JPH0435525B2 - - Google Patents

Info

Publication number
JPH0435525B2
JPH0435525B2 JP4084584A JP4084584A JPH0435525B2 JP H0435525 B2 JPH0435525 B2 JP H0435525B2 JP 4084584 A JP4084584 A JP 4084584A JP 4084584 A JP4084584 A JP 4084584A JP H0435525 B2 JPH0435525 B2 JP H0435525B2
Authority
JP
Japan
Prior art keywords
hot metal
desiliconization
skinmer
desiliconizing
desiliconizing agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP4084584A
Other languages
Japanese (ja)
Other versions
JPS60184614A (en
Inventor
Hiroshi Shibuta
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Sumitomo Metal Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Metal Industries Ltd filed Critical Sumitomo Metal Industries Ltd
Priority to JP4084584A priority Critical patent/JPS60184614A/en
Publication of JPS60184614A publication Critical patent/JPS60184614A/en
Publication of JPH0435525B2 publication Critical patent/JPH0435525B2/ja
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C1/00Refining of pig-iron; Cast iron
    • C21C1/04Removing impurities other than carbon, phosphorus or sulfur

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

発明の技術分野 この発明は高炉から出銑した溶銑の脱珪処理を
出銑樋において効率よく行なう溶銑の脱珪方法に
関する。 従来技術とその問題点 溶銑予備処理法の一つに、高炉の出銑樋内に脱
珪剤を投入して溶銑の脱珪処理を行なう樋脱珪法
が最近よく利用されている。例えば、特公昭58−
56723号で知られるごとく、高炉の出銑口から出
銑された溶銑中に脱珪剤を添加し、一緒に流れて
行く間の自然な混合を利用して溶銑中の含有珪素
を酸化除去する方法が知られている。この他、こ
の種の樋脱珪方法には種々の手段がとられている
が、従来の樋脱珪方法はいずれも溶銑とスラグを
分離するスキンマーの下流において脱珪剤を添加
している。これは、スラグ分離後の方が脱珪効率
が高いことによる。しかし、スキンマー下流にお
ける脱珪剤の添加のみでは以下に示す問題があ
る。 すなわち、出銑〔Si〕の変動に対応しきれない
ことである。例えば、出銑〔Si〕が平均0.45%
で、処理後〔Si〕目標が0.25%の場合、高炉炉況
変動により出銑〔Si〕が0.60%になると、処理後
〔Si〕0.25%達成は困難である。また、次工程で
溶銑脱燐を実施する場合、処理後〔Si〕は極力低
いことが望まれ、〔Si〕≦0.15%が必要とされる。
しかし、スキンマー下流のみでの脱珪処理ではこ
のレベルを安定して達成することは困難である。 これらの対策として、従来はトーピード脱珪等
を利用して調整が行なわれているが、工程増、処
理時間槽から大量の処理には不向きであつた。 発明の目的 この発明は、従来の前記実情に鑑みてなされた
もので、大量の溶銑脱珪・脱燐に対応すべく、高
炉鋳床において確実に〔Si〕≦0.15%を達成し得
る溶銑の樋脱珪法を提案することを目的とするも
のである。 発明の開示 この発明に係る溶銑の脱珪方法は、高炉鋳床に
おいて、出銑口からスキンマーに至る間で脱珪剤
を添加して1次脱珪を行ない、さらにスキンマー
からトーピードに至る間で脱珪剤を添加して2次
脱珪を行なうことを特徴とするものである。 すなわちこの発明は、鋳床脱珪において従来実
施されていなかつたスキンマー上流にて脱珪剤を
添加する1次脱珪と、スキンマー下流における2
次脱珪とのいわゆる2段脱珪処理により、処理後
〔Si〕≦0.15%を達成する方法である。 以下、この発明法を図面を参照しつつ詳細に説
明する。 第1図において、1は高炉、2は出銑口、3は
出銑樋、4はスキンマー、5は溶銑樋、6排滓
口、7はトーピードカーをそれぞれ示す。すなわ
ち、高炉1の出銑口2より排出する溶銑8は出銑
樋3内に設置されているスキンマー4にて溶銑8
とスラグ8−2が分離され、スラグ8−2は排滓
口6より排出し、溶銑8はスキンマー4の下流の
溶銑樋5を流れてトーピードカー7に至る。 この発明は1次脱珪として、出銑口2よりスキ
ンマー4に至るまでの出銑樋3におい脱珪剤9−
1を添加する。この1次脱珪において脱珪剤を添
加する場所は特に限定するものではないが、通常
スキンマー4までは溶銑8上をスラグ8−2が覆
つており自然混合では脱珪効率の低下から考えら
れるので、実際には出銑口2に近い所が望まし
い。特に出銑口から流下する溶銑の落下点に脱珪
剤を添加すればより効果的である。その他、脱珪
を促進させる方法としては、例えば出銑口カバー
を利用してN2ガスまたは空気等と共に固形脱珪
剤をインジエクシヨンする方法や、出銑樋に落差
をつけ、その落差によつて生ずる撹拌流に脱珪剤
を捲込ませる方法等を採用することもできる。な
お、この1次脱珪における脱珪剤の添加量として
は、〔Si〕含有量に応じて定めることになるが、
この段階では前記した通り溶銑がスラグで覆われ
ているので、脱珪剤がスラグに捕捉されやすい。
従つて、多量に添加してもそれがすべて反応する
とは限らないので、溶銑量、〔Si〕含有量に応じ
適当に加減して添加する。 このようにして1次脱珪された溶銑8はスキン
マー4にて高炉スラグと脱珪スラグが分離されて
溶銑樋5へ流れるが、ここでトーピードカー7に
落下する前の溶銑8に脱珪剤9−2を添加して2
次脱珪を行なう。この段階における脱珪剤の添加
量については前記1次脱珪処理後〔Si〕量に応じ
て決定し、その添加方法はN2ガス等と共に吹込
むインジエクシヨン方式等を用いることもでき
る。 上記のごとく、この発明はスキンマーの上流と
下流で脱珪処理を行なうので、高炉から出銑した
高〔Si〕含有溶銑中の〔Si〕を溶銑脱燐に必要と
される0.15%以下に高炉鋳床において達成するこ
とが十分可能である。従つて、この発明によれ
ば、工程増、処理時間増の問題が解決されること
により、大量の溶銑脱珪処理が可能となる。な
お、この発明法における脱珪剤は製鉄ダスト、ミ
ルスケール、粉鉱石、焼結鉱等の酸化鉄系、およ
びMnO系あるいはO2含有ガス等である。 次に、この発明の実施例について説明する。 実施例 高炉から出銑される第1表に示す成分を有する
溶銑(温度1510℃)に対し、スキンマー上流の出
銑樋上で脱珪剤(平均粒度5mmの焼結粉)をイン
ジエクシヨン方式(エアー圧2Kg/cm2)で20Kg/
T吹込んで1次脱珪処理し、さらに1次脱珪処理
後の溶銑に対し、スキンマー下流の溶銑樋上で同
じ脱珪剤を15Kg/T投入して2次脱珪処理した。 本実施例における1次脱珪処理後の溶銑成分と
2次脱珪処理後の溶銑成分を第2表に示す。 第2表より明らかなごとく、この発明の2段脱
珪処理により、高〔Si〕含有溶銑中の〔Si〕を高
炉鋳床において0.15%以下に脱珪することができ
た。
