JPH0411100A - Flameproof flabby crepe paper - Google Patents

Flameproof flabby crepe paper

Info

Publication number
JPH0411100A
JPH0411100A JP10985490A JP10985490A JPH0411100A JP H0411100 A JPH0411100 A JP H0411100A JP 10985490 A JP10985490 A JP 10985490A JP 10985490 A JP10985490 A JP 10985490A JP H0411100 A JPH0411100 A JP H0411100A
Authority
JP
Japan
Prior art keywords
flame
paper
retardant
decorative
flameproofing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10985490A
Other languages
Japanese (ja)
Inventor
Yoshimitsu Saito
斉藤 由光
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
YAMASA MOMI KIKAKU KK
Original Assignee
YAMASA MOMI KIKAKU KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by YAMASA MOMI KIKAKU KK filed Critical YAMASA MOMI KIKAKU KK
Priority to JP10985490A priority Critical patent/JPH0411100A/en
Publication of JPH0411100A publication Critical patent/JPH0411100A/en
Pending legal-status Critical Current

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  • Paper (AREA)

Abstract

PURPOSE:To obtain the subject uneven-quality paper having improved flameproofing properties and a decorative property full of variety by creping a flameproof paper and then spraying a flamepoofing material thereon so that more flameproofing material may deposit on the above-mentioned creped part. CONSTITUTION:Paper is initially subjected to flameproofing finish and then to crepe treatment due to bending, nicking or crumpling so as to loosen its fibrous tissue. Fluff is given thereto at the same time thereby and bulkiness and stereoscopic feeling are obtained therefor. A solution containing a flameproofing material selected from a flameproofing substance, a flameproofing synthetic resin, a ceramics, etc., is subsequently applied to the above-mentioned modified paper by spraying or coating using a roll, an (air)knife, etc., so that more flameproofing material may deposit on the loosened part than on the other part, thus obtaining the objective paper.

Description

【発明の詳細な説明】 (イ) 産業上の利用分野 壁装材、電燈あるいは電気スタンドのカバ袋、ケース、
かばん等の日用雑貨や身廻品等に利用される素材に関す
る。
[Detailed description of the invention] (a) Industrial fields of use Wall covering materials, cover bags and cases for electric lights or desk lamps,
Concerning materials used for daily necessities such as bags and personal items.

(ロ) 従来の技術 従来、防炎あるいは難燃加工紙およびそれらを基材とし
た加工紙、硬3太c;;ご一ル璧1PXr rl 、球
塊、ろるいは凹凸のデザインのあるもので、基材となる
防炎紙は、平滑で、厚さや諸物性およびその機能例えば
、防炎性において均一性が要求されており。
(b) Conventional technology Conventionally, flame-retardant or flame-retardant treated paper and treated paper based on these, hard 3 thick c; The flame retardant paper used as the base material is required to be smooth and uniform in thickness, physical properties, and functions such as flame retardancy.

当然のことながら、その線に沿ったものとなっていた。Naturally, it was along those lines.

(ハ) 発明が解決しようとする課題 基材となる防炎紙およびその表面加工紙(化粧紙)等は
、非平滑で、厚さや諸物性および機能等において不均一
または不均質的なものとして、変化に富み2毛羽立たせ
、ポリウム感や立体感を与え2機能を変え、より装飾性
のあるものとし、化粧紙としていっそう付加価値を高め
るのが課題である。
(C) Problems to be Solved by the Invention Flameproof paper and its surface-treated paper (decorative paper), etc., which serve as the base material, are non-smooth and non-uniform or heterogeneous in thickness, physical properties, functions, etc. The challenge is to make it more decorative by making it more versatile, by fluffing it, giving it a porium feel and three-dimensional effect, and by changing its functions, thereby increasing its added value as a decorative paper.

に) 課題を解決するための手段 基材となる紙類な屈曲、折れ線や筋引き等による筋立て
、あるいは絞りや揉み等の加工を施して基材の紙類に皺
付けをして、凹凸の変化を与えて立体感をよ<シ、繊維
組織の弛緩により、はぐれによるボリウム感を高め2毛
羽立ちし、防炎性材料や化粧用材料の吸収性あるいは浸
透性をよくし部分的機能を変え、接着剤の利用において
もいっそう接着効果を高めるものである。
2) Means to solve the problem The paper used as the base material can be made to have wrinkles by bending, creases, lines, etc., or by applying processes such as squeezing or rolling to create wrinkles in the paper base material to create unevenness. It gives a three-dimensional effect by changing the texture, and by relaxing the fiber structure, it increases the volume due to peeling and becomes fluffy, improves the absorption or permeability of flame-retardant materials and cosmetic materials, and changes the partial function. It also enhances the adhesive effect when using adhesives.

