JPH0361400A - Production of color filter - Google Patents
Production of color filterInfo
- Publication number
- JPH0361400A JPH0361400A JP1194497A JP19449789A JPH0361400A JP H0361400 A JPH0361400 A JP H0361400A JP 1194497 A JP1194497 A JP 1194497A JP 19449789 A JP19449789 A JP 19449789A JP H0361400 A JPH0361400 A JP H0361400A
- Authority
- JP
- Japan
- Prior art keywords
- thin film
- dye
- dyestuff
- color filter
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 239000010409 thin film Substances 0.000 claims abstract description 50
- 229920000642 polymer Polymers 0.000 claims abstract description 27
- 238000000576 coating method Methods 0.000 claims abstract description 13
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 10
- 239000000758 substrate Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000693 micelle Substances 0.000 claims abstract description 7
- 239000004094 surface-active agent Substances 0.000 claims abstract description 7
- 238000002848 electrochemical method Methods 0.000 claims abstract description 4
- 239000003115 supporting electrolyte Substances 0.000 claims abstract description 4
- 230000003647 oxidation Effects 0.000 claims abstract 2
- 238000007254 oxidation reaction Methods 0.000 claims abstract 2
- 239000002245 particle Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 16
- 239000000049 pigment Substances 0.000 claims description 11
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 239000000975 dye Substances 0.000 abstract description 70
- 230000002542 deteriorative effect Effects 0.000 abstract description 3
- 239000011521 glass Substances 0.000 abstract description 3
- 239000013078 crystal Substances 0.000 abstract 2
- 239000011800 void material Substances 0.000 abstract 2
- 239000010408 film Substances 0.000 description 26
- 239000004973 liquid crystal related substance Substances 0.000 description 18
- 239000002243 precursor Substances 0.000 description 12
- 229920001721 polyimide Polymers 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- 239000011248 coating agent Substances 0.000 description 10
- 238000004070 electrodeposition Methods 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 7
- 239000004642 Polyimide Substances 0.000 description 6
- OXHNLMTVIGZXSG-UHFFFAOYSA-N 1-Methylpyrrole Chemical compound CN1C=CC=C1 OXHNLMTVIGZXSG-UHFFFAOYSA-N 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 239000009719 polyimide resin Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 229920000877 Melamine resin Polymers 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 230000009291 secondary effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 238000004506 ultrasonic cleaning Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 241000282898 Sus scrofa Species 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 1
- 229910001486 lithium perchlorate Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000012791 sliding layer Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
Landscapes
- Optical Filters (AREA)
- Liquid Crystal (AREA)
Abstract
Description
【発明の詳細な説明】
【産業上の利用針！！ｆ１
本発明はカラーデイスプレィ！ｔ！ｉ ａ ＋こ用いる
カラーフィルターの製造方法に関する。[Detailed description of the invention] [Industrial use needle! ! f1 This invention is a color display! T! i a + This invention relates to a method of manufacturing a color filter.
［従来の技術１
水に難溶性もしくは不溶性の色素粒子を電解により荷電
する界面活性剤で取り囲み、ミセルコロイドを形成し、
Ｔ！１解酸化によりミセルを破壊することでアノードＷ
ｉ極上に色素粒子膜を形成する方法によりカラーフィル
ターを製造する方法を我１は発明した（特願昭６３−１
７５６１０）。しかし、該色素薄膜は色素粒子の堆積膜
であるため基板上に物理的に吸着されているにすぎず、
また、色素粒子同志も互いに物理吸着しているに過ぎな
いため、例えば液晶ＴＶのような液晶パネルのカラーフ
ィルターとして採用する場合、パネル化のプロセスにお
いて、強力な超音波洗浄を適用すると一部はがれたりあ
るいは液晶配向処理に必要なラビングにより一部工１１
離するというような膜の密着性に関わる問題が発生した
。[Conventional technology 1] Dye particles that are poorly soluble or insoluble in water are surrounded by a surfactant that is charged by electrolysis to form a micelle colloid,
T! 1 By destroying the micelles through deoxidation, the anode W
I have invented a method for manufacturing color filters by forming a pigment particle film on top of the i-layer (Patent Application 1986-1).
75610). However, since the dye thin film is a deposited film of dye particles, it is merely physically adsorbed onto the substrate.
In addition, since the pigment particles are only physically adsorbed to each other, when used as a color filter for an LCD panel such as an LCD TV, some parts of the pigment particles may peel off when powerful ultrasonic cleaning is applied during the process of making the panel. Some processing may be done by rubbing or rubbing necessary for liquid crystal alignment treatment.
