JPH04164015A - Cleaning agent composition - Google Patents
Cleaning agent compositionInfo
- Publication number
- JPH04164015A JPH04164015A JP28770990A JP28770990A JPH04164015A JP H04164015 A JPH04164015 A JP H04164015A JP 28770990 A JP28770990 A JP 28770990A JP 28770990 A JP28770990 A JP 28770990A JP H04164015 A JPH04164015 A JP H04164015A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- cleaning
- surfactant
- surfactants
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 34
- 239000012459 cleaning agent Substances 0.000 title abstract description 6
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 35
- 239000004094 surface-active agent Substances 0.000 claims abstract description 24
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 17
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000011737 fluorine Substances 0.000 claims abstract description 12
- 238000004140 cleaning Methods 0.000 claims abstract description 11
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 10
- 239000010702 perfluoropolyether Substances 0.000 claims abstract description 8
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 5
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 5
- 239000003921 oil Substances 0.000 claims description 11
- 125000001153 fluoro group Chemical group F* 0.000 claims description 5
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims 1
- 239000002453 shampoo Substances 0.000 abstract description 15
- 230000003750 conditioning effect Effects 0.000 abstract description 14
- 238000001035 drying Methods 0.000 abstract description 11
- 239000004615 ingredient Substances 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 2
- 239000000314 lubricant Substances 0.000 abstract 2
- -1 detergency Substances 0.000 description 21
- 239000003599 detergent Substances 0.000 description 14
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- 239000000194 fatty acid Substances 0.000 description 8
- 229930195729 fatty acid Natural products 0.000 description 8
- 150000004665 fatty acids Chemical class 0.000 description 7
- 239000004205 dimethyl polysiloxane Substances 0.000 description 6
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 6
- 239000003205 fragrance Substances 0.000 description 6
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 6
- 239000000049 pigment Substances 0.000 description 6
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 6
- 239000003755 preservative agent Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 235000000346 sugar Nutrition 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 4
- 229920006317 cationic polymer Polymers 0.000 description 4
- 230000003766 combability Effects 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 150000002170 ethers Chemical class 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 230000002335 preservative effect Effects 0.000 description 4
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 150000001413 amino acids Chemical class 0.000 description 3
- 229960003237 betaine Drugs 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000003002 pH adjusting agent Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 150000008163 sugars Chemical class 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- QFOHBWFCKVYLES-UHFFFAOYSA-N Butylparaben Chemical compound CCCCOC(=O)C1=CC=C(O)C=C1 QFOHBWFCKVYLES-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- 229920006318 anionic polymer Polymers 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 229950011087 perflunafene Drugs 0.000 description 2
- UWEYRJFJVCLAGH-IJWZVTFUSA-N perfluorodecalin Chemical compound FC1(F)C(F)(F)C(F)(F)C(F)(F)[C@@]2(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)[C@@]21F UWEYRJFJVCLAGH-IJWZVTFUSA-N 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 229960003080 taurine Drugs 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- WNZGTRLARPEMIG-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-hexacosafluorododecane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F WNZGTRLARPEMIG-UHFFFAOYSA-N 0.000 description 1
- UVWPNDVAQBNQBG-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-icosafluorononane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F UVWPNDVAQBNQBG-UHFFFAOYSA-N 0.000 description 1
- BIHQJMSIEXRWPS-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;dodecyl dihydrogen phosphate Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOP(O)(O)=O BIHQJMSIEXRWPS-UHFFFAOYSA-N 0.000 description 1
- RZRILSWMGXWSJY-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;sulfuric acid Chemical compound OS(O)(=O)=O.OCCN(CCO)CCO RZRILSWMGXWSJY-UHFFFAOYSA-N 0.000 description 1
- CJFUEPJVIFJOOU-UHFFFAOYSA-N 2-perfluorobutyltetrahydrofuran Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C1CCCO1 CJFUEPJVIFJOOU-UHFFFAOYSA-N 0.000 description 1
- FRPAVHFNOFSNDR-UHFFFAOYSA-N 3-(2,4-dioxo-1,3-thiazolidin-3-yl)propanoic acid Chemical compound OC(=O)CCN1C(=O)CSC1=O FRPAVHFNOFSNDR-UHFFFAOYSA-N 0.000 description 1
- 241000283690 Bos taurus Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 1
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229940067596 butylparaben Drugs 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- JZKFHQMONDVVNF-UHFFFAOYSA-N dodecyl sulfate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOS(O)(=O)=O JZKFHQMONDVVNF-UHFFFAOYSA-N 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229940100608 glycol distearate Drugs 0.000 description 1
- 229940074774 glycyrrhizinate Drugs 0.000 description 1
- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229920000591 gum Polymers 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 229940031957 lauric acid diethanolamide Drugs 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 229960004692 perflenapent Drugs 0.000 description 1
- FRZFEPXEUZSBLA-UHFFFAOYSA-N perfluoroadamantane Chemical compound FC1(F)C(C2(F)F)(F)C(F)(F)C3(F)C(F)(F)C1(F)C(F)(F)C2(F)C3(F)F FRZFEPXEUZSBLA-UHFFFAOYSA-N 0.000 description 1
- BPHQIXJDBIHMLT-UHFFFAOYSA-N perfluorodecane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F BPHQIXJDBIHMLT-UHFFFAOYSA-N 0.000 description 1
- YVBBRRALBYAZBM-UHFFFAOYSA-N perfluorooctane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YVBBRRALBYAZBM-UHFFFAOYSA-N 0.000 description 1
- NJCBUSHGCBERSK-UHFFFAOYSA-N perfluoropentane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F NJCBUSHGCBERSK-UHFFFAOYSA-N 0.000 description 1
- 229950001046 piroctone Drugs 0.000 description 1
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229940043810 zinc pyrithione Drugs 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、シャンプー、身体用洗浄剤及び軽質衣料用洗
浄剤等として好適に利用できる洗浄剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a detergent composition that can be suitably used as a shampoo, a body cleansing agent, a light laundry detergent, and the like.
