JPH04353167A - Curing sheet - Google Patents
Curing sheetInfo
- Publication number
- JPH04353167A JPH04353167A JP12739991A JP12739991A JPH04353167A JP H04353167 A JPH04353167 A JP H04353167A JP 12739991 A JP12739991 A JP 12739991A JP 12739991 A JP12739991 A JP 12739991A JP H04353167 A JPH04353167 A JP H04353167A
- Authority
- JP
- Japan
- Prior art keywords
- sheet
- curing sheet
- curing
- effective
- resins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003094 microcapsule Substances 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 9
- 239000004745 nonwoven fabric Substances 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims description 13
- 238000010276 construction Methods 0.000 abstract description 8
- 230000001681 protective effect Effects 0.000 abstract description 4
- 230000002265 prevention Effects 0.000 abstract 1
- 230000003449 preventive effect Effects 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 description 10
- 230000001070 adhesive effect Effects 0.000 description 10
- 229920000126 latex Polymers 0.000 description 9
- 239000004816 latex Substances 0.000 description 9
- 239000010410 layer Substances 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- -1 polyethylene Polymers 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 239000002775 capsule Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 239000002655 kraft paper Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 239000003232 water-soluble binding agent Substances 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920008347 Cellulose acetate propionate Polymers 0.000 description 1
- 239000004859 Copal Substances 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 241000782205 Guibourtia conjugata Species 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 229920006311 Urethane elastomer Polymers 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- KLIYQWXIWMRMGR-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate Chemical compound C=CC=C.COC(=O)C(C)=C KLIYQWXIWMRMGR-UHFFFAOYSA-N 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 229920003090 carboxymethyl hydroxyethyl cellulose Polymers 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 230000009194 climbing Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 235000013808 oxidized starch Nutrition 0.000 description 1
- 239000001254 oxidized starch Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000010454 slate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229920003170 water-soluble synthetic polymer Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Tents Or Canopies (AREA)
- Building Environments (AREA)
- Laminated Bodies (AREA)
Abstract
Description
【０００１】0001
【産業上の利用分野】本発明は、家屋の建築作業中に足
場となったときに汚したり、傷つけ易い場所を保護する
ために、或いは屋根を葺く際に防水目的で屋根の下に敷
くシート（本発明ではこれらを含めて「養生シート」と
いう）の改良に関するものである。[Industrial Application Field] The present invention is used to protect areas that are easily soiled or damaged when used as scaffolding during house construction work, or to be placed under a roof for waterproof purposes when roofing. The present invention relates to improvements in sheets (in the present invention, these are collectively referred to as "curing sheets").
【０００２】0002
【従来の技術】従来、家屋の建築作業中に足場となると
きに汚したり、傷つき易い場所を保護するため使用する
養生シートとしては、新聞紙や空袋等の廃物を利用して
きた。しかし、近年の建築ブームを背景に、養生シート
が一つの商品として生産されるようになってきた。2. Description of the Related Art Conventionally, waste materials such as newspapers and empty bags have been used as curing sheets used as scaffolding during house construction work to protect soiled or easily damaged areas. However, against the backdrop of the recent construction boom, curing sheets have come to be produced as a single product.
【０００３】また、屋根を葺くのに、従来は屋根瓦は土
を介して葺くのが普通であった。しかし、建築様式の多
様化に伴い屋根を葺くのに、最近では土を使わずクラフ
ト紙或いは不織布等の片面乃至両面にポリエチレン（以
下「ＰＥ」と称す）やポリプロピレン（以下「ＰＰ」と
称す）を貼り合わせ或いはラミネートし、その後にエン
ボス加工を施して構成した耐水性シートを介してスレー
ト屋根を葺く場合も多い。[0003] Furthermore, in the past, when roofing was done, roof tiles were usually covered with soil. However, with the diversification of architectural styles, roofing is now done using polyethylene (hereinafter referred to as ``PE'') or polypropylene (hereinafter referred to as ``PP'') on one or both sides of kraft paper or non-woven fabric instead of using soil. ) are bonded or laminated together and then embossed to form a slate roof.