Problems related to the adhesion of the film, such as separation, occurred.
そこでこれらの問題の回ｉ１？Ｊとしては、色素薄膜上
に樹脂等をコーティングする方法が容易に推考される。So what about these problems in i1? As J, a method of coating a resin or the like on the dye thin film is easily considered.
しかしながら、この場合コーティングする樹脂の厚みが
厚いと色素粒子膜は十分ＩＱ 設され、密着性は向上す
るちのの本カラーフィルタの特徴の一つである電解に使
用した電極がそのまま液晶駆動に使用できるというメリ
ットが生かされなくなってしまう。すなわち、色素薄膜
上に厚く樹脂膜が形成されると液晶駆動時に色素薄膜に
よる印加電圧のロスの他に樹脂膜による印加電圧のロス
が生じるため液晶駆動電圧が小さくなり液晶駆動性が低
下してしまうという問題が生しる。However, in this case, if the coating resin is thick, the pigment particle film will have sufficient IQ and the adhesion will improve.One of the features of this color filter is that the electrodes used for electrolysis can be used as they are for driving the liquid crystal. The benefits of this will not be utilized. In other words, if a thick resin film is formed on the dye thin film, when driving the liquid crystal, in addition to the loss of applied voltage due to the dye thin film, there will be a loss of applied voltage due to the resin film, resulting in a decrease in the liquid crystal drive voltage and a decrease in liquid crystal drive performance. There is a problem of putting it away.
−・方、印加電圧を相対的に大きくすることで液晶駆動
電圧の低下をカバーしようとすると、液晶駆動用ＩＣの
耐圧の問題が生じ適切でなかった。- On the other hand, when attempting to compensate for the drop in liquid crystal driving voltage by relatively increasing the applied voltage, a problem arises with the withstand voltage of the liquid crystal driving IC, which is not appropriate.
従って、色素薄膜上に色素薄膜以外の膜を形成しないか
あるいは、形成しても膜厚は可能な限り薄くし、色素薄
膜以外の膜による電圧ロスを最小限度におさえられる方
法で色素′４．膜の密着性を向上させる方法が要求され
ていた。Therefore, the dye '4. There was a need for a method to improve the adhesion of the film.
［発明が解決しようとする課題］
上述のように我々の発明したカラーフィルターを液晶カ
ラーデイスプレィに採用する場合、色素薄膜の密着性が
弱いという問題が発生したが、液晶駆動特性を低下させ
ることなく容易に密着性を向上させることが困難であっ
た。[Problem to be solved by the invention] As mentioned above, when the color filter we invented was used in a liquid crystal color display, there was a problem that the adhesion of the thin dye film was weak, but it was not possible to reduce the liquid crystal drive characteristics. Therefore, it was difficult to easily improve adhesion.
そ５で本発明はそのような課題を解決するためのちので
その目的とするところは、本発明の色素薄膜は色素粒子
の堆積構造であるため膜内には空隙が多いことに着目し
１色素薄膜の粒子内の空隙部にポリマー体組織を形成し
、さら（こ色素薄膜上にちポリマー体組織は形成される
が、ン夜品駆動・Ｉ’ｌ−を低下させない程度に極力薄
く形成することにより、液晶駆動性を低下させることな
く色素薄膜の密着性を向上させる方法を提供することに
ある。Fifth, the purpose of the present invention is to solve such problems by focusing on the fact that the dye thin film of the present invention has a deposited structure of dye particles, so there are many voids within the film. A polymer structure is formed in the voids within the particles of the thin film, and furthermore, the polymer structure is formed on the dye thin film, but it is formed as thinly as possible to the extent that it does not reduce the night product drive and I'l-. Accordingly, it is an object of the present invention to provide a method for improving the adhesion of a dye thin film without reducing liquid crystal drive performance.
