JPH04293982A - Coating composition - Google Patents
Coating compositionInfo
- Publication number
- JPH04293982A JPH04293982A JP8603191A JP8603191A JPH04293982A JP H04293982 A JPH04293982 A JP H04293982A JP 8603191 A JP8603191 A JP 8603191A JP 8603191 A JP8603191 A JP 8603191A JP H04293982 A JPH04293982 A JP H04293982A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- coating composition
- diol
- abrasion resistance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000008199 coating composition Substances 0.000 title claims abstract description 11
- 150000002009 diols Chemical class 0.000 claims abstract description 16
- 229920002545 silicone oil Polymers 0.000 claims abstract description 8
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 125000005442 diisocyanate group Chemical group 0.000 claims abstract description 6
- 229920000728 polyester Polymers 0.000 claims abstract description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 5
- 229920000570 polyether Polymers 0.000 claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- 230000002140 halogenating effect Effects 0.000 claims abstract description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 238000005299 abrasion Methods 0.000 abstract description 10
- 229920001971 elastomer Polymers 0.000 abstract description 6
- 239000005060 rubber Substances 0.000 abstract description 6
- 239000011347 resin Substances 0.000 abstract description 5
- 229920005989 resin Polymers 0.000 abstract description 5
- 239000000835 fiber Substances 0.000 abstract description 3
- 239000000758 substrate Substances 0.000 abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000005062 Polybutadiene Substances 0.000 description 5
- -1 polytetramethylene Polymers 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- SYBYTAAJFKOIEJ-UHFFFAOYSA-N 3-Methylbutan-2-one Chemical compound CC(C)C(C)=O SYBYTAAJFKOIEJ-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 229920002943 EPDM rubber Polymers 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropanol acetate Natural products CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 description 2
- 229940011051 isopropyl acetate Drugs 0.000 description 2
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- INSRQEMEVAMETL-UHFFFAOYSA-N decane-1,1-diol Chemical compound CCCCCCCCCC(O)O INSRQEMEVAMETL-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- 229940050176 methyl chloride Drugs 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920003216 poly(methylphenylsiloxane) Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
【０００１】0001
【産業上の利用分野】本発明はゴム、樹脂製品等の塗装
に適した塗料組成物に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a coating composition suitable for coating rubber, resin products, etc.
【０００２】0002
【従来の技術】一般に、ＮＲ、ＳＢＲ、ＢＲ、ＩＩＲ、
ＣＲ、ＮＢＲ、ＩＲ、ＥＰＤＭ、ＥＰＴ等のゴムや、木
綿、レーヨン、ＡＢＳ、ＰＳ等の樹脂、繊維は耐摩耗性
が非常に悪い。これらにナイロン、エポキシ樹脂、アク
リル樹脂、アクリル−エチレン系樹脂等の樹脂系塗料お
よびＢＲ、ＣＲ、ＳＢＲ等のゴム系塗料を塗布し摩耗を
行なった場合
（Ａ）ゴム、合成樹脂製品、繊維との密着性がないため
摩耗中基材と塗料がはがれる不具合が発生する（Ｂ）塗
料自体に耐摩耗性がないため耐摩耗性にとぼしいという
問題がある。[Prior Art] Generally, NR, SBR, BR, IIR,
Rubbers such as CR, NBR, IR, EPDM, and EPT, resins and fibers such as cotton, rayon, ABS, and PS have very poor abrasion resistance. If these are coated with resin-based paints such as nylon, epoxy resin, acrylic resin, or acrylic-ethylene resin, or rubber-based paints such as BR, CR, or SBR, and subjected to abrasion (A) Rubber, synthetic resin products, or fibers. (B) The paint itself has no abrasion resistance, resulting in poor abrasion resistance.
【０００３】0003
【発明が解決しようとする課題】本発明の目的は上記問
題点を解消し、被塗布物表面との密着性がよく、耐摩耗
性の優れた塗料組成物を提供するものである。SUMMARY OF THE INVENTION An object of the present invention is to solve the above-mentioned problems and provide a coating composition that has good adhesion to the surface of the object to be coated and excellent abrasion resistance.
