JPH0359134A - Core-sheath type composite yarn - Google Patents
Core-sheath type composite yarnInfo
- Publication number
- JPH0359134A JPH0359134A JP19484389A JP19484389A JPH0359134A JP H0359134 A JPH0359134 A JP H0359134A JP 19484389 A JP19484389 A JP 19484389A JP 19484389 A JP19484389 A JP 19484389A JP H0359134 A JPH0359134 A JP H0359134A
- Authority
- JP
- Japan
- Prior art keywords
- yarn
- core
- sheath
- type composite
- synthetic fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 40
- 239000000919 ceramic Substances 0.000 claims abstract description 29
- 239000010419 fine particle Substances 0.000 claims abstract description 25
- 229920002994 synthetic fiber Polymers 0.000 claims abstract description 13
- 239000012209 synthetic fiber Substances 0.000 claims abstract description 13
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 6
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 6
- 230000005855 radiation Effects 0.000 claims description 13
- 238000007665 sagging Methods 0.000 claims description 6
- 239000012530 fluid Substances 0.000 abstract description 18
- 238000002156 mixing Methods 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 15
- 230000000694 effects Effects 0.000 description 15
- 239000004744 fabric Substances 0.000 description 13
- 238000005338 heat storage Methods 0.000 description 13
- 238000000034 method Methods 0.000 description 11
- 238000010521 absorption reaction Methods 0.000 description 10
- 239000000835 fiber Substances 0.000 description 7
- 230000017525 heat dissipation Effects 0.000 description 7
- 238000010586 diagram Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 229920002292 Nylon 6 Polymers 0.000 description 5
- 229910026551 ZrC Inorganic materials 0.000 description 4
- OTCHGXYCWNXDOA-UHFFFAOYSA-N [C].[Zr] Chemical compound [C].[Zr] OTCHGXYCWNXDOA-UHFFFAOYSA-N 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 230000003405 preventing effect Effects 0.000 description 4
- 206010001497 Agitation Diseases 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- -1 etc. Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- 239000002759 woven fabric Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000002074 melt spinning Methods 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、防寒衣料用として好適な優れた吸熱・蓄熱性
を有する糸条に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a yarn having excellent heat absorption and heat storage properties suitable for use in cold weather clothing.
（従来の技術）
近年、防寒衣料の分野においては、遠赤外線放射能力を
有するセラミックス微粒子を含有させた繊維を使用する
ことにより、保温効果の持続性を高める試みが１例えば
特開昭６２−２３８８１１号公報等で多数提案されてい
る。(Prior art) In recent years, in the field of cold-weather clothing, attempts have been made to increase the sustainability of the heat retention effect by using fibers containing ceramic fine particles that have far-infrared radiation ability. Many proposals have been made in publications such as issues.
しかしながら、このような繊維は、セラミックスという
熱伝導率の高い物質を含有しているため。However, such fibers contain ceramics, a substance with high thermal conductivity.
繊維全体の熱伝導率が高くなり、吸収した熱を外部に放
散しやすいのでセラミックスによる保温効果が十分に発
揮されないという欠点がある。The thermal conductivity of the entire fiber is high, and the absorbed heat is easily dissipated to the outside, so the heat retention effect of ceramics cannot be fully demonstrated.
上記のような欠点を解消するために１本発明者らは特願
昭６３−２５７８７９号において、遠赤外線放射能力を
有する微粒子を合成繊維マルチフィラメント中に含有さ
せた糸条にループやタルミを形成させるとともに、糸条
内に空気層を形成することにより熱の散逸を防ぐ方法を
提案した。In order to eliminate the above-mentioned drawbacks, the present inventors have proposed in Japanese Patent Application No. 63-257879 that loops and sag are formed in a synthetic fiber multifilament containing fine particles capable of emitting far infrared rays. In addition, we proposed a method to prevent heat dissipation by forming an air layer within the yarn.
しかしながら、この方法も、吸収した熱を外部に放射さ
せるという欠点を完全には解消し得ないものであった。However, this method could not completely eliminate the drawback of radiating the absorbed heat to the outside.
すなわち、糸条内に多量の空気層が存在しても。That is, even if there is a large amount of air space within the yarn.
