JPH04236211A - Resin composition, overcoating agent for optical disk and cured product thereof - Google Patents
Resin composition, overcoating agent for optical disk and cured product thereofInfo
- Publication number
- JPH04236211A JPH04236211A JP3015640A JP1564091A JPH04236211A JP H04236211 A JPH04236211 A JP H04236211A JP 3015640 A JP3015640 A JP 3015640A JP 1564091 A JP1564091 A JP 1564091A JP H04236211 A JPH04236211 A JP H04236211A
- Authority
- JP
- Japan
- Prior art keywords
- resin composition
- optical disk
- overcoating
- optical
- cured product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000003287 optical effect Effects 0.000 title claims abstract description 36
- 239000011342 resin composition Substances 0.000 title claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- 150000001875 compounds Chemical class 0.000 claims abstract description 13
- 239000003999 initiator Substances 0.000 claims abstract description 12
- 239000002685 polymerization catalyst Substances 0.000 claims description 10
- 239000000758 substrate Substances 0.000 abstract description 7
- UMLWXYJZDNNBTD-UHFFFAOYSA-N alpha-dimethylaminoacetophenone Natural products CN(C)CC(=O)C1=CC=CC=C1 UMLWXYJZDNNBTD-UHFFFAOYSA-N 0.000 abstract description 4
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 abstract description 4
- 239000012965 benzophenone Substances 0.000 abstract description 4
- FYYIUODUDSPAJQ-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]heptan-4-ylmethyl 2-methylprop-2-enoate Chemical compound C1C(COC(=O)C(=C)C)CCC2OC21 FYYIUODUDSPAJQ-UHFFFAOYSA-N 0.000 abstract description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 abstract description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052753 mercury Inorganic materials 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 3
- 229920000098 polyolefin Polymers 0.000 abstract description 3
- 238000004544 sputter deposition Methods 0.000 abstract description 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000012663 cationic photopolymerization Methods 0.000 abstract 2
- 239000000203 mixture Substances 0.000 description 13
- -1 alicyclic epoxides Chemical class 0.000 description 11
- 239000010410 layer Substances 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- 239000000126 substance Substances 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 239000011241 protective layer Substances 0.000 description 5
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 4
- 230000005856 abnormality Effects 0.000 description 4
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- NHJIDZUQMHKGRE-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]heptan-4-yl 2-(7-oxabicyclo[4.1.0]heptan-4-yl)acetate Chemical compound C1CC2OC2CC1OC(=O)CC1CC2OC2CC1 NHJIDZUQMHKGRE-UHFFFAOYSA-N 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 2
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 2
- NJWGQARXZDRHCD-UHFFFAOYSA-N 2-methylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(C)=CC=C3C(=O)C2=C1 NJWGQARXZDRHCD-UHFFFAOYSA-N 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- 229920001153 Polydicyclopentadiene Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 244000028419 Styrax benzoin Species 0.000 description 2
- 235000000126 Styrax benzoin Nutrition 0.000 description 2
- 235000008411 Sumatra benzointree Nutrition 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 229960002130 benzoin Drugs 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 235000019382 gum benzoic Nutrition 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- ZZXXBDPXXIDUBP-UHFFFAOYSA-N hydroxymethyl prop-2-enoate Chemical compound C(C=C)(=O)OCO.C(C=C)(=O)OCO ZZXXBDPXXIDUBP-UHFFFAOYSA-N 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 description 1
- SUDVPELGFZKOMD-UHFFFAOYSA-N 1,2-di(propan-2-yl)thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=C(C(C)C)C(C(C)C)=CC=C3SC2=C1 SUDVPELGFZKOMD-UHFFFAOYSA-N 0.000 description 1
- MSAHTMIQULFMRG-UHFFFAOYSA-N 1,2-diphenyl-2-propan-2-yloxyethanone Chemical compound C=1C=CC=CC=1C(OC(C)C)C(=O)C1=CC=CC=C1 MSAHTMIQULFMRG-UHFFFAOYSA-N 0.000 description 1
- OTKCEEWUXHVZQI-UHFFFAOYSA-N 1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(=O)CC1=CC=CC=C1 OTKCEEWUXHVZQI-UHFFFAOYSA-N 0.000 description 1
- BOCJQSFSGAZAPQ-UHFFFAOYSA-N 1-chloroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2Cl BOCJQSFSGAZAPQ-UHFFFAOYSA-N 0.000 description 1
