JPH0436962A - Fuel cell with solid electrolyte - Google Patents
Fuel cell with solid electrolyteInfo
- Publication number
- JPH0436962A JPH0436962A JP2143481A JP14348190A JPH0436962A JP H0436962 A JPH0436962 A JP H0436962A JP 2143481 A JP2143481 A JP 2143481A JP 14348190 A JP14348190 A JP 14348190A JP H0436962 A JPH0436962 A JP H0436962A
- Authority
- JP
- Japan
- Prior art keywords
- solid electrolyte
- electrolyte layer
- zirconia
- fuel electrode
- nickel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 35
- 239000007784 solid electrolyte Substances 0.000 title claims abstract description 18
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 36
- 230000002093 peripheral effect Effects 0.000 claims abstract description 6
- 239000000758 substrate Substances 0.000 claims description 17
- 239000011195 cermet Substances 0.000 claims description 16
- 239000010410 layer Substances 0.000 claims description 16
- 239000007787 solid Substances 0.000 claims description 9
- 239000011247 coating layer Substances 0.000 claims description 6
- 229910000480 nickel oxide Inorganic materials 0.000 abstract description 9
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 abstract description 8
- NFYLSJDPENHSBT-UHFFFAOYSA-N chromium(3+);lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+3].[La+3] NFYLSJDPENHSBT-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000843 powder Substances 0.000 abstract description 4
- 239000002904 solvent Substances 0.000 abstract description 3
- 238000001035 drying Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract description 2
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 abstract description 2
- 229910009474 Y2O3—ZrO2 Inorganic materials 0.000 abstract 1
- 230000004927 fusion Effects 0.000 abstract 1
- 230000000977 initiatory effect Effects 0.000 abstract 1
- 229910000473 manganese(VI) oxide Inorganic materials 0.000 abstract 1
- 238000007493 shaping process Methods 0.000 abstract 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 22
- 239000007789 gas Substances 0.000 description 17
- 229910052759 nickel Inorganic materials 0.000 description 10
- 239000000463 material Substances 0.000 description 5
- XIVRETJQLTUPPZ-UHFFFAOYSA-N [Ca+2].[La+3].[O-][Cr]([O-])=O Chemical compound [Ca+2].[La+3].[O-][Cr]([O-])=O XIVRETJQLTUPPZ-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 239000002737 fuel gas Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- XGPJPLXOIJRLJN-UHFFFAOYSA-N [Mn].[Sr].[La] Chemical compound [Mn].[Sr].[La] XGPJPLXOIJRLJN-UHFFFAOYSA-N 0.000 description 1
- FVROQKXVYSIMQV-UHFFFAOYSA-N [Sr+2].[La+3].[O-][Mn]([O-])=O Chemical compound [Sr+2].[La+3].[O-][Mn]([O-])=O FVROQKXVYSIMQV-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910002075 lanthanum strontium manganite Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- -1 oxygen ions Chemical class 0.000 description 1
- 238000007750 plasma spraying Methods 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 238000007751 thermal spraying Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
- H01M8/2425—High-temperature cells with solid electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1231—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte with both reactants being gaseous or vaporised
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Fuel Cell (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
この発明は固体電解質型燃料電池の単セルに係り、特に
燃料極である二ッケルージルコニアザーメット基板の信
頼性を向上させた燃料電池に関する。[Detailed Description of the Invention] [Industrial Application Field] This invention relates to a single cell of a solid oxide fuel cell, and in particular to a fuel cell in which the reliability of a Nickel zirconia cermet substrate, which is a fuel electrode, is improved. Regarding.
ジルコニア等の酸化物固体電解質を用いる燃料電池は、
その作動温度が８００〜１１００℃と高温であるため、
発電効率が高い」二に触媒が不要であり、また電解質が
固体であるため取扱いが容易であるなどの特長を有し、
第三世代の燃料電池として期待されている。Fuel cells using oxide solid electrolytes such as zirconia are
Because its operating temperature is as high as 800-1100℃,
It has features such as high power generation efficiency, no need for a catalyst, and easy handling because the electrolyte is solid.
It is expected to be a third-generation fuel cell.