【０００４】0004
【課題を解決するための手段】本発明者は、これらの欠
点を改良するための研究をつづけ、その結果、上記欠点
を改良する塗料組成物をみいだした。[Means for Solving the Problems] The present inventor has continued research to improve these drawbacks, and as a result, has discovered a coating composition that can improve the above drawbacks.
【０００５】本発明の塗料組成物とはポリエーテルジオ
ール、ポリエステルジオール、ジイソシアナートと低
分子ジオールよりなるウレタン組成物１００重量部、
フッ素樹脂２〜１００重量部、シリコーンオイル５〜２
００重量部、ハロゲン化剤０．００２〜２０重量部より
なる塗料組成物である。The coating composition of the present invention consists of polyether diol, polyester diol, diisocyanate and low
100 parts by weight of a urethane composition consisting of a molecular diol,
Fluororesin 2-100 parts by weight, silicone oil 5-2
0.00 parts by weight, and 0.002 to 20 parts by weight of a halogenating agent.
【０００６】[0006]
【実施例】以下に本発明を具体化した実施例について説
明する。[Examples] Examples embodying the present invention will be described below.
【０００７】本発明で用いるポリエーテルジオールとは
ポリエチレンオキシドグリコール、ポリプロピレンオキ
シドグリコール、ポリテトラメチレンオキシドグリコー
ル等である。ポリエステルジオールとはエチレングリコ
ール、プロピレングリコール、ブチレングリコール、ペ
ンタンジオール、ヘキサンジオール、ヘキシレンジオー
ル、オクタンジオール、デカンジオール、ネオペンチル
グリコール等（ジオール類に二重結合、三重結合を含有
するものも含まれる）の一種又は二種以上の混合物と、
アジピン酸、マロン酸、コハク酸、マレイン酸、無水マ
レイン酸、フマル酸、テレフタル酸、無水フタル酸等の
有機酸の一種又は二種以上の混合物を反応させて得られ
る末端にＯＨ基を有するポリエステルジオールである。The polyether diol used in the present invention includes polyethylene oxide glycol, polypropylene oxide glycol, polytetramethylene oxide glycol, and the like. Polyester diols include ethylene glycol, propylene glycol, butylene glycol, pentanediol, hexanediol, hexylene diol, octanediol, decanediol, neopentyl glycol, etc. (diols that contain double bonds and triple bonds are also included) ) or a mixture of two or more of them;
Polyester having an OH group at the end obtained by reacting one or a mixture of two or more organic acids such as adipic acid, malonic acid, succinic acid, maleic acid, maleic anhydride, fumaric acid, terephthalic acid, and phthalic anhydride. It is a diol.
【０００８】ジイソシアネートには、ＭＤＩ、ＴＤＩ、
ＩＰＤＩ、ＸＤＩ、ＮＤＩ等のジイソシアネートが例示
できる。Diisocyanates include MDI, TDI,
Examples include diisocyanates such as IPDI, XDI, and NDI.
【０００９】シリコーンオイルとは、ジメチルシリコー
ンオイル、メチル塩化シリコーンオイル、メチルハイド
ロジエンシリコーンオイル、メチルフェニルシリコーン
オイル、フロロシリコーンオイル等であり、溶剤にはベ
ンゼン、トルエン、キシレン、エチルベンゼン、トリク
ロルエチレン、塩化エチレン、ジメチルホルムアミド、
ジメチルスルホキサイド、メチルエチルケトン、アセト
ン、メチルイソプロピルケトン、酢酸メチル、酢酸エチ
ル、酢酸イソプロピル、酢酸ｎ−ブチル、酢酸イソプロ
ピル、アニソール、テトラヒドロフラン等を用いる。[0009] Silicone oils include dimethyl silicone oil, methyl chloride silicone oil, methylhydrogen silicone oil, methylphenyl silicone oil, fluorosilicone oil, etc., and solvents include benzene, toluene, xylene, ethylbenzene, trichloroethylene, and chloride. ethylene, dimethylformamide,
Dimethyl sulfoxide, methyl ethyl ketone, acetone, methyl isopropyl ketone, methyl acetate, ethyl acetate, isopropyl acetate, n-butyl acetate, isopropyl acetate, anisole, tetrahydrofuran, etc. are used.
