JPH0431481A - Acrylic pressure-sensitive adhesive composition - Google Patents
Acrylic pressure-sensitive adhesive compositionInfo
- Publication number
- JPH0431481A JPH0431481A JP13528190A JP13528190A JPH0431481A JP H0431481 A JPH0431481 A JP H0431481A JP 13528190 A JP13528190 A JP 13528190A JP 13528190 A JP13528190 A JP 13528190A JP H0431481 A JPH0431481 A JP H0431481A
- Authority
- JP
- Japan
- Prior art keywords
- sensitive adhesive
- adhesive
- adhesive composition
- acrylic pressure
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 21
- 239000004820 Pressure-sensitive adhesive Substances 0.000 title claims abstract description 20
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 239000000178 monomer Substances 0.000 claims abstract description 22
- 229920001577 copolymer Polymers 0.000 claims abstract description 14
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 10
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 9
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 125000005907 alkyl ester group Chemical group 0.000 claims description 2
- 239000000853 adhesive Substances 0.000 abstract description 23
- 229920005989 resin Polymers 0.000 abstract description 7
- 239000011347 resin Substances 0.000 abstract description 7
- 239000002390 adhesive tape Substances 0.000 abstract description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract description 4
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract description 4
- -1 alkyl methacrylate Chemical compound 0.000 abstract description 4
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract description 4
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 abstract description 3
- 150000003505 terpenes Chemical class 0.000 abstract description 3
- 235000007586 terpenes Nutrition 0.000 abstract description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract description 2
- 239000005011 phenolic resin Substances 0.000 abstract description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 description 27
- 150000002148 esters Chemical class 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 description 1
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- NQSLZEHVGKWKAY-UHFFFAOYSA-N 6-methylheptyl 2-methylprop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C(C)=C NQSLZEHVGKWKAY-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 1
- 125000003447 alpha-pinene group Chemical group 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229930006722 beta-pinene Natural products 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- GTBGXKPAKVYEKJ-UHFFFAOYSA-N decyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCOC(=O)C(C)=C GTBGXKPAKVYEKJ-UHFFFAOYSA-N 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229920001002 functional polymer Polymers 0.000 description 1
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- LKEDKQWWISEKSW-UHFFFAOYSA-N nonyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCOC(=O)C(C)=C LKEDKQWWISEKSW-UHFFFAOYSA-N 0.000 description 1
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、アクリル系感圧接着剤組成物に関し、更に詳
細には強粘着力でタック、加工適性に優れ、両面粘着シ
ートおよび粘着ラベル等に好ましく使用することのでき
るアクリル系感圧接着剤組成物に関する。Detailed Description of the Invention [Industrial Application Field] The present invention relates to an acrylic pressure-sensitive adhesive composition, and more particularly, it has strong adhesive strength, tack, and processability, and is useful for double-sided adhesive sheets, adhesive labels, etc. The present invention relates to an acrylic pressure-sensitive adhesive composition that can be preferably used for.
［従来の技術およびその課題］
両面粘着シート、粘着ラベル等に使用される感圧接着剤
は、粘着力、凝集力、タック等の粘着物性が優れている
ことが要求されることはもちろんであるが、この他に粘
着加工原反を製品化する際の加工適性が優れていること
も要求される。すなわち、両面粘着シート、粘着ラベル
等の製品化に当たっては、スリッター、スライサー等で
粘着原反を所定の幅に裁断するが、その時に粘着剤のは
み出しがあったり、接着剤の切れが悪いと刃を汚したり
、サイドスティックがでやすくなるため、接着剤にこの
ような現象が起こらない性質、いわゆる加工通性が要求
される。、
しかし、従来提供されている接着剤組成物では、粘着力
、タック等を向上させると加工適性が悪くなるという傾
向があり、その解決が求められていた。[Prior art and its problems] Pressure-sensitive adhesives used for double-sided adhesive sheets, adhesive labels, etc. are of course required to have excellent adhesive properties such as adhesive strength, cohesive force, and tack. However, in addition to this, it is also required to have excellent processing suitability when commercializing the adhesive processed original fabric. In other words, when commercializing double-sided adhesive sheets, adhesive labels, etc., the adhesive material is cut into a specified width using a slitter, slicer, etc., but if the adhesive sticks out or the adhesive is not cut properly, the blade may be damaged. The adhesive is required to have properties that prevent such phenomena from occurring, that is, so-called processability. However, conventionally provided adhesive compositions tend to have poor processability when adhesion, tack, etc. are improved, and a solution to this problem has been sought.