第２図は従来の固体電解質型燃料電池を示す断面図であ
る。ランタンカルシウムクロマイト（１、ａａ、ｅ”Ｃ
ａｏ、 ｚｃｒＯｓ）からなり、反応ガス供給用のリブ
を有するガスセパレータ２４と、単セル３０とが交互に
積層される。単セル３０はニッケルージルコニア（Ｎｉ
−ＺｒＯｚ）サーメット基板である燃料極２１と、８％
イツトリアで安定化されたジルコニア （８％Ｙ２０゜
Ｚｒ０ｚ）からなる固体電解質層２２と、ランタンスト
ロンチウムマンガナイｌ’ （！、ａｏ、ｅＳｒｏ、
ｚＭｎｏｉ）からなる空気極２３とから構成される。燃
料極２１と空気極２３ハカスセバレータ２４と接する。FIG. 2 is a sectional view showing a conventional solid oxide fuel cell. Lanthanum calcium chromite (1, aa, e”C
Gas separators 24 made of acetate (ao, zcrOs) and having ribs for supplying reactive gases and single cells 30 are alternately stacked. The single cell 30 is made of nickel-zirconia (Ni
-ZrOz) fuel electrode 21 which is a cermet substrate, and 8%
A solid electrolyte layer 22 made of zirconia stabilized with yttoria (8%Y20°Zr0z) and lanthanum strontium manganese l' (!, ao, eSro,
zMnoi). The fuel electrode 21 and the air electrode 23 are in contact with the separator 24 .
ガスセパレータ２４の両生面にはそれぞれ燃料ガスと酸
化剤ガスが分離して流される。ガスセパレータ２４は緻
密に形成され再反応ガスが混触しない。またランタンカ
ルシウムクロマイト（Ｌａ６，１ｌＣａｏ、 ｚｃｒｏ
ｉ）等のランタンクロマイト系の材料は導電性であり、
積層された単セル３０の間を電気的に接続させる。ラン
タンクロマイト系の材料はその電気抵抗を減するために
、Ｌａの１部がＢａ、 Ｃａ、 Ｓｒ等で置換される。Fuel gas and oxidant gas are separately flowed onto both sides of the gas separator 24, respectively. The gas separator 24 is formed densely so that the re-reacted gas does not come into contact with it. In addition, lanthanum calcium chromite (La6,1lCao, zcro
Lanthanum chromite materials such as i) are conductive,
The stacked unit cells 30 are electrically connected. In order to reduce the electrical resistance of lanthanum chromite-based materials, part of La is replaced with Ba, Ca, Sr, etc.
この材料を除き燃料電池の運転温度１０００℃において
酸化性と還元性のふん囲気で使用できるものはない。Except for this material, there is no material that can be used in an oxidizing and reducing atmosphere at a fuel cell operating temperature of 1000°C.
空気極２３では次の反応がおこる。The following reaction occurs at the air electrode 23.
０２ ＋ ４ ｅ −２０２−−−−−−−ｆｌ）燃料
極２１では次の反応がおこる。02 + 4 e -202--------fl) The following reaction occurs at the fuel electrode 21.
２０” ＋２ Ｈ２→２ Ｈｚ Ｏ→−４８−一−−（
２＋酸素イオン０トは固体電解質層２２の内部を空気極
２３から燃料極２１に向かって流れる。電子４８はガス
セパレータ２４を含む外部回路を流れる。20" +2 H2→2 Hz O→-48-1--(
The 2+ oxygen ions flow inside the solid electrolyte layer 22 from the air electrode 23 toward the fuel electrode 21 . Electrons 48 flow through an external circuit that includes gas separator 24 .
ガスセパレータ２４は酸化ランタン（ＬａｚＯｉ）＋酸
化カルシウム（Ｃａｂ）、酸化クロム（Ｃｒｚ（ｈ）の
粉体を所定割合で混合して１３００℃で反応させてラン
タンカルシウムクロマイト（Ｌａｏ、ａＣａｏ、 ２Ｃ
ｒＯｓ）を生成させ、粉砕、造粒後プレス成型し、１４
００°Ｃで緻密に焼成して製造される。リブを設けるた
めに厚さは２〜３ｆｌが必要となる。単セル３０は約３
００ｐ厚に固体電解質層２２を形成し、酸化ニッケル（
Ｎｉｐ）とジルコニア（ＺｒＯ□）を所定の割合で含む
ペーストを固体電解質層２２の１主面に塗布してニッケ
ル−ジルコニアサーメット基板に貼着し、さらに他の主
面にはランタンストロンチウムマンガナイト（Ｌａｏ、
ｑ’Ｓｒｏ、 ＋ＭｎＯ：＋）を含むペーストを塗布し
乾燥したのち焼成して製造される。燃料極は酸化ニッケ
ルとジルコニアを用いて形成されるが使用に際して燃料
ガスにより酸化ニッケルが還元され、ニッケルジルコニ
アサーメットが形成される。生成したニッケルが触媒と
して機能する。ジルコニアはニッケルの焼結を防止する
とともに電解質体としても機能する。The gas separator 24 is made of lanthanum calcium chromite (Lao, aCao, 2C) by mixing powders of lanthanum oxide (LazOi), calcium oxide (Cab), and chromium oxide (Crz(h)) at a predetermined ratio and reacting the mixture at 1300°C.
