JPH0430323A - Magnetic recording medium - Google Patents

Magnetic recording medium

Info

Publication number
JPH0430323A
JPH0430323A JP13413590A JP13413590A JPH0430323A JP H0430323 A JPH0430323 A JP H0430323A JP 13413590 A JP13413590 A JP 13413590A JP 13413590 A JP13413590 A JP 13413590A JP H0430323 A JPH0430323 A JP H0430323A
Authority
JP
Japan
Prior art keywords
magnetic recording
recording medium
layer
film
magnetic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP13413590A
Other languages
Japanese (ja)
Inventor
Shinichi Fukawa
府川 信一
Toshio Inao
俊雄 稲生
Akio Kondo
近藤 昭夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tosoh Corp
Original Assignee
Tosoh Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tosoh Corp filed Critical Tosoh Corp
Priority to JP13413590A priority Critical patent/JPH0430323A/en
Publication of JPH0430323A publication Critical patent/JPH0430323A/en
Pending legal-status Critical Current

Links

Landscapes

  • Magnetic Record Carriers (AREA)

Abstract

PURPOSE:To improve the CSS durability of the magnetic recording medium and to provide the sufficient CSS durability even when the thickness of a protection layer is made thin by constituting the protection layer of a 2-layer structure in which a silicon carbide film and a carbon film are laminated from a magnetic recording layer. CONSTITUTION:A nonmagnetic background layer 2 made of a nonmagnetic metallic thin film and a magnetic recording layer 3 are formed on a base 1. Moreover, a protection layer comprising the lamination of a silicon carbide film 4 and a carbon film 5 is formed on the magnetic recording layer 3. Thus, the CSS durability is improved by the synergistic effect of the hard property of the silicon carbide film and the excellent lubricant property of the carbon film formed thereon, the possibility of generation of a head crash is low and the magnetic recording medium with high reliability is realized.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は磁気記録媒体に関するものであり、例えばコン
ピュータ等の外部記憶装置(磁気ディスク装置)におけ
る磁気記憶体などに用いることのできる磁気記録媒体に
関するものである。
Detailed Description of the Invention (Industrial Application Field) The present invention relates to a magnetic recording medium, which can be used, for example, as a magnetic storage body in an external storage device (magnetic disk device) of a computer or the like. It is related to.

(従来の技術) コンピュータなどの記憶媒体として磁気記録媒体が用い
られており、従来磁性粉を塗布したテープなどが広く用
いられていたが、この記憶テープは記憶密度が小さく、
アクセス時間が長いなどの欠点があるため、テープにか
わりランダムアクセスが可能な円板状の磁気ディスクが
用いられてきている。なかでもアルミニウムなどの堅い
基板上に、厚さ1μm程度の磁気記録層を形成して構成
された磁気ディスクが磁気記録媒体として使用されはじ
めている。このような磁気記録媒体の磁気記録層は、酸
化鉄などの磁性粉末をバインダと混合し、これを基板上
にスピンコードなどの手法で塗布することにより得られ
ていたが、この磁気記録層には飽和磁化の大きさに限界
があるため、記録密度に限界があった。そこで最近では
、高記録密度の磁気記録媒体を得るために、より大きい
飽和磁化を有する金属薄膜を磁気記録層として用いた磁
気記録媒体が開発されており、このような磁気記録層は
コバルト・あるいはコバルト系合金からなる薄膜を真空
蒸着法、スパッタリング法などの真空成膜技術により形
成したり、コバルト−リン、コバルト−ニッケルーリン
などの合金薄膜を無電解メツキなどの湿式法により形成
することにより得られている。
(Prior Art) Magnetic recording media are used as storage media in computers, etc., and conventionally tape coated with magnetic powder has been widely used, but this storage tape has a low storage density and
Due to drawbacks such as long access times, disk-shaped magnetic disks that allow random access have been used instead of tapes. Among these, magnetic disks constructed by forming a magnetic recording layer with a thickness of about 1 μm on a hard substrate such as aluminum are beginning to be used as magnetic recording media. The magnetic recording layer of such magnetic recording media was obtained by mixing magnetic powder such as iron oxide with a binder and applying it onto a substrate using a technique such as a spin cord. Since there is a limit to the magnitude of saturation magnetization, there is a limit to the recording density. Recently, in order to obtain magnetic recording media with high recording density, magnetic recording media using metal thin films with higher saturation magnetization as the magnetic recording layer have been developed, and such magnetic recording layers are made of cobalt or cobalt. A thin film made of a cobalt-based alloy can be formed by a vacuum film forming technique such as a vacuum evaporation method or a sputtering method, or a thin film of an alloy such as cobalt-phosphorus or cobalt-nickel-phosphorus can be formed by a wet method such as electroless plating. It is being

