JPH04238130A - Production of and casting mold for base body for information recording medium - Google Patents

Production of and casting mold for base body for information recording medium

Info

Publication number
JPH04238130A
JPH04238130A JP1917391A JP1917391A JPH04238130A JP H04238130 A JPH04238130 A JP H04238130A JP 1917391 A JP1917391 A JP 1917391A JP 1917391 A JP1917391 A JP 1917391A JP H04238130 A JPH04238130 A JP H04238130A
Authority
JP
Japan
Prior art keywords
mold
casting mold
shape
shape memory
information recording
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1917391A
Other languages
Japanese (ja)
Inventor
Tomoyuki Tamura
知之 田村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Canon Inc
Original Assignee
Canon Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Canon Inc filed Critical Canon Inc
Priority to JP1917391A priority Critical patent/JPH04238130A/en
Publication of JPH04238130A publication Critical patent/JPH04238130A/en
Pending legal-status Critical Current

Links

Landscapes

  • Moulds For Moulding Plastics Or The Like (AREA)
  • Manufacturing Optical Record Carriers (AREA)

Abstract

PURPOSE:To form rugged patterns which are fine and have good accuracy by preventing the generation of foaming when a high-viscosity material is poured into the mold in the casting molding method for the base body of optical disks, etc. CONSTITUTION:The method for (a) pouring the material 4 for substrates into the casting mold 5 having a flat shape memory alloy, etc., and (b) heating the mold to deform the shape memory alloy to the fine rugged shape and to simultaneously cure the material and the casting mold to be used in this method.

Description

【発明の詳細な説明】[Detailed description of the invention]

【0001】0001

【産業上の利用分野】本発明は、情報用ビット、プリフ
ォーマット等の凹凸パターンを有する情報記録媒体用基
体を注型成形法に従って製造する方法、および、その方
法に用いる注型成形型に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing information recording medium substrates having uneven patterns such as information bits and preformats according to a cast molding method, and a cast mold used in the method.

【0002】0002

【従来の技術】従来より、情報記録媒体(特に光学的情
報記録媒体)の製造方法において、情報の書き込み読み
出しの便宜から、あらかじめ基体に一定の間隔で溝(案
内溝)を形成しておくことがよく行われている。そして
、この案内溝部と記録部での反射光量の差を利用すれば
、トラック制御、高速アクセスが可能になる。また、追
記型や書き換え可能型の情報記録媒体においては、あら
かじめ必要な情報をプリフォーマットとして記録するこ
とが行なわれている。
[Background Art] Conventionally, in the manufacturing method of information recording media (particularly optical information recording media), grooves (guide grooves) are formed in advance at regular intervals on a substrate for convenience of writing and reading information. is often done. By utilizing the difference in the amount of reflected light between the guide groove portion and the recording portion, track control and high-speed access become possible. Further, in write-once type and rewritable type information recording media, necessary information is recorded in advance as a preformat.

【0003】この様な情報記録媒体用基体の製造方法の
一つとして、注型成形法がある。この方法は、あらかじ
め型の片側あるいは両側にグルーブが形成されている注
型成形型を用い、この型の中にモノマーまたは溶剤を含
んだプレポリマーを注入し、次いで注入液を硬化させる
ために一定温度まで昇温する成形方法である。
[0003] One of the methods for manufacturing such substrates for information recording media is a cast molding method. This method uses a casting mold with grooves pre-formed on one or both sides of the mold, injects a prepolymer containing monomer or solvent into the mold, and then pours a prepolymer containing a monomer or solvent into the mold. This is a molding method in which the temperature is raised to a certain temperature.

【0004】図2は、従来の注型成形装置を模式的に例
示する断面図である。この成形装置は、スペーサー3を
介して鏡面型1と注型成形型6とが対峙して設けられて
おり、注型成形型6は凹凸形状を一体的に有する。この
中に流動性材料4を注入して硬化させれば、注型成形型
6の凹凸形状に対応する凹凸パターンを有する基体が得
られる。
FIG. 2 is a cross-sectional view schematically illustrating a conventional cast molding apparatus. This molding device is provided with a mirror mold 1 and a casting mold 6 facing each other with a spacer 3 in between, and the casting mold 6 integrally has an uneven shape. By injecting the fluid material 4 into this and curing it, a base body having an uneven pattern corresponding to the uneven shape of the cast mold 6 can be obtained.