(ホ)  作     用 基材となる紙類を皺付加工する前、あるいは後工程にお
いて防炎加工を施すが、それは鉱材加工における破損状
態、皺の形成状態によって決めるものである。
(E) Function The paper used as the base material is subjected to flame retardant treatment before or during the post-wrinkling process, but this is determined by the state of damage during mineral processing and the state of wrinkle formation.

紙類な折曲げたり、折筋を入れたり、引きあるいは押動
を刻入するなど、いわゆる筋立てし、凹凸を形成したり
、絞り筋を入れたり、折曲げや屈曲や摺合せを集合した
ような揉み加工により、影響を受けた部分や箇所の繊維
は折損したり1毛羽立ちしたり1組織は弛緩し、いわゆ
る「はぐれた」状態になる。
Paper is folded, creases are made, pulling or pushing motions are carved, etc., so-called creases, unevenness is formed, drawing creases are made, or a combination of folding, bending, and sliding is performed. Due to this rolling process, the fibers in the affected areas or locations may break, become fluffy, or loosen, resulting in a so-called ``separated'' state.

従って、外観上は、厚くなったり、かさだかになったり
、立体感もでてくる。
Therefore, in terms of appearance, it becomes thicker, bulkier, and has a three-dimensional appearance.

また、感触は柔軟になったことが分る。そして機能的に
は、その弛緩部に、他の部分より、多くの各種溶液を吸
収し易くなる。換言すれば、浸透度は高められることに
なり、また付着性あるいは着座性もよくなる。
Also, it can be seen that the feel has become more flexible. Functionally, the relaxed part absorbs more various solutions than other parts. In other words, the degree of penetration will be increased and the adhesion or seating properties will also be improved.

すなわち9例えば、均一な間隙で溶液を塗工した場合で
も溶液溜りが被塗工面に触れるから、その部分は多くの
溶液を吸収して付着濃度は高くなる。
For example, even if the solution is applied with uniform gaps, the solution pool will come into contact with the surface to be coated, so that part will absorb a large amount of the solution and the adhesion concentration will be high.

それらの溶液に、防炎性物質(難燃剤)や、防炎性兼化
粧用材料である合成樹脂類、セラミックス等の防炎性材
料を用いると、防炎性は向上したり、パターンを明確に
し、多彩な外観を与えることにもなる。
If flame retardant substances (flame retardants), synthetic resins that are both flame retardant and cosmetic materials, and flame retardant materials such as ceramics are used in these solutions, the flame retardant properties will be improved and the pattern will be clearer. It also gives it a versatile appearance.

(へ)  実  施  例 坪量約5097−のクラフト紙をメラミン変性ポリリン
酸アンモニウムとポリエチレンイミンの20部混合水溶
液に浸漬し、ピックアツプ量を約100%として乾燥し
防炎処理する。
(f) Example Kraft paper with a basis weight of about 5097 is immersed in a 20-part mixed aqueous solution of melamine-modified ammonium polyphosphate and polyethyleneimine, dried to a pick-up amount of about 100%, and flameproofed.

つぎに、これを補強する意味で、金山のような織布を添
えて、流走方向に交差するように所定の2点間を掴み具
で保持し、その2点間の間隔を狭めて、掴み具を揺動あ
るいは回動して、揉み加工を行って皺付けし、掴み具の
保持を解除して、被加工体を移送する。この操作を順次
繰返して、連続的に皺付けし、添布を分離する。
Next, in order to reinforce this, a gold mine-like woven cloth is attached and held between two predetermined points with a grip so as to cross the running direction, and the distance between the two points is narrowed. The gripping tool is swung or rotated to perform creasing and wrinkle processing, and the holding of the gripping tool is released to transfer the workpiece. This operation is repeated one after another to create continuous wrinkles and separate the attached material.