ところで、一般に使用されている磁気記録媒体のドライ
ブ装置には、ドライブ装置の停止、駆動に伴ないドライ
ブ装置のヘッドが磁気記録媒体に接触、こすれ合う、コ
ンタクト・スタート・ストップ(C3S)方式が採用さ
れているため、磁気記録媒体には上記のドライブ装置に
おけるC8Sに対する耐久性(CSS耐久性)が要求さ
れる。
By the way, drive devices for magnetic recording media that are commonly used employ the contact start-stop (C3S) method, in which the head of the drive device contacts and rubs against the magnetic recording medium as the drive device stops and drives. Therefore, the magnetic recording medium is required to have durability against C8S (CSS durability) in the above drive device.

そこで、磁気記録媒体にはその磁気記録層上に保護層が
設けられており、この保護層によって磁気記録媒体にC
8S耐久性を付与している。通常この保護層としては厚
み300Å以上の炭素膜が用いられているが、その一方
でより高い記録密度を達成するためにこの保護層の厚み
を薄くし、磁気記録媒体の使用の際にドライブ装置のヘ
ッドと磁気記録層のスペーシングロスを小さくすること
により磁気記録媒体の記録密度を向上させることが提案
されている。しかしながら、保護層として厚みの薄い炭
素膜を有する磁気記録媒体は、CSS耐久性が十分では
ないという問題ある。従って、このような磁気記録媒体
においては、使用に伴ないその炭素膜からなる保護層は
ヘッドの接触、こすれ合いにより磨耗してしまう。また
、このような保護層の磨耗はヘッドと磁気記録層とが衝
突するヘッド・クラッシュを引き起こし、これによって
磁気記録媒体あるいはドライブ装置のヘッドの損傷が生
じる。
Therefore, magnetic recording media are provided with a protective layer on the magnetic recording layer, and this protective layer protects the magnetic recording medium from carbon dioxide.
Provides 8S durability. Normally, a carbon film with a thickness of 300 Å or more is used as this protective layer, but on the other hand, in order to achieve higher recording density, the thickness of this protective layer is reduced, and when using magnetic recording media, the drive device It has been proposed to improve the recording density of a magnetic recording medium by reducing the spacing loss between the head and the magnetic recording layer. However, magnetic recording media having a thin carbon film as a protective layer have a problem in that they do not have sufficient CSS durability. Therefore, in such a magnetic recording medium, as the magnetic recording medium is used, the protective layer made of a carbon film is worn out due to head contact and rubbing. Further, such abrasion of the protective layer causes a head crash in which the head collides with the magnetic recording layer, resulting in damage to the magnetic recording medium or the head of the drive device.

(発明が解決しようとする課題) 本発明の目的は、C8s耐久性に優れ、がっ高記録密度
を達成し得る磁気記録媒体を提供することにある。
(Problems to be Solved by the Invention) An object of the present invention is to provide a magnetic recording medium that has excellent C8s durability and can achieve a much higher recording density.

