JPH04100535A - Oil in polyhydric alcohol type emulsified composition - Google Patents
Oil in polyhydric alcohol type emulsified compositionInfo
- Publication number
- JPH04100535A JPH04100535A JP21440790A JP21440790A JPH04100535A JP H04100535 A JPH04100535 A JP H04100535A JP 21440790 A JP21440790 A JP 21440790A JP 21440790 A JP21440790 A JP 21440790A JP H04100535 A JPH04100535 A JP H04100535A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- polyhydric alcohol
- fatty acid
- enzyme treated
- treated lecithin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 21
- 150000005846 sugar alcohols Polymers 0.000 title claims abstract description 17
- -1 fatty acid ester Chemical class 0.000 claims abstract description 12
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims abstract description 11
- 102000004190 Enzymes Human genes 0.000 claims abstract description 11
- 108090000790 Enzymes Proteins 0.000 claims abstract description 11
- 239000000787 lecithin Substances 0.000 claims abstract description 11
- 235000010445 lecithin Nutrition 0.000 claims abstract description 11
- 229940067606 lecithin Drugs 0.000 claims abstract description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 10
- 229930195729 fatty acid Natural products 0.000 claims abstract description 10
- 239000000194 fatty acid Substances 0.000 claims abstract description 10
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 4
- 239000000839 emulsion Substances 0.000 claims description 12
- 229930006000 Sucrose Natural products 0.000 claims description 6
- 239000005720 sucrose Substances 0.000 claims description 6
- 230000001804 emulsifying effect Effects 0.000 claims 1
- 239000002537 cosmetic Substances 0.000 abstract description 7
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 229920006395 saturated elastomer Polymers 0.000 abstract description 2
- 150000004671 saturated fatty acids Chemical class 0.000 abstract description 2
- 238000006467 substitution reaction Methods 0.000 abstract description 2
- 150000004670 unsaturated fatty acids Chemical class 0.000 abstract description 2
- 235000021122 unsaturated fatty acids Nutrition 0.000 abstract description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000008719 thickening Effects 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000003349 gelling agent Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- SQUHHTBVTRBESD-UHFFFAOYSA-N Hexa-Ac-myo-Inositol Natural products CC(=O)OC1C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C1OC(C)=O SQUHHTBVTRBESD-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 description 1
- 229960000367 inositol Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
- Colloid Chemistry (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は化粧料用として好適な、多価アルコール中油型
乳化粗球物に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to an oil-in-polyhydric alcohol emulsified coarse sphere suitable for use in cosmetics.
〔従来の技術１
多価アルコ、−ル中油型乳化物が化粧料や医薬用等に用
いられていることは知られている０例えば多価アルコー
ルとショ糖脂肪酸エステル及び多価アルコール脂肪酸エ
ステルを含有せしめた増粘ゲル化剤組成物（特開昭５５
−２５４３０１．多価アルコールとショ糖脂肪酸エステ
ル及び非イオン界面活性剤を加熱混合したゲル状物に油
分を加えて乳化したもの（特開昭５６−５５３０６）等
が知られている。前者は通常便用される化粧品用の油性
基剤に対して増粘及びゲル化を目的として配合するため
のものであって、後者は多価アルコールとして水産基を
３個以上有するものを用い、かつ常温で液状の非イオン
界面活性剤の使用が不可欠である。[Prior art 1] It is known that oil-in-oil emulsions of polyhydric alcohols and alcohols are used for cosmetics, medicines, etc. A thickening gelling agent composition containing
-254301. A gel-like product obtained by heating and mixing a polyhydric alcohol, a sucrose fatty acid ester, and a nonionic surfactant and adding an oil component to emulsify it is known (Japanese Patent Application Laid-Open No. 56-55306). The former is for blending into commonly used cosmetic oil bases for the purpose of thickening and gelling, and the latter uses polyhydric alcohols having three or more aquatic groups, In addition, it is essential to use a nonionic surfactant that is liquid at room temperature.
Ｃ発明が解決しようとする課題］
上記のような従来のものにおいては、前者は最終製品を
得るためには予め増粘ゲル化剤を調製し、これを油性基
材に配合するものであり、後者は３個以上の水酸基を有
する多価アルコールを用いるものであるから、いずれも
使用感触においてべたつき性が高く、いわゆるおさまり
のないものとなる、また界面活性剤の使用量が多く、マ
ツサージクリーム、クレンジング等洗い流したり、拭き
取るものへの利用以外は好ましくないため、その利用範
囲が制約されるという間趙点があった。Problems to be Solved by the Invention] In the conventional products as described above, in the former, in order to obtain the final product, a thickening gelling agent is prepared in advance and this is blended into an oily base material; Since the latter uses a polyhydric alcohol having three or more hydroxyl groups, both have a highly sticky feel and do not have a sticky feel, and also use a large amount of surfactant, making it difficult to use pine surge cream, Since it is undesirable for uses other than washing or wiping, such as cleansing, the scope of its use is restricted.
