JPH0360848A - Production of 18-8 series austenite stainless steel strip - Google Patents

Production of 18-8 series austenite stainless steel strip

Info

Publication number
JPH0360848A
JPH0360848A JP19679089A JP19679089A JPH0360848A JP H0360848 A JPH0360848 A JP H0360848A JP 19679089 A JP19679089 A JP 19679089A JP 19679089 A JP19679089 A JP 19679089A JP H0360848 A JPH0360848 A JP H0360848A
Authority
JP
Japan
Prior art keywords
strip
stainless steel
slab
nitrogen
austenite stainless
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP19679089A
Other languages
Japanese (ja)
Inventor
Toshiyuki Suehiro
末広 利行
Hidehiko Sumitomo
住友 秀彦
Masanori Ueda
上田 全紀
Shigenori Tanaka
重典 田中
Akio Kasama
昭夫 笠間
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP19679089A priority Critical patent/JPH0360848A/en
Publication of JPH0360848A publication Critical patent/JPH0360848A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B45/00Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
    • B21B45/02Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
    • B21B45/0203Cooling
    • B21B45/0209Cooling devices, e.g. using gaseous coolants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/46Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B3/00Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
    • B21B3/02Rolling special iron alloys, e.g. stainless steel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B9/00Measures for carrying out rolling operations under special conditions, e.g. in vacuum or inert atmosphere to prevent oxidation of work; Special measures for removing fumes from rolling mills

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Continuous Casting (AREA)

Abstract

PURPOSE:To produce the subject strip improved in corrosion resistance without damaging the workability by cooling a cast strip in the range from just below a mold to coiling with nitrogen gas at the time of continuously casting the 18-8 series austenite stainless steel strip. CONSTITUTION:Molten steel 2 is poured between one pair of cooling drums 3 from a tundish 1 to form pool, and solidified shell developed on each peripheral surface of the drums 3 is press-welded at kissing point 4 to make the cast strip 5. This cast strip 5 is sent to a coiling machine 8 with pinch rolls 6 set in a sealing box 7 and coiled and conveyed to the next process. Then, in the sealing box 7, the nitrogen gas having >= about 0.95atm N2 partial pressure and >= about 150Nm<3>/H flow rate, is supplied to cool the cast strip 5. By this method, the strip having concentrated layer of nitrogen on the surface, is continuously obtd., and the high corrosion resistant 18-8 series austenite stainless steel strip is produced without damaging the workability and descaling at the following process is efficiently executed.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は18−8系オーステナイトステンレス薄板の製
造方法に係り、特に鋳片と鋳型内壁面の間に相対速度差
のない、いわゆる同期式連続鋳造プロセスによって鋳造
した製品厚さに近い厚さの鋳片を冷間圧延して、オース
テナイト系ステンレス@薄板を製造する方法に関するも
のである。
[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a method for manufacturing 18-8 series austenitic stainless steel sheet, and in particular a so-called synchronous continuous method in which there is no relative speed difference between the slab and the inner wall surface of the mold. The present invention relates to a method for manufacturing austenitic stainless steel sheet by cold rolling a slab having a thickness close to that of a product cast by a casting process.

〔従来の技術〕[Conventional technology]

連続鋳造法を用いてステンレスfm薄板を製造する従来
の方法は、鋳型を鋳造方向に振動させながら厚さ100
鴻以上の鋳片に鋳造し、得られた鋳片の表面手入れを行
い、加熱炉において1000″C以上に加熱した後、粗
圧延機および仕上圧延機列からなるホットストリップミ
ルにより熱間圧延を施して厚さ数mmのホットストリッ
プとし、さらに必要に応じて焼鈍した後、デスケーリン
グし冷間圧延して最終焼鈍を行うものであった。
The conventional method of manufacturing stainless steel FM thin plates using the continuous casting method is to vibrate the mold in the casting direction and roll it to a thickness of 100 mm.
After casting the slab into slabs with a roughness of 100 lbs. The strip was then processed into a hot strip with a thickness of several mm, and then annealed if necessary, followed by descaling, cold rolling, and final annealing.

このように従来のプロセスにおいては、厚さ10hm+
以上の鋳片を熱間圧延するために、長大なホットストリ
ップミルを必要とし、鋳片の加熱と圧延のために多大な
エネルギーを使用するという問題があった。
In this way, in the conventional process, the thickness is 10hm+
In order to hot-roll the above-mentioned slab, a long hot strip mill is required, and there is a problem in that a large amount of energy is used to heat and roll the slab.

