JPH04194841A - Silver halide photosensitive material - Google Patents
Silver halide photosensitive materialInfo
- Publication number
- JPH04194841A JPH04194841A JP31974390A JP31974390A JPH04194841A JP H04194841 A JPH04194841 A JP H04194841A JP 31974390 A JP31974390 A JP 31974390A JP 31974390 A JP31974390 A JP 31974390A JP H04194841 A JPH04194841 A JP H04194841A
- Authority
- JP
- Japan
- Prior art keywords
- group
- silver halide
- salt
- silver
- formulas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 Silver halide Chemical class 0.000 title claims abstract description 72
- 229910052709 silver Inorganic materials 0.000 title claims abstract description 50
- 239000004332 silver Substances 0.000 title claims abstract description 50
- 239000000463 material Substances 0.000 title claims description 28
- 239000000975 dye Substances 0.000 claims abstract description 39
- 239000000839 emulsion Substances 0.000 claims abstract description 37
- 150000003839 salts Chemical class 0.000 claims abstract description 23
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 11
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 9
- 150000001450 anions Chemical class 0.000 claims abstract description 7
- 125000004433 nitrogen atom Chemical group N* 0.000 claims abstract description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 3
- 125000001424 substituent group Chemical group 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 6
- 230000002378 acidificating effect Effects 0.000 claims description 5
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 claims description 5
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 claims 2
- 239000011248 coating agent Substances 0.000 abstract description 22
- 238000000576 coating method Methods 0.000 abstract description 22
- 238000012545 processing Methods 0.000 abstract description 20
- 239000000758 substrate Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 30
- 239000000243 solution Substances 0.000 description 22
- 239000010410 layer Substances 0.000 description 18
- 108010010803 Gelatin Proteins 0.000 description 15
- 229920000159 gelatin Polymers 0.000 description 15
- 239000008273 gelatin Substances 0.000 description 15
- 235000019322 gelatine Nutrition 0.000 description 15
- 235000011852 gelatine desserts Nutrition 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 239000007864 aqueous solution Substances 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 13
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 13
- 238000011161 development Methods 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 10
- 239000002245 particle Substances 0.000 description 10
- 239000000084 colloidal system Substances 0.000 description 8
- 206010070834 Sensitisation Diseases 0.000 description 7
- 239000013078 crystal Substances 0.000 description 7
- 230000008313 sensitization Effects 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 6
- 125000000542 sulfonic acid group Chemical group 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 5
- 235000010724 Wisteria floribunda Nutrition 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 229910052731 fluorine Inorganic materials 0.000 description 5
- 239000004816 latex Substances 0.000 description 5
- 229920000126 latex Polymers 0.000 description 5
- ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphonic acid group Chemical group P(O)(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- 125000002843 carboxylic acid group Chemical group 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 4
- 229910052737 gold Inorganic materials 0.000 description 4
- 239000010931 gold Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 239000002216 antistatic agent Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 238000003780 insertion Methods 0.000 description 3
- 230000037431 insertion Effects 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000004848 polyfunctional curative Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 230000005070 ripening Effects 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 230000001235 sensitizing effect Effects 0.000 description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 229920002307 Dextran Polymers 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical group NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- 241000047703 Nonion Species 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 238000000149 argon plasma sintering Methods 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- JEHKKBHWRAXMCH-UHFFFAOYSA-N benzenesulfinic acid Chemical compound O[S@@](=O)C1=CC=CC=C1 JEHKKBHWRAXMCH-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 2
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000012362 glacial acetic acid Substances 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- YFSUTJLHUFNCNZ-UHFFFAOYSA-N perfluorooctane-1-sulfonic acid Chemical class OS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YFSUTJLHUFNCNZ-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 229930182490 saponin Natural products 0.000 description 2
- 150000007949 saponins Chemical class 0.000 description 2
- 235000017709 saponins Nutrition 0.000 description 2
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- IZWPGJFSBABFGL-GMFCBQQYSA-M sodium;2-[methyl-[(z)-octadec-9-enoyl]amino]ethanesulfonate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CCS([O-])(=O)=O IZWPGJFSBABFGL-GMFCBQQYSA-M 0.000 description 2
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 150000003871 sulfonates Chemical class 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 150000003557 thiazoles Chemical class 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 2
- 150000003585 thioureas Chemical class 0.000 description 2
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 1
- PQMFVUNERGGBPG-UHFFFAOYSA-N (6-bromopyridin-2-yl)hydrazine Chemical compound NNC1=CC=CC(Br)=N1 PQMFVUNERGGBPG-UHFFFAOYSA-N 0.000 description 1
- LUMLZKVIXLWTCI-NSCUHMNNSA-N (e)-2,3-dichloro-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Cl)=C(/Cl)C=O LUMLZKVIXLWTCI-NSCUHMNNSA-N 0.000 description 1
- QNRATNLHPGXHMA-XZHTYLCXSA-N (r)-(6-ethoxyquinolin-4-yl)-[(2s,4s,5r)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]methanol;hydrochloride Chemical compound Cl.C([C@H]([C@H](C1)CC)C2)CN1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OCC)C=C21 QNRATNLHPGXHMA-XZHTYLCXSA-N 0.000 description 1
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical class C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical class C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- WGJCBBASTRWVJL-UHFFFAOYSA-N 1,3-thiazolidine-2-thione Chemical compound SC1=NCCS1 WGJCBBASTRWVJL-UHFFFAOYSA-N 0.000 description 1
- SAVMNSHHXUMFRQ-UHFFFAOYSA-N 1-[bis(ethenylsulfonyl)methoxy-ethenylsulfonylmethyl]sulfonylethene Chemical compound C=CS(=O)(=O)C(S(=O)(=O)C=C)OC(S(=O)(=O)C=C)S(=O)(=O)C=C SAVMNSHHXUMFRQ-UHFFFAOYSA-N 0.000 description 1
- GIJHFRSMIIPVIJ-UHFFFAOYSA-N 1-ethoxyethanesulfonic acid Chemical compound CCOC(C)S(O)(=O)=O GIJHFRSMIIPVIJ-UHFFFAOYSA-N 0.000 description 1
- ZBHBIODEONVIMN-UHFFFAOYSA-N 1-phenyl-2h-tetrazole-5-thione;silver Chemical compound [Ag].S=C1N=NNN1C1=CC=CC=C1 ZBHBIODEONVIMN-UHFFFAOYSA-N 0.000 description 1
- JAAIPIWKKXCNOC-UHFFFAOYSA-N 1h-tetrazol-1-ium-5-thiolate Chemical class SC1=NN=NN1 JAAIPIWKKXCNOC-UHFFFAOYSA-N 0.000 description 1
- HAZJTCQWIDBCCE-UHFFFAOYSA-N 1h-triazine-6-thione Chemical class SC1=CC=NN=N1 HAZJTCQWIDBCCE-UHFFFAOYSA-N 0.000 description 1
- FXKZPKBFTQUJBA-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetic acid;sodium;dihydrate Chemical compound O.O.[Na].[Na].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O FXKZPKBFTQUJBA-UHFFFAOYSA-N 0.000 description 1
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- PHPYXVIHDRDPDI-UHFFFAOYSA-N 2-bromo-1h-benzimidazole Chemical class C1=CC=C2NC(Br)=NC2=C1 PHPYXVIHDRDPDI-UHFFFAOYSA-N 0.000 description 1
- AYPSHJCKSDNETA-UHFFFAOYSA-N 2-chloro-1h-benzimidazole Chemical class C1=CC=C2NC(Cl)=NC2=C1 AYPSHJCKSDNETA-UHFFFAOYSA-N 0.000 description 1
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- QWZOJDWOQYTACD-UHFFFAOYSA-N 2-ethenylsulfonyl-n-[2-[(2-ethenylsulfonylacetyl)amino]ethyl]acetamide Chemical compound C=CS(=O)(=O)CC(=O)NCCNC(=O)CS(=O)(=O)C=C QWZOJDWOQYTACD-UHFFFAOYSA-N 0.000 description 1
- KTSDQEHXNNLUEA-UHFFFAOYSA-N 2-ethenylsulfonylacetamide Chemical compound NC(=O)CS(=O)(=O)C=C KTSDQEHXNNLUEA-UHFFFAOYSA-N 0.000 description 1
- 229940080296 2-naphthalenesulfonate Drugs 0.000 description 1
- KRTDQDCPEZRVGC-UHFFFAOYSA-N 2-nitro-1h-benzimidazole Chemical class C1=CC=C2NC([N+](=O)[O-])=NC2=C1 KRTDQDCPEZRVGC-UHFFFAOYSA-N 0.000 description 1
- JSIAIROWMJGMQZ-UHFFFAOYSA-N 2h-triazol-4-amine Chemical class NC1=CNN=N1 JSIAIROWMJGMQZ-UHFFFAOYSA-N 0.000 description 1
- CBHTTYDJRXOHHL-UHFFFAOYSA-N 2h-triazolo[4,5-c]pyridazine Chemical class N1=NC=CC2=C1N=NN2 CBHTTYDJRXOHHL-UHFFFAOYSA-N 0.000 description 1
- PHBQDVOLZRHPOJ-UHFFFAOYSA-N 3-ethenylsulfonyl-n-[(3-ethenylsulfonylpropanoylamino)methyl]propanamide Chemical compound C=CS(=O)(=O)CCC(=O)NCNC(=O)CCS(=O)(=O)C=C PHBQDVOLZRHPOJ-UHFFFAOYSA-N 0.000 description 1
- OWIRCRREDNEXTA-UHFFFAOYSA-N 3-nitro-1h-indazole Chemical class C1=CC=C2C([N+](=O)[O-])=NNC2=C1 OWIRCRREDNEXTA-UHFFFAOYSA-N 0.000 description 1
- NYYSPVRERVXMLJ-UHFFFAOYSA-N 4,4-difluorocyclohexan-1-one Chemical compound FC1(F)CCC(=O)CC1 NYYSPVRERVXMLJ-UHFFFAOYSA-N 0.000 description 1
- DSVIHYOAKPVFEH-UHFFFAOYSA-N 4-(hydroxymethyl)-4-methyl-1-phenylpyrazolidin-3-one Chemical compound N1C(=O)C(C)(CO)CN1C1=CC=CC=C1 DSVIHYOAKPVFEH-UHFFFAOYSA-N 0.000 description 1
- ZFIQGRISGKSVAG-UHFFFAOYSA-N 4-methylaminophenol Chemical compound CNC1=CC=C(O)C=C1 ZFIQGRISGKSVAG-UHFFFAOYSA-N 0.000 description 1
- LRUDIIUSNGCQKF-UHFFFAOYSA-N 5-methyl-1H-benzotriazole Chemical compound C1=C(C)C=CC2=NNN=C21 LRUDIIUSNGCQKF-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- KHBQMWCZKVMBLN-UHFFFAOYSA-N Benzenesulfonamide Chemical compound NS(=O)(=O)C1=CC=CC=C1 KHBQMWCZKVMBLN-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical group C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- AFVFQIVMOAPDHO-UHFFFAOYSA-M Methanesulfonate Chemical compound CS([O-])(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-M 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 1
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 1
- 101100274389 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) chz-1 gene Proteins 0.000 description 1
- 229920003171 Poly (ethylene oxide) Chemical class 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical class C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- RWRDLPDLKQPQOW-UHFFFAOYSA-O Pyrrolidinium ion Chemical compound C1CC[NH2+]C1 RWRDLPDLKQPQOW-UHFFFAOYSA-O 0.000 description 1
- 101710084593 Sensory histidine kinase/phosphatase NtrB Proteins 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- SRNKZYRMFBGSGE-UHFFFAOYSA-N [1,2,4]triazolo[1,5-a]pyrimidine Chemical compound N1=CC=CN2N=CN=C21 SRNKZYRMFBGSGE-UHFFFAOYSA-N 0.000 description 1
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
- XCFIVNQHHFZRNR-UHFFFAOYSA-N [Ag].Cl[IH]Br Chemical compound [Ag].Cl[IH]Br XCFIVNQHHFZRNR-UHFFFAOYSA-N 0.000 description 1
