JPH0412237B2 - - Google Patents
Info
- Publication number
- JPH0412237B2 JPH0412237B2 JP59129608A JP12960884A JPH0412237B2 JP H0412237 B2 JPH0412237 B2 JP H0412237B2 JP 59129608 A JP59129608 A JP 59129608A JP 12960884 A JP12960884 A JP 12960884A JP H0412237 B2 JPH0412237 B2 JP H0412237B2
- Authority
- JP
- Japan
- Prior art keywords
- image
- dyes
- dye
- pigments
- yellow
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000012546 transfer Methods 0.000 claims description 33
- 239000010410 layer Substances 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 16
- 239000003963 antioxidant agent Substances 0.000 claims description 13
- 230000003078 antioxidant effect Effects 0.000 claims description 10
- 238000002844 melting Methods 0.000 claims description 7
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 4
- 239000011247 coating layer Substances 0.000 claims description 2
- 239000000049 pigment Substances 0.000 description 32
- 239000000975 dye Substances 0.000 description 26
- 239000000976 ink Substances 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- 239000006096 absorbing agent Substances 0.000 description 7
- 239000002585 base Substances 0.000 description 6
- -1 brighteners Substances 0.000 description 6
- 239000012860 organic pigment Substances 0.000 description 5
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 4
- 239000000987 azo dye Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- DBOSBRHMHBENLP-UHFFFAOYSA-N 4-tert-Butylphenyl Salicylate Chemical compound C1=CC(C(C)(C)C)=CC=C1OC(=O)C1=CC=CC=C1O DBOSBRHMHBENLP-UHFFFAOYSA-N 0.000 description 3
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 229920000609 methyl cellulose Polymers 0.000 description 3
- 239000001923 methylcellulose Substances 0.000 description 3
- 235000010981 methylcellulose Nutrition 0.000 description 3
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 3
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 3
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- OSNILPMOSNGHLC-UHFFFAOYSA-N 1-[4-methoxy-3-(piperidin-1-ylmethyl)phenyl]ethanone Chemical compound COC1=CC=C(C(C)=O)C=C1CN1CCCCC1 OSNILPMOSNGHLC-UHFFFAOYSA-N 0.000 description 2
- ITLDHFORLZTRJI-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-5-octoxyphenol Chemical compound OC1=CC(OCCCCCCCC)=CC=C1N1N=C2C=CC=CC2=N1 ITLDHFORLZTRJI-UHFFFAOYSA-N 0.000 description 2
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 description 2
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 description 2
- QZHXKQKKEBXYRG-UHFFFAOYSA-N 4-n-(4-aminophenyl)benzene-1,4-diamine Chemical compound C1=CC(N)=CC=C1NC1=CC=C(N)C=C1 QZHXKQKKEBXYRG-UHFFFAOYSA-N 0.000 description 2
- AQSOTOUQTVJNMY-UHFFFAOYSA-N 7-(dimethylamino)-4-hydroxy-3-oxophenoxazin-10-ium-1-carboxylic acid;chloride Chemical compound [Cl-].OC(=O)C1=CC(=O)C(O)=C2OC3=CC(N(C)C)=CC=C3[NH+]=C21 AQSOTOUQTVJNMY-UHFFFAOYSA-N 0.000 description 2
- IQFVPQOLBLOTPF-UHFFFAOYSA-L Congo Red Chemical compound [Na+].[Na+].C1=CC=CC2=C(N)C(N=NC3=CC=C(C=C3)C3=CC=C(C=C3)N=NC3=C(C4=CC=CC=C4C(=C3)S([O-])(=O)=O)N)=CC(S([O-])(=O)=O)=C21 IQFVPQOLBLOTPF-UHFFFAOYSA-L 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- LMULDSDQRQVZMW-UHFFFAOYSA-N N-(5-chloro-2,4-dimethoxyphenyl)-4-[[5-(diethylsulfamoyl)-2-methoxyphenyl]diazenyl]-3-hydroxynaphthalene-2-carboxamide Chemical compound CCN(CC)S(=O)(=O)C1=CC=C(OC)C(N=NC=2C3=CC=CC=C3C=C(C=2O)C(=O)NC=2C(=CC(OC)=C(Cl)C=2)OC)=C1 LMULDSDQRQVZMW-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000000999 acridine dye Substances 0.000 description 2
- 239000001000 anthraquinone dye Substances 0.000 description 2
- KSCQDDRPFHTIRL-UHFFFAOYSA-N auramine O Chemical compound [H+].[Cl-].C1=CC(N(C)C)=CC=C1C(=N)C1=CC=C(N(C)C)C=C1 KSCQDDRPFHTIRL-UHFFFAOYSA-N 0.000 description 2
- QFFVPLLCYGOFPU-UHFFFAOYSA-N barium chromate Chemical compound [Ba+2].[O-][Cr]([O-])(=O)=O QFFVPLLCYGOFPU-UHFFFAOYSA-N 0.000 description 2
- 239000000981 basic dye Substances 0.000 description 2
- CJOBVZJTOIVNNF-UHFFFAOYSA-N cadmium sulfide Chemical compound [Cd]=S CJOBVZJTOIVNNF-UHFFFAOYSA-N 0.000 description 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 2
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 2
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 235000019239 indanthrene blue RS Nutrition 0.000 description 2
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 2
- 239000001013 indophenol dye Substances 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 description 2
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 2