【０００４】しかし、従来の養生シートは、これを床や
廊下に敷いてその上を足場に建築作業をする場合には直
ぐにずれてしまって保護の役目を充分に果たせなかった
り、屋根の下に敷く耐水性の養生シートにしても表面層
がＰＥ，ＰＰであるため、これを敷いて屋根葺き作業を
行う場合に足場が滑り易く極めて危険であるという問題
がある。[0004] However, when conventional curing sheets are spread on floors or hallways and used as scaffolding for construction work, they easily shift and cannot fulfill their protective role. Even if a water-resistant curing sheet is used, the surface layer is made of PE or PP, so when roofing work is performed using this sheet, the scaffolding becomes slippery and extremely dangerous.
【０００５】[0005]
【発明が解決しようとする課題】本発明は、建築作業中
に足場となって汚したり、傷つき易い場所を保護するた
めに、或いは屋根の下に耐水性シートとして敷き、その
上に屋根を葺く際に足場の滑りを防止しうる養生シート
を提供することを目的とするものである。[Problems to be Solved by the Invention] The present invention is designed to be used as scaffolding during construction work to protect areas that are easily soiled or damaged, or to be placed under a roof as a water-resistant sheet and then covered with a roof. The purpose of this invention is to provide a curing sheet that can prevent scaffolding from slipping when climbing.
【０００６】[0006]
【課題を解決する為の手段】本発明は、少なくとも基材
の片面に防滑層を設けた事を特徴とする養生シートであ
る。[Means for Solving the Problems] The present invention is a curing sheet characterized in that an anti-slip layer is provided on at least one side of a base material.
【０００７】[0007]
【作用】本発明に於いて防滑層は、ゴム弾性を有する例
えば、シリコンゴム、ウレタンゴム、微粘着剤或いは発
泡性マイクロカプセルを含有する層等で構成される。中
でも発泡性マイクロカプセルは中空の弾性体であること
から、これを使用した防滑層は、他の弾性体に比してよ
り弾性に富み、防滑効果に優れていることから本発明に
とって効果的である。[Function] In the present invention, the anti-slip layer is composed of a layer having rubber elasticity, such as a layer containing silicone rubber, urethane rubber, a slight adhesive, or foamable microcapsules. Among them, foamable microcapsules are hollow elastic bodies, so anti-slip layers using them are more elastic and have excellent anti-slip effects than other elastic bodies, so they are effective for the present invention. be.
【０００８】該発泡性マイクロカプセルは、例えば構成
として芯物質にｎ−ブタン，ｉ−ブタン，ペンタン，ネ
オペンタンの様な低沸点の炭化水素を内包し、壁膜剤と
して塩化ビニリデン，アクリロニトリル，メチルメタク
リレートの様な（メタ）アクリル酸エステル，スチレン
の様な芳香族ビニル化合物を主成分とする熱可塑性樹脂
を使用したマイクロカプセルが挙げられる。The foamable microcapsules have, for example, a core material containing a low-boiling hydrocarbon such as n-butane, i-butane, pentane, or neopentane, and a wall material such as vinylidene chloride, acrylonitrile, or methyl methacrylate. Examples include microcapsules using thermoplastic resins whose main components are (meth)acrylic esters such as (meth)acrylic esters, and aromatic vinyl compounds such as styrene.
【０００９】このような発砲性マイクロカプセルは市販
品として、松本マイクロスフェアＦ−３０，Ｆ−５０，
Ｆ−８０〔何れも松本油脂（株）製の商品名である〕、
エクスパンセルＷＵ−６４２，ＷＵ−５５１，ＷＵ−４
６２〔何れもエクスパンセル社製の商品名である〕が挙
げられる。Such foamable microcapsules are commercially available as Matsumoto Microsphere F-30, F-50,
F-80 [both are trade names manufactured by Matsumoto Yushi Co., Ltd.],
Expancel WU-642, WU-551, WU-4
62 (both are trade names manufactured by Expancel).
