JPH04334309A - Skin cosmetic composition - Google Patents
Skin cosmetic compositionInfo
- Publication number
- JPH04334309A JPH04334309A JP12847791A JP12847791A JPH04334309A JP H04334309 A JPH04334309 A JP H04334309A JP 12847791 A JP12847791 A JP 12847791A JP 12847791 A JP12847791 A JP 12847791A JP H04334309 A JPH04334309 A JP H04334309A
- Authority
- JP
- Japan
- Prior art keywords
- fatty acid
- feeling
- cosmetic composition
- integer
- skin cosmetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 21
- 239000002537 cosmetic Substances 0.000 title claims abstract description 17
- -1 fatty acid ester Chemical class 0.000 claims abstract description 18
- 239000007788 liquid Substances 0.000 claims abstract description 18
- 229920002545 silicone oil Polymers 0.000 claims abstract description 17
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 16
- 229930195729 fatty acid Natural products 0.000 claims abstract description 16
- 239000000194 fatty acid Substances 0.000 claims abstract description 16
- 239000010696 ester oil Substances 0.000 claims description 10
- 150000004665 fatty acids Chemical class 0.000 claims description 8
- 230000000694 effects Effects 0.000 abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 2
- 125000003158 alcohol group Chemical group 0.000 abstract description 2
- 125000005313 fatty acid group Chemical group 0.000 abstract description 2
- 229920006395 saturated elastomer Polymers 0.000 abstract description 2
- 125000005471 saturated fatty acid group Chemical group 0.000 abstract description 2
- 125000005314 unsaturated fatty acid group Chemical group 0.000 abstract description 2
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 229920001214 Polysorbate 60 Polymers 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 210000002966 serum Anatomy 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000003796 beauty Effects 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- ZUBZATZOEPUUQF-UHFFFAOYSA-N isononane Chemical compound CCCCCCC(C)C ZUBZATZOEPUUQF-UHFFFAOYSA-N 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- DHGBAFGZLVRESL-UHFFFAOYSA-N 14-methylpentadecyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCC(C)C DHGBAFGZLVRESL-UHFFFAOYSA-N 0.000 description 1
- ABEXEQSGABRUHS-UHFFFAOYSA-N 16-methylheptadecyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC(C)C ABEXEQSGABRUHS-UHFFFAOYSA-N 0.000 description 1
- NCLNAHJFXIKYBY-UHFFFAOYSA-N 2-hexyldecyl 16-methylheptadecanoate Chemical compound CCCCCCCCC(CCCCCC)COC(=O)CCCCCCCCCCCCCCC(C)C NCLNAHJFXIKYBY-UHFFFAOYSA-N 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000003212 astringent agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- BKEUNIPSDCRXQK-UHFFFAOYSA-N butyl 16-methylheptadecanoate Chemical compound CCCCOC(=O)CCCCCCCCCCCCCCC(C)C BKEUNIPSDCRXQK-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- OIKBVOIOVNEVJR-UHFFFAOYSA-N hexadecyl 6-methylheptanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCC(C)C OIKBVOIOVNEVJR-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229940093629 isopropyl isostearate Drugs 0.000 description 1
- 229940060384 isostearyl isostearate Drugs 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- NEOZOXKVMDBOSG-UHFFFAOYSA-N propan-2-yl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC(C)C NEOZOXKVMDBOSG-UHFFFAOYSA-N 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 125000005480 straight-chain fatty acid group Chemical group 0.000 description 1
- NRLLZRJXDKUVHM-UHFFFAOYSA-N tridecyl 7-methyloctanoate Chemical compound CCCCCCCCCCCCCOC(=O)CCCCCC(C)C NRLLZRJXDKUVHM-UHFFFAOYSA-N 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【０００１】0001
【産業上の利用分野】本発明は良好な使用感を有し、そ
の良好な使用感の持続性にすぐれた皮膚化粧料組成物に
関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a skin cosmetic composition which has a good feeling on use and is excellent in the durability of that good feeling on use.