- XEIPQVVAVOUIOP-UHFFFAOYSA-N [Au]=S Chemical compound [Au]=S XEIPQVVAVOUIOP-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910001963 alkali metal nitrate Inorganic materials 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- UMGDCJDMYOKAJW-UHFFFAOYSA-N aminothiocarboxamide Natural products NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 1
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical class C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 150000001649 bromium compounds Chemical class 0.000 description 1
- 239000006172 buffering agent Substances 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 150000001661 cadmium Chemical class 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 description 1
- 125000002433 cyclopentenyl group Chemical group C1(=CCCC1)* 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011033 desalting Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 229940052303 ethers for general anesthesia Drugs 0.000 description 1
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002344 gold compounds Chemical class 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- AKCUHGBLDXXTOM-UHFFFAOYSA-N hydroxy-oxo-phenyl-sulfanylidene-$l^{6}-sulfane Chemical compound SS(=O)(=O)C1=CC=CC=C1 AKCUHGBLDXXTOM-UHFFFAOYSA-N 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 150000002503 iridium Chemical class 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- ZAKLKBFCSHJIRI-UHFFFAOYSA-N mucochloric acid Natural products OC1OC(=O)C(Cl)=C1Cl ZAKLKBFCSHJIRI-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SQDFHQJTAWCFIB-UHFFFAOYSA-N n-methylidenehydroxylamine Chemical compound ON=C SQDFHQJTAWCFIB-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- KVBGVZZKJNLNJU-UHFFFAOYSA-M naphthalene-2-sulfonate Chemical compound C1=CC=CC2=CC(S(=O)(=O)[O-])=CC=C21 KVBGVZZKJNLNJU-UHFFFAOYSA-M 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 150000004957 nitroimidazoles Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 description 1
- 229950005308 oxymethurea Drugs 0.000 description 1
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- 125000003386 piperidinyl group Chemical group 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- NDGRWYRVNANFNB-UHFFFAOYSA-N pyrazolidin-3-one Chemical class O=C1CCNN1 NDGRWYRVNANFNB-UHFFFAOYSA-N 0.000 description 1
- 125000001725 pyrenyl group Chemical group 0.000 description 1
- UGZVCHWAXABBHR-UHFFFAOYSA-O pyridin-1-ium-1-carboxamide Chemical class NC(=O)[N+]1=CC=CC=C1 UGZVCHWAXABBHR-UHFFFAOYSA-O 0.000 description 1
- HBCQSNAFLVXVAY-UHFFFAOYSA-N pyrimidine-2-thiol Chemical class SC1=NC=CC=N1 HBCQSNAFLVXVAY-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 150000003283 rhodium Chemical class 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- BJWBFXNBFFXUCR-UHFFFAOYSA-M sodium;3,3,5,5-tetramethyl-2-(2-phenoxyethoxy)hexane-2-sulfonate Chemical compound [Na+].CC(C)(C)CC(C)(C)C(C)(S([O-])(=O)=O)OCCOC1=CC=CC=C1 BJWBFXNBFFXUCR-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 150000003431 steroids Chemical class 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229940104261 taurate Drugs 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- 150000003475 thallium Chemical class 0.000 description 1
- JJJPTTANZGDADF-UHFFFAOYSA-N thiadiazole-4-thiol Chemical class SC1=CSN=N1 JJJPTTANZGDADF-UHFFFAOYSA-N 0.000 description 1
- 150000003567 thiocyanates Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 125000005323 thioketone group Chemical group 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/10—Organic substances
- G03C1/12—Methine and polymethine dyes
- G03C1/14—Methine and polymethine dyes with an odd number of CH groups
- G03C1/20—Methine and polymethine dyes with an odd number of CH groups with more than three CH groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/0008—Methine or polymethine dyes, e.g. cyanine dyes substituted on the polymethine chain
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/0066—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain being part of a carbocyclic ring,(e.g. benzene, naphtalene, cyclohexene, cyclobutenene-quadratic acid)
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/02—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups
- C09B23/08—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups more than three >CH- groups, e.g. polycarbocyanines
- C09B23/086—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups more than three >CH- groups, e.g. polycarbocyanines more than five >CH- groups
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明はハロゲン化銀写真感光材料に関し、特に黒白用
ハロゲン化銀写真感光材料を自動現像機（以下、自現機
と呼ぶ）で処理する際に感光材料の位置を検出しやすい
ようにする技術に関するものである。[Detailed Description of the Invention] (Industrial Application Field) The present invention relates to silver halide photographic materials, and in particular, to processing silver halide photographic materials for black and white using an automatic processor (hereinafter referred to as an automatic processor). This invention relates to a technology that makes it easier to detect the position of a photosensitive material.
（従来の技術）
近年感光材料は迅速処理のニーズが高く、特にχレイを
用いる感材においては４５秒で処理工程を終了させるシ
ステムが普及し始めている。また処理液の補充を低減さ
せるといったニーズも高くなっている。このため塗布銀
量を減少させる傾向は大きな流れとなっている。この時
自現機を含めた搬送系に設置させている赤外センサーの
遮光性が減少するため感光材料の位置検出が不能となり
搬送不良の原因となってしまう。(Prior Art) In recent years, there has been a strong need for rapid processing of photosensitive materials, and systems that can complete the processing process in 45 seconds are beginning to become popular, especially for photosensitive materials using chi-ray. There is also a growing need to reduce the need for replenishment of processing liquids. For this reason, there is a major trend toward reducing the amount of coated silver. At this time, the light-shielding ability of the infrared sensor installed in the conveyance system including the automatic processing machine is reduced, making it impossible to detect the position of the photosensitive material and causing conveyance failure.
特開昭６２−２９９９５９号にはある種の赤外線吸収色
素を使用することにより検出不良を改良することが開示
されているが、これはわざわざハロゲン化銀粒子に色素
を吸着させて使用する必要があり、処理工程（特にＦｉ
ｘ ）に負担をかけるし、塗布ハンドリング上複雑であ
ると共に、色素自身可視域の吸収があり銀画像を観察す
る黒白感材では残色として問題となってくる。また特開
昭６３−１３１１３５号に記載のようにハロゲン化銀粒
子のような光散乱粒子を利用して検出不良を改良する方
法が開示されているが、屈折率を利用しているだけなの
でセンサーに対する遮蔽効果が小さいし、ハロゲン化銀
粒子の場合にはＦｉｘ （定着液）に負担をかけるので
、補充液を減らし、且つ迅速処理をする場合には非常に
厳しくなってくる。JP-A No. 62-299959 discloses that poor detection can be improved by using a certain type of infrared absorbing dye, but this requires the dye to be adsorbed onto silver halide grains. Yes, processing steps (especially Fi)
x), is complicated in terms of coating handling, and the dye itself absorbs in the visible range, which poses a problem as residual color in black-and-white photosensitive materials for viewing silver images. In addition, as described in JP-A-63-131135, a method is disclosed that uses light-scattering particles such as silver halide particles to improve detection defects, but since it only uses the refractive index, the sensor In the case of silver halide grains, the shielding effect is small, and in the case of silver halide grains, it places a burden on the Fix (fixer), so it becomes very difficult to reduce the amount of replenisher and to perform rapid processing.
（発明の目的）
本発明の目的は、塗布銀量の少ないハロゲン化銀感光材
料を用いて、補充液の少ない処理系でなおかつ迅速処理
ができるようにし、写真性に影響を与えずにフィルム検
出をしている装置の検出不能をな（すように作られたハ
ロゲン化銀写真感光材料を提供することにある。(Objective of the Invention) The object of the present invention is to use a silver halide photosensitive material with a small amount of coated silver, to enable rapid processing in a processing system with a small amount of replenisher, and to enable film detection without affecting photographic properties. The object of the present invention is to provide a silver halide photographic light-sensitive material that is made to be undetectable by the apparatus used in the present invention.
（問題点を解決するための手段）
本発明の目的は、支持体の少なくとも片側に一層の感光
性ハロゲン化銀乳荊層を有し、両側の塗布銀量の合計が
４．０ｇ／ｍ２未満であり、かつ下記一般弐Ｎ）及び（
Ｈ）で表される染料から選ばれる少なくとも一種を含有
することを特徴とするハロゲン化銀写真感光材料によっ
て達成された。(Means for Solving the Problems) An object of the present invention is to have one photosensitive silver halide opalescent layer on at least one side of the support, and the total amount of coated silver on both sides is less than 4.0 g/m2. , and the following general 2N) and (
This was achieved by a silver halide photographic material containing at least one kind selected from the dyes represented by H).
一般弐Ｎ）
（×−）。−１
式中、Ｒ１、Ｒ２、Ｒゴ、およびＲ４は互いに同しでも
異なっていても良く、水素原子、あるいはアルキル基を
示し、Ｒ’ とＲ２、Ｒ″とＲ４で５〜６員環を形成し
てもよく、またＲ’ 、Ｒ２、Ｒ’、Ｒ’のいずれか、
Ｎ原子及び隣接するヘンゼン環とで５〜６員環を形成し
てもよい。Ｒ５およびＲ６は互いに同しでも異なってい
てもよく、水素原子または１価の基を表わし、χ−はア
ニオンを示し、ｎは１または２であり、染料分子が分子
内塩を形成するときは１である。General 2N) (×-). -1 In the formula, R1, R2, Rgo, and R4 may be the same or different and represent a hydrogen atom or an alkyl group, and R' and R2, R'' and R4 form a 5- to 6-membered ring. Also, any one of R', R2, R', R',
A 5- to 6-membered ring may be formed with the N atom and the adjacent Hensen ring. R5 and R6 may be the same or different and represent a hydrogen atom or a monovalent group, χ- represents an anion, n is 1 or 2, and when the dye molecule forms an intramolecular salt, It is 1.
一般式（１
％式％）
式中、Ｒ７およびＲ８は互いニニ同りでも異なっていて
も良くアルキル基を示し、Ｒ９およびＲｔ。General formula (1% formula%) In the formula, R7 and R8 may be the same or different and represent an alkyl group, and R9 and Rt.
は互いに同しでも異なっていても良く、水素原子または
１価の基を表わし、Ｌはメチン基を表わし、Ｘ−はアニ
オンを示し、ｎは１または２であり、染料分子が分子内
塩を形成するときは１である。may be the same or different and represent a hydrogen atom or a monovalent group, L represents a methine group, X- represents an anion, n is 1 or 2, and the dye molecule forms an inner salt. When forming, it is 1.
また、特に好ましくは、一般式（１）及び（＋１１１に
おいて、各々の染料分子が少なくとも２個の酸性置換基
を有することによって達成できることがわかった。It has also been found that this can be particularly preferably achieved by each dye molecule having at least two acidic substituents in the general formulas (1) and (+111).
本発明の特徴の一つは、塗布銀量のトータルが、４ 、
０ ｇ ／ｖａ２以下、特巳こ好ましくは、１．０ｇ
／ｍ２〜３．５ｇ／Ｐ２であること乙こある。ここにト
ータルとは、ハロゲン化銀乳剤層が複数層ある場合、及
び支持体の両側にそれぞれ１層以上のハロゲン化銀乳剤
層がある場合にはこれらの全ハロゲン化銀乳剤層におけ
る塗布銀量の総和を表わす。One of the features of the present invention is that the total amount of coated silver is 4,
0 g/va2 or less, preferably 1.0 g
/m2~3.5g/P2. Here, total refers to the amount of coated silver in all silver halide emulsion layers when there are multiple silver halide emulsion layers or when there are one or more silver halide emulsion layers on both sides of the support. represents the sum of
一般式（１）および（ＩＩ） ！こついて詳述する。General formulas (1) and (II)! I will explain in detail.
Ｒ電、Ｒ２、Ｒ３、Ｒ４、Ｒ７およびＲＩ＋で表される
アルキル基は好まし、くは炭素数１〜５の低級アルキル
基（例えばメチル基、エチル基、ｎ−ブチル基、イソプ
ロピル基、ｎ−ペンチル基など）を表わし、置換基（例
えばスルホン酸基、カルボン酸基、水酸基、ホスホン酸
基など）を存していてもよい。さらに好ましくは、スル
ホン酸基を有する炭素数１〜５の低級アルキル基（例え
ば２−スルホエチル基、３−スルホプロピル基、４−ス
ルホブチル基など）を表わす。Alkyl groups represented by R, R2, R3, R4, R7 and RI+ are preferred, or lower alkyl groups having 1 to 5 carbon atoms (e.g. methyl group, ethyl group, n-butyl group, isopropyl group, n -pentyl group, etc.), and may have a substituent (for example, a sulfonic acid group, a carboxylic acid group, a hydroxyl group, a phosphonic acid group, etc.). More preferably, it represents a lower alkyl group having 1 to 5 carbon atoms (eg, 2-sulfoethyl group, 3-sulfopropyl group, 4-sulfobutyl group, etc.) having a sulfonic acid group.
