JPH0414758A - Lead-acid accumulator - Google Patents
Lead-acid accumulatorInfo
- Publication number
- JPH0414758A JPH0414758A JP2116225A JP11622590A JPH0414758A JP H0414758 A JPH0414758 A JP H0414758A JP 2116225 A JP2116225 A JP 2116225A JP 11622590 A JP11622590 A JP 11622590A JP H0414758 A JPH0414758 A JP H0414758A
- Authority
- JP
- Japan
- Prior art keywords
- tin
- lead
- added
- active material
- positive electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002253 acid Substances 0.000 title claims description 17
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000007774 positive electrode material Substances 0.000 claims abstract description 13
- FAKFSJNVVCGEEI-UHFFFAOYSA-J tin(4+);disulfate Chemical compound [Sn+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O FAKFSJNVVCGEEI-UHFFFAOYSA-J 0.000 claims abstract description 12
- 150000003606 tin compounds Chemical class 0.000 claims abstract description 8
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910001887 tin oxide Inorganic materials 0.000 claims abstract description 6
- 239000011149 active material Substances 0.000 abstract description 17
- 238000006243 chemical reaction Methods 0.000 abstract description 12
- 238000007600 charging Methods 0.000 abstract description 7
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 abstract description 7
- 230000015572 biosynthetic process Effects 0.000 abstract description 4
- 238000007599 discharging Methods 0.000 abstract description 4
- 239000007772 electrode material Substances 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 14
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 5
- 238000001035 drying Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 239000002142 lead-calcium alloy Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000010277 constant-current charging Methods 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- KEQXNNJHMWSZHK-UHFFFAOYSA-L 1,3,2,4$l^{2}-dioxathiaplumbetane 2,2-dioxide Chemical compound [Pb+2].[O-]S([O-])(=O)=O KEQXNNJHMWSZHK-UHFFFAOYSA-L 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910052924 anglesite Inorganic materials 0.000 description 1
- 239000006182 cathode active material Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000005211 surface analysis Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、鉛蓄電池の正極活物質の利用率の向上に関す
るものである。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to improving the utilization rate of positive electrode active materials in lead-acid batteries.
従来の技術
鉛蓄電池は二次電池として比較的安価で安定な性能を有
し、電子機器の電源や電動車の電源に広く用いられてい
る。しかし、他の蓄電池系と比較して、エネルギー密度
（Ｗｈ／ｋｇ）が劣るという欠点がある。これは活物質
、特に正極活物質の利用率が約４０％〜５０％と悪いた
めであり、活物質の利用率を向上することが望まれる。BACKGROUND OF THE INVENTION Lead-acid batteries are relatively inexpensive and have stable performance as secondary batteries, and are widely used as power sources for electronic devices and electric vehicles. However, it has a drawback of being inferior in energy density (Wh/kg) compared to other storage battery systems. This is because the utilization rate of the active material, particularly the positive electrode active material, is poor at about 40% to 50%, and it is desired to improve the utilization rate of the active material.
鉛蓄電池の正極および、負極の活物質は、原料となる鉛
粉をそれぞれの添加物と共に、希硫酸またはその他の練
液と混合し、撹拌しながらペーストを作り、このペース
トを格子中に充填し、所定の乾燥、化成の工程を経て作
製される。The active materials for the positive and negative electrodes of lead-acid batteries are made by mixing the raw material lead powder with dilute sulfuric acid or other additives, stirring to form a paste, and filling this paste into a lattice. , and is produced through predetermined drying and chemical conversion steps.
正極活物質は二酸化鉛、負極活物質は鉛であり、放電、
充電の反応は、下記の反応式で示すように起こる。The positive electrode active material is lead dioxide, and the negative electrode active material is lead.
The charging reaction occurs as shown in the reaction formula below.
放電
ＰｂＯ２＋２Ｈ２０＋Ｐｂ ご ＰｂＳＯ４＋
２１１２０ ＋ Ｐｂ５Ｏ４（正極） （負極）
充電（正極） （負極）放電反応が進行すると、
硫酸鉛の結晶が成長し、極板の表面を覆うようになる。Discharge PbO2+2H20+Pb PbSO4+
21120 + Pb5O4 (positive electrode) (negative electrode)
Charging (positive electrode) (negative electrode) As the discharge reaction progresses,
Crystals of lead sulfate grow and begin to cover the surface of the electrode plates.
