JPH04247804A - Injecting parts for die casting machine - Google Patents

Injecting parts for die casting machine

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Publication number
JPH04247804A
JPH04247804A JP3025408A JP2540891A JPH04247804A JP H04247804 A JPH04247804 A JP H04247804A JP 3025408 A JP3025408 A JP 3025408A JP 2540891 A JP2540891 A JP 2540891A JP H04247804 A JPH04247804 A JP H04247804A
Authority
JP
Japan
Prior art keywords
powder
composite material
casting machine
alloy powder
die casting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP3025408A
Other languages
Japanese (ja)
Other versions
JPH0784601B2 (en
Inventor
Tomomi Soeda
知美 副田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TYK Corp
Original Assignee
TYK Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TYK Corp filed Critical TYK Corp
Priority to JP3025408A priority Critical patent/JPH0784601B2/en
Priority to DE4201781A priority patent/DE4201781C2/en
Priority to GB9201411A priority patent/GB2253213B/en
Priority to KR1019920000912A priority patent/KR960006046B1/en
Priority to FR9200789A priority patent/FR2672056B1/en
Priority to CA002060028A priority patent/CA2060028C/en
Publication of JPH04247804A publication Critical patent/JPH04247804A/en
Publication of JPH0784601B2 publication Critical patent/JPH0784601B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Abstract

PURPOSE:To provide injecting parts for a die casting machine having superior erosion resistance to a molten nonferrous metal, superior heat retaining property, shock and wear resistances and ensuring a long service life and high work efficiency. CONSTITUTION:At least a portion of the part of injecting parts for a die casting machine brought into contact with a molten metal is formed with a composite material obtd. by sintering a blend of 0.1-50vol.% Mo or Mo alloy powder or granules with Ti or Ti alloy powder or granules and ceramic powder or granules.

Description

【発明の詳細な説明】[Detailed description of the invention]

【0001】0001

【産業上の利用分野】本発明は耐溶損性及び耐衝撃性が
優れており、アルミニウム、亜鉛、スズ及び鉛等の非鉄
金属(その合金も含む)の鋳造に好適のダイカストマシ
ン用射出部品に関する。
[Field of Industrial Application] The present invention relates to an injection part for a die casting machine which has excellent corrosion resistance and impact resistance and is suitable for casting nonferrous metals (including alloys thereof) such as aluminum, zinc, tin, and lead. .

【0002】0002

【従来の技術】近時、アルミニウム等の非鉄金属を高精
度且つ高速度で鋳造できるダイカスト技術は、自動車、
産業機械及び家電機器等の分野において、各種部品の重
要な鋳造手段となっている。
[Prior Art] In recent years, die-casting technology that allows non-ferrous metals such as aluminum to be cast with high precision and high speed has become popular in automobiles,
It is an important casting method for various parts in the fields of industrial machinery and home appliances.

【0003】従来、ダイカストマシン用射出部品にはJ
IS  SKD61の熱間ダイス鋼等が使用されている
。 また、近年、セラミックス製部材を焼きばめ又は鋳ぐる
みすることにより、溶湯と接触する部分にセラミックス
を配置したスリーブ及びプランジャー等のダイカストマ
シン用射出部品も使用されている。
Conventionally, injection parts for die-casting machines include J.
IS SKD61 hot die steel etc. are used. Furthermore, in recent years, injection parts for die-casting machines, such as sleeves and plungers, have been used, such as sleeves and plungers, in which ceramic members are shrink-fitted or cast-inserted, and ceramics are placed in the portions that come into contact with the molten metal.

【0004】0004

【発明が解決しようとする課題】しかしながら、上述し
た従来のダイカストマシン用射出部品には以下に示す問
題点がある。
However, the above-described conventional injection parts for die casting machines have the following problems.

【0005】先ず、ダイス鋼を使用した射出部品におい
ては、一般的に非鉄金属は鉄と反応しやすいという性質
があるため、ダイカストマシンの溶湯と接触する部分で
は著しい溶損が発生する。このため、射出部品を頻繁に
交換する必要があり、寿命が短い。また、鋼は熱伝導性
が高いため、射出部品内に注入された溶湯の温度が低下
しやすく、これにより鋳造品の製造歩留りが著しく低下
する。
First, in injection parts using die steel, nonferrous metals generally tend to react easily with iron, so significant melting loss occurs in the parts that come into contact with the molten metal of the die casting machine. Therefore, the injection parts must be replaced frequently and have a short lifespan. Further, since steel has high thermal conductivity, the temperature of the molten metal injected into the injection part tends to drop, which significantly reduces the manufacturing yield of the cast product.