［課題を解決するための手段１
本発明のカラーフィルターの製造方法は、水に難溶性ら
しくは不溶性の色素粒子、電解により少なくとも酸化で
きる界面活性剤および支持電解質を基本成分とし、該色
素粒子を界面活性剤で取り囲んだ色素のミセルコロイド
水溶液を調製し、このミセルを電解により破壊し、透明
導電体基板上に色素粒子を析出させ色素薄膜を形成した
後、該色素薄膜内空陵部および色素薄ｌｌｑ上にポリマ
ー体組織を形成することを特徴とする。第１図に本発明
により製造したカラーフィルターの断面を模式％式％
ポリマー体組織の形成法としては、電気化学的方法ある
いは塗布法により形成する。[Means for Solving the Problems 1] The method for producing a color filter of the present invention uses as basic components pigment particles that are hardly soluble in water, a surfactant that can be at least oxidized by electrolysis, and a supporting electrolyte, and the pigment particles are A micelle colloid aqueous solution of a dye surrounded by a surfactant is prepared, the micelles are destroyed by electrolysis, and the dye particles are deposited on a transparent conductive substrate to form a dye thin film. It is characterized by forming a polymer body structure on a thin llq. FIG. 1 shows a schematic cross-section of a color filter manufactured according to the present invention. The polymer structure is formed by an electrochemical method or a coating method.
電気化学的方法としては電着法あるいは電解重合〆去を
用い、色素薄膜を形成した透明導電体表面における透明
導電体を色素粒子との空隙部および色素薄膜内の色素粒
子間空隙部および色素薄膜上にポリマー体組織を形成す
る。なお、色素薄膜上にはポリマー体組織は極力薄く形
成するものとし、色素粒子の密着性が確保できる最低限
のレベルが好ましい。色素膜上の形成される膜厚として
は望ましくは色素薄膜の膜厚をほとんど増やさない程度
がよく、上限は色素薄膜の１／２以内の膜厚が好ましい
と考える。As an electrochemical method, electrodeposition or electrolytic polymerization is used, and the transparent conductor on the surface of the transparent conductor on which the dye thin film is formed is applied to the spaces between the dye particles, the spaces between the dye particles in the dye thin film, and the dye thin film. A polymer body structure is formed on top. The polymer structure should be formed on the dye thin film to be as thin as possible, preferably at a minimum level that can ensure the adhesion of the dye particles. The thickness of the film formed on the dye film is preferably such that the thickness of the dye thin film is hardly increased, and the upper limit is preferably within 1/2 of the thickness of the dye thin film.
塗１５法としては、スビンコーｔ−メ去、ディッピング
法、ロールコート法、カーランコート法、っしキリ印刷
法、スクリーン印刷法、スプレー法などがあり特に限定
はしないが、塗布液はできるだけ希薄な濃度が好ましく
、そのことによりポリマ前駆体あるいはポリマー分子が
透明導電体表面と色素粒子との空隙部および色素薄膜内
の色素粒子間空隙部に十分に含浸し、さらには色素薄膜
上には極力薄くポリマー体組織が形成されるものとする
。15 Coating methods include swine coating, dipping, roll coating, curlan coating, paperback printing, screen printing, and spraying, and are not particularly limited, but the coating solution should be as dilute as possible. The concentration is preferable, so that the polymer precursor or polymer molecules are sufficiently impregnated into the voids between the surface of the transparent conductor and the dye particles and the spaces between the dye particles in the thin dye film, and furthermore, the polymer precursor or polymer molecules are impregnated as thinly as possible onto the thin dye film. It is assumed that a polymer body structure is formed.
また、ポリマー体組織は十分に重合、硬化を促進するた
め、塗布した援用いるポリマ−４１１駆体あるいはポリ
マー分子の性質により必要に応して加熱、紫外線照射等
の処理を行うことが望ましい。Further, in order to sufficiently promote polymerization and curing of the polymer structure, it is desirable to perform treatments such as heating and ultraviolet irradiation as necessary depending on the properties of the applied polymer 411 precursor or polymer molecules.
また、ポリマー１本組織はカラーフィルターに用いる性
格上光の透過性をあまり低下させないものが望ましい。In addition, it is desirable that the single polymer structure does not significantly reduce light transmittance due to the nature of its use in color filters.
［実 施 例１
（実施例１）
対角５インチのガラス基板上に透明電極としてＩＴＯを
スパッタリングにより形成し、さらにフォトリソ法を用
い幅１１００ｕで本Ｃ’１３００本のストライブ状の電
極として形成した。[Example 1 (Example 1) ITO was formed as a transparent electrode on a 5-inch diagonal glass substrate by sputtering, and then a strip-shaped electrode of 1,300 strips with a width of 1,100 μ was formed using photolithography. did.
次に第１Ｐに示す組成の赤、Ｌ３．青の色素（有機顔料
）のミセルコロイド水溶液をそれぞれ作成し１色ごとに
電解成膜した。Next, red having the composition shown in 1st P, L3. Micellar colloid aqueous solutions of blue dyes (organic pigments) were prepared and electrolytically deposited for each color.