【0005】[0005]

【発明が解決しようとする課題】しかしながら従来の注
型成形法においては、粘度の高い流動性材料4を注入す
るとグルーブ部分に気泡が付いてしてしまい、脱気工程
を設けても十分にはこれらを除去できず、基体の凹凸パ
ターンに欠陥が生ずる場合があった。これは、微細かつ
精密なパターン形成が要求される情報記録媒体用基体に
関する特有の課題である。
[Problems to be Solved by the Invention] However, in the conventional cast molding method, when a highly viscous fluid material 4 is injected, air bubbles are formed in the groove part, and even if a degassing step is provided, it is not sufficient. In some cases, these cannot be removed, resulting in defects in the uneven pattern of the substrate. This is a unique problem regarding substrates for information recording media that require fine and precise pattern formation.

【0006】本発明は、この様な課題を解決するために
なされたものであり、その目的は、粘度の高い材料を用
いた場合であっても型のグルーブ部分に気泡が付かず、
微細かつ精密なパターンを有する情報記録媒体用基体を
簡易に製造できる方法、およびこの方法に用いるための
注型成形型を提供することにある。
The present invention was made to solve these problems, and its purpose is to prevent air bubbles from forming in the groove portion of the mold even when a highly viscous material is used.
The object of the present invention is to provide a method for easily manufacturing a substrate for an information recording medium having a fine and precise pattern, and a casting mold for use in this method.

【0007】[0007]

【課題を解決するための手段】本発明は、注型成形によ
り凹凸パターンを有する情報記録媒体用基体を製造する
方法において、該凹凸パターンに対応する形状が記憶さ
れた形状記憶合金または形状記憶樹脂を備える注型成形
型に基板用材料を注入し、加熱することによって該注型
成形型の記憶する形状を具現化する工程を有することを
特徴とする情報記録媒体用基体の製造方法、および、凹
凸パターンを有する情報記録媒体用基体を製造するため
の注型成形型であって、該凹凸パターンに対応する形状
が記憶された形状記憶合金または形状記憶樹脂を備える
ことを特徴とする注型成形型である。
[Means for Solving the Problems] The present invention provides a method for producing a substrate for an information recording medium having a concavo-convex pattern by cast molding, in which a shape-memory alloy or a shape-memory resin is memorized with a shape corresponding to the concavo-convex pattern. A method for producing a substrate for an information recording medium, comprising the step of injecting a substrate material into a casting mold and heating it to embody a shape to be memorized by the casting mold, and A cast molding mold for producing a substrate for an information recording medium having an uneven pattern, the casting mold comprising a shape memory alloy or a shape memory resin in which a shape corresponding to the uneven pattern is memorized. It is a type.

【0008】本発明によれば、流動性材料を注入する時
点では型の形状記憶合金等を気泡が付着し難い形状(平
滑面など)にしておき、注入後の加熱によって記憶する
形状を具現化させるので、気泡の無い状態で良好な成形
が可能となる。
According to the present invention, at the time of injecting the flowable material, the shape memory alloy or the like of the mold is made into a shape that makes it difficult for air bubbles to adhere (such as a smooth surface), and the memorized shape is realized by heating after injection. This allows for good molding without bubbles.

【0009】以下に、本発明の注型成形型を図面を用い
て詳細に説明する。
[0009] Below, the casting mold of the present invention will be explained in detail with reference to the drawings.