(課題を解決するための手段) 本発明者らは上記課題を解決するために鋭意検討を行っ
た結果、炭化珪素膜と炭素膜を積層してなる保護層を有
する磁気記録媒体はC8S耐久性に優れるものとなるこ
とを見出だし本発明に至った。すなわち本発明は、非磁
性下地層を被覆した基板、その上に設けた磁性金属薄膜
からなる磁気記録層及び該磁気記録層を保護するための
保護層を含んでなる磁気記録媒体において、保護層が前
記磁気記録層側から炭化珪素膜と炭素膜を積層してなる
二層構造を有することを特徴とする磁気記録媒体である
。本発明の磁気記録媒体は、特に保護層が炭化珪素膜と
炭素膜を積層してなる二層構造を有するところに特徴の
あるものであるが、このことにより磁気記録媒体のC8
S耐久性が向上し、また保護層の厚みを薄くしても十分
なC8S耐久性を有するものとなる。その理由は明らか
ではないが、炭化珪素膜の硬いという特性及びその上に
形成する炭素膜の優れた潤滑性の両者の相乗効果による
ものと考えられる。
(Means for Solving the Problems) As a result of intensive studies to solve the above problems, the present inventors found that a magnetic recording medium having a protective layer formed by laminating a silicon carbide film and a carbon film has C8S durability. The present inventors have discovered that the present invention provides excellent properties. That is, the present invention provides a magnetic recording medium comprising a substrate coated with a non-magnetic underlayer, a magnetic recording layer made of a magnetic metal thin film provided thereon, and a protective layer for protecting the magnetic recording layer. is a magnetic recording medium characterized in that it has a two-layer structure in which a silicon carbide film and a carbon film are laminated from the magnetic recording layer side. The magnetic recording medium of the present invention is particularly characterized in that the protective layer has a two-layer structure formed by stacking a silicon carbide film and a carbon film.
S durability is improved, and even if the thickness of the protective layer is made thinner, sufficient C8S durability can be achieved. The reason for this is not clear, but it is thought to be due to the synergistic effect of the hardness of the silicon carbide film and the excellent lubricity of the carbon film formed thereon.

以下、図面を参照して本発明の詳細な説明する。Hereinafter, the present invention will be described in detail with reference to the drawings.

第1図は本発明の磁気記録媒体の一例の部分断面図であ
る。本発明の磁気記録媒体は第1図に示すように基板1
上に磁気記録層2及び保護層を形成した構成される。こ
の基板1としてはニッケルーリンメツキ膜、陽極酸化ア
ルマイト膜などを被覆したアルミニウム合金、窒化珪素
焼結体、酸化アルミ焼結体などのセラミックスやステン
レス、チタン合金などの金属、ガラスあるいは樹脂など
が用いられる。また、基板1上には磁気記録媒体の磁気
特性を向上させる目的でクロムなどの非磁性金属薄膜な
どからなる非磁性下地層2を形成してもよく、その厚み
は500〜5000人とすることが好ましい。次に基板
1の上には磁気記録層3が形成される。この磁気記録層
としては、例えばコバルト、コバルトニッケル合金から
なる磁性金属あるいはこれら磁性金属にプラチナ、ロジ
ウム、クロム、サマリウム、タンタル、レニウム及びタ
ングステンから選ばれる少なくとも一種以上の金属を添
加したものなどが用いられ、その厚みは300〜100
0人に形成される。さらにその上に炭化珪素膜4及び炭
素膜5を積層してなる保護層が形成される。この保護層
の厚みが厚い場合、スペーシングロスが大きくなり、磁
気記録媒体の高記録密度領域での特性が悪くなるおそれ
があり、一方、薄い場合は得られる磁気記録媒体のC8
S耐久性が向上しないおそれがあるので、炭化珪素膜4
、炭素膜5とも各々20〜300人とすることが好まし
く、50〜100人とすることが更に好ましい。なお本
発明の磁気記録媒体の使用にあたっては、必要に応じて
保護層上に液体潤滑剤、固体潤滑剤あるいはこれらの複
合潤滑剤を塗布し、潤滑層6を形成して使用することが
できる。
FIG. 1 is a partial cross-sectional view of an example of the magnetic recording medium of the present invention. The magnetic recording medium of the present invention has a substrate 1 as shown in FIG.
The structure includes a magnetic recording layer 2 and a protective layer formed thereon. As the substrate 1, ceramics such as aluminum alloys coated with nickel-phosphorous plating films, anodized alumite films, etc., silicon nitride sintered bodies, aluminum oxide sintered bodies, stainless steel, metals such as titanium alloys, glass, or resins are used. It will be done. Further, a non-magnetic underlayer 2 made of a thin film of a non-magnetic metal such as chromium may be formed on the substrate 1 for the purpose of improving the magnetic properties of the magnetic recording medium, and the thickness thereof should be 500 to 5000. is preferred. Next, a magnetic recording layer 3 is formed on the substrate 1. This magnetic recording layer is made of, for example, a magnetic metal such as cobalt, cobalt-nickel alloy, or a magnetic metal to which at least one metal selected from platinum, rhodium, chromium, samarium, tantalum, rhenium, and tungsten is added. and its thickness is 300-100
Formed into 0 people. Furthermore, a protective layer formed by laminating silicon carbide film 4 and carbon film 5 is formed thereon. If this protective layer is thick, the spacing loss will increase and the characteristics of the magnetic recording medium in the high recording density region may deteriorate.On the other hand, if it is thin, the resulting magnetic recording medium may have a C8
Since there is a risk that S durability may not improve, silicon carbide film 4
, and the carbon film 5 are preferably made up of 20 to 300 people, and more preferably 50 to 100 people. When using the magnetic recording medium of the present invention, a liquid lubricant, a solid lubricant, or a combination of these lubricants may be applied on the protective layer to form a lubricant layer 6, if necessary.