本発明において酸性置換基とは、スルホン酸基、ホスホ
ン酸基またはカルボン酸基を表わし、スルホン酸基とは
スルホ基またはその塩を、ホス、云ン′酸基と；よホス
ホン酸またはその塩を、カルボン酸基とはカルボニル基
またはその塩を、それぞれ意味する。塩の例としては、
Ｎａ、になどのアルカリ金属塩、アンモニウム塩、トリ
ブチルアミン′、トリブチルアミン、ピリ、ブンなどの
有機アンモニウム塩を挙げることが出来る。In the present invention, the acidic substituent refers to a sulfonic acid group, a phosphonic acid group, or a carboxylic acid group, and a sulfonic acid group refers to a sulfo group or a salt thereof, a phosphonic acid group or a salt thereof, a phosphonic acid group, or a phosphonic acid group or a salt thereof. and the carboxylic acid group means a carbonyl group or a salt thereof, respectively. An example of salt is
Examples include alkali metal salts such as Na and Ni, ammonium salts, organic ammonium salts such as tributylamine', tributylamine, pyryl, and bung.
特に染料分子内に２個の酸性置換基（さら６二好まじく
はスルホン酸基）を有することが好ましい。In particular, it is preferable to have two acidic substituents (and preferably two sulfonic acid groups) in the dye molecule.
Ｒ１とＲ２、Ｒ１とＲ″で５〜６員環を形成してもよい
。（例えばモルホリン環、ピペリジン環など）またＲ’
、Ｒ２、Ｒ３、Ｒ’のいずれが、Ｎ原子及び隣接する
ヘンゼン環とで５〜６員環を形成してもよい（例えばイ
ンドリン環など）。R1 and R2, R1 and R'' may form a 5- to 6-membered ring (for example, a morpholine ring, a piperidine ring, etc.) or R'
, R2, R3, and R' may form a 5- to 6-membered ring with the N atom and the adjacent Hensen ring (for example, an indoline ring).
Ｒ’、Ｒ６、Ｒ９およびＲ１６で表される一価の基とし
ては、低級アルキル基（例えば、メチル基、エチル基等
）、低級アルコキシ基（メトキシ基など）、ハロゲン原
子（Ｆ、ＣＬ、Ｂｒ）、カルボン酸基、スルホン酸基、
アルコキシカルボニル基（エトキシカルボニル基など）
、ＮＲＩＩ・Ｒ１２で表される基（Ｒ１１、Ｒ１２は、
水素原子または前述Ｕ タＲ’ 、Ｒ２で表した基）等
を挙げることができる。好ましくはＮＲ＋’・Ｒ１２で
表される基である。The monovalent groups represented by R', R6, R9 and R16 include lower alkyl groups (for example, methyl group, ethyl group, etc.), lower alkoxy groups (methoxy group, etc.), halogen atoms (F, CL, Br ), carboxylic acid group, sulfonic acid group,
Alkoxycarbonyl group (ethoxycarbonyl group, etc.)
, a group represented by NRII・R12 (R11 and R12 are
A hydrogen atom or the group represented by the above-mentioned U ta R', R2), etc. can be mentioned. Preferably it is a group represented by NR+'·R12.
弐りで表されるメチン基：よ置換されてもよく、その置
換基の例としては、炭素数１〜５の置換もしくは無置換
の低級アルキル基（例えばメチル基、エチル基、３−ヒ
ドロキノプロピル基、ヘンシル基、２−スルホエチル基
など）、ハロゲン原子（例えばＦ、ＣＬ、Ｂｒなど）、
置換もしくは無置換のアリール基（例えばフェニル基、
４−クロロフェニル基など）、低級アルコキノ基（例え
ば、メトキン基、エトキン基など）、などが好ましい。Methine group represented by Ni: May be substituted. Examples of the substituent include a substituted or unsubstituted lower alkyl group having 1 to 5 carbon atoms (e.g., methyl group, ethyl group, 3-hydroquino propyl group, Hensyl group, 2-sulfoethyl group, etc.), halogen atoms (e.g. F, CL, Br, etc.),
Substituted or unsubstituted aryl groups (e.g. phenyl group,
(4-chlorophenyl group, etc.), lower alkokino groups (eg, metquine group, ethquine group, etc.), and the like are preferred.
またして表されるメチン基の置換基同士が結合して３つ
のメチン基を含む５．６員環（例えば、シクロペンテン
環、シクロヘキセン環、４．４−ジメチルソクロヘキセ
ン環など）を形成してもよい。The substituents of the methine group expressed as above combine to form a 5.6-membered ring containing three methine groups (e.g., cyclopentene ring, cyclohexene ring, 4,4-dimethylsoclohexene ring, etc.). It's okay.
Ｘ−で表されるアニオンの具体例としてはハロゲンイオ
ン（Ｃ’Ｌ、Ｂｒ、［）−Ｐ ）ルエンスルホン酸イ
オン、エチル硫酸イオン 酢酸イオン、ンユウ酸イオン
、ＰＦ、−、ＢＦｔ−、ＣｌＯ２−などが挙げられる。Specific examples of anions represented by Examples include.
ｎは１また１よ２を表ゎし、染料が分子内塩を形成する
ときは１である。n represents 1 or 1 or 2, and is 1 when the dye forms an inner salt.
本発明に用いられる前記一般式四）および（１１）で表
される染料化合物の具体例を以下に示すが、本発明の範
囲はこれらに限定されるものではない。Specific examples of the dye compounds represented by the general formulas 4) and (11) used in the present invention are shown below, but the scope of the present invention is not limited thereto.
化合物例
Ｒ５Ｒｂ
／″
■ −１４
Ｃ，Ｈ，ＳＯ，−Ｃ，Ｈ，ＳＯ，に
−Ｎへ ／＼ ７徐〜／Ｎ＼＼〉（−
”！ ｌ、ｔ ＼１：１’ｓ、、
７＜＞−人Ｃ−Ｃ１１＝４ＣＨ−ＣＨ）＝Ｃ＝人≧２（
、〜ン一へ−／゛＼
（γ−’ニーｔ １′・へ゛パ・
＜’ ／ ＋、・−“。Compound example R5Rb /'' ■ -14 C, H, SO, -C, H, SO, to -N /\7~/N\\〉(-
”! l,t \1:1's,,
7<>-Person C-C11=4CH-CH)=C=Person≧2(
,~n 1 to -/゛\ (γ-'neet 1'・heupa・<'/+,・-“.
＼／ ＼／
Ｃ３Ｈ，ＳＯ３−ｃｍＨ６ＳＯ３Ｋ
Ｒ７−Ｒ８
＼Ｎ ＝ Ｃ−ＣＨ−＝４０Ｈ−ＣＨ）−Ｃ−Ｎ ′Ｒ
・ し・・
ｌ−１１
ＣＪ−５Ｏ３−ＣＨ：ｌ Ｃ２Ｈ−３Ｏ
３に一般式（Ｉ）で表される染料は、Ｊ、 Ａｍｅ、
Ｃｈｅｍ。\/ \/ C3H,SO3-cmH6SO3K R7-R8 \N = C-CH-=40H-CH)-C-N 'R
・... l-11 CJ-5O3-CH:l C2H-3O
The dye represented by general formula (I) in 3 is J, Ame,
Chem.
Ｓｏｃ、８０．３７７２ （１９５８）および特開平２
−２１６１４０号を参考に、また（ＩＩ）で表される染
料は、米国特許４，８３０．９５１号および特開昭６２
−２３０８５７号を参考にして合成することができる。Soc, 80.3772 (1958) and JP-A-2
-216140, and the dye represented by (II) is described in U.S. Pat.
It can be synthesized with reference to No.-230857.
本発明に用いられる親水性コロイドとしては、ゼラチン
が代表的なものであるが、その他写真用に使用しうるも
のとして従来知られているものはいずれも使用できる。Gelatin is a typical hydrophilic colloid used in the present invention, but any other conventionally known hydrophilic colloids that can be used for photography can be used.
本発明で有用な有機色素は、赤外光を露光又は吸収する
ために有用な量で使用できるが、それらが現像処理の間
に可溶化され流出されるような量及び位置でそれらを使
用することが特に有利である。少量の光だけを吸収する
ことが望ましい場合には、少量の染料だけが必要である
。より大量の光を吸収することが望ましい場合には、着
色レベルが特別の写真要素にとって受は入れられるレベ
ルで残留している限りより大量の染料が使用できる。染
料は、好ましくは、１〜１０００ ｍｇ／ ｆｔ２の量
で写真要素中に存在する。The organic dyes useful in this invention can be used in any useful amount to expose or absorb infrared light, provided they are used in amounts and locations such that they are solubilized and washed away during the development process. This is particularly advantageous. If it is desired to absorb only a small amount of light, only a small amount of dye is needed. If it is desired to absorb more light, larger amounts of dye can be used as long as the coloration level remains acceptable for the particular photographic element. The dye is preferably present in the photographic element in an amount of 1 to 1000 mg/ft2.
本発明の感光材料の写真処理には、例えばリサーチ・デ
ィスクロージャ−１７６号第２８〜３０頁（ＲＤ−１７
６４３）に記載されているような、黒白写真処理の公知
の方法及び公知の処理液のいずれをも連用することがで
きる。処理温度は普通１８℃から５０℃の間に選ばれる
が、１８℃より低い温度または５０℃を越える温度とし
てもよいが本発明には２０℃〜４０ｔまでの自動現像機
による処理が好ましい。この場合の処理時間（感材の投
入から乾燥して出て来るまでの時間）は１０秒力・ら５
分までが好ましい。１５秒から３分３０秒までが特に好
ましい。For example, Research Disclosure No. 176, pages 28-30 (RD-17
Any of the known methods and known processing solutions for black-and-white photographic processing, such as those described in 643), can be used. The processing temperature is usually selected between 18°C and 50°C, but temperatures lower than 18°C or above 50°C may also be used, although processing in an automatic processor at temperatures of 20°C to 40t is preferred for the present invention. In this case, the processing time (time from loading the photosensitive material until it comes out dry) is 10 seconds.
Preferably up to 1 minute. Particularly preferred is 15 seconds to 3 minutes and 30 seconds.
黒白写真処理する場合に用いる現像液は、知られている
現像主薬を含むことができる。現像主薬としては、ジヒ
ドロキシヘンゼン類（１ことえばハイドロキノン）、３
−ピラゾリドン類（７：とえば１−フニニル−３−ピラ
ソ゛リドン）、アミノフェノール類（１ことえばＮ−メ
チル−ｐ−アミノフェノールなど）を単独もしくは組合
せて用いることができる。現像液には一般にこの他公知
の保恒剤、アルカリ剤、ｐ）（緩衝剤、カブリ防止剤な
どを含み、さらに必要に応じ溶解助剤、色調剤、現像促
進剤（例えば、４級塩、ヒドラジン、ヘンシルアルコー
ル）、現像抑制剤（例えば沃化物、臭化物、メルカプト
化合物、トリアゾール類など）界面活性剤、消泡剤、硬
水軟化剤、硬膜剤（例えば、グルタルアルデヒド）、粘
性付与剤などを含んでもよい。The developer used in black-and-white photographic processing can contain known developing agents. As developing agents, dihydroxyhenzenes (1 example, hydroquinone), 3
-Pyrazolidones (7: e.g. 1-phnynyl-3-pyrazolydone) and aminophenols (e.g. N-methyl-p-aminophenol) can be used alone or in combination. The developing solution generally contains known preservatives, alkaline agents, buffering agents, antifoggants, etc., and, if necessary, solubilizing agents, color toning agents, development accelerators (for example, quaternary salts, hydrazine, Hensyl alcohol), development inhibitors (e.g. iodides, bromides, mercapto compounds, triazoles, etc.), surfactants, antifoaming agents, water softeners, hardeners (e.g. glutaraldehyde), viscosity imparting agents, etc. May include.