【0006】一方、セラミックスを溶湯接触部に配置し
た射出部品においては、耐溶損性は優れているものの、
ダイカストマシンが溶湯を射出する瞬間に射出部品に極
めて大きな衝撃が加えられるため、本来脆い材質である
セラミックス部分が破壊されることがある。そうすると
、作業を中断する必要があり、作業性が悪い。
On the other hand, injection parts in which ceramics are placed in the molten metal contact area have excellent corrosion resistance, but
The moment a die-casting machine injects molten metal, an extremely large impact is applied to the injected part, which can break the ceramic part, which is an inherently brittle material. In this case, it is necessary to interrupt the work, resulting in poor work efficiency.

【0007】本発明はかかる問題点に鑑みてなされたも
のであって、非鉄金属の溶湯に対する耐溶損性、耐衝撃
性、保温性及び耐摩耗性が優れており、長寿命であって
作業性が良好なダイカストマシン用射出部品を提供する
ことを目的とする。
The present invention has been made in view of the above problems, and has excellent corrosion resistance to molten nonferrous metals, impact resistance, heat retention, and abrasion resistance, long life, and workability. The purpose is to provide injection parts for die casting machines with good quality.

【0008】[0008]

【課題を解決するための手段】本発明に係るダイカスト
マシン用射出部品は、Mo又はMo合金の粉粒体、チタ
ン又はチタン合金の粉粒体及びセラミックス粉粒体を配
合し焼結させて得た複合材料により、溶湯と接触する部
分の少なくとも一部が形成されており、前記Mo又はM
o合金の粉粒体は0.1乃至50体積%配合してあるこ
とを特徴とする。
[Means for Solving the Problems] An injection part for a die casting machine according to the present invention is obtained by blending and sintering Mo or Mo alloy powder, titanium or titanium alloy powder, and ceramic powder. At least a part of the part that comes into contact with the molten metal is formed of the Mo or M composite material.
It is characterized in that the O alloy powder and granules are blended in an amount of 0.1 to 50% by volume.

【0009】[0009]

【作用】本発明においては、溶湯と接触する部分の少な
くとも一部が所定量のMo(モリブデン)又はMo合金
の粉粒体と、チタン又はチタン合金の粉粒体と、セラミ
ックス粉粒体とから作られた複合材料により形成されて
いる。この複合材料は、非鉄金属の溶湯に対して優れた
耐溶損性を有すると共に耐衝撃性にも優れたチタン又は
チタン合金に、高強度且つ高硬度のセラミックス粒子を
添加したものであり、耐溶損性、耐衝撃性及び耐摩耗性
を兼備している。また、この複合材料は熱伝導性が鋼に
比して低く、溶湯保温性が優れている。従って、この複
合材料で溶湯接触部を形成することにより、長寿命であ
って作業性が優れたダイカストマシン用射出部品が得ら
れる。
[Operation] In the present invention, at least a part of the part that comes into contact with the molten metal is made of a predetermined amount of Mo (molybdenum) or Mo alloy powder, titanium or titanium alloy powder, and ceramic powder. It is made of composite material. This composite material is made by adding ceramic particles with high strength and hardness to titanium or titanium alloy, which has excellent corrosion resistance against molten nonferrous metals and has excellent impact resistance. It has excellent strength, impact resistance, and abrasion resistance. Furthermore, this composite material has lower thermal conductivity than steel and has excellent heat retention of molten metal. Therefore, by forming the molten metal contact portion with this composite material, an injection part for a die-casting machine with a long life and excellent workability can be obtained.

【0010】次に、この複合材料の各成分の添加理由及
び組成限定理由について説明する。
Next, the reasons for adding each component of this composite material and the reasons for limiting the composition will be explained.