rOs), pulverized, granulated, and press-molded.
Manufactured by dense firing at 00°C. A thickness of 2 to 3 fl is required to provide the ribs. Single cell 30 is about 3
A solid electrolyte layer 22 is formed with a thickness of 00p, and nickel oxide (
A paste containing a predetermined ratio of lanthanum strontium manganite (Nip) and zirconia (ZrO Lao,
It is manufactured by applying a paste containing q'Sro, +MnO:+), drying it, and then firing it. The fuel electrode is formed using nickel oxide and zirconia, but during use, the nickel oxide is reduced by the fuel gas to form nickel zirconia cermet. The nickel produced functions as a catalyst. Zirconia prevents nickel from sintering and also functions as an electrolyte.
しかしながら上述のような従来の固体電解質型燃料電池
においては、燃料極２１であるニッケルジルコニアサー
メットの内部は燃料ガスに触れ還元ふん囲気となってい
るが、サーメットの周縁部は空気と接触し、酸化ふん囲
気となっている。そのためにサーメットの周縁部はニッ
ケルが酸化され酸化ニッケルとなっている。ニッケルが
酸化ニッケルとなるときの体積増加は６０％であるうえ
に、ニッケル部と酸化ニッケル部の境界領域は燃料電池
運転中のガス圧力のバランスで流動的に変化する。従っ
て境界近傍ではサーメット中のニッケルは内部のガス圧
力の高低により酸化されたり、あるいはまた還元された
りする。この酸化還元の繰り返しによる体積変化で、ニ
ッケル−ジルコニアサーメット基板に亀裂が入り、その
基板に設けられた電解質層にも亀裂が入り、反応ガス同
士の混触が起こって固体電解質型燃料電池の特性が低下
し、さらに運転の続行ができなくなるという問題があっ
た。However, in the conventional solid oxide fuel cell as described above, the inside of the nickel zirconia cermet that is the fuel electrode 21 comes into contact with the fuel gas and becomes a reducing atmosphere, but the periphery of the cermet comes into contact with air and is oxidized. There is a lot of atmosphere. For this reason, the nickel at the periphery of the cermet is oxidized to become nickel oxide. When nickel becomes nickel oxide, the volume increases by 60%, and the boundary area between the nickel part and the nickel oxide part changes fluidly depending on the gas pressure balance during fuel cell operation. Therefore, near the boundary, the nickel in the cermet is oxidized or reduced depending on the internal gas pressure. Due to the volume change caused by this repeated redox, the nickel-zirconia cermet substrate cracks, and the electrolyte layer provided on the substrate also cracks, causing the reaction gases to come into contact with each other and causing the characteristics of the solid oxide fuel cell to deteriorate. There was a problem in that the vehicle speed deteriorated, making it impossible to continue driving.
この発明は上述の点に鑑みてなされその目的はニッケル
−ジルコニアサーメット多孔質基板の亀裂を防止して信
転性に優れる固体電解質型燃料電池を提供することにあ
る。The present invention has been made in view of the above-mentioned points, and its object is to provide a solid oxide fuel cell which prevents cracks in a nickel-zirconia cermet porous substrate and has excellent reliability.
上述の目的はこの発明によれば単セルを有し、単セルは
燃料極２１であるニッケル−ジルコニアサーメット多孔
質基板と、この多孔質基板の１方の主面の全域に設けら
れた固体電解質層２２と、前記多孔質基板の外周側面に
設けられた被覆層２５と、前記固体電解質層に積層され
た空気極２３とを備えることにより達成される。The above-mentioned object has a single cell according to the present invention, and the single cell has a nickel-zirconia cermet porous substrate which is the fuel electrode 21, and a solid electrolyte provided over the entire main surface of one of the porous substrates. This is achieved by comprising a layer 22, a covering layer 25 provided on the outer peripheral side of the porous substrate, and an air electrode 23 laminated on the solid electrolyte layer.