現像処理の特殊な形式として、現像主薬を感光材料中、
たとえば乳剤層中に含み、感光材料をアルカリ水溶液中
で処理して現像を行なわせる方法を用いてもよい、現像
主薬のうち、疎水性のものは、リサーチディスクロージ
ャ１６９号（ＲＤ −１６９２８）、米国特許第２．７
３９．８９０号、英国特許第８１３．２５３号又は***
国特許第１゜５４７．７６３号などに記載の種々の方法
で乳剤層中に含ませることができる。このような現像処
理は、チオシアン酸塩による銀塩安定化処理と組合せて
もよい。As a special form of development processing, a developing agent is added to the light-sensitive material.
For example, among the developing agents that are contained in the emulsion layer and may be developed by processing the light-sensitive material in an alkaline aqueous solution, hydrophobic ones are described in Research Disclosure No. 169 (RD-16928), U.S. Patent No. 2.7
39.890, British Patent No. 813.253 or West German Patent No. 1.547.763. Such development treatment may be combined with silver salt stabilization treatment with thiocyanate.
定着液としては一般に用いられる組成のものを用いるこ
とができる。定着剤としてはチオ硫酸塩、チオシアン酸
塩のほか、定着剤としての効果が知られている有機硫黄
化合物を用いることができる。As the fixer, one having a commonly used composition can be used. As the fixing agent, in addition to thiosulfates and thiocyanates, organic sulfur compounds known to be effective as fixing agents can be used.
定着液には硬膜剤として水溶性アルミニウム塩を含んで
もよい。The fixing solution may contain a water-soluble aluminum salt as a hardening agent.
また、特開昭６１−２３０１３５や同６３−２５６５３
に記載されているような、現像時に抑制剤を放出するよ
うな化合物を併用すると本発明の効果はさらに好ましい
ものとなる。Also, JP-A-61-230135 and JP-A-63-25653
The effect of the present invention becomes even more favorable when a compound that releases an inhibitor during development is used in combination, as described in .
本発明に用いられる感光性ハロゲン化銀乳剤のハロゲン
化銀としては塩臭化銀、臭化銀、沃臭化銀、塩沃臭化銀
を用いることができるが好ましくは沃臭化銀が用いられ
る。ここで沃化銀の含量は好ｇ１．．＜は３０モル％以
下、特に１０モル％以下の範囲であることが好ましい。As the silver halide in the photosensitive silver halide emulsion used in the present invention, silver chlorobromide, silver bromide, silver iodobromide, and silver chloroiodobromide can be used, but silver iodobromide is preferably used. It will be done. Here, the content of silver iodide is preferably g1. ．． < is preferably in the range of 30 mol% or less, particularly 10 mol% or less.
沃臭化銀粒子中の沃素の分布は均一でもよく又、内部と
表面とで異なっていてもよい、平均粒子サイズは０．４
μｍ以上であることが好ましい、特に０．５〜２．０μ
ｍであることが好ましい０粒子サイズ分布は狭くても広
くてもいずれでもよい。The distribution of iodine in the silver iodobromide grains may be uniform or different between the inside and the surface, and the average grain size is 0.4
Preferably larger than μm, especially 0.5 to 2.0 μm
The particle size distribution, preferably m, may be narrow or wide.
乳剤中のハロゲン化銀粒子は立方体、８面体、１４面体
、菱１２面体のような規則的（ｒｅｇｕｌａｒ）な結晶
形を有するものでもよく、また球状、板状、じゃがいも
状などのような変則的（ｉｒｒｅｇｕｌａｒ）な結晶形
を有するものでも或いはこれらの結晶形の複合形を有す
るものでもよい、種々の結晶形の粒子の混合から成って
もよい、また粒子径が粒子厚みの５倍以上の平板粒子は
、本発明に対し好ましく用イラレル（詳シ＜は、ＩＩＥ
ＳＥＡＲＣＩＩ ［］＋５ＣＬＯ５［ＩＲＥ２２５巻１
ｔｅｎ ２２５３４Ｐ、２０−Ｐ、５８．１月号、１９
８３年、及び特開昭５８−１２７９２１号、同５８−１
１３９２６号公報に記載されている）。The silver halide grains in the emulsion may have regular crystal shapes such as cubic, octahedral, tetradecahedral, rhombic dodecahedral, or irregular crystal shapes such as spherical, plate-like, potato-like, etc. It may have an irregular crystal form or a composite form of these crystal forms, it may consist of a mixture of particles of various crystal forms, and it may be a flat plate with a particle diameter of 5 times or more the particle thickness. The particles preferably used for the present invention are
SEARCII []+5CLO5[IRE225 volume 1
ten 22534P, 20-P, 58. January issue, 19
1983, and JP-A-58-127921, JP-A No. 58-1.
13926).
本発明において、感光性ハロゲン化銀乳剤は、２ｍ！以
上のハロゲン化銀乳剤を混合して用いてもよい、混合す
る乳剤の粒子サイズ・ハロゲン組成・感度・等が異なっ
ていてもよい、感光性乳剤に実質的に非５光性の乳１ｉ
ＦＩ＋ （表面あるいは内部がかぶっていてもよいし、
いなくてもよい）を混合して用いてもよいし、別の層に
分けてもよい（詳しくは米国特許２，９９６．３８２号
、同３，３９７．９８７号などに記載されている）。例
えば、球状もしくはじゃがいも状の懲光性乳剤と粒子径
が粒子厚みの５倍以上の平板粒子からなる感光性ハロゲ
ン化銀乳剤と同一層もしくは特開昭５８−１２７９２１
号公報に記載の如く異なった層に用いてもよい。異なっ
た層に用いる時、平板粒子からなる感光性ハロゲン化銀
乳剤は支持体に近い側にあってもよいし、逆に違い側２
あってもよい。In the present invention, the photosensitive silver halide emulsion is 2m! The above silver halide emulsions may be mixed and used, and the mixed emulsions may have different grain sizes, halogen compositions, sensitivities, etc. Substantially non-pentaminous emulsions 1i
FI+ (The surface or interior may be covered,
may be used as a mixture or may be separated into separate layers (details are described in U.S. Pat. No. 2,996.382, U.S. Pat. No. 3,397.987, etc.). . For example, in the same layer as a spherical or potato-shaped punitive emulsion and a light-sensitive silver halide emulsion consisting of tabular grains with a grain size of 5 times or more the grain thickness, or in JP-A-58-127921.
It may be used in different layers as described in the publication. When used in different layers, the light-sensitive silver halide emulsion consisting of tabular grains may be on the side closer to the support, or conversely on the opposite side 2.
There may be.
本発明に用いられる写真乳剤はＰ、Ｇ］ａｆｋｉｄｅｓ
著Ｃｈｉｍｉｅ ａｔ Ｐｈｙｓｉｑｕｅ Ｐｈｏｔｏ
ｇｒａｐｈｉｑｕｅ（Ｐａｕｌ Ｍｏｎｔｅ１社刊、１
９６７年） 、Ｇ、 Ｆ、 Ｄｕｆｆｉｎ 署Ｐｈ
ｏｔｏｇｒａｐｈｉｃ Ｅｍｕｌｓｉｏｎ Ｃｈｅ
ｍｉｓｔｒｙ （Ｔｈｅ ＦｏｃａｌＰｒｅｓｓ刊、１
９６６年年） 、Ｖ、 Ｌ、 Ｚｅｌｉｋｍａｎ ｅｔ
ａｌ著Ｍａｋｉｎｇ ａｎｄ Ｃｏｔｉｎｇ Ｐｈｏｔ
ｏｇｒａｐｈｉｃ Ｅｍｕｌｓｉｏｎ（Ｔｈｅ Ｆｏｃ
ａｌ、 Ｐｒｅｓｓ刊、１９６４年）、特開昭５８−１
２７９２１号及び同５８−１１３９２６号公報などに記
載された方法を用いて８周整することができる。すなわ
ち、酸性法、中性法、アンモニア法等のいずれでもよく
、また可溶性銀塩と可溶性ハロゲン塩を反応させる形式
としては片側混合法、同時混合法、それらの組合セなど
のいずれを用いてもよい。The photographic emulsion used in the present invention is P, G] afkides.
Written by Chimie at Physique Photo
graphique (published by Paul Monte1, 1
967), G, F, Duffin Station Ph.
otographic Emulsion Che
mistry (The Focal Press, 1
(966), V. L., Zelikman et al.
Making and Coating Photo by al
graphic emulsion(The Foc
al, Press, 1964), Japanese Patent Publication No. 58-1
It is possible to prepare eight rounds using the method described in Japanese Patent No. 27921 and No. 58-113926. That is, any of the acidic method, neutral method, ammonia method, etc. may be used, and the method for reacting the soluble silver salt with the soluble halogen salt may be any one-sided mixing method, simultaneous mixing method, combination thereof, etc. good.
ハロゲン化銀粒子を銀イオン過剰の下において形成させ
る方法（いわゆる逆混合法）を用いることもできる。同
時混合法の一つの形式としてハロゲン化銀の生成される
液相中のｐＡｇを一定に保つ方法、すなわちいわゆるコ
ンドロールド・ダブルジェット法を用いることもできる
。この方法によると、結晶形が規則的で粒子サイズが均
一に近いハロゲン化銀粒子よりなるハロゲン化銀乳剤か
えられる。A method in which silver halide grains are formed in an excess of silver ions (so-called back mixing method) can also be used. As one type of simultaneous mixing method, a method in which the pAg in the liquid phase in which silver halide is produced can be kept constant, that is, a so-called Chondrald double jet method can also be used. According to this method, a silver halide emulsion consisting of silver halide grains having a regular crystal shape and a nearly uniform grain size can be obtained.
ハロゲン化銀粒子の結晶構造は内部まで−様なものであ
っても、また内部と外部が異質の層状構造をしたものや
、英国特許６３５，８４１号、米国特許３，６２２．３
１８号に記載されているような、いわゆるコンバージョ
ン型のものであってもよい、ハロゲン化銀製造時のハロ
ゲン化銀粒子形成または物理熟成の過程において、カド
ミウム塩、亜鉛塩、鉛塩、タリウム塩、イリジウム塩ま
たはその錯塩、ロジウム塩ま１：はその錯塩、鉄塩また
は鉄錯塩などを共存させてもよい。Even if the crystal structure of silver halide grains is similar to the inside, there are also those with a layered structure with different inside and outside, British Patent No. 635,841, US Patent No. 3,622.3
In the process of silver halide grain formation or physical ripening during silver halide production, cadmium salt, zinc salt, lead salt, thallium salt may be of the so-called conversion type as described in No. 18. , an iridium salt or a complex salt thereof, a rhodium salt, a complex salt thereof, an iron salt or an iron complex salt, etc. may be coexisting.
また、粒子形成時にはアンモニア、チオエーテル化合物
、チアゾリジン−２−チオン、四１換チオ尿素、ロダン
カリ、ロダンアンモン、アミン化合物の如きいわゆるハ
ロゲン化銀溶剤を存在せしめ粒子成長をコントロールし
てもよい。Further, during grain formation, grain growth may be controlled by allowing so-called silver halide solvents such as ammonia, thioether compounds, thiazolidine-2-thione, 41-substituted thiourea, rhodanpotash, rhodanammonium, and amine compounds to be present.
本発明に用いられるハロゲン化銀乳剤は化学増感されて
いても、されていなくてもよい、化学増感の方法として
は硫黄増感法、還元増想法、金増感法などの知られてい
る方法を用いることができ、単独または組合せで用いら
れる。The silver halide emulsion used in the present invention may or may not be chemically sensitized. Chemical sensitization methods include known methods such as sulfur sensitization, reduction sensitization, and gold sensitization. A number of methods can be used, used alone or in combination.
貴金属増感法のうち金増感法はその代表的なもので金化
合物、主として金錯塩を用いる。金以外の貴金属、たと
えば白金、パラジウム、イリジウム等の錯塩を含有して
も差支えない、その具体例は米国特許２，４４８．０６
号、英国特許６１８．０６１号などに記載されてい
る。Among the noble metal sensitization methods, the gold sensitization method is a typical method and uses a gold compound, mainly a gold complex salt. There is no problem in containing complex salts of noble metals other than gold, such as platinum, palladium, and iridium.
