JPH04178497A - Lubricating composition - Google Patents
Lubricating compositionInfo
- Publication number
- JPH04178497A JPH04178497A JP30452590A JP30452590A JPH04178497A JP H04178497 A JPH04178497 A JP H04178497A JP 30452590 A JP30452590 A JP 30452590A JP 30452590 A JP30452590 A JP 30452590A JP H04178497 A JPH04178497 A JP H04178497A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- talc
- fluororesin
- manufactured
- tetrafluoroethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 15
- 230000001050 lubricating effect Effects 0.000 title claims abstract description 11
- 229920005989 resin Polymers 0.000 claims abstract description 27
- 239000011347 resin Substances 0.000 claims abstract description 27
- 239000004734 Polyphenylene sulfide Substances 0.000 claims abstract description 16
- 229920000069 polyphenylene sulfide Polymers 0.000 claims abstract description 16
- 239000000454 talc Substances 0.000 claims abstract description 12
- 229910052623 talc Inorganic materials 0.000 claims abstract description 12
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 abstract description 9
- 229910000838 Al alloy Inorganic materials 0.000 abstract description 7
- 239000002245 particle Substances 0.000 abstract description 3
- -1 polyphenylene Polymers 0.000 abstract description 3
- 239000007779 soft material Substances 0.000 abstract description 3
- 229920000265 Polyparaphenylene Polymers 0.000 abstract 1
- 238000005299 abrasion Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 22
- 230000013011 mating Effects 0.000 description 16
- 239000000843 powder Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 238000002156 mixing Methods 0.000 description 6
- 239000002994 raw material Substances 0.000 description 5
- 229920003002 synthetic resin Polymers 0.000 description 5
- 239000000057 synthetic resin Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 229910002804 graphite Inorganic materials 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000010439 graphite Substances 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000004760 aramid Substances 0.000 description 2
- 229920003235 aromatic polyamide Polymers 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 229920006358 Fluon Polymers 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 241000282320 Panthera leo Species 0.000 description 1
- 229920006361 Polyflon Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical group FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000003779 heat-resistant material Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- FFNMBRCFFADNAO-UHFFFAOYSA-N pirenzepine hydrochloride Chemical compound [H+].[H+].[Cl-].[Cl-].C1CN(C)CCN1CC(=O)N1C2=NC=CC=C2NC(=O)C2=CC=CC=C21 FFNMBRCFFADNAO-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- SRRKNRDXURUMPP-UHFFFAOYSA-N sodium disulfide Chemical compound [Na+].[Na+].[S-][S-] SRRKNRDXURUMPP-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007592 spray painting technique Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
この発明は各種の摺動部材料として利用されるポリフェ
ニレンサルファイド樹脂を主成分とする潤滑性組成物に
関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a lubricating composition containing polyphenylene sulfide resin as a main component and used as a material for various sliding parts.
近年、合成樹脂滑り軸受の用途分野が拡大するにつれて
、軸受の使用条件、特に高温雰囲気下において、良好な
摩擦摩耗特性を発揮するような耐熱性のある合成樹脂製
軸受が強く要望されるようになってきた。In recent years, as the field of application for synthetic resin plain bearings has expanded, there has been a strong demand for heat-resistant synthetic resin bearings that exhibit good friction and wear characteristics under the conditions in which the bearings are used, especially in high-temperature environments. It has become.
また、軸受の相手材としても安価なアルミニウム合金Ａ
３０５６等が使用されており、使用中に相手材を傷つけ
ないような軸受の特性が要求されている。In addition, aluminum alloy A is inexpensive as a mating material for bearings.
3056 etc. are used, and the bearing is required to have characteristics that will not damage the mating material during use.
