JPH04267135A - Preparation of in-mold formed molded product - Google Patents

Preparation of in-mold formed molded product

Info

Publication number
JPH04267135A
JPH04267135A JP3111246A JP11124691A JPH04267135A JP H04267135 A JPH04267135 A JP H04267135A JP 3111246 A JP3111246 A JP 3111246A JP 11124691 A JP11124691 A JP 11124691A JP H04267135 A JPH04267135 A JP H04267135A
Authority
JP
Japan
Prior art keywords
mold
cavity
particles
molded product
steam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP3111246A
Other languages
Japanese (ja)
Other versions
JP2785076B2 (en
Inventor
Hiroshi Endo
遠藤 紘
Koji Shinto
新堂 幸治
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical BASF Co Ltd
Original Assignee
Mitsubishi Chemical BASF Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical BASF Co Ltd filed Critical Mitsubishi Chemical BASF Co Ltd
Priority to JP3111246A priority Critical patent/JP2785076B2/en
Publication of JPH04267135A publication Critical patent/JPH04267135A/en
Application granted granted Critical
Publication of JP2785076B2 publication Critical patent/JP2785076B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PURPOSE:To easily obtain a bead foamed molded product faithful to the shape of a cavity and having high compression strength by filling a mold with prefoamed particles to foam said particles under heating and moving at least one split mold of a mold to increase the volume of the cavity of the mold. CONSTITUTION:A mold 1 consisting of freely separable split molds 1a, 1b is used and the cavity 2 of the mold 1 set to such a state that the contact surfaces of both split molds 1a, 1b are separated by about 1mm is filled with prefoamed particles using a filling gun 7. After a filling port 6 is closed, steam is introduced into the chamber 4 of the split mold 1b to remove the air present between the particles as much as possible and both split molds 1a, 1b are subsequently brought to a contact state. Next, the particle group is heated and expanded by the steam introduced into the chambers 4 of both split molds 1a, 1b to mutually fuse the particles. Thereafter, the mold 1 is opened to increase the volume of the cavity 2 and steam is introduced into the chambers 4 to expand the foamed body and the expanded body is cooled and the mold 1 is opened to obtain a molded product.

Description

【発明の詳細な説明】[Detailed description of the invention]

【0001】0001

【産業上の利用分野】本発明は軟弱地盤の埋め立て用材
、電化製品等の重量物の包装用コーナーパット等に有用
な型内ビーズ発泡成形品の製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing an in-mold bead foam molded product useful for reclamation of soft ground, corner pads for packaging heavy items such as electrical appliances, and the like.

【0002】0002

【従来の技術】ポリスチレン、ポリプロピレン、ポリエ
チレン等を原料とする型内ビーズ発泡成形品が市販され
ており、これらの成形品は軽量性、断熱性、緩衝特性等
に優れているため、各種の包装材、容器、建築用断熱材
、自動車用バンパーの芯材等に広く用いられている。
[Prior Art] In-mold bead foam molded products made from polystyrene, polypropylene, polyethylene, etc. are commercially available, and these molded products have excellent lightness, heat insulation, and cushioning properties, so they are used in various packaging. It is widely used for materials such as wood, containers, thermal insulation materials for buildings, and core materials for automobile bumpers.

【0003】0003

【発明が解決しようとする課題】上記用途においては、
一般に軽重性及び圧縮強度が高いことが要求される。従
来、型内ビーズ発泡成形品の圧縮強度を上げる方法とし
ては、発泡倍率を低くする、言い換えると、密度を高く
するといった方法がある。この方法によると、製品重量
が増すとか、コストがアップするとか、緩衝性が低下す
るという問題がある。
[Problem to be solved by the invention] In the above application,
Generally, it is required to be lightweight and have high compressive strength. Conventionally, as a method of increasing the compressive strength of an in-mold bead foam molded product, there is a method of lowering the expansion ratio, in other words, increasing the density. According to this method, there are problems such as an increase in product weight, an increase in cost, and a decrease in cushioning properties.