【0011】Mo Moは金属チタン又はチタン合金からなるマトリックス
とセラミックス粒子との間の濡れ性を改善し、両者の接
合性を向上させる効果があるので、Moを複合材料中に
添加することにより複合材料の耐衝撃性を向上させるこ
とができる。このMoは、複合材料の原料粉末中にMo
粉粒体として添加してもよいし、Ti−Mo合金の粉粒
体として複合材料中にMoを含有させてもよい。Ti−
Mo合金の粉粒体として添加する場合は、以下に示すよ
うな3つの態様が考えられる。 ■Ti−Mo合金の粉粒体+Mo粉粒体+セラミックス
粉粒体 ■Ti−Mo合金の粉粒体+セラミックス粉粒体■Ti
−Mo合金の粉粒体+Ti粉粒体+セラミックス粉粒体 上記■〜■のいずれの場合も、複合材料中におけるMo
の含有量は、Mo又はMo合金の粉粒体の配合比で0.
1体積%以上であることが必要である。Moの含有量が
0.1体積%未満である場合は、上述の濡れ性を改善す
る効果が得られない。このため、複合材料の製造時にお
いて原料粉末の焼結が不十分になり、複合材料の硬度及
び伸びが低くなる。一方、Moの含有量が50体積%を
超えると、MoとTiとの間の金属間化合物が必要量以
上に析出し、複合材料が脆性化する。このため、複合材
料中のMoの含有量はMo又はMo合金の粉粒体の配合
比で0.1乃至50体積%とする。
[0011] Mo Mo has the effect of improving the wettability between the matrix made of metallic titanium or titanium alloy and the ceramic particles, and improving the bonding properties between the two, so by adding Mo to the composite material, The impact resistance of the material can be improved. This Mo is contained in the raw material powder of the composite material.
Mo may be added as a powder or granule, or may be contained in the composite material as a Ti-Mo alloy powder. Ti-
When adding Mo alloy as a powder or granule, the following three modes are possible. ■Ti-Mo alloy powder + Mo powder + ceramic powder ■Ti-Mo alloy powder + ceramic powder ■Ti
- Mo alloy powder + Ti powder + ceramic powder In any of the above cases, the amount of Mo in the composite material is
The content of Mo or Mo alloy powder is 0.
It is necessary that the content is 1% by volume or more. If the content of Mo is less than 0.1% by volume, the above-mentioned effect of improving wettability cannot be obtained. For this reason, the raw material powder is insufficiently sintered during the production of the composite material, resulting in low hardness and elongation of the composite material. On the other hand, if the Mo content exceeds 50% by volume, intermetallic compounds between Mo and Ti will precipitate in excess of the required amount, making the composite material brittle. Therefore, the Mo content in the composite material is set to 0.1 to 50% by volume in terms of the blending ratio of Mo or Mo alloy powder.

【0012】なお、Mo又はMo合金の粉粒体及びTi
又はTi合金の粉粒体には不可避的に含まれる不純物が
存在する場合があることはいうまでもない。
[0012] In addition, Mo or Mo alloy powder and Ti
It goes without saying that there may be impurities that are unavoidably included in the Ti alloy powder.

【0013】セラミックス粉粒体 複合材料中のセラミックス粉粒体の体積含有率が0.1
%未満の場合、複合材料の硬度及び耐摩耗性は極めて低
いものとなる。一方、セラミックス粉粒体の体積含有率
が50%を超えると、複合材料が脆性化するため、耐衝
撃性が低下し、割れやすくなる。このため、複合材料中
のセラミックス粉粒体の体積含有率は0.1乃至50%
であることが好ましい。
[0013] The volume content of the ceramic powder in the ceramic powder composite material is 0.1.
%, the hardness and wear resistance of the composite material will be extremely low. On the other hand, if the volume content of the ceramic powder exceeds 50%, the composite material becomes brittle, resulting in a decrease in impact resistance and a tendency to break. Therefore, the volume content of ceramic powder in the composite material is 0.1 to 50%.
It is preferable that

【0014】[0014]

【実施例】次に、本発明の実施例についてその比較例と
比較して説明する。
EXAMPLES Next, examples of the present invention will be explained in comparison with comparative examples thereof.

