JPH0440283A - Water treatment apparatus - Google Patents

Water treatment apparatus

Info

Publication number
JPH0440283A
JPH0440283A JP14837790A JP14837790A JPH0440283A JP H0440283 A JPH0440283 A JP H0440283A JP 14837790 A JP14837790 A JP 14837790A JP 14837790 A JP14837790 A JP 14837790A JP H0440283 A JPH0440283 A JP H0440283A
Authority
JP
Japan
Prior art keywords
filter
water
dissolved
stage
pipe
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP14837790A
Other languages
Japanese (ja)
Inventor
Chiyotarou Hiide
樋出 千代太郎
Masanori Enomoto
榎本 正徳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EASY NET KK
Mitsui and Co Ltd
Gastar Co Ltd
Original Assignee
EASY NET KK
Mitsui and Co Ltd
Gastar Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EASY NET KK, Mitsui and Co Ltd, Gastar Co Ltd filed Critical EASY NET KK
Priority to JP14837790A priority Critical patent/JPH0440283A/en
Publication of JPH0440283A publication Critical patent/JPH0440283A/en
Pending legal-status Critical Current

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  • Water Treatment By Electricity Or Magnetism (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

PURPOSE:To adsorb the component having a small in water, to modify acidic water and to prevent the precipitation of a calcium component by mounting a filter apparatus provided with a filter bed composed of a porous material containing a calcium component and dissolved in water to generate a hydroxyl group and an electrode treatment apparatus. CONSTITUTION:The water flowing in the filter 20 of the uppermost stage from a pipe 14 passes through a filter bed 25 and an inside filter 23 from an outside filter 24 to reach the filter 20 of the second stage from the central hole of a lower frame 21 and successively passes through the filter 20 of the second stage and the filter 20 of the lowermost stage in the same way to flow out to a pipe 15. Since the filter material of the filter bed 25 is porous, the smell component dissolved in the water is adsorbed to make odoriferous water odorless CaO in the filter material is dissolved in water to generate a hydroxyl group OH<-> and the concn. of the hydroxyl group is enhanced to make acidic water neutral or alkaline. Next, the water passed through the filter apparatus 10 passes through an electrode treatment apparatus 40 provided with a cylindrical anode 43 and a rod-shape cathode 44. Since the dissolved solid of calcium present in water flows as suspended matter of a fine single crystal at this time, the precipitation of a calcium component on a pipe is markedly reduced.

Description

【発明の詳細な説明】 く本考案の産業上の利用分野〉 本発明は飲料水、排水などからゴミやにおいを除去する
水処3!!装置に関する。
[Detailed Description of the Invention] Industrial Application Field of the Present Invention The present invention provides a water treatment system for removing dirt and odors from drinking water, wastewater, etc. ! Regarding equipment.

〈従来技術〉 従来の飲料水、排水などの液体(以下、水と記す)を処
理する水処理装置は、砂又はケイソウ土によるろか層あ
るいはポリエチレンなどの合成樹脂から成る糸又は不織
布で作ったフィルタを、飲料水、排水などを通過させて
、ゴミなどの不純物を除去していた。
<Prior art> Conventional water treatment equipment for treating liquids such as drinking water and wastewater (hereinafter referred to as water) uses a filter layer made of sand or diatomaceous earth, or a filter made of thread or nonwoven fabric made of synthetic resin such as polyethylene. was used to pass through drinking water, wastewater, etc., and remove impurities such as dirt.

しかしながら、このような水処理装置では、水中に混入
したゴミなどの不純物は除去されるが、水中に溶存した
においなどを除去できない。
However, although such water treatment equipment removes impurities such as dirt mixed into the water, it cannot remove odors etc. dissolved in the water.

このため、従来では、第4図に示すように砂やケイソウ
土によるろか層あるいはポリエチレンなどの糸、不織布
などで作ったフィルタを用いたうか装置1で、水中のゴ
ミなどの不純物を除去した後、オゾン発生器2からオゾ
ンを注入し、さらに活性炭M3を通過させて、水中に溶
存するにおいの成分を吸着させてにおいを除去していた
For this reason, in the past, as shown in Fig. 4, after removing impurities such as dirt from the water, a filter made of a filter layer made of sand or diatomaceous earth, or a filter made of threads such as polyethylene, or non-woven fabric is used. Ozone was injected from the ozone generator 2 and passed through activated carbon M3 to adsorb odor components dissolved in the water and remove the odor.