【0004】特に、軟弱地盤の埋め立て用材(実開平1
−120533号公報、実開昭63−194948公報
)は、寸法が縦1000mm、横2000mm、高さ5
00mmのブロック(密度が0.02g/cm3)で、
1個の重量が20kgもある。軽い(密度が低い)ブロ
ックで同一圧縮強度のものが存在すれば、その1個の重
量を小さくすることが可能であり、運搬等の取扱いが容
易となるばかりか、材料コストも低減できる。このよう
なことは長さが1500mm、幅が120mm、高さが
100〜150mmである自動車用バンパーの芯材につ
いても同様である。
[0004] In particular, materials for reclamation of soft ground
-120533 publication, Utility Model Application Publication No. 1989-194948) has dimensions of 1000 mm in length, 2000 mm in width, and 5 in height.
00mm block (density 0.02g/cm3),
Each piece weighs 20 kg. If light (low density) blocks with the same compressive strength exist, it is possible to reduce the weight of each block, which not only makes handling such as transportation easier, but also reduces material costs. This also applies to the core material of an automobile bumper, which has a length of 1500 mm, a width of 120 mm, and a height of 100 to 150 mm.

【0005】同一素材、同一密度の型内ビーズ発泡成形
品においては、気泡径が小さい程圧縮強度が大きいと言
われている。  かかる気泡径の調整にはセル調整材が
使用されているが、気泡径の調整による圧縮強度の向上
は多くを期待できないのが現状であって、その向上はそ
こが知れている。
It is said that in in-mold bead foam molded products made of the same material and the same density, the smaller the cell diameter, the higher the compressive strength. Although cell adjustment materials are used to adjust the cell diameter, it is currently not possible to expect much improvement in compressive strength by adjusting the cell diameter, and this improvement is well known.

【0006】本発明は上記の問題に鑑みてなされたもの
で、その目的は同一素材であって、密度が同じ発泡体で
あっても、圧縮強度のより高い型内ビーズ発泡成形品を
得るための製造方法を提供することにある。
The present invention was made in view of the above problems, and its purpose is to obtain an in-mold bead foam molded product with higher compressive strength even when the foam is made of the same material and has the same density. The purpose of this invention is to provide a method for manufacturing the same.

【0007】[0007]

【課題を解決するための手段】上記目的を達成するため
に、本発明の特徴とする型内ビーズ発泡成形品の製造方
法は予備発泡粒子をキャビティの容積変化が可能な金型
内に充填し、この粒子群をスチーム等により加熱発泡さ
せて互いに融着させながら、又は融着させて該粒子間の
隙間が残っている発泡体を得た後、上記金型の一方の割
型或いは双方の割型を移動させることにより上記金型の
キャビティ内の容積を1.1〜2倍に増大させて、この
キャビティ内で上記発泡体を加熱膨脹させることにより
、該キャビティの形状に忠実な発泡成形体を形成し、次
いで、この発泡成形体を冷却するものである。
[Means for Solving the Problems] In order to achieve the above object, the method for manufacturing an in-mold bead foam molded product, which is a feature of the present invention, involves filling pre-expanded particles into a mold whose cavity volume can be changed. After heating and foaming this particle group with steam or the like to fuse them together or fuse them to obtain a foam in which gaps remain between the particles, one or both of the split molds of the above-mentioned mold are By moving the split mold, the volume inside the cavity of the mold is increased by 1.1 to 2 times, and the foam is heated and expanded within this cavity, thereby forming a foam molding that is faithful to the shape of the cavity. The foamed molded product is then cooled.

