樹脂(D−125 エッソ社製) 85重量部 カーボンブラック(#44 三菱カーボン社製) 12重量部 ニグロシン染料 3重量部 上記組成の混合物をヘンシェルミキサー中で十分撹拌混
合した後、熱ロールミルで溶融混練し、室温まで冷却し
ハンマーミルを用いて粗粉砕し、ついで、エアージェッ
トミルにて微粉砕する。得られた微粉末を分級し粒径5
〜25μmのトナーを得た。つぎに、下記組成物をボー
ルミルを用いて室温にて10時間分散溶解して塗布液と
して、スポンジ状材質のトナー供給部材を浸漬し、11
0℃下で完全に溶媒を蒸発させた。 例示化合物[化1]−(1) 5.0g 溶媒 トルエン 300g [図1]に示すように、本トナー供給部材4をトナー搬
送部材2及びトナー層厚規制部材3からなる現像装置に
配設した。この現像装置を用いた現像方法について説明
すると、図に示すように、トナータンク7に内蔵されて
いるトナー6は撹拌羽根5によりトナー供給部材4に強
制的に寄せられ、トナーはトナー供給部材4に供給され
る。そして、トナー供給部材4に取り込まれたトナーは
トナー供給部材が矢印方向に回転することにより、トナ
ー搬送部材2に運ばれ、摩擦され、静電的あるいは物理
的に吸着し、トナー搬送部材2が矢印方向に強く回転
し、トナー層厚規制部材3によって均一なトナー薄層が
形成されるとともに摩擦帯電する。その後トナー搬送部
材2と接触もしくは近接している潜像担持体1の表面に
運ばれ潜像が現像される。本実施例では、前記トナーを
本現像装置に補給し、トナー搬送部材に−200Vトナ
ー供給部材へ−100Vのバイアスを印加し、マイナス
潜像を有する感光体に現像させ、転写・定着工程を経て
画像出しを行ったところ、鮮明な画像を得た。続けて、
50000枚連続複写したところ初期と変わりのない鮮
明な画像が得られた。また、トナー搬送部材状のトナー
の比電荷量(Q/M)を、出口側にフィルターを具備し
たファラデーケージ(図示せず)を介し、トナー搬送部
材上のトナーを吸引しファラデーケージ内にトラップさ
れたトナーの比電荷を測定する吸引式比電荷量測定装置
を用いて、測定したところ、+12.3(μc/g)と
十分な比電荷量であり、50000枚連続複写後のQ/
Mは+11.3(μc/g)と初期とほとんど変わらな
かった。またさらに、35℃・90%RHの高温高湿
下、及び10℃・15%RHの低温低湿環境下でも常温
常湿の時と同等の画像品質が得られた。なお、前記塗布
液を金属板表面にコートしたものとトナーとの摩擦帯電
性を上記のようなトナー吸引式比電荷量測定装置を応用
して、その帯電極性を調べたところ、前記塗布液を金属
板表面にコートしたものは、負極性に帯電した。
The present invention will be described with reference to the following examples. Example 1 Styrenic resin (D-125 manufactured by Esso Co.) 85 parts by weight carbon black (# 44 manufactured by Mitsubishi Carbon Co.) 12 parts by weight Nigrosine dye 3 parts by weight After thoroughly mixing the mixture having the above composition in a Henschel mixer, The mixture is melt-kneaded with a hot roll mill, cooled to room temperature, coarsely pulverized with a hammer mill, and then finely pulverized with an air jet mill. The fine powder obtained is classified to have a particle size of 5
A toner of ˜25 μm was obtained. Next, the following composition was dispersed and dissolved in a ball mill at room temperature for 10 hours to prepare a coating solution, and a toner supply member made of a sponge-like material was immersed in the coating solution.
The solvent was completely evaporated at 0 ° C. Exemplified Compound [Chemical Formula 1]-(1) 5.0 g Solvent Toluene 300 g As shown in FIG. 1, the present toner supply member 4 is disposed in a developing device including a toner conveying member 2 and a toner layer thickness regulating member 3. . A developing method using this developing device will be described. As shown in the figure, the toner 6 contained in the toner tank 7 is forcibly drawn to the toner supply member 4 by the stirring blade 5, and the toner is supplied to the toner supply member 4. Is supplied to. Then, the toner taken into the toner supply member 4 is conveyed to the toner conveying member 2 by the rotation of the toner supplying member in the direction of the arrow, and is rubbed and electrostatically or physically adsorbed, and the toner conveying member 2 is It strongly rotates in the direction of the arrow, and a uniform toner thin layer is formed by the toner layer thickness regulating member 3 and is triboelectrically charged. After that, the toner is conveyed to the surface of the latent image carrier 1 which is in contact with or in the vicinity of the toner conveying member 2 and the latent image is developed. In this embodiment, the toner is supplied to the main developing device, a bias of −100 V is applied to the toner feeding member of −200 V to the toner feeding member to develop it on the photoconductor having a negative latent image, and the transfer / fixing process is performed. When the image was displayed, a clear image was obtained. continue,
When 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner in the toner transport member is trapped in the Faraday cage by sucking the toner on the toner transport member through a Faraday cage (not shown) equipped with a filter on the outlet side. The amount of the specific charge of the toner is measured by using a suction-type specific charge amount measuring device, and it is +12.3 (μc / g), which is a sufficient specific charge amount.
M was +11.3 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. Incidentally, the triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction type specific charge amount measuring device as described above, and its charging polarity was examined. The product coated on the surface of the metal plate was negatively charged.

【0017】実施例2 スチレン−アクリル系樹脂(SBM−73 三洋化成製) 80重量部 カーボンブラック(#44 三菱カーボン社製) 10重量部 低分子量ポリプロピレン 5重量部 四級アンモニウム塩 5重量部 上記組成の混合物を実施例1と同様な方法にてトナーと
した。本トナー100重量部に対し、コロイダルシリカ
(日本アエロジル社製R−972)0.1重量部を添加
した。つぎに、下記組成物をボールミルを用いて室温に
て10時間分散溶解して塗布液として、スポンジ状材質
のトナー供給部材を浸漬し、110℃下で完全に溶媒を
蒸発させた。 例示化合物[化1]−(2)+アクリル樹脂 10+20g 溶媒 トルエン 1000g 本トナー供給部材4を実施例1と同様に現像装置に配設
した。前記トナーを本現像装置に補給し、トナー搬送部
材に−300Vトナー供給部材へ−200Vのバイアス
を印加し、実施例1と同様に現像させ、画像出しを行っ
たところ、鮮明な画像が得られた。続けて、50000
枚連続複写したところ初期と変わりのない鮮明な画像が
得られた。また、トナー搬送部材上のトナーの比電荷量
(Q/M)は、初期+10.9(μc/g)と十分であ
り、50000枚連続複写後のQ/Mは+9.9(μc
/g)と初期とほとんど変わらなかった。またさらに、
35℃・90%RHの高温高湿下、及び10℃・15%
RHの低温低湿環境下でも常温常湿の時と同等の画像品
質が得られた。なお、前記塗布液を金属板表面にコート
したものとトナーとの摩擦帯電性を上記のようなトナー
吸引式比電荷量測定装置を応用して、その帯電極性を調
べたところ、前記塗布液を金属板表面にコートしたもの
は、負極性に帯電した。
Example 2 Styrene-acrylic resin (SBM-73 manufactured by Sanyo Kasei) 80 parts by weight Carbon black (# 44 manufactured by Mitsubishi Carbon Co., Ltd.) 10 parts by weight Low molecular weight polypropylene 5 parts by weight Quaternary ammonium salt 5 parts by weight The mixture was used as a toner in the same manner as in Example 1. To 100 parts by weight of this toner, 0.1 part by weight of colloidal silica (R-972 manufactured by Nippon Aerosil Co., Ltd.) was added. Next, the following composition was dispersed and dissolved in a ball mill at room temperature for 10 hours to prepare a coating solution, which was dipped in a sponge-like toner supplying member, and the solvent was completely evaporated at 110 ° C. Exemplified Compound [Chemical Formula 1]-(2) + Acrylic Resin 10 + 20 g Solvent Toluene 1000 g The toner supply member 4 was arranged in the developing device in the same manner as in Example 1. When the toner is replenished to the main developing device, a bias of −200 V is applied to the toner feeding member to the toner feeding member, and the toner is developed in the same manner as in Example 1 to perform image development, a clear image is obtained. It was Continuously, 50,000
After continuous copying, a clear image was obtained which was the same as the initial one. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is sufficient as the initial value of +10.9 (μc / g), and the Q / M after continuous copying of 50,000 sheets is +9.9 (μc).
/ G) was almost the same as the initial stage. Furthermore,
Under high temperature and high humidity of 35 ° C ・ 90% RH, and 10 ° C ・ 15%
Even under the environment of low temperature and low humidity of RH, the image quality equivalent to that at the time of normal temperature and normal humidity was obtained. Incidentally, the triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction type specific charge amount measuring device as described above, and its charging polarity was examined. The product coated on the surface of the metal plate was negatively charged.

【0018】実施例3 スチレン−2エチルヘキシルアクリレート−nブチルメタ アクリレート系樹脂 80重量部 カーボンブラック(#44 三菱カーボン社製) 12重量部 低分子量ポリプロピレン 5重量部 ニグロシン染料 3重量部 上記組成の混合物を実施例1と同様な方法にてトナーと
した。本トナー100重量部に対し、コロイダルシリカ
(日本アエロジル社製R−972)0.1重量部を添加
した。つぎに、下記組成物をボールミルを用いて室温に
て10時間分散溶解して塗布液として、スポンジ状材質
のトナー供給部材を浸漬し、110℃下で完全に溶媒を
蒸発させた。 例示化合物[化1]−(3) 5.0g 溶媒 トルエン 300g 本トナー供給部材4を実施例1と同様に現像装置に配設
した。前記トナーを本現像装置に補給し、トナー搬送部
材に−450Vトナー供給部材へ−100Vのバイアス
を印加し、実施例1と同様に現像させ、画像出しを行っ
たところ、鮮明な画像が得られた。続けて、50000
枚連続複写したところ初期と変わりのない鮮明な画像が
得られた。また、トナー搬送部材上のトナーの比電荷量
(Q/M)は、初期+11.8(μc/g)と十分であ
り、50000枚連続複写後のQ/Mは+10.7(μ
c/g)と初期とほとんど変わらなかった。またさら
に、35℃・90%RHの高温高湿下、及び10℃・1
5%RHの低温低湿環境下でも常温常湿の時と同等の画
像品質が得られた。なお、前記塗布液を金属板表面にコ
ートしたものとトナーとの摩擦帯電性を上記のようなト
ナー吸引式比電荷量測定装置を応用して、その帯電極性
を調べたところ、前記塗布液を金属板表面にコートした
ものは、負極性に帯電した。
Example 3 Styrene-2 ethylhexyl acrylate-n-butyl methacrylate resin 80 parts by weight carbon black (# 44 manufactured by Mitsubishi Carbon Co.) 12 parts by weight Low molecular weight polypropylene 5 parts by weight Nigrosine dye 3 parts by weight A mixture having the above composition was carried out. A toner was prepared in the same manner as in Example 1. To 100 parts by weight of this toner, 0.1 part by weight of colloidal silica (R-972 manufactured by Nippon Aerosil Co., Ltd.) was added. Next, the following composition was dispersed and dissolved in a ball mill at room temperature for 10 hours to prepare a coating solution, which was dipped in a sponge-like toner supplying member, and the solvent was completely evaporated at 110 ° C. Exemplified Compound [Chemical Formula 1]-(3) 5.0 g Solvent Toluene 300 g The toner supply member 4 was placed in the developing device in the same manner as in Example 1. When the toner was replenished to the main developing device, a bias of -100V was applied to the toner conveying member of -450V and a toner supplying member was applied, and development was performed in the same manner as in Example 1 to perform image development, and a clear image was obtained. It was Continuously, 50,000
After continuous copying, a clear image was obtained which was the same as the initial one. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is sufficient as the initial value of +11.8 (μc / g), and the Q / M after continuous copying of 50,000 sheets is +10.7 (μ).
c / g) was almost unchanged from the initial stage. Furthermore, under high temperature and high humidity of 35 ° C and 90% RH, and at 10 ° C and 1
Even under a low temperature and low humidity environment of 5% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. Incidentally, the triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction type specific charge amount measuring device as described above, and its charging polarity was examined. The product coated on the surface of the metal plate was negatively charged.

【0019】比較例1 実施例1の被覆剤をトナー供給部材4の被覆材として使
用しない以外は実施例1と同様な装置及びトナーで画像
出しを行ったところ、初期から連続複写10000枚ま
では鮮明な画像が得られていたが、20000枚後には
画像濃度が低下し始め、50000枚後ではさらに画像
濃度が低下し残像等も発生し、トナー搬送部材上には均
一なトナー薄層が形成されていなかった。また、実施例
1と同様にトナー搬送部材上のトナーのQ/Mを測定し
たところ、初期は+11.3(μc/g)、20000
枚後で+4.2(μc/g)、50000枚後では+
2.0(μc/g)であった。
Comparative Example 1 An image was formed by the same apparatus and toner as in Example 1 except that the coating material of Example 1 was not used as the coating material of the toner supply member 4, and from the initial stage to 10000 continuous copies. Although a clear image was obtained, the image density started to decrease after 20,000 sheets, and the image density further decreased after 50,000 sheets to cause afterimages, and a uniform thin toner layer was formed on the toner conveying member. Was not done. Further, when the Q / M of the toner on the toner conveying member was measured in the same manner as in Example 1, the initial value was +11.3 (μc / g), 20,000.
+4.2 (μc / g) after printing, + after 50,000
It was 2.0 (μc / g).

【0020】比較例2 実施例1と同様な装置及びトナーを用い、トナー搬送部
材に−250V、トナー供給部材に−300Vのバイア
スを印加して、同様な画像出しを行ったところ、初期か
ら連続複写10000枚までは鮮明な画像が得られてい
たが、20000枚後には画像濃度が低下しはじめ、5
0000枚後ではさらに画像濃度が低下し残像等も発生
し、トナー搬送部材上には均一なトナー薄層が形成され
ておらず、トナー層厚規制部材及びトナー搬送部材の表
面にトナーフィルミングが発生していた。また、実施例
1と同様にトナー搬送部材上のトナーのQ/Mを測定し
たところ、初期は+13.0(μc/g)、20000
枚後で+6.3(μc/g)、50000枚後では+
2.6(μc/g)であった。
Comparative Example 2 Using the same device and toner as in Example 1, applying a bias of −250 V to the toner conveying member and a bias of −300 V to the toner supplying member, the same image was reproduced. A clear image was obtained up to 10,000 copies, but after 20,000 copies, the image density started to decrease.
After 0000 sheets, the image density is further reduced and an afterimage is generated, and a uniform thin toner layer is not formed on the toner conveying member, so that the toner filming is formed on the surfaces of the toner layer thickness regulating member and the toner conveying member. Had occurred. Further, when the Q / M of the toner on the toner conveying member was measured in the same manner as in Example 1, the initial value was +13.0 (μc / g), 20,000.
+6.3 (μc / g) after printing, + after 50,000
It was 2.6 (μc / g).

