JPH04198105A - Stable insecticide preparation - Google Patents
Stable insecticide preparationInfo
- Publication number
- JPH04198105A JPH04198105A JP32518890A JP32518890A JPH04198105A JP H04198105 A JPH04198105 A JP H04198105A JP 32518890 A JP32518890 A JP 32518890A JP 32518890 A JP32518890 A JP 32518890A JP H04198105 A JPH04198105 A JP H04198105A
- Authority
- JP
- Japan
- Prior art keywords
- epoxidized
- compound
- parts
- present
- insecticide preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000002917 insecticide Substances 0.000 title abstract description 9
- 125000005456 glyceride group Chemical group 0.000 claims abstract description 12
- 239000004480 active ingredient Substances 0.000 claims abstract description 4
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 claims abstract 3
- 230000000749 insecticidal effect Effects 0.000 claims description 11
- 229940126062 Compound A Drugs 0.000 abstract description 20
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 abstract description 20
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 abstract description 8
- 238000000354 decomposition reaction Methods 0.000 abstract description 7
- 239000003381 stabilizer Substances 0.000 abstract description 6
- 235000012424 soybean oil Nutrition 0.000 abstract description 4
- 239000003549 soybean oil Substances 0.000 abstract description 4
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 235000012343 cottonseed oil Nutrition 0.000 abstract description 2
- 239000002385 cottonseed oil Substances 0.000 abstract description 2
- 235000021388 linseed oil Nutrition 0.000 abstract description 2
- 239000000944 linseed oil Substances 0.000 abstract description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 abstract 2
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 abstract 2
- 238000009472 formulation Methods 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 9
- 239000004927 clay Substances 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000008187 granular material Substances 0.000 description 4
- 238000003973 irrigation Methods 0.000 description 4
- 230000002262 irrigation Effects 0.000 description 4
- 230000000087 stabilizing effect Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 235000019484 Rapeseed oil Nutrition 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 229910052570 clay Inorganic materials 0.000 description 2
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- -1 polyoxyethylene Polymers 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- AGIJRRREJXSQJR-UHFFFAOYSA-N 2h-thiazine Chemical compound N1SC=CC=C1 AGIJRRREJXSQJR-UHFFFAOYSA-N 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000258937 Hemiptera Species 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 241001602876 Nata Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- SHFGJEQAOUMGJM-UHFFFAOYSA-N dialuminum dipotassium disodium dioxosilane iron(3+) oxocalcium oxomagnesium oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[Na+].[Na+].[Al+3].[Al+3].[K+].[K+].[Fe+3].[Fe+3].O=[Mg].O=[Ca].O=[Si]=O SHFGJEQAOUMGJM-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000004811 liquid chromatography Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
■ 発明の目的
産業上の利用分野
本発明は、殺虫成分を含有する製剤の安定化技術を提供
することに関する。DETAILED DESCRIPTION OF THE INVENTION ■Objective of the invention Industrial field of application The present invention relates to providing a technique for stabilizing formulations containing insecticidal ingredients.
従来の技術
本発明で殺虫剤の有効成分として用いる、ｓ、ｓ’−（
２−（ジメチルアミノ）トリメチレンツビス−ベンゼン
チオスルホネート（以下、「化合物Ａ」という）は、水
稲、あぶらな科野菜、トウモロコシ、改−などの鱗翅目
、半翅目、アザミウマ目、双翅目などの各種害虫に有用
な公知の殺虫剤であるｌ（特公昭４６−１３７５５号報
、特公開４５−１８８４７号報）６公開しながら、化合
物Ａは、粉剤、水利剤などに製剤化して長期間貯蔵した
場合経時的に分解されるという欠点がある。BACKGROUND OF THE INVENTION In the present invention, s, s'-(
2-(Dimethylamino)trimethylene bis-benzenethiosulfonate (hereinafter referred to as "Compound A") is a compound that is used in plants such as Lepidoptera, Hemiptera, Thripsidae, Diptera, etc. Compound A is a known insecticide useful against various pests such as eyes (Japanese Patent Publication No. 46-13755, Japanese Patent Publication No. 45-18847). It has the disadvantage that it decomposes over time if stored for a long period of time.
一方、本発明で使用されるエポキシ化グリセリドは、Ｄ
ＤＶＰ剤の安定化剤（特開昭４９−１２５５３４号公報
）、チアジン系殺虫剤の安定化剤（特開昭５９−２０４
１０９号公報）、ベンジクロン含有混合製剤の安定化剤
（特開昭６３−２１１２０３号公報）などとして公知で
ある。On the other hand, the epoxidized glyceride used in the present invention is D
Stabilizers for DVP agents (JP-A-49-125534), stabilizers for thiazine insecticides (JP-A-59-204)
It is known as a stabilizer for benziclon-containing mixed preparations (Japanese Unexamined Patent Publication No. 63-211203).