【0015】先ず、平均粒径が20μmであるチタン(
Ti)粉末と、平均粒径が5μmである炭化けい素(S
iC)粉末とを5:1の体積比で混合した。そして、こ
の混合粉体に下記表1に示す割合で、平均粒径が15μ
mのMo粉末を均一に混合して原料とした。
First, titanium (
Ti) powder and silicon carbide (S) with an average particle size of 5 μm.
iC) powder at a volume ratio of 5:1. Add to this mixed powder the proportions shown in Table 1 below so that the average particle size is 15 μm.
A raw material was prepared by uniformly mixing 5 m of Mo powder.

【0016】[0016]

【表1】[Table 1]

【0017】この原料をゴム型に密封し、加圧力が1ト
ン/cm2 の条件で冷間静水圧プレス( CIP) 
加工を行って、筒状の圧粉体を得た。そして、真空度が
10−5Torr、温度が1350℃の真空炉中でこの
圧粉体を焼結させた後、この焼結体を施盤加工すること
により、複合材料からなるコールドチャンバ用スリーブ
を製作した。この各スリーブを実施例1乃至3及び比較
例1乃至3とした。
[0017] This raw material was sealed in a rubber mold and cold isostatically pressed (CIP) at a pressure of 1 ton/cm2.
Processing was performed to obtain a cylindrical green compact. After sintering this green compact in a vacuum furnace with a vacuum degree of 10-5 Torr and a temperature of 1350°C, the sintered body is lathed to produce a sleeve for a cold chamber made of a composite material. did. These sleeves were designated as Examples 1 to 3 and Comparative Examples 1 to 3.

【0018】次に、15体積%のMoを含有し、残部が
チタン及び不可避的不純物からなり、平均粒径が45μ
mであるチタン合金粉末と、平均粒径が10μmである
炭化タングステン(WC)粉末とを下記表2に示す割合
で均一に混合して原料とした。
Next, it contains 15% by volume of Mo, the remainder consists of titanium and unavoidable impurities, and has an average particle size of 45 μm.
A raw material was prepared by uniformly mixing a titanium alloy powder having a particle diameter of 100 m and a tungsten carbide (WC) powder having an average particle size of 10 μm in the proportions shown in Table 2 below.

【0019】[0019]

【表2】[Table 2]

【0020】この原料を、上述の実施例1乃至3及び比
較例1乃至3と同様に、冷間静水圧プレス加工した後、
真空中で焼結させ、この焼結体を旋盤加工することによ
り、筒状の複合材料を得た。この複合材料を従来のコー
ルドチャンバ用スリーブ(材質;SKD61)の内面に
焼きばめすることにより、溶湯と接触する部分に前記複
合材料が配置されたコールドチャンバ用スリーブを製作
した。これらのスリーブを実施例4乃至7及び比較例4
乃至6とした。
After this raw material was subjected to cold isostatic pressing in the same manner as in Examples 1 to 3 and Comparative Examples 1 to 3,
A cylindrical composite material was obtained by sintering in vacuum and lathing the sintered body. By shrink-fitting this composite material to the inner surface of a conventional sleeve for a cold chamber (material: SKD61), a sleeve for a cold chamber in which the composite material was disposed in the portion that contacts the molten metal was manufactured. These sleeves were used in Examples 4 to 7 and Comparative Example 4.
It was set as 6 to 6.

【0021】また、従来から使用されている熱間ダイス
鋼(SKD61)製のコールドチャンバ用スリーブを従
来例1とし、内面にセラミックス(窒化けい素)を焼き
ばめしたコールドチャンバ用スリーブを従来例2とした
[0021] In addition, conventional example 1 is a sleeve for a cold chamber made of hot die steel (SKD61) that has been used conventionally, and a sleeve for a cold chamber whose inner surface is shrink-fitted with ceramics (silicon nitride) is a conventional example. It was set as 2.

【0022】上述した実施例、比較例及び従来例の各ス
リーブに対し、下記に示す試験を行ってその性能を調べ
た。 ■硬度試験 スリーブ内面のマイクロビッカース硬度を測定した。 ■引張試験 スリーブ内面の部材の伸びを測定した。 ■実用試験 コールドチャンバ用ダイカストマシン(能力;250ト
ン)にスリーブを取り付けて実際にアルミニウム合金(
ADC12)溶湯から自動車用エンジンカバーを鋳造し
た。そして、10000回ショットした後にスリーブを
取り外し、溶損状況を調べた。
The following tests were conducted on the sleeves of the above-mentioned Examples, Comparative Examples, and Conventional Examples to examine their performance. ■Hardness test The micro Vickers hardness of the inner surface of the sleeve was measured. ■Tensile test The elongation of the inner surface of the sleeve was measured. ■Practical test A sleeve was attached to a cold chamber die-casting machine (capacity: 250 tons) and an aluminum alloy (
ADC12) An automobile engine cover was cast from molten metal. After 10,000 shots, the sleeve was removed and the state of melting and damage was examined.