- CERJZAHSUZVMCH-UHFFFAOYSA-N 2,2-dichloro-1-phenylethanone Chemical compound ClC(Cl)C(=O)C1=CC=CC=C1 CERJZAHSUZVMCH-UHFFFAOYSA-N 0.000 description 1
- PIZHFBODNLEQBL-UHFFFAOYSA-N 2,2-diethoxy-1-phenylethanone Chemical class CCOC(OCC)C(=O)C1=CC=CC=C1 PIZHFBODNLEQBL-UHFFFAOYSA-N 0.000 description 1
- BTJPUDCSZVCXFQ-UHFFFAOYSA-N 2,4-diethylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC(CC)=C3SC2=C1 BTJPUDCSZVCXFQ-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- ZCDADJXRUCOCJE-UHFFFAOYSA-N 2-chlorothioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(Cl)=CC=C3SC2=C1 ZCDADJXRUCOCJE-UHFFFAOYSA-N 0.000 description 1
- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 description 1
- IQQVCMQJDJSRFU-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO IQQVCMQJDJSRFU-UHFFFAOYSA-N 0.000 description 1
- SJEBAWHUJDUKQK-UHFFFAOYSA-N 2-ethylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC=C3C(=O)C2=C1 SJEBAWHUJDUKQK-UHFFFAOYSA-N 0.000 description 1
- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 description 1
- GRWFFFOEIHGUBG-UHFFFAOYSA-N 3,4-Epoxy-6-methylcyclohexylmethyl-3,4-epoxy-6-methylcyclo-hexanecarboxylate Chemical compound C1C2OC2CC(C)C1C(=O)OCC1CC2OC2CC1C GRWFFFOEIHGUBG-UHFFFAOYSA-N 0.000 description 1
- SLJFKNONPLNAPF-UHFFFAOYSA-N 3-Vinyl-7-oxabicyclo[4.1.0]heptane Chemical compound C1C(C=C)CCC2OC21 SLJFKNONPLNAPF-UHFFFAOYSA-N 0.000 description 1
- YXSMNOHOLATKLF-UHFFFAOYSA-N 4-methyl-5-[(4-methyl-7-oxabicyclo[4.1.0]heptan-4-yl)methyl]-7-oxabicyclo[4.1.0]heptane-4-carboxylic acid Chemical compound C1CC2OC2CC1(C)CC1C2OC2CCC1(C)C(O)=O YXSMNOHOLATKLF-UHFFFAOYSA-N 0.000 description 1
- BMIOTMCWMGQPAA-UHFFFAOYSA-N 5-methyl-3-[(5-methyl-7-oxabicyclo[4.1.0]heptan-3-yl)methyl]-7-oxabicyclo[4.1.0]heptane-3-carboxylic acid Chemical compound C1C2OC2C(C)CC1(C(O)=O)CC1CC(C)C2OC2C1 BMIOTMCWMGQPAA-UHFFFAOYSA-N 0.000 description 1
- KYUGRJLPPCDMOH-UHFFFAOYSA-N 6-(7-oxabicyclo[4.1.0]heptan-3-ylmethoxy)-6-oxohexanoic acid Chemical compound C1C(COC(=O)CCCCC(=O)O)CCC2OC21 KYUGRJLPPCDMOH-UHFFFAOYSA-N 0.000 description 1
- YXALYBMHAYZKAP-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]heptan-4-ylmethyl 7-oxabicyclo[4.1.0]heptane-4-carboxylate Chemical compound C1CC2OC2CC1C(=O)OCC1CC2OC2CC1 YXALYBMHAYZKAP-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- AJDPRSJBHBDFOZ-UHFFFAOYSA-N C1CC2OC2(C)CC1(C(O)=O)CC1CC(C)(O2)C2CC1 Chemical compound C1CC2OC2(C)CC1(C(O)=O)CC1CC(C)(O2)C2CC1 AJDPRSJBHBDFOZ-UHFFFAOYSA-N 0.000 description 1
- 229910052692 Dysprosium Inorganic materials 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 1
- XRMBQHTWUBGQDN-UHFFFAOYSA-N [2-[2,2-bis(prop-2-enoyloxymethyl)butoxymethyl]-2-(prop-2-enoyloxymethyl)butyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(CC)COCC(CC)(COC(=O)C=C)COC(=O)C=C XRMBQHTWUBGQDN-UHFFFAOYSA-N 0.000 description 1
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- WAQJWJHUIZCDFA-UHFFFAOYSA-N bis(7-oxabicyclo[4.1.0]heptan-4-ylmethyl) heptanedioate Chemical compound C1CC2OC2CC1COC(=O)CCCCCC(=O)OCC1CC2OC2CC1 WAQJWJHUIZCDFA-UHFFFAOYSA-N 0.000 description 1
- LHQZPSHKKVHDTB-UHFFFAOYSA-N bis(7-oxabicyclo[4.1.0]heptan-4-ylmethyl) oxalate Chemical compound C1CC2OC2CC1COC(=O)C(=O)OCC1CC2OC2CC1 LHQZPSHKKVHDTB-UHFFFAOYSA-N 0.000 description 1
- LMMDJMWIHPEQSJ-UHFFFAOYSA-N bis[(3-methyl-7-oxabicyclo[4.1.0]heptan-4-yl)methyl] hexanedioate Chemical compound C1C2OC2CC(C)C1COC(=O)CCCCC(=O)OCC1CC2OC2CC1C LMMDJMWIHPEQSJ-UHFFFAOYSA-N 0.000 description 1
- MSODWKQDERPZOY-UHFFFAOYSA-N bis[2-(2-hydroxycyclohexyl)phenyl]methanone Chemical compound OC1CCCCC1C1=CC=CC=C1C(=O)C1=CC=CC=C1C1C(O)CCCC1 MSODWKQDERPZOY-UHFFFAOYSA-N 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 238000010538 cationic polymerization reaction Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910001004 magnetic alloy Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Abstract
Description
【０００１】0001
【産業上の利用分野】本発明は、光信号を高速・高密度
に記録、再生、消去する光ディスク記録媒体用オーバー
コート剤として有用な紫外線等により硬化し、記録媒体
に対する接着性、耐湿性が良好で、逆反りしない、硬度
の優れた紫外線硬化型樹脂組成物及びその硬化物に関す
る。[Industrial Application Field] The present invention is a useful overcoat agent for optical disk recording media that records, reproduces, and erases optical signals at high speed and high density. This invention relates to an ultraviolet curable resin composition that is good, does not warp, and has excellent hardness, and a cured product thereof.