く本発明が解決しようとする問題点〉 しかしながら、このような従来の水処理装置では、活性
炭層3を設けなければならないため、装置全体が大型と
なり、高価となるという問題点があった。
Problems to be Solved by the Present Invention> However, in such a conventional water treatment device, since the activated carbon layer 3 must be provided, there is a problem that the entire device becomes large and expensive.

また、ゴミやにお訃を除去するだけで、水の水質が変化
しないため、水処3!!!@置の後段の配管内部が腐蝕
するという問題点があった。
In addition, simply removing garbage and dead bodies does not change the quality of the water, making it the third water source! ! ! There was a problem in that the inside of the piping at the latter stage of the installation was corroded.

本発明はこれらの問題点を解決した水処jp装置を菱供
することを目的としている。
The object of the present invention is to provide a water treatment plant that solves these problems.

〈前記問題点を解決するための手段〉 前記問題点を解決するために本発明の水処理装置では、 容器内にカルシウム成分を含み、水に溶解して水酸基を
生じる水溶性の多孔質材料から戒るろか層を設けたうか
@lと、 前記ろか装置を通過した水路中流水に対し電気的に作用
する一対の電極を設けた電極処理装置とを備えた ことを特徴としている。
<Means for solving the above-mentioned problems> In order to solve the above-mentioned problems, in the water treatment device of the present invention, the container is made of a water-soluble porous material that contains a calcium component and dissolves in water to generate hydroxyl groups. The present invention is characterized by comprising a filter layer provided therein, and an electrode processing device provided with a pair of electrodes that act electrically on the flowing water in the channel that has passed through the filter device.

く作用〉 このようにしたため、水がろか装置を通過する闇に、ろ
か閣が多孔質のため水中に溶存したにおいを有する成分
が扱者され、また、ろ材が水に溶解して水酸基を生じて
、酸性の水の水質が中性やアルカリ性に改質される。
As a result, as the water passes through the filter device, components with odors dissolved in the water due to the filter material being porous are exposed to the handler, and the filter material dissolves in water and generates hydroxyl groups. As a result, the quality of acidic water is modified to become neutral or alkaline.

しかして、ろ材がカルシウム成分を含むため、カルシウ
ムが水に溶解するが、後段の電極処理装置を通過する間
に、一対の電極により流水中に電流が流れて溶解したカ
ルシウム成分の分子に運動エネルギーが付与され、カル
シウム成分の分子が細分化され、活動度を増す。このた
め、その後段の管内へのカルシウム化合物の付着が低減
される。
However, since the filter medium contains calcium components, calcium dissolves in the water, but while it passes through the electrode processing device in the latter stage, a current is passed through the flowing water by a pair of electrodes, and the molecules of the dissolved calcium components are given kinetic energy. is given, the calcium component molecules are fragmented, and their activity increases. For this reason, the adhesion of calcium compounds into the tube at the subsequent stage is reduced.

〈実施例〉 以下、図面に基づいて本発明の詳細な説明する。<Example> Hereinafter, the present invention will be described in detail based on the drawings.

第1〜3図は本発明の一実施例を示している。1 to 3 show an embodiment of the invention.

第1図において、10はろか装置を示すものであって、
11は筒状の容器、12はその上蓋、13は底蓋である
。11aは水の流入口、11bは流出口であって、それ
ぞれバイブ14.15が接続されている。
In FIG. 1, numeral 10 indicates a filter device,
11 is a cylindrical container, 12 is its top lid, and 13 is its bottom lid. 11a is a water inlet, and 11b is a water outlet, to which vibrators 14 and 15 are connected.

容器11の下部内壁には、受板16が固定されている。A receiving plate 16 is fixed to the lower inner wall of the container 11.

受板16には、複数段、例えば3段にろか器20が積重
ねられ、上1112との間に設置された固定用スプリン
グ17によって、最上段のるか器20を押圧することに
よって、固定されている。
A plurality of filters 20 are stacked on the receiving plate 16, for example three stages, and the filters 20 are fixed by pressing the top row filter 20 with a fixing spring 17 installed between the top plate 1112 and the top 1112. ing.

ろか器20は、中央に穴21aを備えた円板状の下枠2
1と、板枠21より直径の小さい円板状の上枠22とを
備えている。
The filter 20 has a disc-shaped lower frame 2 with a hole 21a in the center.
1, and a disk-shaped upper frame 22 having a smaller diameter than the plate frame 21.

下枠21と上枠22との闇には、膜、網状なとの筒状の
内側フィルタ23、外側フィルタ24が取付けられ、内
側フィルタ23と外側フィルタ24の間には、ろ材が充
填されたろか層25が設けられている。
A cylindrical inner filter 23 and an outer filter 24 are attached to the space between the lower frame 21 and the upper frame 22, and a filter filled with filter material is installed between the inner filter 23 and the outer filter 24. A layer 25 is provided.