従来、耐熱性が良く機械的強度の優れた熱可塑性合成樹
脂としてポリフェニレンサルファイド（ＰＰＳと略称す
る）樹脂が用いられていることはよく知られている。し
かし、このＰＰＳ樹脂は自己潤滑性が乏しいため、潤滑
性を必要とする部分の材料として使用するに際しては、
潤滑剤などを添加して別途潤滑性を付与しなければなら
ない。It is well known that polyphenylene sulfide (abbreviated as PPS) resin has been used as a thermoplastic synthetic resin with good heat resistance and mechanical strength. However, this PPS resin has poor self-lubricating properties, so when using it as a material for parts that require lubricity,
Lubricating properties must be provided separately by adding a lubricant or the like.
そこで、このようなＰＰＳ樹脂に、たとえば黒鉛、四フ
ッ化エチレン樹脂、潤滑油、金属酸化物、芳香族ポリア
ミド樹脂等を添加した複合材料が開発されている。しか
し、このような複合材料は高温、高負荷条件のもとて良
好な摩擦摩耗特性を発揮させるという点で決して充分で
あるとは言えない。Therefore, composite materials have been developed in which graphite, tetrafluoroethylene resin, lubricating oil, metal oxides, aromatic polyamide resins, and the like are added to such PPS resins. However, such composite materials cannot be said to be sufficient in terms of exhibiting very good friction and wear characteristics under high temperature and high load conditions.
また、ＰＰＳ樹脂に四フッ化エチレン樹脂およびＰＰＳ
樹脂より耐熱性のある合成樹脂粉末を添加した複合材料
も開発されているが、相手材が硬質の材料である場合、
良好な摩擦摩耗特性を発揮するものの、相手材がアルミ
ニウム合金の場合は相手材を傷つけてしまう。一方、炭
素繊維を配合した複合材料は初期においては良好な摩擦
摩耗特性を示すが、相手材が硬質でも相手材を損傷させ
、その損傷にともない摩擦摩耗特性が急激に悪化する。In addition, PPS resin and tetrafluoroethylene resin and PPS
Composite materials containing synthetic resin powder, which is more heat resistant than resin, have also been developed, but if the other material is a hard material,
Although it exhibits good friction and wear characteristics, if the mating material is an aluminum alloy, it will damage the mating material. On the other hand, a composite material containing carbon fibers exhibits good friction and wear characteristics in the initial stage, but even if the mating material is hard, it damages the mating material, and as the material is damaged, the friction and wear characteristics rapidly deteriorate.
このように、従来の技術においては良好な潤滑特性を備
えた耐熱性材料がなく世間の要望に対処し得ないという
問題点があり、これを解決することが課題となっていた
。As described above, the conventional technology has the problem that it cannot meet the demands of the public because there is no heat-resistant material with good lubrication properties, and it has been an issue to solve this problem.
（課題を解決するための手段〕
上記の課題を解決するために、この発明は、ＰＰＳ樹脂
にフッ素樹脂５〜４０重量％と、タルク５〜３０重量％
とを必須成分として添加した潤滑性組成物とする手段を
採用したものである。以下その詳細を述べる。(Means for Solving the Problems) In order to solve the above problems, the present invention includes PPS resin containing 5 to 40% by weight of fluororesin and 5 to 30% by weight of talc.
This method employs a method of creating a lubricating composition in which the following are added as essential components. The details will be described below.
まず、この発明におけるＰＰＳ樹脂は、−Ｃ式％式％
で示される合成樹脂である。ここで、式中−ｐｈ−であ
り、ＱはＦ、ＣＩ、ＢｒのハロゲンもしくはＣＩ＋３で
あり、ｍは１〜４の整数を示す。これらのうち、で示さ
れるものであり、米国フィリップス・ベトローリアム社
から「ライドン」の商標で市販され、その製造方法は米
国特許第３．３５４，１２９号（対応特許特公昭４５−
３３６８号）に開示されている。それによると、ライド
ンはＮ−メチルピロリドン溶媒中、１６０〜２５０°Ｃ
１加圧条件下にｐ〜ジクロルヘンゼンと二硫化ソーダと
を反応させることによって製造され、樹脂中に交差結合
が全くないものから部分的交差結合を有するものに至る
まで各種重合度のものを後熱処理工程にかけて自由に製
造することができるので、目的の溶媒ブレンドに適正な
溶融粘度特性を有するものを任意に選択使用することが
可能である。また、架橋構造をとらず直鎖状のものも使
用できる。First, the PPS resin in this invention is a synthetic resin represented by the formula -C. Here, in the formula, -ph-, Q is a halogen of F, CI, Br, or CI+3, and m represents an integer of 1 to 4. Among these, it is commercially available from Philips Vetroleum Company of the United States under the trademark "Rydon", and its manufacturing method is described in U.S. Patent No. 3,354,129 (corresponding patent No.