［課題を解決するための手段］
本発明者は粘着力、タック等の粘着物性を損なうことな
く加工適性に優れたアクリル系感圧接着剤組成物を提供
すべく鋭意研究を行なった結果、特定のメタクリル酸ア
ルキルエステルを選択使用すれば、粘着物性、加工適性
が両立し得ることを見出し、本発明を完成した。[Means for Solving the Problems] As a result of intensive research aimed at providing an acrylic pressure-sensitive adhesive composition with excellent processing suitability without impairing adhesive properties such as adhesive strength and tack, the present inventors found that The present invention was completed based on the discovery that adhesive properties and processing suitability can be achieved by selectively using methacrylic acid alkyl esters.
すなわち、本発明はアルキル基の炭素数が８〜１６のメ
タクリル酸アルキルエステル、官能性子ツマ−及び共重
合可能な他のビニル系モノマーからなる共重合物を含有
するアクリル系感圧接着剤を提供するものである。That is, the present invention provides an acrylic pressure-sensitive adhesive containing a copolymer of a methacrylic acid alkyl ester having an alkyl group having 8 to 16 carbon atoms, a functional polymer, and another copolymerizable vinyl monomer. It is something to do.
本発明で用いられる共重合体は、アルキルエステル部の
アルキル基が炭素数８〜１６であるメタクリル酸アルキ
ルエステル（以下、「メタクリル酸Ｃ８−１６エステル
」と称する）と官能性モノマー及びメタクリル酸アルキ
ルエステルと共重合可能な他のビニル系ポリマー（以下
「ビニル系モノマー」と称する）を常法により共重合さ
せることにより製造される。The copolymer used in the present invention consists of a methacrylic acid alkyl ester in which the alkyl group in the alkyl ester moiety has 8 to 16 carbon atoms (hereinafter referred to as "methacrylic acid C8-16 ester"), a functional monomer, and an alkyl methacrylate. It is produced by copolymerizing another vinyl polymer (hereinafter referred to as "vinyl monomer") copolymerizable with the ester using a conventional method.
この共重合体は、好ましくはメタクリル酸Ｃ８−＋ ｅ
エステル５０〜９９．９５重量％（以下、単に「％」で
示す）、官能性モノマー０．０５〜１５％及びビニル系
モノマー ０〜４９．９５％の千ツマ−の割合で共重合
させることにより得られる。This copolymer preferably contains methacrylic acid C8-+ e
By copolymerizing at a ratio of 50 to 99.95% by weight of ester (hereinafter simply indicated as "%"), 0.05 to 15% of functional monomer, and 0 to 49.95% of vinyl monomer. can get.
本発明で用いるメタクリル酸ｃｏ−１゜エステルの例と
しては、オクチルメタクリレート、イソオクチルメタク
リレート、ノニルメタクリレート、デシルメタクリレー
ト、ラウリルメタクリレート等が挙げられる。Examples of the methacrylic acid co-1° ester used in the present invention include octyl methacrylate, isooctyl methacrylate, nonyl methacrylate, decyl methacrylate, and lauryl methacrylate.
メタクリル酸アルキルエステルのアルキル基の炭素数が
８未満または１６を越える場合は主モノマーとして使う
にはガラス転移点が高くなりすき粘着剤としての実用性
からはずれる。また、この欠点を補うためにこれらのモ
ノマーにガラス転移点が低くなるアクリル酸エステル等
を共重合しても粘着物性と加工適性とのバランスをとる
ことが難しい。If the number of carbon atoms in the alkyl group of the methacrylic acid alkyl ester is less than 8 or more than 16, the glass transition point will be too high for use as the main monomer, making it impractical as an adhesive. Furthermore, even if these monomers are copolymerized with acrylic esters or the like that have a low glass transition point in order to compensate for this drawback, it is difficult to maintain a balance between adhesive properties and processability.
本発明の共重合体を調製するために用いるメタクリル酸
０８〜１６エステルのアルギル基の炭素数は、１０〜１
４、特に１２のものが好ましい。The number of carbon atoms in the argyl group of the methacrylic acid 08-16 ester used for preparing the copolymer of the present invention is 10-1.
4, especially 12 is preferred.
一方、メタクリル酸Ｃ６〜１６エステルと共重合させつ
る千ツマ−のうち、ビニル系モノマーとしては、（メタ
）アクリル酸アルキルエステル、スチレン、酢酸ビニル
等が、また官能性モノマーとしては（メタ）アクリル酸
、（メタ）アクリル酸グリシジル、（メタ）アクリル酸
２−ヒドロキシエチル、Ｎ−メチロール（メタ）アクリ
ルアミド等が挙げられる。On the other hand, among the vinyl monomers copolymerized with methacrylic acid C6-16 esters, (meth)acrylic acid alkyl esters, styrene, vinyl acetate, etc. are used as vinyl monomers, and (meth)acrylic acid as functional monomers. acid, glycidyl (meth)acrylate, 2-hydroxyethyl (meth)acrylate, N-methylol (meth)acrylamide, and the like.