【0008】しかして、この製造方法に使用される予備
発泡粒子、例えばスチレン系樹脂の予備発泡粒子は、プ
ロパン、ブタン、ペンタン、ヘキサン等の脂肪酸炭化水
素、又は塩化メチル、テトラクロルエチレン等のハロゲ
ン化炭化水素、或いは石油エーテル等の易揮発性物質を
膨脹剤として、粒子中にこの膨脹剤を2〜15重量部含
むスチレン系樹脂粒子を撹拌しながらスチームにより加
熱し、密度を0.015〜0.15g/cm3、粒子径
を2〜8mmの大きさに予備発泡させて成るものである
。また、スチレン系樹脂としては、スチレン、メチルス
チレン、クロロスチレン等のスチレン系単量体の単独重
合体、又はこの種の単量体相互間の共重合体、或いはこ
の種の単量体と他の重合性中量体、例えばブタジエン、
イソプレン、塩化ビニル、メチルメタアクリレート等と
の共重合体が使用される。
[0008] The pre-expanded particles used in this production method, for example, the pre-expanded particles of styrene resin, are made of fatty acid hydrocarbons such as propane, butane, pentane, hexane, etc., or halogens such as methyl chloride, tetrachloroethylene, etc. Styrenic resin particles containing 2 to 15 parts by weight of this swelling agent in the particles are heated with steam while stirring to have a density of 0.015 to 0.015 using a readily volatile substance such as hydrogenated hydrocarbon or petroleum ether as an expansion agent. It is made by pre-foaming to a particle size of 0.15 g/cm3 and a particle size of 2 to 8 mm. In addition, the styrene resin may be a homopolymer of styrene monomers such as styrene, methylstyrene, or chlorostyrene, or a copolymer of these monomers, or a combination of this type of monomer and other monomers. polymerizable intermediates such as butadiene,
Copolymers with isoprene, vinyl chloride, methyl methacrylate, etc. are used.

【0009】更に、本発明において、発泡体の膨脹及び
圧縮は、発泡体の原料樹脂が可塑性をもたらす温度(ポ
リスチレンでは75〜80℃)以上の温度で行われる。 本発明を実施するに、予備発泡粒子を最初にスチーム加
熱するのみで膨脹時及び圧縮時に発泡体は該熱変形温度
以上の温度であるので、外部からの加熱は必要でないが
、必要に応じては外部から加熱してもよい。また、予備
発泡粒子としてはポリプロピレン、低密度ポリエチレン
、高密度ポリエチレン及び線状ポリエチレン等の熱可塑
性樹脂の予備発泡粒子も使用できる。
Furthermore, in the present invention, the expansion and compression of the foam are carried out at a temperature higher than the temperature at which the raw material resin of the foam becomes plastic (75 to 80° C. for polystyrene). In carrying out the present invention, only the pre-expanded particles are first heated with steam, and the foam is at a temperature above the heat distortion temperature during expansion and compression, so external heating is not necessary. may be heated externally. Pre-expanded particles of thermoplastic resins such as polypropylene, low-density polyethylene, high-density polyethylene, and linear polyethylene can also be used as the pre-expanded particles.

【0010】0010

【実施例】先ず、本発明方法の実施に使用される金型の
1例を図面を参照しながら説明する。図1において、1
はキャビティ2の容積を変化きる金型で、離接自在な割
型1aと割型1bにより形成されている。3は両割型1
a,1bの接触面(パーテイングライン)である。4は
加熱流体(スチーム)や冷却流体(水)を導入するチャ
ンバー、5はスチームは通過できるが、予備発泡粒子は
通過できないように両割型1a,1bに穿設されている
多数の孔、6は割型1b側に穿設した成形材料の充填口
、7は該充填口6に装着した充填ガンで、送気管8によ
り供給される圧縮空気によって予備発泡粒子をキャビテ
ィ2内に充填できる機能を有している。9はホッパー(
図示せず)側に連なる材料供給管、10は上記充填口6
を開閉するピストンである。
[Example] First, an example of a mold used for carrying out the method of the present invention will be explained with reference to the drawings. In Figure 1, 1
1 is a mold that can change the volume of the cavity 2, and is formed by a split mold 1a and a split mold 1b that can be freely moved into and out of contact. 3 is double split type 1
This is the contact surface (parting line) between a and 1b. 4 is a chamber for introducing heating fluid (steam) and cooling fluid (water); 5 is a large number of holes drilled in the split molds 1a and 1b so that steam can pass through but not pre-foamed particles; Reference numeral 6 indicates a filling port for molding material formed on the side of the split mold 1b, and 7 indicates a filling gun attached to the filling port 6, which has a function of filling pre-expanded particles into the cavity 2 using compressed air supplied from an air supply pipe 8. have. 9 is the hopper (
(not shown) side, a material supply pipe 10 is the above-mentioned filling port 6
It is a piston that opens and closes the