No. 618.061, British Patent No. 618.061, etc.
硫黄増感剤としては、ゼラチン中に含まれる硫黄化合物
のほか、種々の硫黄化合物、たとえばチオ硫酸塩、チオ
尿素類、チアゾール類、ローダニン類等を用いることが
できる。As the sulfur sensitizer, in addition to the sulfur compounds contained in gelatin, various sulfur compounds such as thiosulfates, thioureas, thiazoles, rhodanines, etc. can be used.
還元増感剤としては第一すず塩、アミン類、ホルムアミ
ジンスルフィン酸、ンラン化合吻などを用いることがで
きる。As the reduction sensitizer, stannous salts, amines, formamidine sulfinic acid, nitrogen compounds, etc. can be used.
本発明に用いられる写真乳剤には、感光材料の製造工程
、保存中あるいは写真処理中のカブリを防止し、あるい
は写真性能を安定化差せる目的で、種々の化合物を含存
させることができる。すなわちアゾール類（例えばベン
ゾチアゾリウム塩、ニトロイミダゾール類、ニトロベン
ズイミダゾール類、クロロベンズイミダゾール類、ブロ
モベンズイミダゾール類、ニトロインダゾール類、ベン
ゾトリアゾール類、アミノトリアゾール類など） ；メ
ルカプト化合物類（例えばメルカプ））チアゾール類、
メルカプトベンゾチアゾール類、メルカプトベンズイミ
ダゾール類、メルカプトチアジアゾール類、メルカプト
テトラゾール類（特に１−フニニル−５−メルカフ゛ト
チトラン゛−ル）、メルカプトピリミジン類、メルカプ
トトリアジン類など） ：例えばオキサドリンテ万ンの
ようなチオケト化合物；アザインデン類（例えばトリア
ザインデン類、テトラアザインデン類（詩に４−ヒドロ
キシ置換（１，３，３ａ、７）テトラアザインデン類）
、ペンタアザインデン類など） ；ベンゼンチオスルホ
ン酸、ベンゼンスルフィン酸、ベンゼンスルホン酸アミ
ドのようなカブリ防止剤または安定側として知られた、
多くの化合物を加えることができる。The photographic emulsion used in the present invention may contain various compounds for the purpose of preventing fog during the manufacturing process, storage, or photographic processing of the light-sensitive material, or for stabilizing photographic performance. Namely, azoles (e.g., benzothiazolium salts, nitroimidazoles, nitrobenzimidazoles, chlorobenzimidazoles, bromobenzimidazoles, nitroindazoles, benzotriazoles, aminotriazoles, etc.); mercapto compounds (e.g., mercapto compounds); )) Thiazoles,
mercaptobenzothiazoles, mercaptobenzimidazoles, mercaptothiadiazoles, mercaptotetrazoles (particularly 1-phnynyl-5-mercaptothitranyl), mercaptopyrimidines, mercaptotriazines, etc.): For example, oxadolintetrazole thioketo compounds; azaindenes (e.g. triazaindenes, tetraazaindenes (4-hydroxy-substituted (1,3,3a,7) tetraazaindenes)
, pentaazaindenes, etc.); known as antifoggants or stabilizing agents such as benzenethiosulfonic acid, benzenesulfinic acid, benzenesulfonic acid amide;
Many compounds can be added.
特に特開昭６０−７６７４３号、同６０−８７３２２号
公報に記載のニトロン及びその誘導体・特開昭６０−８
０８３９号公報に記載のメルカプト化合物、特開昭５７
−１６４７３５号公報に記載のへテロ環化合物、及びペ
テロ環化合物と銀の錯塩（例えば１−フェニル−５−メ
ルカプトテトラゾール銀）などを好ましく用いることが
できる。In particular, nitrone and its derivatives described in JP-A-60-76743 and JP-A-60-87322, JP-A-60-8
Mercapto compound described in Publication No. 0839, JP-A-57
The heterocyclic compound described in Japanese Patent No. 164735, a complex salt of a tetracyclic compound and silver (for example, 1-phenyl-5-mercaptotetrazole silver), and the like can be preferably used.
本発明の感光性ハロゲン化銀乳剤は、増悪色素によって
比較的長波長の青色光、緑色光、赤色光または赤外光に
分光増悪されてもよい、増悪色素として、シアニン色素
、メロンアニン色素、コンプレックスソアニン色素、コ
ンプレックスメロンアニン色素、ホロホーラージアニン
色素、スチリル色素、ヘミシアニン色素、オキソノール
色素、ヘミオキソノール色素等を用いることができる。The light-sensitive silver halide emulsion of the present invention may be spectrally enhanced into relatively long-wavelength blue light, green light, red light, or infrared light by an enhancing dye, which may include cyanine dyes, melonanine dyes, and complex dyes. Soanine dyes, complex melonanine dyes, holophoradianine dyes, styryl dyes, hemicyanine dyes, oxonol dyes, hemioxonol dyes, and the like can be used.
ここで増感色素は写真乳剤の製造工程のいかなる工程に
存在させて用いることもできるし、製造後塗布直前まで
のいかなる段階に存在させることもできる。前者の例と
しては、ハロゲン化銀粒子形成工程、物理熟成工程、化
学熟成工程などである。The sensitizing dye can be used at any stage of the photographic emulsion manufacturing process, or at any stage after manufacturing until immediately before coating. Examples of the former include a silver halide grain formation process, a physical ripening process, and a chemical ripening process.
本発明の感光材料の写真乳剤層または他の親水性コロイ
ド層には塗布助剤、帯電防止、スベリ性改良、乳化分散
、接着防止及び写真特性改良（例えば、現像促進、硬調
化、増悪）等種々の目的で、程々の界面活性剤を含んで
もよい。The photographic emulsion layer or other hydrophilic colloid layer of the light-sensitive material of the present invention includes coating aids, antistatic properties, improvement in slipperiness, emulsification and dispersion, prevention of adhesion, and improvement in photographic properties (for example, development acceleration, contrast enhancement, deterioration), etc. Moderate amounts of surfactants may be included for various purposes.
例えばサポニン（ステロイド系）、アルキレンオキサイ
ド誘導体（例えばポリエチレングリコール、ポリエチレ
ングリコール／ポリプロピレングリコール縮合物、ポリ
エチレングリコールアルキルエーテル類又はポリエチレ
ングリコールアルキルアリールエーテル類、ソリコーン
のポリエチレンオキサイド付加物り、垢のアルキルエス
テル類などの非イオン性界面活性剤；フルキルスルフォ
ン酸塩、アルキルベンゼンスルフォン酸塩、アルキルナ
フタレンスルフォン酸塩、アルキル硫酸エステル類、Ｎ
−アシル−Ｎ−アルキルタウリン類、スルホコハク酸エ
ステル類、スルホアルキルポリオキシエチレンアルキル
フェニルエーテル類、などのアニオン界面活性剤：アル
キルベタイン類、アルキルスルホベタイン類などの両性
界面活性剤：脂肪族あるいは芳香族第４級アンモニウム
塩類、ピリジニウム塩類、イミダヅリウム塩類などのカ
チオン界面活性剤を用いることができる。この内、サポ
ニン、ドデシルベンゼンスルホン酸Ｎ ａ 塩、ジ・２
・エチルヘキシルα−スルホコハクｆｌｊＮａ塩、ｐ−
オクチルフニノキンエトキシエトキシエタンスルホン酸
Ｎａ塩、ドデシルｆＬｅｔ Ｎ ａ塩、トリイゾプロビ
ルナフタレンスルホン酸Ｎ ａ塩、Ｎ−メチル−オレオ
イルタウリンＮａ塩、等のアニオン、ドデシルトリメチ
ルアンモニウムクロライド、Ｎ−オレオイル−Ｎ’、Ｎ
’、Ｎ’−トリメチルアンモニオジアミノプロパンブロ
マイド、ドデシルピリジウムクロライドなどのカチオン
、Ｎ−ドデシルーＮ、Ｎ−ジメチルカルボキシベタイン
、Ｎ−オレイル−Ｎ、Ｎ−ジメチルスルホブチルベタイ
ンなどのベタイン、ポリ （平均重合度ｎ＝１０）オキ
シエチレン七チルエーテル、ポリ（ｎ＝’２５）オキソ
エチレンｐ−ノニルフェノールエーテル、ビス（１−ポ
リ （’ｎ＝１５＞オキシエチレン−オキシ−２４−ジ
−ｔ−ペンチルフェニル）エタンなどのノニオンを特に
好ましく用いることができる。For example, saponins (steroids), alkylene oxide derivatives (e.g. polyethylene glycol, polyethylene glycol/polypropylene glycol condensates, polyethylene glycol alkyl ethers or polyethylene glycol alkyl aryl ethers, polyethylene oxide adducts of soricone, alkyl esters of scale, etc.) Nonionic surfactants; furkyl sulfonates, alkylbenzene sulfonates, alkylnaphthalene sulfonates, alkyl sulfates, N
-Anionic surfactants such as acyl-N-alkyl taurines, sulfosuccinates, sulfoalkylpolyoxyethylene alkylphenyl ethers, etc.Amphoteric surfactants such as alkylbetaines and alkylsulfobetaines: Aliphatic or aromatic Cationic surfactants such as quaternary ammonium salts, pyridinium salts, and imidazurium salts can be used. Among these, saponin, dodecylbenzenesulfonic acid Na salt, di-2
・Ethylhexyl α-sulfosucci fljNa salt, p-
Anions such as octylphuninoquine ethoxyethoxyethanesulfonic acid Na salt, dodecyl fLet Na salt, triisoprobyl naphthalene sulfonic acid Na salt, N-methyl-oleoyl taurine Na salt, dodecyltrimethylammonium chloride, N-oleoyl taurate Na salt, etc. Oil - N', N
', N'-trimethylammoniodiaminopropane bromide, cations such as dodecylpyridium chloride, betaines such as N-dodecyl-N, N-dimethylcarboxybetaine, N-oleyl-N, N-dimethylsulfobutylbetaine, poly (average Polymerization degree n=10) oxyethylene heptyl ether, poly(n='25) oxoethylene p-nonylphenol ether, bis(1-poly ('n=15>oxyethylene-oxy-24-di-t-pentylphenyl) Nonions such as ethane can be particularly preferably used.
Ｈ防止剤としてはパーフルオロオクタンスルホン酸に塩
、Ｎ−プロピル−Ｎ−パーフルオロオクタンスルホニル
グリシンＮａ塩、Ｎ−プロピル塩、ｐ−オクチルフエノ
モソエトキシエトキシエタンスルホン酸Ｎａ塩、ドデシ
ル硫酸Ｎａ塩、トリイヅプロピルナフタレンスルホン酸
Ｎａ塩、Ｎ−メチル−オレオイルタウリンＮａ塩、等の
アニオン、ドデシルトリメチルアンモニウムクロライド
、Ｎ−オレオイル−Ｎ’、Ｎ’、Ｎ’−）リメチルアン
モニオジアミノプロパンブロマイド、ドデシルピリジウ
ムクロライドなどのカチオン、Ｎ−ドデシルーＮ、Ｎ−
ジメチルカルボキシベタイン、Ｎ−オレイル−Ｎ、Ｎ−
ジメチルスルホブチルベタインなどのベタイン、ポリ
（平均重合度ｎ−１０）オキシエチレン七チルエーテル
、ポリ（ｎ＝’２５）オキシエチレンｐ−ノニルフェノ
ールエーテル、ビス（１−ポリ（ｎ＝１５）オキシエチ
レン−オキシ−２４−ジーｔ−ペンチルフェニル）エタ
ンなどのノニオンを特に好ましく用いることができる。H inhibitors include perfluorooctanesulfonic acid salt, N-propyl-N-perfluorooctanesulfonylglycine Na salt, N-propyl salt, p-octylphenomosoethoxyethoxyethanesulfonic acid Na salt, and dodecyl sulfate Na salt. , triidupropylnaphthalenesulfonic acid Na salt, N-methyl-oleoyl taurine Na salt, anions such as dodecyltrimethylammonium chloride, N-oleoyl-N', N', N'-)limethylammoniodiaminopropane Bromide, cations such as dodecylpyridium chloride, N-dodecyl-N, N-
Dimethylcarboxybetaine, N-oleyl-N,N-
Betaines such as dimethylsulfobutylbetaine, poly
(Average degree of polymerization n-10) oxyethylene heptyl ether, poly(n='25) oxyethylene p-nonylphenol ether, bis(1-poly(n=15) oxyethylene-oxy-24-di-t-pentylphenyl) Nonions such as ethane can be particularly preferably used.