〔従来の技術及び発明が解決しようとする課題〕シャン
プーのような洗浄剤においては、洗浄力という洗浄剤と
しての基本的な機能のほかに、洗髪中の指通り、なめら
かさ、すすぎ時の指通り、きしみのないこと、また乾燥
時においてはすべり、柔らかさ、まとまり、くし通り等
、いわゆるコンディショニング効果が良好であることが
望まれる場合が多い。[Prior art and problems to be solved by the invention] In addition to the basic function of detergents such as detergency, detergents such as shampoos have the ability to run smoothly and smoothly with the fingers during hair washing, and to improve the smoothness of the hair during rinsing. In many cases, it is desired that the material does not run or squeak, and that it has good conditioning effects such as slippage, softness, cohesiveness, and combability during drying.
良好なコンディショニング効果付与成分としては従来か
らカチオン性ポリマーが知られている。Cationic polymers have been known as components that provide good conditioning effects.
また近年、高分子シリコーンも有効なコンディショニン
グ効果付与成分として利用できることがわかってきた。Furthermore, in recent years, it has been found that polymeric silicones can also be used as effective conditioning effect-imparting ingredients.
例えば、特開昭61−210022号公報に記載のシャ
ンプー組成物には、陰イオン性界面活性剤とともに用い
る高分子シリコーンとして不溶性不揮発性シリコーン(
例えば、ジメチルポリシロキサン)が用いられており、
また、特開昭63−22010号公報に記載の整髪組成
物には硬質シリコーン重合体(例えば、ジメチルポリシ
ロキサン)が用いられている。For example, in the shampoo composition described in JP-A-61-210022, insoluble non-volatile silicone (
For example, dimethylpolysiloxane) is used,
Further, a hard silicone polymer (for example, dimethylpolysiloxane) is used in the hair styling composition described in JP-A-63-22010.
これらシリコーン誘導体を含有する洗浄剤組成物は、カ
チオン性ポリマー等を含有した従来の洗浄剤組成物と比
較し、乾燥後の指通り、くし通り等に関して優れてはい
るが、その効果は未だ満足できるものではなかった。更
にシリコーン誘導体とトリ長鎖アルキルモノ短鎖アルキ
ル第四級アンモニウム塩とを併用(特開昭62−773
11号)したもの及びシリコーン誘導体とカチオン性ポ
リマーとを併用(特開昭56−72095号)したもの
が開示されているが、これらの組成物も髪の指通り、く
し通り、柔らかさ等のコンディショニング効果に関して
、まだ充分満足できるものではなかった。Cleaning compositions containing these silicone derivatives are superior to conventional cleaning compositions containing cationic polymers and the like in terms of finger compatibility and combing after drying, but their effects are still unsatisfactory. It wasn't possible. Furthermore, silicone derivatives and tri-long-chain alkyl mono-short-chain alkyl quaternary ammonium salts are used in combination (JP-A-62-773).
No. 11) and a combination of a silicone derivative and a cationic polymer (Japanese Patent Application Laid-Open No. 72095/1989) have been disclosed, but these compositions also improve the hair's ability to run through fingers, comb through, and soften the hair. The conditioning effect was still not fully satisfactory.
一方、パーフルオロポリエーテル類は毛髪に潤滑性や柔
軟性を付与する作用を有し、シャンプー等に配合できる
ことが知られているCL、 Rigano。On the other hand, perfluoropolyethers have the effect of imparting lubricity and flexibility to hair, and are known to be able to be incorporated into shampoos and the like.