【0011】次ぎに、上記金型1を使用しての本発明方
法を説明する。予備発泡粒子を、割型1aと割型1bの
接触面3が1mm離れている状態の金型1のキャビティ
2内に充填ガン7を用いて充填し、充填口6を閉じた後
で、圧力が0.5〜5kg/cm2Gのスチームを割型
1bのチャンバー4内に5〜10秒間導入し、粒子間に
存在する空気をできるかぎり除去した後、割型1aと1
bを接触させ、次いで、両割型1a,1bのチャンバー
4内に同圧のスチームを約20〜100秒間導入して上
記粒子群を加熱し、膨脹させると共に粒子相互を融着さ
せる。この際、粒子の融着は隙間がない完全な密着状態
でなく、次の加熱工程で加熱のためのスチームが通過で
きるような空隙を5〜30%残しておく必要がある。
Next, the method of the present invention using the mold 1 described above will be explained. The pre-expanded particles are filled into the cavity 2 of the mold 1 with the contact surfaces 3 of the split molds 1a and 1b separated by 1 mm using the filling gun 7, and after the filling port 6 is closed, the pressure is Steam of 0.5 to 5 kg/cm2G is introduced into the chamber 4 of the split mold 1b for 5 to 10 seconds to remove as much air as possible between the particles, and then the split molds 1a and 1
Then, steam of the same pressure is introduced into the chambers 4 of the two split molds 1a and 1b for about 20 to 100 seconds to heat and expand the particles and fuse the particles together. At this time, the particles are not completely adhered to each other with no gaps, but it is necessary to leave 5 to 30% of voids through which steam for heating can pass in the next heating step.

【0012】次いで、金型1を開いてキャビティ2の容
積を1.1〜2倍に増大させ、かつ、チャンバー4内に
スチームを導入して発泡体を膨脹ささせた後(図2を参
照)、冷却水を約30秒間チャンバー4内に導いて該発
泡成形体を冷却し、その後で金型1を開き成形品を得る
。この成形品fの断面は、図3に示すように金型1を開
いた方向(矢印)の気泡径がその直角方向の径よりも大
であり、この方向に対する圧縮強度がこれの直角方向の
圧縮強度より大となる。この場合、型開きによるキャビ
ティ2の容積増大が1.1倍より低いと、得られる発泡
成形体は圧縮強度の向上が見られず、また、2倍を越す
と、表面が平滑な成形品(金型のキャビティ形状に忠実
な成形品)を得ることはできない。
Next, the mold 1 is opened to increase the volume of the cavity 2 by 1.1 to 2 times, and steam is introduced into the chamber 4 to expand the foam (see FIG. 2). ), cooling water is introduced into the chamber 4 for about 30 seconds to cool the foamed molded product, and then the mold 1 is opened to obtain a molded product. In the cross section of this molded product f, as shown in Fig. 3, the bubble diameter in the direction (arrow) in which the mold 1 is opened is larger than the diameter in the direction perpendicular to it, and the compressive strength in this direction is It is greater than the compressive strength. In this case, if the volume increase of the cavity 2 due to mold opening is less than 1.1 times, the compressive strength of the obtained foamed molded product will not improve, and if it exceeds 2 times, the molded product with a smooth surface ( It is not possible to obtain a molded product that is faithful to the shape of the mold cavity.