【０００２】0002
【従来の技術】光磁気記録媒体は垂直磁気記録と磁気光
学効果を利用するもので、従来の光記録媒体と同様にレ
ーザ光を用いて情報の記録、再生を行うため記録容量が
大きくその上書き換えが可能である。さらにヘッドと媒
体が非接触で記録再生を行うことができ、塵埃の影響を
受けないため安定性にも優れている。この光磁気記録媒
体は、現在盛んに研究されており、文書情報ファイル、
ビデオ静止画ファイル、コンピュータ用メモリ等への利
用或いはフロッピーディスク、ハードディスクの代替が
期待され、商品化段階を迎えている。[Prior Art] Magneto-optical recording media utilize perpendicular magnetic recording and magneto-optical effects, and as with conventional optical recording media, information is recorded and reproduced using laser light, so they have a large recording capacity. Can be rewritten. Furthermore, recording and reproduction can be performed without contact between the head and the medium, and it is not affected by dust, so it has excellent stability. This magneto-optical recording medium is currently being actively researched.
It is expected to be used for video still image files, computer memory, etc., or as a replacement for floppy disks and hard disks, and is now at the commercialization stage.
【０００３】このような光磁気記録媒体の記録層として
は、遷移金属（Ｆｅ，Ｃｏ）と希土類金属（Ｇｄ，Ｄｙ
，Ｔｂ等）とを組合せた種々の非晶質（アモルファス）
磁性合金膜が提案されている。又、媒体の構成としては
、基板上に誘電層、記録層、誘電層を設けた単板タイプ
のもの、或いはこの単板タイプのものと同様な構造体を
一組用意し、記録層を内側に対向させて接着剤により接
合した貼り合せタイプのものが一般的である。The recording layer of such a magneto-optical recording medium is made of transition metals (Fe, Co) and rare earth metals (Gd, Dy).
, Tb, etc.)
Magnetic alloy films have been proposed. In addition, the structure of the medium is a single-plate type in which a dielectric layer, a recording layer, and a dielectric layer are provided on a substrate, or a set of a structure similar to this single-plate type is prepared, and the recording layer is placed on the inside. The most common type is a bonded type in which the panels are placed facing each other and bonded with an adhesive.
【０００４】一方、基板上の積層される無機層における
クラックの発生を防止し、記録層への酸素、水分の侵入
防止をより完全化し、高温多湿の環境下においても光磁
気特性を長期にわたって維持する目的で誘電層の上にア
クリレート系樹脂組成物の硬化物或いは、エポキシ系樹
脂組成物の硬化物を有機保護層に用いたものが例えば、
特開昭６１−１２３５９３、特開昭６１−１３３０６７
、特開昭６１−１３９９６１、特開昭６１−１５３８４
４、特開平２−１０７６３０、特開平２−１３２６６４
号公報等に開示されている。On the other hand, it is possible to prevent the occurrence of cracks in the inorganic layer laminated on the substrate, to more completely prevent the intrusion of oxygen and moisture into the recording layer, and to maintain magneto-optical characteristics for a long period of time even in a high temperature and humidity environment. For example, a cured product of an acrylate resin composition or a cured product of an epoxy resin composition is used as an organic protective layer on a dielectric layer for the purpose of
JP-A-61-123593, JP-A-61-133067
, JP-A-61-139961, JP-A-61-15384
4, JP-A-2-107630, JP-A-2-132664
It is disclosed in the publication number etc.
【０００５】[0005]
【発明が解決しようとする課題】しかしながら、上記従
来例の光学的記録媒体は、前記紫外線硬化型アクリレー
ト系樹脂組成物の硬化物からなる保護層を設けることに
より、外部からのキズや汚れに対する保護という目的は
達成されるが、該光学的記録媒体を環境耐久試験（７０
℃、９０％ＲＨ、２０００時間）の条件下に放置すると
、光磁気記録層の孔食劣化が増加したり、ディスク基板
からの保護層の剥離が発生する場合があり問題である。
又、エポキシ系樹脂組成物の硬化物からなる保護層を設
けた場合、光磁気記録層の孔食劣化の発生は、少ないが
ディスクの逆反りが生じ問題である。[Problems to be Solved by the Invention] However, the conventional optical recording medium described above has a protective layer made of a cured product of the ultraviolet curable acrylate resin composition, thereby providing protection against external scratches and stains. Although this objective was achieved, the optical recording medium was subjected to an environmental durability test (70
C., 90% RH, 2000 hours), there is a problem in that the pitting corrosion deterioration of the magneto-optical recording layer may increase or the protective layer may peel off from the disk substrate. Further, when a protective layer made of a cured product of an epoxy resin composition is provided, pitting corrosion deterioration of the magneto-optical recording layer is less likely to occur, but reverse warping of the disk occurs, which is a problem.