第 １ 表
＊
フェロセニルＰＥＧ （同じ化学製）
（電解で酸化、還元できる）
＊２ 臭化リチウム
＊３ アントラキノン系顔料
＊４ 臭素化塩素化鋼フタロシアニン
＊５ α型銅フタロシアニン
電解電位は０．４Ｖ （ｖｓ、Ｓ、Ｃ，Ｅ）とし、電解
時間は色素膜厚が、それぞれ１．Ｏｕｍとなるように調
整した。また、色素、４膜は青、緑、青の繰り返しのス
トライブパターンになるように、電解時に電極を選択的
に通電した。成膜後は１８０℃で３０分焼成した。Table 1 * Ferrocenyl PEG (manufactured by the same chemical) (Can be oxidized and reduced by electrolysis) *2 Lithium bromide *3 Anthraquinone pigment *4 Brominated chlorinated steel phthalocyanine *5 α-type copper phthalocyanine electrolytic potential is 0.4V ( vs, S, C, E), and the electrolysis time is 1. Adjusted so that it was Oum. Further, during electrolysis, the electrodes were selectively energized so that the dye 4 film had a blue, green, blue repeating stripe pattern. After the film was formed, it was baked at 180°C for 30 minutes.
以上の操作により、赤、緑、青の３色の繰り返しのスト
ライブパターンからなる色素ｎｔｌｉを形成した。Through the above operations, a dye ntli consisting of a repeating stripe pattern of three colors of red, green, and blue was formed.
続いて、この色素薄膜を形成した基板を下記に記述する
電着可能なポリマー前駆体溶液中に浸漬し、色素薄膜が
形成されている透明電極を電着用電極として再度利用し
ポリマー前駆体の電着を行なった。Next, the substrate on which the dye thin film has been formed is immersed in the electrodepositable polymer precursor solution described below, and the transparent electrode on which the dye thin film is formed is again used as an electrode for electrodeposition, and the electrodeposition of the polymer precursor is carried out. I got dressed.
ポリマー前駆体溶ン夜はアクリル酸とメラミンを７：３
の割合で含み、イソプロピルアルコール。Polymer precursor solution: 7:3 acrylic acid and melamine
Contains isopropyl alcohol.
ブヂルセロソルブを含む水溶液（株式会社シミズ製）で
あり、アクリル酸＋メラミンが５ｗｔ％含まれるように
濃度調整したものを用いた。An aqueous solution containing butyl cellosolve (manufactured by Shimizu Co., Ltd.) whose concentration was adjusted to contain 5 wt % of acrylic acid + melamine was used.
電着は色素薄膜が形成されている透明電極側をアノード
とし、白金の対向電極間に＋３，５Ｖを印加し５分行な
った。電着後は純水中で３０秒間水洗レスビンドライヤ
ーにより水の振り切り乾燥をした後１８０℃で３０分焼
成した。Electrodeposition was carried out for 5 minutes by using the transparent electrode side on which the dye thin film was formed as the anode, and applying +3.5V between the platinum opposing electrodes. After electrodeposition, the electrodeposition was washed in pure water for 30 seconds and dried by shaking off the water using a resbin dryer, and then baked at 180° C. for 30 minutes.
以上の操作によりアクリル・メラミン重合体が色素膜中
に形成された。また、色素膜上にはＯ０５ｕｍのみ重合
体が形成されたにすぎなかった。Through the above operations, an acrylic/melamine polymer was formed in the pigment film. Moreover, only a polymer of O05um was formed on the dye film.
色素膜内にポリマー体が形成されたか否かは、密着性テ
ストにより確認された。Whether or not a polymer body was formed within the dye film was confirmed by an adhesion test.
すなわち、完成したカラーフィルターのスコッチテープ
のひきはがしによる密着付テストを実施しても色素膜は
全く剥離することはなかった。That is, even when an adhesion test was conducted by peeling off Scotch tape from the completed color filter, the dye film did not peel off at all.
また、アルカリ脱脂液（６０℃）中に浸漬し、超音波洗
浄を試みたが、従来の色素薄膜単体のちのは２０秒で一
部ハクリが生したちのの本実施例のものは、全く問題が
なかった。In addition, we tried ultrasonic cleaning by immersing it in an alkaline degreasing solution (60°C), but some parts of the conventional dye thin film peeled off after 20 seconds, but this example did not show any results. There were no problems.
さらに液晶パネル化プロセスを流動したが全く問題はな
く、ラビング処理でダメージを受けることちなかった。Furthermore, it was passed through the process of making an LCD panel, but there were no problems at all, and there was no damage caused by the rubbing process.