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000983 mordant dye Substances 0.000 description 2
- 239000001005 nitro dye Substances 0.000 description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
- 239000001006 nitroso dye Substances 0.000 description 2
- 125000000018 nitroso group Chemical group N(=O)* 0.000 description 2
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 239000001007 phthalocyanine dye Substances 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 229960001860 salicylate Drugs 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 150000003346 selenoethers Chemical class 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- RBYJOOWYRXEJAM-UHFFFAOYSA-M sodium;5,9-dianilino-7-phenylbenzo[a]phenazin-7-ium-4,10-disulfonate Chemical compound [Na+].C=1C=CC=CC=1[N+]1=C2C=C(NC=3C=CC=CC=3)C(S(=O)(=O)[O-])=CC2=NC(C2=CC=CC(=C22)S([O-])(=O)=O)=C1C=C2NC1=CC=CC=C1 RBYJOOWYRXEJAM-UHFFFAOYSA-M 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 2
- 235000021286 stilbenes Nutrition 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000001016 thiazine dye Substances 0.000 description 2
- 239000001017 thiazole dye Substances 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 2
- 239000000984 vat dye Substances 0.000 description 2
- 239000001018 xanthene dye Substances 0.000 description 2
- VNFXPOAMRORRJJ-UHFFFAOYSA-N (4-octylphenyl) 2-hydroxybenzoate Chemical compound C1=CC(CCCCCCCC)=CC=C1OC(=O)C1=CC=CC=C1O VNFXPOAMRORRJJ-UHFFFAOYSA-N 0.000 description 1
- QBZIEGUIYWGBMY-FUZXWUMZSA-N (5Z)-5-hydroxyimino-6-oxonaphthalene-2-sulfonic acid iron Chemical compound [Fe].O\N=C1/C(=O)C=Cc2cc(ccc12)S(O)(=O)=O.O\N=C1/C(=O)C=Cc2cc(ccc12)S(O)(=O)=O.O\N=C1/C(=O)C=Cc2cc(ccc12)S(O)(=O)=O QBZIEGUIYWGBMY-FUZXWUMZSA-N 0.000 description 1
- XLTMWFMRJZDFFD-UHFFFAOYSA-N 1-[(2-chloro-4-nitrophenyl)diazenyl]naphthalen-2-ol Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C([N+]([O-])=O)C=C1Cl XLTMWFMRJZDFFD-UHFFFAOYSA-N 0.000 description 1
- MEZZCSHVIGVWFI-UHFFFAOYSA-N 2,2'-Dihydroxy-4-methoxybenzophenone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1O MEZZCSHVIGVWFI-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- KHEJIASFXAZENA-UHFFFAOYSA-N 2,3-dicyanopent-2-enoic acid Chemical compound CCC(=C(C#N)C(=O)O)C#N KHEJIASFXAZENA-UHFFFAOYSA-N 0.000 description 1
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
- LHPPDQUVECZQSW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-ditert-butylphenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=CC=CC3=N2)=C1O LHPPDQUVECZQSW-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- GPNYZBKIGXGYNU-UHFFFAOYSA-N 2-tert-butyl-6-[(3-tert-butyl-5-ethyl-2-hydroxyphenyl)methyl]-4-ethylphenol Chemical compound CC(C)(C)C1=CC(CC)=CC(CC=2C(=C(C=C(CC)C=2)C(C)(C)C)O)=C1O GPNYZBKIGXGYNU-UHFFFAOYSA-N 0.000 description 1
- WZSFTHVIIGGDOI-UHFFFAOYSA-N 4,5,6,7-tetrachloro-3-[2-methyl-3-[(4,5,6,7-tetrachloro-3-oxoisoindol-1-yl)amino]anilino]isoindol-1-one Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C2=C1C(NC1=CC=CC(NC=3C4=C(C(=C(Cl)C(Cl)=C4Cl)Cl)C(=O)N=3)=C1C)=NC2=O WZSFTHVIIGGDOI-UHFFFAOYSA-N 0.000 description 1
- DWDURZSYQTXVIN-UHFFFAOYSA-N 4-[(4-aminophenyl)-(4-methyliminocyclohexa-2,5-dien-1-ylidene)methyl]aniline Chemical compound C1=CC(=NC)C=CC1=C(C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 DWDURZSYQTXVIN-UHFFFAOYSA-N 0.000 description 1
- IYHIFXGFKVJNBB-UHFFFAOYSA-N 5-chloro-2-[(2-hydroxynaphthalen-1-yl)diazenyl]-4-methylbenzenesulfonic acid Chemical compound C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S(O)(=O)=O IYHIFXGFKVJNBB-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Natural products C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
- 239000004255 Butylated hydroxyanisole Substances 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- 108091005944 Cerulean Proteins 0.000 description 1
- 239000002656 Distearyl thiodipropionate Substances 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 239000004233 Indanthrene blue RS Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- GRPFBMKYXAYEJM-UHFFFAOYSA-M [4-[(2-chlorophenyl)-[4-(dimethylamino)phenyl]methylidene]cyclohexa-2,5-dien-1-ylidene]-dimethylazanium;chloride Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C(=CC=CC=1)Cl)=C1C=CC(=[N+](C)C)C=C1 GRPFBMKYXAYEJM-UHFFFAOYSA-M 0.000 description 1