【0010】図1は、本発明の注型成形型の一実施態様
を備えた注型成形装置を示す模式的断面図である。注型
成形型5は、形状記憶合金または形状記憶樹脂2を備え
ており、スペーサー3を介して鏡面型1と対峙させて用
いられる。この形状記憶合金等2には、あらかじめ情報
用ビットやプリフォーマット等の必要な凹凸パターンが
記憶されている。そして、注型成形型5は、流動材料4
の注入時は平滑な面形状を有し〔図1(a) 〕、一定
温度に加熱することによって記憶された凹凸形状が具現
化される〔図1(b) 〕。
FIG. 1 is a schematic sectional view showing a cast molding apparatus equipped with an embodiment of the cast mold of the present invention. The casting mold 5 includes a shape memory alloy or a shape memory resin 2, and is used facing the mirror mold 1 with a spacer 3 interposed therebetween. In this shape memory alloy etc. 2, necessary uneven patterns such as information bits and preformats are stored in advance. Then, the casting mold 5 uses the fluid material 4
When injected, it has a smooth surface shape [FIG. 1(a)], and by heating it to a constant temperature, the memorized uneven shape is realized [FIG. 1(b)].

【0011】平滑な形状記憶合金2は、例えば、凹凸形
状を記憶させてから平滑なローラーによって引き伸ばす
等の方法で平滑化したものを用いることができる。
[0011] The smooth shape memory alloy 2 can be made by, for example, memorizing the uneven shape and then smoothing it by a method such as stretching it with a smooth roller.

【0012】形状記憶合金2の材質としては、例えば、
Ti−Ni合金、Cu−Al−X合金(Xはハロゲン原
子を表わす)などを挙げることができる。一方、形状記
憶樹脂2としては、例えば、ポリノルボルネン、トラン
スポリイソプレン、スチレンブタジエン共重合体などを
挙げることができる。
[0012] Examples of the material of the shape memory alloy 2 include:
Examples include Ti-Ni alloy and Cu-Al-X alloy (X represents a halogen atom). On the other hand, examples of the shape memory resin 2 include polynorbornene, transpolyisoprene, and styrene-butadiene copolymer.

【0013】注型成形型5のその他の部位や鏡面型1な
どは、本発明において特に限定は無く、従来より用いら
れる種々のものが使用可能である。また、本発明の注型
成形型は図1に示される態様に限定されず、該凹凸パタ
ーンに対応する形状が記憶された形状記憶合金または形
状記憶樹脂を備える型であればよい。例えば、注型成形
型5の形状記憶合金等2以外の部分(本体)は金属やガ
ラス等で構成し、形状記憶合金等2の変形を妨害しない
様に、本体に部分的に固定または支持して構成すること
ができる。
The other parts of the casting mold 5 and the mirror mold 1 are not particularly limited in the present invention, and various conventionally used parts can be used. Furthermore, the casting mold of the present invention is not limited to the embodiment shown in FIG. 1, but may be any mold that includes a shape memory alloy or shape memory resin in which a shape corresponding to the concavo-convex pattern is memorized. For example, the part (main body) of the casting mold 5 other than the shape memory alloy etc. 2 is made of metal, glass, etc., and is partially fixed or supported by the main body so as not to interfere with the deformation of the shape memory alloy etc. 2. It can be configured as follows.

【0014】次に、本発明の製造方法について詳細に説
明する。
Next, the manufacturing method of the present invention will be explained in detail.

【0015】まず、図1(a) に示す様に、形状記憶
合金等2が平滑面の状態の時に流動性材料4を注入する
。この様に平滑面の状態で注入すれば、液状材料4の粘
度が高くても気泡が付着し難く、注入をスムーズに行な
うことができる。この注入時の温度は形状記憶合金等2
の記憶形状が現われない温度であればよいが、通常は常
温である。
First, as shown in FIG. 1(a), a flowable material 4 is injected into the shape memory alloy 2 when the surface is smooth. If the liquid material 4 is injected with a smooth surface as described above, even if the liquid material 4 has a high viscosity, air bubbles will not easily adhere to it, and the injection can be carried out smoothly. The temperature during this injection is such as shape memory alloy 2
The temperature may be any temperature at which the memorized shape does not appear, but it is usually room temperature.

【0016】また流動性材料4は、情報記録媒体用基体
を構成するための材料を用いればよい。特に、注型成形
法に適するものとして知られる樹脂材料が望ましく、透
明な未硬化の熱硬化性樹脂、熱可塑性樹脂または光硬化
性樹脂など種々のものを用い得る。
[0016] The fluid material 4 may be a material for constructing a substrate for an information recording medium. In particular, resin materials known to be suitable for cast molding are desirable, and various materials such as transparent uncured thermosetting resins, thermoplastic resins, and photocurable resins can be used.