また、本発明で使用される２、６−ジーｔｅｒｔ −ブ
チル−４−メチルフェノールは、ＤＤＶＰ剤の安定化剤
（特開昭４９−１２５５３４号公報）として公知である
。Furthermore, 2,6-di-tert-butyl-4-methylphenol used in the present invention is known as a stabilizer for DDVP agents (Japanese Unexamined Patent Publication No. 125534/1984).
ナオ、ＤＤＶＰ、ベンジクロンは既知農薬成分の一般名
である。Nao, DDVP, and Benziclone are common names of known pesticide ingredients.
発明が解決しようとする課題
農園芸用殺虫剤として公知の化合物Ａは、粉剤、水利剤
、粒剤に常用される鉱物質担体、例えば、クレー、タル
ク、ベントナイトなどに担持せしめて粉剤、水和剤など
に製剤化し、長期間貯蔵すると、経時的に化合物Ａが分
離し、貯蔵中の製剤の劣化、殺虫剤として使用したとき
に生物活性の低下や分解生成物による作物への薬害など
を招く。Problem to be Solved by the Invention Compound A, which is known as an agricultural and horticultural insecticide, can be prepared by supporting it on a mineral carrier commonly used in powders, irrigation agents, and granules, such as clay, talc, bentonite, etc. When formulated into a pesticide and stored for a long period of time, Compound A separates over time, leading to deterioration of the formulation during storage, a decrease in biological activity when used as an insecticide, and chemical damage to crops due to decomposition products. .
しかしながら、これまで化合物Ａの経時的安定化をはか
る技術はまだ確立されていない。However, no technology has been established to stabilize Compound A over time.
したがって、本発明は、化合物Ａを含有する殺虫製剤の
経時的安定化技術を提供せんとするにある。Therefore, the present invention aims to provide a technique for stabilizing an insecticidal formulation containing Compound A over time.
■ 発明の構成
課題を解決するだめの手段
本発明者らは、かかる現状に鑑み、前記殺虫成分である
化合物Ａを有する製剤の安定化を図る新規な技術につい
て鋭意研究を重ねた。その結果、エポキシ化グリセリド
および２．６−ジ−ｔｅｒｔ−ブチル−４−メチルフェ
ノール（以下１７ＨＴ、、＋という）を、これらの合計
量として興剤中に０．５重量％以上、望ましくは、０．
５〜１０重量％以上を添加することにより、化合物Ａの
経時的分解を長期間にわたり抑制しうろことを見出し、
本発明を完成するに至った。(2) Means for Solving the Constituent Problems of the Invention In view of the current situation, the present inventors have conducted intensive research on a new technique for stabilizing a preparation containing Compound A, which is the insecticidal component. As a result, the total amount of epoxidized glyceride and 2,6-di-tert-butyl-4-methylphenol (hereinafter referred to as 17HT) is 0.5% by weight or more in the agent, preferably, 0.
It has been discovered that by adding 5 to 10% by weight or more, the decomposition of compound A over time can be suppressed for a long period of time,
The present invention has now been completed.
本発明に使用されるエポキシ化グリセリドは、エポキシ
化大豆油、エポキシ化菜種油、エボキン化綿実油、エポ
キシ化菜種油などが挙げられるが、これらの例示のみに
限定されるものではない。The epoxidized glyceride used in the present invention includes, but is not limited to, epoxidized soybean oil, epoxidized rapeseed oil, evoquinized cottonseed oil, and epoxidized rapeseed oil.
本発明のエポキシ化グリセリドおよびＢ）ＩＴの添加量
は、これらの合軒量として製剤中に０．５重量％以上で
あればよく、効果と経済性を考えると、１．０〜ＩＯ重
量％が望ましい。また、エポキシ化グリセリドとＢＨＴ
の製剤中への配合比率は、エポキシ化グリセリド１重量
部に対し、ＢＨＴ Ｏ，５〜２重量部の範囲が望まし
いが、剤型などにより、適宜変動させてもかまわない。The amount of the epoxidized glyceride of the present invention and B) IT to be added may be 0.5% by weight or more in the formulation as a combined amount of these, and from 1.0 to IO% by weight considering effectiveness and economy. is desirable. Also, epoxidized glycerides and BHT
The blending ratio in the formulation is preferably in the range of 5 to 2 parts by weight of BHT O per 1 part by weight of epoxidized glyceride, but it may be varied as appropriate depending on the dosage form.
作 用
化合物Ａを含む殺虫製剤にエポキシ化グリセリドとＢＨ
Ｔを同時に添加することにより、化合物Ａの貯蔵中の分
解を長期間にわたり抑制する。Epoxidized glycerides and BH in insecticidal preparations containing active compound A.