【0023】これらの試験結果を下記表3及び表4に示
す。但し、溶損状況は使用前の寸法に対するスリーブ内
面の最大溶損量が0.1mm以下である場合を◎で示し
、0.1mmを超え0.3mm以下である場合を○で示
し、0.3mmを超える場合を△で示した。
The results of these tests are shown in Tables 3 and 4 below. However, regarding the state of melting loss, cases where the maximum amount of melting loss on the inner surface of the sleeve relative to the dimensions before use is 0.1 mm or less are indicated by ◎, cases where it exceeds 0.1 mm and 0.3 mm or less are indicated by ○, and 0. Cases exceeding 3 mm are indicated by △.

【0024】[0024]

【表3】[Table 3]

【0025】[0025]

【表4】[Table 4]

【0026】この表3及び表4から明らかなように、実
施例1乃至7に係るスリーブはいずれも内面の硬度が高
く耐摩耗性が優れていると共に、伸びが大きく耐衝撃性
が優れていた。また、実施例1乃至7に係るスリーブは
10000回ショットした後にも殆ど溶損されておらず
、割れも発生しなかった。
As is clear from Tables 3 and 4, the sleeves according to Examples 1 to 7 all had high inner hardness and excellent wear resistance, as well as high elongation and excellent impact resistance. . In addition, the sleeves according to Examples 1 to 7 were hardly eroded and damaged even after being shot 10,000 times, and no cracks occurred.

【0027】一方、比較例2,3,6及び従来例2は伸
びが0.8%以下と極めて低く、割れが発生した。また
、その他の比較例1,4,5及び従来例1はいずれも溶
損量が0.1mmを超えており、耐溶損性が悪いもので
あった。
On the other hand, in Comparative Examples 2, 3, and 6 and Conventional Example 2, the elongation was extremely low at 0.8% or less, and cracks occurred. Further, in other Comparative Examples 1, 4, and 5 and Conventional Example 1, the amount of erosion loss exceeded 0.1 mm, and the erosion resistance was poor.

【0028】なお、本発明において使用可能なセラミッ
クスは上述のSiC及びWCに限定されるものではなく
、Cr2 O3 、TiO2 、ZrO2 、MgO及
びY2 O3 等の酸化物系セラミックス、Si3 N
4 、TiN、BN及びAlN等の窒化物系セラミック
ス、TiC、B4 C及びCrC2等の炭化物系セラミ
ックス、ZrB2 及びTiB2 等のホウ化物系セラ
ミックス並びにサイアロン等、種々のものを使用するこ
とができる。また、これらのセラミックスを2種類以上
混合して使用することもできる。
The ceramics that can be used in the present invention are not limited to the above-mentioned SiC and WC, but also include oxide ceramics such as Cr2O3, TiO2, ZrO2, MgO and Y2O3, and Si3N.
4, nitride ceramics such as TiN, BN, and AlN, carbide ceramics such as TiC, B4C, and CrC2, boride ceramics such as ZrB2 and TiB2, and sialon can be used. Moreover, two or more types of these ceramics can be mixed and used.

【0029】また、上述の実施例はコールドチャンバ用
スリーブについてのものであるが、この外、コールドチ
ャンバ用プランジャーチップ及びスリーブブッシュ、ホ
ットチャンバ用スリーブ、プランジャーリング、プラン
ジャーチップ及びノズル並びに溶湯輸送管等のダイカス
トマシン用射出部品についても、Mo又はMo合金の粉
粒体とチタン又はチタン合金の粉粒体とセラミックス粉
粒体とから作られた複合材料により形成することができ
る。
[0029]Although the above-mentioned embodiments relate to sleeves for cold chambers, in addition to these, plunger tips and sleeve bushes for cold chambers, sleeves for hot chambers, plunger rings, plunger tips and nozzles, and molten metal Injection parts for die casting machines such as transport pipes can also be formed from a composite material made from Mo or Mo alloy powder, titanium or titanium alloy powder, and ceramic powder.