TECHNICAL FIELD OF THE INVENTION The present invention relates to a method for desiliconizing hot metal tapped from a blast furnace, in which the desiliconization treatment of hot metal is efficiently carried out in a tap trough. Prior art and its problems One of the hot metal pretreatment methods that has recently been widely used is the trough desiliconization method, in which a desiliconizing agent is introduced into the tap trough of a blast furnace to desiliconize the hot metal. For example, the
As known from No. 56723, a desiliconizing agent is added to the hot metal tapped from the taphole of a blast furnace, and the silicon contained in the hot metal is oxidized and removed using natural mixing as it flows together. method is known. In addition, various methods have been adopted for this type of gutter desiliconization method, but in all conventional gutter desiliconization methods, a desiliconizing agent is added downstream of a skinmer that separates hot metal and slag. This is because the desiliconization efficiency is higher after slag separation. However, only adding a desiliconizing agent downstream of the skinmer has the following problems. In other words, it is not possible to cope with fluctuations in iron tap [Si]. For example, tap iron [Si] averages 0.45%
If the after-treatment [Si] target is 0.25%, if the tapped iron [Si] becomes 0.60% due to changes in blast furnace conditions, it will be difficult to achieve the after-treatment [Si] of 0.25%. Furthermore, when hot metal dephosphorization is performed in the next step, it is desirable that [Si] be as low as possible after the treatment, and [Si]≦0.15% is required.
However, it is difficult to stably achieve this level by desiliconization treatment only downstream of the skinmer. Conventionally, as a countermeasure against these problems, adjustment has been carried out using torpedo desiliconization, etc., but this is not suitable for large-scale processing due to the increase in steps and processing time. Purpose of the Invention The present invention was made in view of the above-mentioned conventional situation, and in order to cope with the desiliconization and dephosphorization of a large amount of hot metal, it is possible to produce hot metal that can reliably achieve [Si]≦0.15% in a blast furnace cast bed. The purpose of this paper is to propose a method for removing silicon from gutters. DISCLOSURE OF THE INVENTION The method for desiliconizing hot metal according to the present invention involves adding a desiliconizing agent between the taphole and the skinmer to perform primary desiliconization in a blast furnace casthouse, and then performing the primary desiliconization between the skinmer and the torpedo. This method is characterized by performing secondary desiliconization by adding a desiliconizing agent. In other words, the present invention provides primary desiliconization in which a desiliconizing agent is added upstream of the skinmer, which has not been conventionally carried out in castbed desiliconization, and secondary desiliconization in the downstream of the skinmer.
This is a method of achieving [Si]≦0.15% after treatment by a so-called two-stage desiliconization treatment including a subsequent desiliconization. Hereinafter, this invention method will be explained in detail with reference to the drawings. In FIG. 1, 1 is a blast furnace, 2 is a tap hole, 3 is a tap sluice, 4 is a skimmer, 5 is a hot metal sluice, 6 is a slag discharge port, and 7 is a torpedo car. That is, the hot metal 8 discharged from the tap hole 2 of the blast furnace 1 is removed by the skinmer 4 installed in the tap sluice 3.
The slag 8-2 is separated, the slag 8-2 is discharged from the slag discharge port 6, and the hot metal 8 flows through the hot metal trough 5 downstream of the skinmer 4 and reaches the torpedo car 7. This invention uses a desiliconizing agent 9- in the tap duct 3 from the taphole 2 to the skinmer 4 as primary desiliconization.