【0021】実施例4 実施例1の例示化合物[化1]−(1)の代わりに例示
化合物[化1]−(4)をトナー供給部材4の被覆材と
して使用した以外は実施例1と同様な装置及びトナー
で、トナー搬送部材に−350Vトナー供給部材へ−2
00Vのバイアスを印加し、実施例1と同様に現像さ
せ、画像出しを行ったところ、鮮明な画像が得られた。
続けて、50000枚連続複写したところ初期と変わり
のない鮮明な画像が得られた。また、トナー搬送部材上
のトナーの比電荷量(Q/M)は、初期+12.7(μ
c/g)と十分であり、50000枚連続複写後のQ/
Mは+11.1(μc/g)と初期とほとんど変わらな
かった。またさらに、35℃・90%RHの高温高湿
下、及び10℃・15%RHの低温低湿環境下でも常温
常湿の時と同等の画像品質が得られた。なお、前記塗布
液を金属板表面にコートしたものとトナーとの摩擦帯電
性を上記のようなトナー吸引比電荷量測定装置を応用し
て、その帯電極性を調べたところ、前記塗布液を金属板
表面にコートしたものは、負極性に帯電した。
Example 4 As Example 1 except that the exemplified compound [Chemical Formula 1]-(4) was used as a coating material for the toner supply member 4 in place of the exemplary compound [Chemical Formula 1]-(1) of Example 1. With the same device and toner, -350V for toner feeding member -2 for toner feeding member
A bias of 00 V was applied, development was performed in the same manner as in Example 1, and an image was output. As a result, a clear image was obtained.
Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +12.7 (μ
c / g) is sufficient, and Q / after continuous copying of 50,000 sheets
M was +11.1 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0022】実施例5 実施例2の例示化合物[化1]−(2)の代わりに例示
化合物[化1]−(6)をトナー供給部材4の被覆材と
して使用した以外は実施例2と同様な装置及びトナー
で、トナー搬送部材に−300Vトナー供給部材へ−1
50Vのバイアスを印加し、実施例2と同様に現像さ
せ、画像出しを行ったところ、鮮明な画像が得られた。
続けて、50000枚連続複写したところ初期と変わり
のない鮮明な画像が得られた。また、トナー搬送部材上
のトナーの比電荷量(Q/M)は、初期+8.7(μc
/g)と十分であり、50000枚連続複写後のQ/M
は+8.0(μc/g)と初期とほとんど変わらなかっ
た。またさらに、35℃・90%RHの高温高湿下、及
び10℃・15%RHの低温低湿環境下でも常温常湿の
時と同等の画像品質が得られた。なお、前記塗布液を金
属板表面にコートしたものとトナーとの摩擦帯電性を上
記のようなトナー吸引比電荷量測定装置を応用して、そ
の帯電極性を調べたところ、前記塗布液を金属板表面に
コートしたものは、負極性に帯電した。
Example 5 As Example 2 except that the exemplified compound [Chemical Formula 1]-(6) was used as a coating material for the toner supply member 4 instead of the exemplary compound [Chemical Formula 1]-(2) of Example 2. With the same device and toner, -300V for toner feeding member and -1 for toner feeding member
When a bias of 50 V was applied and development was carried out in the same manner as in Example 2 and an image was formed, a clear image was obtained.
Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +8.7 (μc
/ G) is sufficient, and Q / M after continuous copying of 50,000 sheets
Was +8.0 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0023】実施例6 実施例2の例示化合物[化1]−(2)の代わりに例示
化合物[化1]−(8)をトナー供給部材4の被覆材と
して使用した以外は実施例2と同様な装置及びトナー
で、トナー搬送部材に−400Vトナー供給部材へ−2
00Vのバイアスを印加し、実施例2と同様に現像さ
せ、画像出しを行ったところ、鮮明な画像が得られた。
続けて、50000枚連続複写したところ初期と変わり
のない鮮明な画像が得られた。また、トナー搬送部材上
のトナーの比電荷量(Q/M)は、初期+9.9(μc
/g)と十分であり、50000枚連続複写後のQ/M
は+8.2(μc/g)と初期とほとんど変わらなかっ
た。またさらに、35℃・90%RHの高温高湿下、及
び10℃・15%RHの低温低湿環境下でも常温常湿の
時と同等の画像品質が得られた。なお、前記塗布液を金
属板表面にコートしたものとトナーとの摩擦帯電性を上
記のようなトナー吸引比電荷量測定装置を応用して、そ
の帯電極性を調べたところ、前記塗布液を金属板表面に
コートしたものは、負極性に帯電した。
Example 6 As Example 2 except that Exemplified Compounds [Chemical Formula 1]-(8) in place of Exemplified Compounds [Chemical Formula 1]-(2) of Example 2 was used as a coating material for the toner supply member 4. With the same device and toner, -400V for toner feeding member -2 for toner feeding member
A bias of 00 V was applied, development was performed in the same manner as in Example 2, and an image was output. As a result, a clear image was obtained.
Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner transport member is initially +9.9 (μc
/ G) is sufficient, and Q / M after continuous copying of 50,000 sheets
Was +8.2 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0024】実施例7 実施例1の例示化合物[化1]−(1)の代わりに例示
化合物[化1]−(10)をトナー供給部材4の被覆材
として使用した以外は実施例1と同様な装置及びトナー
で、トナー搬送部材に−300Vトナー供給部材へ−2
00Vのバイアスを印加し、実施例1と同様に現像さ
せ、画像出しを行ったところ、鮮明な画像が得られた。
続けて、50000枚連続複写したところ初期と変わり
のない鮮明な画像が得られた。また、トナー搬送部材上
のトナーの比電荷量(Q/M)は、初期+10.2(μ
c/g)と十分であり、50000枚連続複写後のQ/
Mは+8.1(μc/g)と初期とほとんど変わらなか
った。またさらに、35℃・90%RHの高温高湿下、
及び10℃・15%RHの低温低湿環境下でも常温常湿
の時と同等の画像品質が得られた。なお、前記塗布液を
金属板表面にコートしたものとトナーとの摩擦帯電性を
上記のようなトナー吸引比電荷量測定装置を応用して、
その帯電極性を調べたところ、前記塗布液を金属板表面
にコートしたものは、負極性に帯電した。
Example 7 Example 1 was repeated except that the exemplary compound [Chemical Formula 1]-(10) was used as a coating material for the toner supply member 4 instead of the exemplary compound [Chemical Formula 1]-(1) of Example 1. With the same device and toner, -300V for toner feeding member and -2 for toner feeding member
A bias of 00 V was applied, development was performed in the same manner as in Example 1, and an image was output. As a result, a clear image was obtained.
Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +10.2 (μ
c / g) is sufficient, and Q / after continuous copying of 50,000 sheets
M was +8.1 (μc / g), which was almost the same as the initial value. Furthermore, under high temperature and high humidity of 35 ° C and 90% RH,
In addition, even under a low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. By applying the toner suction specific charge amount measuring device as described above to the triboelectric charging property between the coating liquid coated on the metal plate surface and the toner,
When the charging polarity was examined, the coating liquid coated on the surface of the metal plate was negatively charged.

【0025】実施例8 実施例1の例示化合物[化1]−(1)の代わりに例示
化合物[化1]−(12)をトナー供給部材4の被覆材
として使用した以外は実施例1と同様な装置及びトナー
で、トナー搬送部材に−250Vトナー供給部材へ−1
00Vのバイアスを印加し、実施例1と同様に現像さ
せ、画像出しを行ったところ、鮮明な画像が得られた。
続けて、50000枚連続複写したところ初期と変わり
のない鮮明な画像が得られた。また、トナー搬送部材上
のトナーの比電荷量(Q/M)は、初期+12.2(μ
c/g)と十分であり、50000枚連続複写後のQ/
Mは+10.9(μc/g)と初期とほとんど変わらな
かった。またさらに、35℃・90%RHの高温高湿
下、及び10℃・15%RHの低温低湿環境下でも常温
常湿の時と同等の画像品質が得られた。なお、前記塗布
液を金属板表面にコートしたものとトナーとの摩擦帯電
性を上記のようなトナー吸引比電荷量測定装置を応用し
て、その帯電極性を調べたところ、前記塗布液を金属板
表面にコートしたものは、負極性に帯電した。
Example 8 As Example 1 except that the exemplified compound [Chemical Formula 1]-(12) was used as a coating material for the toner supply member 4 instead of the exemplary compound [Chemical Formula 1]-(1) of Example 1. Using the same device and toner, -250V for toner feeding member and -1 for toner feeding member
A bias of 00 V was applied, development was performed in the same manner as in Example 1, and an image was output. As a result, a clear image was obtained.
Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is +12.2 (μ
c / g) is sufficient, and Q / after continuous copying of 50,000 sheets
M was +10.9 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0029】実施例9 スチレン系樹脂(D−125 エッソ社製) 85重量部 カーボンブラック(#44 三菱カーボン社製) 12重量部 ニグロシン染料 3重量部 上記組成の混合物をヘンシェルミキサー中で十分撹拌混
合した後、熱ロールミルで溶融混練し、室温まで冷却し
ハンマーミルを用いて粗粉砕し、ついで、エアージェッ
トミルにて微粉砕する。得られた微粉末を分級し粒径5
〜25μmのトナーを得た。つぎに、下記組成物をボー
ルミルを用いて室温にて10時間分散溶解して塗布液と
して、スポンジ状材質のトナー供給部材を浸漬し、11
0℃下で完全に溶媒を蒸発させた。 例示化合物[化2]−(1) 5.0g 溶媒 トルエン 300g 図に示すように、本トナー供給部材4をトナー搬送部材
2及びトナー層厚規制部材3からなる現像装置に配設し
た。この現像装置を用いた現像方法について説明する
と、図に示すように、トナータンク7に内蔵されている
トナー6は撹拌羽根5によりトナー供給部材4に強制的
に寄せられ、トナーはトナー供給部材4に供給される。
そして、トナー供給部材4に取り込まれたトナーはトナ
ー供給部材が矢印方向に回転することにより、トナー搬
送部材2に運ばれ、摩擦され、静電的あるいは物理的に
吸着し、トナー搬送部材2が矢印方向に強く回転し、ト
ナー層厚規制部材3によって均一なトナー薄層が形成さ
れるとともに摩擦帯電する。その後トナー搬送部材2と
接触もしくは近接している潜像担持体1の表面に運ばれ
潜像が現像される。本実施例では、前記トナーを本現像
装置に補給し、トナー搬送部材に−200Vトナー供給
部材へ−100Vのバイアスを印加し、マイナス潜像を
有する感光体に現像させ、転写・定着工程を経て画像出
しを行ったところ、鮮明な画像を得た。続けて、500
00枚連続複写したところ初期と変わりのない鮮明な画
像が得られた。また、トナー搬送部材上のトナーの比電
荷量(Q/M)を、出口側にフィルターを具備したファ
ラデーケージ(図示せず)を介し、トナー搬送部材上の
トナーを吸引しファラデーケージ内にトラップされたト
ナーの比電荷を測定する吸引式比電荷量測定装置を用い
て、測定したところ、+11.6(μc/g)と十分な
比電荷量であり、50000枚連続複写後のQ/Mは+
10.4(μc/g)と初期とほとんど変わらなかっ
た。またさらに、35℃・90%RHの高温高湿下、及
び10℃・15%RHの低温低湿環境下でも常温常湿の
時と同等の画像品質が得られた。なお、前記塗布液を金
属板表面にコートしたものとトナーとの摩擦帯電性を上
記のようなトナー吸引式比電荷量測定装置を応用して、
その帯電極性を調べたところ、前記塗布液を金属板表面
にコートしたものは、負極性に帯電した。
Example 9 Styrenic resin (D-125 manufactured by Esso Co.) 85 parts by weight carbon black (# 44 manufactured by Mitsubishi Carbon Co.) 12 parts by weight Nigrosine dye 3 parts by weight The mixture having the above composition is sufficiently stirred and mixed in a Henschel mixer. After that, the mixture is melt-kneaded with a hot roll mill, cooled to room temperature, coarsely pulverized with a hammer mill, and then finely pulverized with an air jet mill. The fine powder obtained is classified to have a particle size of 5
A toner of ˜25 μm was obtained. Next, the following composition was dispersed and dissolved in a ball mill at room temperature for 10 hours to prepare a coating solution, and a toner supply member made of a sponge-like material was immersed in the coating solution.
The solvent was completely evaporated at 0 ° C. Exemplified Compound [Chemical Formula 2]-(1) 5.0 g Solvent Toluene 300 g As shown in the figure, the present toner supply member 4 was disposed in a developing device including the toner conveying member 2 and the toner layer thickness regulating member 3. A developing method using this developing device will be described. As shown in the figure, the toner 6 contained in the toner tank 7 is forcibly drawn to the toner supply member 4 by the stirring blade 5, and the toner is supplied to the toner supply member 4. Is supplied to.
Then, the toner taken into the toner supply member 4 is conveyed to the toner conveying member 2 by the rotation of the toner supplying member in the direction of the arrow, and is rubbed and electrostatically or physically adsorbed, and the toner conveying member 2 is It strongly rotates in the direction of the arrow, and a uniform toner thin layer is formed by the toner layer thickness regulating member 3 and is triboelectrically charged. After that, the toner is conveyed to the surface of the latent image carrier 1 which is in contact with or in the vicinity of the toner conveying member 2 and the latent image is developed. In this embodiment, the toner is supplied to the main developing device, a bias of −100 V is applied to the toner feeding member of −200 V to the toner feeding member to develop it on the photoconductor having a negative latent image, and the transfer / fixing process is performed. When the image was displayed, a clear image was obtained. Continuously, 500
When 00 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner carrying member is trapped in the Faraday cage by sucking the toner on the toner carrying member through a Faraday cage (not shown) equipped with a filter on the outlet side. It was +11.6 (μc / g), which was a sufficient specific charge amount when measured with a suction-type specific charge amount measuring device for measuring the specific charge of the toner, and the Q / M after 50,000 sheets were continuously copied. Is +
It was 10.4 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. In addition, applying the toner suction type specific charge amount measuring device as described above to the triboelectrification property of the coating liquid on the surface of a metal plate and the toner,
When the charging polarity was examined, the coating liquid coated on the surface of the metal plate was negatively charged.

【0027】実施例10 スチレン−アクリル系樹脂(SBM−73 三洋化成製) 80重量部 カーボンブラック(#44 三菱カーボン社製) 10重量部 低分子量ポリプロピレン 5重量部 4級アンモニウム塩 5重量部 上記組成の混合物を実施例9と同様な方法にてトナーと
した。本トナー100重量部に対し、コロイダルシリカ
(日本アエロジル社製R−972)0.1重量部を添加
した。つぎに、下記組成物をボールミルを用いて室温に
て10時間分散溶解して塗布液として、スポンジ状材質
のトナー供給部材を浸漬し、110℃下で完全に溶媒を
蒸発させた。 例示化合物[化2]−(2)+アクリル樹脂 10+20g 溶媒 トルエン 1000g 本トナー供給部材4を実施例9と同様に現像装置に配設
した。前記トナーを本現像装置に補給し、トナー搬送部
材に−300Vトナー供給部材へ−200Vのバイアス
を印加し、実施例9と同様に現像させ、画像出しを行っ
たところ、鮮明な画像が得られた。続けて、50000
枚連続複写したところ初期と変わりのない鮮明な画像が
得られた。また、トナー搬送部材上のトナーの比電荷量
(Q/M)は、初期+9.8(μc/g)と十分であ
り、50000枚連続複写後のQ/Mは+9.2(μc
/g)と初期とほとんど変わらなかった。またさらに、
35℃・90%RHの高温高湿下、及び10℃・15%
RHの低温低湿環境下でも常温常湿の時と同等の画像品
質が得られた。なお、前記塗布液を金属板表面にコート
したものとトナーとの摩擦帯電性を上記のようなトナー
吸引式比電荷量測定装置を応用して、その帯電極性を調
べたところ、前記塗布液を金属板表面にコートしたもの
は、負極性に帯電した。
Example 10 Styrene-acrylic resin (SBM-73 manufactured by Sanyo Kasei) 80 parts by weight Carbon black (# 44 manufactured by Mitsubishi Carbon Co.) 10 parts by weight Low molecular weight polypropylene 5 parts by weight Quaternary ammonium salt 5 parts by weight The above composition The mixture was used as a toner in the same manner as in Example 9. To 100 parts by weight of this toner, 0.1 part by weight of colloidal silica (R-972 manufactured by Nippon Aerosil Co., Ltd.) was added. Next, the following composition was dispersed and dissolved in a ball mill at room temperature for 10 hours to prepare a coating solution, which was dipped in a sponge-like toner supplying member, and the solvent was completely evaporated at 110 ° C. Exemplified Compound [Chemical Formula 2]-(2) + Acrylic Resin 10 + 20 g Solvent Toluene 1000 g The toner supply member 4 was placed in the developing device in the same manner as in Example 9. When the toner was replenished to the main developing device, a bias of -200V was applied to the toner feeding member of -300V, the toner was developed in the same manner as in Example 9, and an image was formed. It was Continuously, 50,000
After continuous copying, a clear image was obtained which was the same as the initial one. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is sufficient at the initial +9.8 (μc / g), and the Q / M after continuous copying of 50,000 sheets is +9.2 (μc).
/ G) was almost the same as the initial stage. Furthermore,
Under high temperature and high humidity of 35 ° C ・ 90% RH, and 10 ° C ・ 15%
Even under the environment of low temperature and low humidity of RH, the image quality equivalent to that at the time of normal temperature and normal humidity was obtained. Incidentally, the triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction type specific charge amount measuring device as described above, and its charging polarity was examined. The product coated on the surface of the metal plate was negatively charged.