S、 5avonelli and P、L、Benc
ini、 InternationalJourna
l of (:osmetic 5cience 11
. 259−282(1989))。しかしながら、こ
のパーフルオロポリエーテル類のコンディショニング効
果は未だ充分ではなく、添加量によってはべたつき等が
生じるという問題もあった。S, 5avonelli and P, L, Benc.
ini, International Journal
l of (:osmetic 5science 11
.. 259-282 (1989)). However, the conditioning effect of these perfluoropolyethers is still not sufficient, and depending on the amount added, there is a problem that stickiness may occur.
従って、優れたコンディショニング効果を有する新たな
洗浄剤組成物の開発が望まれていた。Therefore, it has been desired to develop a new detergent composition that has excellent conditioning effects.
斯かる実情において、本発明者らは鋭意研究を行った結
果、陰イオン性界面活性剤、両性界面活性剤及び非イオ
ン性界面活性剤から選ばれる一種又は2種以上にシリコ
ーン誘導体及びフッ素系油剤を含有せしめれば、コンデ
ィショニング効果に優れた洗浄剤組成物が得られること
、及びこの洗浄剤組成物は身体洗浄剤及び軽質衣料用洗
浄剤としても好適に利用できることを見出し本発明を完
成した。Under these circumstances, the present inventors conducted extensive research and found that one or more selected from anionic surfactants, amphoteric surfactants, and nonionic surfactants contain silicone derivatives and fluorine-based oils. The present invention was completed based on the discovery that a detergent composition with excellent conditioning effects can be obtained by containing the following, and that this detergent composition can also be suitably used as a body cleansing agent and a light laundry detergent.
すなわち本発明は、次の成分(A)、(B)及び(C)
(A)陰イオン性界面活性剤、両性界面活性剤及び非イ
オン性界面活性剤から選ばれる一種又は二種以上の界面
活性剤
(B)シリコーン誘導体
(C)フッ素系油剤
を含有する洗浄剤組成物を提供するものである。That is, the present invention provides the following components (A), (B), and (C) (A) one or more types of interface selected from anionic surfactants, amphoteric surfactants, and nonionic surfactants; The present invention provides a cleaning composition containing an activator (B) a silicone derivative and (C) a fluorine-based oil.
本発明に用いられる洗浄用基剤たる(A)成分は、通常
シャンプー、身体洗浄剤又は軽質衣料用洗浄剤に用いら
れる陰イオン性界面活性剤、非イオン性界面活性剤、両
性界面活性剤であり、これらは単独又は2種以上を組合
せて使用してもよい。Component (A), which is the cleaning base used in the present invention, is an anionic surfactant, a nonionic surfactant, or an amphoteric surfactant that is usually used in shampoos, body cleansers, or light laundry detergents. These may be used alone or in combination of two or more.
これら界面活性剤の例としては、直鎖または分岐鎖アル
キルベンゼンスルホン酸塩、アルキルまたはアルケニル
硫酸塩、エチレンオキサイドおよび/またはプロピレン
オキサイドを付加したアルキルまたはアルケニルエーテ
ル硫酸塩、オレフィンスルホン酸塩、アルカンスルホン
酸塩、飽和または不飽和脂肪酸塩、エチレンオキサイド
および/またはプロピレンオキサイドを付加したアルキ
ルまたはアルケニルエーテルカルボン酸塩、α−スルホ
脂肪酸エステルまたはその塩、アミノ酸型界面活性剤、
リン酸エステル型界面活性剤、スルホコハク酸型界面活
性剤、タウリン型界面活性剤、アマイドエーテルサルフ
ェート型界面活性剤、スルホン酸型界面活性剤、ベタイ
ン型両性界面活性剤、アルキルアミンオキサイド、ポリ
オキシアルキルまたはアルケニルエーテル、ポリオキシ
アルキルフェニルエーテル、高級脂肪酸アルカノールア
ミドまたはアルキレンオキサイド付加物、多価アルコー
ルと脂肪酸のエステル、ソルビトールと脂肪酸のエステ
ル、ショ糖と脂肪酸のエステル、高級アルコールと糖の
エーテル等が挙げられる。Examples of these surfactants include linear or branched alkylbenzene sulfonates, alkyl or alkenyl sulfates, alkyl or alkenyl ether sulfates with ethylene oxide and/or propylene oxide, olefin sulfonates, alkanesulfonic acids. salts, saturated or unsaturated fatty acid salts, alkyl or alkenyl ether carboxylates with ethylene oxide and/or propylene oxide added, α-sulfo fatty acid esters or salts thereof, amino acid type surfactants,
Phosphate ester type surfactant, sulfosuccinic acid type surfactant, taurine type surfactant, amide ether sulfate type surfactant, sulfonic acid type surfactant, betaine type amphoteric surfactant, alkylamine oxide, polyoxyalkyl Alkenyl ethers, polyoxyalkylphenyl ethers, higher fatty acid alkanolamides or alkylene oxide adducts, esters of polyhydric alcohols and fatty acids, esters of sorbitol and fatty acids, esters of sucrose and fatty acids, ethers of higher alcohols and sugars, etc. It will be done.