【0013】実施例1 図1に示す金型1を用い、このキャビティ2(縦が50
0mm、横が500mm、高さが200mm)内にポリ
スチレン予備発泡粒子〔三菱油化バーデイツシエ株式会
社製のJF−151(商品名)、嵩密度が0.03g/
cm3〕を充填し、次いで、0.6kg/cm2Gのス
チームを5秒間キャビティ2内に導入して脱気した後、
同圧のスチームを20秒間導入して空隙率が約10%の
発泡体を得た(第1工程)。そして、この発泡体を冷却
することなく、80℃以上の温度であるうちに金型1を
30%開き(型開き速度は68m/秒)、0.6kg/
cm2Gのスチームを15秒間導入し、発泡を完全にさ
せてキャビティ形状に忠実な発泡成形体(縦が500m
m、横が500mm、高さが260mm)とし(第2工
程)、次いで、チャンバー4内に20℃の水を15秒間
導入し、更に5分間放冷した後で型開きし、密度が約0
.023g/cm3の表面が平滑な成形品(金型のキャ
ビティ形状に忠実な型内ビーズ発泡成形体)を得た。 この発泡成形体の高さ方向の5%ひずみ時の圧縮強度は
2.04kg/cm2で、これと直角の方向の5%ひず
み時の圧縮強度は1.45kg/cm2であった。
Example 1 Using the mold 1 shown in FIG.
Pre-expanded polystyrene particles [JF-151 (trade name) manufactured by Mitsubishi Yuka Verdice Co., Ltd., bulk density 0.03 g/
cm3], and then 0.6 kg/cm2G of steam was introduced into the cavity 2 for 5 seconds to degas it.
Steam of the same pressure was introduced for 20 seconds to obtain a foam with a porosity of about 10% (first step). Then, without cooling this foam, the mold 1 was opened by 30% while the temperature was 80°C or higher (mold opening speed was 68 m/sec), and the mold 1 was opened at 0.6 kg/sec.
Steam of cm2G was introduced for 15 seconds to complete foaming, resulting in a foamed molded product that was faithful to the cavity shape (length: 500m).
m, width 500 mm, height 260 mm) (second step), then 20°C water was introduced into the chamber 4 for 15 seconds, and after cooling for another 5 minutes, the mold was opened and the density was about 0.
.. A molded product (in-mold bead foamed molded product faithful to the shape of the mold cavity) with a weight of 0.023 g/cm3 and a smooth surface was obtained. The compressive strength of this foam molded article at 5% strain in the height direction was 2.04 kg/cm2, and the compressive strength at 5% strain in the direction perpendicular to this was 1.45 kg/cm2.

【0014】比較例1 図1に示す金型1を用い、この金型1のキャビティ2(
縦が500mm、横が500mm、高さが200mm)
内にポリスチレン予備発泡粒子〔三菱油化バーデイツシ
エ株式会社製のJF−151(商品名)、嵩密度が0.
03g/cm3〕を充填し、次いで、0.6kg/cm
2Gのスチームを5秒間キャビティ2内に導入して脱気
した後、同圧のスチームを35秒間導入した。次いで、
チャンバー4内に20℃の水を15秒間導入し、更に5
分間放冷した後で型開きし、密度が約0.03g/cm
3の型内ビーズ発泡成形体(縦が500mm、横が50
0mm、高さが200mm)を得た。この発泡成形体の
高さ方向の5%ひずみ時の圧縮強度は2.40kg/c
m2で、これと直角の方向の5%ひずみ時の圧縮強度は
2.37kg/cm2でった。
Comparative Example 1 Using the mold 1 shown in FIG. 1, the cavity 2 of this mold 1 (
(length: 500mm, width: 500mm, height: 200mm)
Pre-expanded polystyrene particles [JF-151 (trade name) manufactured by Mitsubishi Yuka Verdice Co., Ltd., with a bulk density of 0.
03g/cm3], then 0.6kg/cm
After 2G of steam was introduced into the cavity 2 for 5 seconds to degas it, steam of the same pressure was introduced for 35 seconds. Then,
Water at 20°C was introduced into chamber 4 for 15 seconds, and then
After cooling for a minute, the mold is opened and the density is approximately 0.03g/cm.
3 in-mold bead foam molded product (length: 500 mm, width: 50 mm)
0 mm and a height of 200 mm). The compressive strength of this foam molded product at 5% strain in the height direction is 2.40 kg/c
m2, the compressive strength at 5% strain in the direction perpendicular to this was 2.37 kg/cm2.

【0015】実施例2〜3及び比較例2〜3嵩密度の異
なる予備発泡粒子を用いる他は実施例1.比較例1とそ
れぞれ同様に製造して表1に示すような発泡成形体を得
た。
Examples 2-3 and Comparative Examples 2-3 Example 1 except that pre-expanded particles having different bulk densities were used. The foamed molded products shown in Table 1 were produced in the same manner as in Comparative Example 1.