本発明の感圧接着剤組成物は、上記の如くして得られた
共重合物を、必要に応じて他の公知の架橋剤、例えばロ
ジン、変性ロジンおよびこれらのエステル化物、アルキ
ルフェノール樹脂ロジンおよびアルキルフェノール変性
キシレン樹脂、テルペンフェノール樹脂、テルペン系樹
脂（αおよびβ−ピネンの重合体など）、オレフィン系
樹脂、芳香族および芳香族−脂肪族共重合系石油樹脂、
クマロン−インデン樹脂等の粘着付与樹脂などとともに
配合することにより調製することができる。The pressure-sensitive adhesive composition of the present invention uses the copolymer obtained as described above, if necessary, with other known crosslinking agents, such as rosin, modified rosin, and esterified products thereof, alkylphenol resin rosin, and Alkylphenol-modified xylene resins, terpene phenol resins, terpene resins (α and β-pinene polymers, etc.), olefin resins, aromatic and aromatic-aliphatic copolymer petroleum resins,
It can be prepared by blending with a tackifying resin such as coumaron-indene resin.
［発明の効果］
如」二の如くして得られる感圧接着剤組成物は、後記試
験例にも示すように、粘着力、タック等の粘着物性と、
裁断時等の加工適性のいずれもが優れたものである。[Effects of the Invention] As shown in the test examples below, the pressure-sensitive adhesive composition obtained as described in ``2'' has excellent adhesive physical properties such as adhesive force and tack;
It has excellent processing suitability during cutting, etc.
従って、本発明の感圧ｆａ着剤組成物は、最終的に裁断
して商品とする製品、例えば両面粘着性テープ、粘着ラ
ベル等に有利に使用することができる。Therefore, the pressure-sensitive fa adhesive composition of the present invention can be advantageously used for products that are finally cut into commercial products, such as double-sided adhesive tapes and adhesive labels.
［実施例］ 次に実施例を挙げ、本発明を更に詳しく説明する。[Example] Next, the present invention will be explained in more detail with reference to Examples.
実施例 １
撹拌装置、還流冷却器、窒素導入管および温度計を備え
た反応装置に酢酸エチル９０部、トルエン６０部、メタ
クリル酸ラウリル９７部、アクリル酸３部、アゾビスイ
ソブチロニトリル０．２部を仕込んだ後、窒素気流下に
系内温度を７５°Ｃに昇温し、１０時間重合反応を行い
、共重合物溶液を得た。Example 1 90 parts of ethyl acetate, 60 parts of toluene, 97 parts of lauryl methacrylate, 3 parts of acrylic acid, and 0.0 parts of azobisisobutyronitrile were placed in a reaction apparatus equipped with a stirring device, a reflux condenser, a nitrogen inlet tube, and a thermometer. After charging 2 parts, the temperature inside the system was raised to 75°C under a nitrogen stream, and a polymerization reaction was carried out for 10 hours to obtain a copolymer solution.
得られた共重合物溶液は透明で、固形分４０％、２５°
Ｃの粘度が５２００ｃｐｓ、重量平均分子量１２０万で
あった。The resulting copolymer solution was clear, had a solids content of 40%, and was heated at 25°C.
The viscosity of C was 5,200 cps and the weight average molecular weight was 1,200,000.
得られたポリマー溶液に架橋剤としてコロネートしく日
本ポリウレタン■製）を固形分比で１．２％配合し、ア
クリル系感圧接着剤組成物を得た。Coronate (manufactured by Nippon Polyurethane ■) as a crosslinking agent was added to the resulting polymer solution at a solid content of 1.2% to obtain an acrylic pressure-sensitive adhesive composition.
この感圧接着剤組成物を２５μｍのポリエステルフィル
ム上に乾燥状態で２５±２ｇ／イになるように塗布、８
０℃で２分間乾燥し粘着シートを作成した。This pressure-sensitive adhesive composition was applied onto a 25 μm polyester film at a dry weight of 25 ± 2 g/day.
It was dried at 0° C. for 2 minutes to prepare a pressure-sensitive adhesive sheet.