【0028】実施例11 スチレン−2エチルヘキシルアクリレート−nブチルメタ アクリレート系樹脂 80重量部 カーボンブラック(#44 三菱カーボン社製) 12重量部 低分子量ポリプロピレン 5重量部 ニグロシン染料 3重量部 上記組成の混合物を実施例9と同様な方法にてトナーと
した。本トナー100重量部に対し、コロイダルシリカ
(日本アエロジル社製R−972)0.1重量部を添加
した。つぎに、下記組成物をボールミルを用いて室温に
て10時間分散溶解して塗布液として、スポンジ状材質
のトナー供給部材を浸漬し、110℃下で完全に溶媒を
蒸発させた。 例示化合物[化2]−(3) 5.0g 溶媒 トルエン 300g 本トナー供給部材4を実施例9と同様に現像装置に配設
した。前記トナーを本現像装置に補給し、トナー搬送部
材に−450Vトナー供給部材へ−100Vのバイアス
を印加し、実施例9と同様に現像させ、画像出しを行っ
たところ、鮮明な画像が得られた。続けて、50000
枚連続複写したところ初期と変わりのない鮮明な画像が
得られた。また、トナー搬送部材上のトナーの比電荷量
(Q/M)は、初期+10.2(μc/g)と十分であ
り、50000枚連続複写後のQ/Mは+9.9(μc
/g)と初期とほとんど変わらなかった。またさらに、
35℃・90%RHの高温高湿下、及び10℃・15%
RHの低温低湿環境下でも常温常湿の時と同等の画像品
質が得られた。なお、前記塗布液を金属板表面にコート
したものとトナーとの摩擦帯電性を上記のようなトナー
吸引式比電荷量測定装置を応用して、その帯電極性を調
べたところ、前記塗布液を金属板表面にコートしたもの
は、負極性に帯電した。
Example 11 Styrene-2 ethylhexyl acrylate-n-butyl methacrylate resin 80 parts by weight carbon black (# 44 manufactured by Mitsubishi Carbon Co.) 12 parts by weight Low molecular weight polypropylene 5 parts by weight Nigrosine dye 3 parts by weight A mixture having the above composition was carried out. A toner was prepared in the same manner as in Example 9. To 100 parts by weight of this toner, 0.1 part by weight of colloidal silica (R-972 manufactured by Nippon Aerosil Co., Ltd.) was added. Next, the following composition was dispersed and dissolved in a ball mill at room temperature for 10 hours to prepare a coating solution, which was dipped in a sponge-like toner supplying member, and the solvent was completely evaporated at 110 ° C. Exemplified Compound [Chemical Formula 2]-(3) 5.0 g Solvent Toluene 300 g The toner supply member 4 was placed in the developing device in the same manner as in Example 9. The toner was replenished to the main developing device, a bias of −100V was applied to the toner feeding member to the toner feeding member, and the toner was developed in the same manner as in Example 9 to perform image development, and a clear image was obtained. It was Continuously, 50,000
After continuous copying, a clear image was obtained which was the same as the initial one. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is sufficient as the initial value of +10.2 (μc / g), and the Q / M after continuous copying of 50,000 sheets is +9.9 (μc).
/ G) was almost the same as the initial stage. Furthermore,
Under high temperature and high humidity of 35 ° C ・ 90% RH, and 10 ° C ・ 15%
Even under the environment of low temperature and low humidity of RH, the image quality equivalent to that at the time of normal temperature and normal humidity was obtained. Incidentally, the triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction type specific charge amount measuring device as described above, and its charging polarity was examined. The product coated on the surface of the metal plate was negatively charged.

【0029】比較例3 実施例9と同様な装置及びトナーを用い、トナー搬送部
材に−250V、トナー供給部材に−300Vのバイア
スを印加して、同様な画像出しを行ったところ、初期か
ら連続複写10000枚までは鮮明な画像が得られてい
たが、20000枚後には画像濃度が低下しはじめ、5
0000枚後ではさらに画像濃度が低下し残像等も発生
し、トナー搬送部材上には均一なトナー薄層が形成され
ておらず、トナー層厚規制部材及びトナー搬送部材の表
面にトナーフィルミングが発生していた。また、実施例
9と同様にトナー搬送部材上のトナーのQ/Mを測定し
たところ、初期は+10.7(μc/g)、20000
枚後で+5.6(μc/g)、50000枚後では+
3.7(μc/g)であった。
Comparative Example 3 Using the same apparatus and toner as in Example 9, applying a bias of −250 V to the toner conveying member and a bias of −300 V to the toner supplying member, the same image was reproduced. A clear image was obtained up to 10,000 copies, but after 20,000 copies, the image density started to decrease.
After 0000 sheets, the image density is further reduced and an afterimage is generated, and a uniform thin toner layer is not formed on the toner conveying member, so that the toner filming is formed on the surfaces of the toner layer thickness regulating member and the toner conveying member. Had occurred. Further, when the Q / M of the toner on the toner conveying member was measured in the same manner as in Example 9, the initial value was +10.7 (μc / g), 20,000.
+5.6 (μc / g) after printing, + after 50,000
It was 3.7 (μc / g).

【0030】実施例12 実施例9の例示化合物[化2]−(1)の代わりに例示
化合物[化2]−(4)をトナー供給部材4の被覆材と
して使用した以外は実施例9と同様な装置及びトナー
で、トナー搬送部材に−350Vトナー供給部材へ−2
00Vのバイアスを印加し、実施例9と同様に現像さ
せ、画像出しを行ったところ、鮮明な画像が得られた。
続けて、50000枚連続複写したところ初期と変わり
のない鮮明な画像が得られた。また、トナー搬送部材上
のトナーの比電荷量(Q/M)は、初期+12.4(μ
c/g)と十分であり、50000枚連続複写後のQ/
Mは+11.9(μc/g)と初期とほとんど変わらな
かった。またさらに、35℃・90%RHの高温高湿
下、及び10℃・15%RHの低温低湿環境下でも常温
常湿の時と同等の画像品質が得られた。なお、前記塗布
液を金属板表面にコートしたものとトナーとの摩擦帯電
性を上記のようなトナー吸引比電荷量測定装置を応用し
て、その帯電極性を調べたところ、前記塗布液を金属板
表面にコートしたものは、負極性に帯電した。
Example 12 Example 9 was repeated except that the exemplified compound [Chemical formula 2]-(4) was used as a coating material for the toner supply member 4 instead of the exemplified compound [Chemical formula 2]-(1) of Example 9. With the same device and toner, -350V for toner feeding member -2 for toner feeding member
A bias of 00 V was applied, development was performed in the same manner as in Example 9, and an image was output. As a result, a clear image was obtained.
Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +12.4 (μ
c / g) is sufficient, and Q / after continuous copying of 50,000 sheets
M was +11.9 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0031】実施例13 実施例10の例示化合物[化2]−(2)の代わりに例
示化合物[化2]−(6)をトナー供給部材4の被覆材
として使用した以外は実施例10と同様な装置及びトナ
ーで、トナー搬送部材に−300Vトナー供給部材へ−
150Vのバイアスを印加し、実施例10と同様に現像
させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+8.9
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+8.1(μc/g)と初期とほとんど変わら
なかった。またさらに、35℃・90%RHの高温高湿
下、及び10℃・15%RHの低温低湿環境下でも常温
常湿の時と同等の画像品質が得られた。なお、前記塗布
液を金属板表面にコートしたものとトナーとの摩擦帯電
性を上記のようなトナー吸引比電荷量測定装置を応用し
て、その帯電極性を調べたところ、前記塗布液を金属板
表面にコートしたものは、負極性に帯電した。
Example 13 The same as Example 10 except that the exemplified compound [Chemical formula 2]-(6) was used as a coating material for the toner supply member 4 instead of the exemplified compound [Chemical formula 2]-(2) of Example 10. With the same device and toner, to the toner conveying member-to the 300V toner supplying member-
When a bias of 150 V was applied and development was carried out in the same manner as in Example 10 and an image was formed, a clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. In addition, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +8.9.
(Μc / g) was sufficient, and the Q / M after continuous copying of 50,000 sheets was +8.1 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0032】実施例14 実施例10の例示化合物[化2]−(2)の代わりに例
示化合物[化2]−(8)をトナー供給部材4の被覆材
として使用した以外は実施例2と同様な装置及びトナー
で、トナー搬送部材に−400Vトナー供給部材へ−2
00Vのバイアスを印加し、実施例10と同様に現像さ
せ、画像出しを行ったところ、鮮明な画像が得られた。
続けて、50000枚連続複写したところ初期と変わり
のない鮮明な画像が得られた。また、トナー搬送部材上
のトナーの比電荷量(Q/M)は、初期+9.4(μc
/g)と十分であり、50000枚連続複写後のQ/M
は+8.1(μc/g)と初期とほとんど変わらなかっ
た。またさらに、35℃・90%RHの高温高湿下、及
び10℃・15%RHの低温低湿環境下でも常温常湿の
時と同等の画像品質が得られた。なお、前記塗布液を金
属板表面にコートしたものとトナーとの摩擦帯電性を上
記のようなトナー吸引比電荷量測定装置を応用して、そ
の帯電極性を調べたところ、前記塗布液を金属板表面に
コートしたものは、負極性に帯電した。
Example 14 As Example 2 except that Exemplified Compound [Chemical Formula 2]-(8) was used as a coating material for the toner supply member 4 instead of Exemplified Compound [Chemical Formula 2]-(2) of Example 10. With the same device and toner, -400V for toner feeding member -2 for toner feeding member
A bias of 00 V was applied, development was performed in the same manner as in Example 10, and an image was output. As a result, a clear image was obtained.
Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +9.4 (μc
/ G) is sufficient, and Q / M after continuous copying of 50,000 sheets
Was +8.1 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0033】実施例15 実施例9の例示化合物[化2]−(1)の代わりに例示
化合物[化2]−(10)をトナー供給部材4の被覆材
として使用した以外は実施例9と同様な装置及びトナー
で、トナー搬送部材に−300Vトナー供給部材へ−2
00Vのバイアスを印加し、実施例9と同様に現像さ
せ、画像出しを行ったところ、鮮明な画像が得られた。
続けて、50000枚連続複写したところ初期と変わり
のない鮮明な画像が得られた。また、トナー搬送部材上
のトナーの比電荷量(Q/M)は、初期+10.9(μ
c/g)と十分であり、50000枚連続複写後のQ/
Mは+10.0(μc/g)と初期とほとんど変わらな
かった。またさらに、35℃・90%RHの高温高湿
下、及び10℃・15%RHの低温低湿環境下でも常温
常湿の時と同等の画像品質が得られた。なお、前記塗布
液を金属板表面にコートしたものとトナーとの摩擦帯電
性を上記のようなトナー吸引比電荷量測定装置を応用し
て、その帯電極性を調べたところ、前記塗布液を金属板
表面にコートしたものは、負極性に帯電した。
Example 15 Example 9 was repeated except that the exemplified compound [Chemical formula 2]-(10) was used as a coating material for the toner supply member 4 instead of the exemplified compound [Chemical formula 2]-(1) of Example 9. With the same device and toner, -300V for toner feeding member and -2 for toner feeding member
A bias of 00 V was applied, development was performed in the same manner as in Example 9, and an image was output. As a result, a clear image was obtained.
Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +10.9 (μ
c / g) is sufficient, and Q / after continuous copying of 50,000 sheets
M was +10.0 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0034】実施例16 実施例9の例示化合物[化2]−(1)の代わりに例示
化合物[化2]−(12)をトナー供給部材4の被覆材
として使用した以外は実施例9と同様な装置及びトナー
で、トナー搬送部材に−250Vトナー供給部材へ−1
00Vのバイアスを印加し、実施例9と同様に現像さ
せ、画像出しを行ったところ、鮮明な画像が得られた。
続けて、50000枚連続複写したところ初期と変わり
のない鮮明な画像が得られた。また、トナー搬送部材上
のトナーの比電荷量(Q/M)は、初期+12.0(μ
c/g)と十分であり、50000枚連続複写後のQ/
Mは+11.1(μc/g)と初期とほとんど変わらな
かった。またさらに、35℃・90%RHの高温高湿
下、及び10℃・15%RHの低温低湿環境下でも常温
常湿の時と同等の画像品質が得られた。なお、前記塗布
液を金属板表面にコートしたものとトナーとの摩擦帯電
性を上記のようなトナー吸引比電荷量測定装置を応用し
て、その帯電極性を調べたところ、前記塗布液を金属板
表面にコートしたものは、負極性に帯電した。
Example 16 As Example 9 except that the exemplified compound [Chemical formula 2]-(12) was used as a coating material for the toner supply member 4 instead of the exemplified compound [Chemical formula 2]-(1) of Example 9. Using the same device and toner, -250V for toner feeding member and -1 for toner feeding member
A bias of 00 V was applied, development was performed in the same manner as in Example 9, and an image was output. As a result, a clear image was obtained.
Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is +12.0 (μ
c / g) is sufficient, and Q / after continuous copying of 50,000 sheets
M was +11.1 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0035】実施例17 スチレン系樹脂(D−125 エッソ社製) 85重量部 カーボンブラック(#44 三菱カーボン社製) 12重量部 ニグロシン染料 3重量部 上記組成の混合物をヘンシェルミキサー中で十分撹拌混
合した後、熱ロールミルで溶融混練し、室温まで冷却し
ハンマーミルを用いて粗粉砕し、ついで、エアージェッ
トミルにて微粉砕する。得られた微粉末を分級し粒径5
〜25μmのトナーを得た。つぎに、下記組成物をボー
ルミルを用いて室温にて10時間分散溶解して塗布液と
して、スポンジ状材質のトナー供給部材を浸漬し、11
0℃下で完全に溶媒を蒸発させた。 例示化合物[化3]−(1) 5.0g 溶媒 トルエン 300g 図に示すように、本トナー供給部材4をトナー搬送部材
2及びトナー層厚規制部材3からなる現像装置に配設し
た。この現像装置を用いた現像方法について説明する
と、図に示すように、トナータンク7に内蔵されている
トナー6は撹拌羽根5によりトナー供給部材4に強制的
に寄せられ、トナーはトナー供給部材4に供給される。
そして、トナー供給部材4に取り込まれたトナーはトナ
ー供給部材が矢印方向に回転することにより、トナー搬
送部材2に運ばれ、摩擦され、静電的あるいは物理的に
吸着し、トナー搬送部材2が矢印方向に強く回転し、ト
ナー層厚規制部材3によって均一なトナー薄層が形成さ
れるとともに摩擦帯電する。その後トナー搬送部材2と
接触もしくは近接している潜像担持体1の表面に運ばれ
潜像が現像される。本実施例では、前記トナーを本現像
装置に補給し、トナー搬送部材に−200Vトナー供給
部材へ−100Vのバイアスを印加し、マイナス潜像を
有する感光体に現像させ、転写・定着工程を経て画像出
しを行ったところ、鮮明な画像を得た。続けて、500
00枚連続複写したところ初期と変わりのない鮮明な画
像が得られた。また、トナー搬送部材上のトナーの比電
荷量(Q/M)を、出口側にフィルターを具備したファ
ラデーケージ(図示せず)を介し、トナー搬送部材上の
トナーを吸引しファラデーケージ内にトラップされたト
ナーの比電荷を測定する吸引式比電荷量測定装置を用い
て、測定したところ、+12.7(μc/g)と十分な
比電荷量であり、50000枚連続複写後のQ/Mは+
11.7(μc/g)と初期とほとんど変わらなかっ
た。またさらに、35℃・90%RHの高温高湿下、及
び10℃・15%RHの低温低湿環境下でも常温常湿の
時と同等の画像品質が得られた。なお、前記塗布液を金
属板表面にコートしたものとトナーとの摩擦帯電性を上
記のようなトナー吸引式比電荷量測定装置を応用して、
その帯電極性を調べたところ、前記塗布液を金属板表面
にコートしたものは、負極性に帯電した。
Example 17 Styrenic resin (D-125 manufactured by Esso Co.) 85 parts by weight Carbon black (# 44 manufactured by Mitsubishi Carbon Co.) 12 parts by weight Nigrosine dye 3 parts by weight A mixture of the above composition is sufficiently stirred and mixed in a Henschel mixer. After that, the mixture is melt-kneaded with a hot roll mill, cooled to room temperature, coarsely pulverized with a hammer mill, and then finely pulverized with an air jet mill. The fine powder obtained is classified to have a particle size of 5
A toner of ˜25 μm was obtained. Next, the following composition was dispersed and dissolved in a ball mill at room temperature for 10 hours to prepare a coating solution, and a toner supply member made of a sponge-like material was immersed in the coating solution.
The solvent was completely evaporated at 0 ° C. Exemplified Compound [Chemical Formula 3]-(1) 5.0 g Solvent Toluene 300 g As shown in the figure, the toner supplying member 4 was disposed in a developing device including the toner conveying member 2 and the toner layer thickness regulating member 3. A developing method using this developing device will be described. As shown in the figure, the toner 6 contained in the toner tank 7 is forcibly drawn to the toner supply member 4 by the stirring blade 5, and the toner is supplied to the toner supply member 4. Is supplied to.
Then, the toner taken into the toner supply member 4 is conveyed to the toner conveying member 2 by the rotation of the toner supplying member in the direction of the arrow, and is rubbed and electrostatically or physically adsorbed, and the toner conveying member 2 is It strongly rotates in the direction of the arrow, and a uniform toner thin layer is formed by the toner layer thickness regulating member 3 and is triboelectrically charged. After that, the toner is conveyed to the surface of the latent image carrier 1 which is in contact with or in the vicinity of the toner conveying member 2 and the latent image is developed. In this embodiment, the toner is supplied to the main developing device, a bias of −100 V is applied to the toner feeding member of −200 V to the toner feeding member to develop it on the photoconductor having a negative latent image, and the transfer / fixing process is performed. When the image was displayed, a clear image was obtained. Continuously, 500
When 00 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner carrying member is trapped in the Faraday cage by sucking the toner on the toner carrying member through a Faraday cage (not shown) equipped with a filter on the outlet side. The specific charge of the toner was measured with a suction-type specific charge amount measuring device, and the measured value was +12.7 (μc / g), which was a sufficient specific charge amount. Is +
The value was 11.7 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. In addition, applying the toner suction type specific charge amount measuring device as described above to the triboelectrification property of the coating liquid on the surface of a metal plate and the toner,
When the charging polarity was examined, the coating liquid coated on the surface of the metal plate was negatively charged.