【０００２】0002
【従来技術及びその問題点】近年、皮膚化粧料としては
、ベたつきや油性感が小さく、さっぱりとし、かつすべ
すべした軽い感触の使用感を有する化粧料が求めらるよ
うになってきている。従来、化粧料に対し、べたつきや
油性感が小さく、更に、さっぱりとし、かつすべすべと
した使用感を付与させるために、油分を少量配合したり
、表面張力の低いシリコーン油を配合することは知られ
ている。しかしながら、油分を少量配合したものについ
ては、良好な使用感の持続性が弱く、スキンケア効果も
あまる期待できないため、使用実感に乏しいといった欠
点がある。また、シリコーン油は、現在のところ、シリ
コーン油自体が他の油分との相溶性が悪くしかも乳化性
も悪いためそれを使いこなすことが比較的困難であるが
、そのすぐれた特性により使用の範囲が広がってきてい
る。このシリコーン油においては、特に、環状シリコー
ン油や、低重合度ジメチルシリコーン油を使用した場合
には、さっぱり感、すべすべ感の良好なものが得られる
。しかし、これらのものはその良好な使用感の持続性が
弱いため、使用実感に乏しい。また、中重合度のジメチ
ルシリコーン油や、プロピレンオキシドやエチレンオキ
シドを反応させて変性したシリコーン油は、使用直後の
使用感において、べたつきや、油性感が強いため好まし
いものとは言えない。このようなことから、現状におい
ては、使用直後からべたつきや油性感が小さく、しかも
、さっぱり感、すべすべ感が良好で、かつその良好な使
用感の持続性の高い化粧料は得られていない。[Prior art and its problems] In recent years, there has been a demand for skin cosmetics that are less sticky and oily, have a refreshing, smooth, and light feel. . Conventionally, it has been known to add small amounts of oil or silicone oil with low surface tension to cosmetics in order to make them less sticky and oily, and to give them a refreshing and smooth feel. It is being However, products that contain a small amount of oil have the disadvantage that they do not provide a good feeling when used for long periods of time, and cannot be expected to have much skin care effect, resulting in a poor feeling of use. Furthermore, at present, it is relatively difficult to fully utilize silicone oil because silicone oil itself has poor compatibility with other oils and poor emulsifying properties, but its excellent properties have expanded its range of use. It's spreading. Among these silicone oils, particularly when cyclic silicone oil or low degree of polymerization dimethyl silicone oil is used, a good refreshing and smooth feeling can be obtained. However, these products do not provide a good feeling when used, and therefore have a poor feeling when used. Further, dimethyl silicone oil with a medium degree of polymerization and silicone oil modified by reacting with propylene oxide or ethylene oxide are not preferred because they have a strong sticky or oily feel immediately after use. For these reasons, at present, there is no cosmetic that has a low stickiness or oily feeling immediately after use, has a good refreshing and smooth feeling, and has a long-lasting good feeling on use.
【０００３】0003
【発明が解決しようとする課題】本発明は、使用直後の
べたつきや油性感が小さく、しかもさっぱり感、すべす
べ感が良好であり、かつその良好なさっぱり感及びすべ
すべ感の持続性に優れている皮膚化粧料を提供すること
をその課題とする。[Problems to be Solved by the Invention] The present invention provides a product that has less stickiness and oily feeling immediately after use, has a good refreshing and smooth feeling, and has excellent sustainability of the good refreshing and smooth feeling. Its objective is to provide skin cosmetics.
【０００４】0004
【課題を解決するための手段】本発明者らは、前記課題
を解決すべく鋭意研究を重ねた結果、本発明を完成する
に至った。すなわち、本発明によれば、下記一般式で表
わされる液状ポリエーテル変性シリコーン油成分（Ａ）
と、液状高級分岐脂肪酸エステル油成分（Ｂ）を含有す
ることを特徴とする使用感の良好な皮膚化粧料組成物が
提供される。[Means for Solving the Problems] The present inventors have conducted extensive research to solve the above problems, and as a result, have completed the present invention. That is, according to the present invention, a liquid polyether-modified silicone oil component (A) represented by the following general formula
Accordingly, there is provided a skin cosmetic composition which is characterized by containing a liquid higher branched fatty acid ester oil component (B) and which has a good feel when used.
【０００５】[0005]
【化１】[Chemical formula 1]
【０００６】（式中、Ｒはアセトキシル基、ｍは１０〜
５００の整数、ｎは１〜４０の整数、 ａは０〜３０
の整数及びｂは０〜３０の整数を各示す）(In the formula, R is an acetoxyl group, m is 10-
An integer of 500, n is an integer of 1 to 40, a is an integer of 0 to 30
and b are integers from 0 to 30)
【０００７】
本発明で用いる前記一般式で表わされる液状ポリエーテ
ル変性シリコーン油成分Ａとしては、特に、ｍが１００
〜４００、ｎが３〜２０、ａが０〜２０、ｂが０〜２０
の範囲にあるものの使用が好ましい。[0007]
In particular, as the liquid polyether-modified silicone oil component A represented by the above general formula used in the present invention, m is 100
~400, n is 3-20, a is 0-20, b is 0-20
It is preferable to use a substance within the range of .