- AUNAPVYQLLNFOI-UHFFFAOYSA-L [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O Chemical compound [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O AUNAPVYQLLNFOI-UHFFFAOYSA-L 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- HFVAFDPGUJEFBQ-UHFFFAOYSA-M alizarin red S Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=C(S([O-])(=O)=O)C(O)=C2O HFVAFDPGUJEFBQ-UHFFFAOYSA-M 0.000 description 1
- AOADSHDCARXSGL-ZMIIQOOPSA-M alkali blue 4B Chemical compound CC1=CC(/C(\C(C=C2)=CC=C2NC2=CC=CC=C2S([O-])(=O)=O)=C(\C=C2)/C=C/C\2=N\C2=CC=CC=C2)=CC=C1N.[Na+] AOADSHDCARXSGL-ZMIIQOOPSA-M 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- UHHXUPJJDHEMGX-UHFFFAOYSA-K azanium;manganese(3+);phosphonato phosphate Chemical compound [NH4+].[Mn+3].[O-]P([O-])(=O)OP([O-])([O-])=O UHHXUPJJDHEMGX-UHFFFAOYSA-K 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 229940083898 barium chromate Drugs 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- OCWYEMOEOGEQAN-UHFFFAOYSA-N bumetrizole Chemical compound CC(C)(C)C1=CC(C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O OCWYEMOEOGEQAN-UHFFFAOYSA-N 0.000 description 1
- 235000019282 butylated hydroxyanisole Nutrition 0.000 description 1
- 229940043253 butylated hydroxyanisole Drugs 0.000 description 1
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- PZTQVMXMKVTIRC-UHFFFAOYSA-L chembl2028348 Chemical compound [Ca+2].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 PZTQVMXMKVTIRC-UHFFFAOYSA-L 0.000 description 1
- YOCIQNIEQYCORH-UHFFFAOYSA-M chembl2028361 Chemical compound [Na+].OC1=CC=C2C=C(S([O-])(=O)=O)C=CC2=C1N=NC1=CC=CC=C1 YOCIQNIEQYCORH-UHFFFAOYSA-M 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910000152 cobalt phosphate Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- FPVGTPBMTFTMRT-UHFFFAOYSA-L disodium;2-amino-5-[(4-sulfonatophenyl)diazenyl]benzenesulfonate Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 FPVGTPBMTFTMRT-UHFFFAOYSA-L 0.000 description 1
- WSALIDVQXCHFEG-UHFFFAOYSA-L disodium;4,8-diamino-1,5-dihydroxy-9,10-dioxoanthracene-2,6-disulfonate Chemical compound [Na+].[Na+].O=C1C2=C(N)C=C(S([O-])(=O)=O)C(O)=C2C(=O)C2=C1C(O)=C(S([O-])(=O)=O)C=C2N WSALIDVQXCHFEG-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 description 1
- 235000019305 distearyl thiodipropionate Nutrition 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- YQGOJNYOYNNSMM-UHFFFAOYSA-N eosin Chemical compound [Na+].OC(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C(O)=C(Br)C=C21 YQGOJNYOYNNSMM-UHFFFAOYSA-N 0.000 description 1
- PLYDMIIYRWUYBP-UHFFFAOYSA-N ethyl 4-[[2-chloro-4-[3-chloro-4-[(3-ethoxycarbonyl-5-oxo-1-phenyl-4h-pyrazol-4-yl)diazenyl]phenyl]phenyl]diazenyl]-5-oxo-1-phenyl-4h-pyrazole-3-carboxylate Chemical compound CCOC(=O)C1=NN(C=2C=CC=CC=2)C(=O)C1N=NC(C(=C1)Cl)=CC=C1C(C=C1Cl)=CC=C1N=NC(C(=N1)C(=O)OCC)C(=O)N1C1=CC=CC=C1 PLYDMIIYRWUYBP-UHFFFAOYSA-N 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 235000019233 fast yellow AB Nutrition 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 238000007757 hot melt coating Methods 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 235000010187 litholrubine BK Nutrition 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229940107698 malachite green Drugs 0.000 description 1
- FDZZZRQASAIRJF-UHFFFAOYSA-M malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000434 metal complex dye Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- OBJNZHVOCNPSCS-UHFFFAOYSA-N naphtho[2,3-f]quinazoline Chemical compound C1=NC=C2C3=CC4=CC=CC=C4C=C3C=CC2=N1 OBJNZHVOCNPSCS-UHFFFAOYSA-N 0.000 description 1
- CTIQLGJVGNGFEW-UHFFFAOYSA-L naphthol yellow S Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C=C2C([O-])=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 CTIQLGJVGNGFEW-UHFFFAOYSA-L 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- ZZSIDSMUTXFKNS-UHFFFAOYSA-N perylene red Chemical compound CC(C)C1=CC=CC(C(C)C)=C1N(C(=O)C=1C2=C3C4=C(OC=5C=CC=CC=5)C=1)C(=O)C2=CC(OC=1C=CC=CC=1)=C3C(C(OC=1C=CC=CC=1)=CC1=C2C(C(N(C=3C(=CC=CC=3C(C)C)C(C)C)C1=O)=O)=C1)=C2C4=C1OC1=CC=CC=C1 ZZSIDSMUTXFKNS-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- RSRNHSYYBLEMOI-UHFFFAOYSA-M primuline Chemical compound [Na+].S1C2=C(S([O-])(=O)=O)C(C)=CC=C2N=C1C(C=C1S2)=CC=C1N=C2C1=CC=C(N)C=C1 RSRNHSYYBLEMOI-UHFFFAOYSA-M 0.000 description 1
- 235000012752 quinoline yellow Nutrition 0.000 description 1
- 239000004172 quinoline yellow Substances 0.000 description 1