【0036】実施例18 スチレン−アクリル系樹脂(SBM−73 三洋化成製) 80重量部 カーボンブラック(#44 三菱カーボン社製) 10重量部 低分子量ポリプロピレン 5重量部 4級アンモニウム塩 5重量部 上記組成の混合物を実施例17と同様な方法にてトナー
とした。本トナー100重量部に対し、コロイダルシリ
カ(日本アエロジル社製R−972)0.1重量部を添
加した。つぎに、下記組成物をボールミルを用いて室温
にて10時間分散溶解して塗布液として、スポンジ状材
質のトナー供給部材を浸漬し、110℃下で完全に溶媒
を蒸発させた。 例示化合物[化3]−(2)+アクリル樹脂 10+20g 溶媒 トルエン 1000g 本トナー供給部材4を実施例17と同様に現像装置に配
設した。前記トナーを本現像装置に補給し、トナー搬送
部材に−300Vトナー供給部材へ−200Vのバイア
スを印加し、実施例17と同様に現像させ、画像出しを
行ったところ、鮮明な画像が得られた。続けて、500
00枚連続複写したところ初期と変わりのない鮮明な画
像が得られた。また、トナー搬送部材上のトナーの比電
荷量(Q/M)は、初期+11.2(μc/g)と十分
であり、50000枚連続複写後のQ/Mは+10.8
(μc/g)と初期とほとんど変わらなかった。またさ
らに、35℃・90%RHの高温高湿下、及び10℃・
15%RHの低温低湿環境下でも常温常湿の時と同等の
画像品質が得られた。なお、前記塗布液を金属板表面に
コートしたものとトナーとの摩擦帯電性を上記のような
トナー吸引式比電荷量測定装置を応用して、その帯電極
性を調べたところ、前記塗布液を金属板表面にコートし
たものは、負極性に帯電した。
Example 18 Styrene-acrylic resin (SBM-73 manufactured by Sanyo Kasei) 80 parts by weight Carbon black (# 44 manufactured by Mitsubishi Carbon Co.) 10 parts by weight Low molecular weight polypropylene 5 parts by weight Quaternary ammonium salt 5 parts by weight Above composition The mixture was used as a toner in the same manner as in Example 17. To 100 parts by weight of this toner, 0.1 part by weight of colloidal silica (R-972 manufactured by Nippon Aerosil Co., Ltd.) was added. Next, the following composition was dispersed and dissolved in a ball mill at room temperature for 10 hours to prepare a coating solution, which was dipped in a sponge-like toner supplying member, and the solvent was completely evaporated at 110 ° C. Exemplified Compound [Chemical Formula 3]-(2) + Acrylic Resin 10 + 20 g Solvent Toluene 1000 g The toner supply member 4 was placed in the developing device in the same manner as in Example 17. When the toner was replenished to the main developing device, a bias of -200V was applied to the toner feeding member of -300V and the toner was developed in the same manner as in Example 17, and an image was formed, a clear image was obtained. It was Continuously, 500
When 00 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is sufficient as the initial +11.2 (μc / g), and the Q / M after continuous copying of 50,000 sheets is +10.8.
(Μc / g) was almost unchanged from the initial stage. Furthermore, under high temperature and high humidity of 35 ° C ・ 90% RH, and 10 ° C ・
Even under a low temperature and low humidity environment of 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. Incidentally, the triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction type specific charge amount measuring device as described above, and its charging polarity was examined. The product coated on the surface of the metal plate was negatively charged.

【0037】実施例19 スチレン−2エチルヘキシルアクリレート−nブチルメタ アクリレート系樹脂 80重量部 カーボンブラック(#44 三菱カーボン社製) 12重量部 低分子量ポリプロピレン 5重量部 ニグロシン染料 3重量部 上記組成の混合物を実施例17と同様な方法にてトナー
とした。本トナー100重量部に対し、コロイダルシリ
カ(日本アエロジル社製R−972)0.1重量部を添
加した。つぎに、下記組成物をボールミルを用いて室温
にて10時間分散溶解して塗布液として、スポンジ状材
質のトナー供給部材を浸漬し、110℃下で完全に溶媒
を蒸発させた。 例示化合物[化3]−(3) 5.0g 溶媒 トルエン 300g 本トナー供給部材4を実施例17と同様に現像装置に配
設した。前記トナーを本現像装置に補給し、トナー搬送
部材に−450Vトナー供給部材へ−100Vのバイア
スを印加し、実施例17と同様に現像させ、画像出しを
行ったところ、鮮明な画像が得られた。続けて、500
00枚連続複写したところ初期と変わりのない鮮明な画
像が得られた。また、トナー搬送部材上のトナーの比電
荷量(Q/M)は、初期+10.2(μc/g)と十分
であり、50000枚連続複写後のQ/Mは+9.9
(μc/g)と初期とほとんど変わらなかった。またさ
らに、35℃・90%RHの高温高湿下、及び10℃・
15%RHの低温低湿環境下でも常温常湿の時と同等の
画像品質が得られた。なお、前記塗布液を金属板表面に
コートしたものとトナーとの摩擦帯電性を上記のような
トナー吸引式比電荷量測定装置を応用して、その帯電極
性を調べたところ、前記塗布液を金属板表面にコートし
たものは、負極性に帯電した。
Example 19 Styrene-2 ethylhexyl acrylate-n-butyl methacrylate resin 80 parts by weight carbon black (# 44 manufactured by Mitsubishi Carbon Co.) 12 parts by weight Low molecular weight polypropylene 5 parts by weight Nigrosine dye 3 parts by weight A mixture of the above composition was carried out. A toner was prepared in the same manner as in Example 17. To 100 parts by weight of this toner, 0.1 part by weight of colloidal silica (R-972 manufactured by Nippon Aerosil Co., Ltd.) was added. Next, the following composition was dispersed and dissolved in a ball mill at room temperature for 10 hours to prepare a coating solution, which was dipped in a sponge-like toner supplying member, and the solvent was completely evaporated at 110 ° C. Exemplified Compound [Chemical Formula 3]-(3) 5.0 g Solvent Toluene 300 g The toner supply member 4 was placed in the developing device in the same manner as in Example 17. When the toner was replenished to the main developing device, a bias of -100V was applied to the toner conveying member of -450V and a toner supplying member was applied, and development was carried out in the same manner as in Example 17 to perform image development, and a clear image was obtained. It was Continuously, 500
When 00 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is sufficient as the initial +10.2 (μc / g), and the Q / M after continuous copying of 50,000 sheets is +9.9.
(Μc / g) was almost unchanged from the initial stage. Furthermore, under high temperature and high humidity of 35 ° C ・ 90% RH, and 10 ° C ・
Even under a low temperature and low humidity environment of 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. Incidentally, the triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction type specific charge amount measuring device as described above, and its charging polarity was examined. The product coated on the surface of the metal plate was negatively charged.

【0038】比較例4 実施例17と同様な装置及びトナーを用い、トナー搬送
部材に−250V、トナー供給部材に−300Vのバイ
アスを印加して、同様な画像出しを行ったところ、初期
から連続複写10000枚までは鮮明な画像が得られて
いたが、20000枚後には画像濃度が低下しはじめ、
50000枚後ではさらに画像濃度が低下し残像等も発
生し、トナー搬送部材上には均一なトナー薄層が形成さ
れておらず、トナー層厚規制部材及びトナー搬送部材の
表面にトナーフィルミングが発生していた。また、実施
例17と同様にトナー搬送部材上のトナーのQ/Mを測
定したところ、初期は+10.9(μc/g)、200
00枚後で+6.0(μc/g)、50000枚後では
+2.7(μc/g)であった。
Comparative Example 4 Using the same apparatus and toner as in Example 17, applying a bias of −250 V to the toner conveying member and a bias of −300 V to the toner supplying member, the same image was reproduced. A clear image was obtained up to 10,000 copies, but after 20,000 copies, the image density began to decrease.
After 50,000 sheets, the image density is further reduced and an afterimage is generated, and a uniform thin toner layer is not formed on the toner conveying member. Had occurred. Further, when the Q / M of the toner on the toner conveying member was measured in the same manner as in Example 17, the initial value was +10.9 (μc / g), 200
It was +6.0 (μc / g) after 00 sheets and +2.7 (μc / g) after 50,000 sheets.

【0039】実施例20 実施例17の例示化合物[化3]−(1)の代わりに例
示化合物[化3]−(4)をトナー供給部材4の被覆材
として使用した以外は実施例17と同様な装置及びトナ
ーで、トナー搬送部材に−350Vトナー供給部材へ−
200Vのバイアスを印加し、実施例17と同様に現像
させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+12.0
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+11.2(μc/g)と初期とほとんど変わ
らなかった。またさらに、35℃・90%RHの高温高
湿下、及び10℃・15%RHの低温低湿環境下でも常
温常湿の時と同等の画像品質が得られた。なお、前記塗
布液を金属板表面にコートしたものとトナーとの摩擦帯
電性を上記のようなトナー吸引比電荷量測定装置を応用
して、その帯電極性を調べたところ、前記塗布液を金属
板表面にコートしたものは、負極性に帯電した。
Example 20 Example 17 was repeated except that the exemplified compound [Chemical Formula 3]-(4) was used as a coating material for the toner supply member 4 instead of the exemplary compound [Chemical Formula 3]-(1) of Example 17. Using the same device and toner, -350V toner supply member for the toner conveying member-
A bias of 200 V was applied, development was performed in the same manner as in Example 17, and an image was formed. A clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +12.0.
(Μc / g) was sufficient, and the Q / M after continuous copying of 50,000 sheets was +11.2 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0040】実施例21 実施例18の例示化合物[化3]−(2)の代わりに例
示化合物[化3]−(6)をトナー供給部材4の被覆材
として使用した以外は実施例18と同様な装置及びトナ
ーで、トナー搬送部材に−300Vトナー供給部材へ−
150Vのバイアスを印加し、実施例18と同様に現像
させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+9.2
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+9.0(μc/g)と初期とほとんど変わら
なかった。またさらに、35℃・90%RHの高温高湿
下、及び10℃・15%RHの低温低湿環境下でも常温
常湿の時と同等の画像品質が得られた。なお、前記塗布
液を金属板表面にコートしたものとトナーとの摩擦帯電
性を上記のようなトナー吸引比電荷量測定装置を応用し
て、その帯電極性を調べたところ、前記塗布液を金属板
表面にコートしたものは、負極性に帯電した。
Example 21 As Example 18 except that the exemplified compound [Chemical Formula 3]-(6) was used as a coating material for the toner supply member 4 instead of the exemplary compound [Chemical Formula 3]-(2) of Example 18. With the same device and toner, to the toner conveying member-to the 300V toner supplying member-
When a bias of 150 V was applied and development was carried out in the same manner as in Example 18 and an image was formed, a clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +9.2.
(Μc / g) was sufficient, and the Q / M after continuous copying of 50,000 sheets was +9.0 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0041】実施例22 実施例18の例示化合物[化3]−(2)の代わりに例
示化合物[化3]−(8)をトナー供給部材4の被覆材
として使用した以外は実施例18と同様な装置及びトナ
ーで、トナー搬送部材に−400Vトナー供給部材へ−
200Vのバイアスを印加し、実施例18と同様に現像
させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+10.4
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+10.0(μc/g)と初期とほとんど変わ
らなかった。またさらに、35℃・90%RHの高温高
湿下、及び10℃・15%RHの低温低湿環境下でも常
温常湿の時と同等の画像品質が得られた。なお、前記塗
布液を金属板表面にコートしたものとトナーとの摩擦帯
電性を上記のようなトナー吸引比電荷量測定装置を応用
して、その帯電極性を調べたところ、前記塗布液を金属
板表面にコートしたものは、負極性に帯電した。
Example 22 Example 18 except that the exemplified compound [Chemical Formula 3]-(8) was used as a coating material for the toner supply member 4 instead of the exemplary compound [Chemical Formula 3]-(2) of Example 18. With the same device and toner, to the toner transport member-to the 400V toner supply member-
A bias of 200 V was applied, development was performed in the same manner as in Example 18, and an image was output. As a result, a clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +10.4.
(Μc / g) was sufficient, and the Q / M after continuous copying of 50,000 sheets was +10.0 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0042】実施例23 実施例17の例示化合物[化3]−(1)の代わりに例
示化合物[化3]−(10)をトナー供給部材4の被覆
材として使用した以外は実施例17と同様な装置及びト
ナーで、トナー搬送部材に−300Vトナー供給部材へ
−200Vのバイアスを印加し、実施例17と同様に現
像させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+10.0
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+9.8(μc/g)と初期とほとんど変わら
なかった。またさらに、35℃・90%RHの高温高湿
下、及び10℃・15%RHの低温低湿環境下でも常温
常湿の時と同等の画像品質が得られた。なお、前記塗布
液を金属板表面にコートしたものとトナーとの摩擦帯電
性を上記のようなトナー吸引比電荷量測定装置を応用し
て、その帯電極性を調べたところ、前記塗布液を金属板
表面にコートしたものは、負極性に帯電した。
Example 23 As Example 17 except that the exemplified compound [Chemical Formula 3]-(10) was used as a coating material for the toner supply member 4 instead of the exemplary compound [Chemical Formula 3]-(1) of Example 17. Using the same apparatus and toner, a bias of -200V was applied to the toner feeding member to the -300V toner supplying member, development was performed in the same manner as in Example 17, and image development was performed. As a result, a clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +10.0.
(Μc / g) was sufficient, and the Q / M after continuous copying of 50,000 sheets was +9.8 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0043】実施例24 実施例17の例示化合物[化3]−(1)の代わりに例
示化合物[化3]−(12)をトナー供給部材4の被覆
材として使用した以外は実施例17と同様な装置及びト
ナーで、トナー搬送部材に−250Vトナー供給部材へ
−100Vのバイアスを印加し、実施例17と同様に現
像させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+12.4
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+11.8(μc/g)と初期とほとんど変わ
らなかった。またさらに、35℃・90%RHの高温高
湿下、及び10℃・15%RHの低温低湿環境下でも常
温常湿の時と同等の画像品質が得られた。なお、前記塗
布液を金属板表面にコートしたものとトナーとの摩擦帯
電性を上記のようなトナー吸引比電荷量測定装置を応用
して、その帯電極性を調べたところ、前記塗布液を金属
板表面にコートしたものは、負極性に帯電した。
Example 24 As Example 17 except that the exemplified compound [Chemical Formula 3]-(12) was used as a coating material for the toner supply member 4 instead of the exemplary compound [Chemical Formula 3]-(1) of Example 17. Using the same apparatus and toner, a bias of -100 V was applied to the toner feeding member of -250 V to the toner supplying member, development was carried out in the same manner as in Example 17, and image formation was carried out. As a result, a clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +12.4.
(Μc / g) was sufficient, and the Q / M after continuous copying of 50,000 sheets was +11.8 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0044】実施例25 スチレン系樹脂(D−125 エッソ社製) 85重量部 カーボンブラック(#44 三菱カーボン社製) 12重量部 ニグロシン染料 3重量部 上記組成の混合物をヘンシェルミキサー中で十分撹拌混
合した後、熱ロールミルで溶融混練し、室温まで冷却し
ハンマーミルを用いて粗粉砕し、ついで、エアージェッ
トミルにて微粉砕する。得られた微粉末を分級し粒径5
〜25μmのトナーを得た。つぎに、下記組成物をボー
ルミルを用いて室温にて10時間分散溶解して塗布液と
して、スポンジ状材質のトナー供給部材を浸漬し、11
0℃下で完全に溶媒を蒸発させた。 例示化合物[化4]−(1) 5.0g 溶媒 トルエン 300g 図に示すように、本トナー供給部材4をトナー搬送部材
2及びトナー層厚規制部材3からなる現像装置に配設し
た。この現像装置を用いた現像方法について説明する
と、図に示すように、トナータンク7に内蔵されている
トナー6は撹拌羽根5によりトナー供給部材4に強制的
に寄せられ、トナーはトナー供給部材4に供給される。
そして、トナー供給部材4に取り込まれたトナーはトナ
ー供給部材が矢印方向に回転することにより、トナー搬
送部材2に運ばれ、摩擦され、静電的あるいは物理的に
吸着し、トナー搬送部材2が矢印方向に強く回転し、ト
ナー層厚規制部材3によって均一なトナー薄層が形成さ
れるとともに摩擦帯電する。その後トナー搬送部材2と
接触もしくは近接している潜像担持体1の表面に運ばれ
潜像が現像される。本実施例では、前記トナーを本現像
装置に補給し、トナー搬送部材に−200Vトナー供給
部材へ−100Vのバイアスを印加し、マイナス潜像を
有する感光体に現像させ、転写・定着工程を経て画像出
しを行ったところ、鮮明な画像を得た。続けて、500
00枚連続複写したところ初期と変わりのない鮮明な画
像が得られた。また、トナー搬送部材上のトナーの比電
荷量(Q/M)を、出口側にフィルターを具備したファ
ラデーケージ(図示せず)を介し、トナー搬送部材上の
トナーを吸引しファラデーケージ内にトラップされたト
ナーの比電荷を測定する吸引式比電荷量測定装置を用い
て、測定したところ、+12.4(μc/g)と十分な
比電荷量であり、50000枚連続複写後のQ/Mは+
11.7(μc/g)と初期とほとんど変わらなかっ
た。またさらに、35℃・90%RHの高温高湿下、及
び10℃・15%RHの低温低湿環境下でも常温常湿の
時と同等の画像品質が得られた。なお、前記塗布液を金
属板表面にコートしたものとトナーとの摩擦帯電性を上
記のようなトナー吸引式比電荷量測定装置を応用して、
その帯電極性を調べたところ、前記塗布液を金属板表面
にコートしたものは、負極性に帯電した。
Example 25 Styrenic resin (D-125 manufactured by Esso Co.) 85 parts by weight Carbon black (# 44 manufactured by Mitsubishi Carbon Co.) 12 parts by weight Nigrosine dye 3 parts by weight The mixture having the above composition is sufficiently stirred and mixed in a Henschel mixer. After that, the mixture is melt-kneaded with a hot roll mill, cooled to room temperature, coarsely pulverized with a hammer mill, and then finely pulverized with an air jet mill. The fine powder obtained is classified to have a particle size of 5
A toner of ˜25 μm was obtained. Next, the following composition was dispersed and dissolved in a ball mill at room temperature for 10 hours to prepare a coating solution, and a toner supply member made of a sponge-like material was immersed in the coating solution.
The solvent was completely evaporated at 0 ° C. Exemplified Compound [Chemical Formula 4]-(1) 5.0 g Solvent Toluene 300 g As shown in the figure, the toner supplying member 4 was disposed in a developing device including the toner conveying member 2 and the toner layer thickness regulating member 3. A developing method using this developing device will be described. As shown in the figure, the toner 6 contained in the toner tank 7 is forcibly drawn to the toner supply member 4 by the stirring blade 5, and the toner is supplied to the toner supply member 4. Is supplied to.
Then, the toner taken into the toner supply member 4 is conveyed to the toner conveying member 2 by the rotation of the toner supplying member in the direction of the arrow, and is rubbed and electrostatically or physically adsorbed, and the toner conveying member 2 is It strongly rotates in the direction of the arrow, and a uniform toner thin layer is formed by the toner layer thickness regulating member 3 and is triboelectrically charged. After that, the toner is conveyed to the surface of the latent image carrier 1 which is in contact with or in the vicinity of the toner conveying member 2 and the latent image is developed. In this embodiment, the toner is supplied to the main developing device, a bias of −100 V is applied to the toner feeding member of −200 V to the toner feeding member to develop it on the photoconductor having a negative latent image, and the transfer / fixing process is performed. When the image was displayed, a clear image was obtained. Continuously, 500
When 00 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner carrying member is trapped in the Faraday cage by sucking the toner on the toner carrying member through a Faraday cage (not shown) equipped with a filter on the outlet side. It was +12.4 (μc / g), which was a sufficient specific charge amount when measured with a suction type specific charge amount measuring device for measuring the specific charge of the toner, and the Q / M after 50,000 sheets were continuously copied. Is +
The value was 11.7 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. In addition, applying the toner suction type specific charge amount measuring device as described above to the triboelectrification property of the coating liquid on the surface of a metal plate and the toner,
When the charging polarity was examined, the coating liquid coated on the surface of the metal plate was negatively charged.