この皺付加工紙の片面に、ビニルペーストレシン100
部、塩素系難燃性可塑剤(メチルペンタクロロステアレ
ート)  15部、  フタル酸エステル(DOP)6
0部、複合安定剤3部、三酸化ア/チモン7部、トリジ
クロロプロピルホスフェ−)7部。
Apply vinyl paste resin 100 to one side of this wrinkled paper.
15 parts of chlorine-based flame retardant plasticizer (methylpentachlorostearate), 6 parts of phthalate ester (DOP)
0 parts, 3 parts of composite stabilizer, 7 parts of amine trioxide/thimony trioxide, 7 parts of tridichloropropyl phosphate.

水酸化アルミニウム 15部、グレーカラー加工顔料3
部を混合してペースト状とし、ことを約709/イエア
ナイフコーテイングして、いわゆる化粧し、135°か
ら145°Cで1分30秒処理し、さらに1600から
165°Cで1分間処理してゲル化する。
Aluminum hydroxide 15 parts, gray color processing pigment 3
The parts were mixed to form a paste, and then coated with about 709/year knife coating, so-called makeup, and treated at 135° to 145°C for 1 minute and 30 seconds, and then at 1600 to 165°C for 1 minute. Gel.

このようにすると、皺付防燃紙の皺付部分には非皺付部
分より多くのビニル組成物が浸透して。
In this way, more of the vinyl composition penetrates into the wrinkled portions of the wrinkled flame retardant paper than the non-creased portions.

やや黒い滲みの皺筋の大理石模様を形成する。It forms a marbled pattern of wrinkled lines with a slightly black ooze.

以上は実施の1例を示したものであって、これを基本的
な゛ものとして応用し、多様化できる。
The above is an example of implementation, and this can be applied as a basic implementation and diversified.

使用材料について言えば、基材となる紙類は。Regarding the materials used, what kind of paper is the base material?

クラフト紙、包装紙、壁紙用紙、すでに加工した防炎紙
など各種のものが利用できる。
Various materials can be used, including kraft paper, wrapping paper, wallpaper paper, and already processed flame-retardant paper.

防炎性材料としては、ハロゲン(フッ素、 塩素。Flame retardant materials include halogen (fluorine, chlorine).

臭素など)有機化合物2例えば、ヘキサブロモベンゼン
(HBB)、2.2ビス(4−ヒドロキシ−3,5−ジ
ブロモフェニール)プロパン(TEA)、  可W剤と
しては、塩化パラフィン、塩素化脂肪酸エステル、リン
酸化合物としては、無機化合物では。
(bromine, etc.) Organic compounds 2 For example, hexabromobenzene (HBB), 2.2bis(4-hydroxy-3,5-dibromophenyl)propane (TEA); As a W agent, chlorinated paraffin, chlorinated fatty acid ester, As a phosphoric acid compound, it is an inorganic compound.

ポリリン酸アンモニウム、ポリリン酸カルバメート等ノ
リン酸塩、有機化合物では、ポリリン酸アミド、トリス
(モノクロロプロピル)ホスフェート。
Ammonium polyphosphate, polyphosphate carbamate, etc., and organic compounds such as polyphosphoric acid amide and tris (monochloropropyl) phosphate.

トリス(1,3ジクロロプロピル) ホスフェートなど
、可塑剤としては、トリクレジイルホスフェ−)  (
TCP)、  )リオクチルホスフェート (TOP)
Tris (1,3 dichloropropyl) phosphate, etc., as a plasticizer, tricrediyl phosphate) (
TCP), ) lyoctyl phosphate (TOP)
.

トリフェニルフォスフェート(TPP)などがある。Examples include triphenyl phosphate (TPP).

そのほか、無機化合物として、酸化物では、三酸化アン
チモン、水酸化物としては、水酸化アルミニウムなどが
用いられる。
In addition, as inorganic compounds, antimony trioxide is used as an oxide, and aluminum hydroxide is used as a hydroxide.

これらは、その溶解性や分散性等により、水や油剤(可
塑剤)、あるいは合成樹脂溶液に溶解または分散し、こ
のものを含浸加工して基材自体を改質し、あるいは基材
の表面加工を施して化粧用にも使用し得るものである。
Depending on their solubility and dispersibility, they can be dissolved or dispersed in water, oil agents (plasticizers), or synthetic resin solutions, and can be impregnated to modify the base material itself, or the surface of the base material. It can also be processed and used for cosmetic purposes.