セラミックスを含有したフィラメントが露出しているた
め、蓄熱効果が乏しく、このため、晴天時には太陽エネ
ルギーを吸収するが、曇天に移行直後、吸熱作用がなく
なると同時に、熱の散逸のみが生じるため、急激な温度
変化によりかえって冷感が増大するという欠点があった
。Because the ceramic-containing filament is exposed, it has a poor heat storage effect, and therefore absorbs solar energy during sunny days, but immediately after the weather turns cloudy, the heat absorption effect disappears and only heat dissipation occurs, resulting in rapid However, there was a drawback in that the cold sensation actually increased due to temperature changes.
（発明が解決しようとする課題）
本発明は、上記の欠点を解消し、吸熱性と蓄熱性の両方
とも良好な芯・鞘型複合糸条を提供することを技術的な
課題とするものである。(Problems to be Solved by the Invention) The technical object of the present invention is to eliminate the above-mentioned drawbacks and provide a core-sheath type composite yarn with good heat absorption and heat storage properties. be.
（課題を解決するための手段）
本発明者らは、上記課題を解決するために鋭意研究した
結果、フィラメント中に遠赤外線放射能力を有するセラ
ミックス微粒子を含有させた糸条を芯糸とし、熱伝導率
の低い通常の合成繊維マルチフィラメント糸を鞘糸とし
た芯・鞘型複合糸条とすれば、従来にない優れた吸熱性
と蓄熱性を有する糸条が得られることを知見して本発明
に到達した。(Means for Solving the Problems) As a result of intensive research in order to solve the above problems, the present inventors have found that a filament containing ceramic fine particles having far-infrared radiation ability is used as a core yarn, We discovered that by creating a core-sheath type composite yarn using ordinary synthetic fiber multifilament yarn with low conductivity as a sheath yarn, we could obtain a yarn with unprecedented heat absorption and storage properties. invention has been achieved.
すなわち１本発明は、遠赤外線放射能力を有するセラミ
ックス微粒子を０．１〜２０重量％含有した合成繊維マ
ルチフィラメント糸（糸条Ａ）が主として芯部を形成し
９通常の熱可塑性合成繊維マルチフィラメント系（糸条
Ｂ）が主として鞘部を形成した芯・鞘型複合糸であって
、糸条Ａと糸条Ｂの重量比が２０ ： ８０〜７０ ：
３０であることを特徴とする芯・鞘型複合糸条を要旨
とするものである。That is, 1 the present invention is a conventional thermoplastic synthetic fiber multifilament in which a synthetic fiber multifilament yarn (yarn A) containing 0.1 to 20% by weight of ceramic fine particles having far-infrared radiation ability mainly forms the core portion. The system (yarn B) is a core-sheath type composite yarn mainly forming a sheath part, and the weight ratio of yarn A and yarn B is 20:80 to 70:
The gist is a core-sheath type composite yarn characterized by a fiber diameter of 30.
以下１本発明について詳細に説明する。The present invention will be explained in detail below.
本発明の芯・鞘型複合糸条は、遠赤外線放射能力を有す
るセラミックス微粒子を含有した糸条Ａが主として芯部
を形成しているとともに９通常の熱可塑性合成繊維マル
チフィラメント糸である糸条Ｂが主として鞘部を形成し
ていることが必要である。The core-sheath type composite yarn of the present invention mainly includes yarn A containing ceramic fine particles having far-infrared radiation ability, which forms the core part, and yarn A that is a normal thermoplastic synthetic fiber multifilament yarn. It is necessary that B primarily forms the sheath.
防寒衣料用の糸条としては、セラミックス微粒子を含有
した糸条Ａにより吸収した熱を、曇天時に移行後、すな
わち太陽エネルギーが低下した状態においても外部に放
散させないことが重要である。そのために９本発明の芯
・鞘型複合糸条では。As a yarn for cold-weather clothing, it is important that the heat absorbed by the yarn A containing ceramic fine particles is not dissipated to the outside even after transferring to cloudy weather, that is, even when solar energy is low. For this purpose, the core/sheath type composite yarn of the present invention.