- 229940051201 quinoline yellow Drugs 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 238000001454 recorded image Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- MCTSPGQLUUIIJY-LBEJWNQZSA-M sodium (1E)-2-hydroxy-1-hydroxyiminonaphthalene-2-sulfonate Chemical compound [Na+].O\N=C1/c2ccccc2C=CC1(O)S([O-])(=O)=O MCTSPGQLUUIIJY-LBEJWNQZSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000000988 sulfur dye Substances 0.000 description 1
- CXVGEDCSTKKODG-UHFFFAOYSA-N sulisobenzone Chemical compound C1=C(S(O)(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC=CC=C1 CXVGEDCSTKKODG-UHFFFAOYSA-N 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- LVEOKSIILWWVEO-UHFFFAOYSA-N tetradecyl 3-(3-oxo-3-tetradecoxypropyl)sulfanylpropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCC LVEOKSIILWWVEO-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
Description
(A) 産業上の利用分野
本発明は画像保存性を向上させた熱転写記録材
料に関する。さらに詳しくは、基材の片面に加熱
時転写可能な熱溶融性インク層を設けた転写シー
トと、該転写シートからの転写像を受ける受像シ
ートを組み合わせてなる熱転写記録材料におい
て、該転写シートと接する受像シート面に紫外線
吸収剤、および／または酸化防止剤を含有する塗
工層を設けることにより、画像保存性を向上させ
た熱転写記録材料に関する。
(B) 従来技術
近年、カラープリンターやカラーフアクシミリ
の開発が盛んに行なわれ、カラー記録への関心が
高まつてきている。特に、熱転写記録は、装置の
機構が簡単なため保守が容易で、かつ価格および
維持費が低いこと、また低エネルギーで鮮明な高
濃度の記録ができること、および多色のインクシ
ートを用いることにより比較的容易にカラー記録
が可能であること等から、最近注目を集めてい
る。
カラーの溶融型熱転写記録の特徴として、画像
保存性の良いことがよく挙げられる。しかしなが
ら、カラーの溶融型熱転写記録の画像保存性は、
昇華型熱転写記録やインクジエツト記録のそれよ
り優れているものの、その印字サンプルを太陽光
や紫外線に長期間曝露すると退色または黒変が認
められ、耐光性については実用上充分とは言い難
い。
カラーの溶融型熱転写記録では、インク層中に
含有されている色材として、色再現性の観点より
有機顔料や染料が多く用いられている。これらの
有機顔料や染料が紫外線により酸化劣化し、退色
または黒変が起ると考えられる。
(C) 発明の目的
本発明は上記の事情を鑑みてなされたもので、
画像保存性を向上させた熱転写記録材料を提供す
ることを目的とする。
(D) 発明の構成
即ち、本発明は、基材の片面に加熱時転写可能
な熱溶融性インク層を設けた転写シートと、該転
写シートからの転写像を受ける受像シートを組み
合わせてなる熱転写記録材料において、該転写シ
ートと接する受像シート面に紫外線吸収剤、およ
び／または酸化防止剤を含有する受像層を設ける
ことにより、画像保存性を向上させた熱転写記録
材料を提供できた。
本発明において、受像シートの転写像を受ける
面に塗設された受像層に含有される紫外線吸収剤
および酸化防止剤の融点は50〜150℃が好ましい。
融点が50℃より低いものは受像シートのべたつき
やブロツキングを引き起こす。また、150℃より
高いものは、熱ヘツドによる加熱では溶融し難い
ため、転写したインク層と完全に混らず、効果が
著しく低下する。本発明において用いられる紫外
線吸収剤および酸化防止剤の例を以下に挙げる
が、これらが本発明を何ら限定するものではな
い。
紫外線吸収剤
ｐ−tert−ブチルフエニルサリシレートおよび
ｐ−オクチルフエニルサリシレート等のサリチル
酸系紫外線吸収剤、２，４−ジヒドロキシベンゾ
フエノン、２−ヒドロキシ−４−メトキシベンゾ
フエノン、２，2′−ジヒドロキシ−４−メトキシ
ベンゾフエノン、２，2′−ジヒドロキシ−４，
4′−ジメトキシベンゾフエノン、および２−ヒド
ロキシ−４−メトキシ−５−スルホベンゾフエノ
ン等のベンゾフエノン系紫外線吸収剤、２−
（2′−ヒドロキシ−5′−メチルフエニル）ベンゾ
トリアゾール、２−（2′−ヒドロキシ−3′，5′−
ジ・tert−ブチルフエニル）ベンゾトリアゾー
ル、２−（2′−ヒドロキシ−3′−tert−ブチル−
5′−メチルフエニル）−５−クロロベンゾトリア
ゾール、２−（2′−ヒドロキシ−3′，5′−ジ・tert
−ブチルフエニル）−５−クロロベンゾトリアゾ
ールおよび２−（2′−ヒドロキシ−4′−オクトキ
シフエニル）ベンゾトリアゾール等のベンゾトリ
アゾール系紫外線吸収剤、エチル−２−シアノ−
３，3′−ジフエニルアクリレート等のシアノアク
リレート系紫外線吸収剤、および、ニツケル−ジ
ブチルジチオカルバメート、ベンゾエートタイプ
のクエンチヤーおよびヒンダードアミン等の紫外
線安定剤。
酸化防止剤
２，６−ジ・tert−ブチル−ｐ−クレゾール、
ブチル化ヒドロキシアニゾール、ステアリル−β
−（３，５−ジ・tert−ブチル−４−ヒドロキシ
フエニル）プロピオネート、２，2′−メチレン−
ビス−（４−メチル−６−tert−ブチルフエノー
ル）、２，2′−メチレン−ビス−（４−エチル−６
−tert.−ブチルフエノール）、およびテトラキス
−｛メチレン−３−（3′，5′−ジ・tert−ブチル−
4′−ヒドロキシフエニル）プロピオネート｝メタ
ン等のフエノール系酸化防止剤、ジミリスチルチ
オジプロピオネートおよびジステアリルチオジプ
ロピオネート等の硫黄系酸化防止剤、およびリン
系酸化防止剤以上のような紫外線吸収剤および酸
化防止剤に、たとえばポリビニルアルコール、メ
チルセルロース、ヒドロキシエチルセルロース、
カルボキシメチルセルロース、アラビアゴム、で
ん粉、ゼラチン、カゼイン、ポリビニルピロリド
ン、スチレン・ブタジエン共重合体系ラテツクス
類および酢酸ビニル系共重合体系ラテツクス類な
どの適当なバインダーの１種以上を併用すること
ができる。更に必要に応じ分散剤、消泡剤、増白
剤あるいはタルク、クレー、でん粉粒子などの充
填剤、およびワツクス類等の助剤を添加した水分
散性塗液を、受像シートの基材に塗布することに
より、本発明の受像層を形成することができる。
なお、上記の塗液においてバインダーの使用量
は、用いられる紫外線吸収剤および酸化防止剤と
バインダーの種類により異なるが、一般に紫外線
吸収剤および酸化防止剤の１〜50重量％、好まし
くは５〜30重量％である。また、受像シートの基
材としては紙、プラスチツクフイルム、合成紙を
用いることができる。
上記塗液の受像シート基材への塗工は、エアー
ナイフコーター、ロールコーター、プレードコー
ターおよびバーコーター等の通常用いられている
塗工機で行なうことができる。
紫外線吸収剤および酸化防止剤の塗布量は、転
写シート上のインク層に含まれる顔料および／ま
たは染料の10〜500重量％が好ましい。10重量％
以下では十分な効果を得ることができず、また
500重量％以上では経済性に問題が生じる。
上記のようにして塗工した受像層を有する本発
明の受像シートと組み合せて用いられる転写シー
トは、各種の公知の転写シートを使用できる。
転写シート基材としては厚さ３〜25μで密度0.9
〜1.4ｇ／cm3のプラスチツクフイルム（ポリエス
テル、ポリイミド、セロフアン等）や紙（コンデ
ンサー紙、合成紙、ラミネート紙等）が用いられ
る。
該基材上に設けられた加熱時転写可能なインク
層は顔料および／または染料を熱可融性物質に含
有させたものである。一般にカラーの溶融型熱転
写記録では、色再現性のため有機顔料や染料が用
いられる。本発明では、有機顔料および染料の場
合に対しその効果が顕著であるが、無機顔料の場
合に対しても同様の効果を示す。
有機顔料としては、アゾ顔料（モノアゾ、ビス
アゾ、縮合アゾ顔料）、染色レーキ顔料（酸性染
料レーキ、塩基性染料レーキ、媒染染料レーキ顔
料）、ニトロ顔料、ニトロソ顔料、フタロシアニ
ン顔料、高級顔料（建染染料系顔料、金属錯塩染
料、ペリレン顔料、イソインドリノン顔料、キナ
クリドン顔料）などを挙げることができる。さら
に具体的に例示すると、アゾ顔料としてはハンザ
エローＧ（C.I.11680、以下カツコはC.I.No.を示
す）、ハンザエローＲ（12710）、ピラゾロンレツド
Ｂ（21120）、パーマネントレツドＲ（12085）、レー
キレツドＣ（15585）、ブリリアントカーミン6B
（15850）、パーマネントカーミンFB（12490）（以
上モノアゾ顔料）、ベンジジンエローＧ（21090）、
ベンジジンエローGR（21100）、パーマネントエ
ローNCR（20040）（以上ビスアゾ顔料）、クロモ
フタルイエロー、クロモフタルレツド（以上縮合
アゾ顔料）などがある。染色レーキ顔料として
は、キノリンエローレーキ（47005）、エオシンレ
ーキ（45380）、アルカリブルーレーキ（42750A、
42770A）（以上酸性染料レーキ顔料）、ローダミ
ンレーキＢ（45170）、メチルバイオレツトレーキ
（42535）、ビクトリアブルーレーキ（44045）、マ
ラカイトグリーンレーキ（42000）（以上塩基性染
料レーキ顔料）、アリザリンレーキ（58000）（媒
染染料レーキ顔料）などがある。ニトロ顔料とし
てナフトールエローＳ（10316）、ニトロソ顔料と
してピグメントグリーンＢ（10006）、ナフトール
グリーンＢ（10020）、フタロシアニン顔料として
は、無金属フタロシアニンブルー（74100）、フタ
ロシアニンブルー（74160）、フタロシアニングリ
ーン（74260）などがある。高級顔料としては、
アンスラピリミジンエロー（68420）、インダンス