【００１０】該発泡性マイクロカプセルは、これを接着
剤と併用して塗被液となし基材に塗布するが、この塗被
液を構成する接着剤としては、水性系として塗布する場
合には、ラテックス系バインダー，水溶性バインダーが
使用される。また非水性系として塗布する場合には、油
溶性バインダーが使用される。また電子線或いは紫外線
で硬化する場合には、エチレン性不飽和結合を有するモ
ノマー，オリゴマー或いはプレポリマーが使用される。[0010] The foamable microcapsules are applied to the base material using a coating liquid in combination with an adhesive, but the adhesive constituting this coating liquid is when applied as an aqueous system. , latex binders, and water-soluble binders are used. Moreover, when applying as a non-aqueous system, an oil-soluble binder is used. When curing with electron beams or ultraviolet rays, monomers, oligomers or prepolymers having ethylenically unsaturated bonds are used.
【００１１】ここで使用されるラテックス系バインダー
としては、スチレン・ブタジエン系ラテックス，アクリ
ロニトリル・ブタジエン系ラテックス，メチルメタクリ
レート・ブタジエン系ラテックス，アクリル酸エステル
系ラテックス，酢酸ビニル系ラテックス，塩化ビニル系
ラテックス，及びこれらにアクリル酸の如き官能基を含
有させたものが挙げられる。[0011] The latex binder used here includes styrene-butadiene latex, acrylonitrile-butadiene latex, methyl methacrylate-butadiene latex, acrylic ester latex, vinyl acetate latex, vinyl chloride latex, and Examples include those containing a functional group such as acrylic acid.
【００１２】水溶性バインダーとしては、ゼラチン，カ
ゼイン等のプロテイン類，エーテル化澱粉，エステル化
澱粉，酸化澱粉等の澱粉類，カルボキシメチルセルロー
ス，ヒドロキシエチルセルロース等のセルロース類，ア
ルギン酸ソーダ，アラビヤゴム等の多糖類の如き水溶性
天然高分子化合物，ポリビニルアルコール，ポリアクリ
ル酸，ポリビニルピロリドン，ポリアクリルアミド，マ
レイン酸共重合体等の如き水溶性合成高分子化合物が挙
げられる。Examples of water-soluble binders include proteins such as gelatin and casein, starches such as etherified starch, esterified starch, and oxidized starch, celluloses such as carboxymethyl cellulose and hydroxyethyl cellulose, and polysaccharides such as sodium alginate and gum arabic. Examples include water-soluble natural polymer compounds such as , water-soluble synthetic polymers such as polyvinyl alcohol, polyacrylic acid, polyvinylpyrrolidone, polyacrylamide, maleic acid copolymers, and the like.
【００１３】油溶性バインダーとしては、各種ロジン，
コーパル，ダルマン等の天然樹脂，エチルセルロース，
ヒドロキシプロピルセルロース，ヒドロキシエチルセル
ロース，セルロースアセテートプロピオネート，重合ロ
ジン，エステルガム等の半合成樹脂，フェノール樹脂メ
ラミン樹脂，キシレン樹脂，尿素樹脂，石油樹脂，アル
キド樹脂，アクリル樹脂，塩化ビニル・酢酸ビニル共重
合体，ポリアミド樹脂，ポリウレタン，エポキシ樹脂等
の合成樹脂が挙げられる。[0013] As the oil-soluble binder, various rosins,
Natural resins such as copal and dalman, ethyl cellulose,
Hydroxypropyl cellulose, hydroxyethyl cellulose, cellulose acetate propionate, polymerized rosin, semi-synthetic resins such as ester gum, phenolic resins, melamine resins, xylene resins, urea resins, petroleum resins, alkyd resins, acrylic resins, vinyl chloride and vinyl acetate resins Examples include synthetic resins such as polymers, polyamide resins, polyurethane, and epoxy resins.
【００１４】また電子線或いは紫外線で硬化するエチレ
ン性不飽和結合を有するモノマー、オリゴマー、プレポ
リマーとしては、各種単官能，多官能の（メタ）アクリ
ル酸エステル類，ポリエステルアクリレート，ポリウレ
タンアクリレート等従来公知の化合物があげられる。な
かでもガラス転移点が４０℃以下の接着剤が防滑効果の
点で好ましい。Monomers, oligomers, and prepolymers having ethylenically unsaturated bonds that can be cured by electron beams or ultraviolet rays include conventionally known monofunctional and polyfunctional (meth)acrylic esters, polyester acrylates, polyurethane acrylates, etc. The following compounds can be mentioned. Among them, adhesives having a glass transition point of 40° C. or lower are preferred from the viewpoint of anti-slip effect.