【0030】[0030]

【発明の効果】以上説明したように本発明に係るダイカ
ストマシン用射出部品は、溶湯と接触する部分の少なく
とも一部が所定量のMo又はMo合金の粉粒体とチタン
又はチタン合金の粉粒体とセラミックス粉粒体とから作
られた複合材料により形成されているから、これらの部
品の溶損及び摩耗を極めて低く抑制できる。また、耐衝
撃性も優れており、部品の割れを回避できるから、連続
して作業を行うことが可能であり、作業性が優れている
As explained above, in the injection part for a die casting machine according to the present invention, at least a part of the part that comes into contact with the molten metal contains a predetermined amount of Mo or Mo alloy powder and granules of titanium or titanium alloy. Since it is made of a composite material made from a ceramic body and ceramic powder, it is possible to suppress erosion and wear of these parts to an extremely low level. In addition, it has excellent impact resistance and can avoid cracking of parts, allowing continuous work and excellent workability.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】  Mo又はMo合金の粉粒体、チタン又
はチタン合金の粉粒体及びセラミックス粉粒体を配合し
焼結させて得た複合材料により、溶湯と接触する部分の
少なくとも一部が形成されており、前記Mo又はMo合
金の粉粒体は0.1乃至50体積%配合してあることを
特徴とするダイカストマシン用射出部品。
Claim 1: A composite material obtained by blending and sintering Mo or Mo alloy powder, titanium or titanium alloy powder, and ceramic powder allows at least a portion of the part that comes into contact with the molten metal to An injection part for a die-casting machine, characterized in that the Mo or Mo alloy powder and granules are blended in an amount of 0.1 to 50% by volume.
【請求項2】  前記セラミックス粉粒体の体積含有率
が0.1乃至50%であることを特徴とする請求項1に
記載のダイカストマシン用射出部品。
2. The injection part for a die casting machine according to claim 1, wherein the volume content of the ceramic powder is 0.1 to 50%.
JP3025408A 1991-01-24 1991-01-24 Injection parts for die casting machine Expired - Lifetime JPH0784601B2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP3025408A JPH0784601B2 (en) 1991-01-24 1991-01-24 Injection parts for die casting machine
DE4201781A DE4201781C2 (en) 1991-01-24 1992-01-23 Injection part for a die casting machine
GB9201411A GB2253213B (en) 1991-01-24 1992-01-23 Injection part for die-casting machines
KR1019920000912A KR960006046B1 (en) 1991-01-24 1992-01-23 Injection part for die-casting machines
FR9200789A FR2672056B1 (en) 1991-01-24 1992-01-24 INJECTION MEMBER FOR PRESSURE CASTING MACHINES.
CA002060028A CA2060028C (en) 1991-01-24 1992-01-24 Injection part for die-casting machines

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3025408A JPH0784601B2 (en) 1991-01-24 1991-01-24 Injection parts for die casting machine

Publications (2)

Publication Number Publication Date
JPH04247804A true JPH04247804A (en) 1992-09-03
JPH0784601B2 JPH0784601B2 (en) 1995-09-13

Family

ID=12165092

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3025408A Expired - Lifetime JPH0784601B2 (en) 1991-01-24 1991-01-24 Injection parts for die casting machine

Country Status (1)

Country Link
JP (1) JPH0784601B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08197220A (en) * 1995-01-23 1996-08-06 Tokyo Yogyo Co Ltd Sleeve for die casting machine

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6745754B2 (en) 2017-04-28 2020-08-26 東京窯業株式会社 Metal matrix composite

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02280953A (en) * 1989-04-21 1990-11-16 Tokyo Yogyo Co Ltd Injecting parts for die casting machine

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02280953A (en) * 1989-04-21 1990-11-16 Tokyo Yogyo Co Ltd Injecting parts for die casting machine

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08197220A (en) * 1995-01-23 1996-08-06 Tokyo Yogyo Co Ltd Sleeve for die casting machine

Also Published As

Publication number Publication date
JPH0784601B2 (en) 1995-09-13

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