No. 3368). According to it, Rydon is heated at 160-250°C in N-methylpyrrolidone solvent.
1 Manufactured by reacting p~dichlorohenzene with sodium disulfide under pressurized conditions, and post-heat treatment of resins with various degrees of polymerization, ranging from those with no cross-linking to those with partial cross-linking. Since it can be manufactured freely through various processes, it is possible to arbitrarily select and use a solvent having appropriate melt viscosity characteristics for the desired solvent blend. Moreover, a linear one without a crosslinked structure can also be used.
また、この発明におけるフッ素樹脂は四フフ化エチレン
樹脂、エチレン−テトラフルオロエチレン共重合体、テ
トラフルオロエチレン−パーフルオロアルキルビニルエ
ーテル共重合体、テトラフルオロエチレン−ヘキサフル
オロプロピレン共重合体、ポリトリクロロフルオロエチ
レン等があげられるが、特に四フッ化エチレン樹脂が好
ましい。In addition, the fluororesin in this invention includes tetrafluoroethylene resin, ethylene-tetrafluoroethylene copolymer, tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer, tetrafluoroethylene-hexafluoropropylene copolymer, polytrichlorofluoroethylene Among them, tetrafluoroethylene resin is particularly preferred.
そして、四フッ化エチレン樹脂は、四フッ化エチレンの
重合体であり、成形用の粉末であっても、また、いわゆ
る固体潤滑剤用の微粉末であってもよく、たとえば三片
デュポン・フロロケミカル社製：テフロン７Ｊ、 Ｔ１
．Ｐ−１０、旭硝子社製：フルオンＧ１６３、ダイキン
工業社製：ポリフロンＭ１５、ルブロンし５などを例示
することができる。Tetrafluoroethylene resin is a polymer of tetrafluoroethylene, and may be a powder for molding or a fine powder for so-called solid lubricants, such as Mikata DuPont Fluoroethylene. Manufactured by Chemical Company: Teflon 7J, T1
．． P-10, Fluon G163 (manufactured by Asahi Glass Co., Ltd.), Polyflon M15 (manufactured by Daikin Industries, Ltd.), LeBlon Shi 5, etc. can be exemplified.
また、この発明におけるタルクは、マグネシウムの含水
ケイ酸塩であって、粉末状、鱗片状、繊維状のものが好
ましい。また、これらの粒径は０．１〜１００ ｐｖａ
、好ましくは０．５〜６０μｍのものである。Moreover, the talc in this invention is a hydrous silicate of magnesium, and is preferably in the form of powder, scale, or fiber. In addition, these particle sizes range from 0.1 to 100 pva
, preferably 0.5 to 60 μm.
なお、この発明において、フッ素樹脂の量を５〜４０重
世％に限定する理由は５重量％より少ないと潤滑特性が
悪く、４０重量％をこえると著しく成形性がそこなわれ
るからである。また、タルクの量を５〜３０重量％に限
定する理由は、この範囲外では潤滑特性が悪く、３０重
量％を越えると極端にもろくなるからである。In this invention, the reason why the amount of fluororesin is limited to 5 to 40% by weight is that if it is less than 5% by weight, the lubricating properties will be poor, and if it exceeds 40% by weight, the moldability will be significantly impaired. Further, the reason why the amount of talc is limited to 5 to 30% by weight is that outside this range, the lubricating properties are poor, and if it exceeds 30% by weight, it becomes extremely brittle.