好ましい界面活性剤としては、アルキル硫酸塩型界面活
性剤、アルキルエーテル硫酸塩型界面活性剤、オレフィ
ンスルホン酸塩型界面活性剤、すン酸エステル型界面活
性剤、アルキルエーテルカルボン酸塩型界面活性剤、ア
ミノ酸型界面活性剤、スルホコハク酸型界面活性剤、タ
ウリン型界面活性剤、スルホン酸型両性界面活性剤、ベ
タイン型両性界面活性剤、高級脂肪酸アルカノールアミ
ド、高級アルコールと糖のエーテル等が挙げられる。Preferred surfactants include alkyl sulfate type surfactants, alkyl ether sulfate type surfactants, olefin sulfonate type surfactants, sulfate type surfactants, and alkyl ether carboxylate type surfactants. Examples include amino acid type surfactants, sulfosuccinic acid type surfactants, taurine type surfactants, sulfonic acid type amphoteric surfactants, betaine type amphoteric surfactants, higher fatty acid alkanolamides, and ethers of higher alcohols and sugars. It will be done.
さらに特に好ましい界面活性剤としては、スルホコハク
酸型界面活性剤、スルホン酸型両性界面活性剤、ベタイ
ン型両性界面活性剤、高級脂肪酸ア 、ルカノールアミ
ド、リン酸エステル型界面活性剤、アミノ酸型界面活性
剤、高級アルコールと糖のエーテル等が挙げられる。Particularly preferred surfactants include sulfosuccinic acid type surfactants, sulfonic acid type amphoteric surfactants, betaine type amphoteric surfactants, higher fatty acids, lucanolamides, phosphate ester type surfactants, and amino acid type surfactants. Examples include ethers of higher alcohols and sugars.
上記の界面活性剤は、全組成物に対して5〜50重量%
(以下、単に%で示す)、10〜40重量%配合するの
が好ましい。The above surfactant is 5 to 50% by weight based on the total composition.
(hereinafter simply expressed as %), preferably 10 to 40% by weight.
(B)成分のシリコーン誘導体は、ポリシロキサン、ポ
リシロキサンに各種官能基が導入された変性シリコーン
、シリコーンレジン等が例示される。具体的には、例え
ば、ポリシロキサン誘導体としてはジメチルポリシロキ
サン、メチルフェニルポリシロキサン、環状シリコーン
等が挙げられ;変性シリコーンとしては、ポリエーテル
変性シリコーン、エポキシ変性シリコーン、フッ素変性
シリコーン、アルコール変性シリコーン、アルキル変性
シリコーン、アミノ変性シリコーン、カルボキシ変性シ
リコーン、脂肪酸変性シリコーン、アルコキシ変性シリ
コ〒ン、カルビノール変性シリコーン、メチルスチレン
変性シリコーン、糖度性シリコーン等が挙げられる。変
性シリコーンに導入された官能基の位置は制限されるも
のではなく、側鎖型、片末端型、両末端型及びこれらを
二種以上組合わされたものも含まれている。好ましくは
、ジメチルポリシロキサン、メチルフェニルポリシロキ
サン、ポリエーテル変性シリコーン、アミノ変性シリコ
ーン、アルコール変性シリコーン等である。Examples of the silicone derivative as component (B) include polysiloxane, modified silicone in which various functional groups are introduced into polysiloxane, and silicone resin. Specifically, for example, polysiloxane derivatives include dimethylpolysiloxane, methylphenylpolysiloxane, cyclic silicone, etc.; modified silicones include polyether-modified silicone, epoxy-modified silicone, fluorine-modified silicone, alcohol-modified silicone, Examples include alkyl-modified silicones, amino-modified silicones, carboxy-modified silicones, fatty acid-modified silicones, alkoxy-modified silicones, carbinol-modified silicones, methylstyrene-modified silicones, and sugar content silicones. The position of the functional group introduced into the modified silicone is not limited, and includes side chain type, single terminal type, double terminal type, and combinations of two or more of these types. Preferred are dimethylpolysiloxane, methylphenylpolysiloxane, polyether-modified silicone, amino-modified silicone, alcohol-modified silicone, and the like.
シリコーン誘導体は一種又は二種以上を組み合わせて用
いる事ができ、シリコーン誘導体の配合量は0.01〜
8%、特に0.1〜5%が好ましい。Silicone derivatives can be used alone or in combination of two or more, and the blending amount of silicone derivatives is from 0.01 to
8%, especially 0.1-5% is preferred.
0.01%未満であるとコンディショニング効果が低く
、8%を超えると泡立ちが低下し、乾燥後べたつく等の
問題点が認められ好ましくない。If it is less than 0.01%, the conditioning effect will be low, and if it exceeds 8%, problems such as poor foaming and stickiness after drying will be observed, which is not preferable.