本発明の目的は、このような従来の多価アルコール中油
型乳化組成物の有する問題点を解決し、べたつき性がな
くおさまりのある使用感を有し。The object of the present invention is to solve the problems of conventional oil-in-polyhydric alcohol emulsion compositions, and to provide a composition that is not sticky and has a smooth feel when used.
各種化粧料として応用範囲の広い多価アルコール中油型
乳化組成物を提供するにある。An object of the present invention is to provide an oil-in-polyhydric alcohol emulsion composition that has a wide range of applications as various cosmetics.
すなわち前記の目的を達成するため、本発明の多価アル
コール中油型乳化組成物は水酸基を２個以上有する多価
アルコール中油型乳化組成物において、ショ糖脂肪酸エ
ステル、酵素処理レシチン又は水素添加酵素処理レシチ
ン、低級アルコール及び又はシリコンを含有せしめたこ
とを特徴とするものである。That is, in order to achieve the above object, the oil-in-polyhydric alcohol emulsion composition of the present invention is an oil-in-polyhydric emulsion composition having two or more hydroxyl groups, which contains sucrose fatty acid ester, enzyme-treated lecithin, or hydrogenated enzyme treatment. It is characterized by containing lecithin, lower alcohol and/or silicone.
本発明において多価アルコールとしては、例えばプロピ
レングリコール、ｌ、３−ブチレングリコール、エチレ
ングリコール、グリセリン、及びジグリセリン、テトラ
グリセリンなどのポリグリセリン、グルコース、マルト
ース、マルチトール、ショ糖、フラクトース、キシリト
ール、イノシトール、ペンクエリスリトール等があげら
れ、その組成比率は５〜６０％（重量以下同じ）の範囲
が好ましい。In the present invention, polyhydric alcohols include, for example, propylene glycol, 1,3-butylene glycol, ethylene glycol, glycerin, and polyglycerols such as diglycerin and tetraglycerin, glucose, maltose, maltitol, sucrose, fructose, xylitol, Examples include inositol, penquerythritol, etc., and the composition ratio thereof is preferably in the range of 5 to 60% (the same below weight).
ショ糖脂肪酸エステルとしては、例えばＣ１２〜１８の
飽和又は不飽和脂肪酸からなるショ糖エステル置換度１
８以下の化合物があげられ、組成比率は０．１〜５．０
％が好ましい。As the sucrose fatty acid ester, for example, a sucrose ester consisting of a C12-18 saturated or unsaturated fatty acid with a degree of substitution of 1
8 or less, and the composition ratio is 0.1 to 5.0.
% is preferred.
レシチンを酵素処理したもの又は更に水素添加したもの
は好ましくは０．０５〜５０％の範囲である。The amount of lecithin treated with an enzyme or further hydrogenated is preferably in the range of 0.05 to 50%.
低級アルコールとしてはエタノール、インプロパツール
があげられ０．１〜２０％の範囲がよい、またシリコン
及びシリコン系界面活性剤として１例えばメチルポリシ
ロキサン、メチルフェニルポリシロキサン、オクタメチ
ルシクロテトラシロギサン、デカメチルシクロペンタン
シロキサン、及びジメチルシロキサン・メチル（ポリオ
キシエチレン）シロキサン共重合体等があげられ、０．
１〜５０％の範囲で適宜配合される。なお使用目的によ
り必要に応じて界面活性剤、水、多糖類などを適宜添加
してもよい。Examples of lower alcohols include ethanol and impropatol, preferably in a range of 0.1 to 20%, and examples of silicone and silicone surfactants include methylpolysiloxane, methylphenylpolysiloxane, octamethylcyclotetrasiloxane, Examples include decamethylcyclopentane siloxane, dimethylsiloxane/methyl(polyoxyethylene)siloxane copolymer, etc.
It is suitably blended in a range of 1 to 50%. Incidentally, a surfactant, water, polysaccharide, etc. may be added as appropriate depending on the purpose of use.