被覆層２５はガス不透過性であることが要求される。固
体電解質層２２と同一材料を用いることもできる。被覆
層としてはアルミナ、ジルコニア、ランタンクロマイト
等が好適に用いられる。The covering layer 25 is required to be gas impermeable. The same material as the solid electrolyte layer 22 can also be used. Alumina, zirconia, lanthanum chromite, etc. are preferably used as the coating layer.
被覆層２５を設けるとニッケル−ジルコニアサーメット
基板に空気が浸入することがなくなり、サーメット中の
ニッケルは還元状態に維持される。Providing the coating layer 25 prevents air from entering the nickel-zirconia cermet substrate, and the nickel in the cermet is maintained in a reduced state.
次にこの発明の実施例を図面に基いて説明する。 Next, embodiments of the present invention will be described based on the drawings.
第１図はこの発明の実施例に係る固体電解質型燃料電池
のガスセパレータ２４と単セル３０＾の配置を示す断面
図である。従来の燃料電池とは被覆層２５を設けた点が
異なっている。酸化ニッケル（ＮＩＯ）と８％イツトリ
アで安定化されたジルコニア （８％ＹｚＯ＋−ＺｒＯ
□）の各粉体を所定の割合で混合し造粒したのちプレス
成型して温度１４００〜１６００℃で焼成し多孔質の燃
料極２１が得られる。燃料極２１を支持体として燃料極
２１のリブを有しない主面と、外周側面にジルコニアが
プラズマ溶射され、固体電解質層２２と被覆層２５が形
成される。ジルコニアの溶射は、直流減圧ブラスマ溶射
法を用いて行われる。FIG. 1 is a sectional view showing the arrangement of a gas separator 24 and a single cell 30^ of a solid oxide fuel cell according to an embodiment of the present invention. This fuel cell differs from conventional fuel cells in that a covering layer 25 is provided. Zirconia stabilized with nickel oxide (NIO) and 8% yttria (8% YzO+-ZrO
The powders of □) are mixed in a predetermined ratio, granulated, press-molded, and fired at a temperature of 1400 to 1600°C to obtain a porous fuel electrode 21. Using the fuel electrode 21 as a support, zirconia is plasma sprayed onto the rib-free main surface and the outer peripheral side surface of the fuel electrode 21 to form a solid electrolyte layer 22 and a coating layer 25. Thermal spraying of zirconia is performed using a direct current reduced pressure plasma spraying method.
ガスはＡｒ／Ｈｅの混合ガスであり圧力はｌ００Ｔｏｒ
ｒである。続いてＬａｏ、 ９Ｓｒｏ、 ＋ Ｍｎ０ａ
と溶剤からなるペーストが固体電解質層２２の上に刷毛
塗りされ乾燥後１２００℃で焼成して空気極２３が形成
される。ガスセパレータ２４はランタンクロマイト（Ｌ
ａｏ、 ＢＣａｏ、 ｚｃｒｏ３）を用い従来技術と同
様にして調製される。The gas is a mixed gas of Ar/He and the pressure is 100 Torr.
It is r. Followed by Lao, 9Sro, + Mn0a
A paste consisting of a solvent and a solvent is brushed onto the solid electrolyte layer 22, dried, and then fired at 1200° C. to form the air electrode 23. The gas separator 24 is made of lanthanum chromite (L
ao, BCao, zcro3) in the same manner as in the prior art.
この発明によれば単セルを有し、
単セルは燃料極であるニソケルージルコニアザーメット
多孔質基板と、この多孔質基板の１方の主面の全域に設
けられた固体電解質層と、前記多孔質基板の外周側面に
設けられた被覆層と、前記固体電解質層に積層された空
気極とを備えるのでニッケルーシルコニアサ−メソ１〜
多孔質基板は被覆層により空気と遮断され、サーメット
のニッケルは常に還元状態に維持されて酸化と還元の繰
返しを行うことがなくなりサーメット基板に亀裂が入る
ことが防止される。このようにして信幀性に優れる固体
電解質型燃料電池が得られる。According to the present invention, a single cell is provided, and the single cell includes a porous Nisokeru-zirconia cermet substrate serving as a fuel electrode, a solid electrolyte layer provided over the entire area of one main surface of the porous substrate, Since it includes a coating layer provided on the outer peripheral side surface of the porous substrate and an air electrode laminated on the solid electrolyte layer, the nickel-silconia thermeso 1 to
The porous substrate is isolated from the air by the coating layer, and the nickel in the cermet is always maintained in a reduced state, preventing repeated oxidation and reduction, thereby preventing the cermet substrate from cracking. In this way, a solid oxide fuel cell with excellent reliability can be obtained.