レンブリリアントオレンジGK（59305）、インダ
ンスレンブルーRS（69800）、チオインジゴレツド
Ｂ（73300）（以上建染染料系顔料）、ニツケルアゾ
エロー（12775）（金属錯塩顔料）、ペリレンレツ
ド（71140）、ペリレンスカーレツト（71137）（以
上ペリレン顔料）、イソインドリノンエロー（イ
ソインドリノン顔料）、キナクリドンレツドＹ
（46500）、キナクリドンマゼンタ（73915）などが
ある。
染料としては、ニトロソ染料、ニトロ染料、ア
ゾ染料（モノ、ビス、トリス、テトラキスアゾ染
料）、スチルベンアゾ染料、ケトイミン（ジフエ
ニルメタン）染料、トリフエニルメタン染料、キ
サンテン染料、アクリジン染料、キノリン染料、
メチン・ポリメチン染料、チアゾール染料、イン
ダミン・インドフエノール染料、アジン染料、オ
キサジン染料、チアジン染料、硫化染料、アミノ
ケトン・オキシケトン染料、アントラキノン染
料、インジゴイド染料、フタロシアニン染料など
を挙げることができる。さらに具体的に例示する
と、ニトロソ染料としてはモーダントグリーン４
（C.I.10005、以下カツコ内はC.I.No.を示す）、ニト
ロ染料としてはデイスパーズイエロー14（10340）、
アゾ染料としてはダイレクトレツド28（22120）、
スチルベンアゾ染料としてはダイレクトオレンジ
71（40205）、ケトイミン（ジフエニルメタン）染
料としてはベーシツクイエロー２（41000）、トリ
フエニルメタン染料としてはベーシツクブルー１
（42025）、キサンテン染料としてはアシツドレツ
ド52（45100）、アクリジン染料としてはベーシツ
クオレンジ23（46075）、キノリン染料としてはア
シツドイエロー２（47010）、メチン・ポリメチン
染料としてはデイスパーズイエロー31（48000）、
チアゾール染料としてはダイレクトイエロー59
（49000）、インダミン・インドフエノール染料と
してはソルベントブルー22（49705）、アジン染料
としてはアシツドブルー59（50315）、オキサジン
染料としてはモーダントブルー10（51030）、チア
ジン染料としてはベーシツクブルー９（52015）、
アミノケトン・オキシケトン染料としてはバツト
レツド33（56050）、アントラキノン染料としては
アシツドブルー45（63010）、インジゴイド染料と
してはバツトブルー41（73040）、フタロシアニン
染料としてはダイレクトブルー86（74180）などが
ある。
無機顔料としては、酸化物、硫化物、セレン化
物、フエロシアン化物、クロム酸塩、ケイ酸塩、
リン酸塩などを挙げることができる。さらに具体
的に例示すると、酸化物としてはベンガラ（C.
I.77491、以下カツコ内はC.I.No.を示す）、コバル
トブルー（77346）、鉛丹（77578）、コバルトグリ
ーン、酸化クロム（77288）、セルリアンブルー
（77368）、ビリジアン（77289）、および黄色酸化
鉄（77492）、硫化物としては、カドミウムエロー
（77199）、銀朱（77766）、セレン化物としてはブ
ルシアンブルー（77510と77520）、クロム酸塩と
しては、クロムエロー（77600）、クロムバーミリ
オン（77605）、ジンククロメート（77955）、クロ
ム酸バリウム（77955）、ケイ酸塩としてはウルト
ラマリン（77007）、リン酸塩としてはコバルトバ
イオレツトデイープ（77360）、マンガンバイオレ
ツト（77742）などがある。
熱可融性物質としては融点が50〜150℃のパラ
フインワツクス、カルナウバワツクス、モンタン
ワツクス、ポリエチレンワツクス、合成ワツク
ス、固体脂肪酸、固体アミド等が用いられる。
更に上記のインキ層中に必要に応じて、石油樹
脂、ポリ酢酸ビニル、ポリスチレン、スチレン−
ブタジエン共重合体、セルロースエーテル類、セ
ルロースエステル類およびアクリル系樹脂等の熱
可塑性高分子物質、または鉱物油、動物油、植物
油等の油状物等の油状物質および可塑剤等を柔軟
剤として添加することもできる。
転写シート基材への上記のインク層の塗工は、
一般のホツトメルトコーテイングやソルベルトコ
ーテイングによつて行なわれるが、水系塗液とし
て塗工することも可能である。
以上の本発明の熱転写型記録シートでは、受像
シート上に紫外線吸収剤および／または酸化防止
剤を含有する受像層が設けられているため、耐光
性の極めて優れた転写像を得ることができる。
以下に本発明を更に具体的に説明するために実
施例を示すが、もちろん本発明がこれらに限定さ
れるものではない。また実施例中の部および％は
重量部または重量％を示す。
(E) 実施例
実施例 １
第１表に示す組成のイエロー、マゼンタおよび
シアンのインクを調製した。
これらのインクを、厚さ13μ、密度0.90ｇ／cm3
のコンデンサー紙にホツトメルトコーターで4.0
ｇ／m2塗布して、転写シートを得た。
別に、ｐ−tert−ブチルフエニルサリシレート
25ｇを３％メチルセルロース水溶液75ｇと共にボ
ールミルで24時間分散し、受像層の塗液を得た。
これを坪量55ｇ／m2の普通紙に固型分塗布量が
１ｇ／m2となるように塗布乾燥し、スーパーカレ
ンダーで処理して受像シートを得た。
転写シートのインク層面と受像シートの受像層
面を合わせ、転写シートの裏面から、松下電子部
品製フアクシミリ試験機を用い、パルス巾2.0m
sec、電圧16.0Vで、イエロー、マゼンタおよび
シアンの３色を印字した。
(A) Industrial Application Field The present invention relates to a thermal transfer recording material with improved image storage stability. More specifically, in a thermal transfer recording material that combines a transfer sheet having a heat-melting ink layer that can be transferred when heated on one side of a base material, and an image receiving sheet that receives a transferred image from the transfer sheet, the transfer sheet and The present invention relates to a thermal transfer recording material in which image storage stability is improved by providing a coating layer containing an ultraviolet absorber and/or an antioxidant on the surface of an image-receiving sheet in contact with the image-receiving sheet. (B) Prior Art In recent years, color printers and color facsimile machines have been actively developed, and interest in color recording is increasing. In particular, thermal transfer recording is easy to maintain due to the simple mechanism of the device, has low price and maintenance costs, is capable of clear, high-density recording with low energy, and uses multicolor ink sheets. It has recently attracted attention because color recording is relatively easy. One of the characteristics of color melt-type thermal transfer recording is that it has good image storage stability. However, the image storage stability of color melt-type thermal transfer recording is
Although it is superior to sublimation thermal transfer recording and inkjet recording, when the printed sample is exposed to sunlight or ultraviolet rays for a long period of time, discoloration or blackening is observed, and its light resistance cannot be said to be sufficient for practical use. In color melt-type thermal transfer recording, organic pigments and dyes are often used as coloring materials contained in the ink layer from the viewpoint of color reproducibility. It is thought that these organic pigments and dyes are oxidized and degraded by ultraviolet rays, causing discoloration or blackening. (C) Purpose of the invention The present invention has been made in view of the above circumstances.