帯電防止剤としてはパーフルオロオクタンスルホン酸に
塩、Ｎ−プロピル−Ｎ−パーフルオロオクタンスルホニ
ルグリシンＮａ塩、Ｎ−プロピル−Ｎ−パーフルオロオ
クタンスルホニルアミノエチルオキシポリ （ｎ＝３）
オキシエチレンブタンスルホン酸Ｎ ａ 塩、Ｎ−パー
フルオロオクタンスルホニル−Ｎ’、Ｎ’、Ｎ’−）リ
メチルアンモニオジアミノプロパンクロライド、Ｎ−パ
ーフルオロデカノイルアミノプロピルＮ’、Ｎ’ジメチ
ル−Ｎ′−カルボキシベタインの如き含フツ素界面活性
剤、特開昭６０−８０８４８号、同６１−１１２１４４
号、特願昭６１−１３３９８号、同６１−１６０５６号
などに記載のノニオン系界面活性剤、アルカリ金属の硝
酸塩、導電性酸化スズ、酸化亜鉛、五酸化バナジウム又
はこれらにアンチモン等をドープした複合酸化物を好ま
しく用いることができる。As an antistatic agent, perfluorooctanesulfonic acid salt, N-propyl-N-perfluorooctanesulfonylglycine Na salt, N-propyl-N-perfluorooctanesulfonylaminoethyloxypoly (n=3)
Oxyethylene butanesulfonic acid Na salt, N-perfluorooctanesulfonyl-N',N',N'-)limethylammoniodiaminopropane chloride, N-perfluorodecanoylaminopropyl N',N'dimethyl-N Fluorine-containing surfactants such as '-carboxybetaine, JP-A Nos. 60-80848 and 61-112144
Nonionic surfactants, alkali metal nitrates, conductive tin oxide, zinc oxide, vanadium pentoxide, or composites of these doped with antimony, etc. Oxides can be preferably used.
本発明に於てはマント剤としてポリメチルメタクリレー
トのホモポリマー又はメチルメタクリレートとメタクリ
ル酸とのポリマー、デンプンなどのを機化合物、シリカ
、二酸化チタン、等の無機化合物の微粒子を用いること
ができる１粒子サイズとしては１．０〜１０μｍ、特に
２〜５μｍであることが好ましい。In the present invention, a homopolymer of polymethyl methacrylate or a polymer of methyl methacrylate and methacrylic acid, organic compounds such as starch, fine particles of inorganic compounds such as silica, titanium dioxide, etc. can be used as the capping agent. The size is preferably 1.0 to 10 μm, particularly 2 to 5 μm.
本発明の写真感光材料の表面層には滑り剤として米国特
許第３．４８９．５７６号、同４，０４７．９５８号等
に記載のシリコーン化合物、特公昭５６−２３１３９号
公報に記載のコロイダルシリカの他に、パラフィンワッ
クス、高級脂肪酸エステル、デン粉ｇ４体等を用いるこ
とができる。The surface layer of the photographic light-sensitive material of the present invention contains silicone compounds described in U.S. Pat. No. 3,489,576 and U.S. Pat. In addition, paraffin wax, higher fatty acid ester, starch g4, etc. can be used.
本発明の写真感光材料の親水性コロイド層には、トリメ
チロールプロパン、ベンタンジオール、ブタンジオール
、エチレングリコール、グリセリン等のポリオール類を
可塑側として用いることができる。さらに、本発明の写
真感光材料の親水性コ、ロイド厘には、耐圧力性改良の
目的でポリマーラテックスを含有せしめることが好まし
い、ポリマーとしてはアクリル酸のアルキルエステルの
ホモポリマー又はアクリル酸とのコポリマー、スチレン
−ブタジェンコポリマー、活性メチレン基を有するモノ
マーからなるポリマー又はコポリマーを好ましく用いる
ことができ名。In the hydrophilic colloid layer of the photographic material of the present invention, polyols such as trimethylolpropane, bentanediol, butanediol, ethylene glycol, and glycerin can be used as plasticizers. Furthermore, it is preferable that the hydrophilic polymer latex of the photographic light-sensitive material of the present invention contains a polymer latex for the purpose of improving pressure resistance. Copolymers, styrene-butadiene copolymers, polymers or copolymers consisting of monomers having active methylene groups can be preferably used.
本発明の写真乳剤及び非感光性の親水性コロイドには無
機または臂機の硬膜剤を含有してよい。The photographic emulsions and non-light-sensitive hydrophilic colloids of this invention may contain inorganic or organic hardeners.
例えばクロム塩、アルデヒド類（ホルムアルデヒド、ク
リタールアルデヒドなど）、Ｎ−メチロール化合物（ジ
メチロール尿素など）、活性ビニル化合物（１，３，５
−）リアクリロイル−へキザヒドロ−５−）リアジン、
ビス（ビニルスルボニル）メチルエーテル、Ｎ、Ｎ’−
メチレンビス−〔β−（ビニルスルホニル）プロピオン
アミド〕など）、活性ハロゲン化合物（２，４−ジクロ
ル−６−ヒドロキシ＝Ｓ−）リアジンなど）、ムコハロ
ゲン酸類（ムコクロル酸など）、Ｎ−カルバモイルピリ
ジニウム塩類（（１−モルホリノカルボニル−３−ピリ
ジニオ）メタンスルホナートなど）、ハロアミジニウム
塩！（１−（１−クロロ−１−ピリジノメチレン）ピロ
リジニウム、２−ナフタレンスルホナートなど）を単独
または組合せて用いることができる。な刀・でも、特開
昭５３−４１２２０、同５３−５７２５７、同５９−１
６２５４６、同６０−８０８４６に記載の活性ビニル化
合物および米国特許３，３２５．２８１号に記載の活性
ハロゲン化物が好ましい。For example, chromium salts, aldehydes (formaldehyde, clitaldehyde, etc.), N-methylol compounds (dimethylol urea, etc.), activated vinyl compounds (1,3,5
-) lyacryloyl-hexahydro-5-) riazine,
Bis(vinylsulfonyl)methyl ether, N, N'-
methylenebis-[β-(vinylsulfonyl)propionamide], etc.), active halogen compounds (2,4-dichloro-6-hydroxy=S-)riazine, etc.), mucohalogen acids (mucochloric acid, etc.), N-carbamoylpyridinium salts ((1-morpholinocarbonyl-3-pyridinio)methanesulfonate, etc.), haloamidinium salt! (1-(1-chloro-1-pyridinomethylene)pyrrolidinium, 2-naphthalenesulfonate, etc.) can be used alone or in combination. Japanese Patent Publication No. 53-41220, No. 53-57257, No. 59-1
62546, 60-80846 and the active halides described in U.S. Pat. No. 3,325,281 are preferred.
本発明の８光材料がＸレイ感材として用いられる場合親
水性コロイド層はこれらの硬膜剤により水中での膨潤ぶ
が２００％以下、特に１５０％以下になるように硬膜さ
れていることが好ましい。When the 8-photo material of the present invention is used as an X-ray sensitive material, the hydrophilic colloid layer must be hardened with these hardening agents so that the swelling in water is 200% or less, especially 150% or less. is preferred.
本発明の怒光材料の乳剤層や中間層に用いることのでき
る結合剤または保護コロイドとしては、ゼラチンを用い
るのが存利であるが、それ以外の親水性コロイドも用い
ることができる。As the binder or protective colloid that can be used in the emulsion layer or intermediate layer of the photosensitive material of the present invention, it is preferable to use gelatin, but other hydrophilic colloids can also be used.
例えばデキストラン、ポリビニルアルコール、ポリビニ
ルアルコール部分アセタール、ポリ−Ｎ−ビニルピロリ
ドン、ポリアクリル酸、ポリアクリルアミド、ポリビニ
ルイミダ・プールの箪−あるいは共重合体の如き多種の
合成親水性高分子物質を用いることができる。A wide variety of synthetic hydrophilic polymeric materials can be used, such as dextran, polyvinyl alcohol, polyvinyl alcohol partial acetals, poly-N-vinylpyrrolidone, polyacrylic acid, polyacrylamide, polyvinylimida pools or copolymers. I can do it.
ゼラチンとしては石灰処理ゼラチンの）よか、酸処理ゼ
ラチンや酵素処理ゼラチンを用いてもよく、また、ゼラ
チンの加水分解物も用いることができる。As the gelatin, lime-treated gelatin, acid-treated gelatin, or enzyme-treated gelatin may be used, and a hydrolyzate of gelatin may also be used.
これらの中でもゼラチンとともにデキストラン及びポリ
アクリルアミドを併用することが好ましい。Among these, it is preferable to use dextran and polyacrylamide together with gelatin.
本発明の現像処理に関しても前記リサーチ・ディスクロ
ジャー誌の記載を参考にすることができる。Regarding the development process of the present invention, the description in the above-mentioned Research Disclosure magazine can be referred to.
次に本発明を実施例により更に具体的に説明する。Next, the present invention will be explained in more detail with reference to Examples.
（実施例）
実施例−１
（１）へ旦ｆノ北１１１辺１玉
ゼラチンと臭化カリウムと水が入った５５°Ｃに加温さ
れた容器に適当量のアンモニアを入れた後、反応容器中
のＰＡｇ値を１５６０に保ちつつ硝酸銀水溶液と臭化カ
リウム水／８液とをダブルジェット法により添加して平
均粒子サイズが０．５５μの単分散臭化銀乳剤粒子を調
製した。この乳剤粒子は、平均粒子サイズの±４０％以
内−二全粒子数の９８％が存在していた。この乳剤を脱
塩処理後、ｐＨを６．２、ＰＡｇを８．６に合わせてか
ら千オ硫酸ナトリウムと塩化金酸とにより金 硫黄増感
を行った。(Example) Example-1 (1) After putting an appropriate amount of ammonia into a container heated to 55°C containing gelatin, potassium bromide, and water, a reaction was carried out. While maintaining the PAg value in the container at 1560, a silver nitrate aqueous solution and potassium bromide aqueous/8 solution were added by a double jet method to prepare monodisperse silver bromide emulsion grains having an average grain size of 0.55 μm. The emulsion grains were present within ±40% of the average grain size - 98% of the total grain number. After desalting this emulsion, the pH was adjusted to 6.2 and the PAg to 8.6, and then gold-sulfur sensitization was performed using sodium 1,000 sulfate and chloroauric acid.
この乳剤の（１００）面／（１１１）面比率をクベルカ
ムツク法で測定したところ９８／２であった。これを乳
剤Ａと称する。The (100) plane/(111) plane ratio of this emulsion was measured by the Kubelkamtzk method and was found to be 98/2. This is called emulsion A.
（３）１剋１春放り量製
乳剤Ａを１ｇ秤取し、４０°Ｃに加温溶解後、近赤外域
増感色素構造式Ｓ−１のメタノール溶液（９ＸｌＯ−’
Ｍ、／ｌ）を７０ｍ１．４〜ヒドロキシ−６−メチル−
１，３，３ａ、 ７−テトラザインデン水溶液、塗布
助則ドデノルヘンゼンスルフオン酸塩の水溶液、増粘剤
ポリボタシウムーＰ−ビニルヘンゼンスルフォネート化
合物の水溶液を添加して乳剤塗布液とした。(3) Weigh out 1 g of emulsion A, heat it to 40°C, dissolve it, and add a methanol solution of near-infrared sensitizing dye structural formula S-1 (9XlO-'
M,/l) to 70ml1.4~hydroxy-6-methyl-
An emulsion coating solution was prepared by adding an aqueous solution of 1,3,3a,7-tetrazaindene, an aqueous solution of dodenorhenzenesulfonate as a coating aid, and an aqueous solution of a thickener polybotacium P-vinylhenzenesulfonate compound. did.