合成樹脂類としては、主として熱可塑性合成樹脂2例え
ば、ビニルやポリアミド樹脂や若干可燃性のものであっ
ても防炎加工施すので使用できる。
As the synthetic resins, mainly thermoplastic synthetic resins 2, such as vinyl and polyamide resins, and even slightly flammable materials can be used because they can be flame-retardantly treated.

熱硬化性合成樹脂は、防炎性は比較的によくエマルジョ
ン仕様の場合の組成物としては、メラミン樹脂など併用
し得る。ゴム類等もラテックス仕様などの場合は利用で
きる。
Thermosetting synthetic resins have relatively good flame retardant properties and can be used in combination with melamine resins and the like in emulsion formulations. Rubber materials can also be used if they are made of latex.

つぎに加工法について言えば、皺付けは、折曲げ、折筋
、押動あるいは絞り筋をつけたり、揉み等の加工が利用
できる。
Next, regarding processing methods, wrinkles can be created by bending, creases, pressing or drawing creases, or rubbing.

基材の防炎加工の順序は、基材に皺付加工する前、ある
いは後工程において、また、化粧用加工を施した後でも
実施し得る。
The flame retardant treatment of the base material can be performed before or after the wrinkle treatment on the base material, or even after the cosmetic treatment is applied.

防炎加工および化粧用加工は、それらの溶液に浸漬して
含浸し、吹付けたり、グラビヤロール。
Flame-retardant and cosmetic treatments can be done by dipping in those solutions, impregnating them, spraying them, or gravure rolls.

コーティングロール、ナイフ、あるいはエアナイフ等に
よる塗工が行われる。
Coating is performed using a coating roll, knife, air knife, or the like.

以上のような原材料や加工法によって作製される皺付弛
緩防炎加工紙は、その構成面からみると基材紙に防炎性
材料を付与し、基材自体を改質しただけで、その生地や
外観を活用するもの、またつぎに防炎加工を施した基材
紙の表面に防炎性材料を塗装し、化粧したもの2例えば
、透明、半透明、不透明の無着色あるいは着色体とした
もの。
From the viewpoint of its composition, wrinkled relaxed flame-retardant paper produced using the raw materials and processing methods described above is simply a matter of adding flame-retardant material to the base paper and modifying the base material itself. Those that make use of the fabric or appearance, and those that are coated with a flame-retardant material on the surface of the base paper that has been subjected to flame-retardant treatment.2 For example, transparent, semi-transparent, opaque uncolored or colored materials. What I did.

さらに、また、上記のような構成体のものについて、裏
面が接着剤により接着加工がしにくし・ような場合、さ
らに、その面に防炎加工を施した。平滑または皺付紙を
ラミネートしたものなどが、この発明の皺付弛緩防炎加
工紙となる。
Furthermore, in cases where the back surface of the structure described above was difficult to be bonded with an adhesive, flame retardant treatment was applied to that surface. The wrinkled, relaxed, flame-retardant treated paper of the present invention may be a laminated sheet of smooth or wrinkled paper.

(ト) 発明の効果 基材とする紙類に皺付加工することにより、外観に変化
を与え、加工により影響を受けた部分や箇所の繊維は折
損したり1毛羽立ちしたり1組織は施緩し、いわゆる、
はぐれた状態になる。
(g) Effects of the invention By applying wrinkle processing to the paper used as the base material, the appearance changes, and the fibers in the parts and locations affected by the processing are broken, become fluffy, and the texture is loosened. So-called,
become separated.

このことは、外観上は、厚くなったり、かさだかになっ
たり、立体感がでてくる。
This results in a thicker, bulkier, and three-dimensional appearance.

感触は柔軟になり1機能的には2組織の弛緩部や繊維の
毛羽立ちのところに防炎性材料の吸収や浸透がよくなり
、その部分における付着性、あるいは着座性がよくなり
、濃度は他の部分より高くなる。
The feel becomes softer. 1. Functionally, 2. the absorption and penetration of the flame retardant material improves in the relaxed parts of the tissue and the fluffy areas of the fibers, and the adhesion or seating properties in those areas improves. higher than that part.

すなわち、防炎性はよくなる。In other words, the flame resistance is improved.

そして、化粧用材料を塗工あるいは付与することにより
、皺付部分と非皺付部分に濃淡差を士じ。
Then, by coating or applying a cosmetic material, a difference in shade is created between the wrinkled and non-wrinkled areas.