セラミックス微粒子含有マルチフィラメント糸が主とし
て芯部に配され、その周囲が熱伝導率の低い通常の糸条
Ｂのフィラメント群で覆われている。A multifilament yarn containing ceramic fine particles is mainly disposed in the core, and its periphery is covered with a group of ordinary yarn B filaments having low thermal conductivity.
また２本発明糸条の形態は、特に限定されるものではな
く９例えば鞘部を構成する糸条Ｂが芯部を構成する糸条
Ａに撚回状に巻きついたものや。Further, the form of the yarn of the present invention is not particularly limited;9 For example, the yarn B constituting the sheath portion may be twisted around the yarn A constituting the core portion.
鞘部を構成する糸条Ｂのフィラメント群がほとんど無撚
状で開繊部を形成し、芯部を構成する糸条Ａを被覆した
ものがある。There is one in which the filament group of yarn B constituting the sheath portion is almost untwisted and forms a spread portion, which covers the yarn A constituting the core portion.
このような糸条形態において、芯部を構成する糸条Ａの
表面積の約５０％以上が鞘部を構成する糸条Ｂによって
被覆されていれば９本発明の糸条とみなすことができる
。In such a yarn form, if approximately 50% or more of the surface area of the yarn A forming the core portion is covered by the yarn B forming the sheath portion, it can be considered as the yarn of the present invention.
また、上記鞘部を構成する糸条Ｂは、フィラメント間、
特に芯部糸条Ａのフィラメント群との間に空隙を有して
いることが好ましい。In addition, the thread B constituting the sheath part is between the filaments,
In particular, it is preferable to have a gap between the core yarn A and the filament group.
特に、セラミックス微粒子を含有した糸条Ａを通常の糸
条Ｂのフィラメント群で覆うとともに。In particular, yarn A containing ceramic fine particles is covered with a group of ordinary yarn B filaments.
糸条全体にループやタルミ及び交絡を多数形成した芯・
鞘型複合糸条とし、フィラメント間に微小空間を多数形
成すれば、糸条Ａで吸収した熱がこの微小空間内で滞留
することとなり、外部への熱の放散が防止され、蓄熱効
果を一層大きくすることができる。A core with many loops, sagging, and entanglements throughout the yarn.
If the sheath-type composite yarn is used and many micro spaces are formed between the filaments, the heat absorbed by the thread A will stay in these micro spaces, preventing heat dissipation to the outside and further enhancing the heat storage effect. Can be made larger.
本発明でいう遠赤外線放射能力とは、遠赤外線以外の波
長領域の電磁波を吸収後、遠赤外線に変換して放射する
能力のことである。このような能力を有するセラミック
スとしては、マンガン、亜鉛、鉄、銅、コバルト等の酸
化物及びこれらの混合物、ジルコニウム、ハフニウム、
ケイ素、ホウ素、タンタル等の酸化物および炭化物を挙
げることができる。The far-infrared radiation ability as used in the present invention refers to the ability to absorb electromagnetic waves in a wavelength range other than far-infrared rays, convert them into far-infrared rays, and then radiate the same. Ceramics with this ability include oxides of manganese, zinc, iron, copper, cobalt, etc., and mixtures thereof, zirconium, hafnium,
Oxides and carbides of silicon, boron, tantalum and the like can be mentioned.
本発明の芯・鞘型複合糸条において、主として芯部を形
成する糸条Ａに含有させる遠赤外線放射能力を有するセ
ラミックス微粒子の量は、０．１〜２０重量％であるこ
とが必要であり、１〜１５重量％がより好ましい。この
含有率が０．１重量％未満では目的とする吸熱効果が十
分に得られず、一方。In the core-sheath type composite yarn of the present invention, the amount of ceramic fine particles having far-infrared radiation ability to be contained in the yarn A that mainly forms the core portion must be 0.1 to 20% by weight. , 1 to 15% by weight is more preferable. On the other hand, if this content is less than 0.1% by weight, the desired endothermic effect cannot be sufficiently obtained.
２０重量％を超えると、フィラメントの強伸度が低下す
るので好ましくない。If it exceeds 20% by weight, the strength and elongation of the filament decreases, which is not preferable.