以上、非磁性下地層2から炭素膜5までの金属あるいは
無機物質の薄膜の形成にあたってはDCあるいはRFス
パッタリング法あるいは真空蒸着法などの真空成膜技術
が有効に用いられる。
As described above, in forming the thin films of metal or inorganic substances from the non-magnetic underlayer 2 to the carbon film 5, vacuum film forming techniques such as DC or RF sputtering or vacuum evaporation are effectively used.

(実施例) 以下、本発明を実施例に基づき説明するが、本発明はこ
れら実施例に限定されるものではない。
(Examples) Hereinafter, the present invention will be explained based on Examples, but the present invention is not limited to these Examples.

実施例 第1図に示す磁気記録媒体を作製した。基板1としてニ
ッケルーリンメツキ膜を被覆した円板状アルミニウム合
金を用い、この基板1の上にDCスパッタリング法によ
り3000人のクロム膜からなる非磁性下地層2を形成
した。次にこの上に磁気記録層3としてニッケル20原
子%、クロム10原子%を含むコバルト合金膜をDCス
パッタリング法により600人の厚みに形成した。更に
、この上に保護層として厚み100人の炭化珪素膜4及
び厚み100人の炭素膜5をそれぞれDCスパッタリン
グ法により積層して形成し、次いで、この保護層上に液
体潤滑剤からなる潤滑層6をディッピング法により形成
することにより磁気記録媒体を作製した。
Example A magnetic recording medium shown in FIG. 1 was produced. A disc-shaped aluminum alloy coated with a nickel-phosphorus plating film was used as the substrate 1, and a non-magnetic underlayer 2 made of a 3000 chrome film was formed on the substrate 1 by DC sputtering. Next, a cobalt alloy film containing 20 atom % of nickel and 10 atom % of chromium was formed thereon as a magnetic recording layer 3 to a thickness of 600 mm by DC sputtering. Furthermore, a silicon carbide film 4 with a thickness of 100 ml and a carbon film 5 with a thickness of 100 ml as a protective layer are laminated thereon by DC sputtering, and then a lubricating layer made of a liquid lubricant is formed on this protective layer. A magnetic recording medium was manufactured by forming 6 by a dipping method.

磁気記録媒体の作製後、得られた磁気記録媒体のC8S
耐久性を測定した。この耐久性の測定はC8S測定装置
を用いて行ない、磁気記録媒体上でヘッドをスタート−
ストップさせ、これを1サイクルとし、所定のサイクル
後の磁気記録媒体上の摩擦係数を求めることにより行な
った。その結果を表1に示す。表1から本発明の磁気記
録媒体は摩擦係数の増加が小さく、C8S耐久性に優れ
ていることがわかる。
After manufacturing the magnetic recording medium, C8S of the obtained magnetic recording medium
Durability was measured. This durability measurement was performed using a C8S measuring device, and the head was started on the magnetic recording medium.
The measurement was performed by stopping the magnetic recording medium, making this one cycle, and determining the coefficient of friction on the magnetic recording medium after a predetermined cycle. The results are shown in Table 1. It can be seen from Table 1 that the magnetic recording medium of the present invention has a small increase in the coefficient of friction and is excellent in C8S durability.

比較例 1 保護層を厚み200人の炭素膜だけで形成した以外は、
実施例と同様の方法で、磁気記録媒体を作製し、C8S
耐久性を測定した。その結果を表1に示す。
Comparative Example 1 Except that the protective layer was formed only with a carbon film with a thickness of 200 mm,
A magnetic recording medium was produced in the same manner as in the example, and C8S
Durability was measured. The results are shown in Table 1.