【０００６】[0006]
【課題を解決するための手段】本発明は、この様な従来
の課題を解決するためになされたものであり、保護層と
して構造中にエポキシ基とアクリレート基を同時にもっ
ている化合物を含んだ樹脂組成物を用いることにより、
外部からのキズや汚れを防止すると共に光磁気記録層の
孔食劣化が極めて少なく、又、逆反りもなく、長期の信
頼性を維持することが可能な光学的記録媒体を提供する
ものである。[Means for Solving the Problems] The present invention has been made to solve these conventional problems, and provides a resin containing a compound having both an epoxy group and an acrylate group in its structure as a protective layer. By using the composition,
To provide an optical recording medium that can prevent scratches and stains from the outside, have extremely little pitting corrosion deterioration of a magneto-optical recording layer, and can maintain long-term reliability without reverse warping. .
【０００７】即ち、本発明は、
１） 式〔１〕で表される化合物（Ａ）（式中、Ｒは
、Ｈ又ＣＨ３ である。）と光重合開始剤（Ｂ）と任意
成分として光カチオン重合触媒（Ｃ）を含む樹脂組成物
。
２） １）項記載の式〔１〕で表される化合物（Ａ）
と光重合開始剤（Ｂ）と任意成分として光カチオン重合
触媒（Ｃ）を含む光ディスク用オーバーコート剤。
３） １）項記載の樹脂組成物の硬化物及び２）項記
載の光ディスク用オーバーコート剤の硬化物に関する。That is, the present invention comprises: 1) a compound (A) represented by the formula [1] (wherein R is H or CH3), a photopolymerization initiator (B), and optionally a photopolymerization initiator (B); A resin composition containing a cationic polymerization catalyst (C). 2) Compound (A) represented by formula [1] described in section 1)
An overcoat agent for optical discs, comprising a photopolymerization initiator (B) and a photocationic polymerization catalyst (C) as an optional component. 3) A cured product of the resin composition described in section 1) and a cured product of the overcoat agent for optical discs described in section 2).
【０００８】本発明において使用される式〔１〕で表さ
れる化合物（Ａ）の具体例としては、例えば、Specific examples of the compound (A) represented by formula [1] used in the present invention include, for example,
【０００
９】000
9]
【００１０】（ダイセル化学工業（株）製、ＡＥＴＨＢ
）(Manufactured by Daicel Chemical Industries, Ltd., AETHB)
)
【００１１】[0011]
【００１２】（ダイセル化学工業（株）製、ＭＥＴＨＢ
）等を挙げることができる。(Manufactured by Daicel Chemical Industries, Ltd., METHB)
) etc.
【００１３】本発明では、必要に応じて式〔１〕で表さ
れる化合物（Ａ）以外に脂環式エポキシド類（例えば、
３，４−エポキシシクロヘキシルメチル−３，４−エポ
キシシクロヘキサンカルボキシレート、３，４−エポキ
シ−１−メチルシクロヘキシルメチル−３，４−エポキ
シ−１−メチルシクロヘキサンカルボキシレート；６−
メチル−３，４−エポキシシクロヘキシルメチル−６−
メチル−３，４−エポキシシクロヘキサンカルボキシレ
ート；３，４−エポキシ−３−メチルシクロヘキシルメ
チル−３，４−エポキシ−３−メチルシクロヘキサンカ
ルボキシレート；３，４−エポキシ−５−メチルシクロ
ヘキシルメチル−３，４−エポキシ−５−メチルシクロ
ヘキサンカルボキシレート；２−（３，４−エポキシシ
クロヘキシル−５，５−スピロ−３，４−エポキシ）シ
クロヘキサン−メタ−ジオキサン；ビス（３，４−エポ
キシシクロヘキシルメチル）オキサレート；ビス（３，
４−エポキシシクロヘキシルメチル）アジペート；ビス
（３，４−エポキシ−６−メチルシクロヘキシルメチル
）アジペート；ビス（３，４−エポキシシクロヘキシル
メチル）ピメレート；４−ビニルシクロヘキサンモノエ
ポキシド；ノルボルネンモノエポキシド；リモネンモノ
エポキシド等）、In the present invention, in addition to the compound (A) represented by formula [1], alicyclic epoxides (for example,
3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexanecarboxylate, 3,4-epoxy-1-methylcyclohexylmethyl-3,4-epoxy-1-methylcyclohexanecarboxylate; 6-
Methyl-3,4-epoxycyclohexylmethyl-6-
Methyl-3,4-epoxycyclohexanecarboxylate; 3,4-epoxy-3-methylcyclohexylmethyl-3,4-epoxy-3-methylcyclohexanecarboxylate; 3,4-epoxy-5-methylcyclohexylmethyl-3, 4-Epoxy-5-methylcyclohexanecarboxylate; 2-(3,4-epoxycyclohexyl-5,5-spiro-3,4-epoxy)cyclohexane-meta-dioxane; Bis(3,4-epoxycyclohexylmethyl)oxalate ; screw (3,
4-Epoxycyclohexylmethyl)adipate; Bis(3,4-epoxy-6-methylcyclohexylmethyl)adipate; Bis(3,4-epoxycyclohexylmethyl)pimelate; 4-vinylcyclohexane monoepoxide; Norbornene monoepoxide; Limonene monoepoxide etc),
【００１４】アクリレート類〔例えば、２−ヒドロキシ
エチルアクリレート、イソボルニルアクリレート、水添
ジシクロペンタジエンアクリレート（日立化成（株）製
、ＦＡ−５１３Ａ）、トリシクロデカンジメチロールジ
アクリレート、トリメチロールプロパントリアクリレー
ト、ペンタエリスリトールトリアクリレート、ジトリメ
チロールプロパンテトラアクリレート、ジペンタエリス
リトールヘキサアクリレート、エポキシアクリレート（
例えば、ビスフェノール型エポキシ樹脂とアクリル酸と
の反応物等）、ウレタンアクリレート（例えば、ポリテ
トラメチレングリコール、エチレングリコール等のジオ
ール化合物とイソホロンジイソシアネート等のジイソシ
アネート化合物と２−ヒドロキシエチルアクリレート等
の分子中に１個の水酸基を有するアクリレート化合物と
の反応物等）等〕を使用することができる。Acrylates [for example, 2-hydroxyethyl acrylate, isobornyl acrylate, hydrogenated dicyclopentadiene acrylate (manufactured by Hitachi Chemical Co., Ltd., FA-513A), tricyclodecane dimethylol diacrylate, trimethylolpropane triacrylate acrylate, pentaerythritol triacrylate, ditrimethylolpropane tetraacrylate, dipentaerythritol hexaacrylate, epoxy acrylate (
For example, a reaction product of bisphenol type epoxy resin and acrylic acid), urethane acrylate (for example, a diol compound such as polytetramethylene glycol or ethylene glycol, a diisocyanate compound such as isophorone diisocyanate, and a molecule such as 2-hydroxyethyl acrylate) A reaction product with an acrylate compound having one hydroxyl group, etc.) can be used.