Add 1. The place where the desiliconizing agent is added in this primary desiliconization is not particularly limited, but the slag 8-2 usually covers the hot metal 8 up to skinmer 4, and it is thought that natural mixing will reduce the desiliconizing efficiency. Therefore, a location close to taphole 2 is actually desirable. In particular, it is more effective to add a desiliconizing agent to the drop point of the hot metal flowing down from the taphole. Other methods for promoting desiliconization include, for example, using a taphole cover to inject a solid desiliconizing agent with N 2 gas or air, or adding a head to the tap runner and using the head It is also possible to adopt a method in which a desiliconizing agent is stirred into the resulting stirring flow. The amount of desiliconizing agent added in this primary desiliconization is determined depending on the [Si] content.
At this stage, as described above, the hot metal is covered with slag, so the desiliconizing agent is likely to be captured by the slag.
Therefore, even if a large amount is added, not all of it will react, so it should be added in an appropriate amount depending on the amount of hot metal and [Si] content. The hot metal 8 that has been subjected to the primary desiliconization in this way is separated into blast furnace slag and desiliconized slag by the skimmer 4 and flows to the hot metal trough 5, where the desiliconization agent 9 is added to the hot metal 8 before falling into the torpedo car 7. -2 by adding 2
Next, remove the silicon. The amount of the desiliconizing agent to be added at this stage is determined depending on the amount of [Si] after the first desiliconizing treatment, and the addition method may be an injection method in which the desiliconizing agent is blown together with N 2 gas or the like. As mentioned above, this invention performs desiliconization treatment upstream and downstream of the skinmer, so the Si content in the high Si content hot metal tapped from the blast furnace is reduced to below 0.15%, which is required for hot metal dephosphorization. It is quite possible to achieve this in a casthouse. Therefore, according to the present invention, the problems of increased process steps and increased processing time are solved, and a large amount of hot metal can be desiliconized. Note that the desiliconizing agent used in the method of this invention is iron oxide based such as iron dust, mill scale, fine ore, sintered ore, and MnO based or O 2 -containing gas. Next, embodiments of the invention will be described. Example A desiliconizing agent (sintered powder with an average particle size of 5 mm) was applied to hot metal having the components shown in Table 1 (temperature: 1510°C), which is tapped from a blast furnace, on the tap flute upstream of the skinmer using an in-die extraction method (air pressure). 2Kg/ cm2 ) and 20Kg/
First desiliconization treatment was carried out by blowing T into the hot metal, and 15 kg/T of the same desiliconizing agent was added to the hot metal after the first desiliconization treatment on the hot metal trough downstream of the skinmer to carry out a second desiliconization treatment. Table 2 shows the hot metal components after the primary desiliconization treatment and the hot metal components after the secondary desiliconization treatment in this example. As is clear from Table 2, by the two-stage desiliconization treatment of the present invention, [Si] in high [Si]-containing hot metal could be desiliconized to 0.15% or less in the blast furnace cast bed.