【０００８】本発明で用いる液状高級分岐脂肪酸エステ
ル油としては、常温で液状を示すものであればよく、そ
の分岐脂肪酸基は、飽和又は不飽和脂肪酸基であってよ
く、その炭素数は、通常、８〜３５、好ましくは８〜１
８である。一方、液状高級分岐脂肪酸エステル油におけ
るアルコール基は、直鎖又は分岐状アルコールから誘導
されたもので、その炭素数は、通常、３〜３２、好まし
くは３〜２０である。高級直鎖脂肪酸エステル油の使用
は、さっぱり感が乏しいの点で好ましくない。The liquid higher branched fatty acid ester oil used in the present invention may be any oil that is liquid at room temperature, and the branched fatty acid group may be a saturated or unsaturated fatty acid group, and the number of carbon atoms thereof is usually , 8-35, preferably 8-1
It is 8. On the other hand, the alcohol group in the liquid higher branched fatty acid ester oil is derived from a linear or branched alcohol, and usually has 3 to 32 carbon atoms, preferably 3 to 20 carbon atoms. The use of higher straight chain fatty acid ester oil is not preferable because it lacks a refreshing feeling.
【０００９】前記液状高級分岐脂肪酸エステル油の具体
例としては、例えば、イソミリスチン酸イソセチル、イ
ソステアリン酸イソプロピル、イソステアリン酸イソセ
チル、イソステアリン酸ブチル、イソステアリン酸イソ
ステアリル、イソステアリン酸トリデシル、イソステア
リン酸ヘキシルデシル、イソノナン酸イソノニル、イソ
ノナン酸トリデシル、イソペラルゴン酸イソオクチル、
イソオクタン酸セチル等が挙げられる。これらのものは
、単独または混合物であっても良い。液状ポリエーテル
変性シリコーン油と液状高級分岐脂肪酸エステル油の重
量比率は、０．０５：１〜２：１、好ましくは０．１：
１〜１：１の範囲である。また、これらの成分の合計量
は組成物全体に対して１〜３０重量％、好ましくは２〜
２０重量％の範囲である。Specific examples of the liquid higher branched fatty acid ester oil include isocetyl isomyristate, isopropyl isostearate, isocetyl isostearate, butyl isostearate, isostearyl isostearate, tridecyl isostearate, hexyldecyl isostearate, and isononane. Isononyl acid, tridecyl isononanoate, isooctyl isoperargonate,
Examples include cetyl isooctanoate. These materials may be used alone or as a mixture. The weight ratio of liquid polyether-modified silicone oil to liquid higher branched fatty acid ester oil is 0.05:1 to 2:1, preferably 0.1:
It is in the range of 1 to 1:1. In addition, the total amount of these components is 1 to 30% by weight, preferably 2 to 30% by weight based on the entire composition.
It is in the range of 20% by weight.
【００１０】本発明の皮膚化粧料組成物において、液状
ポリエーテル変性シリコーン油の割合が前記範囲より小
さすぎると、さっぱり感、すべすべ感等の良好な使用感
は発現できなくなる。一方、前記比率より大きすぎると
、べたつきや、油性感が強くなり、軽く良好な感触が損
なわれてしまう。また、液状ポリエーテル変性シリコー
ン油と液状高級分岐脂肪酸エステル油の組成物全体に対
する含有量が前記範囲より少なすぎると、さっぱり感、
すべすべ感の良好な使用感が得られず、一方、前記範囲
より大きすぎると、べたつき、油性感が強くなり、好ま
しくない。[0010] In the skin cosmetic composition of the present invention, if the proportion of the liquid polyether-modified silicone oil is too small than the above range, it will not be possible to provide a good feeling of use such as a refreshing feeling or a smooth feeling. On the other hand, if the ratio is too large, the stickiness and oily feel will be strong, and the light and good feel will be impaired. In addition, if the content of the liquid polyether-modified silicone oil and the liquid higher branched fatty acid ester oil in the entire composition is too small than the above range, it will give a refreshing feeling.