【0045】実施例26 スチレン−アクリル系樹脂(SBM−73 三洋化成製) 80重量部 カーボンブラック(#44 三菱カーボン社製) 10重量部 低分子量ポリプロピレン 5重量部 4級アンモニウム塩 5重量部 上記組成の混合物を実施例25と同様な方法にてトナー
とした。本トナー100重量部に対し、コロイダルシリ
カ(日本アエロジル社製R−972)0.1重量部を添
加した。つぎに、下記組成物をボールミルを用いて室温
にて10時間分散溶解して塗布液として、スポンジ状材
質のトナー供給部材を浸漬し、110℃下で完全に溶媒
を蒸発させた。 例示化合物[化4]−(2)+アクリル樹脂 10+20g 溶媒 トルエン 1000g 本トナー供給部材4を実施例25と同様に現像装置に配
設した。前記トナーを本現像装置に補給し、トナー搬送
部材に−300Vトナー供給部材へ−200Vのバイア
スを印加し、実施例25と同様に現像させ、画像出しを
行ったところ、鮮明な画像が得られた。続けて、500
00枚連続複写したところ初期と変わりのない鮮明な画
像が得られた。また、トナー搬送部材上のトナーの比電
荷量(Q/M)は、初期+12.0(μc/g)と十分
であり、50000枚連続複写後のQ/Mは+11.8
(μc/g)と初期とほとんど変わらなかった。またさ
らに、35℃・90%RHの高温高湿下、及び10℃・
15%RHの低温低湿環境下でも常温常湿の時と同等の
画像品質が得られた。なお、前記塗布液を金属板表面に
コートしたものとトナーとの摩擦帯電性を上記のような
トナー吸引式比電荷量測定装置を応用して、その帯電極
性を調べたところ、前記塗布液を金属板表面にコートし
たものは、負極性に帯電した。
Example 26 Styrene-acrylic resin (SBM-73, manufactured by Sanyo Kasei) 80 parts by weight Carbon black (# 44, manufactured by Mitsubishi Carbon Co.) 10 parts by weight Low molecular weight polypropylene 5 parts by weight Quaternary ammonium salt 5 parts by weight The mixture was used as a toner in the same manner as in Example 25. To 100 parts by weight of this toner, 0.1 part by weight of colloidal silica (R-972 manufactured by Nippon Aerosil Co., Ltd.) was added. Next, the following composition was dispersed and dissolved in a ball mill at room temperature for 10 hours to prepare a coating solution, which was dipped in a sponge-like toner supplying member, and the solvent was completely evaporated at 110 ° C. Exemplified Compound [Chemical Formula 4]-(2) + Acrylic Resin 10 + 20 g Solvent Toluene 1000 g The toner supply member 4 was placed in the developing device in the same manner as in Example 25. The toner was replenished to the main developing device, a bias of −200 V was applied to the toner feeding member of −300 V, and the toner was developed in the same manner as in Example 25 to perform image development, and a clear image was obtained. It was Continuously, 500
When 00 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is sufficient as the initial value of +12.0 (μc / g), and the Q / M after continuous copying of 50,000 sheets is +11.8.
(Μc / g) was almost unchanged from the initial stage. Furthermore, under high temperature and high humidity of 35 ° C ・ 90% RH, and 10 ° C ・
Even under a low temperature and low humidity environment of 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. Incidentally, the triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction type specific charge amount measuring device as described above, and its charging polarity was examined. The product coated on the surface of the metal plate was negatively charged.

【0046】実施例27 スチレン−2エチルヘキシルアクリレート−nブチルメタ アクリレート系樹脂 80重量部 カーボンブラック(#44 三菱カーボン社製) 12重量部 低分子量ポリプロピレン 5重量部 ニグロシン染料 3重量部 上記組成の混合物を実施例25と同様な方法にてトナー
とした。本トナー100重量部に対し、コロイダルシリ
カ(日本アエロジル社製R−972)0.1重量部を添
加した。つぎに、下記組成物をボールミルを用いて室温
にて10時間分散溶解して塗布液として、スポンジ状材
質のトナー供給部材を浸漬し、110℃下で完全に溶媒
を蒸発させた。 例示化合物[化4]−(3) 5.0g 溶媒 トルエン 300g 本トナー供給部材4を実施例25と同様に現像装置に配
設した。前記トナーを本現像装置に補給し、トナー搬送
部材に−450Vトナー供給部材へ−100Vのバイア
スを印加し、実施例25と同様に現像させ、画像出しを
行ったところ、鮮明な画像が得られた。続けて、500
00枚連続複写したところ初期と変わりのない鮮明な画
像が得られた。また、トナー搬送部材上のトナーの比電
荷量(Q/M)は、初期+11.7(μc/g)と十分
であり、50000枚連続複写後のQ/Mは+10.6
(μc/g)と初期とほとんど変わらなかった。またさ
らに、35℃・90%RHの高温高湿下、及び10℃・
15%RHの低温低湿環境下でも常温常湿の時と同等の
画像品質が得られた。なお、前記塗布液を金属板表面に
コートしたものとトナーとの摩擦帯電性を上記のような
トナー吸引式比電荷量測定装置を応用して、その帯電極
性を調べたところ、前記塗布液を金属板表面にコートし
たものは、負極性に帯電した。
Example 27 Styrene-2 ethylhexyl acrylate-n-butyl methacrylate resin 80 parts by weight carbon black (# 44 manufactured by Mitsubishi Carbon Co.) 12 parts by weight Low molecular weight polypropylene 5 parts by weight Nigrosine dye 3 parts by weight A mixture of the above composition was carried out. A toner was prepared in the same manner as in Example 25. To 100 parts by weight of this toner, 0.1 part by weight of colloidal silica (R-972 manufactured by Nippon Aerosil Co., Ltd.) was added. Next, the following composition was dispersed and dissolved in a ball mill at room temperature for 10 hours to prepare a coating solution, which was dipped in a sponge-like toner supplying member, and the solvent was completely evaporated at 110 ° C. Exemplified Compound [Chemical Formula 4]-(3) 5.0 g Solvent Toluene 300 g The toner supply member 4 was placed in the developing device in the same manner as in Example 25. When the toner was replenished to the main developing device, a bias of -100V was applied to the toner feeding member of -450V to the toner feeding member, development was performed in the same manner as in Example 25, and an image was formed, and a clear image was obtained. It was Continuously, 500
When 00 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is sufficient as the initial value of +11.7 (μc / g), and the Q / M after continuous copying of 50,000 sheets is +10.6.
(Μc / g) was almost unchanged from the initial stage. Furthermore, under high temperature and high humidity of 35 ° C ・ 90% RH, and 10 ° C ・
Even under a low temperature and low humidity environment of 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. Incidentally, the triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction type specific charge amount measuring device as described above, and its charging polarity was examined. The product coated on the surface of the metal plate was negatively charged.

【0047】比較例5 実施例25と同様な装置及びトナーを用い、トナー搬送
部材に−250V、トナー供給部材に−300Vのバイ
アスを印加して、同様な画像出しを行ったところ、初期
から連続複写10000枚までは鮮明な画像が得られて
いたが、20000枚後には画像濃度が低下しはじめ、
50000枚後ではさらに画像濃度が低下し残像等も発
生し、トナー搬送部材上には均一なトナー薄層が形成さ
れておらず、トナー層厚規制部材及びトナー搬送部材の
表面にトナーフィルミングが発生していた。また、実施
例25と同様にトナー搬送部材上のトナーのQ/Mを測
定したところ、初期は+11.8(μc/g)、200
00枚後で+6.0(μc/g)、50000枚後では
+3.1(μc/g)であった。
Comparative Example 5 Using the same apparatus and toner as in Example 25, applying a bias of −250 V to the toner conveying member and a bias of −300 V to the toner supplying member, a similar image was formed. A clear image was obtained up to 10,000 copies, but after 20,000 copies, the image density began to decrease.
After 50,000 sheets, the image density is further reduced and an afterimage is generated, and a uniform thin toner layer is not formed on the toner conveying member. Had occurred. Further, when the Q / M of the toner on the toner conveying member was measured in the same manner as in Example 25, the initial value was +11.8 (μc / g), 200
It was +6.0 (μc / g) after 00 sheets and +3.1 (μc / g) after 50,000 sheets.