【００１５】本発明の樹脂組成物及び光ディスク用オー
バーコート剤（以下、単に「組成物」という。）に使用
される脂環式エポキシ類やアクリレート類の使用量は、
一般的〔１〕で表される化合物（Ａ）１００重量部に対
して、０〜１０００重量部が好ましく、特に好ましくは
、０〜２００重量部である。[0015] The amounts of the alicyclic epoxies and acrylates used in the resin composition and optical disc overcoat agent (hereinafter simply referred to as "composition") of the present invention are as follows:
The amount is preferably 0 to 1000 parts by weight, particularly preferably 0 to 200 parts by weight, per 100 parts by weight of the compound (A) represented by general [1].
【００１６】本発明に使用される光重合開始剤（Ｂ）と
しては、公知のどのような光重合開始剤でも使用するこ
とができる。具体的には例えば、ベンゾイン、ベンゾイ
ンメチルエーテル、ベンゾインエチルエーテル、ベンゾ
インイソプロピルエーテルなどのベンゾインとそのアル
キルエーテル類；アセトフェノン、２，２−ジメトキシ
−２−フェニルアセトフェノン、２，２−ジエトキシ−
２−フェニルアセトフェノン、１，１−ジクロロアセト
フェノンなどのアセトフェノン類；２−メチルアントラ
キノン、２−エチルアントラキノン、１−クロロアント
ラキノン等のアントラキノン類；２，４−ジエチルチオ
キサントン、２−クロロチオキサントンジイソプロピル
チオキサントンなどのチオキサントン類；ベンジルジメ
チルケタール、２−ヒドロキシシクロヘキシルフェニル
ケトン、ベンゾフェノン等を使用することができる。こ
の光重合開始剤（Ｂ）は必要に応じて、安息香酸系又は
、第三級アミン系などの公知慣用の光重合促進剤の１種
又は２種以上と組み合わせて用いることができる。光重
合開始剤（Ｂ）の使用量の好適な範囲は、本発明の組成
物中、０．５〜２０重量％、特に好ましくは３〜１０重
量％である。As the photopolymerization initiator (B) used in the present invention, any known photopolymerization initiator can be used. Specifically, for example, benzoin and its alkyl ethers such as benzoin, benzoin methyl ether, benzoin ethyl ether, and benzoin isopropyl ether; acetophenone, 2,2-dimethoxy-2-phenylacetophenone, 2,2-diethoxy-
Acetophenones such as 2-phenylacetophenone and 1,1-dichloroacetophenone; Anthraquinones such as 2-methylanthraquinone, 2-ethylanthraquinone, and 1-chloroanthraquinone; 2,4-diethylthioxanthone, 2-chlorothioxanthone, diisopropylthioxanthone, etc. Thioxanthone; benzyl dimethyl ketal, 2-hydroxycyclohexylphenyl ketone, benzophenone, etc. can be used. This photopolymerization initiator (B) can be used in combination with one or more known and commonly used photopolymerization accelerators such as benzoic acid-based or tertiary amine-based photopolymerization accelerators, if necessary. A suitable range of the amount of the photopolymerization initiator (B) to be used in the composition of the present invention is 0.5 to 20% by weight, particularly preferably 3 to 10% by weight.