The purpose of the present invention is to provide a thermal transfer recording material with improved image storage properties. (D) Structure of the Invention That is, the present invention provides a thermal transfer method that combines a transfer sheet having a heat-melting ink layer that can be transferred when heated on one side of a base material, and an image receiving sheet that receives a transferred image from the transfer sheet. In the recording material, by providing an image receiving layer containing an ultraviolet absorber and/or an antioxidant on the surface of the image receiving sheet in contact with the transfer sheet, it was possible to provide a thermal transfer recording material with improved image storage stability. In the present invention, the melting point of the ultraviolet absorber and antioxidant contained in the image-receiving layer coated on the surface of the image-receiving sheet that receives the transferred image is preferably 50 to 150°C.
Those with a melting point lower than 50°C cause stickiness and blocking of the image-receiving sheet. In addition, if the temperature is higher than 150°C, it is difficult to melt when heated with a thermal head, so it does not mix completely with the transferred ink layer, resulting in a significant decrease in effectiveness. Examples of the ultraviolet absorber and antioxidant used in the present invention are listed below, but these do not limit the present invention in any way. UV absorbers Salicylic acid UV absorbers such as p-tert-butylphenyl salicylate and p-octylphenyl salicylate, 2,4-dihydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2,2' -dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,
Benzophenone ultraviolet absorbers such as 4'-dimethoxybenzophenone and 2-hydroxy-4-methoxy-5-sulfobenzophenone, 2-
(2'-hydroxy-5'-methylphenyl)benzotriazole, 2-(2'-hydroxy-3',5'-
di-tert-butylphenyl)benzotriazole, 2-(2'-hydroxy-3'-tert-butyl-
5'-methylphenyl)-5-chlorobenzotriazole, 2-(2'-hydroxy-3',5'-di-tert
Benzotriazole UV absorbers such as -butylphenyl)-5-chlorobenzotriazole and 2-(2'-hydroxy-4'-octoxyphenyl)benzotriazole, ethyl-2-cyano-
Cyanoacrylate UV absorbers such as 3,3'-diphenyl acrylate, and UV stabilizers such as nickel-dibutyldithiocarbamate, benzoate type quenchers and hindered amines. Antioxidant 2,6-di-tert-butyl-p-cresol,
Butylated hydroxyanisole, stearyl-β
-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, 2,2'-methylene-
Bis-(4-methyl-6-tert-butylphenol), 2,2'-methylene-bis-(4-ethyl-6
-tert.-butylphenol), and tetrakis-{methylene-3-(3',5'-di-tert-butyl-
4′-Hydroxyphenyl)propionate} Phenolic antioxidants such as methane, sulfur-based antioxidants such as dimyristylthiodipropionate and distearylthiodipropionate, and phosphorus-based antioxidants. Absorbents and antioxidants such as polyvinyl alcohol, methylcellulose, hydroxyethylcellulose,
One or more suitable binders such as carboxymethylcellulose, gum arabic, starch, gelatin, casein, polyvinylpyrrolidone, styrene-butadiene copolymer latexes, and vinyl acetate copolymer latexes can be used in combination. Furthermore, a water-dispersible coating liquid to which dispersants, antifoaming agents, brighteners, fillers such as talc, clay, starch particles, and auxiliary agents such as waxes are added is applied to the base material of the image-receiving sheet. By doing so, the image receiving layer of the present invention can be formed. The amount of binder used in the above coating fluid varies depending on the type of UV absorber and antioxidant used and the binder, but is generally 1 to 50% by weight, preferably 5 to 30% by weight of the UV absorber and antioxidant. Weight%. Moreover, paper, plastic film, or synthetic paper can be used as the base material of the image-receiving sheet. The coating liquid can be applied to the image-receiving sheet substrate using a commonly used coating machine such as an air knife coater, roll coater, blade coater, or bar coater. The amount of the ultraviolet absorber and antioxidant applied is preferably 10 to 500% by weight of the pigment and/or dye contained in the ink layer on the transfer sheet. 10% by weight
You may not be able to obtain sufficient effects with the following
If it exceeds 500% by weight, problems will arise in terms of economic efficiency. Various known transfer sheets can be used as the transfer sheet used in combination with the image-receiving sheet of the present invention having the image-receiving layer coated as described above. As a transfer sheet base material, the thickness is 3 to 25μ and the density is 0.9.
A plastic film (polyester, polyimide, cellophane, etc.) or paper (condenser paper, synthetic paper, laminated paper, etc.) with a weight of ~1.4 g/cm 3 is used. The heat-transferable ink layer provided on the substrate includes a heat-fusible substance containing a pigment and/or dye. Generally, in color melt-type thermal transfer recording, organic pigments and dyes are used for color reproducibility. In the present invention, the effect is remarkable for organic pigments and dyes, but the same effect is shown for inorganic pigments as well. Organic pigments include azo pigments (monoazo, bisazo, condensed azo pigments), dyeing lake pigments (acid dye lake, basic dye lake, mordant dye lake pigment), nitro pigments, nitroso pigments, phthalocyanine pigments, and high-grade pigments (vat dye lake pigments). Examples include dye pigments, metal complex dyes, perylene pigments, isoindolinone pigments, and quinacridone pigments). To give more specific examples, examples of azo pigments include Hansa Yellow G (CI11680, the box below indicates CI No.), Hansa Yellow R (12710), Pyrazolone Red B (21120), Permanent Red R (12085), Lake Red C ( 15585), Brilliant Carmine 6B
(15850), Permanent Carmine FB (12490) (monoazo pigments), Benzidine Yellow G (21090),
Examples include Benzidine Yellow GR (21100), Permanent Yellow NCR (20040) (bisazo pigments), Chromophthal Yellow, and Chromophthal Red (condensed azo pigments). Dyeing lake pigments include quinoline yellow lake (47005), eosin lake (45380), alkali blue lake (42750A,
42770A) (Acidic dye lake pigment), Rhodamine Lake B (45170), Methyl Violet Lake (42535), Victoria Blue Lake (44045), Malachite Green Lake (42000) (Basic dye lake pigment), Alizarin Lake ( 58000) (mordant dye lake pigment). Nitro pigments include naphthol yellow S (10316), nitroso pigments include pigment green B (10006) and naphthol green B (10020), and phthalocyanine pigments include metal-free phthalocyanine blue (74100), phthalocyanine blue (74160), and phthalocyanine green (74260). )and so on. As a high-grade pigment,
Anthrapyrimidine Yellow (68420), Indanthrene Brilliant Orange GK (59305), Indanthrene Blue RS (69800), Thioindigolet B (73300) (vat dye pigments), Nickel Azo Yellow (12775) ( Metal complex salt pigment), perylene red (71140), perylene scarlet (71137) (perylene pigment), isoindolinone yellow (isoindolinone pigment), quinacridone red Y
(46500) and Quinacridone Magenta (73915). Dyes include nitroso dyes, nitro dyes, azo dyes (mono, bis, tris, and tetrakisazo dyes), stilbene azo dyes, ketoimine (diphenylmethane) dyes, triphenylmethane dyes, xanthene dyes, acridine dyes, quinoline dyes,
Examples include methine/polymethine dyes, thiazole dyes, indamine/indophenol dyes, azine dyes, oxazine dyes, thiazine dyes, sulfur dyes, aminoketone/oxyketone dyes, anthraquinone dyes, indigoid dyes, and phthalocyanine dyes. To give a more specific example, Mordant Green 4 is a nitroso dye.