最終的にＴＮ型液晶を用いカラー液晶パネルを作成し、
液晶の駆動特性を確認したが、従来の色素薄膜単体の場
合に比べて何ら差異は認められなく良好な結果が得られ
た。Finally, a color liquid crystal panel was created using TN type liquid crystal,
We checked the driving characteristics of the liquid crystal, and found that there was no difference in comparison to the case of a conventional dye thin film alone, and good results were obtained.
（実施例２）
実施例１と同様に３色の色素薄膜を形成した後この色素
薄膜を形成した基板を電解置台可能なモノマー溶液中に
浸漬し、これをアノードとして電解重合を行なった。(Example 2) After forming dye thin films of three colors in the same manner as in Example 1, the substrate on which the dye thin films were formed was immersed in a monomer solution that could be placed on an electrolytic stand, and electrolytic polymerization was performed using this as an anode.
モノマー溶液は、プロピレンカーボネートを溶媒とし、
０．２ＭのＮ−メチルビロールを含み、支持電解質とし
て０．２Ｍの過塩素酸リチウムも含んでいる。The monomer solution uses propylene carbonate as a solvent,
It contains 0.2M N-methylpyrrole and also contains 0.2M lithium perchlorate as a supporting electrolyte.
Ｎ−メチルビロールの電解重合は白金板を対向電極とし
て′０．０５ｍＡ／ｃｒｎ’の定電流重合で１分行なっ
た。Electrolytic polymerization of N-methylpyrrol was carried out for 1 minute at a constant current of 0.05 mA/crn using a platinum plate as a counter electrode.
電解重合を行なった後は基板を１５０°Ｃで１０分乾燥
した。After electrolytic polymerization, the substrate was dried at 150°C for 10 minutes.
以上の換作によりポリ−Ｎ−メチルピロールが色素膜内
に形成された。また、色素薄膜−Ｌには、０、 ｌｕ
ｍのポリピロールが形成されたにすぎなかった。さらに
ポリ−Ｎ−メチルビロールは通常褐色を呈するが、本実
施例では、膜厚が薄いため、カラーフィルターとしての
光透過性にはほとんど影響を与えなかった。Poly-N-methylpyrrole was formed within the dye film by the above-mentioned modification. In addition, the dye thin film-L contains 0, lu
Only m polypyrrole was formed. Further, although poly-N-methylpyrrole normally exhibits a brown color, in this example, since the film thickness was thin, it had almost no effect on the light transmittance as a color filter.
結果として、色素薄膜の密着性は実施例１と同様に良好
であった。また、本実施例は液晶駆動・［Ｉ［を大幅に
向上させるメリットを（Ｅんだ。As a result, the adhesion of the dye thin film was as good as in Example 1. In addition, this embodiment has the advantage of significantly improving the liquid crystal drive and [I[.
すなわち、ポリ−Ｎ−メチルビロールは導電性有機物質
であり、そのことにより、色素薄膜による電圧ロスが低
減されたことによるものであった。That is, poly-N-methylpyrrole is an electrically conductive organic substance, and as a result, voltage loss due to the dye thin film was reduced.
（実施例３）
実施例１と同様の電着法を実施例１の色素薄膜を１色形
成し焼成するごとに適用したが、実施例１と同等の良好
な結果が得られた。(Example 3) The same electrodeposition method as in Example 1 was applied each time one color of the dye thin film of Example 1 was formed and fired, and good results equivalent to those in Example 1 were obtained.
（実施例４）
実施例１と同様の電着法を実施例１の色素薄膜を１色成
膜し水洗するのみで焼成することなく適用し、これを３
回繰り返すことで３色のカラーフィルターを作成したが
実施例１と同等の良好な結果が得られた。(Example 4) The same electrodeposition method as in Example 1 was applied to form the dye thin film of Example 1 in one color and washing with water without baking was applied.
Three color filters were prepared by repeating the process several times, and good results similar to those in Example 1 were obtained.
（実施例５〉
実施例２と同様の電解重合法を実施例１の色素薄膜を１
色形成し焼成するごとに］０用したが実施例２と同等の
良好な結果が得られた。(Example 5) The same electrolytic polymerization method as in Example 2 was applied to the dye thin film of Example 1.
Each time the color was formed and fired] was used, good results equivalent to those of Example 2 were obtained.
（実施例６）
実施例２と同様の電解重合法を実施例１の色素薄膜を１
色形成し水洗するのみで焼成することなく適用し、こね
を３回繰り返すことで３色のカラーフィルターを作成し
たが実施例２と同等の良好な結果が得られた。(Example 6) The same electrolytic polymerization method as in Example 2 was applied to the dye thin film of Example 1.