そして、軸体26の下端に固定された水平材27の両端
が、下枠21の穴21aの縁部の切欠き21bに嵌合さ
れ、軸体26の上端部が、上枠22の中央を上方へ貫通
して、上側からボルト28を螺着することによって、下
枠21と上枠22が締結されている。
Then, both ends of the horizontal member 27 fixed to the lower end of the shaft body 26 are fitted into the notches 21b at the edge of the hole 21a of the lower frame 21, and the upper end of the shaft body 26 touches the center of the upper frame 22. The lower frame 21 and the upper frame 22 are fastened together by penetrating upward and screwing bolts 28 from above.

下枠21の外径は容器11の内径より僅かに小で、下枠
21の外端面の溝に嵌ったOリング29が、容器11の
内壁に密着して水の通過を阻止している。
The outer diameter of the lower frame 21 is slightly smaller than the inner diameter of the container 11, and an O-ring 29 fitted in a groove on the outer end surface of the lower frame 21 closely contacts the inner wall of the container 11 to prevent water from passing through.

上下のるか器20.20は、3本の支柱30で連結され
ている。
The upper and lower containers 20.20 are connected by three supports 30.

ろか1125のろ材としては、水に溶解して水酸基を生
じる水溶性の多孔質材料、例えば、CAOと5in2、
その他を含んだ混合材を用いる。
The filter medium for Roka 1125 is a water-soluble porous material that dissolves in water and generates hydroxyl groups, such as CAO and 5in2,
Use a mixture containing other ingredients.

なお、第1図において31は排気孔で、エアー抜き弁(
図示せず)が取付けられている。また、32はドレイン
排出口で、ドレイン排出弁(図示せず)が取付けられて
いる。
In addition, in Fig. 1, 31 is an exhaust hole, and the air bleed valve (
(not shown) is attached. Further, 32 is a drain outlet, to which a drain outlet valve (not shown) is attached.

40は電極処理装置である。40 is an electrode processing device.

第3図に示すように41は円筒状の鋼管であって、鋼管
41の内側には、絶縁1!42が同心状に内接して配置
されている。さらに、絶縁管42の内側には、例えばア
ルミニウム(あるいは金、銀、白金など)からなる円筒
状の陽極電極43が、内接して取りつけられている。
As shown in FIG. 3, 41 is a cylindrical steel pipe, and an insulator 1!42 is disposed concentrically inscribed inside the steel pipe 41. Further, inside the insulating tube 42, a cylindrical anode electrode 43 made of, for example, aluminum (or gold, silver, platinum, etc.) is attached inscribed.

そして、円筒状電極43の内部には、中心軸に沿って例
えば炭素(あるいはマグネシウム、亜鉛など)から成る
棒状の陰極電極44が配置されている。この棒状の陰極
電極44は、絶縁材から成る支持体45によって、円筒
状の陽極電極43に支持されている。
Inside the cylindrical electrode 43, a rod-shaped cathode electrode 44 made of, for example, carbon (or magnesium, zinc, etc.) is arranged along the central axis. This rod-shaped cathode electrode 44 is supported on the cylindrical anode electrode 43 by a support body 45 made of an insulating material.

鋼管41の両端には7ランジ46.47が螺着されてい
る。フランジ46はパイプ15に接続され、フランジ4
7はパイプ48に接続されている。
Seven flanges 46 and 47 are screwed onto both ends of the steel pipe 41. The flange 46 is connected to the pipe 15, and the flange 46
7 is connected to a pipe 48.

パイプ14を通った水は、ろかfi、B10の流入口1
1aから容器11内へ流入し、最上段のろかB20の下
枠21と容111の内壁とが0リング29で密封されて
いるため、外側フィルタ24からろか1125、内側フ
ィルタ23を通過した優、下枠21の中央の穴21aか
ら2段目のるか器20へ到り、2段目のろか器20の上
枠22と容器11の内!との間を通って同様に外側フィ
ルタ24、ろか1125、内側フィルタ23を通り、以
下同様に最下段のるか器20を通過して容器11の流出
口11bからパイプ15へ流出する。
The water that has passed through the pipe 14 flows through the inlet 1 of Rakafi, B10.
1a into the container 11, and since the lower frame 21 of the uppermost filter B20 and the inner wall of the container 111 are sealed with the O ring 29, the water that has passed from the outer filter 24 to the filter 1125 and the inner filter 23, The hole 21a in the center of the lower frame 21 reaches the second stage filter vessel 20, and the inside of the upper frame 22 of the second stage filter vessel 20 and the container 11! Similarly, the water passes through the outer filter 24, the filter 1125, and the inner filter 23, and then similarly passes through the lowermost funnel 20 and flows out from the outlet 11b of the container 11 to the pipe 15.