【００１５】前記発泡性マイクロカプセルと接着剤の割
合は、通常接着剤１００重量部に対して発泡性マイクロ
カプセルが１〜９０重量部、好ましくは３〜５０重量部
、より好ましくは５〜３０重量部になる様に調製される
。The ratio of the expandable microcapsules to the adhesive is usually 1 to 90 parts by weight, preferably 3 to 50 parts by weight, more preferably 5 to 30 parts by weight, per 100 parts by weight of the adhesive. It is prepared in such a way that it becomes a portion.
【００１６】また発泡性マイクロカプセルと接着剤を主
成分とする塗料には、必要に応じて他にシリカ，水酸化
アルミニウム，炭酸カルシウム，カオリン，酸化チタン
，プラスチックピグメント等の顔料，ポリエチレンワッ
クス等の離型剤、再剥離粘着剤に使用される微粘着粒子
、界面活性剤、分散剤、帯電防止剤、消泡剤、着色剤、
蛍光染料等の助剤を添加する事も出来る。[0016] In addition, the paint containing foamable microcapsules and adhesive as its main components may also contain pigments such as silica, aluminum hydroxide, calcium carbonate, kaolin, titanium oxide, plastic pigments, polyethylene wax, etc. Mold release agents, slightly adhesive particles used in removable adhesives, surfactants, dispersants, antistatic agents, antifoaming agents, colorants,
Auxiliary agents such as fluorescent dyes can also be added.
【００１７】防滑剤塗料の調製法は、例えば水や有機溶
剤等の媒体に発泡性マイクロカプセル及び必要により顔
料等の助剤を添加し、更に接着剤を添加して調製する。
本発明における基材としては、紙、フィルム、不織布等
の基材を使用出来る。基材の強度、防水性、クッション
性等の点からは不織布が好ましい。そして不織布の中で
も、特に乾式法、スパンポンド法で製造した不織布は、
強度、耐水性、等に優れているので好ましい。The anti-slip paint is prepared, for example, by adding foamable microcapsules and, if necessary, an auxiliary agent such as a pigment to a medium such as water or an organic solvent, and further adding an adhesive. As the base material in the present invention, base materials such as paper, film, and nonwoven fabric can be used. Nonwoven fabrics are preferred from the standpoint of base material strength, waterproofness, cushioning properties, and the like. Among non-woven fabrics, non-woven fabrics manufactured by dry method and spun-pond method are particularly
It is preferable because it has excellent strength, water resistance, etc.
【００１８】防滑剤塗料の基材への塗布は、養生シート
の用途に応じて、片面又は両面に塗布することになる。
例えば、床、廊下等を保護するために使用する養生シー
トにあっては片面に塗布したもので良いが、屋根の下に
敷く養生シートにあっては両面に塗布したものが好まし
い。[0018] The anti-slip coating may be applied to one or both sides of the substrate depending on the use of the curing sheet. For example, a curing sheet used to protect floors, hallways, etc. may be coated on one side, but a curing sheet placed under a roof is preferably coated on both sides.
【００１９】防滑剤塗料の基材への塗布方式には、例え
ばバーコーター、エアーナイフコーター、グラビアコー
ター、ロールコーター等が使用される。防滑剤塗料の塗
布量は、防滑効果とコストを考慮して、乾燥後の塗布量
が片面当たり１〜３０ｇ／ｍ２ 、好ましくは３〜２０
ｇ／ｍ２ 程度になる様に塗布される。For example, a bar coater, an air knife coater, a gravure coater, a roll coater, etc. are used to apply the anti-slip coating to the base material. The amount of anti-slip coating applied after drying is 1 to 30 g/m2, preferably 3 to 20 g/m2 per side, considering the anti-slip effect and cost.
It is applied to approximately g/m2.