【００１０】ａ）塗料組成物の調製
上記ポリエステルジオール、ポリエーテルジオール、ジ
イソシアナートと溶剤を適宜選択して使用し（選択例を
表−１に示す）、乾燥窒素ガス中、８０℃、３時間反応
させ、末端にＮＣＯ基を有するウレタンプレポリマーを
合成し、さらに低分子ジオールと溶剤を加え乾燥窒素ガ
ス中３０分間反応を行ない得られる末端にＯＨ基又はＮ
ＣＯ基を有するウレタンポリマー（固形分）１００重量
部に対して、フッ素樹脂２〜１００重量部、シリコーン
オイル５〜２００重量部、ハロゲン化剤０．００２〜２
０重量部を加え、さらに溶剤を加えて塗布に適した、粘
度に調整する。この場合、フッ素樹脂のかわりに二硫化
モリブデン、ガラス繊維、カーボン繊維、ポリエチレン
、酸化ケイ素、炭酸カルシウム、炭酸マグネシウム、ク
レー、ナイロン等を使用してもよい。a) Preparation of coating composition The above-mentioned polyester diol, polyether diol, diisocyanate and solvent were appropriately selected and used (selected examples are shown in Table 1), and the mixture was heated at 80°C for 30 minutes in dry nitrogen gas. A urethane prepolymer having an NCO group at the end is synthesized by reacting for a period of time, and then a low molecular diol and a solvent are added and the reaction is carried out in dry nitrogen gas for 30 minutes.
2 to 100 parts by weight of fluororesin, 5 to 200 parts by weight of silicone oil, and 0.002 to 2 parts by weight of halogenating agent per 100 parts by weight of urethane polymer (solid content) having CO groups.
Add 0 parts by weight and further add a solvent to adjust the viscosity to a value suitable for coating. In this case, molybdenum disulfide, glass fiber, carbon fiber, polyethylene, silicon oxide, calcium carbonate, magnesium carbonate, clay, nylon, etc. may be used instead of the fluororesin.
【００１１】ｂ）基材の調製
ＥＰＤＭ１００重量部に対して、カーボンブラック７０
重量部、鉱物油３５重量部、亜鉛華７重量部、ステアリ
ン酸２重量部、加硫促進剤２重量部、イオウ１．５重量
部のゴム配合物を１６０℃で３０分間加硫した。b) Preparation of base material To 100 parts by weight of EPDM, add 70 parts by weight of carbon black.
A rubber compound containing 35 parts by weight of mineral oil, 7 parts by weight of zinc white, 2 parts by weight of stearic acid, 2 parts by weight of vulcanization accelerator, and 1.5 parts by weight of sulfur was vulcanized at 160° C. for 30 minutes.
【００１２】また、耐摩耗試験方法は、下記条件で行い
摩耗減量で耐摩耗性を評価した。
試験機：テイパー式ロータリアブレッサー（株式会社東
洋精機製作所製）
試験条件：摩耗輪…Ｈ−２２、荷重…１ｋｇ摩耗回転速
度…６０ｒｐｍ
試料寸法…１００ｍｍ×１００ｍｍ
摩耗回転…１０００回[0012] Furthermore, the abrasion resistance test was carried out under the following conditions and the abrasion resistance was evaluated by wear loss. Testing machine: Taper type rotary breather (manufactured by Toyo Seiki Seisakusho Co., Ltd.) Test conditions: Wearing wheel...H-22, Load...1kg Wearing rotation speed...60rpm Sample size...100mm x 100mm
Wear rotation…1000 times
【００１３】このようにして得られた本発明の塗料組成
物を用いた耐摩耗性の試験結果を表−２に示す。Table 2 shows the results of the abrasion resistance test using the coating composition of the present invention thus obtained.