水中のゴミなどの不純物は、外側フィルタ24、内側フ
ィルタ23で除去される。そして、ろか125のろ材が
多孔質であるため、水中に溶存したにおいの成分が吸着
されて、臭気のある水を無臭にする。
Impurities such as dirt in the water are removed by an outer filter 24 and an inner filter 23. Since the filter medium of the filter 125 is porous, odor components dissolved in the water are adsorbed, making odorless water odorless.

且つ、ろ材中のCaOが水に溶けて CへQ +1−(20→Cユ(OH)2Ca(O)4)
2→Ca(O)−1f+0H−Ca(Of−1)”−+
Ca”十〇H″″のように水酸基OHを生じて、水酸基
濃度を^め、酸性の水を中性あるいはアルカリ性にする
Moreover, CaO in the filter medium dissolves in water and converts to C. Q +1-(20→Cyu(OH)2Ca(O)4)
2→Ca(O)-1f+0H-Ca(Of-1)"-+
Produces hydroxyl group OH as in Ca"10H", lowers the hydroxyl group concentration, and makes acidic water neutral or alkaline.

なお、CaO,SiO2の含有量は、CaOが10〜4
0%、好ましくは25%、Sin、の含有量は65〜3
5%、好ましくは50%が適当である。
Note that the content of CaO and SiO2 is 10 to 4.
0%, preferably 25%, Sin content is 65-3
5%, preferably 50% is suitable.

CaOの含有量が40%を超えると、水への溶解反応が
高くなりすぎ、ろ材としての消耗が大きくなりすぎる。
When the content of CaO exceeds 40%, the dissolution reaction in water becomes too high, resulting in excessive consumption as a filter medium.

また10%より少ないと、pH値が高くならない。Moreover, if it is less than 10%, the pH value will not become high.

また、Siへの含有量が35%より少ないと、多孔質に
ならず、CaOが多くなりすぎて溶けやすくなり、ろ材
としの消耗が大きくなりすぎる。
On the other hand, if the content of Si is less than 35%, it will not become porous, and the amount of CaO will be too large, making it easy to dissolve, resulting in excessive wear as a filter medium.

このようにしてるか装置10を通過して流出した水は、
ゴミなどの不純物が除去されるだけでなく、においなど
の成分も除去され、さらに酸性の場合は中性やアルカリ
性に改質されているが、カルシウム成分が溶解している
。このため、このろか装置10を経た水を加熱して温水
として利用すると、水の硬度が増加して、カルシウム成
分がCαCO3として析出して後段の熱交換器などのパ
イプに付着して通路詰りを生じたり、熱効率の低下を招
く。これを防ぐために、ろか装M10を経た水をパイプ
11b、パイプ15を経て、電極処理装[40の内筒状
の陽極電極43内を通過させる。
The water that has passed through the device 10 in this way is
Not only are impurities such as dust removed, but components such as odors are also removed, and if acidic, it is modified to be neutral or alkaline, but calcium components are dissolved. For this reason, when the water that has passed through the filter device 10 is heated and used as hot water, the hardness of the water increases, and calcium components precipitate as CαCO3 and adhere to the pipes of the downstream heat exchanger, etc., clogging the passages. or cause a decrease in thermal efficiency. In order to prevent this, the water that has passed through the filter M10 is passed through the pipe 11b and the pipe 15, and then through the inner cylindrical anode electrode 43 of the electrode treatment device [40].

電極処理装置40内では、ここを通る水が電解質である
ため、円筒状の陽極電極43と棒状の陽極電極44開に
0.7V程度の電圧が生じ、流水に電流が流れて、多分
子(クラスター)化した水分子に運動エネルギーを与え
、水の活動度が増すため、水中に存在するカルシウムの
溶解固形分を細分化させて、微細な単結晶にする。この
ため溶解固形分は水中で浮遊化物となるため、後段のバ
イブ内において付着することなく、流れる。従って、パ
イプ内へのカルシウム成分の析出が著しく低減される。
In the electrode treatment device 40, since the water passing through it is an electrolyte, a voltage of about 0.7V is generated between the cylindrical anode electrode 43 and the rod-shaped anode electrode 44, and a current flows through the flowing water, causing polymolecules ( This gives kinetic energy to the clustered water molecules, increasing the activity of the water, and fragmenting the dissolved solids of calcium present in the water into fine single crystals. Therefore, the dissolved solids become suspended substances in the water, and therefore flow without adhering to the latter part of the vibrator. Therefore, precipitation of calcium components into the pipe is significantly reduced.