油分としては、炭化水素化合物、高級アルコール高級脂
肪酸モノエステル化合物、二塩基酸高級アルコールジエ
ステル化合物、グリコール高級脂肪酸ジエステル化合物
、動植物又は合成トリグリセライド化合物のｉｌｌ又は
２種以上及び各種高級アルコール、脂肪酸類があげられ
、使用目的に応じ適宜選択して使用する。Examples of oils include hydrocarbon compounds, higher alcohol higher fatty acid monoester compounds, dibasic acid higher alcohol diester compounds, glycol higher fatty acid diester compounds, ill or two or more of animal, plant, or synthetic triglyceride compounds, and various higher alcohols and fatty acids. Select and use as appropriate depending on the purpose of use.
以下本発明の実施例及び比較例をあげて説明する。EXAMPLES The present invention will be described below with reference to Examples and Comparative Examples.
〔実施例１〜３、比較例１〜３ｊ
表−１に示す配合組成で、先ず混合物（Ａ）を７０℃に
加温混合溶解し、これに予め７０’Ｃに加温した混合物
（Ｂ）を徐々に撹拌混合した後冷却し４０℃の時点で（
Ｃ）を徐々に加えながらよく撹拌した。[Examples 1 to 3, Comparative Examples 1 to 3j With the formulation shown in Table 1, the mixture (A) was mixed and dissolved by heating to 70°C, and the mixture (B) was heated to 70°C in advance. After gradually stirring and mixing, the mixture was cooled to 40°C (
C) was gradually added and stirred well.
本発明の実施例１〜３は、安定かっペタツキのないゲル
状の多価アルコール中油型乳化組成物が得られた。一方
比較例１〜３はいずれも乳化せずに分離し、ゲル状の多
価アルコール中油型乳化組成物は得られなかった。In Examples 1 to 3 of the present invention, stable gel-like oil-in-polyhydric alcohol emulsion compositions without stickiness were obtained. On the other hand, in Comparative Examples 1 to 3, the emulsions were separated without being emulsified, and gel-like oil-in-polyhydric alcohol emulsion compositions were not obtained.
表
数字は重量％
【発明の効果］
本発明による多価アルコール中油型乳化組成物は、皮膚
に塗布した際へりつかず、おさまりのある感触が得られ
るので、従来のようにふきとり又は洗い流しを要するも
のへの利用に限られることなく、多価アルコール中油型
乳化組成物の有する長所を生かして広く各種化粧品分野
への応用が可能となる。そして製造に当っては協力な乳
化装！や合成界面活性剤を使用せずに安定したエマルシ
ョンが得られるので極めて有益である。The figures in the table are percentages by weight. [Effect of the invention] The oil-in-polyhydric alcohol emulsion composition of the present invention does not stick to the skin when applied to the skin and provides a soothing feel, so it does not require wiping or rinsing off as in conventional methods. The present invention is not limited to use in cosmetics, but can be widely applied to various cosmetic fields by taking advantage of the advantages of the oil-in-polyhydric alcohol emulsion composition. And we cooperated with the manufacturing process! This is extremely beneficial because stable emulsions can be obtained without the use of surfactants or synthetic surfactants.
特許出願人 株式会社 セブン化学
代理人 弁理士 木 村 芳 男代理人 弁理士
木 村 軍 彦手続補正書（自発）
平成２年９月１７日Patent applicant Seven Chemical Co., Ltd. Agent Yoshio Kimura Patent attorney Gunhiko Kimura Procedural amendment (voluntary) September 17, 1990
Claims (1)
物において、ショ糖脂肪酸エステル、酵素処理レシチン
又は水素添加酵素処理レシチン、低級アルコール及び又
はシリコンを含有せしめたことを特徴とする多価アルコ
ール中油型乳化組成物。An oil-in-polyhydric alcohol emulsion composition having two or more hydroxyl groups, characterized in that it contains sucrose fatty acid ester, enzyme-treated lecithin or hydrogenated enzyme-treated lecithin, a lower alcohol, and/or silicone. Emulsifying composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21440790A JPH04100535A (en) | 1990-08-15 | 1990-08-15 | Oil in polyhydric alcohol type emulsified composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21440790A JPH04100535A (en) | 1990-08-15 | 1990-08-15 | Oil in polyhydric alcohol type emulsified composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04100535A true JPH04100535A (en) | 1992-04-02 |
Family
ID=16655282
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21440790A Pending JPH04100535A (en) | 1990-08-15 | 1990-08-15 | Oil in polyhydric alcohol type emulsified composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04100535A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001206817A (en) * | 1999-11-15 | 2001-07-31 | Shiseido Co Ltd | Oil-in-polyhydric alcohol type thermal substrate |