Three color filters were made by forming the color and washing with water without baking, and kneading was repeated three times, and good results similar to those in Example 2 were obtained.
（実施例７）
実施例１と同様に３色の色素薄膜を形成した１多この色
素薄膜上にスビンコー１−法により熱硬化望のポリイミ
ド前駆体溶液を塗布した。(Example 7) A polyimide precursor solution to be thermally cured was applied onto the dye thin film formed with three colors in the same manner as in Example 1 by the Svinko 1-method.
ｐ奥硬化型のポリイミド前駆体溶液はチッソ（株）製Ｐ
ＳＩ−Ｇ７４２５ＺＳＡを用いた。固形分濃度が２％に
なるようにエチルカルピトールにより希釈して用いた。The p-hardening type polyimide precursor solution is P manufactured by Chisso Corporation.
SI-G7425ZSA was used. It was diluted with ethyl carpitol so that the solid content concentration was 2%.
塗１５後は３０分風乾し２００°Ｃで３０分間焼成した
。After 15 coats, it was air-dried for 30 minutes and baked at 200°C for 30 minutes.
以上の操作によってポリイミド前駆体の含浸作用により
ポリイミド樹脂が色素薄膜内にも形成され、また色素薄
膜上には０．０５＋１ｍ形成されたにすぎなかった。Through the above operations, polyimide resin was also formed within the dye thin film due to the impregnating action of the polyimide precursor, and the polyimide resin was formed on the dye thin film by only 0.05+1 m.
結果として、色素薄膜の密着性は実施例１と同様に良好
であった。また、液晶駆動性についても同等であった。As a result, the adhesion of the dye thin film was as good as in Example 1. Furthermore, the liquid crystal drive performance was also equivalent.
（実施例８）
実施例ｌと同様に３色の色素薄膜を形成した後この色素
薄膜上にロールコート法により光硬化型のポリイミド前
駆体漬液を塗布した。(Example 8) After forming three color dye thin films in the same manner as in Example 1, a photocurable polyimide precursor dipping solution was applied onto the dye thin films by roll coating.
光硬化型ポリイミド前駆体溶油は宇部興産製Ｐ１−３０
０を用いた。固形分濃度が２％になるようにＮ−メグル
ー２−ピロッドンにより希釈して用いた
塗布後は３０風乾し、１００℃で５分ブレベク後ＵＶ照
射装置によりｌ Ｊ ／ ｃ ｍ’のエネルギの紫外線
を照射した。さらに２００℃で５分間のポストベークし
た。The photocurable polyimide precursor solution is P1-30 manufactured by Ube Industries.
0 was used. After application, it was diluted with N-Meglu 2-Pyrodon so that the solid content concentration was 2%, air-dried for 30 minutes, heated at 100°C for 5 minutes, and then exposed to ultraviolet rays with an energy of l J/cm' using a UV irradiation device. was irradiated. Further, post-baking was performed at 200°C for 5 minutes.
以上の操作によりポリイミド前駆体の含浸作用によりポ
リイミド樹脂が色素薄膜内にも形成されまｔ：色素薄膜
上には０．０８ｕｍ形成されたにすぎなかった。Through the above operations, polyimide resin was also formed within the dye thin film due to the impregnating action of the polyimide precursor, but only 0.08 um of polyimide resin was formed on the dye thin film.
結果として、色素薄膜の密着性は実施例１と同様に良好
であった６また。液晶駆動性についても同様に良好であ
った。As a result, the adhesion of the dye thin film was as good as in Example 16. The liquid crystal drive performance was similarly good.
さらに実施例７．８については形成したポリイミド膜が
液晶配向膜として使用できる副次的るｈ果も見い出した
。すなわち、配向！ｌＸ塗布を工夫すればそのまま密着
性向上処理にも用いることができるというメリットが得
られた。Furthermore, in Examples 7 and 8, a secondary effect was discovered in which the formed polyimide film could be used as a liquid crystal alignment film. Namely, orientation! An advantage was obtained that if the lX coating was modified, it could be used as it was for adhesion improvement treatment.