(C)成分として用いられるフッ素系油剤としては、常
温で液状のフッ素原子を含有した有機化合物であり、例
えばパーフルオロデカリン、パーフルオロアダマンタン
、パーフルオロブチルテトラハイドロフラン、パーフル
オロオクタン、パーフルオロノナン、パーフルオロペン
タン、パーフルオロデカン、パーフルオロドデカン、パ
ーフルオロポリエーテル等が挙げられ、特に次の一般式
〔式中、R’、 R3、R4及びR5は同一でも異なっ
てもよく、それぞれフッ素原子、パーフルオロアルキル
基又はパーフルオロアルキルオキシ基を R2はフッ素
原子又はパーフルオロアルキル基を、plq及びrは分
子量が500〜100.000となる0以上の数を示す
。ただし、p=q=r=oとなることはない。〕
で表されるパーフルオロポリエーテルが好ましい。The fluorine-based oil used as component (C) is an organic compound containing a fluorine atom that is liquid at room temperature, such as perfluorodecalin, perfluoroadamantane, perfluorobutyltetrahydrofuran, perfluorooctane, and perfluorononane. , perfluoropentane, perfluorodecane, perfluorododecane, perfluoropolyether, etc. In particular, the following general formula [wherein R', R3, R4 and R5 may be the same or different, and each is a fluorine atom] , a perfluoroalkyl group or a perfluoroalkyloxy group, R2 represents a fluorine atom or a perfluoroalkyl group, and plq and r represent a number of 0 or more such that the molecular weight is 500 to 100.000. However, p=q=r=o is never satisfied. ] A perfluoropolyether represented by these is preferred.
なお、ここでカッコ内に示される各パーフルオロ基はこ
の順で並んでいる必要はなく、またランダム重合でもブ
ロック重合でもかまわない。かかるパーフルオロポリエ
ーテルとしては、特に粘度が5〜5.000cStの液
体状のものが好ましく、例えば次の一般式(n)
CF3
CF、ロー(CFCF、0)−−(CF、0)y−CF
、 [: If ](式中、X及びy
は分子量が500〜10.000となる数を示し、x/
yは0.2〜2である。)’を表t)CtL6 FOM
BLIN HClO4(平均分子量1.500)、同H
C/25 (同3.200)及び同)IC/R(同6.
600) (以上モンテフルオス社製)や、次の一般式
(III)F(ChCPiChOh−ChCh
(III)(式中、2は4〜500の数を示す。)
で表わされるデムナムS−20(重量平均分子量25.
000> 、同S−65(同4.500)、同S−10
0(同5.600)及び同S−200(同8,400>
(、以上ダイキン工業社製)などの市販品を使用する
ことができる。Note that the perfluoro groups shown in parentheses do not need to be arranged in this order, and random polymerization or block polymerization may be used. Such perfluoropolyethers are preferably liquid ones with a viscosity of 5 to 5.000 cSt, for example, those represented by the following general formula (n) CF3 CF, rho (CFCF, 0) -- (CF, 0) y -- C.F.
, [: If] (where X and y
represents the number that makes the molecular weight 500 to 10.000, and x/
y is 0.2-2. )' t)CtL6 FOM
BLIN HClO4 (average molecular weight 1.500), same H
C/25 (3.200) and IC/R (6.200)
600) (manufactured by Montefluos), and the following general formula (III) F (ChCPiChOh-ChCh
(III) (In the formula, 2 represents a number from 4 to 500.)
Demnum S-20 (weight average molecular weight 25.
000>, S-65 (4.500), S-10
0 (5.600) and S-200 (8,400)
(manufactured by Daikin Industries, Ltd.) and other commercially available products can be used.
フッ素系油剤は一種又は二種以上組み合わせて用いる事
ができ、これらフッ素系油剤は全組成物中に0.01〜
5%、特に0.1〜1%配合されるのが好ましい。0.
01%未満であると、コンディショニング効果が低く、
5%を超えると、泡立ちを低下させたり、乾燥後べたつ
くなどの欠点が見られ、好ましくない。Fluorine-based oils can be used alone or in combination of two or more, and these fluorine-based oils may be present in the total composition in an amount of 0.01 to
It is preferably blended in an amount of 5%, particularly 0.1 to 1%. 0.
If it is less than 0.01%, the conditioning effect is low;
If it exceeds 5%, disadvantages such as decreased foaming and stickiness after drying are observed, which is not preferable.