ここで、配合割合の決まった各添加物を混合する方法は
特に限定するものではなく、通常広く用いられている方
法、たとえば主成分となる樹脂、その他の諸原料をそれ
ぞれ個別に、またはヘンシェルミキサー、ボールミル、
タンブラ−ミキサー等の混合機によって適宜乾式混合し
た後、溶融混合性のよい射出成形機もしくは溶融押出成
形機に供給するか、または、予め熱ロール、ニーダ、バ
ンバリーミキサ−１熔融押出機などで溶融混合するなど
の方法を利用すればよい、さらに、この発明の組成物を
成形するにあたっても、特にその方法を限定するもので
はな（、圧縮成形、押出成形、射出成形等の通常の方法
、または組成物を溶融混合した後、これをジェットミル
、冷凍粉砕機等によって粉砕し、所望の粒径に分級する
か、または分級しないままで、得られた粉末を用いた流
動浸漬塗装、静電粉体塗装などを行なうことも可能であ
る。また、得られた粉末を溶剤に分散させて、スプレー
塗装または浸漬塗装を行なうことも可能である。Here, the method of mixing each additive with a fixed blending ratio is not particularly limited, and any commonly used method may be used, such as mixing the main component resin and other raw materials individually, or using a Henschel mixer. , ball mill,
After dry mixing as appropriate using a mixer such as a tumbler mixer, the mixture is supplied to an injection molding machine or melt extrusion molding machine with good melt mixing properties, or it is melted in advance using a heated roll, kneader, Banbury mixer 1 melt extruder, etc. Furthermore, the method for molding the composition of the present invention is not particularly limited (eg, ordinary methods such as compression molding, extrusion molding, injection molding, or After melt-mixing the composition, it is pulverized using a jet mill, frozen pulverizer, etc., and classified to a desired particle size, or the resulting powder is used for fluidized dip coating, electrostatic powder coating, etc. It is also possible to perform body painting etc. It is also possible to disperse the obtained powder in a solvent and perform spray painting or dip painting.
なお、この発明のＰＰＳ樹脂を主成分とする潤滑性組成
物に対して、潤滑特性を悪化させない範囲内において各
種添加剤を配合することもできる。Note that various additives may be added to the lubricating composition containing the PPS resin of the present invention as a main component within a range that does not deteriorate the lubricating properties.
またその他に、潤滑性をさらに改良するために、各種耐
摩耗性改良剤を配合してもよい。そのような耐摩耗性改
良剤の好ましい例としては、芳香族ポリアミド繊維、グ
ラファイト、芳香族ポリエステル樹脂等を例示できるが
、これらに限定されるものではない。In addition, various wear resistance improvers may be added to further improve the lubricity. Preferred examples of such wear resistance improvers include, but are not limited to, aromatic polyamide fibers, graphite, and aromatic polyester resins.
以上述べたこの発明の組成物は、必須成分としてフッ素
樹脂、タルクを併用することによって、高温雰囲気中で
も良好な転移膜を相手材上に形成し、相手材がアルミニ
ウム合金でも傷つけることなく、良好な潤滑特性を示す
。By using a fluororesin and talc together as essential components, the composition of the present invention described above forms a good transfer film on the mating material even in a high temperature atmosphere, and can form a good transfer film on the mating material without damaging it even if the mating material is an aluminum alloy. Shows lubricating properties.
まず、実施例および比較例に用いた諸原材料を一括して
示すとつぎのとおりである。なお各成分の配合割合は、
すべて重量％である。First, the raw materials used in the Examples and Comparative Examples are listed below. The blending ratio of each ingredient is
All percentages are by weight.