凹凸とともに模様の多様化ができて装飾性を高め製品の
付加価値を高めることにもなる。
Along with the unevenness, patterns can be diversified, increasing decorativeness and increasing the added value of the product.

Claims (1)

【特許請求の範囲】 1 紙、防炎加工紙あるいは防炎加工を施してから、こ
れを折曲げ、筋立て、あるいは揉み等の皺付加工を施し
て、加工された部分を弛緩し、毛羽立たせ、ボリウム感
および立体感を付加して見掛容積を増大さし、防炎性物
質、防炎性合成樹脂類、あるいはセラミック等のいずれ
か、あるいは複合使用における防炎性材料からなる溶液
を吹付け、ロール、ナイフ、エアナイフ等により塗工し
、その施緩部分により多くの防炎性材料等を充てん、あ
るいは付与し、防炎性および装飾性を高めたことを特徴
とした皺付弛緩防炎加工紙。 2 皺付弛緩防炎加工紙、あるいは化粧紙を防炎性材料
からなる溶液に浸漬して、より多くの防炎性物質を含浸
し、これらの加工紙の非化粧面または裏面に、さらに防
炎加工紙を貼着したことを特徴とした皺付弛緩防炎加工
紙。 3 紙および化粧紙に皺付加工を施したのち、防炎性材
料からなる溶液を吹付け、あるいは塗工して、その加工
された組織の弛緩部分により多くの防炎性材料を付与す
るようにしたことを特徴とする皺付弛緩防炎加工紙。 4 紙および化粧紙に皺付加工を施したのち、防炎性材
料からなる溶液を吹付け、あるいは塗工して、その加工
された組織の弛緩部分に、より多くの防炎性材料を付与
し、あるいは化粧的加工を施し、さらに、その反対面に
も防炎性材料からなる溶液を吹付け、あるいは塗工した
ことを特徴とする皺付弛緩防炎加工紙。
[Claims] 1 Paper, flame-retardant treated paper, or flame-retardant treated paper, and then subjected to wrinkle processing such as folding, creasing, or rolling, to loosen and fluff the processed parts. , increase the apparent volume by adding a sense of volume and three-dimensionality, and spray a solution consisting of flame-retardant substances, flame-retardant synthetic resins, ceramics, etc., or flame-retardant materials in combination. A wrinkle-relaxation prevention product that is characterized by being applied with a roll, knife, air knife, etc., and by filling or applying a large amount of flame-retardant material to the applied part to improve flame-retardancy and decorative properties. Flame processed paper. 2. Dip wrinkled relaxed flame-retardant treated paper or decorative paper in a solution made of flame-retardant material to impregnate more flame-retardant material and apply further flame retardant to the non-decorative side or back side of these treated papers. A wrinkled, relaxed, flame-retardant treated paper that is characterized by having a flame-treated paper attached to it. 3 After the paper and decorative paper are wrinkled, a solution consisting of a flame-retardant material is sprayed or coated to impart more flame-retardant material to the relaxed parts of the processed tissue. A wrinkled, relaxed, flame-retardant treated paper. 4 After applying wrinkle processing to paper and decorative paper, spraying or coating a solution consisting of a flame retardant material to impart more flame retardant material to the relaxed parts of the processed tissue. 1. A wrinkled, relaxed flame-retardant treated paper characterized in that it has been subjected to a decorative or decorative treatment, and the opposite side thereof is also sprayed or coated with a solution of a flame-retardant material.
JP10985490A 1990-04-24 1990-04-24 Flameproof flabby crepe paper Pending JPH0411100A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10985490A JPH0411100A (en) 1990-04-24 1990-04-24 Flameproof flabby crepe paper

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10985490A JPH0411100A (en) 1990-04-24 1990-04-24 Flameproof flabby crepe paper

Publications (1)

Publication Number Publication Date
JPH0411100A true JPH0411100A (en) 1992-01-16

Family

ID=14520874

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10985490A Pending JPH0411100A (en) 1990-04-24 1990-04-24 Flameproof flabby crepe paper

Country Status (1)

Country Link
JP (1) JPH0411100A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06287892A (en) * 1993-03-31 1994-10-11 Nippon Paper Ind Co Ltd Flameproof paper and its production

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06287892A (en) * 1993-03-31 1994-10-11 Nippon Paper Ind Co Ltd Flameproof paper and its production

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