【００１７】本発明の任意成分として使用される光カチ
オン重合触媒（Ｃ）としては、公知のどのような光カチ
オン重合触媒でも使用することができる。具体的には例
えば、ポリアリールスルホニウムヘキサフルオロホスフ
ェート（３Ｍカンパニー社製、ＦＣ−５０８、ＦＸ−５
１２）、ポリアリールスルホニウムヘキサフルオロアン
チモン塩（ゼネラルエレクトリック・カンパニー社製、
ＵＶＥ−１０１４）、ＳＰ−１７０、ＳＰ−１５０（旭
電化（株）製、ポリアリールスルホニウムヘキサフルオ
ロホスフェート、ポリアリールスルホニウムヘキサフル
オロアンチモネート）等を使用することができる。これ
ら光カチオン重合触媒（Ｃ）は、１種または２種以上を
任意の割合で混合して使用する事ができる。光カチオン
重合触媒（Ｃ）の使用量の好適な範囲は、本発明の組成
物中、０〜２重量％、特に好ましくは０〜０．５重量％
である。As the photocationic polymerization catalyst (C) used as an optional component in the present invention, any known photocationic polymerization catalyst can be used. Specifically, for example, polyarylsulfonium hexafluorophosphate (manufactured by 3M Company, FC-508, FX-5
12), polyarylsulfonium hexafluoroantimony salt (manufactured by General Electric Company,
UVE-1014), SP-170, SP-150 (manufactured by Asahi Denka Co., Ltd., polyarylsulfonium hexafluorophosphate, polyarylsulfonium hexafluoroantimonate), etc. can be used. These photocationic polymerization catalysts (C) can be used alone or in combination of two or more in any proportion. A suitable range of the amount of the photocationic polymerization catalyst (C) used is 0 to 2% by weight, particularly preferably 0 to 0.5% by weight in the composition of the present invention.
It is.
【００１８】本発明の組成物は、（Ａ）及び（Ｂ）の成
分だけで十分所期の目的を達成するものであるが、さら
に（Ｃ）成分を加えることによって、硬化物の硬度を高
くすることができる。又性能改良のため、本来の特性を
変えない範囲で、ポリジシクロペンタジェン（日本ゼオ
ン（株）製、クイントン１７００等）、レベリング剤、
シランカップリング剤、溶剤、非塩基性充填剤（例えば
、シルカ、タルク、アルミニウム、銀、酸化亜鉛等）な
ども含むことができる。本発明の組成物は各成分を均一
に混合することにより得ることができる。[0018] The composition of the present invention sufficiently achieves the intended purpose with only components (A) and (B), but by further adding component (C), the hardness of the cured product can be increased. can do. In order to improve performance, polydicyclopentadiene (manufactured by Nippon Zeon Co., Ltd., Quinton 1700, etc.), leveling agents,
A silane coupling agent, a solvent, a non-basic filler (for example, silica, talc, aluminum, silver, zinc oxide, etc.) can also be included. The composition of the present invention can be obtained by uniformly mixing each component.
【００１９】本発明の組成物の紫外線照射による硬化は
常法により行なうことができる。例えば、低圧又は高圧
水銀灯、キセノン灯等を用いて紫外線を照射すればよい
。本発明の組成物は、特に光ディスク用オーバーコート
剤として有用であるが、その他にも、光ディスク用溝材
、金属、プラスチック、ゴム、紙、木材及びガラス、セ
ラミック用コーティング材等にも使用できる。Curing of the composition of the present invention by irradiation with ultraviolet rays can be carried out by a conventional method. For example, ultraviolet rays may be irradiated using a low-pressure or high-pressure mercury lamp, a xenon lamp, or the like. The composition of the present invention is particularly useful as an overcoat agent for optical discs, but can also be used as a groove material for optical discs, a coating material for metals, plastics, rubber, paper, wood and glass, ceramics, and the like.
【００２０】本発明の光ディスク用オーバーコート剤を
用いた光ディスク（基板に使用される材料は、ポリカー
ボネート、ポリオレフイン、ポリエポキシ、ポリメチル
メタクリレート等のプラスチック及びガラス等である。
）の記録膜の保護膜の形成は、光ディスクの記録膜の上
に光ディスク用オーバーコート剤を例えばスピンコート
法等により塗布し、紫外線を照射して硬化することによ
って保護膜を形成させる。光ディスクの記録膜の上に光
ディスク用オーバーコート剤を塗布する場合、その厚さ
は通常２〜２０μ程度とするのが好ましい。A protective film for a recording film of an optical disc (materials used for the substrate are plastics such as polycarbonate, polyolefin, polyepoxy, polymethyl methacrylate, etc.) and glass using the overcoat agent for optical discs of the present invention. To form a protective film, an overcoat agent for optical discs is applied onto the recording film of an optical disc by, for example, a spin coating method, and is cured by irradiation with ultraviolet rays. When applying an optical disc overcoat agent onto the recording film of an optical disc, the thickness thereof is usually preferably about 2 to 20 μm.
【００２１】[0021]
【実施例】以下に、本発明を実施例により具体的に説明
する。なお、実施例中の部は、重量部である。[Examples] The present invention will be specifically explained below using examples. Note that parts in the examples are parts by weight.
【００２２】実施例１．前記式〔２〕で表される化合物
（ダイセル化学工業（株）製、ＡＥＴＨＢ）１００部ベ
ンゾフェノン０．５部、及びＮ，Ｎ−ジメチルアミノ−
アセトフェノン０．５部を混合し光ディスク用オーバー
コート剤を調製した。Example 1. 100 parts of the compound represented by the formula [2] (manufactured by Daicel Chemical Industries, Ltd., AETHB), 0.5 parts of benzophenone, and N,N-dimethylamino-
An overcoat agent for optical discs was prepared by mixing 0.5 part of acetophenone.