【0017】具体的には、例えば、熱硬化性樹脂として
は、フェノール樹脂、エポキシ樹脂、ポリエステル系樹
脂についてのモノマーやプレポリマー等が挙げられる。 また、熱可塑性樹脂としては、ビニル樹脂、スチレン樹
脂、アクリル樹脂、ポリカーボネート樹脂、酢酸セルロ
ース樹脂、ポリエステル系樹脂についてのモノマーやプ
レポリマー等が挙げられる。また、未硬化の光硬化性樹
脂としては、紫外線硬化型樹脂等が用いられ、例えば、
アクリル樹脂、アリル樹脂、ビニル樹脂、エポキシ樹脂
についてのモノマーやプレポリマー等が挙げられる。
Specifically, examples of thermosetting resins include monomers and prepolymers for phenol resins, epoxy resins, and polyester resins. Examples of thermoplastic resins include monomers and prepolymers for vinyl resins, styrene resins, acrylic resins, polycarbonate resins, cellulose acetate resins, and polyester resins. Further, as the uncured photocurable resin, ultraviolet curable resin etc. are used, for example,
Examples include monomers and prepolymers for acrylic resins, allyl resins, vinyl resins, and epoxy resins.

【0018】本発明の製造方法においては、流動性材料
4が硬化する前に形状記憶合金等2の記憶形状が具現化
する必要がある。従って、より簡易な工程(連続的工程
、加熱手段の単一化)とするためには、形状記憶合金等
2の記憶形状が具現化する温度域を、流動性材料4が硬
化する温度域よりも低く設定すればよい。換言すれば形
状記憶合金等2としては、その記憶形状が具現化する温
度域が材料4の熱変形温度から硬化温度の間のものを選
択して用いればよい。
In the manufacturing method of the present invention, the memorized shape of the shape memory alloy 2 needs to be realized before the fluid material 4 hardens. Therefore, in order to make the process simpler (continuous process, unification of heating means), the temperature range in which the memorized shape of the shape memory alloy 2 is realized is lower than the temperature range in which the fluid material 4 hardens. You can also set it low. In other words, as the shape memory alloy 2, one may be selected and used whose temperature range in which the memory shape is realized is between the heat deformation temperature of the material 4 and the hardening temperature.

【0019】例えば、材料4としてメチルメタクリレー
ト(重合温度 130℃)を用いる際には、形状記憶合
金2としては、Cu:30at% 、Ni:20at%
 、Ti:1at% (熱変形温度85℃)の合金を用
いると好適である。
For example, when methyl methacrylate (polymerization temperature 130° C.) is used as the material 4, the shape memory alloy 2 contains Cu: 30 at% and Ni: 20 at%.
, Ti: 1 at% (heat distortion temperature: 85° C.) is preferably used.

【0020】また、本発明の製造方法を、注型成形法以
外の、例えばインジェクション法、熱プレス法、2P法
などと比較すると、基体内部の残留応力や分子配向が少
ないので基体のソリや光学的異方性が生じ難いなどの点
でも優れている。
Furthermore, when the manufacturing method of the present invention is compared with methods other than cast molding methods, such as injection method, hot press method, and 2P method, it is found that residual stress and molecular orientation inside the substrate are small, so warping of the substrate and optical It is also excellent in that it does not easily cause optical anisotropy.