【0048】実施例28 実施例25の例示化合物[化4]−(1)の代わりに例
示化合物[化4]−(4)をトナー供給部材4の被覆材
として使用した以外は実施例25と同様な装置及びトナ
ーで、トナー搬送部材に−350Vトナー供給部材へ−
200Vのバイアスを印加し、実施例25と同様に現像
させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+13.0
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+12.1(μc/g)と初期とほとんど変わ
らなかった。またさらに、35℃・90%RHの高温高
湿下、及び10℃・15%RHの低温低湿環境下でも常
温常湿の時と同等の画像品質が得られた。なお、前記塗
布液を金属板表面にコートしたものとトナーとの摩擦帯
電性を上記のようなトナー吸引比電荷量測定装置を応用
して、その帯電極性を調べたところ、前記塗布液を金属
板表面にコートしたものは、負極性に帯電した。
Example 28 As Example 25 except that the exemplified compound [Chemical Formula 4]-(4) was used as a coating material for the toner supply member 4 instead of the exemplified compound [Chemical Formula 4]-(1) of Example 25. Using the same device and toner, -350V toner supply member for the toner conveying member-
A bias of 200 V was applied, development was performed in the same manner as in Example 25, and an image was formed. A clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is +13.0 at the initial stage.
(Μc / g) was sufficient, and the Q / M after continuous copying of 50,000 sheets was +12.1 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0049】実施例29 実施例26の例示化合物[化4]−(2)の代わりに例
示化合物[化4]−(6)をトナー供給部材4の被覆材
として使用した以外は実施例26と同様な装置及びトナ
ーで、トナー搬送部材に−300Vトナー供給部材へ−
150Vのバイアスを印加し、実施例26と同様に現像
させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+9.2
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+8.9(μc/g)と初期とほとんど変わら
なかった。またさらに、35℃・90%RHの高温高湿
下、及び10℃・15%RHの低温低湿環境下でも常温
常湿の時と同等の画像品質が得られた。なお、前記塗布
液を金属板表面にコートしたものとトナーとの摩擦帯電
性を上記のようなトナー吸引比電荷量測定装置を応用し
て、その帯電極性を調べたところ、前記塗布液を金属板
表面にコートしたものは、負極性に帯電した。
Example 29 Example 26 is the same as Example 26 except that the exemplified compound [Chemical formula 4]-(6) was used as a coating material for the toner supply member 4 instead of the exemplified compound [Chemical formula 4]-(2). With the same device and toner, -300V toner supply member to the toner conveying member-
A bias of 150 V was applied, development was carried out in the same manner as in Example 26, and an image was formed. A clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +9.2.
(Μc / g) was sufficient, and the Q / M after continuous copying of 50,000 sheets was +8.9 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0050】実施例30 実施例26の例示化合物[化4]−(2)の代わりに例
示化合物[化4]−(8)をトナー供給部材4の被覆材
として使用した以外は実施例26と同様な装置及びトナ
ーで、トナー搬送部材に−400Vトナー供給部材へ−
200Vのバイアスを印加し、実施例26と同様に現像
させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+9.4
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+8.6(μc/g)と初期とほとんど変わら
なかった。またさらに、35℃・90%RHの高温高湿
下、及び10℃・15%RHの低温低湿環境下でも常温
常湿の時と同等の画像品質が得られた。なお、前記塗布
液を金属板表面にコートしたものとトナーとの摩擦帯電
性を上記のようなトナー吸引比電荷量測定装置を応用し
て、その帯電極性を調べたところ、前記塗布液を金属板
表面にコートしたものは、負極性に帯電した。
Example 30 Example 26 except that the exemplified compound [Chemical Formula 4]-(8) was used as a coating material for the toner supply member 4 instead of the exemplary compound [Chemical Formula 4]-(2) of Example 26. With the same device and toner, to the toner transport member-to the 400V toner supply member-
A bias of 200 V was applied, development was performed in the same manner as in Example 26, and an image was formed. A clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. In addition, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +9.4.
(Μc / g) was sufficient, and the Q / M after continuous copying of 50,000 sheets was +8.6 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0051】実施例31 実施例25の例示化合物[化4]−(1)の代わりに例
示化合物[化4]−(10)をトナー供給部材4の被覆
材として使用した以外は実施例25と同様な装置及びト
ナーで、トナー搬送部材に−300Vトナー供給部材へ
−200Vのバイアスを印加し、実施例25と同様に現
像させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+10.0
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+8.3(μc/g)と初期とほとんど変わら
なかった。またさらに、35℃・90%RHの高温高湿
下、及び10℃・15%RHの低温低湿環境下でも常温
常湿の時と同等の画像品質が得られた。なお、前記塗布
液を金属板表面にコートしたものとトナーとの摩擦帯電
性を上記のようなトナー吸引比電荷量測定装置を応用し
て、その帯電極性を調べたところ、前記塗布液を金属板
表面にコートしたものは、負極性に帯電した。
Example 31 As Example 25 except that the exemplified compound [Chemical Formula 4]-(10) was used as a coating material for the toner supply member 4 instead of the exemplified compound [Chemical Formula 4]-(1) of Example 25. Using the same apparatus and toner, a bias of -200V was applied to the toner feeding member to the -300V toner supplying member, development was carried out in the same manner as in Example 25, and image development was carried out. As a result, a clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +10.0.
(Μc / g) was sufficient, and the Q / M after continuous copying of 50,000 sheets was +8.3 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0052】実施例32 実施例25の例示化合物[化4]−(1)の代わりに例
示化合物[化4]−(12)をトナー供給部材4の被覆
材として使用した以外は実施例25と同様な装置及びト
ナーで、トナー搬送部材に−250Vトナー供給部材へ
−100Vのバイアスを印加し、実施例25と同様に現
像させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+12.0
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+11.4(μc/g)と初期とほとんど変わ
らなかった。またさらに、35℃・90%RHの高温高
湿下、及び10℃・15%RHの低温低湿環境下でも常
温常湿の時と同等の画像品質が得られた。なお、前記塗
布液を金属板表面にコートしたものとトナーとの摩擦帯
電性を上記のようなトナー吸引比電荷量測定装置を応用
して、その帯電極性を調べたところ、前記塗布液を金属
板表面にコートしたものは、負極性に帯電した。
Example 32 Example 25 was repeated except that the exemplified compound [Chemical Formula 4]-(12) was used as a coating material for the toner supply member 4 instead of the exemplified compound [Chemical Formula 4]-(1) of Example 25. Using the same apparatus and toner, a bias of -100 V was applied to the toner feeding member of -250 V to the toner supplying member, development was performed in the same manner as in Example 25, and an image was formed. A clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +12.0.
(Μc / g) was sufficient, and the Q / M after continuous copying of 50,000 sheets was +11.4 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0053】実施例33 スチレン系樹脂(D−125 エッソ社製) 85重量部 カーボンブラック(#44 三菱カーボン社製) 12重量部 ニグロシン染料 3重量部 上記組成の混合物をヘンシェルミキサー中で十分撹拌混
合した後、熱ロールミルで溶融混練し、室温まで冷却し
ハンマーミルを用いて粗粉砕し、ついで、エアージェッ
トミルにて微粉砕する。得られた微粉末を分級し粒径5
〜25μmのトナーを得た。つぎに、下記組成物をボー
ルミルを用いて室温にて10時間分散溶解して塗布液と
して、スポンジ状材質のトナー供給部材を浸漬し、11
0℃下で完全に溶媒を蒸発させた。 例示化合物[化5]−(1) 5.0g 溶媒 水/イソプロピルアルコール(1:1) 300g 図に示すように、本トナー供給部材4をトナー搬送部材
2及びトナー層厚規制部材3からなる現像装置に配設し
た。この現像装置を用いた現像方法について説明する
と、図に示すように、トナータンク7に内蔵されている
トナー6は撹拌羽根5によりトナー供給部材4に強制的
に寄せられ、トナーはトナー供給部材4に供給される。
そして、トナー供給部材4に取り込まれたトナーはトナ
ー供給部材が矢印方向に回転することにより、トナー搬
送部材2に運ばれ、摩擦され、静電的あるいは物理的に
吸着し、トナー搬送部材2が矢印方向に強く回転し、ト
ナー層厚規制部材3によって均一なトナー薄層が形成さ
れるとともに摩擦帯電する。その後トナー搬送部材2と
接触もしくは近接している潜像担持体1の表面に運ばれ
潜像が現像される。本実施例では、前記トナーを本現像
装置に補給し、トナー搬送部材に−200Vトナー供給
部材へ−100Vのバイアスを印加し、マイナス潜像を
有する感光体に現像させ、転写・定着工程を経て画像出
しを行ったところ、鮮明な画像を得た。続けて、500
00枚連続複写したところ初期と変わりのない鮮明な画
像が得られた。また、トナー搬送部材上のトナーの比電
荷量(Q/M)を、出口側にフィルターを具備したファ
ラデーケージ(図示せず)を介し、トナー搬送部材上の
トナーを吸引しファラデーケージ内にトラップされたト
ナーの比電荷を測定する吸引式比電荷量測定装置を用い
て、測定したところ、+12.4(μc/g)と十分な
比電荷量であり、50000枚連続複写後のQ/Mは+
11.5(μc/g)と初期とほとんど変わらなかっ
た。またさらに、35℃・90%RHの高温高湿下、及
び10℃・15%RHの低温低湿環境下でも常温常湿の
時と同等の画像品質が得られた。なお、前記塗布液を金
属板表面にコートしたものとトナーとの摩擦帯電性を上
記のようなトナー吸引式比電荷量測定装置を応用して、
その帯電極性を調べたところ、前記塗布液を金属板表面
にコートしたものは、負極性に帯電した。
Example 33 Styrene-based resin (D-125 manufactured by Esso) 85 parts by weight Carbon black (# 44 manufactured by Mitsubishi Carbon Co.) 12 parts by weight Nigrosine dye 3 parts by weight The mixture having the above composition is sufficiently stirred and mixed in a Henschel mixer. After that, the mixture is melt-kneaded with a hot roll mill, cooled to room temperature, coarsely pulverized with a hammer mill, and then finely pulverized with an air jet mill. The fine powder obtained is classified to have a particle size of 5
A toner of ˜25 μm was obtained. Next, the following composition was dispersed and dissolved in a ball mill at room temperature for 10 hours to prepare a coating solution, and a toner supply member made of a sponge-like material was immersed in the coating solution.
The solvent was completely evaporated at 0 ° C. Exemplified Compound [Chemical Formula 5]-(1) 5.0 g Solvent Water / Isopropyl alcohol (1: 1) 300 g Placed in the device. A developing method using this developing device will be described. As shown in the figure, the toner 6 contained in the toner tank 7 is forcibly drawn to the toner supply member 4 by the stirring blade 5, and the toner is supplied to the toner supply member 4. Is supplied to.
Then, the toner taken into the toner supply member 4 is conveyed to the toner conveying member 2 by the rotation of the toner supplying member in the direction of the arrow, and is rubbed and electrostatically or physically adsorbed, and the toner conveying member 2 is It strongly rotates in the direction of the arrow, and a uniform toner thin layer is formed by the toner layer thickness regulating member 3 and is triboelectrically charged. After that, the toner is conveyed to the surface of the latent image carrier 1 which is in contact with or in the vicinity of the toner conveying member 2 and the latent image is developed. In this embodiment, the toner is supplied to the main developing device, a bias of −100 V is applied to the toner feeding member of −200 V to the toner feeding member to develop it on the photoconductor having a negative latent image, and the transfer / fixing process is performed. When the image was displayed, a clear image was obtained. Continuously, 500
When 00 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner carrying member is trapped in the Faraday cage by sucking the toner on the toner carrying member through a Faraday cage (not shown) equipped with a filter on the outlet side. It was +12.4 (μc / g), which was a sufficient specific charge amount when measured with a suction type specific charge amount measuring device for measuring the specific charge of the toner, and the Q / M after 50,000 sheets were continuously copied. Is +
The value was 11.5 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. In addition, applying the toner suction type specific charge amount measuring device as described above to the triboelectrification property of the coating liquid on the surface of a metal plate and the toner,
When the charging polarity was examined, the coating liquid coated on the surface of the metal plate was negatively charged.

【0054】実施例34 スチレン−アクリル系樹脂(SBM−73 三洋化成製) 80重量部 カーボンブラック(#44 三菱カーボン社製) 10重量部 低分子量ポリプロピレン 5重量部 4級アンモニウム塩 5重量部 上記組成の混合物を実施例33と同様な方法にてトナー
とした。本トナー100重量部に対し、コロイダルシリ
カ(日本アエロジル社製R−972)0.1重量部を添
加した。つぎに、下記組成物をボールミルを用いて室温
にて10時間分散溶解して塗布液として、スポンジ状材
質のトナー供給部材を浸漬し、110℃下で完全に溶媒
を蒸発させた。 例示化合物[化5]−(2)+アクリル樹脂 10+20g 溶媒 水/イソプロピルアルコール(1:1) 1000g 本トナー供給部材4を実施例33と同様に現像装置に配
設した。前記トナーを本現像装置に補給し、トナー搬送
部材に−300Vトナー供給部材へ−200Vのバイア
スを印加し、実施例33と同様に現像させ、画像出しを
行ったところ、鮮明な画像が得られた。続けて、500
00枚連続複写したところ初期と変わりのない鮮明な画
像が得られた。また、トナー搬送部材上のトナーの比電
荷量(Q/M)は、初期+10.9(μc/g)と十分
であり、50000枚連続複写後のQ/Mは+10.0
(μc/g)と初期とほとんど変わらなかった。またさ
らに、35℃・90%RHの高温高湿下、及び10℃・
15%RHの低温低湿環境下でも常温常湿の時と同等の
画像品質が得られた。なお、前記塗布液を金属板表面に
コートしたものとトナーとの摩擦帯電性を上記のような
トナー吸引式比電荷量測定装置を応用して、その帯電極
性を調べたところ、前記塗布液を金属板表面にコートし
たものは、負極性に帯電した。
Example 34 Styrene-acrylic resin (SBM-73 manufactured by Sanyo Kasei) 80 parts by weight Carbon black (# 44 manufactured by Mitsubishi Carbon Co., Ltd.) 10 parts by weight Low molecular weight polypropylene 5 parts by weight Quaternary ammonium salt 5 parts by weight The mixture was used as a toner in the same manner as in Example 33. To 100 parts by weight of this toner, 0.1 part by weight of colloidal silica (R-972 manufactured by Nippon Aerosil Co., Ltd.) was added. Next, the following composition was dispersed and dissolved in a ball mill at room temperature for 10 hours to prepare a coating solution, which was dipped in a sponge-like toner supplying member, and the solvent was completely evaporated at 110 ° C. Exemplified Compound [Chemical Formula 5]-(2) + Acrylic Resin 10 + 20 g Solvent Water / Isopropyl Alcohol (1: 1) 1000 g The toner supply member 4 was placed in the developing device in the same manner as in Example 33. The toner was replenished to the main developing device, a bias of −200V was applied to the toner feeding member of −300V, and the toner was developed in the same manner as in Example 33 to perform image development, and a clear image was obtained. It was Continuously, 500
When 00 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is +10.9 (μc / g) at the beginning, which is sufficient, and the Q / M after continuous copying of 50,000 sheets is +10.0.
(Μc / g) was almost unchanged from the initial stage. Furthermore, under high temperature and high humidity of 35 ° C ・ 90% RH, and 10 ° C ・
Even under a low temperature and low humidity environment of 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. Incidentally, the triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction type specific charge amount measuring device as described above, and its charging polarity was examined. The product coated on the surface of the metal plate was negatively charged.

【0055】実施例35 スチレン−2エチルヘキシルアクリレート−nブチルメタ アクリレート系樹脂 80重量部 カーボンブラック(#44 三菱カーボン社製) 12重量部 低分子量ポリプロピレン 5重量部 ニグロシン染料 3重量部 上記組成の混合物を実施例33と同様な方法にてトナー
とした。本トナー100重量部に対し、コロイダルシリ
カ(日本アエロジル社製R−972)0.1重量部を添
加した。つぎに、下記組成物をボールミルを用いて室温
にて10時間分散溶解して塗布液として、スポンジ状材
質のトナー供給部材を浸漬し、110℃下で完全に溶媒
を蒸発させた。 例示化合物[化5]−(3) 5.0g 溶媒 トルエン 300g 本トナー供給部材4を実施例33と同様に現像装置に配
設した。前記トナーを本現像装置に補給し、トナー搬送
部材に−450Vトナー供給部材へ−100Vのバイア
スを印加し、実施例33と同様に現像させ、画像出しを
行ったところ、鮮明な画像が得られた。続けて、500
00枚連続複写したところ初期と変わりのない鮮明な画
像が得られた。また、トナー搬送部材上のトナーの比電
荷量(Q/M)は、初期+11.7(μc/g)と十分
であり、50000枚連続複写後のQ/Mは+10.4
(μc/g)と初期とほとんど変わらなかった。またさ
らに、35℃・90%RHの高温高湿下、及び10℃・
15%RHの低温低湿環境下でも常温常湿の時と同等の
画像品質が得られた。なお、前記塗布液を金属板表面に
コートしたものとトナーとの摩擦帯電性を上記のような
トナー吸引式比電荷量測定装置を応用して、その帯電極
性を調べたところ、前記塗布液を金属板表面にコートし
たものは、負極性に帯電した。
Example 35 Styrene-2 ethylhexyl acrylate-n-butyl methacrylate resin 80 parts by weight carbon black (# 44 manufactured by Mitsubishi Carbon Co.) 12 parts by weight Low molecular weight polypropylene 5 parts by weight Nigrosine dye 3 parts by weight A mixture of the above composition was carried out. A toner was prepared in the same manner as in Example 33. To 100 parts by weight of this toner, 0.1 part by weight of colloidal silica (R-972 manufactured by Nippon Aerosil Co., Ltd.) was added. Next, the following composition was dispersed and dissolved in a ball mill at room temperature for 10 hours to prepare a coating solution, which was dipped in a sponge-like toner supplying member, and the solvent was completely evaporated at 110 ° C. Exemplified Compound [Chemical Formula 5]-(3) 5.0 g Solvent Toluene 300 g The toner supply member 4 was placed in the developing device in the same manner as in Example 33. The toner was replenished to the main developing device, a bias of -100V was applied to the toner feeding member of -450V to the toner feeding member, the development was performed in the same manner as in Example 33, and an image was formed. A clear image was obtained. It was Continuously, 500
When 00 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is sufficient as the initial value of +11.7 (μc / g), and the Q / M after continuous copying of 50,000 sheets is +10.4.
(Μc / g) was almost unchanged from the initial stage. Furthermore, under high temperature and high humidity of 35 ° C ・ 90% RH, and 10 ° C ・
Even under a low temperature and low humidity environment of 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. Incidentally, the triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction type specific charge amount measuring device as described above, and its charging polarity was examined. The product coated on the surface of the metal plate was negatively charged.

【0056】比較例5 実施例33と同様な装置及びトナーを用い、トナー搬送
部材に−250V、トナー供給部材に−300Vのバイ
アスを印加して、同様な画像出しを行ったところ、初期
から連続複写10000枚までは鮮明な画像が得られて
いたが、20000枚後には画像濃度が低下しはじめ、
50000枚後ではさらに画像濃度が低下し残像等も発
生し、トナー搬送部材上には均一なトナー薄層が形成さ
れておらず、トナー層厚規制部材及びトナー搬送部材の
表面にトナーフィルミングが発生していた。また、実施
例33と同様にトナー搬送部材上のトナーのQ/Mを測
定したところ、初期は+12.3(μc/g)、200
00枚後で+5.9(μc/g)、50000枚後では
+1.6(μc/g)であった。
Comparative Example 5 Using the same apparatus and toner as in Example 33, applying a bias of −250 V to the toner conveying member and a bias of −300 V to the toner supplying member, a similar image was formed. A clear image was obtained up to 10,000 copies, but after 20,000 copies, the image density began to decrease.
After 50,000 sheets, the image density is further reduced and an afterimage is generated, and a uniform thin toner layer is not formed on the toner conveying member. Had occurred. Further, when the Q / M of the toner on the toner conveying member was measured in the same manner as in Example 33, the initial value was +12.3 (μc / g), 200
It was +5.9 (μc / g) after 00 sheets and +1.6 (μc / g) after 50,000 sheets.