【００２０】マイクロカプセルの発泡は、通常カプセル
塗料を基材に塗布する際の乾燥過程で行われるが、場合
によってはコーター等による再加熱或いは印刷工程中の
加熱によっても可能である。その際の加熱温度は、使用
するカプセル壁膜のガラス転移点や処理時間等により変
わり一概に言えないが、前記市販のカプセルの場合は９
０〜１７０℃に設定するのが好ましい。加熱方法として
は、熱風、熱ロール，赤外線ヒーター，マイクロ波等従
来公知の方法を使用できる。Foaming of the microcapsules is usually carried out during the drying process when applying the capsule coating material to the base material, but in some cases it can also be carried out by reheating with a coater or the like or by heating during the printing process. The heating temperature at that time varies depending on the glass transition point of the capsule wall membrane used, the processing time, etc., and cannot be definitively stated, but in the case of the commercially available capsules mentioned above,
It is preferable to set the temperature to 0 to 170°C. As the heating method, conventionally known methods such as hot air, hot rolls, infrared heaters, microwaves, etc. can be used.
【００２１】尚、基材と防滑層の密着性が不充分な場合
には、基材に予めプライマー処理を施しておくとよい。[0021] If the adhesion between the base material and the anti-slip layer is insufficient, it is advisable to apply a primer treatment to the base material in advance.
【００２２】[0022]
【実施例】以下、実施例を挙げて本発明を説明するが、
本発明はこの実施例のみに限定されるものではない。ま
た、特に断らない限り、例中の部、％は重量部、重量％
をさす。[Examples] The present invention will be explained below with reference to Examples.
The present invention is not limited to this example. In addition, unless otherwise specified, parts and % in examples are parts by weight and % by weight.
point to
【００２３】実施例１
発泡性マイクロカプセル含有塗料として下記組成の塗料
を調製し、６０ｇ／ｍ２ の不織布（旭化成製、商品名
「ルクサー」）の片面に乾燥重量が１５ｇ／ｍ２になる
ように塗布し、８０℃で乾燥した。更に反対側の面にも
同じく１５ｇ／ｍ２ 塗布し１４０℃で１分間乾燥し、
両面防滑性の養生シートを得た。
〔発泡性マイクロカプセル含有塗料の構成〕発泡性マイ
クロカプセル
１０部 （エクスパンセル社製、商品名「エ
クスパンセルＷＵ−６４２」）スチレン・ブタジエン共
重合体ラテックス
９０部 （住友ノー
ガタック社製、商品名「Ｐ−９Ｙ８６」固形分濃度４９
％）水酸化アルミニウム
４５部 （昭和電工製、
商品名「ハイジライトＨ−４２」）水
１０５部Example 1 A paint having the following composition was prepared as an expandable microcapsule-containing paint, and applied to one side of a 60 g/m2 nonwoven fabric (manufactured by Asahi Kasei, trade name "Luxar") so that the dry weight was 15 g/m2. and dried at 80°C. Furthermore, the same 15g/m2 was applied to the opposite side and dried at 140℃ for 1 minute.
A curing sheet with anti-slip properties on both sides was obtained. [Composition of paint containing expandable microcapsules] Expandable microcapsules
10 parts (manufactured by Expancel, trade name "Expancel WU-642") Styrene-butadiene copolymer latex
90 parts (manufactured by Sumitomo Naugatuck Co., Ltd., product name "P-9Y86" solid content concentration 49
%) aluminum hydroxide
45 copies (manufactured by Showa Denko,
Product name: “Hygilite H-42”) Water
105 copies
【００２４】比較例１
１００ｇ／ｍ２ のクラフト紙の両面に２０μｍの延伸
ＰＰフィルムを貼り合わせてエンボス加工を施し、これ
を養生シートとした。Comparative Example 1 A 20 μm stretched PP film was laminated on both sides of 100 g/m 2 kraft paper and embossed, and this was used as a curing sheet.