【0021】[0021]

【実施例】以下、実施例により本発明を更に詳細に説明
する。 実施例1 形状記憶合金2として、Cu:30at% 、Ni:2
0at%、Ti:1at% の組成で、熱変形温度(逆
変態温度)が85℃のものを準備した。この合金2に、
巾5μm、深さ0.5μm、ピッチ15μmの案内溝、
および巾5μm、長さ5μm、深さ0.5 μmの情報
用ピットから成るプリフォーマットの凹凸パターンに対
応する形状をあらかじめ記憶させておき、その後平滑な
ローラーなどで引き伸ばし、平滑な平板状の形状記憶合
金2とした。そして、この形状記憶合金2をニッケル金
属板上に設けて注型成形型5とした。
[Examples] The present invention will be explained in more detail with reference to Examples below. Example 1 Shape memory alloy 2: Cu: 30 at%, Ni: 2
A material having a composition of 0 at%, Ti: 1 at%, and a heat distortion temperature (reverse transformation temperature) of 85° C. was prepared. In this alloy 2,
Guide grooves with a width of 5 μm, a depth of 0.5 μm, and a pitch of 15 μm,
A shape corresponding to a preformatted concavo-convex pattern consisting of information pits with a width of 5 μm, a length of 5 μm, and a depth of 0.5 μm is stored in advance, and then stretched with a smooth roller to form a smooth flat plate-like shape. Memory alloy 2 was used. Then, this shape memory alloy 2 was provided on a nickel metal plate to form a casting mold 5.

【0022】この注型成形型5を、スペーサ3を介して
鏡面研磨されたニッケル金属板(鏡面型1)と対向して
組立てることにより注型成形装置を得た。
A cast molding device was obtained by assembling this cast mold 5 so as to face a mirror-polished nickel metal plate (mirror mold 1) with a spacer 3 interposed therebetween.

【0023】この注型成形装置内に、流動性材料4とし
て、以下の配合組成の液状アクリル樹脂を注入した。 (配合組成)     メタクリル酸メチル            
                         
   70重量部    メタクリル酸ターシャリブチ
ル                        
      25重量部    ポリエチレングリコー
ルジメタクリレート(平均分子量 620)   5重
量部この液状アクリル樹脂の注入時において、形状記憶
合金2の平滑面には気泡が生成しなかった。
[0023] A liquid acrylic resin having the following composition was injected into the cast molding apparatus as the fluid material 4. (Composition) Methyl methacrylate

70 parts by weight tert-butyl methacrylate
25 parts by weight Polyethylene glycol dimethacrylate (average molecular weight 620) 5 parts by weight No bubbles were generated on the smooth surface of shape memory alloy 2 when this liquid acrylic resin was injected.

【0024】注入後加熱すると、その昇温過程の80℃
付近において形状記憶合金2が形状回復し、図1(b)
 に示す様に所望の凹凸形状に変形した。その後、13
5 ℃、6時間加熱し、次いで室温に降温し、離型して
アクリル樹脂製の情報記録媒体用基体を得た。
[0024] When heated after injection, the temperature rises to 80°C.
The shape memory alloy 2 recovers its shape in the vicinity, as shown in Fig. 1(b).
It was deformed into the desired uneven shape as shown in the figure. After that, 13
The mixture was heated at 5° C. for 6 hours, then cooled to room temperature, and released from the mold to obtain an acrylic resin substrate for an information recording medium.

【0025】この基体の凹凸パターンを目視にて検査し
たところ、気泡による欠陥は全く認められなかった。 比較例1 金属板(Fe、Co、Ni等)をエッチングすることに
よって、図2に示すような凹凸形状を一体的に有する注
型成形型6であって、実施例1の凹凸形状と同じサイズ
の凹凸形状を有する型6を作製した。
When the uneven pattern of this substrate was visually inspected, no defects due to air bubbles were observed. Comparative Example 1 A casting mold 6 that integrally has an uneven shape as shown in FIG. 2 by etching a metal plate (Fe, Co, Ni, etc.), the same size as the uneven shape of Example 1. A mold 6 having a concavo-convex shape was produced.

【0026】この注型成形型6を用いた以外は実施例1
と同様にして注型成形装置を組み立て、同じ液状アクリ
ル樹脂4を注入し、情報記録媒体用基体を得た。
Example 1 except that this casting mold 6 was used.
A cast molding apparatus was assembled in the same manner as above, and the same liquid acrylic resin 4 was injected to obtain a substrate for an information recording medium.

【0027】この基体を約 100個製造して、その凹
凸パターンを目視にて検査したところ、気泡による欠陥
が有るものが全体のうちの10%にも達していた。
Approximately 100 of these substrates were manufactured and their uneven patterns were visually inspected, and it was found that as many as 10% of the substrates had defects due to air bubbles.