実施例２〜８
メタクリル酸アルキルエステルを生モノマーとし、第１
表に示したモノマー仕込み組成により、実施例１と同様
にしてアクリル系感圧接着剤組成物及び粘着シートを調
製した。Examples 2 to 8 Using methacrylic acid alkyl ester as a raw monomer, the first
An acrylic pressure-sensitive adhesive composition and a pressure-sensitive adhesive sheet were prepared in the same manner as in Example 1 using the monomer charge compositions shown in the table.
なお、得られる共重合物の性状も第１表中に示す。The properties of the obtained copolymer are also shown in Table 1.
（以 下 余 白 ）
比較例１〜７
第２表に示したモノマー仕込み組成により、実施例１と
同様にしてアクリル系感圧接着剤組成物及び粘着シート
を調製した。なお、得られる共重合物の性状も第２表中
に示す。(Hereinafter, blank) Comparative Examples 1 to 7 Acrylic pressure-sensitive adhesive compositions and pressure-sensitive adhesive sheets were prepared in the same manner as in Example 1 using the monomer charge compositions shown in Table 2. The properties of the obtained copolymer are also shown in Table 2.
（以 下 余 白 ）
試験例
実施例１〜８及び比較例１〜７て調製した粘着テープに
ついて、下記方法でその性能を試験した。この結果を第
３表に示す。(Left below) Test Examples The adhesive tapes prepared in Examples 1 to 8 and Comparative Examples 1 to 7 were tested for their performance in the following manner. The results are shown in Table 3.
試験方法：
（粘着力）
各試験粘着テープを、ステンレスおよびアルミニウムの
試料上に２ｋｇハンドローラーを１往復させて圧着、貼
合わせる。２０分後に２３°Ｃで、引張速度３００關／
分で１８０°剥離させるときに要した力を測定。Test method: (Adhesive strength) Each test adhesive tape is pressed and bonded onto a stainless steel or aluminum sample by moving a 2 kg hand roller back and forth once. After 20 minutes, at 23°C, the tensile speed was 300°/
Measure the force required to peel 180° in minutes.
（保持力）
ステンレス試料上に、貼付面積２０Ｘ２０ｍｒａ２で各
試料粘着テープを貼付した。荷重１眩を負荷し、４０°
Ｃで６０分後のズレ距離［關］または落下時間［分］を
測定した。(Holding force) Each sample adhesive tape was pasted on a stainless steel sample with a pasting area of 20 x 20 mra2. Load 1 dazzle, 40°
At C, the displacement distance [關] or falling time [minutes] after 60 minutes was measured.
（ポールタック）
Ｊ、Ｄｏｗ法によりＺ３０°、１Ｏｃａ＋助走、２３°
Ｃにて測定。(Pole tack) J, Z30°, 1 Oca + run-up, 23° by Dow method
Measured at C.
（加工適性）
両面粘着テープ（テープ厚１５０μ、セパレーター付き
総厚２５０μ）を２０枚重ね、裁断機で裁断しサイドへ
の粘着剤のはみ出しを観察し、次の基準で評価した。(Processability) 20 sheets of double-sided adhesive tape (tape thickness 150 μm, total thickness with separator 250 μm) were stacked and cut using a cutting machine, and the protrusion of the adhesive to the sides was observed and evaluated based on the following criteria.
内 容 はみ出しなし。Contents No protrusion.
はとんどはみ出しなし。There is almost no protrusion.
少しはみ出しあり。There is a little protrusion.
はみ出しあり。There is protrusion.
以
下
余 白 ）
第 ３ 表
第３表から明らかなように、生モノマーとして炭素数８
〜１６のアルキル基を有するメタクリル酸アルキルエス
テルを用いたときにのみ、粘着物性と加工適性を併有す
る感圧接着剤組成物が得られる。(Left below) Table 3 As is clear from Table 3, the raw monomer has 8 carbon atoms.
Only when a methacrylic acid alkyl ester having 16 to 16 alkyl groups is used, a pressure-sensitive adhesive composition having both adhesive properties and processability can be obtained.
以 上that's all
Claims (3)
ルキルエステル、官能性モ ノマー及び共重合可能な他のビニル系モ ノマーからなる共重合物を含有するアク リル系感圧接着剤組成物。(1) An acrylic pressure-sensitive adhesive composition containing a copolymer of a methacrylic acid alkyl ester having an alkyl group having 8 to 16 carbon atoms, a functional monomer, and another copolymerizable vinyl monomer.
素数が１０〜１４である請求 項第１項記載のアクリル系感圧接着剤組 成物。(2) The acrylic pressure-sensitive adhesive composition according to claim 1, wherein the alkyl group of the methacrylic acid alkyl ester has 10 to 14 carbon atoms.