【0016】実施例4 前記実施例1において金型を30%開く代わリに60%
と変更する他は同様に製造して、金型のキャビティ形状
に忠実な発泡成形体(表1を参照)を得た。
Example 4 Instead of opening the mold by 30% in Example 1, the mold was opened by 60%.
A foamed molded article (see Table 1) faithful to the mold cavity shape was obtained by manufacturing in the same manner except for the following changes.

【0017】[0017]

【表1】[Table 1]

【0018】上記表1に示すように、本発明の製造方法
により得られる型内ビーズ発泡成形品の型開きした方向
の圧縮強度は通常品(比較例)に比べると、約30〜4
0%向上していることが理解できる。
As shown in Table 1 above, the compressive strength in the mold opening direction of the in-mold bead foam molded product obtained by the manufacturing method of the present invention is about 30 to 4
It can be seen that there is an improvement of 0%.

【0019】[0019]

【発明の効果】本発明は上記の如くであって、同一素材
であって、密度が同じ発泡体であっても、圧縮強度のよ
り高い型内ビーズ発泡成形品を製造でき、材料の節約が
可能で大巾にコストダウンできることと相俟って、その
経済的効果は多大である。
[Effects of the Invention] The present invention is as described above, and even if the foams are made of the same material and have the same density, an in-mold bead foam molded product with higher compressive strength can be manufactured, and material can be saved. Coupled with the fact that it is possible and the cost can be drastically reduced, the economic effect is enormous.

【図面の簡単な説明】[Brief explanation of the drawing]

【図1】  本発明製造方法の実施に用いる金型の断面
図であって、予備発泡粒子を充填した時の初期成形段階
を示す図である。
FIG. 1 is a cross-sectional view of a mold used for implementing the manufacturing method of the present invention, showing an initial molding stage when filled with pre-expanded particles.

【図2】  終期成形段階における金型の断面図である
FIG. 2 is a cross-sectional view of the mold at the final molding stage.

【図3】  成形品の一部拡大断面図である。FIG. 3 is a partially enlarged sectional view of the molded product.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】  予備発泡粒子をキャビティの容積変化
が可能な金型内に充填し、この粒子群を加熱発泡させて
互いに融着させながら、又は融着させて該粒子間の隙間
が残っている発泡体を得た後、上記金型の一方の割型或
いは双方の割型を移動させることにより上記金型のキャ
ビティ内の容積をl.1〜2倍に増大させて、このキャ
ビティ内で上記発泡体を加熱膨脹させることにより、該
キャビティの形状に忠実な発泡成形体を形成し、次いで
、この発泡成形体を冷却することを特徴とする型内ビー
ズ発泡成形品の製造方法。
Claim 1: Pre-expanded particles are filled into a mold that can change the volume of the cavity, and the particles are heated and foamed to fuse each other, or are fused so that no gaps remain between the particles. After obtaining the foam, the volume inside the cavity of the mold is reduced to l. by moving one or both of the mold halves. The foam is increased by 1 to 2 times and heated and expanded in this cavity to form a foamed molded product that is faithful to the shape of the cavity, and then this foamed molded product is cooled. A method for manufacturing an in-mold bead foam molded product.
JP3111246A 1991-02-21 1991-02-21 Method for producing bead-in-mold molded product Expired - Fee Related JP2785076B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3111246A JP2785076B2 (en) 1991-02-21 1991-02-21 Method for producing bead-in-mold molded product

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3111246A JP2785076B2 (en) 1991-02-21 1991-02-21 Method for producing bead-in-mold molded product

Publications (2)

Publication Number Publication Date
JPH04267135A true JPH04267135A (en) 1992-09-22
JP2785076B2 JP2785076B2 (en) 1998-08-13

Family

ID=14556299

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3111246A Expired - Fee Related JP2785076B2 (en) 1991-02-21 1991-02-21 Method for producing bead-in-mold molded product

Country Status (1)

Country Link
JP (1) JP2785076B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102020113838A1 (en) 2020-05-22 2021-11-25 Siegfried Hofmann Gmbh Molding tool for processing expandable or expanded plastic particles

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102020113838A1 (en) 2020-05-22 2021-11-25 Siegfried Hofmann Gmbh Molding tool for processing expandable or expanded plastic particles

Also Published As

Publication number Publication date
JP2785076B2 (en) 1998-08-13

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