【0057】実施例36 実施例33の例示化合物[化5]−(1)の代わりに例
示化合物[化5]−(4)をトナー供給部材4の被覆材
として使用した以外は実施例33と同様な装置及びトナ
ーで、トナー搬送部材に−350Vトナー供給部材へ−
200Vのバイアスを印加し、実施例33と同様に現像
させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+12.9
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+11.8(μc/g)と初期とほとんど変わ
らなかった。またさらに、35℃・90%RHの高温高
湿下、及び10℃・15%RHの低温低湿環境下でも常
温常湿の時と同等の画像品質が得られた。なお、前記塗
布液を金属板表面にコートしたものとトナーとの摩擦帯
電性を上記のようなトナー吸引比電荷量測定装置を応用
して、その帯電極性を調べたところ、前記塗布液を金属
板表面にコートしたものは、負極性に帯電した。
Example 36 As Example 33 except that the exemplified compound [Chemical Formula 5]-(4) was used as a coating material for the toner supply member 4 instead of the exemplary compound [Chemical Formula 5]-(1) of Example 33. Using the same device and toner, -350V toner supply member for the toner conveying member-
A bias of 200 V was applied, development was performed in the same manner as in Example 33, and an image was formed. A clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +12.9.
(Μc / g) was sufficient, and the Q / M after continuous copying of 50,000 sheets was +11.8 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0058】実施例37 実施例34の例示化合物[化5]−(2)の代わりに例
示化合物[化5]−(6)をトナー供給部材4の被覆材
として使用した以外は実施例34と同様な装置及びトナ
ーで、トナー搬送部材に−300Vトナー供給部材へ−
150Vのバイアスを印加し、実施例34と同様に現像
させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+9.9
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+8.7(μc/g)と初期とほとんど変わら
なかった。またさらに、35℃・90%RHの高温高湿
下、及び10℃・15%RHの低温低湿環境下でも常温
常湿の時と同等の画像品質が得られた。なお、前記塗布
液を金属板表面にコートしたものとトナーとの摩擦帯電
性を上記のようなトナー吸引比電荷量測定装置を応用し
て、その帯電極性を調べたところ、前記塗布液を金属板
表面にコートしたものは、負極性に帯電した。
Example 37 As Example 34, except that the exemplified compound [Chemical Formula 5]-(6) was used in place of the exemplified compound [Chemical Formula 5]-(2) of Example 34 as a coating material for the toner supply member 4. With the same device and toner, to the toner conveying member-to the 300V toner supplying member-
When a bias of 150 V was applied and development was carried out in the same manner as in Example 34 to form an image, a clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. In addition, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +9.9.
(Μc / g) was sufficient, and the Q / M after continuous copying of 50,000 sheets was +8.7 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0059】実施例38 実施例34の例示化合物[化5]−(2)の代わりに例
示化合物[化5]−(8)をトナー供給部材4の被覆材
として使用した以外は実施例34と同様な装置及びトナ
ーで、トナー搬送部材に−400Vトナー供給部材へ−
200Vのバイアスを印加し、実施例34と同様に現像
させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+10.0
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+9.4(μc/g)と初期とほとんど変わら
なかった。またさらに、35℃・90%RHの高温高湿
下、及び10℃・15%RHの低温低湿環境下でも常温
常湿の時と同等の画像品質が得られた。なお、前記塗布
液を金属板表面にコートしたものとトナーとの摩擦帯電
性を上記のようなトナー吸引比電荷量測定装置を応用し
て、その帯電極性を調べたところ、前記塗布液を金属板
表面にコートしたものは、負極性に帯電した。
Example 38 As Example 34, except that the exemplified compound [Chemical Formula 5]-(8) was used as a coating material for the toner supply member 4 instead of the exemplary compound [Chemical Formula 5]-(2) of Example 34. With the same device and toner, to the toner transport member-to the 400V toner supply member-
A bias of 200 V was applied, development was performed in the same manner as in Example 34, and an image was formed. A clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +10.0.
(Μc / g) was sufficient, and the Q / M after continuous copying of 50,000 sheets was +9.4 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0060】実施例39 実施例34の例示化合物[化5]−(1)の代わりに例
示化合物[化5]−(10)をトナー供給部材4の被覆
材として使用した以外は実施例34と同様な装置及びト
ナーで、トナー搬送部材に−300Vトナー供給部材へ
−200Vのバイアスを印加し、実施例34と同様に現
像させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+10.6
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+8.9(μc/g)と初期とほとんど変わら
なかった。またさらに、35℃・90%RHの高温高湿
下、及び10℃・15%RHの低温低湿環境下でも常温
常湿の時と同等の画像品質が得られた。なお、前記塗布
液を金属板表面にコートしたものとトナーとの摩擦帯電
性を上記のようなトナー吸引比電荷量測定装置を応用し
て、その帯電極性を調べたところ、前記塗布液を金属板
表面にコートしたものは、負極性に帯電した。
Example 39 Example 34 is the same as Example 34 except that the exemplified compound [Chemical formula 5]-(10) was used as a coating material for the toner supply member 4 instead of the exemplary compound [Chemical formula 5]-(1). Using the same apparatus and toner, a bias of -200V was applied to the toner feeding member to the -300V toner supplying member, development was performed in the same manner as in Example 34, and image development was carried out. As a result, a clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +10.6.
(Μc / g) was sufficient, and the Q / M after continuous copying of 50,000 sheets was +8.9 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0061】実施例40 実施例33の例示化合物[化5]−(1)の代わりに例
示化合物[化5]−(12)をトナー供給部材4の被覆
材として使用した以外は実施例33と同様な装置及びト
ナーで、トナー搬送部材に−250Vトナー供給部材へ
−100Vのバイアスを印加し、実施例33と同様に現
像させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+11.7
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+11.0(μc/g)と初期とほとんど変わ
らなかった。またさらに、35℃・90%RHの高温高
湿下、及び10℃・15%RHの低温低湿環境下でも常
温常湿の時と同等の画像品質が得られた。なお、前記塗
布液を金属板表面にコートしたものとトナーとの摩擦帯
電性を上記のようなトナー吸引比電荷量測定装置を応用
して、その帯電極性を調べたところ、前記塗布液を金属
板表面にコートしたものは、負極性に帯電した。
Example 40 As Example 33, except that the exemplified compound [Chemical Formula 5]-(12) was used as a coating material for the toner supply member 4 instead of the exemplary compound [Chemical Formula 5]-(1) of Example 33. Using the same apparatus and toner, a bias of -100 V was applied to the toner feeding member of -250 V to the toner supplying member, development was performed in the same manner as in Example 33, and an image was formed. A clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner transport member is initially +11.7.
(Μc / g) was sufficient, and the Q / M after continuous copying of 50,000 sheets was +11.0 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0062】実施例41 スチレン系樹脂(D−125 エッソ社製) 85重量部 カーボンブラック(#44 三菱カーボン社製) 12重量部 ニグロシン染料 3重量部 上記組成の混合物をヘンシェルミキサー中で十分撹拌混
合した後、熱ロールミルで溶融混練し、室温まで冷却し
ハンマーミルを用いて粗粉砕し、ついで、エアージェッ
トミルにて微粉砕する。得られた微粉末を分級し粒径5
〜25μmのトナーを得た。つぎに、下記組成物をボー
ルミルを用いて室温にて10時間分散溶解して塗布液と
して、スポンジ状材質のトナー供給部材を浸漬し、11
0℃下で完全に溶媒を蒸発させた。 例示化合物[化6]−(1) 5.0g 溶媒 トルエン 300g 図に示すように、本トナー供給部材4をトナー搬送部材
2及びトナー層厚規制部材3からなる現像装置に配設し
た。この現像装置を用いた現像方法について説明する
と、図に示すように、トナータンク7に内蔵されている
トナー6は撹拌羽根5によりトナー供給部材4に強制的
に寄せられ、トナーはトナー供給部材4に供給される。
そして、トナー供給部材4に取り込まれたトナーはトナ
ー供給部材が矢印方向に回転することにより、トナー搬
送部材2に運ばれ、摩擦され、静電的あるいは物理的に
吸着し、トナー搬送部材2が矢印方向に強く回転し、ト
ナー層厚規制部材3によって均一なトナー薄層が形成さ
れるとともに摩擦帯電する。その後トナー搬送部材2と
接触もしくは近接している潜像担持体1の表面に運ばれ
潜像が現像される。本実施例では、前記トナーを本現像
装置に補給し、トナー搬送部材に−200Vトナー供給
部材へ−100Vのバイアスを印加し、マイナス潜像を
有する感光体に現像させ、転写・定着工程を経て画像出
しを行ったところ、鮮明な画像を得た。続けて、500
00枚連続複写したところ初期と変わりのない鮮明な画
像が得られた。また、トナー搬送部材上のトナーの比電
荷量(Q/M)を、出口側にフィルターを具備したファ
ラデーケージ(図示せず)を介し、トナー搬送部材上の
トナーを吸引しファラデーケージ内にトラップされたト
ナーの比電荷を測定する吸引式比電荷量測定装置を用い
て、測定したところ、+12.5(μc/g)と十分な
比電荷量であり、50000枚連続複写後のQ/Mは+
11.7(μc/g)と初期とほとんど変わらなかっ
た。またさらに、35℃・90%RHの高温高湿下、及
び10℃・15%RHの低温低湿環境下でも常温常湿の
時と同等の画像品質が得られた。なお、前記塗布液を金
属板表面にコートしたものとトナーとの摩擦帯電性を上
記のようなトナー吸引式比電荷量測定装置を応用して、
その帯電極性を調べたところ、前記塗布液を金属板表面
にコートしたものは、負極性に帯電した。
Example 41 Styrenic resin (D-125 manufactured by Esso Co.) 85 parts by weight Carbon black (# 44 manufactured by Mitsubishi Carbon Co.) 12 parts by weight Nigrosine dye 3 parts by weight The mixture having the above composition is sufficiently stirred and mixed in a Henschel mixer. After that, the mixture is melt-kneaded with a hot roll mill, cooled to room temperature, coarsely pulverized with a hammer mill, and then finely pulverized with an air jet mill. The fine powder obtained is classified to have a particle size of 5
A toner of ˜25 μm was obtained. Next, the following composition was dispersed and dissolved in a ball mill at room temperature for 10 hours to prepare a coating solution, and a toner supply member made of a sponge-like material was immersed in the coating solution.
The solvent was completely evaporated at 0 ° C. Exemplified Compound [Chemical Formula 6]-(1) 5.0 g Solvent Toluene 300 g As shown in the figure, the toner supplying member 4 is disposed in a developing device including the toner conveying member 2 and the toner layer thickness regulating member 3. A developing method using this developing device will be described. As shown in the figure, the toner 6 contained in the toner tank 7 is forcibly drawn to the toner supply member 4 by the stirring blade 5, and the toner is supplied to the toner supply member 4. Is supplied to.
Then, the toner taken into the toner supply member 4 is conveyed to the toner conveying member 2 by the rotation of the toner supplying member in the direction of the arrow, and is rubbed and electrostatically or physically adsorbed, and the toner conveying member 2 is It strongly rotates in the direction of the arrow, and a uniform toner thin layer is formed by the toner layer thickness regulating member 3 and is triboelectrically charged. After that, the toner is conveyed to the surface of the latent image carrier 1 which is in contact with or in the vicinity of the toner conveying member 2 and the latent image is developed. In this embodiment, the toner is supplied to the main developing device, a bias of −100 V is applied to the toner feeding member of −200 V to the toner feeding member to develop it on the photoconductor having a negative latent image, and the transfer / fixing process is performed. When the image was displayed, a clear image was obtained. Continuously, 500
When 00 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner carrying member is trapped in the Faraday cage by sucking the toner on the toner carrying member through a Faraday cage (not shown) equipped with a filter on the outlet side. The specific charge of the toner was measured by using a suction-type specific charge amount measuring device, and it was +12.5 (μc / g), which was a sufficient specific charge amount. Is +
The value was 11.7 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. In addition, applying the toner suction type specific charge amount measuring device as described above to the triboelectrification property of the coating liquid on the surface of a metal plate and the toner,
When the charging polarity was examined, the coating liquid coated on the surface of the metal plate was negatively charged.

【0063】実施例42 スチレン−アクリル系樹脂(SBM−73 三洋化成製) 80重量部 カーボンブラック(#44 三菱カーボン社製) 10重量部 低分子量ポリプロピレン 5重量部 4級アンモニウム塩 5重量部 上記組成の混合物を実施例41と同様な方法にてトナー
とした。本トナー100重量部に対し、コロイダルシリ
カ(日本アエロジル社製R−972)0.1重量部を添
加した。つぎに、下記組成物をボールミルを用いて室温
にて10時間分散溶解して塗布液として、スポンジ状材
質のトナー供給部材を浸漬し、110℃下で完全に溶媒
を蒸発させた。 例示化合物[化6]−(2)+アクリル樹脂 10+20g 溶媒 トルエン 1000g 本トナー供給部材4を実施例41と同様に現像装置に配
設した。前記トナーを本現像装置に補給し、トナー搬送
部材に−300Vトナー供給部材へ−200Vのバイア
スを印加し、実施例41と同様に現像させ、画像出しを
行ったところ、鮮明な画像が得られた。続けて、500
00枚連続複写したところ初期と変わりのない鮮明な画
像が得られた。また、トナー搬送部材上のトナーの比電
荷量(Q/M)は、初期+11.1(μc/g)と十分
であり、50000枚連続複写後のQ/Mは+10.8
(μc/g)と初期とほとんど変わらなかった。またさ
らに、35℃・90%RHの高温高湿下、及び10℃・
15%RHの低温低湿環境下でも常温常湿の時と同等の
画像品質が得られた。なお、前記塗布液を金属板表面に
コートしたものとトナーとの摩擦帯電性を上記のような
トナー吸引式比電荷量測定装置を応用して、その帯電極
性を調べたところ、前記塗布液を金属板表面にコートし
たものは、負極性に帯電した。
Example 42 Styrene-acrylic resin (SBM-73 manufactured by Sanyo Kasei) 80 parts by weight Carbon black (# 44 manufactured by Mitsubishi Carbon Co.) 10 parts by weight Low molecular weight polypropylene 5 parts by weight Quaternary ammonium salt 5 parts by weight The mixture was used as a toner in the same manner as in Example 41. To 100 parts by weight of this toner, 0.1 part by weight of colloidal silica (R-972 manufactured by Nippon Aerosil Co., Ltd.) was added. Next, the following composition was dispersed and dissolved in a ball mill at room temperature for 10 hours to prepare a coating solution, which was dipped in a sponge-like toner supplying member, and the solvent was completely evaporated at 110 ° C. Exemplified Compound [Chemical Formula 6]-(2) + Acrylic Resin 10 + 20 g Solvent Toluene 1000 g The toner supply member 4 was placed in the developing device in the same manner as in Example 41. The toner was replenished to the main developing device, a bias of -200V was applied to the toner feeding member of -300V, and the toner was developed in the same manner as in Example 41. When an image was formed, a clear image was obtained. It was Continuously, 500
When 00 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is sufficiently +11.1 (μc / g) at the initial stage, and the Q / M after continuous copying of 50,000 sheets is +10.8.
(Μc / g) was almost unchanged from the initial stage. Furthermore, under high temperature and high humidity of 35 ° C ・ 90% RH, and 10 ° C ・
Even under a low temperature and low humidity environment of 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. Incidentally, the triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction type specific charge amount measuring device as described above, and its charging polarity was examined. The product coated on the surface of the metal plate was negatively charged.

【0064】実施例43 スチレン−2エチルヘキシルアクリレート−nブチルメタ アクリレート系樹脂 80重量部 カーボンブラック(#44 三菱カーボン社製) 12重量部 低分子量ポリプロピレン 5重量部 ニグロシン染料 3重量部 上記組成の混合物を実施例41と同様な方法にてトナー
とした。本トナー100重量部に対し、コロイダルシリ
カ(日本アエロジル社製R−972)0.1重量部を添
加した。つぎに、下記組成物をボールミルを用いて室温
にて10時間分散溶解して塗布液として、スポンジ状材
質のトナー供給部材を浸漬し、110℃下で完全に溶媒
を蒸発させた。 例示化合物[化6]−(3) 5.0g 溶媒 トルエン 300g 本トナー供給部材4を実施例41と同様に現像装置に配
設した。前記トナーを本現像装置に補給し、トナー搬送
部材に−450Vトナー供給部材へ−100Vのバイア
スを印加し、実施例41と同様に現像させ、画像出しを
行ったところ、鮮明な画像が得られた。続けて、500
00枚連続複写したところ初期と変わりのない鮮明な画
像が得られた。また、トナー搬送部材上のトナーの比電
荷量(Q/M)は、初期+12.1(μc/g)と十分
であり、50000枚連続複写後のQ/Mは+11.8
(μc/g)と初期とほとんど変わらなかった。またさ
らに、35℃・90%RHの高温高湿下、及び10℃・
15%RHの低温低湿環境下でも常温常湿の時と同等の
画像品質が得られた。なお、前記塗布液を金属板表面に
コートしたものとトナーとの摩擦帯電性を上記のような
トナー吸引式比電荷量測定装置を応用して、その帯電極
性を調べたところ、前記塗布液を金属板表面にコートし
たものは、負極性に帯電した。
Example 43 Styrene-2 ethylhexyl acrylate-n-butyl methacrylate resin 80 parts by weight carbon black (# 44 manufactured by Mitsubishi Carbon Co.) 12 parts by weight Low molecular weight polypropylene 5 parts by weight Nigrosine dye 3 parts by weight A mixture of the above composition was carried out. A toner was prepared in the same manner as in Example 41. To 100 parts by weight of this toner, 0.1 part by weight of colloidal silica (R-972 manufactured by Nippon Aerosil Co., Ltd.) was added. Next, the following composition was dispersed and dissolved in a ball mill at room temperature for 10 hours to prepare a coating solution, which was dipped in a sponge-like toner supplying member, and the solvent was completely evaporated at 110 ° C. Exemplified Compound [Chemical Formula 6]-(3) 5.0 g Solvent Toluene 300 g The toner supply member 4 was placed in the developing device in the same manner as in Example 41. When the toner was replenished to the main developing device, a −450V toner supply member was applied with a bias of −100V to the toner supply member, development was carried out in the same manner as in Example 41, and an image was formed. A clear image was obtained. It was Continuously, 500
When 00 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is sufficiently +12.1 (μc / g) at the initial stage, and the Q / M after continuous copying of 50,000 sheets is +11.8.
(Μc / g) was almost unchanged from the initial stage. Furthermore, under high temperature and high humidity of 35 ° C ・ 90% RH, and 10 ° C ・
Even under a low temperature and low humidity environment of 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. Incidentally, the triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction type specific charge amount measuring device as described above, and its charging polarity was examined. The product coated on the surface of the metal plate was negatively charged.