ル酸Ｃ＿８＿〜＿１＿６アルキルエステル、０．０５〜
１５重量％の官能性モノマー 及び０〜４９．９５重量％のビニル系モ ノマーからなる請求項第１項記載のアク リル系感圧接着剤組成物。(3) The copolymer is 50 to 99.95% by weight of methacrylic acid C_8_ to_1_6 alkyl ester, 0.05 to
2. The acrylic pressure sensitive adhesive composition of claim 1, comprising 15% by weight of functional monomer and 0 to 49.95% by weight of vinyl monomer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13528190A JPH0431481A (en) | 1990-05-28 | 1990-05-28 | Acrylic pressure-sensitive adhesive composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13528190A JPH0431481A (en) | 1990-05-28 | 1990-05-28 | Acrylic pressure-sensitive adhesive composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0431481A true JPH0431481A (en) | 1992-02-03 |
Family
ID=15148039
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13528190A Pending JPH0431481A (en) | 1990-05-28 | 1990-05-28 | Acrylic pressure-sensitive adhesive composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0431481A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08165464A (en) * | 1994-12-15 | 1996-06-25 | Japan Synthetic Rubber Co Ltd | Water-base pressure-sensitive adhesive |
| WO2012173039A1 (en) * | 2011-06-14 | 2012-12-20 | 日東電工株式会社 | Adhesive composition, adhesive layer, and adhesive sheet |
| JP2015086231A (en) * | 2013-10-28 | 2015-05-07 | 東洋インキＳｃホールディングス株式会社 | Adhesive agent and adhesive sheet |
| US9653006B2 (en) | 2008-09-17 | 2017-05-16 | Avery Dennison Corporation | Activatable adhesive, labels, and related methods |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58222170A (en) * | 1982-06-16 | 1983-12-23 | Daio Kakoshi Kogyo Kk | Surface protective sheet for plastic plate |
| JPS6386777A (en) * | 1986-09-30 | 1988-04-18 | Japan Synthetic Rubber Co Ltd | Aqueous pressure-sensitive adhesive |
| JPH02110183A (en) * | 1988-10-19 | 1990-04-23 | Nitto Denko Corp | Acrylic pressure-sensitive adhesive |
| JPH03229783A (en) * | 1990-02-02 | 1991-10-11 | Sekisui Chem Co Ltd | Acrylic self-adhesive composition and self-adhesive tape, label, and sheet |
| JPH03237181A (en) * | 1990-02-14 | 1991-10-23 | Sekisui Chem Co Ltd | Acrylic tack agent composition and adhesive tape, label and sheet using same |
-
1990
- 1990-05-28 JP JP13528190A patent/JPH0431481A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58222170A (en) * | 1982-06-16 | 1983-12-23 | Daio Kakoshi Kogyo Kk | Surface protective sheet for plastic plate |
| JPS6386777A (en) * | 1986-09-30 | 1988-04-18 | Japan Synthetic Rubber Co Ltd | Aqueous pressure-sensitive adhesive |
| JPH02110183A (en) * | 1988-10-19 | 1990-04-23 | Nitto Denko Corp | Acrylic pressure-sensitive adhesive |
| JPH03229783A (en) * | 1990-02-02 | 1991-10-11 | Sekisui Chem Co Ltd | Acrylic self-adhesive composition and self-adhesive tape, label, and sheet |
| JPH03237181A (en) * | 1990-02-14 | 1991-10-23 | Sekisui Chem Co Ltd | Acrylic tack agent composition and adhesive tape, label and sheet using same |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08165464A (en) * | 1994-12-15 | 1996-06-25 | Japan Synthetic Rubber Co Ltd | Water-base pressure-sensitive adhesive |
| US9653006B2 (en) | 2008-09-17 | 2017-05-16 | Avery Dennison Corporation | Activatable adhesive, labels, and related methods |
| US10140891B2 (en) | 2008-09-17 | 2018-11-27 | Avery Dennison Corporation | Activatable adhesive, labels, and related methods |
| WO2012173039A1 (en) * | 2011-06-14 | 2012-12-20 | 日東電工株式会社 | Adhesive composition, adhesive layer, and adhesive sheet |
| JP2013001761A (en) * | 2011-06-14 | 2013-01-07 | Nitto Denko Corp | Self-adhesive composition, self-adhesive layer, and self-adhesive sheet |
| JP2015086231A (en) * | 2013-10-28 | 2015-05-07 | 東洋インキＳｃホールディングス株式会社 | Adhesive agent and adhesive sheet |
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