| JP2002363062A (en) * | 2001-06-01 | 2002-12-18 | Kanebo Ltd | Skin wiping agent composition |
| KR100633022B1 (en) * | 1999-11-15 | 2006-10-11 | 가부시키가이샤 시세이도 | Oil-in-polyhydric alcohol thermal base |
| JP2008290951A (en) * | 2007-05-22 | 2008-12-04 | Mikimoto Pharmaceut Co Ltd | Emulsion composition |
| JP2009126791A (en) * | 2007-11-20 | 2009-06-11 | Kracie Home Products Kk | Oil-in-polyhydric alcohol type emulsified cosmetic |
| JP2010070595A (en) * | 2008-09-16 | 2010-04-02 | Dai Ichi Kogyo Seiyaku Co Ltd | Thickening and gelling agent |
| JP2010518121A (en) * | 2007-02-09 | 2010-05-27 | マクニール−ピーピーシー・インコーポレーテツド | Lotion composition for personal use |
| WO2010082487A1 (en) * | 2009-01-16 | 2010-07-22 | 学校法人日本大学 | Oil-gelling agent comprising reverse worm-like micelles and thickened gel-like composition |
| WO2010122694A1 (en) * | 2009-04-23 | 2010-10-28 | 学校法人日本大学 | Oil gel comprising reverse thread-like micelle |
| WO2021124911A1 (en) * | 2019-12-17 | 2021-06-24 | 国立研究開発法人産業技術総合研究所 | Thickener |
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| JPS6295132A (en) * | 1985-10-21 | 1987-05-01 | Nippon Saafuakutanto Kogyo Kk | Oil-in-polyhydric alcohol emulsion composition |
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| JPS6295132A (en) * | 1985-10-21 | 1987-05-01 | Nippon Saafuakutanto Kogyo Kk | Oil-in-polyhydric alcohol emulsion composition |
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| KR100633022B1 (en) * | 1999-11-15 | 2006-10-11 | 가부시키가이샤 시세이도 | Oil-in-polyhydric alcohol thermal base |
| JP2001206817A (en) * | 1999-11-15 | 2001-07-31 | Shiseido Co Ltd | Oil-in-polyhydric alcohol type thermal substrate |
| JP2002363062A (en) * | 2001-06-01 | 2002-12-18 | Kanebo Ltd | Skin wiping agent composition |
| JP2010518121A (en) * | 2007-02-09 | 2010-05-27 | マクニール−ピーピーシー・インコーポレーテツド | Lotion composition for personal use |
| EP2702980A3 (en) * | 2007-02-09 | 2015-03-11 | Reckitt Benckiser (Brands) Limited | Lotion composition for personal use |
| JP2008290951A (en) * | 2007-05-22 | 2008-12-04 | Mikimoto Pharmaceut Co Ltd | Emulsion composition |
| JP2009126791A (en) * | 2007-11-20 | 2009-06-11 | Kracie Home Products Kk | Oil-in-polyhydric alcohol type emulsified cosmetic |
| JP2010070595A (en) * | 2008-09-16 | 2010-04-02 | Dai Ichi Kogyo Seiyaku Co Ltd | Thickening and gelling agent |
| JP5586026B2 (en) * | 2009-01-16 | 2014-09-10 | 学校法人日本大学 | Oil gelling agent and thickened gel composition comprising reverse string micelle |
| WO2010082487A1 (en) * | 2009-01-16 | 2010-07-22 | 学校法人日本大学 | Oil-gelling agent comprising reverse worm-like micelles and thickened gel-like composition |
| JPWO2010082487A1 (en) * | 2009-01-16 | 2012-07-05 | 学校法人日本大学 | Oil gelling agent and thickened gel composition comprising reverse string micelle |
| WO2010122694A1 (en) * | 2009-04-23 | 2010-10-28 | 学校法人日本大学 | Oil gel comprising reverse thread-like micelle |
| JP5679215B2 (en) * | 2009-04-23 | 2015-03-04 | 学校法人日本大学 | Oil gel consisting of reverse string micelles |
| JPWO2010122694A1 (en) * | 2009-04-23 | 2012-10-25 | 学校法人日本大学 | Oil gel consisting of reverse string micelles |
| WO2021124911A1 (en) * | 2019-12-17 | 2021-06-24 | 国立研究開発法人産業技術総合研究所 | Thickener |
| CN114981380A (en) * | 2019-12-17 | 2022-08-30 | 国立研究开发法人产业技术总合研究所 | Tackifier |
| CN114981380B (en) * | 2019-12-17 | 2023-08-18 | 国立研究开发法人产业技术总合研究所 | Tackifier(s) |
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