第１図はこの発明の実施例に係る燃料電池のガスセパレ
ータと単セルの配置を示す断面図、第２図は従来の燃料
電池のガスセパレータと単セルの配置を示す断面図であ
る。FIG. 1 is a sectional view showing the arrangement of a gas separator and a single cell of a fuel cell according to an embodiment of the present invention, and FIG. 2 is a sectional view showing the arrangement of a gas separator and a single cell of a conventional fuel cell.
Claims (1)
多孔質基板と、この多孔質基板の１方の主面の全域に設
けられた固体電解質層と前記多孔質基板の外周側面に設
けられた被覆層と、前記固体電解質層に積層された空気
極とを備えることを特徴とする固体電解質型燃料電池。[Claims] 1) It has a single cell, and the single cell includes a nickel-zirconia cermet porous substrate serving as a fuel electrode, and a solid electrolyte layer provided over the entire main surface of one of the porous substrates. A solid oxide fuel cell comprising: a coating layer provided on an outer peripheral side surface of the porous substrate; and an air electrode laminated on the solid electrolyte layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2143481A JPH0436962A (en) | 1990-06-01 | 1990-06-01 | Fuel cell with solid electrolyte |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2143481A JPH0436962A (en) | 1990-06-01 | 1990-06-01 | Fuel cell with solid electrolyte |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0436962A true JPH0436962A (en) | 1992-02-06 |
Family
ID=15339708
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2143481A Pending JPH0436962A (en) | 1990-06-01 | 1990-06-01 | Fuel cell with solid electrolyte |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0436962A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006108006A (en) * | 2004-10-08 | 2006-04-20 | Nissan Motor Co Ltd | Separator, solid electrolyte fuel cell using this, and its manufacturing method |
| US7122268B2 (en) | 2001-04-23 | 2006-10-17 | Nissan Motor Co., Ltd. | Solid oxide electrolyte fuel cell plate structure, stack and electrical power generation unit |
| KR100736161B1 (en) * | 2005-03-31 | 2007-07-06 | 고등기술연구원연구조합 | Electric cell for high and a method of preparing the same for the high temperature electrolysis |
| JP2008251246A (en) * | 2007-03-29 | 2008-10-16 | Dainippon Printing Co Ltd | Structure for solid oxide fuel cell, and solid oxide fuel cell using this |
| JP2008251241A (en) * | 2007-03-29 | 2008-10-16 | Dainippon Printing Co Ltd | Solid oxide fuel cell and its stack structure |
| JP2008293843A (en) * | 2007-05-25 | 2008-12-04 | Ngk Spark Plug Co Ltd | Solid oxide fuel cell |
-
1990
- 1990-06-01 JP JP2143481A patent/JPH0436962A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7122268B2 (en) | 2001-04-23 | 2006-10-17 | Nissan Motor Co., Ltd. | Solid oxide electrolyte fuel cell plate structure, stack and electrical power generation unit |
| US8323845B2 (en) | 2001-04-23 | 2012-12-04 | Nissan Motor Co., Ltd. | Solid oxide electrolyte fuel cell plate structure, stack and electrical power generation unit |
| JP2006108006A (en) * | 2004-10-08 | 2006-04-20 | Nissan Motor Co Ltd | Separator, solid electrolyte fuel cell using this, and its manufacturing method |
| KR100736161B1 (en) * | 2005-03-31 | 2007-07-06 | 고등기술연구원연구조합 | Electric cell for high and a method of preparing the same for the high temperature electrolysis |
| JP2008251246A (en) * | 2007-03-29 | 2008-10-16 | Dainippon Printing Co Ltd | Structure for solid oxide fuel cell, and solid oxide fuel cell using this |
| JP2008251241A (en) * | 2007-03-29 | 2008-10-16 | Dainippon Printing Co Ltd | Solid oxide fuel cell and its stack structure |
| JP2008293843A (en) * | 2007-05-25 | 2008-12-04 | Ngk Spark Plug Co Ltd | Solid oxide fuel cell |
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