硫酸鉛は、鉛や二酸化鉛よりも電導度が小さいので、放
電反応の進行と共に極板の電気抵抗が増大し、電圧の降
下が起こり、放電の終了となる。このとき、極板内部に
は、未反応の活物質が残存しているため、極板全体の活
物質の利用率が低（なる。このことが鉛蓄電池のエネル
ギー密度（Ｗｈ／ｋｇ）を低下させる原因の一つである
と考えられる。Since lead sulfate has a lower conductivity than lead or lead dioxide, as the discharge reaction progresses, the electrical resistance of the electrode plates increases, causing a voltage drop and ending the discharge. At this time, unreacted active material remains inside the electrode plate, resulting in a low utilization rate of the active material of the entire electrode plate.This reduces the energy density (Wh/kg) of the lead-acid battery. This is thought to be one of the reasons for this.
発明が解決しようとする課題
上記のように鉛蓄電池では、放電反応生成物の硫酸鉛が
、正、負極板を覆い、内部に放電反応に関与できない活
物質が存在するという理由から、エネルギー密度（Ｗｈ
／ｋｇ）が低いという欠点を生じていた。Problems to be Solved by the Invention As mentioned above, in lead-acid batteries, the discharge reaction product lead sulfate covers the positive and negative electrode plates, and the energy density ( Wh
/kg).
本発明は上記の課題を解決するもので、正極活物質の利
用率を向上させ、エネルギー密度（Ｗｈ／ｋｇ）を向上
させた鉛蓄電池を提供することを目的とするものである
。The present invention solves the above-mentioned problems, and aims to provide a lead-acid battery with improved utilization of a positive electrode active material and improved energy density (Wh/kg).
課題を解決するための手段
上記の課題を解決するため本発明の鉛蓄電池は、金属錫
、もしくは錫化合物を正極活物質間に添加した極板を用
いたものである。Means for Solving the Problems In order to solve the above problems, the lead-acid battery of the present invention uses an electrode plate in which metallic tin or a tin compound is added between positive electrode active materials.
作用
上記の構成のように、正極活物質間に金属錫、もしくは
錫化合物を添加すると、化成中あるいは充電中にこれが
酸化され、導電性が高（、反応に関与しない酸化錫が活
物質問に生成する。このため放電により電導度が小さい
硫酸鉛が生成されても活物質の電導性が保たれ、極板内
部まで反応が起こり、活物質の利用率が高められる。す
なわち、電池のエネルギー密度（Ｗｈ／ｋｇ）が向上す
ることになる。Effect When metal tin or a tin compound is added between the cathode active materials as in the above configuration, it will be oxidized during formation or charging, and the conductivity will be high. Therefore, even if lead sulfate, which has low conductivity, is generated due to discharge, the conductivity of the active material is maintained, reactions occur inside the electrode plates, and the utilization rate of the active material is increased.In other words, the energy density of the battery is increased. (Wh/kg) will be improved.
実施例 本発明の実施例を図面を参照しながら説明する。Example Embodiments of the present invention will be described with reference to the drawings.
実施例１
鉛粉１０００ｇに、鉛粉中の鉛のモル数に対して錫のモ
ル数が１％となるように硫酸錫を添加し撹拌した。これ
に、２００ｇの水を加えて練った。さらに、６０ｇの５
０％硫酸を徐々に滴下しつつ加えて練合した。これによ
って得られたペーストをペーストＡとする。ペーストＡ
を鉛−カルシウム系合金の鋳造格子に充填し、乾燥、化
成の工程を経て本発明による正極板Ａを得た。Example 1 Tin sulfate was added to 1000 g of lead powder so that the number of moles of tin was 1% with respect to the number of moles of lead in the lead powder, and the mixture was stirred. To this, 200 g of water was added and kneaded. In addition, 60g of 5
0% sulfuric acid was gradually added dropwise and kneaded. The paste obtained in this way is referred to as paste A. Paste A
A positive electrode plate A according to the present invention was obtained by filling a cast grid of a lead-calcium alloy and undergoing drying and chemical conversion steps.
同様に従来のペーストとして、鉛粉１０００ｇに、２０
０ｇの水を加えて練った。これに、６０ｇの５０％硫酸
を徐々に滴下しつつ加えて練合した。これによって得ら
れたペーストをペーストＨとする。ペーストＨを鉛−カ
ルシウム系合金の鋳造格子に充填し、乾燥、化成の工程
を経て従来の正極板Ｈを得た。この正極板Ｈと負極板を
２枚７３枚で配設し、その間にガラス繊維からなるマッ
ト状セパレータを介在させて組合せ、電解液として希硫
酸を含浸させ２Ａｈ （１０時間率）の従来の密閉型鉛
蓄電池Ｈを得た。Similarly, as a conventional paste, 20 g of lead powder is added to 1000 g of lead powder.