本発明に用いられるフッ素系油剤は、水に対して不溶性
であり、炭化水素系油剤と比較し、比重も大きい。その
為、フッ素系油剤を含む洗浄剤は、その形態に応じて、
これを分散安定化させる技術が必要とされる場合がある
。この分散には、一般に使用されるアニオン性ポリマー
、非イオン性ポリマー、カチオン性ポリマー等の増粘剤
が有効である。例えば、アニオン性ポリマーとしては、
牛サンタンガム、カルボキシビニルポリマー、カルボキ
シメチルセルロース等が挙げられ、非イオン性ポリマー
としてはメチルでルロース、ヒドロキシエチルセルロー
ス、ヒドロキシプロピルセルロースが挙げられ、カチオ
ン化ポリマーとしてはカチオン化グアーガムなど挙げら
れるが、好ましくはキサンタンガム、カルボキシビニル
ポリマーである。The fluorine-based oil used in the present invention is insoluble in water and has a higher specific gravity than hydrocarbon-based oils. Therefore, depending on the form of cleaning agents containing fluorine-based oils,
A technique to stabilize this dispersion may be required. Generally used thickeners such as anionic polymers, nonionic polymers, and cationic polymers are effective for this dispersion. For example, as an anionic polymer,
Examples of the nonionic polymers include bovine suntan gum, carboxyvinyl polymer, carboxymethyl cellulose, etc. Examples of the nonionic polymer include methyl luulose, hydroxyethyl cellulose, and hydroxypropyl cellulose. Examples of the cationized polymer include cationized guar gum, but xanthan gum is preferable. , a carboxyvinyl polymer.
これら増粘剤は、全組成物中に0.05〜5%、特に0
,1〜2%配合されるのが好ましい。0.05%未満で
あると安定化効果が充分でなく、5%を超えるとコンデ
ィショニング効果に悪影響を及ぼすなどの欠点が生じ好
ましくない。These thickeners may be added in an amount of 0.05 to 5% in the total composition, especially 0.
, 1 to 2% is preferred. If it is less than 0.05%, the stabilizing effect will not be sufficient, and if it exceeds 5%, there will be disadvantages such as an adverse effect on the conditioning effect, which is not preferable.
また、本発明に係る洗浄剤が均一な液相系でない場合、
例えば、噴射剤と混合しエアゾールタイプとして使用す
る場合、使用時に振とうして使用する場合等においては
、これら増粘剤を必ずしも必要としない。Furthermore, if the cleaning agent according to the present invention is not a uniform liquid phase system,
For example, when mixed with a propellant and used as an aerosol type, or when shaken before use, these thickeners are not necessarily required.
更に、本発明の洗浄剤組成物は、本発明の効果を損なわ
ない範囲で洗浄剤組成物に通常用いられる成分、例えば
アルキルアミンオキサイド、脂肪酸アルカノールアミド
等の増泡剤、スクワレン、ラノリン、カチオン性界面活
性剤等の感触向上剤;プロピレングリコール、グリセリ
ン、ジエチレングリコールモノエチルエーテル、ソルビ
トール等の保湿剤;ポリオキシエチレングリコールジス
テアレート、エタノール等の粘度調整剤;パール化剤、
香料、色素、紫外線吸収剤、酸化防止剤、トリクロサン
、トリクロロカルパン等の殺菌剤;グリチルリチン酸カ
リウム、酢酸トコフェロール等の抗炎症剤;ジンクピリ
チオン、オクトピロックス等の抗フケ剤;メチルパラベ
ン、ブチルパラベン等の防腐剤、その他、エンサイクロ
ペディア・オブ・シャンプー・インダレディエンッ[B
NCYCLOPBDIA OF SHAMPOOI
NGRBOIBNTS(MICBLLB PRBSS、
1985年)〕に記載されている成分等を所望により
、添加する事ができる。Furthermore, the cleaning composition of the present invention may contain ingredients commonly used in cleaning compositions, such as foam enhancers such as alkylamine oxides and fatty acid alkanolamides, squalene, lanolin, and cationic components, to the extent that the effects of the present invention are not impaired. Feel improvers such as surfactants; humectants such as propylene glycol, glycerin, diethylene glycol monoethyl ether, and sorbitol; viscosity modifiers such as polyoxyethylene glycol distearate and ethanol; pearling agents,
Fragrances, pigments, ultraviolet absorbers, antioxidants, disinfectants such as triclosan and trichlorocarpan; anti-inflammatory agents such as potassium glycyrrhizinate and tocopherol acetate; anti-dandruff agents such as zinc pyrithione and octopirox; methylparaben, butylparaben, etc. Preservatives, etc., Encyclopedia of Shampoo Indalien [B
NCYCLOPBDIA OF SHAMPOOI
NGRBOIBNTS(MICBLLB PRBSS,
1985)] may be added as desired.
本発明の洗浄剤組成物は、乾燥後の髪の滑り、くし通り
、柔かさ等のコンディショニング効果に優れるものであ
り、シャンプーに好適に利用できる。さらに身体に応用
した場合、肌がべたつかず、サラットした感触が得られ
、ボディシャンプーや洗顔料等の身体洗浄剤として有用
である。また、軽質衣料用洗浄剤としても有用である。The detergent composition of the present invention has excellent conditioning effects such as smoothness, combability, and softness of hair after drying, and can be suitably used in shampoos. Furthermore, when applied to the body, the skin does not feel sticky and has a smooth feel, making it useful as a body cleansing agent such as body shampoo or facial cleanser. It is also useful as a light laundry detergent.