セラミックス微粒子を含有した糸条Ａは、ポリアミド、
ポリエステル、レーヨン、アセテート等の繊維を製造す
る際に、セラミックス微粒子を紡糸以前の工程で混合し
た後、紡糸するブレンド法や、セラミックス微粒子を含
有したポリマーが芯部となり、含有しないポリマーが鞘
部となるように紡糸する複合紡糸法等によって得ること
ができる。The yarn A containing ceramic fine particles is made of polyamide,
When producing fibers such as polyester, rayon, acetate, etc., there are blending methods in which fine ceramic particles are mixed in a process before spinning and then spun, or a polymer containing fine ceramic particles becomes the core and a polymer that does not contain it forms the sheath. It can be obtained by a composite spinning method, etc., in which the fibers are spun in such a manner that
また、糸条Ａの周囲を被覆する熱伝導率の低い通常の糸
条Ｂとしては１例えばポリエステル系。Further, as the ordinary yarn B having a low thermal conductivity and covering the periphery of the yarn A, for example, polyester is used.
ポリアミド系、アクリル系のマルチフィラメント糸を挙
げることができる。糸条Ｂは、なま糸文は捲縮糸のいず
れでもよいが、捲縮糸の方が、フィラメント自体のクリ
ンプ形態に起因するきめ細かい空間が形成され、蓄熱効
果が向上するので好ましい。Examples include polyamide-based and acrylic-based multifilament yarns. The yarn B may be either a flat yarn or a crimped yarn, but a crimped yarn is preferable because fine spaces are formed due to the crimp form of the filament itself and the heat storage effect is improved.
本発明の芯・鞘型複合糸条を構成する糸条Ａと糸条Ｂの
重量比は、２０：８０〜７０ ： ３０であることが必
要であり、３０ニア０〜６０ ： ４０であることがよ
り好ましい。糸条Ａの比率が上記範囲より少なくなると
、遠赤外線放射能力を有するセラミックス微粒子含有フ
ィラメントによる吸熱効果が満足に得られず、一方、糸
条Ａの比率が上記範囲より大きくなると、鞘部を構成す
る糸条で芯部を構成する糸条を覆いきれなくなり、この
ため、外部への熱の放散を防ぐ効果が減少するので好ま
しくない。The weight ratio of yarn A and yarn B constituting the core-sheath type composite yarn of the present invention must be 20:80 to 70:30, and 30:0 to 60:40. is more preferable. If the ratio of yarn A is less than the above range, a satisfactory heat absorption effect by the filament containing ceramic fine particles having far-infrared radiation ability cannot be obtained. On the other hand, if the ratio of yarn A is higher than the above range, the sheath part This is not preferable because the threads constituting the core cannot be completely covered by the threads forming the core, which reduces the effect of preventing heat dissipation to the outside.
次に１本発明を図面に基づいて説明する。Next, one embodiment of the present invention will be explained based on the drawings.
第１図は１本発明の芯・鞘型複合糸条の一実施態様を示
す側面模式図である。第１図において。FIG. 1 is a schematic side view showing an embodiment of the core-sheath type composite yarn of the present invention. In FIG.
複合糸Ｙ１は、遠赤外線放射能力を有するセラミックス
微粒子を含有した糸条Ａと通常の糸条Ｂで構成されてお
り、糸条Ａに糸条Ｂが撚回状に巻きついたいわゆるカバ
リング糸の形態をとっている。Composite yarn Y1 is composed of yarn A containing ceramic particles capable of emitting far infrared rays and ordinary yarn B, and is a so-called covering yarn in which yarn B is twisted around yarn A. It takes a form.
第２図は、他の実施態様を示す側断面模式図である。第
２図において、複合糸Ｙ２は、糸条Ｂが開繊状態で糸条
Ａを被覆した開繊被覆部ｌと、フィラメントのズレや素
抜けを防ぐための交絡部２を有している。FIG. 2 is a schematic side sectional view showing another embodiment. In FIG. 2, the composite yarn Y2 has a spread covering part 1 in which the thread B covers the thread A in an opened state, and an intertwining part 2 for preventing the filament from slipping or falling through.