比較例 2 保護層を厚み200人の炭化珪素膜だけで形成した以外
は、実施例と同様の方法で、磁気記録媒体を作製し、C
8S耐久性を測定した。その結果を表1に示す。
Comparative Example 2 A magnetic recording medium was manufactured in the same manner as in Example except that the protective layer was formed using only a silicon carbide film with a thickness of 200 mm.
8S durability was measured. The results are shown in Table 1.

表1 (発明の効果) 以上の述べたとおり、本発明の磁気記録媒体は、C8S
耐久性が著しく向上するので、この磁気記録媒体はヘッ
ド・クラッシュが生じる可能性が低くなり、信頼性の高
い磁気記録媒体となる。更に、本発明の磁気記録媒体は
保護層の厚みを薄くしても十分なC8S耐久性を示すの
で、高記録密度を達成し得るものとなる。
Table 1 (Effects of the invention) As described above, the magnetic recording medium of the present invention has C8S
Since the durability is significantly improved, this magnetic recording medium is less likely to cause a head crash and becomes a highly reliable magnetic recording medium. Furthermore, since the magnetic recording medium of the present invention exhibits sufficient C8S durability even when the thickness of the protective layer is reduced, high recording density can be achieved.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の磁気記録媒体の一例の部分断面図であ
る。 図中、 1・・・基板       2・・・下地層3・・・磁
気記録層    4・・・珪素炭化物膜5・・・炭素膜
      6・・・潤滑層を各々示す。
FIG. 1 is a partial cross-sectional view of an example of the magnetic recording medium of the present invention. In the figure, 1...Substrate 2...Underlayer 3...Magnetic recording layer 4...Silicon carbide film 5...Carbon film 6...Lubricant layer, respectively.

Claims (1)

【特許請求の範囲】[Claims] (1)非磁性下地層を被覆した基板、その上に設けた磁
性金属薄膜からなる磁気記録層及び該磁気記録層を保護
するための保護層を含んでなる磁気記録媒体において、
保護層が前記磁気記録層側から炭化珪素膜と炭素膜を積
層してなる二層構造を有することを特徴とする磁気記録
媒体。
(1) A magnetic recording medium comprising a substrate coated with a non-magnetic underlayer, a magnetic recording layer made of a magnetic metal thin film provided thereon, and a protective layer for protecting the magnetic recording layer,
A magnetic recording medium characterized in that the protective layer has a two-layer structure in which a silicon carbide film and a carbon film are laminated from the magnetic recording layer side.
JP13413590A 1990-05-25 1990-05-25 Magnetic recording medium Pending JPH0430323A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13413590A JPH0430323A (en) 1990-05-25 1990-05-25 Magnetic recording medium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13413590A JPH0430323A (en) 1990-05-25 1990-05-25 Magnetic recording medium

Publications (1)

Publication Number Publication Date
JPH0430323A true JPH0430323A (en) 1992-02-03

Family

ID=15121290

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13413590A Pending JPH0430323A (en) 1990-05-25 1990-05-25 Magnetic recording medium

Country Status (1)

Country Link
JP (1) JPH0430323A (en)

Similar Documents

Publication Publication Date Title
US4898774A (en) Corrosion and wear resistant magnetic disk
JP2010218610A (en) Magnetic recording medium and magnetic recording device
US6238780B1 (en) Magnetic recording medium comprising multilayered carbon-containing protective overcoats
JPH0430323A (en) Magnetic recording medium
JP2952967B2 (en) Magnetic recording media
JPS61199224A (en) Magnetic recording medium
JPS626425A (en) Magnetic recording medium
JP3030990B2 (en) Magnetic recording media
JPH0514325B2 (en)
JP3044571B2 (en) Magnetic recording media
JP2814630B2 (en) Magnetic recording media
JP2000348334A (en) Magnetic recording medium and magnetic disk device
JPH0196820A (en) Magnetic recording medium
JPS6342021A (en) Magnetic recording medium
JPH02121116A (en) Magnetic recording medium
JP2861081B2 (en) Magnetic recording media
JPH0467252B2 (en)
JPH0467251B2 (en)
JPS60167117A (en) Magnetic recording medium
JPH02139709A (en) Magnetic recording medium and its production
JPH0334122A (en) Magnetic recording medium and production thereof
JPH04285727A (en) Magnetic disk device
JPH03102616A (en) Magnetic recording medium
JPH0467250B2 (en)
JPH0581658A (en) Magnetic recording medium