On the other hand, if it is too large than the above range, the stickiness and oiliness will become strong, which is not preferable.
【００１１】本発明の皮膚化粧料組成物には、前記した
必須成分の他、本発明の目的を特に阻害しない限り必要
に応じ、乳液、クリーム等の乳化物や、美容液に慣用の
添加剤、例えば、乳化剤や可溶化剤としての界面活性剤
、保湿剤、防腐剤、殺菌剤、ビタミン類、紫外線吸収剤
、抗炎症剤、収れん剤、油分、粘度調整剤、ｐＨ調整剤
等を適量配合することができる。In addition to the above-mentioned essential ingredients, the skin cosmetic composition of the present invention may contain, as necessary, emulsions such as milky lotions and creams, and additives commonly used in beauty serums, as long as they do not particularly impede the purpose of the present invention. For example, appropriate amounts of surfactants as emulsifiers and solubilizers, humectants, preservatives, bactericidal agents, vitamins, ultraviolet absorbers, anti-inflammatory agents, astringents, oils, viscosity regulators, pH regulators, etc. can do.
【００１２】本発明の皮膚化粧料組成物のうち、特に乳
化組成物については、従来公知の乳化方法により調製す
ることができる。この場合、乳化剤としては、親油型界
面活性剤、親水型界面活性剤を単独または混合して用い
る。これらの界面活性剤としては、例えばソルビタン脂
肪酸エステル、グリセリン脂肪酸エステル、ポリオキシ
エチレンソルビタン脂肪酸エステル、ポリオキシエチレ
ンソルビット脂肪酸エステル、ポリオキシエチレングリ
セリン脂肪酸エステル、ポリエチレングリコール脂肪酸
エステル、ポリオキシエチレンアルキルエーテル、ポリ
オキシエチレンアルキルフェニルエーテル、ポリオキシ
エチレン硬化ヒマシ油、ポリオキシエチレンヒマシ油等
が好適に用いられる。また、美容液等として用いる透明
タイプの組成物には、可溶化剤として界面活性剤等が好
適に用いられる。[0012] Among the skin cosmetic compositions of the present invention, especially emulsified compositions can be prepared by conventionally known emulsification methods. In this case, as the emulsifier, a lipophilic surfactant or a hydrophilic surfactant may be used alone or in combination. These surfactants include, for example, sorbitan fatty acid ester, glycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyethylene glycol fatty acid ester, polyoxyethylene alkyl ether, and polyoxyethylene sorbitan fatty acid ester. Oxyethylene alkyl phenyl ether, polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, etc. are preferably used. Furthermore, in transparent compositions used as beauty serums, etc., surfactants and the like are preferably used as solubilizers.
【００１３】[0013]
【発明の効果】本発明の皮膚化粧料組成物は、べたつき
や油性感が極めて小さく、しかも、さっぱり感、すべす
べ感も良好であり、さらにその良好な使用感の持続性に
すぐれている。従って、本発明組成物は、顔や手、身体
等に適用されるクリーム、乳液、美容液等の皮膚化粧料
として特に好適なものである。[Effects of the Invention] The skin cosmetic composition of the present invention has extremely low stickiness and oily feeling, has a good refreshing feeling and smooth feeling, and has excellent durability of the good feeling when used. Therefore, the composition of the present invention is particularly suitable for use as skin cosmetics such as creams, milky lotions, and serums to be applied to the face, hands, body, and the like.
【００１４】[0014]
【実施例】次に本発明を実施例によりさらに詳細に説明
する。なお、以下において示す％は重量％である。EXAMPLES Next, the present invention will be explained in more detail with reference to examples. Note that the percentages shown below are percentages by weight.
【００１５】実施例１〜３、比較例１〜５表１に示した
組成（重量％）の配合成分と、ソルビタンモノステアレ
ート２．３％、モノステアリン酸のエチレンオキシド４
０モル付加物１．７％、カルボキシビニルポリマー０．
２％、グリセリン５％、及びその他適量の防腐剤、香料
、中和剤を含む水中油滴型乳液を調製し、その使用感及
びその使用感の持続性について評価した。
その結果を表１に示す。この場合、使用感及びその使用
感の持続性の評価基準は次の通りである。
〔使用感〕
◎・・・極めて良好 ○・・・良好 △・・・やや
不良 ×・・・不良
〔持続性〕使用後６時間経過後に使用感を次の基準によ
り評価した。
◎・・・極めて良好 ○・・・良好 △・・・やや
不良 ×・・・不良
なお、表１において示すＰＯ，ＥＯ変性シリコーン＊１
は、前記一般式において、ｍ＝４００、ｎ＝５、ａ＝２
０、ｂ＝２０を有するものであり、ＰＯ，ＥＯ変性シリ
コーン＊２は、前記一般式において、ｍ＝１００、ｎ＝
５、ａ＝２０、ｂ＝２０を有するものである。Examples 1 to 3, Comparative Examples 1 to 5 Ingredients having the composition (wt%) shown in Table 1, 2.3% of sorbitan monostearate, and 4% of ethylene oxide of monostearic acid.