【００２５】（評価）実施例１及び比較例１で得た養生
シートについて以下の評価を行った。■プリント合板に
対する摩擦角をＪ．Ｔａｐｐｉ紙パルプ試験法Ｎｏ３１
−７９に準じて測定した。その結果、実施例１の養生シ
ートの摩擦角は５５°であり、比較例１の摩擦角は３５
°であった。■３０度の勾配の木床の上に各々の養生シ
ートを敷き詰め、その上で屋根葺きを行い作業性を比べ
た。その結果、実施例１の養生シートを使用した場合は
滑りはなく作業上の危険性は全くなかった。しかし、比
較例１の養生シートを使用した場合は滑り易く、作業上
の危険性は解消されなかった。(Evaluation) The curing sheets obtained in Example 1 and Comparative Example 1 were evaluated as follows. ■Friction angle against printed plywood by J. Tappi paper pulp test method No.31
-79. As a result, the friction angle of the curing sheet of Example 1 was 55°, and the friction angle of Comparative Example 1 was 35°.
It was °. ■Each type of curing sheet was spread on a wooden floor with a 30 degree slope, roofing was done on top of it, and the workability was compared. As a result, when the curing sheet of Example 1 was used, there was no slippage and there was no operational danger at all. However, when the curing sheet of Comparative Example 1 was used, it was slippery and the operational danger was not eliminated.
【００２６】[0026]
【発明の効果】本発明の養生シートは、片面又は両面に
防滑層を設けていることを特徴としているため、これを
家屋の建築作業中に、汚したり、傷つき易い場所に保護
シートとして使用すれば、その上を足場にして作業して
もずれることがないため、汚れ、損傷を効果的に防ぐこ
とができ、またこれを屋根の下に耐水シートとして敷く
と、その上に屋根を葺く際にも足場の滑りが効果的に防
止でき、しかも屋根の滑り防止にも優れた効果が得られ
る。[Effects of the Invention] The curing sheet of the present invention is characterized by having an anti-slip layer on one or both sides, so it can be used as a protective sheet in areas that are easily soiled or damaged during house construction work. For example, it will not shift even if you work on it as a scaffold, so it can effectively prevent dirt and damage. Also, if you lay it under the roof as a waterproof sheet, you can cover it with a roof. It is possible to effectively prevent scaffolding from slipping even in the event of an emergency, and it also has an excellent effect on preventing roofs from slipping.
Claims (3)
事を特徴とする養生シート。1. A curing sheet, characterized in that an anti-slip layer is provided on at least one side of a base material.
る請求項１記載の養生シート。2. The curing sheet according to claim 1, wherein the anti-slip layer contains foamed microcapsules.
得られた不織布である請求項１記載の養生シート。3. The curing sheet according to claim 1, wherein the base material is a nonwoven fabric obtained by a dry method or a spunbond method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12739991A JPH04353167A (en) | 1991-05-30 | 1991-05-30 | Curing sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12739991A JPH04353167A (en) | 1991-05-30 | 1991-05-30 | Curing sheet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04353167A true JPH04353167A (en) | 1992-12-08 |
Family
ID=14959033
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12739991A Pending JPH04353167A (en) | 1991-05-30 | 1991-05-30 | Curing sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04353167A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1122206A (en) * | 1997-07-04 | 1999-01-26 | Otsuka Chem Co Ltd | Curing sheet |
| JP2019196696A (en) * | 2018-05-08 | 2019-11-14 | カーライル・インタンジブル・エルエルシー | Roof membrane having removable protective sheet |
| CN110591592A (en) * | 2019-09-25 | 2019-12-20 | 无锡旺绿鸿纺织品有限公司 | Environment-friendly anti-slip strip-shaped foaming coating and preparation method thereof |
-
1991
- 1991-05-30 JP JP12739991A patent/JPH04353167A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1122206A (en) * | 1997-07-04 | 1999-01-26 | Otsuka Chem Co Ltd | Curing sheet |
| JP2019196696A (en) * | 2018-05-08 | 2019-11-14 | カーライル・インタンジブル・エルエルシー | Roof membrane having removable protective sheet |
| CN110591592A (en) * | 2019-09-25 | 2019-12-20 | 无锡旺绿鸿纺织品有限公司 | Environment-friendly anti-slip strip-shaped foaming coating and preparation method thereof |
| JP2021049769A (en) * | 2019-09-25 | 2021-04-01 | 無錫旺緑鴻紡織品有限公司 | Environmentally friendly bar-like non-slip foam coating layer and method for producing the same |
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