0 g of water was added and kneaded. To this, 60 g of 50% sulfuric acid was gradually added dropwise and kneaded. The paste thus obtained is referred to as paste H. A conventional positive electrode plate H was obtained by filling paste H into a cast grid made of a lead-calcium alloy and performing drying and chemical conversion steps. The positive electrode plate H and the negative electrode plate are arranged in two pieces (73 pieces), combined with a mat-like separator made of glass fiber interposed between them, impregnated with dilute sulfuric acid as an electrolytic solution, and sealed at 2Ah (10 hour rate). A type lead acid battery H was obtained.
正極板Ａも負極板と２枚７３枚で配設し、その間にガラ
ス繊維からなるマット状セパレータを介在させて組合せ
、電解液として希硫酸を含浸させ、従来の密閉型鉛蓄電
池Ｈと同体積、同重量である本発明の密閉型鉛蓄電池Ａ
を得た。これらの電池ＡおよびＨについて充電２００
ｍ Ａ 、放電６００ｍＡの定電流充放電でサイクル試
験を行った。なお放電の終止電圧は１．７５Ｖに設定し
、充電電気量は放電電気量の１２０％とした。The positive electrode plate A and the negative electrode plate are arranged in two pieces (73 pieces), and are combined with a mat-like separator made of glass fiber interposed between them, and are impregnated with dilute sulfuric acid as an electrolyte, so that the volume is the same as that of a conventional sealed lead-acid battery H. , the sealed lead-acid battery A of the present invention having the same weight as
I got it. Charge 200 for these batteries A and H
A cycle test was conducted with constant current charging and discharging at mA and discharge of 600 mA. Note that the final voltage of discharge was set to 1.75 V, and the amount of charged electricity was 120% of the amount of discharged electricity.
第１図に放電容量の比較図を示す。従来電池Ｈの容量が
１８５０ｍＡｈであるのに対して、本発明電池Ａは２０
００ｍＡｈであり、８．１％の増加となった。放電終了
後、これらの電池ＡおよびＨの極板を取り出して、イオ
ウＳの分布をＸ線マイクロアナライザーを用いて面分析
を行い確認した。この結果、電池Ａでは電池Ｈの場合と
比べて極板の内部までイオウＳが広く分布していた。こ
のことから正極活物質間に添加した硫酸錫は化成あるい
は充電中に、導電性が高（、放電反応に関与しない酸化
錫に酸化される。そのため、放電時に導電性の低い硫酸
鉛が極板中に生成されても、高抵抗化による電圧降下が
抑制されるので、極板の内部まで放電に関与でき、活物
質の利用率が向上したことが確認された。Figure 1 shows a comparison diagram of discharge capacity. While the conventional battery H has a capacity of 1850mAh, the battery A of the present invention has a capacity of 20mAh.
00mAh, an increase of 8.1%. After the discharge was completed, the electrode plates of Batteries A and H were taken out, and the distribution of sulfur S was confirmed by surface analysis using an X-ray microanalyzer. As a result, in Battery A, sulfur S was more widely distributed inside the electrode plate than in Battery H. Therefore, during formation or charging, tin sulfate added between the positive electrode active materials has high conductivity (and is oxidized to tin oxide, which does not participate in the discharge reaction. Therefore, during discharge, the lead sulfate with low conductivity is It was confirmed that even if the active material is generated inside the electrode, the voltage drop due to the increase in resistance is suppressed, allowing the inside of the electrode plate to participate in the discharge and improving the utilization rate of the active material.
第２図にサイクル試験の寿命カーブを示した。Figure 2 shows the life curve of the cycle test.
容量が１００１００Ｏを切ったところをサイクル寿命と
した。活物質の利用率が大きくなったにも係わらず、本
発明による電池Ａも従来電池Ｈも３５０サイクルとほと
んど同じサイクル数であった。The cycle life was defined as the point where the capacity was less than 100,100O. Although the utilization rate of the active material was increased, both the battery A according to the present invention and the conventional battery H had almost the same number of cycles, 350 cycles.
実施例２ 硫酸錫の添加量を変えてその特性の比較を行った。Example 2 The properties were compared by changing the amount of tin sulfate added.