【0065】比較例6 実施例41と同様な装置及びトナーを用い、トナー搬送
部材に−250V、トナー供給部材に−300Vのバイ
アスを印加して、同様な画像出しを行ったところ、初期
から連続複写10000枚までは鮮明な画像が得られて
いたが、20000枚後には画像濃度が低下しはじめ、
50000枚後ではさらに画像濃度が低下し残像等も発
生し、トナー搬送部材上には均一なトナー薄層が形成さ
れておらず、トナー層厚規制部材及びトナー搬送部材の
表面にトナーフィルミングが発生していた。また、実施
例41と同様にトナー搬送部材上のトナーのQ/Mを測
定したところ、初期は+12.3(μc/g)、200
00枚後で+5.9(μc/g)、50000枚後では
+2.6(μc/g)であった。
Comparative Example 6 Using the same apparatus and toner as in Example 41, applying a bias of −250 V to the toner conveying member and a bias of −300 V to the toner supplying member, a similar image was reproduced. A clear image was obtained up to 10,000 copies, but after 20,000 copies, the image density began to decrease.
After 50,000 sheets, the image density is further reduced and an afterimage is generated, and a uniform thin toner layer is not formed on the toner conveying member. Had occurred. Further, when the Q / M of the toner on the toner conveying member was measured in the same manner as in Example 41, the initial value was +12.3 (μc / g), 200
It was +5.9 (μc / g) after 00 sheets and +2.6 (μc / g) after 50,000 sheets.

【0066】実施例44 実施例41の例示化合物[化6]−(1)の代わりに例
示化合物[化6]−(4)をトナー供給部材4の被覆材
として使用した以外は実施例41と同様な装置及びトナ
ーで、トナー搬送部材に−350Vトナー供給部材へ−
200Vのバイアスを印加し、実施例41と同様に現像
させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+9.9
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+8.1(μc/g)と初期とほとんど変わら
なかった。またさらに、35℃・90%RHの高温高湿
下、及び10℃・15%RHの低温低湿環境下でも常温
常湿の時と同等の画像品質が得られた。なお、前記塗布
液を金属板表面にコートしたものとトナーとの摩擦帯電
性を上記のようなトナー吸引比電荷量測定装置を応用し
て、その帯電極性を調べたところ、前記塗布液を金属板
表面にコートしたものは、負極性に帯電した。
Example 44 Example 41 is the same as Example 41 except that the exemplified compound [Chemical formula 6]-(4) was used as a coating material for the toner supply member 4. Using the same device and toner, -350V toner supply member for the toner conveying member-
A bias of 200 V was applied, development was performed in the same manner as in Example 41, and an image was formed. A clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. In addition, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +9.9.
(Μc / g) was sufficient, and the Q / M after continuous copying of 50,000 sheets was +8.1 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0067】実施例45 実施例42の例示化合物[化6]−(2)の代わりに例
示化合物[化6]−(6)をトナー供給部材4の被覆材
として使用した以外は実施例42と同様な装置及びトナ
ーで、トナー搬送部材に−300Vトナー供給部材へ−
150Vのバイアスを印加し、実施例42と同様に現像
させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+10.1
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+9.7(μc/g)と初期とほとんど変わら
なかった。またさらに、35℃・90%RHの高温高湿
下、及び10℃・15%RHの低温低湿環境下でも常温
常湿の時と同等の画像品質が得られた。なお、前記塗布
液を金属板表面にコートしたものとトナーとの摩擦帯電
性を上記のようなトナー吸引比電荷量測定装置を応用し
て、その帯電極性を調べたところ、前記塗布液を金属板
表面にコートしたものは、負極性に帯電した。
Example 45 As Example 42, except that the exemplified compound [Chemical Formula 6]-(6) was used as a coating material for the toner supply member 4 instead of the exemplary compound [Chemical Formula 6]-(2) of Example 42. With the same device and toner, to the toner conveying member-to the 300V toner supplying member-
A bias of 150 V was applied, development was performed in the same manner as in Example 42, and an image was formed. A clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner transport member is initially +10.1.
(Μc / g) was sufficient, and the Q / M after continuous copying of 50,000 sheets was +9.7 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0068】実施例46 実施例42の例示化合物[化6]−(2)の代わりに例
示化合物[化6]−(7)をトナー供給部材4の被覆材
として使用した以外は実施例42と同様な装置及びトナ
ーで、トナー搬送部材に−400Vトナー供給部材へ−
200Vのバイアスを印加し、実施例42と同様に現像
させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+10.4
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+9.6(μc/g)と初期とほとんど変わら
なかった。またさらに、35℃・90%RHの高温高湿
下、及び10℃・15%RHの低温低湿環境下でも常温
常湿の時と同等の画像品質が得られた。なお、前記塗布
液を金属板表面にコートしたものとトナーとの摩擦帯電
性を上記のようなトナー吸引比電荷量測定装置を応用し
て、その帯電極性を調べたところ、前記塗布液を金属板
表面にコートしたものは、負極性に帯電した。
Example 46 As Example 42, except that the exemplified compound [Chemical Formula 6]-(7) was used as a coating material for the toner supply member 4 instead of the exemplary compound [Chemical Formula 6]-(2) of Example 42. With the same device and toner, to the toner transport member-to the 400V toner supply member-
A bias of 200 V was applied, development was performed in the same manner as in Example 42, and an image was formed. A clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is initially +10.4.
(Μc / g) was sufficient, and the Q / M after continuous copying of 50,000 sheets was +9.6 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0069】実施例47 実施例41の例示化合物[化6]−(1)の代わりに例
示化合物[化6]−(10)をトナー供給部材4の被覆
材として使用した以外は実施例41と同様な装置及びト
ナーで、トナー搬送部材に−300Vトナー供給部材へ
−200Vのバイアスを印加し、実施例41と同様に現
像させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+13.0
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+12.1(μc/g)と初期とほとんど変わ
らなかった。またさらに、35℃・90%RHの高温高
湿下、及び10℃・15%RHの低温低湿環境下でも常
温常湿の時と同等の画像品質が得られた。なお、前記塗
布液を金属板表面にコートしたものとトナーとの摩擦帯
電性を上記のようなトナー吸引比電荷量測定装置を応用
して、その帯電極性を調べたところ、前記塗布液を金属
板表面にコートしたものは、負極性に帯電した。
Example 47 Example 41 is the same as Example 41 except that the exemplified compound [Chemical Formula 6]-(10) was used as a coating material for the toner supply member 4 instead of the exemplary compound [Chemical Formula 6]-(1). Using the same apparatus and toner, a bias of -200V was applied to the toner feeding member to the -300V toner supplying member, development was performed in the same manner as in Example 41, and image development was carried out. As a result, a clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner conveying member is +13.0 at the initial stage.
(Μc / g) was sufficient, and the Q / M after continuous copying of 50,000 sheets was +12.1 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0070】実施例48 実施例41の例示化合物[化6]−(1)の代わりに例
示化合物[化6]−(12)をトナー供給部材4の被覆
材として使用した以外は実施例41と同様な装置及びト
ナーで、トナー搬送部材に−250Vトナー供給部材へ
−100Vのバイアスを印加し、実施例41と同様に現
像させ、画像出しを行ったところ、鮮明な画像が得られ
た。続けて、50000枚連続複写したところ初期と変
わりのない鮮明な画像が得られた。また、トナー搬送部
材上のトナーの比電荷量(Q/M)は、初期+11.7
(μc/g)と十分であり、50000枚連続複写後の
Q/Mは+10.8(μc/g)と初期とほとんど変わ
らなかった。またさらに、35℃・90%RHの高温高
湿下、及び10℃・15%RHの低温低湿環境下でも常
温常湿の時と同等の画像品質が得られた。なお、前記塗
布液を金属板表面にコートしたものとトナーとの摩擦帯
電性を上記のようなトナー吸引比電荷量測定装置を応用
して、その帯電極性を調べたところ、前記塗布液を金属
板表面にコートしたものは、負極性に帯電した。
Example 48 As Example 41, except that the exemplified compound [Chemical Formula 6]-(12) was used as a coating material for the toner supply member 4 instead of the exemplary compound [Chemical Formula 6]-(1) of Example 41. Using the same device and toner, a bias of -100 V was applied to the toner feeding member of -250 V to the toner supplying member, development was performed in the same manner as in Example 41, and an image was formed. A clear image was obtained. Subsequently, when 50,000 sheets were continuously copied, a clear image similar to the initial one was obtained. Further, the specific charge amount (Q / M) of the toner on the toner transport member is initially +11.7.
(Μc / g) was sufficient, and Q / M after continuous copying of 50,000 sheets was +10.8 (μc / g), which was almost the same as the initial value. Furthermore, even under high temperature and high humidity of 35 ° C. and 90% RH and in low temperature and low humidity environment of 10 ° C. and 15% RH, image quality equivalent to that at normal temperature and normal humidity was obtained. The triboelectrification property between the coating liquid coated on the surface of a metal plate and the toner was applied to the toner suction specific charge amount measuring device as described above, and its charging polarity was examined. Those coated on the plate surface were negatively charged.

【0071】[0071]

【発明の効果】以上説明したように、本発明によればト
ナー供給部材にコートすることにより、その表面エネル
ギーが小さくなり、トナーの融着防止及びトナーとの摩
擦帯電の経時・環境安定性が良好となり、トナー搬送部
材へのトナー補給性が良くなる。フッ素によって、トナ
ーを正帯電しやすくなり、現像装置としてのトナーの摩
擦帯電効率が向上する。
As described above, according to the present invention, by coating the toner supplying member, the surface energy of the toner supplying member is reduced, the fusion of the toner is prevented, and the frictional electrification with the toner is stable over time and environmentally stable. The toner replenishment property to the toner conveying member is improved. The fluorine makes it easier to positively charge the toner, and improves the triboelectrification efficiency of the toner as a developing device.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の現像装置の一例を示す概略図。FIG. 1 is a schematic view showing an example of a developing device of the present invention.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 少なくともトナー搬送部材、トナー層厚
規制部材を有し、トナー搬送部材に接触しつつ自在に回
転可能に支持されトナーを前記搬送部材上に供給するト
ナー供給部材とを有する現像装置において、少なくとも
前記トナー供給部材の表面を下記の一般式で表わされる
化合物の群から選択された少なくとも一種の芳香族フッ
素化合物で被覆し、前記トナー供給部材に前記トナー搬
送部材よりも0〜500V正電位のバイアスを印加する
ことを特徴とする正帯電性トナー用現像装置。 【化1】 [式中、R1:H、Cl、Br、F、OH、NH2、CO
OH、CONH2、CN、NO2、 R2:H、Cl、Br、OH、NH2、COOH、CON
2、CN、NO2] 【化2】 [但し、Rf;Cn2n+1、OCn2n+1 n;正の整数 R3,R4;H、Cl、Br、COOH、NH2、CON
2、CONH(CH22CH3、NHCOCH3、C
N、NO2] 【化3】 [但し、R5;COOH、CN、F、Cl、CONH2
NHCOCH3 6;H、OH、NH2、CN、COOH、C
l] 【化4】 [但し、R7;H、Cl、Br、F、COOH、低級ア
ルキル、パーフロロアルキル、パーフロロアルコキシ、 R8;H、Cl、Br、ハロゲン化アルキル、NO2、C
N] 【化5】 [但し、R9〜12:炭素数1〜10の低級アルキル、ア
リール、 n:正の整数、 m:正の整数、 X:−CO、−SO2
1. At least a toner conveying member and a toner layer thickness
It has a regulating member and can rotate freely while contacting the toner conveying member.
Toner that is rotatably supported and supplies toner onto the transport member.
A developing device having a toner supply member,
The surface of the toner supply member is represented by the following general formula.
At least one aromatic fluoride selected from the group of compounds
It is coated with an elemental compound, and the toner is conveyed to the toner supply member.
Apply a bias of 0-500V positive potential than the sending member
A developing device for positively chargeable toner characterized by the above. [Chemical 1] [In the formula, R1: H, Cl, Br, F, OH, NH2, CO
OH, CONH2, CN, NO2, R2: H, Cl, Br, OH, NH2, COOH, CON
H2, CN, NO2] [Chemical 2] [However, Rf; CnF2n + 1, OCnF2n + 1           n; positive integer R3, RFourH, Cl, Br, COOH, NH2, CON
H2, CONH (CH2)2CH3, NHCOCH3, C
N, NO2] [Chemical 3] [However, RFiveCOOH, CN, F, Cl, CONH2,
NHCOCH3         R6; H, OH, NH2, CN, COOH, C
l] [Chemical 4] [However, R7H, Cl, Br, F, COOH, lower
Rukiru, perfluoroalkyl, perfluoroalkoxy, R8H, Cl, Br, alkyl halides, NO2, C
N] [Chemical 5] [However, R9-12: Lower alkyl having 1 to 10 carbon atoms, a
reel, n: positive integer, m: positive integer, X: -CO, -SO2
【請求項2】 (1)少なくともトナー搬送部材、トナ
ー層厚規制部材を有し、トナー搬送部材に接触しつつ自
在に回転可能に支持されトナーを前記搬送部材上に供給
するトナー供給部材とを有する現像装置において、少な
くとも前記トナー供給部材の表面を下記一般式で表わさ
れる単量体を重合又は共重合して得られた重合体で被覆
し、前記トナー供給部材に前記トナー搬送部材よりも0
〜500V正電位のバイアスを添加することを特徴とす
る正帯電性トナー用現像装置。 【化6】 [但し、R13:H、CH3 14,R15:CN、COOH、NO2 16:F、Cl、Br]
2. (1) At least a toner conveying member and a toner
-Has a layer thickness control member that automatically contacts the toner transport member
Toner is rotatably supported and supplies toner onto the transport member.
In the developing device having the toner supply member
At least the surface of the toner supply member is represented by the following general formula.
Coated with polymer obtained by polymerizing or copolymerizing
However, the toner supply member is 0 than the toner transport member.
Characterized in that a bias of up to 500 V is added
Developing device for positively charged toner. [Chemical 6] [However, R13: H, CH3         R14, R15: CN, COOH, NO2         R16: F, Cl, Br]
JP3012392A 1991-01-10 1991-01-10 Developing device Pending JPH0511499A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3012392A JPH0511499A (en) 1991-01-10 1991-01-10 Developing device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3012392A JPH0511499A (en) 1991-01-10 1991-01-10 Developing device

Publications (1)

Publication Number Publication Date
JPH0511499A true JPH0511499A (en) 1993-01-22

Family

ID=11804000

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3012392A Pending JPH0511499A (en) 1991-01-10 1991-01-10 Developing device

Country Status (1)

Country Link
JP (1) JPH0511499A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004011450A1 (en) * 2002-07-30 2004-02-05 Orion Corporation Fermion Process for the preparation of 1-(3-dimethylaminopropyl) -1-(4-fluorophenyl) -1,3-dihydroisobenzofuran -5-carbonitrile
US8055017B2 (en) 2007-01-31 2011-11-08 Fuji Jukogyo Kabushiki Kaisha Headlamp monitoring apparatus for image exposure adjustment
CN103193912A (en) * 2013-04-19 2013-07-10 苏州大学 Copolymer containing zinc-phthalocyanine group on side chain and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004011450A1 (en) * 2002-07-30 2004-02-05 Orion Corporation Fermion Process for the preparation of 1-(3-dimethylaminopropyl) -1-(4-fluorophenyl) -1,3-dihydroisobenzofuran -5-carbonitrile
US8055017B2 (en) 2007-01-31 2011-11-08 Fuji Jukogyo Kabushiki Kaisha Headlamp monitoring apparatus for image exposure adjustment
CN103193912A (en) * 2013-04-19 2013-07-10 苏州大学 Copolymer containing zinc-phthalocyanine group on side chain and preparation method thereof

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