【００１４】[0014]
【発明の効果】これらの塗料組成物は被塗布物に塗布し
た場合、被塗布物の材料特性を損なうことなく、塗膜が
被塗布物表面との優れた密着性を有し、優れた耐摩耗性
を示す。Effects of the Invention When these coating compositions are applied to the object to be coated, the coating film has excellent adhesion to the surface of the object to be coated and has excellent durability without impairing the material properties of the object. Shows abrasive properties.
【００１５】[0015]
【００１６】[0016]
【００１７】[0017]
【００１８】[0018]
【００１９】
出光シールＡＢ−７００Ｗ：商品名、液状ポリブタ
ジエン 出光石油株式会社製
出光シールＡＢ−１００：商品名、液状ポリブタジエン
出光石油株式会社製
ボンド Ｇ２ ：商品名、クロロプレン系ゴム ト
ルエン７４％溶 液コニシ株式会社製Idemitsu Seal AB-700W: Product name, liquid polybutadiene Idemitsu Seal AB-100: Product name, liquid polybutadiene Idemitsu Seal AB-100: Product name, liquid polybutadiene Bond G2: Product name, chloroprene rubber 74% toluene solution Konishi Made by Co., Ltd.
Claims (1)
ールとジイソシアナートよりなり末端にＮＣＯ基を有す
るウレタンプレポリマーにさらに低分子ジオールを反応
させて得られる末端にＮＣＯ基又はＯＨ基を有するウレ
タン組成物１００重量部、フッ素樹脂２〜１００重量部
、シリコーンオイル５〜２００重量部、ハロゲン化剤０
．００２〜２０重量部よりなる塗料組成物。[Claim 1] Urethane composition 100 having NCO groups or OH groups at the ends obtained by reacting a urethane prepolymer comprising polyether diol, polyester diol and diisocyanate and having NCO groups at the ends with a low molecular weight diol. Parts by weight, 2 to 100 parts by weight of fluororesin, 5 to 200 parts by weight of silicone oil, 0 parts by weight of halogenating agent
．． A coating composition comprising 0.002 to 20 parts by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8603191A JPH04293982A (en) | 1991-03-25 | 1991-03-25 | Coating composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8603191A JPH04293982A (en) | 1991-03-25 | 1991-03-25 | Coating composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04293982A true JPH04293982A (en) | 1992-10-19 |
Family
ID=13875293
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8603191A Withdrawn JPH04293982A (en) | 1991-03-25 | 1991-03-25 | Coating composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04293982A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001021721A1 (en) * | 1999-09-22 | 2001-03-29 | Takeda Chemical Industries, Ltd. | Coating material for coating molded object made by dip forming |
| CN1100838C (en) * | 1999-03-05 | 2003-02-05 | 旭丽股份有限公司 | Organosilicon modified polyurethane paint |
| US7378032B2 (en) * | 2002-12-24 | 2008-05-27 | Daikin Industries, Ltd. | Coating composition for leather, coating method, and coated leather |
| JP2014148599A (en) * | 2013-01-31 | 2014-08-21 | Fukoku Co Ltd | Coating composition and rubber member |
-
1991
- 1991-03-25 JP JP8603191A patent/JPH04293982A/en not_active Withdrawn
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1100838C (en) * | 1999-03-05 | 2003-02-05 | 旭丽股份有限公司 | Organosilicon modified polyurethane paint |
| WO2001021721A1 (en) * | 1999-09-22 | 2001-03-29 | Takeda Chemical Industries, Ltd. | Coating material for coating molded object made by dip forming |
| US7378032B2 (en) * | 2002-12-24 | 2008-05-27 | Daikin Industries, Ltd. | Coating composition for leather, coating method, and coated leather |
| JP2014148599A (en) * | 2013-01-31 | 2014-08-21 | Fukoku Co Ltd | Coating composition and rubber member |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A300 | Application deemed to be withdrawn because no request for examination was validly filed |
Free format text: JAPANESE INTERMEDIATE CODE: A300 Effective date: 19980514 |