Ｃ２）Ｉ、Ｂｒ−Ｃ２Ｈ３
（４）革 声の 声 ′の８゜１１４０°Ｃ
に加温されたｌ Ｑｗｔ％ゼラチン水ｆ４液に、増粘剤
ポリエチレンスルフォン酸ソーダ水溶液、マント剤ポリ
メチルメタクリレート微粒子（平均粒子サイズ３．０μ
ｍ）、硬膜剤Ｎ、Ｎ’−エナレンビスー（ビニルスルフ
ォニルアセトアミド）、塗布助剤ｔ−オクチルフエノキ
ンエトキソエタンスルフォン酸ナナトリウム水溶液帯電
防止剤としてポリエチレン系界面活性剤水溶液お、よび
下記構造の含フツ素化合物の水溶液とを添加じて塗布液
とした。C2) I, Br-C2H3 (4) Leather voice 8° 1140°C
To lQwt% gelatin water F4 solution heated to
m), a hardening agent N, N'-enalene bis(vinylsulfonylacetamide), a coating aid t-octylphenoquine ethoxoethanesulfonate aqueous solution, an aqueous polyethylene surfactant solution as an antistatic agent, and a polyethylene surfactant aqueous solution with the following structure. A coating solution was prepared by adding an aqueous solution of a fluorine-containing compound.
Ｃ８Ｆ＋７ＳＯ□１１（Ｃ３Ｈ，）ＣＨ２ＣＯＯＫ
およびＣｌ１Ｆ、 ７ＳＯＺＮ （ＣＪ７） （ＣＨｚ
ＣＨｚ−０＋Ｖ、 Ｈ（５）ハ り ゛のｉ、′１
４０’Ｃに加温された１０ｗＬ％ゼラチン水溶液１ｋｇ
シニ下記染料−１を１．７５ｇ、増粘剤ポリエチレンス
ルフォン酸ソーダ水溶液、硬膜剤Ｎ、Ｎ’−エチレンビ
ス−（ビニルスルフォニルアセトアミド）水溶液、塗布
助剤ｔ−オクチルフェノキンエトキシエタンスルフオン
酸ナトリウム水溶液とを加えてハック塗布液とした。但
し表−Ｉの本発明の染料を添加した。C8F+7SO□11(C3H,)CH2COOK
and Cl1F, 7SOZN (CJ7) (CHz
1 kg of 10 wL% gelatin aqueous solution heated to 40'C
1.75 g of the following dye-1, thickener polyethylene sulfonate sodium aqueous solution, hardener N, N'-ethylene bis-(vinylsulfonylacetamide) aqueous solution, coating aid t-octylphenoquine ethoxyethane sulfonic acid A hack coating solution was prepared by adding an aqueous sodium solution. However, the dyes of the present invention shown in Table I were added.
〔染ｔＡ−１）
ｅ
（ＣＨ２） ｍ５Ｏｘ （ＣＨｚ） ａｓＯＪ
（６） −１公、、−λ層−の表１１保１１層Ｕ布４
じλ聾目菫４０’Ｃに加温されたｌＱｗＬ％ゼラチン水
７８液水増８液ボ′ｌエチレンスルフォン酸ソーダ水７
８液、７、・ト則ポリメチルメタクリレート微粒子（平
均粒子サイズ３０μｍ）、塗布助剤ｔ−オクチルフェノ
キシエトキシエタンスルフオン酸ナトリウム水７８′／
ｆ！１．、帯電防止剤としてポリエチレン系界面活性剤
水溶液および（４）で用いたと同し含フツ素化合物の水
溶液とを添加して塗布液とした。[Staining tA-1) e (CH2) m5Ox (CHz) asOJ
(6) -1 public, -λ layer- table 11 protection 11 layer U cloth 4
1 QwL% gelatin water heated to 40'C 78 liquids Increased water 8 liquids 1 bottle ethylene sulfonate sodium water 7
8 liquids, 7, polymethyl methacrylate fine particles (average particle size 30 μm), coating aid sodium t-octylphenoxyethoxyethanesulfonate water 78'/
f! 1. A coating solution was prepared by adding an aqueous solution of a polyethylene surfactant as an antistatic agent and an aqueous solution of the same fluorine-containing compound as used in (4).
（７）１充跋料五作衣
前記のパック塗布液をハックの表面保護Ｎ塗布液ととも
に下記のポリエチレンテレフタレート支持体の一方の側
にゼラチン塗布量が４ｇ／ｍ”となるように塗布した。(7) 1 Pack Coating Solution The pack coating solution described above was coated together with Huck's surface protection N coating solution on one side of the following polyethylene terephthalate support so that the gelatin coating amount was 4 g/m''.
これに続いて支持体の反対の側に先ず、近赤外増怒色素
入りの乳剤Ａの乳剤塗布液とこれ用の表面保護層塗布液
とを塗布銀量が３．５ｇ／ｍ”となるように塗布し、試
料を作成した。Subsequently, on the opposite side of the support, first, an emulsion coating solution of emulsion A containing a near-infrared sensitizing dye and a coating solution for a surface protective layer were coated so that the amount of silver was 3.5 g/m''. A sample was prepared.
支■体
二軸延伸された厚さ１７５μｍのポリエチレンナレフタ
レートフィルム上にコロナ放電処Ｆｌヲオこない、下記
の組成より成る第１下塗液を塗布量か５．ｌｃｃ／ｍ”
となるようにワイヤーバーコーターにより塗布し、１７
５°Ｃにて１分間乾燥した。A 175 μm thick biaxially stretched polyethylene nalphthalate film was subjected to corona discharge treatment, and a first undercoating liquid having the following composition was applied in an amount of 5.5 μm. lcc/m”
Apply with a wire bar coater so that 17
Dry for 1 minute at 5°C.
次に反対面にも同様にして第１下塗層を設けた。Next, a first undercoat layer was provided on the opposite side in the same manner.
ｒブタジェン−スチレン共電
： 合体ラテックス溶ＩＦＩ（固
゛ 型骨４０％ブタジェン／
ｉ スチレン重量比−３１／
’、 ６９
７９ｃｃ：
１２．４−ジクロロ−６−ヒ
■ ドロキシ−３−トリアジ
１．
１ ノナトリウム塩４％溶液 ２０．５ｃｃ１蒸
留水 ９００．５ｃｃ■
ｉ＊ラテックス溶液中には、乳化分散剤としてをラテッ
クス固型分に対し０．４ｗｔ％含存。r Butadiene-styrene co-electric: Combined latex soluble IFI (hard bone 40% butadiene/i styrene weight ratio -31/', 69
79cc: 12.4-dichloro-6-hydroxy-3-triazide 1. 1 Nonsodium salt 4% solution 20.5 cc 1 Distilled water 900.5 cc ■ The i* latex solution contains 0.4 wt % of an emulsifying dispersant based on the latex solid content.
上記の両面の第１下塗層上に下記の組成から成る第２の
下塗液を塗布量が８．５ｃｃ／ｍ”となるように片面ず
つ、両面器こ塗布・乾燥して下塗済フィルムを完成した
。On both sides of the first undercoat layer, apply a second undercoat liquid having the composition shown below to one side at a time with a coating amount of 8.5 cc/m'' and dry to form the undercoated film. completed.
第２の下塗液
０ゼラチン ３０ｇ（Ｏマッ
ト剖
１ 平均粒径２．５μｍのポ
斐
”ＪＪ＋ｔ、）９．’）Ｉｙ−） ０．３ｇＤ
Ｉｌｉｎを目視観察し残色の評価をした。Second base coating solution 0 gelatin 30 g (O matte analysis 1 average particle size 2.5 μm pores"JJ+t,)9.')Iy-) 0.3 gD
Ilin was visually observed and residual color was evaluated.
○：実用上問題なし
×：実用上問題あり
これらの試料をそれぞれ、画像露光／自動現像装置を使
用して、下記露光、現像、定着、水洗、乾燥の処理を行
った。○: No practical problem ×: Practical problem Each of these samples was subjected to the following exposure, development, fixing, water washing, and drying processes using an image exposure/automatic developing device.
露光は７８０ｎｍの波長の半導体レーザを用いて１０−
７秒のスキャニング露光を行った。Exposure was performed using a semiconductor laser with a wavelength of 780 nm.
A scanning exposure of 7 seconds was performed.
露光後の現像および定着は、下記の現像液と定着液にて
用いた。そしてｉ準現像温度３５°Ｃで定着、水洗、乾
燥を含めて７０秒の処理を行った。For development and fixing after exposure, the following developer and fixer were used. Then, processing including fixing, washing with water, and drying was performed for 70 seconds at an i-semi-development temperature of 35°C.
現像液
水酸化カリウム １６．９８ｇ氷酢酸
１．８ｇ亜硫酸ナトリウム
６０ｇ重炭酸カリウム
５．０ｇホウ酸
３、Ｏｇ〕エチレングリコール １
２．０ｇジエチレントリアミン五酢酸 ２，０ｇ
５−メチルベンゾトリアゾール ０．６ｇハイドロ
キノン ２５．０ｇ４−ヒドロキシメ
チル−４−メ
チル−１−フェニル−３−ピ
ラゾリドン １．６５ｇ臭化カリ
ウム ２，０ｇ水を加えて１１
に仕上げる。Developer solution Potassium hydroxide 16.98g Glacial acetic acid
1.8g sodium sulfite 60g potassium bicarbonate
5.0g boric acid
3, Og] ethylene glycol 1
2.0g diethylenetriaminepentaacetic acid 2.0g
5-Methylbenzotriazole 0.6g Hydroquinone 25.0g 4-Hydroxymethyl-4-methyl-1-phenyl-3-pyrazolidone 1.65g Potassium bromide 2.0g Add water and prepare 11
Finish it.
（ｐＨを１０．２５に調整する。）
定着液
チオ硫酸アンモニウム １４０ｇ亜硫酸ナ
トリウム（集水） １５ｇエチレンジアミ
ン四酢酸二ナト
リうムニ水塩 ０．０２５ｇ氷酢酸でｐ
Ｈ５，１に調整する。(Adjust the pH to 10.25.) Fixer Ammonium thiosulfate 140g Sodium sulfite (water collection) 15g Ethylenediaminetetraacetic acid disodium dihydrate 0.025g P with glacial acetic acid
Adjust to H5.1.
水を加えて全量を１１にする。Add water to bring the total volume to 11.
〈センサー検出性〉
試料を各１０枚自動現像機のフィルム挿入口より挿入し
検出されたかどうかをテストした。<Sensor Detectability> Ten samples each were inserted into the film insertion slot of an automatic processor and tested to see if they were detected.
この自動現像機はフィルム挿入口に一対の赤外線発光素
子（第１図参照）と受光素子（第２図参照）を持ち、挿
入された試料が赤外線を充分に遮断することによって゛
試料の挿入を認識し、それによって搬送ローラーが始動
してフィルムを現像槽へと搬送する機構になっている。This automatic processor has a pair of infrared light-emitting elements (see Figure 1) and light-receiving elements (see Figure 2) in the film insertion slot. The mechanism recognizes this and starts the transport rollers to transport the film to the developer tank.
〈定着液補充３／４での定着性〉
上記定着液の補充を３／４に減らしてランニングし定着
のレベルを評価した。<Fixing performance with fixer replenishment 3/4> The fixing level was evaluated by running with the fixer replenishment reduced to 3/4.
○：実用上問題なし
×：定着不良あり問題
表１
試料５：特開昭６２−２９９９５９に準して、化学熟成
されていない平均サイズ０．１９μの沃臭化銀乳剤（Ａ
ｇ量として０．２７ｇ／ｌ１１ ）と比較ｄｙｅ −１
（７、５Ｂ／ｒａ”を予めまぶした後、ハックＮ塗布液
に添加し、塗布した。○: No practical problem ×: Poor fixation Problem Table 1 Sample 5: Silver iodobromide emulsion (A
compared with 0.27g/l11) dye-1
(7.5B/ra" was pre-sprinkled, then added to the Huck N coating solution and applied.