この問題に対して、ホットストリップと同等かあるいは
それに近い厚さの鋳片を連続鋳造によって製造するプロ
セスの研究が進められている。たとえば、「鉄と鋼J 
’85−A197〜”85−A256に特集された論文
に紹介されているような、双ロール法、双ベルト法等、
鋳片と鋳型内壁面間に相対速度差のない同期式連続鋳造
プロセスである。
To address this problem, research is underway on a process for manufacturing slabs with a thickness equal to or close to that of hot strip by continuous casting. For example, "Tetsu to Hagane J
The twin-roll method, the twin-belt method, etc., as introduced in the papers featured in '85-A197~'85-A256,
This is a synchronous continuous casting process with no relative speed difference between the slab and the inner wall of the mold.

特開昭62−21443号公報には双ロール法を用いた
薄板連続鋳造装置が開示されている。
Japanese Unexamined Patent Publication No. 62-21443 discloses a continuous thin plate casting apparatus using a twin roll method.

しかし、これら同期式連続鋳造プロセスを経てステンレ
スfi1m板製品を製造するには、未解決の課題が残さ
れていた。
However, unresolved issues remain in manufacturing stainless steel FI1M plate products through these synchronous continuous casting processes.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

上記双ロール法、双ベルト法等の連続鋳造によってステ
ンレス鋼薄板を製造する場合、従来の鋳造から製品迄の
工程が大幅に省略、短縮される利点がある。一般にステ
ンレス鋼の問題点の一つは塩化物を含む水溶液中におい
て、孔食−隙間腐食等の局部腐食感受性が高い。このた
め新しい耐食材料としてCr、MoあるいはNを高めた
ステンレス鋼が開発されている。これらの元素のうちC
rあるいはMoを高めるとコストアップとなり、汎用材
料としてのメリットがなくなる。
When producing a stainless steel thin plate by continuous casting such as the above-mentioned twin roll method or twin belt method, there is an advantage that the conventional process from casting to the product can be significantly omitted and shortened. Generally speaking, one of the problems with stainless steel is that it is highly susceptible to localized corrosion such as pitting corrosion and crevice corrosion in aqueous solutions containing chlorides. For this reason, stainless steel with increased Cr, Mo, or N content has been developed as a new corrosion-resistant material. Of these elements, C
If r or Mo is increased, the cost will increase and there will be no merit as a general-purpose material.

本発明は、双ロール法等の連続鋳造法により鋳造した薄
帯状鋳片を冷間圧延して18−8系オーステナイトステ
ンレス薄板を製造するに際し、薄板製品の本来の加工性
を損うことなく耐食性を向上させることを目的とする。
The present invention aims to improve corrosion resistance without impairing the original workability of the thin sheet product when manufacturing an 18-8 austenitic stainless steel thin sheet by cold rolling a thin strip cast slab cast by a continuous casting method such as the twin roll method. The purpose is to improve

〔課題を解決するための手段〕[Means to solve the problem]

上記課題は本発明によれば、鋳型壁面が鋳片に同期して
移動する連続鋳造機により薄帯状鋳片に鋳造し、冷間圧
延し、焼鈍を行う工程を含む18−8系オーステナイト
ステンレス薄板の製造方法において、前記鋳型直下から
巻取り迄の領域の前記薄帯状鋳片を窒素ガスを用いて冷
却する工程を含むことを特徴とする18−8系オーステ
ナイトステンレス薄板の製造方法によって解決される。
According to the present invention, the above-mentioned problem can be solved by casting an 18-8 series austenitic stainless steel sheet into a strip-shaped slab using a continuous casting machine in which the mold wall surface moves in synchronization with the slab, cold rolling it, and annealing it. The present invention is solved by a method for manufacturing an 18-8 austenitic stainless steel sheet, which includes a step of cooling the thin strip-shaped slab in the area from directly below the mold to winding using nitrogen gas. .

〔作 用〕[For production]

本発明によれば、双ロール法等を用いて188系オース
テナイトステンレス鋼の薄帯状鋳片を連続鋳造するに際
し、ロール等の鋳型直下から巻取り迄の鋳片が窒素ガス
を用いて冷却されるので、鋳片の表面層に窒素ガスが浸
入して窒素濃化層が形成される。得られた鋳片は、窒素
ガスによって酸化スケールの発生が抑制されているので
、スケールオフされる量が少なく、デスケーリング後も
窒素濃化層が表面に残存する。
According to the present invention, when continuously casting thin strip slabs of 188 series austenitic stainless steel using the twin roll method etc., the slab from directly below the mold such as rolls to winding is cooled using nitrogen gas. Therefore, nitrogen gas penetrates into the surface layer of the slab, forming a nitrogen-concentrated layer. Since the generation of oxide scale in the obtained slab is suppressed by nitrogen gas, the amount of scale removed is small, and a nitrogen-concentrated layer remains on the surface even after descaling.