By adding T at the same time, decomposition of Compound A during storage is suppressed for a long period of time.
したがって、本発明では、これらの２種の添加剤は化合
物Ａの経時的分解防止剤として作用する。Therefore, in the present invention, these two additives act as agents for preventing compound A from decomposing over time.
本発明の実施方法（ＩＩ剤化の方法）
本発明の安定な殺虫製剤を製造するには、化合物Ａ１エ
ポキシ化グリセリド、ＢＨＴ、担体、その他必要に応じ
て種々の補助剤を添加することにより、常法によって、
粉剤、ＤＬ粉剤、水利剤、顆粒水利剤、粒剤、微粒剤な
ど各種剤型に製剤化できる。Method of carrying out the present invention (Method of formulating II) In order to produce the stable insecticidal formulation of the present invention, by adding Compound A1 epoxidized glyceride, BHT, a carrier, and other various auxiliary agents as necessary, By common law,
It can be formulated into various dosage forms such as powders, DL powders, irrigation agents, granular irrigation agents, granules, and fine granules.
また、本発明で用いることのできる担体としては、特に
限定されることはないが、例えば、クレー、タルク、ベ
ントナイト、珪藻土、ゼオライト、パーライト、酸性白
土、珪砂などの一般鉱物質担体、炭酸カルシウム、炭酸
マグネシウム、硫酸ナトリウム、硫酸アンモニウム、硫
酸カルシウム、酸化チタン、蔗糖、カゼイン、デンプン
などを挙げることができる。Further, carriers that can be used in the present invention are not particularly limited, but include, for example, general mineral carriers such as clay, talc, bentonite, diatomaceous earth, zeolite, perlite, acid clay, and silica sand, calcium carbonate, Examples include magnesium carbonate, sodium sulfate, ammonium sulfate, calcium sulfate, titanium oxide, sucrose, casein, and starch.
また、本発明の安定な殺虫製剤は、殺菌剤、殺虫剤、植
物成長調節剤などと混合して使用できる。Furthermore, the stable insecticidal formulation of the present invention can be used in combination with fungicides, insecticides, plant growth regulators, and the like.
次に本発明の安定な殺虫製剤の製剤化の実施例について
説明するが、これら実施例に限定されるものではなく、
化合物Ａの含有量、安定化剤の添加量、各種補助剤の種
類とその添加量、製剤化方法などは適宜変更して実施す
ることができる。Next, examples of formulation of the stable insecticidal formulation of the present invention will be described, but the invention is not limited to these examples.
The content of compound A, the amount of stabilizer added, the types and amounts of various auxiliary agents added, the formulation method, etc. can be changed as appropriate.
なお、実施例中で部とは、すべて重量部を示す。In addition, all parts in Examples indicate parts by weight.
実施例１ 粉剤
化合物Ａ ２部、ホワイトカーボン １部、エポキシ化
ナタ不油 ２部、Ｂ）ＩＴ １部、クレー９４ｇをハン
マーミルで混合して本発明の粉剤を得る。Example 1 A powder agent of the present invention is obtained by mixing 2 parts of powder compound A, 1 part of white carbon, 2 parts of epoxidized Nata oil, 1 part of B)IT, and 94 g of clay in a hammer mill.
実施例２ 粉剤ＤＬ
化合物Ａ ２．０部、０−ｓｅｃ−ブチルフェニル−Ｎ
−メチルカーバメート３．０部、ホワイトカーボン ３
．０部、エポキシ化大豆油 １．０部、ＢＨＴ２．０部
、トリレスＣ（三共（株）製ドリフト防止剤の商品名）
０．３部、クレー８８．７部をハンマーミルで混合して
本発明の粉剤ＤＬを得る。Example 2 Powder DL Compound A 2.0 parts, 0-sec-butylphenyl-N
-Methyl carbamate 3.0 parts, white carbon 3
．． 0 parts, epoxidized soybean oil 1.0 parts, BHT 2.0 parts, Toriless C (trade name of anti-drift agent manufactured by Sankyo Co., Ltd.)
0.3 parts of clay and 88.7 parts of clay were mixed in a hammer mill to obtain the powder DL of the present invention.
実施例３ 粒剤
化合物Ａ ４部、Ｏ−５ｅｃ−ブチル７ ｘ ニー ル
ーＮ−メチルカーバメート ４部、エポキシ化亜麻仁油
２部、８８７１部、ポリビニルアルコール ２部、ク
レー８７部をハンマーミルで混合し、次いで水 １５部
を加えて押し出し造粒機で造粒する。乾燥後、篩別（１
４〜３２メツシユ）して本発明の粉剤を得る。Example 3 4 parts of granule compound A, 4 parts of O-5ec-butyl 7 x N-methyl carbamate, 2 parts of epoxidized linseed oil, 8871 parts, 2 parts of polyvinyl alcohol, and 87 parts of clay were mixed in a hammer mill. Then, 15 parts of water is added and granulated using an extrusion granulator. After drying, sieve (1
4 to 32 meshes) to obtain the powder of the present invention.