比較ｄｙｅ−１
ＣｂＨｓ ＣＪｓ試料６：特開昭
６３−１３１１３５に準して光散乱粒子を用意した。（
化学熟成していない平均粒子サイズ０．７２μの沃臭化
銀乳剤を０．２２ｇ／ｍ”塗布した）
第１表かられかるように本発明の試料はセンサー検出性
、残色、定着性を満足し優れていることがわかる。試料
５は水溶性の低い染料を使用しているため残色が非常に
問題である。Comparison dye-1 CbHs CJs Sample 6: Light scattering particles were prepared according to JP-A-63-131135. (
A silver iodobromide emulsion with an average grain size of 0.72μ that had not been chemically ripened was coated at 0.22g/m'') As can be seen from Table 1, the samples of the present invention had excellent sensor detectability, residual color, and fixability. It can be seen that the results are satisfactory and excellent.Sample 5 uses a dye with low water solubility, so residual color is a serious problem.
（発明の効果）
本発明の染料を含有するハロゲン化銀写真感光材料は、
センサーの検出性に優れているばかりでなく、残色およ
び定着性の点でも極めて優れるものである。(Effect of the invention) The silver halide photographic material containing the dye of the invention is
It not only has excellent sensor detectability, but also extremely excellent color retention and fixing properties.
第１図及び第２図は実施例−１で用いた自現機のフィル
ム挿入口における赤外線発光素子（第１図）及び受光素
子（第２図）の分光感度特性を表わす。
各々、その横軸は波長域を表わし、第１図の縦軸はセン
サー相対輝度を、第２図の縦軸はセンサー相対感度を表
わす。
特許出願人 冨士写真フィルム株式会社第１図
第２図
板長を労肩）
手続補正書
平成３年乙月／？日
特許庁長官 殿 ８邑゛。
１、 事件の表示 平成２年特願第３１９７４３号２
、発明の名称 ハロゲン化銀写真感光材料３、補正を
する者
事件との関係 特許出願人
住 所 神奈川県南足柄市中沼２１０番地名 称（
５２０）富士写真フィルム株式会社連絡先 〒１０６東
京都港区西麻布２丁目２６番３０号富士写真７１Ａ株式
会社 東京本社
電話（３４０６） ２５３７
４、補正の対象 明細書の「発明の詳細な説明」の欄
５、補正の内容
明細書の「発明の詳細な説明」の項の記載を下記の通り
補正する。
１） 第９頁３行目の
「好ましくはＮＲ”・ＲＩ２で表わされる基である」
を削除する。
平成３年２月２日
特許庁長官 殿 −１１、
事件の表示 平成２年特願第３１９７４３号２、 発
明の名称 ハロゲン化銀写真感光材料３、補正をする
者
事件との関係 特許出願人
住 所 神奈川県南足柄市中沼２１０番地名 称（
５２０）富士写真フィルム株式会社連絡先 〒１０６東
京都港区西麻布２丁目２６番３０号冨士写真ｙ ＜ ル
ム株式会社 東京本社電話（３４０６） ２５３７
４、補正の対象 明細書の「発明の詳細な説明」の欄
５、補正の内容
明細書のｒ発明の詳細な説明」の項の記載を下記の通り
補正する。
１） 第１４頁の■−１１の化学構造式をと補正する。
２） 第１４頁の■−１２の化学構造式を’ Ｃ！Ｈ
４５Ｏ３−ＣＨｉ ＣｚＨａＳＯｚＫｌ
１ １と補正する。
３） 第１４頁下から８行目の
ｒＡｍｅ、Ｊを
ｒＡｍ、 Ｊ
４） 第３３頁１９行目の
「１ｇ」を
’１ｋｇ」
と補正する。
５） 第３７頁の
」
’ ｎｃＪ＋３００ｃｃＨ２
ｎｃＪ＋５ｏＯｃｃＨ−５ＯＪａ Ｊ
と補正する。1 and 2 show the spectral sensitivity characteristics of the infrared light emitting element (Fig. 1) and the light receiving element (Fig. 2) in the film insertion slot of the automatic processing machine used in Example-1. In each case, the horizontal axis represents the wavelength range, the vertical axis in FIG. 1 represents the sensor relative brightness, and the vertical axis in FIG. 2 represents the sensor relative sensitivity. Patent applicant: Fuji Photo Film Co., Ltd. Figure 1, Figure 2, board manager) Procedural amendment written in Otsu-Mon, 1991/? Dear Commissioner of the Japan Patent Office, 8-e. 1. Indication of the incident 1990 Patent Application No. 319743 2
, Title of the invention, Silver halide photographic light-sensitive material 3, Relationship to the amended person's case Patent applicant address 210 Nakanuma, Minamiashigara City, Kanagawa Prefecture Name (
520) Fuji Photo Film Co., Ltd. Contact information: 2-26-30 Nishi-Azabu, Minato-ku, Tokyo 106 Fuji Photo 71A Co., Ltd. Tokyo Head Office Telephone: (3406) 2537 4. Subject of amendment: ``Detailed description of the invention'' in the specification. Column 5: The description in the "Detailed Description of the Invention" section of the description of contents of the amendment is amended as follows. 1) Delete "Preferably a group represented by NR" and RI2 on page 9, line 3. February 2, 1991 Commissioner of the Patent Office -11
Indication of the case 1990 Japanese Patent Application No. 3197432, Title of the invention Silver halide photographic light-sensitive material 3, Person making the amendment Relationship to the case Patent applicant address 210 Nakanuma, Minamiashigara City, Kanagawa Prefecture Name (
520) Fuji Photo Film Co., Ltd. Contact information Fuji Photo Y 2-26-30 Nishi-Azabu, Minato-ku, Tokyo 106 < Lum Co., Ltd. Tokyo Head Office Telephone: (3406) 2537 4. Subject of amendment ``Detailed description of the invention'' in the specification The description in Column 5, ``Detailed Description of the Invention'' of the Description of Contents of Amendment is amended as follows. 1) Correct the chemical structural formula in ■-11 on page 14. 2) Replace the chemical structural formula of ■-12 on page 14 with 'C! H
45O3-CHi CzHaSOzKl
1 Correct as 1. 3) rAme, J on the 8th line from the bottom of page 14 is rAm, J 4) Correct "1g" on page 33, line 19 to '1kg'. 5) Correct it to ``' ncJ+300ccH2 ncJ+5oOccH-5OJa J on page 37.
Claims (2)
化銀乳剤層を有し、両側の塗布銀量の合計が４．０ｇ／
ｍ＾２未満であり、かつ下記一般式（ I ）及び（II）
で表される染料から選ばれる少なくとも一種を含有する
ことを特徴とするハロゲン化銀写真感光材料。 一般式（ I ） ▲数式、化学式、表等があります▼ 式中、Ｒ＾１、Ｒ＾２、Ｒ＾３、およびＲ＾４は互いに
同じでも異なっていても良く、水素原子、あるいはアル
キル基を示し、Ｒ＾１とＲ＾２、Ｒ＾３とＲ＾４で５〜
６員環を形成してもよく、またＲ＾１、Ｒ＾２、Ｒ＾３
、Ｒ＾４のいずれか、Ｎ原子及び隣接するベンゼン環と
で５〜６員環を形成してもよい。Ｒ＾５およびＲ＾６は
互いに同じでも異なっていてもよく、水素原子または１
価の基を表わし、Ｘ＾−はアニオンを示し、ｎは１また
は２であり、染料分子が分子内塩を形成するときは１で
ある。 一般式（II） ▲数式、化学式、表等があります▼ 式中、Ｒ＾７およびＲ＾８は互いに同じでも異なってい
ても良くアルキル基を示し、Ｒ＾９およびＲ＾１＾０は
互いに同じでも異なっていても良く、水素原子または１
価の基を表わし、Ｌはメチン基を表わし、Ｘ＾−はアニ
オンを示し、ｎは１または２であり、染料分子が分子内
塩を形成するときは１である。(1) The support has one photosensitive silver halide emulsion layer on at least one side, and the total amount of silver coated on both sides is 4.0 g/
m^2, and the following general formulas (I) and (II)
A silver halide photographic material containing at least one kind selected from the dyes represented by: General formula (I) ▲There are mathematical formulas, chemical formulas, tables, etc.▼ In the formula, R^1, R^2, R^3, and R^4 may be the same or different, and are hydrogen atoms or alkyl groups. , R^1 and R^2, R^3 and R^4 are 5~
A 6-membered ring may be formed, and R^1, R^2, R^3
, R^4 may form a 5- to 6-membered ring with the N atom and the adjacent benzene ring. R^5 and R^6 may be the same or different, and each represents a hydrogen atom or 1
It represents a valent group, X^- represents an anion, n is 1 or 2, and is 1 when the dye molecule forms an inner salt. General formula (II) ▲There are mathematical formulas, chemical formulas, tables, etc.▼ In the formula, R^7 and R^8 may be the same or different from each other and represent an alkyl group, and R^9 and R^1^0 are mutually May be the same or different, hydrogen atom or 1
represents a valent group, L represents a methine group, X^- represents an anion, n is 1 or 2, and is 1 when the dye molecule forms an inner salt.
料分子が少なくとも２個の酸性置換基を有することを特
徴とするハロゲン化銀写真感光材料。(2) A silver halide photographic light-sensitive material represented by general formulas (I) and (II), characterized in that each dye molecule has at least two acidic substituents.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2319743A JP2676117B2 (en) | 1990-11-22 | 1990-11-22 | Silver halide photographic material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2319743A JP2676117B2 (en) | 1990-11-22 | 1990-11-22 | Silver halide photographic material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04194841A true JPH04194841A (en) | 1992-07-14 |
| JP2676117B2 JP2676117B2 (en) | 1997-11-12 |
Family
ID=18113677
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2319743A Expired - Lifetime JP2676117B2 (en) | 1990-11-22 | 1990-11-22 | Silver halide photographic material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2676117B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998022146A3 (en) * | 1996-11-19 | 1998-10-15 | Diagnostikforschung Inst | Optical diagnostic agents for diagnosis of neurodegenerative diseases by means of near infra-red radiation (nir radiation) |
| EP1093015A1 (en) * | 1999-10-13 | 2001-04-18 | Agfa-Gevaert N.V. | IR-photographic sensitizing dyes |
| US6461804B1 (en) | 1999-10-13 | 2002-10-08 | Agfa-Gevaert | IR-photographic sensitizing dyes |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62230857A (en) * | 1986-03-12 | 1987-10-09 | バスフ アクチェン ゲゼルシャフト | Naphtholactam dye and optical recording medium containing the same |
| JPS62299959A (en) * | 1986-06-20 | 1987-12-26 | Konica Corp | Silver halide photographic sensitive material for exposure to radiation |
| JPH02216140A (en) * | 1988-12-23 | 1990-08-29 | Minnesota Mining & Mfg Co <3M> | Infrared ray sensitive photographic material with anti-halation dye and/or acutance dye blended |
-
1990
- 1990-11-22 JP JP2319743A patent/JP2676117B2/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62230857A (en) * | 1986-03-12 | 1987-10-09 | バスフ アクチェン ゲゼルシャフト | Naphtholactam dye and optical recording medium containing the same |
| JPS62299959A (en) * | 1986-06-20 | 1987-12-26 | Konica Corp | Silver halide photographic sensitive material for exposure to radiation |
| JPH02216140A (en) * | 1988-12-23 | 1990-08-29 | Minnesota Mining & Mfg Co <3M> | Infrared ray sensitive photographic material with anti-halation dye and/or acutance dye blended |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998022146A3 (en) * | 1996-11-19 | 1998-10-15 | Diagnostikforschung Inst | Optical diagnostic agents for diagnosis of neurodegenerative diseases by means of near infra-red radiation (nir radiation) |
| US6329531B1 (en) | 1996-11-19 | 2001-12-11 | Schering Ag | Optical diagnostic agents for diagnosis of neurodegenerative diseases by means of near infrared radiation (NIR radiation) |
| EP1093015A1 (en) * | 1999-10-13 | 2001-04-18 | Agfa-Gevaert N.V. | IR-photographic sensitizing dyes |
| US6461804B1 (en) | 1999-10-13 | 2002-10-08 | Agfa-Gevaert | IR-photographic sensitizing dyes |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2676117B2 (en) | 1997-11-12 |
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