このようにして表面に窒素濃化層が形成された18−8
系オーステナイトステンレス鋼の薄帯状鋳片を冷間圧延
し、焼鈍と必要に応じて酸洗を行って薄板にすると、鋳
片から薄板までの全圧下率が従来法に比べて著しく低い
ので、薄板製品の表面にも窒素濃化層が残存する。した
がって、製品表面の窒素濃化層により耐孔食性、耐隙間
腐食性等の耐食性向上が図られる。そして、薄板製品の
内層は窒素が濃化されないので、本来の加工性は損われ
ない。
18-8 where a nitrogen-concentrated layer was formed on the surface in this way.
When a thin strip of austenitic stainless steel is cold-rolled, annealed and optionally pickled to form a thin plate, the total reduction from the slab to the thin plate is significantly lower than in the conventional method, so it is possible to A nitrogen-concentrated layer also remains on the surface of the product. Therefore, the nitrogen enriched layer on the surface of the product improves corrosion resistance such as pitting corrosion resistance and crevice corrosion resistance. Furthermore, since the inner layer of the thin sheet product is not enriched with nitrogen, its original workability is not impaired.

本発明において、鋳片の冷却はシールボックス内で行う
のが好ましく、シールボックスは耐熱性の優れたステン
レス鋼等で作られる。ドラムおよび巻取機との境のシー
ルはカーテンシールや内圧を高めにして外気の混入を防
止して行う。冷却雰囲気のN2分圧は、0 、95a 
tm以上とするのが表面の酸化スケールの生成を抑制す
るために好ましく、その流量は150tJm3/ H(
毎時)以上が鋭敏化を防止する冷却速度の確保のため好
ましい。
In the present invention, the slab is preferably cooled in a seal box, and the seal box is made of stainless steel or the like with excellent heat resistance. The boundary between the drum and the winder is sealed by using a curtain seal or by increasing the internal pressure to prevent outside air from entering. The N2 partial pressure of the cooling atmosphere is 0.95a
tm or more is preferable in order to suppress the formation of oxide scale on the surface, and the flow rate is 150 tJm3/H (
per hour) or more is preferable in order to ensure a cooling rate that prevents sensitization.

また本発明では5US304 、 S[l5304L、
 5IIS316等の18−8系オーステナイトステン
レスにその対象を絞ったが、その理由は深絞り加工など
の加工用途として使用される汎用材料の耐食性を改善す
るためである。
In addition, in the present invention, 5US304, S[l5304L,
The purpose of this study was to focus on 18-8 austenitic stainless steels such as 5IIS316, in order to improve the corrosion resistance of general-purpose materials used for processing such as deep drawing.

なお、第1図に示すタンデイツシュ1と冷却ドラム3の
間でも窒素シールを行なうと、より効果的である。
Note that it is more effective to perform nitrogen sealing between the tundish dish 1 and the cooling drum 3 shown in FIG. 1 as well.

〔実施例〕〔Example〕

以下本発明の実施例を図面に基づいて説明する。 Embodiments of the present invention will be described below based on the drawings.

第1図は本発明に係る双ロール法を用いた連続鋳造によ
り薄帯状鋳片を製造する方法を説明する概略断面図であ
る。
FIG. 1 is a schematic cross-sectional view illustrating a method of manufacturing a ribbon-shaped slab by continuous casting using a twin-roll method according to the present invention.