0 mole adduct 1.7%, carboxyvinyl polymer 0.
An oil-in-water emulsion containing 2% glycerin, 5% glycerin, and appropriate amounts of other preservatives, fragrances, and neutralizing agents was prepared and evaluated for its feeling of use and the durability of the feeling of use. The results are shown in Table 1. In this case, the evaluation criteria for the feeling of use and the sustainability of the feeling of use are as follows. [Feeling in use] ◎...Extremely good ○...Good △...Slightly poor ×...Poor [Persistence] After 6 hours of use, the feeling in use was evaluated according to the following criteria. ◎...Very good ○...Good △...Slightly poor ×...Poor In addition, PO, EO modified silicone *1 shown in Table 1
In the general formula, m=400, n=5, a=2
0, b=20, and PO, EO modified silicone *2 has m=100, n=
5, a=20, b=20.
【００１６】[0016]
【表１】[Table 1]
【００１７】前記表１に示された結果からわかるように
、本発明品（実施例１〜３）の場合には、使用直後の、
べたつきのなさ、油性感のなさが良好で、しかもさっぱ
り感、すべすべ感が良好であり、特に環状シリコーン油
（デカメチルシクロペンタシロキサン）を併用すること
により、使用直後のすべすべ感が更に良好になった。一
方、通常のエステル油及び低重合度ジメチルシロキサン
を組み合せた比較例１では、使用直後の油性感が強く、
更に、使用感の持続性においては油性感のなさ、さっぱ
り感、すべすべ感が不満足であり、慣用の炭化水素（流
動パラフィン）とＰＯ，ＥＯ変性シリコーンの組合せ（
比較例２）、液状エステルとＰＯ，ＥＯ変性シリコーン
の組合せ（比較例３）においては使用直後の油性感のな
さ、さっぱり感、すべすべ感が充分でなく、また使用感
の持続性も不満足である。また、液状高級分岐脂肪酸エ
ステル油を含まない比較例４においてはすべすべ感の持
続性が悪く、ＰＯ，ＥＯ変性シリコーンの代りに低重合
度ジメチルシリコーン油を用いた比較例５では使用直後
の油性感が強く、また、油性感のなさ及びすべすべ感の
持続性の点で不満足であった。As can be seen from the results shown in Table 1, in the case of the products of the present invention (Examples 1 to 3), immediately after use,
It has good non-stickiness and no oily feel, and also has a refreshing and smooth feeling. Especially when used in combination with cyclic silicone oil (decamethylcyclopentasiloxane), the smooth feeling immediately after use is even better. Ta. On the other hand, in Comparative Example 1, which combined ordinary ester oil and low polymerization degree dimethylsiloxane, the oily feeling was strong immediately after use.
Furthermore, regarding the durability of the feeling of use, the lack of oily feeling, refreshing feeling, and smooth feeling are unsatisfactory.
Comparative Example 2), the combination of liquid ester and PO, EO-modified silicone (Comparative Example 3) does not have an oily feeling immediately after use, does not have a refreshing feeling, and does not have a smooth smooth feeling, and the durability of the feeling after use is also unsatisfactory. . In addition, in Comparative Example 4, which did not contain liquid higher branched fatty acid ester oil, the smooth feeling did not last long, and in Comparative Example 5, in which low polymerization degree dimethyl silicone oil was used instead of PO, EO modified silicone, there was an oily feeling immediately after use. It was also unsatisfactory in terms of lack of oily feel and durability of smooth feeling.