実施例４ 水利剤
化合物Ａ、 ５０部、ホワイトカーボン １０部、エポ
キシ化大豆油 ２部、８８７２部、ポリオキシエチレン
アルキルフェニルエーテル ３部、ナフタレンスルホン
際ソーダホルマリン縮金物２部、クレー ３３部をハン
マーミルで混合して本発明の水利剤を得る。Example 4 Irrigation compound A, 50 parts, white carbon 10 parts, epoxidized soybean oil 2 parts, 8872 parts, polyoxyethylene alkylphenyl ether 3 parts, naphthalene sulfone-condensed soda formalin metal 2 parts, and clay 33 parts were hammered. The water conservancy of the present invention is obtained by mixing in a mill.
発明の効果
化合物Ａを含有する殺虫製剤にエポキシ化グリセリドお
よびＢＩＴを、製剤全量の０．５重量％以上、望ましく
は、０．５〜１Ｏ００重量％となるように添加すること
により、４０°０１６０日問および４０”ｃ、ｓｏ％Ｒ
Ｈ（湿度、６０日間の貯蔵テスト後も、有効成分である
化合物Ａの分解率は０．・５〜３．０％に抑制される。Effects of the Invention By adding epoxidized glyceride and BIT to an insecticidal preparation containing Compound A in an amount of 0.5% by weight or more, preferably 0.5 to 1000% by weight of the total amount of the preparation, 40°0160 daily questions and 40”c, so%R
H (humidity) Even after a 60-day storage test, the decomposition rate of Compound A, the active ingredient, is suppressed to 0.5 to 3.0%.
したがって、本発明の安定な殺虫製剤は、長期間貯蔵後
でも、その殺虫効力を有効に保有する。Therefore, the stable insecticidal formulation of the present invention effectively retains its insecticidal efficacy even after long-term storage.
次に、本発明の安定化効果を試験例により立証する。Next, the stabilizing effect of the present invention will be demonstrated through test examples.
実験例１ 分解防止効果試験
実施例にしたがって調製した製剤１００ｇを広口褐色ガ
ラス瓶に入れて密栓し、４０℃の恒温器へ、更に１００
ｇをクラフト袋に入れて密封し、４０℃、相対湿度８０
％の状態に設定した恒温湿器の中へ放置する。Experimental Example 1 Decomposition Prevention Effect Test 100 g of the preparation prepared according to Example was placed in a wide-mouth brown glass bottle, tightly stoppered, and placed in a thermostat at 40°C for further 100 g.
g in a kraft bag, sealed, 40℃, relative humidity 80
Leave it in a constant temperature and humidity chamber set at %.
放置後６０日後（常温で２か年貯蔵したことに相当）、
それぞれの状態より取り出し、化合物Ａの含有量を液体
クロマトグラフにより分析し、初期含有量に対する分解
率（％）を求めた。得られた結果を第１表に示す。60 days after leaving it (equivalent to 2 years of storage at room temperature)
The samples were taken out from each state, and the content of compound A was analyzed by liquid chromatography to determine the decomposition rate (%) relative to the initial content. The results obtained are shown in Table 1.
Claims (1)
ス−ベンゼンチオスルホネートを有効成分として、含有
する殺虫製剤において、エポキシ化グリセリドおよび２
，６−ジ−ｔｅｒｔ−ブチル−４−メチルフェノールを
添加してなることを特徴とする、安定な殺虫製剤[Scope of Claim] An insecticidal preparation containing S,S'-[2-(dimethylamino)trimethylene]bis-benzenethiosulfonate as an active ingredient, epoxidized glyceride and
, 6-di-tert-butyl-4-methylphenol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP32518890A JPH04198105A (en) | 1990-11-29 | 1990-11-29 | Stable insecticide preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP32518890A JPH04198105A (en) | 1990-11-29 | 1990-11-29 | Stable insecticide preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04198105A true JPH04198105A (en) | 1992-07-17 |
Family
ID=18173997
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP32518890A Pending JPH04198105A (en) | 1990-11-29 | 1990-11-29 | Stable insecticide preparation |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04198105A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006124478A (en) * | 2004-10-27 | 2006-05-18 | Nitto Denko Corp | Semiconductor-sealing epoxy resin composition and semiconductor device sealed therewith |
-
1990
- 1990-11-29 JP JP32518890A patent/JPH04198105A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006124478A (en) * | 2004-10-27 | 2006-05-18 | Nitto Denko Corp | Semiconductor-sealing epoxy resin composition and semiconductor device sealed therewith |
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