第1図に示すように冷却ドラム(双ロール)3を組込み
薄帯状鋳片5を鋳造し、窒素ガス雰囲気で冷却し、捲取
機8に捲取った。タンデイツシュ1から注入された例え
ばS[l5304の溶鋼2は、一対の冷却ドラム3の間
でプールを形成する。それぞれの冷却ドラム3の周面で
成長した凝固シェルは、キッシングポイント4で圧接さ
れ、薄帯状鋳片5として送り出され、シールボックス7
内に配置されたピンチロール6により捲取機8に送られ
、捲取られて次工程に搬送される。なお、冷却ドラム3
の周面には、クリーニングブラシ9、ドラムコータlO
等を配置する場合がある。上記シールボックス7内には
N2分圧0.95atm以上で流量15ONm’/H以
上の窒素ガスを供給して、鋳片5を冷却した。
As shown in FIG. 1, a cooling drum (twin roll) 3 was installed and a thin strip-shaped slab 5 was cast, cooled in a nitrogen gas atmosphere, and wound up in a winding machine 8. Molten steel 2 of, for example, S[15304] injected from the tandem steel 1 forms a pool between the pair of cooling drums 3. The solidified shells that have grown on the circumferential surface of each cooling drum 3 are pressed together at the kissing point 4 and sent out as a ribbon-shaped slab 5, and then placed in a seal box 7.
The paper is sent to a winding machine 8 by a pinch roll 6 disposed therein, wound up, and transported to the next process. In addition, the cooling drum 3
A cleaning brush 9, a drum coater lO
etc. may be placed. Nitrogen gas was supplied into the seal box 7 at a N2 partial pressure of 0.95 atm or more and a flow rate of 15 ONm'/H or more to cool the slab 5.

第1表に示した成分の5US304供試材1,2.3を
用いてそれぞれ本発明法、比較法及び従来法により薄板
製品を製造した。
Using 5US304 sample materials 1 and 2.3 having the components shown in Table 1, thin plate products were manufactured by the method of the present invention, the comparative method, and the conventional method, respectively.

第2表に、鋳造条件と薄板製品の機械的性質および耐食
性を示す。本発明法および比較法は、薄帯状鋳片をデス
ケーリングした後、0.8 mmに冷間圧延し、最終焼
鈍し、酸洗して薄板製品とし、従来法は鋳片(スラブ)
を4Mに熱間圧延し、デスケーリングした後、0.8 
mmに冷間圧延し、最終焼鈍し、酸洗して薄板製品とし
た。第2表において、耐孔食性はJISGO577に示
されている孔食電位で示し、発錆ランクは35°Cにお
ける0、5%塩化ナトリウム+0.2%過酸化水素溶液
を噴霧し、24h後の発錆状況を示した。
Table 2 shows the casting conditions and the mechanical properties and corrosion resistance of the sheet products. The present invention method and the comparative method descale a thin strip slab, then cold roll it to 0.8 mm, final annealing, and pickling to produce a thin plate product, whereas the conventional method descales a thin strip slab.
After hot rolling to 4M and descaling, 0.8
It was cold-rolled to a thickness of mm, final annealed, and pickled to produce a sheet product. In Table 2, the pitting corrosion resistance is shown by the pitting potential shown in JISGO577, and the rusting rank is shown after 24 hours by spraying 0.5% sodium chloride + 0.2% hydrogen peroxide solution at 35°C. The state of rust is shown.

以下余白 第2表に示すように本発明法により製造した5US30
4i板製品は、耐孔食性が優れ、中性塩化物環境中での
発錆はなく比較法、従来法に比し耐食性が良好であるの
がわかる。しかもその機械的性質は本発明法、比較法、
従来法とも大差はなかった。
5US30 manufactured by the method of the present invention as shown in Table 2 in the margin below.
It can be seen that the 4i board product has excellent pitting corrosion resistance, does not rust in a neutral chloride environment, and has better corrosion resistance than the comparative method and the conventional method. Moreover, its mechanical properties are determined by the method of the present invention, the comparative method,
There was no significant difference from the conventional method.

第2図は鋳片表層からの深さ(ハ)と窒素含有ff1(
%)との関係を示すグラフである。
Figure 2 shows the depth from the surface of the slab (c) and the nitrogen content ff1 (
%).

第2図によれば本発明によって得られた鋳片の表面から
約30n迄は窒素が濃化した濃化層となっているのがわ
かった。
According to FIG. 2, it was found that the slab obtained by the present invention had a nitrogen-concentrated layer up to about 30 nm from the surface.

このような表面の窒素濃化層が薄板製品まで残存し、第
2表に示した如く耐食性の向上に寄与したものと思われ
る。
It is believed that such a nitrogen-concentrated layer on the surface remained even in the thin plate product and contributed to the improvement in corrosion resistance as shown in Table 2.

〔発明の効果〕〔Effect of the invention〕

以上説明した様に本発明によれば表面層に窒素の深化層
を有する薄板を連続的に得ることができるので加工性へ
の影響がなくしかも高耐食性の18−8系オーステナイ
トステンレス薄板を得る。
As explained above, according to the present invention, it is possible to continuously obtain a thin plate having a deepening layer of nitrogen in the surface layer, thereby obtaining an 18-8 series austenitic stainless steel plate that has no influence on workability and has high corrosion resistance.