Claims (3)
テル変性シリコーン油成分（Ａ）と、液状高級分岐脂肪
酸エステル油成分（Ｂ）を含有することを特徴とする使
用感の良好な皮膚化粧料組成物。 【化１】 （式中、Ｒはアセトキシル基、ｍは１０〜５００の整数
、ｎは１〜４０の整数、 ａは０〜３０の整数及びｂ
は０〜３０の整数を各示す）1. A skin cosmetic composition with a good feel when used, characterized by containing a liquid polyether-modified silicone oil component (A) represented by the following general formula and a liquid higher branched fatty acid ester oil component (B). thing. [Formula 1] (wherein R is an acetoxyl group, m is an integer of 10 to 500, n is an integer of 1 to 40, a is an integer of 0 to 30, and b
(indicates an integer from 0 to 30)
０．０５：１〜２：１の範囲である請求項１の皮膚化粧
料組成物。2. The skin cosmetic composition according to claim 1, wherein the weight ratio of component (A) to component (B) is in the range of 0.05:1 to 2:1.
成物全体に対して１．０〜３０重量％である請求項１又
は２の皮膚化粧料組成物。3. The skin cosmetic composition according to claim 1, wherein the total amount of component (A) and component (B) is 1.0 to 30% by weight based on the entire composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12847791A JPH04334309A (en) | 1991-05-01 | 1991-05-01 | Skin cosmetic composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12847791A JPH04334309A (en) | 1991-05-01 | 1991-05-01 | Skin cosmetic composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04334309A true JPH04334309A (en) | 1992-11-20 |
Family
ID=14985708
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12847791A Pending JPH04334309A (en) | 1991-05-01 | 1991-05-01 | Skin cosmetic composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04334309A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000053554A (en) * | 1998-08-10 | 2000-02-22 | Kao Corp | Water-in-oil type emulsion cosmetic |
| EP1044677A1 (en) * | 1999-04-16 | 2000-10-18 | L'oreal | Cosmetic composition containing the combination of a particular ester and a silicone compound |
| US6517820B1 (en) * | 1999-03-04 | 2003-02-11 | L'oreal S.A. | Cosmetic composition in the form of a powder comprising a specific ester |
-
1991
- 1991-05-01 JP JP12847791A patent/JPH04334309A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000053554A (en) * | 1998-08-10 | 2000-02-22 | Kao Corp | Water-in-oil type emulsion cosmetic |
| US6517820B1 (en) * | 1999-03-04 | 2003-02-11 | L'oreal S.A. | Cosmetic composition in the form of a powder comprising a specific ester |
| EP1044677A1 (en) * | 1999-04-16 | 2000-10-18 | L'oreal | Cosmetic composition containing the combination of a particular ester and a silicone compound |
| FR2792191A1 (en) * | 1999-04-16 | 2000-10-20 | Oreal | COSMETIC COMPOSITION COMPRISING THE ASSOCIATION OF A PARTICULAR ESTER AND A SILICONE COMPOUND |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4880563A (en) | Composition for personal care product comprising alkoxylated fatty alcohol and polysiloxane | |
| EP0373661B1 (en) | Water-in-oil type emulsion cosmetic | |
| JPH10513179A (en) | Roll-on antiperspirant composition | |
| JP5949233B2 (en) | Cosmetic composition | |
| KR20100028568A (en) | Water-in-oil type emulsion composition | |
| JP2007261971A (en) | Oil-in-water type emulsified cosmetic | |
| JPH04334309A (en) | Skin cosmetic composition | |
| JP5189836B2 (en) | Oil-containing cosmetic composition | |
| JP2007297300A (en) | Emulsion composition for hair fixing | |
| JP2014214090A (en) | Cosmetic | |
| JP5777859B2 (en) | Emulsified composition | |
| JPH11335258A (en) | Cosmetic | |
| JP2005255526A5 (en) | ||
| WO2004103324A1 (en) | Hair care emulsions | |
| JP3323339B2 (en) | Cosmetics | |
| JP7352713B2 (en) | emulsifying composition | |
| JP7494415B2 (en) | Water-in-oil emulsion cosmetics | |
| JP2003012469A (en) | Emulsion cosmetic for hair | |
| JP2013075870A (en) | Emulsified antiperspirant cosmetic | |
| JP4125463B2 (en) | O / W / O emulsified cosmetic | |
| JP3610480B2 (en) | Body rinse composition | |
| KR20220052276A (en) | Cosmetic bases and cosmetics | |
| JP2016130228A (en) | Aqueous skin cosmetic | |
| JPH10203936A (en) | Cosmetic | |
| JP2022017832A (en) | Aqueous cleansing cosmetics |