く本発明の効果〉 以上説明したように、本発明の水弟jp装置では、水中
に溶存したにおいを有する成分が@看され、従来のよう
に活性炭層を設けなくても悪臭の水を無臭にすることが
でき、装置が小型、安価となり、また、ろ材中のCaO
が水に溶解して水i!基を生じて、酸性の強い水の水質
を中性又はアルカリ性に改質することができるため、配
管内部の腐蝕を防止することができ、さらにカルシウム
成分の析出を防ぐことができる。
Effects of the Present Invention> As explained above, in the water drop device of the present invention, odor-bearing components dissolved in water can be detected, and odorless water can be made odorless without providing an activated carbon layer as in conventional methods. This makes the device smaller and cheaper, and also reduces the amount of CaO in the filter medium.
is dissolved in water and water i! Since it is possible to modify the quality of highly acidic water to neutral or alkaline by generating groups, it is possible to prevent corrosion inside the piping and further prevent the precipitation of calcium components.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の一実施例を示す一部を破断して描いた
正面図である。第2図はるか器の底面図、第3図は電極
処理装置を示す断面図である。 第4図は従来の水処理装置の構成を示す概念図である。 10・・・・・・ろか@置、1″1・・・・・−容器、
11a・・・・・・流入口、11b・・・・・・流出口
、20・・・・・・ろか器、21・・・・・・下枠、2
2・・・・・・上枠、23・・・・・・内側フィルタ、
24・・・・・・外側フィルタ、25・・・・・・ろか
層、40・・・・・・電極処理装置、43・・・・・・
陽極電極、44・・・・・・陰極電極。
FIG. 1 is a partially cutaway front view showing one embodiment of the present invention. FIG. 2 is a bottom view of the container, and FIG. 3 is a sectional view showing the electrode processing device. FIG. 4 is a conceptual diagram showing the configuration of a conventional water treatment device. 10...Roka@place, 1″1...-container,
11a... Inlet, 11b... Outlet, 20... Filter, 21... Lower frame, 2
2... Upper frame, 23... Inner filter,
24...Outer filter, 25...Lower layer, 40...Electrode processing device, 43...
Anode electrode, 44... cathode electrode.

Claims (1)

【特許請求の範囲】 容器内にカルシウム成分を含み、水に溶解して水酸基を
生じる水溶性の多孔質材料から成るろか層を設けたろか
装置と、 前記ろか装置を通過した水路中流水に対し電気的に作用
する一対の電極を設けた電極処理装置と を備えた水処理装置。
[Scope of Claim] A filter device having a filter layer made of a water-soluble porous material containing a calcium component and dissolving in water to generate hydroxyl groups in a container, and for water flowing in a waterway that has passed through the filter device. A water treatment device comprising an electrode treatment device provided with a pair of electrodes that act electrically.
JP14837790A 1990-06-06 1990-06-06 Water treatment apparatus Pending JPH0440283A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP14837790A JPH0440283A (en) 1990-06-06 1990-06-06 Water treatment apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14837790A JPH0440283A (en) 1990-06-06 1990-06-06 Water treatment apparatus

Publications (1)

Publication Number Publication Date
JPH0440283A true JPH0440283A (en) 1992-02-10

Family

ID=15451401

Family Applications (1)

Application Number Title Priority Date Filing Date
JP14837790A Pending JPH0440283A (en) 1990-06-06 1990-06-06 Water treatment apparatus

Country Status (1)

Country Link
JP (1) JPH0440283A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05337475A (en) * 1992-06-05 1993-12-21 Nippon Gijutsu Kaihatsu Center:Kk Method for activating water solution
JP2006346550A (en) * 2005-06-15 2006-12-28 Kido Toshihiro Water treatment tool
JP2012006011A (en) * 2008-08-29 2012-01-12 Yoji Hayakawa Aqueous environmental battery

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05337475A (en) * 1992-06-05 1993-12-21 Nippon Gijutsu Kaihatsu Center:Kk Method for activating water solution
JP2006346550A (en) * 2005-06-15 2006-12-28 Kido Toshihiro Water treatment tool
JP4613260B2 (en) * 2005-06-15 2011-01-12 城戸 敏弘 Water treatment tool
JP2012006011A (en) * 2008-08-29 2012-01-12 Yoji Hayakawa Aqueous environmental battery

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