錫粉１０００ｇに、鉛粉中の鉛のモル数に対して錫のモ
ル数が第１表に前記のＡとともに示す各各の割合となる
ように硫酸錫を添加し撹拌した。Tin sulfate was added to 1000 g of tin powder and stirred so that the number of moles of tin was in the ratio shown in Table 1 along with A above with respect to the number of moles of lead in the lead powder.
これに、２００ｇの水を加え練った。さらに、６０ｇの
５０％硫酸を徐々に滴下しつつ加え練合した。To this, 200 g of water was added and kneaded. Furthermore, 60 g of 50% sulfuric acid was gradually added dropwise and kneaded.
これによって得られたペーストをペーストＢ〜Ｇとする
。ペーストＢ〜Ｇを鉛−カルシウム系合金の鋳造格子に
充填し、乾燥、化成の工程を経て本発明による正極板Ｂ
−Ｇを得た。これらの正極板Ｂ〜Ｇを負極板と２枚／３
枚で配殺し、その間にガラス繊維からなるマット状セパ
レータを介在させて組合せ、電解液として希硫酸を含浸
させて従来の密閉型鉛蓄電池Ｈと同体積、同重量である
本発明の密閉型鉛蓄電池Ｂ−Ｇを得た。これらの電池Ｂ
−Ｇについて充電２００ ｍ Ａ 、放電６００ｍＡの
定電流充放電でサイクル試験を行った。なお放電の終止
電圧は１．７５Ｖｉ：１ｍ設定し、充電電気量は放電容
量の１２０％とした。The pastes obtained in this way are referred to as pastes B to G. The pastes B to G are filled into a cast grid made of lead-calcium alloy, and the positive electrode plate B according to the present invention is produced through a drying and chemical formation process.
-G was obtained. These positive electrode plates B to G are 2/3 with the negative electrode plate.
The sealed lead-acid battery of the present invention has the same volume and weight as the conventional sealed lead-acid battery H, which is assembled by interposing a mat-like separator made of glass fiber between them, and impregnated with dilute sulfuric acid as an electrolyte. Storage batteries BG were obtained. These batteries B
-G was subjected to a cycle test with constant current charging and discharging at 200 mA for charging and 600 mA for discharging. Note that the final discharge voltage was set to 1.75 Vi: 1 m, and the amount of charging electricity was 120% of the discharge capacity.
第１表
硫酸錫の添加量に対する放電容量を第３図に示した。硫
酸錫の添加量が増加するに従い、放電容量も増加する。Table 1 shows the discharge capacity versus the amount of tin sulfate added. As the amount of tin sulfate added increases, the discharge capacity also increases.
しかし添加量０．００１％では従来電池Ｈの容量と差は
なかった。However, when the amount added was 0.001%, there was no difference in capacity from the conventional battery H.
第４図に硫酸錫の添加量とサイクル寿命の関係を示した
。添加量５％まで従来の電池Ｈとの差は見られないが、
添加量が７％になるとサイクル寿命は３３０サイクルと
なり、従来電池Ｈよりも寿命が短くなった。Figure 4 shows the relationship between the amount of tin sulfate added and the cycle life. Although there is no difference from conventional Battery H up to an additive amount of 5%,
When the amount added was 7%, the cycle life was 330 cycles, which was shorter than the conventional battery H.
これらの結果より硫酸錫の添加量が多くなるに従って容
量は増加する傾向を示すが、添加する硫酸錫の量が５％
を越えると寿命が短くなってしまう。このため、容量と
サイクル寿命の両面から見ると、添加する錫の量は０．
０１％〜５％の範囲にせねばならない。These results show that the capacity tends to increase as the amount of tin sulfate added increases, but when the amount of tin sulfate added is 5%
Exceeding this will shorten the lifespan. Therefore, from the standpoint of both capacity and cycle life, the amount of tin added is 0.
It must be in the range of 0.01% to 5%.
なお、上記２つの実施例においては、添加物として硫酸
錫を用いたが、金属錫、酸化錫でも同様の効果が見られ
た。ただし、添加量した銅元素のモル数が正極活物質中
の鉛のモル数に対して０．０１％〜５％でなくてはなら
ない。In the above two examples, tin sulfate was used as the additive, but similar effects were observed with metallic tin and tin oxide. However, the number of moles of the copper element added must be 0.01% to 5% with respect to the number of moles of lead in the positive electrode active material.