次に、実施例を挙げて本発明を説明する。 Next, the present invention will be explained by giving examples.
実施例1
第1表に示す組成のシャンプー組成物を常法に従って調
製し、それぞれ乾燥後の髪の感触を下記方法により評価
した。結果を第1表に示す。Example 1 Shampoo compositions having the compositions shown in Table 1 were prepared according to a conventional method, and the feel of each shampoo after drying was evaluated by the following method. The results are shown in Table 1.
く評価方法〉
健常な日本人女性の毛髪20g(15cm)にシャンプ
ー1gを塗布し、1分間泡立て、すすいだ後、ドライヤ
ーで乾燥させ、髪のくし通り、柔かさについて専門パネ
ラ−15名により下記の基準で評価した。Evaluation method: Apply 1 g of shampoo to 20 g (15 cm) of hair of a healthy Japanese woman, lather for 1 minute, rinse, dry with a hair dryer, and evaluate the combability and softness of the hair as described below by a panel of 15 experts. It was evaluated based on the following criteria.
乾燥後のくし通り
A:くし通りが良くなめらか
B:くしを通す際、多少ひっかかる
C:毛先等のくし通り悪くひっかかる
A:柔らかい
B:多少、柔らかい
C:はとんど柔かさを感じない
以下余白
第1表から明らかなように、本発明のシャンプー組成物
は、乾燥後のくし通り性、柔さに優れたものである。After drying, A: Easy to comb and smooth B: Slightly gets caught when combing C: Difficult to comb through the tips of the hair, etc. A: Soft B: Somewhat soft C: Doesn't feel soft at all As is clear from Table 1 below, the shampoo composition of the present invention has excellent combability and softness after drying.
実施例2〜5
次に示す組成のシャンプー組成物は、いずれも乾燥後の
感触が良好で、コンディショニング効果に優れたもので
ある。Examples 2 to 5 Shampoo compositions having the compositions shown below all had a good feel after drying and had excellent conditioning effects.
(実施例2) (%)ポ
リオキシエチレンラウリルエーテル 8硫酸トリエタ
ノールアミン(3B、D、”)デシルポリグルコシド
8(糖の重合度= 1.2)
ラウリン酸ジェタノールアミド 4ジメチルポ
リシロキサン 2(粘度400万cSt
と100cStの4:6混合物)パーフルオロポリエー
テル 0.4(FOMBLIN HClO
4:モンテフルオス社)キサンタンガム
1(エコーガム二人日本製薬味)
エチレングリコールジステアレート1.5防腐剤
0.1
香料、色素、pH1Ji整剤 (適量)
水 バランス合計
100.0
(実施例3) (%)ラウ
リル硫酸トリエタノールアミン 4ラウリン酸ジエ
タノールアミド 5防腐剤 0.
1
香料、色素、pH調整剤 (適量)水
−バランス
合計 100.0
(実施例4)
(%)
キシプロピルスルホヘゲ1ノ
ラウリン酸モノエタノールアミド 4防腐剤
0.1
香料、色素、pH調整剤 (適量)水
バランス合計
100.0
(実施例5)
(%)
ジメチルポリシロキサン l(粘度40
0万cStと100cStの4:6混合物)パーフルオ
ロデカリン 0.5(アルドリッチ社
)
防腐剤 0.1
香料、色素、pH調整剤 (適量)水
バランス合計
100.0
実施例6
次に示す組成の身体洗浄剤組成物は、乾燥後の肌がさら
つとする等の感触に優れるものである。(Example 2) (%) Polyoxyethylene lauryl ether 8 sulfate triethanolamine (3B, D, “) decyl polyglucoside
8 (degree of polymerization of sugar = 1.2) Lauric acid jetanolamide 4 Dimethyl polysiloxane 2 (viscosity 4 million cSt
and 100 cSt) perfluoropolyether 0.4 (FOMBLIN HClO
4: Montefluos) xanthan gum
1 (Echo Gum Futari Nippon Pharmaceutical Flavor) Ethylene Glycol Distearate 1.5 Preservative
0.1 Fragrance, pigment, pH1Ji adjuster (appropriate amount)
Water Balance total 100.0 (Example 3) (%) Lauryl sulfate triethanolamine 4 Lauric acid diethanolamide 5 Preservative 0.