また、実施例７．８のような塗市法においてちｔ）ｆ
ノ１な材料が適用できるわけであるが１例えば、！を市
して焼成することによりＳ ｎ ０２やＺｎＯのような
導電性酸化物膜が形成できるような有機金属溶液を塗布
剤として用いることにより、色素、１膜に導電性を付与
すれば７夜品駆動性ち大幅に向上できるという大きなメ
リッ１−も期待できる。In addition, in the coating city law such as Example 7.8,
No. 1 material can be applied, but for example,! By using an organometallic solution as a coating agent that can form a conductive oxide film such as Sn02 or ZnO by baking and baking, dyes can be applied for 7 days if conductivity is imparted to one film. The major advantage of this method is that it can significantly improve product drive performance.
［発明の効果］
以上のように本発明により電解により成膜した色素薄膜
の密着性を液晶駆動性を低下させることなく飛躍的に向
−ヒさせることができ、高性能、高信頼性でさらに低コ
ストのカラーフィルターを提供できるこつとなった。[Effects of the Invention] As described above, according to the present invention, the adhesion of the dye thin film formed by electrolysis can be dramatically improved without deteriorating the liquid crystal drive performance, and further improved with high performance and reliability. This became the key to providing low-cost color filters.
また、実施例に示したように、カラーフィルターへの導
電性の付与などの大きな副次的効果ら（号られ、さらに
電解重合による方法は、電子写真感光体の作成法にその
まま適用できる可能性も示唆された。すなわち、色素膜
をキャリア発生層とし、電解重合膜をキャリア梯動層に
適用すればよいことになる。In addition, as shown in the examples, there are significant secondary effects such as imparting electrical conductivity to color filters (No. It was also suggested that the dye film should be used as the carrier generation layer and the electrolytically polymerized film should be used as the carrier sliding layer.
第１図は本発明のカラーフィルターの断面を模式的に示
す図である。
色素粒子
ポリマー組織体
ＴＯ
ガラス基板FIG. 1 is a diagram schematically showing a cross section of a color filter of the present invention. Dye particle polymer organization TO glass substrate
Claims (1)
少なくとも酸化できる界面活性剤および支持電解質を基
本成分とし、該色素粒子が該界面活性剤で取り囲まれた
色素粒子のミセルコロイド水溶液を調製した後、該ミセ
ルを電解酸化により破壊し、導電体基板上に色素粒子を
析出させ色素薄膜を形成する方法を用いたカラーフィル
ターの製造方法において、該色素薄膜を形成した後該色
素薄膜内空隙部および色素薄膜上にポリマー体組織を形
成することを特徴とするカラーフィルターの製造方法。 ２）ポリマー体組織が電気化学的方法により形成される
ことを特徴とする請求項１記載のカラーフィルターの製
造方法。 ３）ポリマー体組織が塗布法により形成されることを特
徴とする請求項１記載のカラーフィルターの製造方法。[Scope of Claims] 1) Micelles of pigment particles whose basic components include pigment particles that are insoluble or sparingly soluble in water, a surfactant that can be at least oxidized by electrolysis, and a supporting electrolyte, and in which the pigment particles are surrounded by the surfactant. In a method for manufacturing a color filter using a method in which a colloidal aqueous solution is prepared, the micelles are destroyed by electrolytic oxidation, and dye particles are deposited on a conductive substrate to form a dye thin film, after forming the dye thin film, A method for producing a color filter, comprising forming a polymer structure in voids within the dye thin film and on the dye thin film. 2) The method for producing a color filter according to claim 1, wherein the polymer structure is formed by an electrochemical method. 3) The method for producing a color filter according to claim 1, wherein the polymer structure is formed by a coating method.