【0028】[0028]

【発明の効果】以上説明したように本発明によれば、粘
度の高い材料を用いた場合であっても型のグルーブ部分
に気泡が付かず、微細かつ精密なパターンを有する情報
記録媒体用基体を簡易に製造できる。
Effects of the Invention As explained above, according to the present invention, even when a highly viscous material is used, air bubbles do not form in the groove portion of the mold, and a substrate for an information recording medium having a fine and precise pattern can be obtained. can be easily manufactured.

【図面の簡単な説明】[Brief explanation of the drawing]

【図1】本発明の注型成形型の一実施態様を備えた注型
成形装置を示す模式的断面図であり、(a) は材料注
入時の成形型の状態を、(b) は加熱硬化時の成形型
の状態を表わす。
FIG. 1 is a schematic sectional view showing a cast molding apparatus equipped with an embodiment of the cast mold of the present invention, in which (a) shows the state of the mold during material injection, and (b) shows the state of the mold during heating. Represents the state of the mold during curing.

【図2】従来の注型成形装置を模式的に例示する断面図
である。
FIG. 2 is a cross-sectional view schematically illustrating a conventional cast molding apparatus.

【符号の説明】[Explanation of symbols]

1  鏡面型 2  形状記憶合金または形状記憶樹脂3  スペーサ
ー 4  流動性材料 5  注型成形型 6  従来の注型成形型
1 Mirror surface mold 2 Shape memory alloy or shape memory resin 3 Spacer 4 Fluid material 5 Casting mold 6 Conventional casting mold

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】  注型成形により凹凸パターンを有する
情報記録媒体用基体を製造する方法において、該凹凸パ
ターンに対応する形状が記憶された形状記憶合金または
形状記憶樹脂を備える注型成形型に基板用材料を注入し
、加熱することによって該注型成形型の記憶する形状を
具現化する工程を有することを特徴とする情報記録媒体
用基体の製造方法。
1. A method for producing a substrate for an information recording medium having a concavo-convex pattern by cast molding, in which a substrate is placed in a cast molding mold comprising a shape memory alloy or a shape memory resin in which a shape corresponding to the concavo-convex pattern is memorized. 1. A method for producing a substrate for an information recording medium, the method comprising the step of injecting a material and heating it to realize the shape to be memorized by the casting mold.
【請求項2】  凹凸パターンを有する情報記録媒体用
基体を製造するための注型成形型であって、該凹凸パタ
ーンに対応する形状が記憶された形状記憶合金または形
状記憶樹脂を備えることを特徴とする注型成形型。
2. A casting mold for producing a substrate for an information recording medium having a concavo-convex pattern, characterized by comprising a shape memory alloy or shape memory resin in which a shape corresponding to the concavo-convex pattern is memorized. Casting mold.
JP1917391A 1991-01-21 1991-01-21 Production of and casting mold for base body for information recording medium Pending JPH04238130A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1917391A JPH04238130A (en) 1991-01-21 1991-01-21 Production of and casting mold for base body for information recording medium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1917391A JPH04238130A (en) 1991-01-21 1991-01-21 Production of and casting mold for base body for information recording medium

Publications (1)

Publication Number Publication Date
JPH04238130A true JPH04238130A (en) 1992-08-26

Family

ID=11991962

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1917391A Pending JPH04238130A (en) 1991-01-21 1991-01-21 Production of and casting mold for base body for information recording medium

Country Status (1)

Country Link
JP (1) JPH04238130A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7632628B2 (en) * 2003-04-18 2009-12-15 Pioneer Corporation Stamper and method for production thereof
US7998605B2 (en) 2005-09-28 2011-08-16 Hitachi Global Storage Technologies Netherlands B.V. Magnetic recording medium and method for production thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7632628B2 (en) * 2003-04-18 2009-12-15 Pioneer Corporation Stamper and method for production thereof
US7998605B2 (en) 2005-09-28 2011-08-16 Hitachi Global Storage Technologies Netherlands B.V. Magnetic recording medium and method for production thereof

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