(CI10005, below the box indicates CI No.), Disperse Yellow 14 (10340) as a nitro dye,
Direct Red 28 (22120) is an azo dye.
Direct orange as a stilbene azo dye
71 (40205), Basic Yellow 2 (41000) as a ketoimine (diphenylmethane) dye, and Basic Blue 1 as a triphenylmethane dye.
(42025), xanthene dye Acid Dred 52 (45100), acridine dye Basic Orange 23 (46075), quinoline dye Acid Yellow 2 (47010), methine/polymethine dye Disperse Yellow 31 (48000). ),
Direct Yellow 59 as a thiazole dye
(49000), Solvent Blue 22 (49705) as an indamine/indophenol dye, Acid Blue 59 (50315) as an azine dye, Mordant Blue 10 (51030) as an oxazine dye, and Basic Blue 9 (52015) as a thiazine dye. ),
Examples of aminoketone/oxyketone dyes include Battled 33 (56050), anthraquinone dyes such as Acid Blue 45 (63010), indigoid dyes such as Batt Blue 41 (73040), and phthalocyanine dyes such as Direct Blue 86 (74180). Inorganic pigments include oxides, sulfides, selenides, ferrocyanides, chromates, silicates,
Examples include phosphates. To give a more specific example, examples of oxides include red iron (C.
I.77491, CI No. is shown below), cobalt blue (77346), red lead (77578), cobalt green, chromium oxide (77288), cerulean blue (77368), viridian (77289), and yellow iron oxide (77492), sulfides include cadmium yellow (77199) and silver vermilion (77766), selenides include Brucian blue (77510 and 77520), and chromates include chrome yellow (77600) and chrome vermilion (77605). , zinc chromate (77955), barium chromate (77955), silicates such as ultramarine (77007), and phosphates such as cobalt violet deep (77360) and manganese violet (77742). As the thermofusible substance, paraffin wax, carnauba wax, montan wax, polyethylene wax, synthetic wax, solid fatty acid, solid amide, etc. having a melting point of 50 to 150°C are used. Furthermore, in the above ink layer, petroleum resin, polyvinyl acetate, polystyrene, styrene-
Adding thermoplastic polymer substances such as butadiene copolymers, cellulose ethers, cellulose esters, and acrylic resins, or oily substances such as mineral oils, animal oils, vegetable oils, and plasticizers as softeners. You can also do it. Coating the above ink layer onto the transfer sheet base material is as follows:
This is done by general hot melt coating or solbert coating, but it is also possible to apply it as a water-based coating liquid. In the thermal transfer type recording sheet of the present invention described above, since an image receiving layer containing an ultraviolet absorber and/or an antioxidant is provided on the image receiving sheet, a transferred image with extremely excellent light resistance can be obtained. Examples will be shown below to more specifically explain the present invention, but the present invention is of course not limited to these. Further, parts and % in the examples indicate parts by weight or % by weight. (E) Examples Example 1 Yellow, magenta and cyan inks having the compositions shown in Table 1 were prepared. These inks have a thickness of 13μ and a density of 0.90g/cm 3
4.0 with a hot melt coater on condenser paper.
g/m 2 was applied to obtain a transfer sheet. Separately, p-tert-butylphenyl salicylate
25 g was dispersed in a ball mill for 24 hours with 75 g of a 3% aqueous methyl cellulose solution to obtain a coating liquid for the image-receiving layer. This was coated on plain paper with a basis weight of 55 g/m 2 so that the solid content coating amount was 1 g/m 2 and dried, and treated with a super calendar to obtain an image-receiving sheet. Align the ink layer surface of the transfer sheet and the image-receiving layer surface of the image-receiving sheet, and apply a pulse width of 2.0 m from the back side of the transfer sheet using a facsimile tester manufactured by Matsushita Electronic Components.
sec, and a voltage of 16.0 V, printing was performed in three colors: yellow, magenta, and cyan.
【表】
実施例 ２
実施例１のｐ−tert−ブチルフエニルサリシレ
ートにかえて２−ヒドロキシ−４−メトキシベン
ゾフエノンを用い、以下実施例１と同様の手順に
て受像シートを作製し、印字を行つた。
実施例 ３
実施例１のｐ−tert.−ブチルフエニルサリシレ
ートにかえて２−（2′−ヒドロキシ−4′−オクト
キシフエニル）ベンゾトリアゾール25ｇを５％メ
チルセルロース75ｇと共にボールミルで24時間分
散し、受像層の塗液を得た。これを実施例１と同
様の手順にて受像シートを作製し、印字を行つ
た。
実施例 ４
実施例１のｐ−tert.−ブチルフエニルサリシレ
ートに変えて、２，６−ジ−tert.−ブチル−ｐ−
クレゾールを用い、以下実施例１と同様の手順に
て受像シートを作製し、印字を行つた。
比較例
実施例１の受像シートのかわりに普通紙を用
い、実施例１と同様の手順にて印字を行つた。
以上のようにして得た印字サンプルを太陽光下
およびスガ試験機株式会社製キセノン ロングラ
イフ フエードメータHAL−25X−HCL内に放
置し、経時的な反射濃度変化をマクベス濃度計に
て測定した。反射濃度の残存率は次式より求め
た。
残存率＝放置後の反射濃度／印字直後の反射濃度×10
0
すなわち、残存率は100％以下であると退色を、
100％以上であると黒変を表わしている。
測定結果を表２に示した。これより明らかに本
発明の記録画像は保存性に優れていることがわか
る。[Table] Example 2 An image-receiving sheet was prepared in the same manner as in Example 1 using 2-hydroxy-4-methoxybenzophenone instead of p-tert-butylphenyl salicylate in Example 1. I printed it. Example 3 Instead of p-tert.-butylphenyl salicylate in Example 1, 25 g of 2-(2'-hydroxy-4'-octoxyphenyl)benzotriazole was dispersed with 75 g of 5% methylcellulose in a ball mill for 24 hours. , a coating solution for an image-receiving layer was obtained. An image receiving sheet was prepared using the same procedure as in Example 1, and printing was performed. Example 4 In place of p-tert.-butylphenyl salicylate in Example 1, 2,6-di-tert.-butyl-p-
An image receiving sheet was prepared using cresol in the same manner as in Example 1, and printing was performed. Comparative Example Printing was performed in the same manner as in Example 1, using plain paper instead of the image-receiving sheet of Example 1. The printed sample obtained as described above was left under sunlight and in a Xenon Long Life Fademeter HAL-25X-HCL manufactured by Suga Test Instruments Co., Ltd., and changes in reflection density over time were measured using a Macbeth densitometer. The residual rate of reflection density was calculated from the following formula. Remaining rate = Reflection density after leaving / Reflection density immediately after printing x 10