【表】【table】

【表】【table】 【図面の簡単な説明】[Brief explanation of drawings]

第1図はこの発明の一実施例を示す概略図であ
る。 1……高炉、2……出銑口、3……出銑樋、4
……スキンマー、5……溶銑樋、6……排滓口、
7……トーピードカー、8……溶銑、9−1,9
−2……脱珪剤。
FIG. 1 is a schematic diagram showing an embodiment of the present invention. 1...Blast furnace, 2...Tapping hole, 3...Tapping sluice, 4
...Skinmer, 5...Hot metal trough, 6...Slag outlet,
7...Torpedo car, 8...Hot metal, 9-1,9
-2... Desiliconizing agent.

Claims (1)

【特許請求の範囲】[Claims] 1 高炉出銑樋上で溶銑の脱珪処理を行なう方法
において、出銑口からスキンマーに至る間で脱珪
剤を添加して1次脱珪を行ない、さらにスキンマ
ーからトーピードに至る間で脱珪剤を添加して2
次脱珪を行なうことを特徴とする溶銑の脱珪方
法。
1 In a method of desiliconizing hot metal on the taphole of a blast furnace, a desiliconizing agent is added between the tap hole and the skinmer to perform primary desiliconization, and then a desiliconizing agent is added between the skinmer and the torpedo. Add 2
A method for desiliconization of hot metal, characterized by carrying out subsequent desiliconization.
JP4084584A 1984-03-02 1984-03-02 Method for desiliconizing molten iron Granted JPS60184614A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4084584A JPS60184614A (en) 1984-03-02 1984-03-02 Method for desiliconizing molten iron

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4084584A JPS60184614A (en) 1984-03-02 1984-03-02 Method for desiliconizing molten iron

Publications (2)

Publication Number Publication Date
JPS60184614A JPS60184614A (en) 1985-09-20
JPH0435525B2 true JPH0435525B2 (en) 1992-06-11

Family

ID=12591924

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4084584A Granted JPS60184614A (en) 1984-03-02 1984-03-02 Method for desiliconizing molten iron

Country Status (1)

Country Link
JP (1) JPS60184614A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020022577A1 (en) * 2018-07-24 2020-01-30 주식회사 포스코 Apparatus for molten iron runner desilication

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63213615A (en) * 1987-02-27 1988-09-06 Kobe Steel Ltd Desiliconizing method in molten iron trough with multi step

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020022577A1 (en) * 2018-07-24 2020-01-30 주식회사 포스코 Apparatus for molten iron runner desilication

Also Published As

Publication number Publication date
JPS60184614A (en) 1985-09-20

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