1 Fragrance, pigment, pH adjuster (appropriate amount) water
-Balance total 100.0 (Example 4) (%) Xypropylsulfohage 1 Norauric acid monoethanolamide 4 Preservative
0.1 Fragrance, pigment, pH adjuster (appropriate amount) Water
balance total
100.0 (Example 5) (%) Dimethylpolysiloxane l (viscosity 40
(4:6 mixture of 00,000 cSt and 100 cSt) Perfluorodecalin 0.5 (Aldrich) Preservative 0.1 Fragrance, pigment, pH adjuster (appropriate amount) Water
balance total
100.0 Example 6 A body cleansing composition having the composition shown below has an excellent feel, such as leaving the skin smooth after drying.
(%)
ラウリルリン酸トリエタノールアミン 18ラウリン酸
トリエタノールアミン 2ラウリン酸ジエタノー
ルアミド 2防腐剤 0.1
香料、色素、pHWl整剤 (適量)水
バランス合計
100.0
試験例1
実施例30組成物を30℃の恒温槽にて20日間保存し
、沈殿の有無を観察した。(%) Triethanolamine lauryl phosphate 18 Triethanolamine laurate 2 Diethanolamide laurate 2 Preservatives 0.1 Fragrance, pigment, pHWl adjuster (appropriate amount) Water Balance total
100.0 Test Example 1 The composition of Example 30 was stored in a constant temperature bath at 30° C. for 20 days, and the presence or absence of precipitation was observed.
その結果、沈殿は見られずフッ素系油剤が安定に分散さ
れていることが確認できた。As a result, no precipitate was observed, and it was confirmed that the fluorine-based oil was stably dispersed.
以上that's all
Claims (1)
オン性界面活性剤から選ばれる一種又は二種以上の界面
活性剤 (B)シリコーン誘導体 (C)フッ素系油剤 を含有する洗浄剤組成物。 2、(C)成分のフッ素系油剤が次の一般式( I ) ▲数式、化学式、表等があります▼〔 I 〕 〔式中、R^1、R^3、R^4及びR^5は同一でも
異なってもよく、それぞれフッ素原子、パーフルオロア
ルキル基又はパーフルオロアルキルオキシ基を、R^2
はフッ素原子又はパーフルオロアルキル基を、p、q及
びrは分子量が500〜100,000となる0以上の
数を示す。ただし、p=q=r=0となることはない。 〕 で表されるパーフルオロポリエーテルである請求項1記
載の洗浄剤組成物。[Claims] 1. One or two components selected from the following components (A), (B), and (C) (A) anionic surfactants, amphoteric surfactants, and nonionic surfactants. A cleaning composition containing the above surfactant (B) a silicone derivative and (C) a fluorine-based oil. 2. The fluorine-based oil agent (C) has the following general formula (I) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [I] [In the formula, R^1, R^3, R^4 and R^5 may be the same or different, and each represents a fluorine atom, a perfluoroalkyl group, or a perfluoroalkyloxy group, and R^2
represents a fluorine atom or a perfluoroalkyl group, and p, q and r represent a number of 0 or more such that the molecular weight is 500 to 100,000. However, p=q=r=0 is never satisfied. ] The cleaning composition according to claim 1, which is a perfluoropolyether represented by:
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP28770990A JPH04164015A (en) | 1990-10-25 | 1990-10-25 | Cleaning agent composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP28770990A JPH04164015A (en) | 1990-10-25 | 1990-10-25 | Cleaning agent composition |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH04164015A true JPH04164015A (en) | 1992-06-09 |
Family
ID=17720728
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP28770990A Pending JPH04164015A (en) | 1990-10-25 | 1990-10-25 | Cleaning agent composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH04164015A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005307020A (en) * | 2004-04-22 | 2005-11-04 | Asahi Kasei Chemicals Corp | Detergent composition |
JP2006503974A (en) * | 2002-11-04 | 2006-02-02 | ザ プロクター アンド ギャンブル カンパニー | Liquid laundry detergent |
CN102086430A (en) * | 2011-02-09 | 2011-06-08 | 白玉清 | Cleaning agent for airplane runways |
WO2011136389A2 (en) | 2010-04-28 | 2011-11-03 | Dow Corning Toray Co., Ltd. | Cosmetic and topical skin preparation comprising higher alcohol-modified silicone |
-
1990
- 1990-10-25 JP JP28770990A patent/JPH04164015A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006503974A (en) * | 2002-11-04 | 2006-02-02 | ザ プロクター アンド ギャンブル カンパニー | Liquid laundry detergent |
JP2005307020A (en) * | 2004-04-22 | 2005-11-04 | Asahi Kasei Chemicals Corp | Detergent composition |
WO2011136389A2 (en) | 2010-04-28 | 2011-11-03 | Dow Corning Toray Co., Ltd. | Cosmetic and topical skin preparation comprising higher alcohol-modified silicone |
US9283164B2 (en) | 2010-04-28 | 2016-03-15 | Dow Corning Toray Co., Ltd. | Cosmetic and topical skin preparation comprising higher alcohol-modified silicone |
CN102086430A (en) * | 2011-02-09 | 2011-06-08 | 白玉清 | Cleaning agent for airplane runways |
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