■ ＰＰＳ樹脂（東ソーサスティール社製：ＰＰＳ＃■
ＰＰＳ樹脂（クレハ化学社製： ＫＰＳ−Ｗ２Ｏ３）
■ タルクＡ（松材産業社製：クラウン・タルクＰＰ、
Ｍ片状）
■ タルクＢ（富士タルク工業社製：タルクＲＦ−８゜
繊維状）
■ 四フフ化エチレン樹脂Ａ（三片デュポン・フロロケ
ミカル社製：テフロン７Ｊ）
■ 四フッ化エチレン樹脂Ｂ（喜多村社製：ＫＴ３００
Ｍ、焼成粉）
■ 芳香族ポリエステル樹脂（住人化学工業社製：エコ
ノールＥＩＯＩＭ ）
■ カーボンブランク（ライオン社製：ケソチェンＥＣ
−Ｘ）
■ グラファイト（日本黒鉛社製： ＡＣＰ）実施例１
〜４：
第１表に示す割合で諸原材料を配合した。そして組成物
の成形にあたっては、まず原材料をヘンシェルミキサー
で充分混合し、二軸溶融押出機に供給し、シリンダー温
度３００°Ｃ２回転数毎分１００回転の溶融混合条件で
押出して造粒し、得られたペレットを樹脂温度３１０°
Ｃ１射出圧力８００ｋｇ／ｃｄ、金型温度１４０℃の射
出成形条件下で外径３５刷、内径２５ｍｍ、幅６閣のリ
ング状試験片を成形し、この試験片を用いて以下に示す
高温ラジアル摩擦摩耗試験を行なった。■ PPS resin (manufactured by Tososa Steel Co., Ltd.: PPS#■
PPS resin (manufactured by Kureha Chemical Co., Ltd.: KPS-W2O3)
■ Talc A (Matsuzai Sangyo Co., Ltd.: Crown Talc PP,
M flakes) ■ Talc B (manufactured by Fuji Talc Industries Co., Ltd.: Talc RF-8° fibrous) ■ Tetrafluoroethylene resin A (manufactured by Mikata DuPont Fluorochemical Co., Ltd.: Teflon 7J) ■ Tetrafluoroethylene resin B ( Manufactured by Kitamurasha: KT300
M, fired powder) ■ Aromatic polyester resin (manufactured by Sumima Kagaku Kogyo Co., Ltd.: ECONOL EIOIM) ■ Carbon blank (manufactured by Lion Corporation: Kesochen EC)
-X) ■ Graphite (manufactured by Nippon Graphite Co., Ltd.: ACP) Example 1
~4: Raw materials were blended in the proportions shown in Table 1. To mold the composition, first, the raw materials are thoroughly mixed in a Henschel mixer, then fed to a twin-screw melt extruder, and extruded and granulated at a cylinder temperature of 300°C and a rotation speed of 100 revolutions per minute. The pellets were heated to a resin temperature of 310°.
A ring-shaped test piece with an outer diameter of 35 mm, an inner diameter of 25 mm, and a width of 6 mm was molded under injection molding conditions of a C1 injection pressure of 800 kg/cd and a mold temperature of 140°C, and this test piece was used to perform the high-temperature radial friction shown below. A wear test was conducted.
高温ラジアル摩擦摩耗試験：
密閉された２００°Ｃの雰囲気下で駆動される回転軸に
、同軸外周にアルミニウム合金（Ａ５０５６）製筒形の
相手材を嵌め、この相手材の外周に回転自在第１表
第２表
に嵌めたリング状試験片を相手材周面に対して２．７ｋ
ｇ ｆ ／ ｃＴＡの圧力で押圧し、前記回転軸には、
トルクメークを取り付け、周速が３ｍ／分であるよう１
６８時間連続回転した後、試験片の摩耗量（Ｉｌｇ）、
回転軸のトルク（ｋｇｆ−ｃｍ）を測定し、かつ相手材
の損傷度を観察した。損傷度については、損傷しない（
○印）、やや損傷する（Δ印）または損傷する（×印）
の三段階評価で表わした。得られた結果は第２表にまと
めた。High-temperature radial friction and wear test: A cylindrical mating material made of aluminum alloy (A5056) is fitted around the outer circumference of a rotating shaft driven in a sealed 200°C atmosphere, and a rotatable first rotary shaft is fitted around the outer circumference of the coaxial shaft. The ring-shaped test piece fitted in Table 2 is 2.7k against the surrounding surface of the mating material.