【００２３】ポリオレフイン基板に記録膜を作製（スパ
ッタリングにより）した光ディスクの記録膜の上に、上
記の光ディスク用オーバーコート剤をスピンコーターで
塗布し、高圧水銀灯（日本電池（株）製、２ＫＷ）によ
り照射し該組成物を硬化させた。オーバーコートされた
光ディスクを７０℃の９０％ＲＨの状態に放置し、耐湿
性試験を行なった処、２０００時間経過しても記録膜に
異常がなかった。又、逆反り及び剥離もなかった。A recording film was prepared on a polyolefin substrate (by sputtering). The above-mentioned overcoating agent for optical discs was applied with a spin coater onto the recording film of the optical disc, and then the recording film was coated with a high-pressure mercury lamp (manufactured by Nippon Battery Co., Ltd., 2KW). The composition was cured by irradiation. When the overcoated optical disk was left at 70° C. and 90% RH and subjected to a moisture resistance test, no abnormality was found in the recording film even after 2000 hours. Further, there was no reverse warping or peeling.
【００２４】実施例２．前記式〔２〕で表される化合物
（ダイセル化学工業（株）製、ＡＥＴＨＢ）８０部、ト
リシクロデカンジメチロールジアクリレート１０部、ク
イントン１７００（日本ゼオン（株）製、水酸基を有す
るポリジシクロペンタジエン）１０部、ベンゾフェノン
０．５部、Ｎ，Ｎ−ジメチルアミノアセトフェノン０．
５部を混合し光ディスク用オーバーコート剤を調製した
。これを用いて、実施例１と同様にして、オーバーコー
トされた光ディスクを得た。実施例１と同様に試験を行
ない、耐湿性の試験の結果、２０００時間経過しても異
常がなかった。又、逆反り及び剥離もなかった。Example 2. 80 parts of the compound represented by the above formula [2] (manufactured by Daicel Chemical Industries, Ltd., AETHB), 10 parts of tricyclodecane dimethylol diacrylate, Quinton 1700 (manufactured by Nippon Zeon Co., Ltd., polydicyclopentadiene having a hydroxyl group) ) 10 parts, benzophenone 0.5 part, N,N-dimethylaminoacetophenone 0.
5 parts were mixed to prepare an overcoat agent for optical discs. Using this, an overcoated optical disc was obtained in the same manner as in Example 1. A test was conducted in the same manner as in Example 1, and as a result of the moisture resistance test, no abnormality was found even after 2000 hours. Further, there was no reverse warping or peeling.
【００２５】実施例３．前記式〔３〕で表される化合物
（ダイセル化学工業（株）製、ＭＥＴＨＢ）３０部、前
記式〔２〕で表される化合物（ダイセル化学工業（株）
製 ＡＥＴＨＢ）４０部、３，４−エポキシシクロヘ
キシルメチル−３，４−エポキシシクロヘキサンカルボ
キシレート３０部、ＳＰ−１７０〔旭電化（株）製、光
カチオン重合触媒、プロピレンカーボネート５０％希釈
品〕０．３部及びイルガキュアー６５１（チバ・ガイギ
ー社製、光重合開始材）７部を混合し、光ディスク用オ
ーバーコート剤を調製した。これを用い、実施例１と同
様にして、オーバーコートされた光ディスクを得た。実
施例１と同様に試験を行ない、耐湿性の試験の結果、２
０００時間経過しても異常がなかった。又、逆反り及び
剥離もなかった。Example 3. 30 parts of the compound represented by the above formula [3] (manufactured by Daicel Chemical Industries, Ltd., METHB), 30 parts of the compound represented by the above formula [2] (manufactured by Daicel Chemical Industries, Ltd.)
40 parts of 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexanecarboxylate (manufactured by AETHB), 30 parts of 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexanecarboxylate, SP-170 (manufactured by Asahi Denka Co., Ltd., photocationic polymerization catalyst, 50% propylene carbonate diluted product) 0. 3 parts and 7 parts of Irgacure 651 (manufactured by Ciba Geigy, photopolymerization initiator) were mixed to prepare an overcoat agent for optical discs. Using this, an overcoated optical disc was obtained in the same manner as in Example 1. A test was conducted in the same manner as in Example 1, and the results of the moisture resistance test were 2.
No abnormality was found even after 000 hours had passed. Further, there was no reverse warping or peeling.
【００２６】比較例１．光ディスク用オーバーコート剤
として、ＳＤ−１７〔商品名：大日本インキ化学（株）
製〕を用いた以外は、実施例１と同様にして、光ディス
クを得た。実施例１と同様に試験を行ない、耐湿性の試
験の結果、２０００時間経過後、記録膜の全面に孔食劣
化が発生した。又、逆反りや剥離はなかった。Comparative Example 1. SD-17 [Product name: Dainippon Ink Chemical Co., Ltd.] is used as an overcoat agent for optical discs.
An optical disc was obtained in the same manner as in Example 1, except that the following was used. A test was conducted in the same manner as in Example 1, and as a result of the moisture resistance test, pitting corrosion deterioration occurred on the entire surface of the recording film after 2000 hours. Further, there was no reverse warping or peeling.