0 In other words, if the residual rate is less than 100%, fading will occur.
A value of 100% or more indicates black discoloration. The measurement results are shown in Table 2. This clearly shows that the recorded images of the present invention have excellent storage stability.
【表】
(F) 発明の効果
本発明の受像シート上に記録された画像は、従
来の普通紙に記録されたものに比べ保存性が著し
く向上しており、カラーの溶融型熱転写記録の利
点をさらに高める上で本発明の工業的意義は極め
て高いものである。[Table] (F) Effects of the invention Images recorded on the image-receiving sheet of the present invention have significantly improved storage stability compared to those recorded on conventional plain paper, which is an advantage of color melt-type thermal transfer recording. The present invention has extremely high industrial significance in further increasing the
Claims (1)
ク層を設けた転写シートと、該転写シートからの
転写像を受ける受像シートを組み合せてなる熱転
写記録材料において、該転写シートと接する受像
シート面に融点が50℃〜150℃の紫外線吸収剤お
よび／または酸化防止剤を含有する塗工層を設け
たことを特徴とする熱転写記録材料。1. In a thermal transfer recording material consisting of a combination of a transfer sheet having a heat-melting ink layer that can be transferred when heated on one side of a base material, and an image-receiving sheet that receives an image transferred from the transfer sheet, an image-receiving sheet that is in contact with the transfer sheet. A thermal transfer recording material characterized in that a coating layer containing an ultraviolet absorber and/or an antioxidant having a melting point of 50°C to 150°C is provided on the surface.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59129608A JPS618388A (en) | 1984-06-22 | 1984-06-22 | Thermal transfer recording material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59129608A JPS618388A (en) | 1984-06-22 | 1984-06-22 | Thermal transfer recording material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS618388A JPS618388A (en) | 1986-01-16 |
| JPH0412237B2 true JPH0412237B2 (en) | 1992-03-03 |
Family
ID=15013665
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59129608A Granted JPS618388A (en) | 1984-06-22 | 1984-06-22 | Thermal transfer recording material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS618388A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6154982A (en) * | 1984-08-27 | 1986-03-19 | Konishiroku Photo Ind Co Ltd | Thermal transfer recording method and picture-receiving element |
| JPS63194981A (en) * | 1987-02-10 | 1988-08-12 | Fuji Kagakushi Kogyo Co Ltd | Display member provided with surface protection film and manufacture thereof |
| US4855281A (en) * | 1987-10-23 | 1989-08-08 | Eastman Kodak Company | Stabilizer-donor element used in thermal dye transfer |
| JP2020147013A (en) * | 2019-03-15 | 2020-09-17 | 大日本印刷株式会社 | Thermal transfer sheet, thermal transfer image-receiving sheet, intermediate transfer medium and combination of them |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5418752A (en) * | 1977-07-13 | 1979-02-13 | Hitachi Ltd | Heat sensitive recording paper |
| JPS5787989A (en) * | 1980-11-21 | 1982-06-01 | Matsushita Electric Ind Co Ltd | Ink jet recording paper |
| JPS5787988A (en) * | 1980-11-21 | 1982-06-01 | Matsushita Electric Ind Co Ltd | Ink jet recording paper |
| JPS59158289A (en) * | 1983-02-28 | 1984-09-07 | Konishiroku Photo Ind Co Ltd | Image receiving element for heat transfer material |
-
1984
- 1984-06-22 JP JP59129608A patent/JPS618388A/en active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5418752A (en) * | 1977-07-13 | 1979-02-13 | Hitachi Ltd | Heat sensitive recording paper |
| JPS5787989A (en) * | 1980-11-21 | 1982-06-01 | Matsushita Electric Ind Co Ltd | Ink jet recording paper |
| JPS5787988A (en) * | 1980-11-21 | 1982-06-01 | Matsushita Electric Ind Co Ltd | Ink jet recording paper |
| JPS59158289A (en) * | 1983-02-28 | 1984-09-07 | Konishiroku Photo Ind Co Ltd | Image receiving element for heat transfer material |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS618388A (en) | 1986-01-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0342713B1 (en) | Thermal transfer recording material and method | |
| DE2800485A1 (en) | HEAT-SENSITIVE RECORDING MATERIAL | |
| US4614682A (en) | Thermosensitive image transfer recording medium | |
| JPH0153198B2 (en) | ||
| US4755432A (en) | Thermal transfer recording medium | |
| US5268052A (en) | Thermal transfer material and thermal transfer recording method | |
| JPH0412237B2 (en) | ||
| US4756950A (en) | Gradation recording heat-transfer sheet | |
| JPH0561114B2 (en) | ||
| JPH0441918B2 (en) | ||
| JPS60225795A (en) | Thermal transfer recording medium | |
| US5047284A (en) | Thermal transfer recording sheet | |
| GB2200220A (en) | Heat-sensitive color recording material | |
| JPS618386A (en) | Gradated thermal transfer recording material | |
| JPH0377078B2 (en) | ||
| JPS60101078A (en) | Image recording method | |
| JPS6046292A (en) | Thermal recording material | |
| JP2539883B2 (en) | Thermal transfer recording sheet | |
| JPS5822197A (en) | Heat-sensitive recording material | |
| JPH0441919B2 (en) | ||
| JPH0338385A (en) | Thermal transfer recording medium | |
| JPH0473388B2 (en) | ||
| JPH09226260A (en) | Metal gloss thermal transfer recording medium | |
| JPS63151484A (en) | Thermal transfer sheet | |
| JPH03247491A (en) | Heat transfer sheet and thermally transferring method |