Press with a pressure of g f / cTA, and the rotating shaft has a
Attach the torque make and set the circumferential speed to 3 m/min.
After continuous rotation for 68 hours, the wear amount (Ilg) of the test piece,
The torque (kgf-cm) of the rotating shaft was measured, and the degree of damage to the mating material was observed. Regarding the degree of damage, no damage (
○ mark), slightly damaged (Δ mark), or damaged (x mark)
It was expressed as a three-level evaluation. The results obtained are summarized in Table 2.
比較例１〜５；
第１表に示した割合で原材料を配合したこと以外は実施
例１と全く同様にして試験片を作り、緒特性を求め、得
られた結果を第２表に併記した。Comparative Examples 1 to 5: Test pieces were prepared in the same manner as in Example 1 except that the raw materials were mixed in the proportions shown in Table 1, and the properties of the test pieces were determined. The obtained results are also listed in Table 2. .
第２表に示す結果から、比較例１〜５においては、いず
れも摩耗量、回転トルクが大きく、また、比較例１．２
および５では相手材の損傷が大きかった。一方、実施例
１〜４では、摩耗量、回転トルクとも小さく、しかも相
手材のアルミニウム合金を損傷させないことが明らかに
なった。From the results shown in Table 2, in Comparative Examples 1 to 5, the amount of wear and rotational torque were large, and Comparative Examples 1 and 2
In cases 5 and 5, the damage to the mating material was large. On the other hand, in Examples 1 to 4, both the amount of wear and rotational torque were small, and it was revealed that the aluminum alloy of the mating material was not damaged.
［効果］
以上述べたように、この発明の組成物から得られる成形
体はアルミニウム合金等の軟質材相手でも看れた耐摩耗
性を有しており、しかも相手材を損傷しないので、相手
材を選ばず、軸受材として使用できる。また、ＰＰＳ樹
脂の耐熱性を利用しているので、高温条件下、軟質材相
手で耐摩耗性を要求される用途には格好のものであると
いえる。[Effects] As described above, the molded product obtained from the composition of the present invention has wear resistance that can be observed even when mating with soft materials such as aluminum alloys, and does not damage the mating material. It can be used as a bearing material regardless of the material. Furthermore, since it utilizes the heat resistance of PPS resin, it can be said to be ideal for applications that require wear resistance when working with soft materials under high temperature conditions.
また、この発明の組成物は射出成形を行ない得て成形も
容易であることから、この発明の意義はきわめて大きい
ということができる。Furthermore, since the composition of the present invention can be easily injection molded and molded, it can be said that the present invention is extremely significant.
Claims (1)
５〜４０重量％とタルク５〜３０重量％とを必須成分と
して添加したことを特徴とする潤滑性組成物。(1) A lubricating composition characterized in that 5 to 40% by weight of a fluororesin and 5 to 30% by weight of talc are added as essential components to a polyphenylene sulfide resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30452590A JP3009210B2 (en) | 1990-11-09 | 1990-11-09 | Lubricating composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30452590A JP3009210B2 (en) | 1990-11-09 | 1990-11-09 | Lubricating composition |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16648699A Division JP3126352B2 (en) | 1999-06-14 | 1999-06-14 | Plain bearing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04178497A true JPH04178497A (en) | 1992-06-25 |
| JP3009210B2 JP3009210B2 (en) | 2000-02-14 |
Family
ID=17934067
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP30452590A Expired - Lifetime JP3009210B2 (en) | 1990-11-09 | 1990-11-09 | Lubricating composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3009210B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5990225A (en) * | 1995-05-17 | 1999-11-23 | Mitsubishi Chemical Corporation | Resin of polyphenylene sulfide, polyethylene graft and TFE for sliding member |
-
1990
- 1990-11-09 JP JP30452590A patent/JP3009210B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5990225A (en) * | 1995-05-17 | 1999-11-23 | Mitsubishi Chemical Corporation | Resin of polyphenylene sulfide, polyethylene graft and TFE for sliding member |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3009210B2 (en) | 2000-02-14 |
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