発明の効果
以上のように本発明の正極活物質間に金属錫、もしくは
錫化合物を添加すると、導電性の良い酸化錫が活物質問
に生成されるため、放電により電導度が小さい硫酸鉛が
生成しても、活物質相互の導電性が保たれて極板内部ま
で反応が起こり、活物質の利用率が高められ、電池のエ
ネルギー密度（Ｗｈ／ｋｇ）を向上させるという効果が
得られた。Effects of the Invention As described above, when metallic tin or a tin compound is added between the positive electrode active materials of the present invention, tin oxide with good conductivity is generated in the active material, so lead sulfate with low conductivity is removed by discharge. Even when the active materials are formed, the mutual conductivity between the active materials is maintained and reactions occur inside the electrode plates, increasing the utilization rate of the active materials and improving the energy density (Wh/kg) of the battery. .
第１図は本発明の密閉型鉛蓄電池および従来品の放電容
量の比較を示す図、第２図はサイクル試験の寿命の比較
を示す図、第３図は錫の添加量に対する放電容量を示す
図、第４図は錫の添加量に対するサイクル寿命を示す図
である。
代理人の氏名 弁理士 粟野重孝 ほか１名男
図
族質容ｔ
（…Ａｈａ
勇
麹
第
図
盗Ｘｌ 量
ｆ％〕
第
図Figure 1 is a diagram showing a comparison of the discharge capacity of the sealed lead acid battery of the present invention and a conventional product, Figure 2 is a diagram showing a comparison of the life of a cycle test, and Figure 3 is a diagram showing the discharge capacity with respect to the amount of tin added. FIG. 4 is a diagram showing the cycle life with respect to the amount of tin added. Name of agent: Patent attorney Shigetaka Awano and 1 other person
Claims (1)
したことを特徴とする鉛蓄電池。（２）錫化合物が硫酸
錫、または酸化錫である特許請求の範囲第１項記載の鉛
蓄電池。 （３）添加した錫元素のモル数が、正極活物質中の鉛の
モル数に対して０．０１％〜５％である特許請求の範囲
第１項記載の鉛蓄電池。[Claims] (1) A lead-acid battery characterized in that metallic tin or a tin compound is added between positive electrode active materials. (2) The lead-acid battery according to claim 1, wherein the tin compound is tin sulfate or tin oxide. (3) The lead-acid battery according to claim 1, wherein the number of moles of added tin element is 0.01% to 5% with respect to the number of moles of lead in the positive electrode active material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2116225A JP2949772B2 (en) | 1990-05-02 | 1990-05-02 | Liquid-filled lead-acid battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2116225A JP2949772B2 (en) | 1990-05-02 | 1990-05-02 | Liquid-filled lead-acid battery |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0414758A true JPH0414758A (en) | 1992-01-20 |
| JP2949772B2 JP2949772B2 (en) | 1999-09-20 |
Family
ID=14681931
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2116225A Expired - Lifetime JP2949772B2 (en) | 1990-05-02 | 1990-05-02 | Liquid-filled lead-acid battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2949772B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0849816A1 (en) * | 1996-12-19 | 1998-06-24 | Japan Storage Battery Company Limited | Lead-acid battery and producing method thereof |
| JP2017183160A (en) * | 2016-03-31 | 2017-10-05 | 日立化成株式会社 | Lead storage battery |
| WO2018025837A1 (en) * | 2016-08-05 | 2018-02-08 | 株式会社Ｇｓユアサ | Lead storage cell |
| US9970394B2 (en) | 2012-07-25 | 2018-05-15 | Baldwin Filters, Inc. | Filter housing, fluted filter and safety filter |
-
1990
- 1990-05-02 JP JP2116225A patent/JP2949772B2/en not_active Expired - Lifetime
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0849816A1 (en) * | 1996-12-19 | 1998-06-24 | Japan Storage Battery Company Limited | Lead-acid battery and producing method thereof |
| US9970394B2 (en) | 2012-07-25 | 2018-05-15 | Baldwin Filters, Inc. | Filter housing, fluted filter and safety filter |
| JP2017183160A (en) * | 2016-03-31 | 2017-10-05 | 日立化成株式会社 | Lead storage battery |
| WO2018025837A1 (en) * | 2016-08-05 | 2018-02-08 | 株式会社Ｇｓユアサ | Lead storage cell |
| CN109565040A (en) * | 2016-08-05 | 2019-04-02 | 株式会社杰士汤浅国际 | Lead storage battery |
| CN109565040B (en) * | 2016-08-05 | 2022-03-01 | 株式会社杰士汤浅国际 | Lead-acid battery |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2949772B2 (en) | 1999-09-20 |
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