更に本発明では鋳造中の酸化が抑制され後工程のデスケ
ーリングが能率的となる。
Furthermore, in the present invention, oxidation during casting is suppressed, and descaling in the post-process becomes efficient.

【図面の簡単な説明】 第1図は本発明に係る双ロール法を用いた連続鋳造によ
り薄帯状鋳片を製造する方法を説明する概略断面図であ
り、 第2図は鋳片表層からの深さ(n)と窒素含有il(%
)との関係を示すグラフである。 1・・・タンデイツシュ、   2・・・溶鋼、3・・
・冷却ドラム、 4・・・キッシングポイント、5・・・薄肉鋳片、6・
・・ピンチロール、    7・・・シールボックス、
8・・・捲取機、 9・・・クリーニングブラシ、10・・・ドラムコータ
。 第 図
[Brief Description of the Drawings] Fig. 1 is a schematic cross-sectional view illustrating the method of manufacturing a ribbon-shaped slab by continuous casting using the twin-roll method according to the present invention, and Fig. 2 is a schematic cross-sectional view illustrating a method for manufacturing a ribbon-shaped slab by continuous casting using a twin-roll method according to the present invention. Depth (n) and nitrogen content (%
) is a graph showing the relationship between 1... Tandaitsu, 2... Molten steel, 3...
・Cooling drum, 4. Kissing point, 5. Thin slab, 6.
... Pinch roll, 7... Seal box,
8... Winding machine, 9... Cleaning brush, 10... Drum coater. Diagram

Claims (1)

【特許請求の範囲】 1、鋳型壁面が鋳片に同期して移動する連続鋳造機によ
り薄帯状鋳片に鋳造し、冷間圧延し、焼鈍を行う工程を
含む18−8系オーステナイトステンレス薄板の製造方
法において、 前記鋳型直下から巻取り迄の領域の前記薄帯状鋳片を窒
素ガスを用いて冷却する工程を含むことを特徴とする1
8−8系オーステナイトステンレス薄板の製造方法。
[Scope of Claims] 1. An 18-8 series austenitic stainless steel thin plate comprising the steps of casting into a thin strip slab using a continuous casting machine in which the mold wall surface moves in synchronization with the slab, cold rolling it, and annealing it. A manufacturing method, characterized in that it includes a step of cooling the thin strip-shaped slab in an area from directly below the mold to winding using nitrogen gas.
A method for manufacturing an 8-8 series austenitic stainless steel sheet.
JP19679089A 1989-07-31 1989-07-31 Production of 18-8 series austenite stainless steel strip Pending JPH0360848A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP19679089A JPH0360848A (en) 1989-07-31 1989-07-31 Production of 18-8 series austenite stainless steel strip

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP19679089A JPH0360848A (en) 1989-07-31 1989-07-31 Production of 18-8 series austenite stainless steel strip

Publications (1)

Publication Number Publication Date
JPH0360848A true JPH0360848A (en) 1991-03-15

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JP19679089A Pending JPH0360848A (en) 1989-07-31 1989-07-31 Production of 18-8 series austenite stainless steel strip

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0852165A2 (en) * 1996-12-11 1998-07-08 Sms Schloemann-Siemag Aktiengesellschaft Method and apparatus for producing of coated continuous casting products
KR100562640B1 (en) * 2001-11-20 2006-03-20 주식회사 포스코 coiling method of the stainless steel to control the embrittlement
KR100633030B1 (en) * 1997-12-03 2006-12-22 에스엠에스 데마그 악티엔게젤샤프트 Funnel-shaped mold for continuous metal casting

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0852165A2 (en) * 1996-12-11 1998-07-08 Sms Schloemann-Siemag Aktiengesellschaft Method and apparatus for producing of coated continuous casting products
EP0852165A3 (en) * 1996-12-11 1999-01-07 Sms Schloemann-Siemag Aktiengesellschaft Method and apparatus for producing of coated continuous casting products
KR100633030B1 (en) * 1997-12-03 2006-12-22 에스엠에스 데마그 악티엔게젤샤프트 Funnel-shaped mold for continuous metal casting
KR100562640B1 (en) * 2001-11-20 2006-03-20 주식회사 포스코 coiling method of the stainless steel to control the embrittlement

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