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19449789A JP2707746B2 (en) | 1989-07-27 | 1989-07-27 | Color filter, method of manufacturing the same, and liquid crystal device |
| EP19900113106 EP0407947A3 (en) | 1989-07-12 | 1990-07-09 | Color filter and process for preparing the same |
| KR1019900010544A KR910003426A (en) | 1989-07-12 | 1990-07-12 | Color filter and its manufacturing method |
| US08/183,204 US5399450A (en) | 1989-04-28 | 1994-01-18 | Method of preparation of a color filter by electrolytic deposition of a polymer material on a previously deposited pigment |
| US08/406,263 US5554466A (en) | 1989-04-28 | 1995-03-17 | Color filter and method of preparation |
| US08/468,479 US5705302A (en) | 1989-04-28 | 1995-06-06 | Color filter for liquid crystal display device and method for producing the color filter |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19449789A JP2707746B2 (en) | 1989-07-27 | 1989-07-27 | Color filter, method of manufacturing the same, and liquid crystal device |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0361400A true JPH0361400A (en) | 1991-03-18 |
| JP2707746B2 JP2707746B2 (en) | 1998-02-04 |
Family
ID=16325505
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19449789A Expired - Fee Related JP2707746B2 (en) | 1989-04-28 | 1989-07-27 | Color filter, method of manufacturing the same, and liquid crystal device |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2707746B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03102302A (en) * | 1989-09-18 | 1991-04-26 | Idemitsu Kosan Co Ltd | Color filter and production thereof |
| JPH03271396A (en) * | 1990-03-20 | 1991-12-03 | Seiko Epson Corp | Wet type formation of thin film |
| JPH0481804A (en) * | 1990-07-25 | 1992-03-16 | Idemitsu Kosan Co Ltd | Production of color filter and production and driving method of color liquid crystal panel |
| JPH04342206A (en) * | 1991-05-20 | 1992-11-27 | Seiko Epson Corp | Production of color filter |
| JPH04342207A (en) * | 1991-05-20 | 1992-11-27 | Seiko Epson Corp | Production of color filter |
| US10486909B2 (en) | 2015-10-30 | 2019-11-26 | Koh Young Technology Inc. | Item transfer apparatus, item inspection apparatus, item transfer method, and item inspection method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63243298A (en) * | 1987-03-31 | 1988-10-11 | Idemitsu Kosan Co Ltd | Production of organic thin film |
| JPS63287802A (en) * | 1987-05-20 | 1988-11-24 | Dainippon Printing Co Ltd | Production of color filter |
-
1989
- 1989-07-27 JP JP19449789A patent/JP2707746B2/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63243298A (en) * | 1987-03-31 | 1988-10-11 | Idemitsu Kosan Co Ltd | Production of organic thin film |
| JPS63287802A (en) * | 1987-05-20 | 1988-11-24 | Dainippon Printing Co Ltd | Production of color filter |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03102302A (en) * | 1989-09-18 | 1991-04-26 | Idemitsu Kosan Co Ltd | Color filter and production thereof |
| JPH03271396A (en) * | 1990-03-20 | 1991-12-03 | Seiko Epson Corp | Wet type formation of thin film |
| JPH0481804A (en) * | 1990-07-25 | 1992-03-16 | Idemitsu Kosan Co Ltd | Production of color filter and production and driving method of color liquid crystal panel |
| JPH04342206A (en) * | 1991-05-20 | 1992-11-27 | Seiko Epson Corp | Production of color filter |
| JPH04342207A (en) * | 1991-05-20 | 1992-11-27 | Seiko Epson Corp | Production of color filter |
| US10486909B2 (en) | 2015-10-30 | 2019-11-26 | Koh Young Technology Inc. | Item transfer apparatus, item inspection apparatus, item transfer method, and item inspection method |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2707746B2 (en) | 1998-02-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5554466A (en) | Color filter and method of preparation | |
| JPH0335648B2 (en) | ||
| JPH0361400A (en) | Production of color filter | |
| JPS59114572A (en) | Manufacture of multicolor display | |
| JPS6023832A (en) | Preparation of multicolor display device | |
| JPH0259966B2 (en) | ||
| EP0407947A2 (en) | Color filter and process for preparing the same | |
| JPH0344498A (en) | Production of color filter | |
| JP2707787B2 (en) | Method of forming thin film and method of manufacturing color filter for liquid crystal device | |
| JP2893840B2 (en) | Color filter manufacturing method and color liquid crystal panel | |
| JPS62164730A (en) | Production of polyaniline film | |
| JPH0634809A (en) | Color filter for liquid crystal panel and production thereof | |
| JPH0235402A (en) | Electroconductive composite color filer and manufacture thereof | |
| JPS6023805A (en) | Preparation of colored layer | |
| JP2764962B2 (en) | Manufacturing method of color filter | |
| KR960009734B1 (en) | Processes for producing color display material and color filter | |
| JPH0260164B2 (en) | ||
| JPH03150504A (en) | Production of color filter | |
| JPH04122902A (en) | Production of color filter | |
| JPH11326627A (en) | Color filter | |
| JPH03293635A (en) | Production of color filter | |
| JPH09278487A (en) | Production of conductive particle, production of color filter using the particle, and color filter, display panel and electronic device using the particle | |
| JPH04110901A (en) | Color filter and production thereof and color liquid crystal panel and driving method thereof | |
| JP2906568B2 (en) | Thin film deposition by micellar electrolysis | |
| JPS62124534A (en) | Electrochromic element |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20081017 Year of fee payment: 11 |
|
| LAPS | Cancellation because of no payment of annual fees |