【００２７】比較例２．３，４−エポキシシクロヘキシ
ルメチル−３，４−エポキシシクロヘキサンカルボキシ
レート１００部、ＳＰ−１７０〔旭電化（株）製、光カ
チオン重合触媒、プロピレンカーボネート５０％希釈品
〕０．３部を混合し、光ディスク用オーバーコート剤を
調製した。これを用い、実施例１と同様にして、オーバ
ーコートされた光ディスクを得た。実施例１と同様に試
験を行ない、耐湿性の試験の結果、２０００時間経過し
ても異常がなかった。逆反りが大きかった。剥離はなか
った。Comparative Example 2. 100 parts of 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexanecarboxylate, SP-170 [manufactured by Asahi Denka Co., Ltd., photocationic polymerization catalyst, 50% propylene carbonate diluted product] 0 .3 parts were mixed to prepare an overcoat agent for optical discs. Using this, an overcoated optical disc was obtained in the same manner as in Example 1. A test was conducted in the same manner as in Example 1, and as a result of the moisture resistance test, no abnormality was found even after 2000 hours. There was a lot of backlash. There was no peeling.
【００２８】[0028]
【発明の効果】本発明の樹脂組成物は、耐湿性、接着性
に優れ、逆反りの問題もなく、特に光ディスク用オーバ
ーコート剤として有用である。EFFECTS OF THE INVENTION The resin composition of the present invention has excellent moisture resistance and adhesive properties, and has no problem of reverse warping, and is particularly useful as an overcoat agent for optical discs.
Claims (4)
合物（Ａ）と光重合開始剤（Ｂ）と任意成分として光カ
チオン重合触媒（Ｃ）を含む樹脂組成物。Claim 1: A compound (A) represented by the formula [1] (wherein R is H or CH3), a photopolymerization initiator (B), and a photocationic polymerization catalyst (C) as an optional component. A resin composition containing.
（Ａ）と光重合開始剤（Ｂ）と任意成分として光カチオ
ン重合触媒（Ｃ）を含む光ディスク用オーバーコート剤
。2. An overcoat agent for optical discs, comprising a compound (A) represented by the formula [1] according to claim 1, a photopolymerization initiator (B), and an optional photocationic polymerization catalyst (C).
ト剤の硬化物。4. A cured product of the overcoat agent for optical discs according to claim 2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3015640A JPH04236211A (en) | 1991-01-17 | 1991-01-17 | Resin composition, overcoating agent for optical disk and cured product thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3015640A JPH04236211A (en) | 1991-01-17 | 1991-01-17 | Resin composition, overcoating agent for optical disk and cured product thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04236211A true JPH04236211A (en) | 1992-08-25 |
Family
ID=11894319
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3015640A Pending JPH04236211A (en) | 1991-01-17 | 1991-01-17 | Resin composition, overcoating agent for optical disk and cured product thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04236211A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0736555A3 (en) * | 1995-04-05 | 1997-06-18 | Ucb Sa | Radiation-curable epoxy resin composition |
| US6818681B2 (en) | 2002-02-22 | 2004-11-16 | Nagase Chemtex Corporation | Ultraviolet-curable resin composition for optical discs |
| JP2008214593A (en) * | 2007-03-07 | 2008-09-18 | Denki Kagaku Kogyo Kk | Resin composition as well as temporary fixing method and surface protecting method for workpiece by using same |
| KR20160001687A (en) | 2014-06-26 | 2016-01-06 | 후지필름 가부시키가이샤 | Method of manufacturing hard coat film, hard coat film, polarizing plate, and liquid crystal display device |
| US9829606B2 (en) | 2014-06-26 | 2017-11-28 | Fujifilm Corporation | Method of manufacturing hard coat film, hard coat film, polarizing plate, and liquid crystal display device |
| US10365411B2 (en) | 2015-02-06 | 2019-07-30 | Fujifilm Corporation | Hardcoat film, polarizing plate, liquid crystal display, and method for manufacturing hardcoat film |
| JP2022161889A (en) * | 2021-04-09 | 2022-10-21 | エス．ア．エス． スリーディーセラム － シントー | Curable composition for manufacture, by stereolithography, of green part of ceramic or metallic material by photo-thermal route |
-
1991
- 1991-01-17 JP JP3015640A patent/JPH04236211A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0736555A3 (en) * | 1995-04-05 | 1997-06-18 | Ucb Sa | Radiation-curable epoxy resin composition |
| US6818681B2 (en) | 2002-02-22 | 2004-11-16 | Nagase Chemtex Corporation | Ultraviolet-curable resin composition for optical discs |
| JP2008214593A (en) * | 2007-03-07 | 2008-09-18 | Denki Kagaku Kogyo Kk | Resin composition as well as temporary fixing method and surface protecting method for workpiece by using same |
| KR20160001687A (en) | 2014-06-26 | 2016-01-06 | 후지필름 가부시키가이샤 | Method of manufacturing hard coat film, hard coat film, polarizing plate, and liquid crystal display device |
| US9829606B2 (en) | 2014-06-26 | 2017-11-28 | Fujifilm Corporation | Method of manufacturing hard coat film, hard coat film, polarizing plate, and liquid crystal display device |
| US10365411B2 (en) | 2015-02-06 | 2019-07-30 | Fujifilm Corporation | Hardcoat film, polarizing plate, liquid crystal display, and method for manufacturing hardcoat film |
| JP2022161889A (en) * | 2021-04-09 | 2022-10-21 | エス．ア．エス． スリーディーセラム － シントー | Curable composition for manufacture, by stereolithography, of green part of ceramic or metallic material by photo-thermal route |
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