次に、第３図は、ループやタルミ及び交絡が形成されて
いる芯・鞘型複合糸条の一実施態様を示す側面模式図で
ある。第３図において、複合糸Ｙ。Next, FIG. 3 is a schematic side view showing an embodiment of a core-sheath type composite yarn in which loops, sagging, and entanglements are formed. In FIG. 3, composite yarn Y.
は、糸条Ａが芯部、糸条Ｂが鞘部に配されており。The thread A is arranged in the core part and the thread B is arranged in the sheath part.
また、糸条には多数のループやタルミが形成され。In addition, many loops and sag are formed in the yarn.
フィラメント間には微小空間３が多数存在している。A large number of micro spaces 3 exist between the filaments.
次に９本発明の芯・鞘型複合糸条の製法例について説明
する。Next, an example of the manufacturing method of the core/sheath type composite yarn of the present invention will be described.
第４図は、第１図で示した複合糸Ｙ１を製造するための
概略工程図である。第４図において、パーン４から引出
された遠赤外線放射能力を有するセラミックス微粒子を
含有した糸条Ａは、フィードローラ５を経て中空スピン
ドル６に導かれる。FIG. 4 is a schematic process diagram for manufacturing the composite yarn Y1 shown in FIG. 1. In FIG. 4, yarn A containing ceramic fine particles having far-infrared radiation ability drawn out from a pirn 4 is guided to a hollow spindle 6 via a feed roller 5.
一方、中空スピンドル６に装着した鞘糸ボビンから引き
出された糸条Ｂは、鞘糸ボビンの回転によって糸条Ａに
巻付きつき、複合糸Ｙ、としてパッケージ７に巻き取ら
れる。On the other hand, the yarn B pulled out from the sheath yarn bobbin attached to the hollow spindle 6 is wound around the yarn A by the rotation of the sheath yarn bobbin, and is wound into the package 7 as a composite yarn Y.
第５図は、第２図で示した複合糸Ｙ２を製造するための
概略工程図である。第５図において、パーン８から引出
された糸条Ｂは、フィードローラ９を経て流体処理ノズ
ル１０に供給される。FIG. 5 is a schematic process diagram for manufacturing the composite yarn Y2 shown in FIG. 2. In FIG. 5, yarn B pulled out from the pirn 8 is supplied to a fluid treatment nozzle 10 via a feed roller 9.
一方、パーン４から引出された遠赤外線放射能力を有す
るセラミックス微粒子を含有した糸条Ａは、フィードロ
ーラ１１を経て流体処理ノズルＩＯに供給され、流体処
理ノズル１０で糸条Ｂとともに流体交絡処理が施された
後、デリベリローラ１２で複合糸Ｙ２として引取られる
。On the other hand, the yarn A containing ceramic fine particles having far-infrared radiation ability drawn out from the pirn 4 is supplied to the fluid treatment nozzle IO through the feed roller 11, and is subjected to fluid entanglement treatment together with the yarn B in the fluid treatment nozzle 10. After being applied, the composite yarn Y2 is taken off by the delivery roller 12.
上記の流体処理ノズルＩＯとは、糸条を開繊する能力と
交絡させる能力の両方を兼備したものをいう。糸条Ａよ
り糸条Ｂのオーバーフィード率を大きくして流体処理ノ
ズル１０に供給することにより。The above-mentioned fluid treatment nozzle IO has both the ability to open the yarn and the ability to entangle the yarn. By supplying yarn B to the fluid treatment nozzle 10 at a higher overfeed rate than yarn A.
糸条Ｂは流体処理ノズル１０内でより大きく開繊され、
糸条Ａを被覆することになる。また、同時に。The yarn B is opened more widely in the fluid treatment nozzle 10,
This will cover yarn A. Also, at the same time.
糸条Ｂの糸長は、糸条Ａのそれよりも長いため。The yarn length of yarn B is longer than that of yarn A.
たるみが生じて適度な空隙が形成される。Sagging occurs and appropriate voids are formed.
なお、上記のように、芯・鞘構造の糸条とするためには
、［ね糸条Ｂのオーバーフィード率を７％以下、セラミ
ックス微粒子を含有した糸条Ａのオーバーフィード率を
２％以下とし、かつ２両者のオーバーフィード率の差を
３％〜５％とすることが好ましい。As mentioned above, in order to obtain a yarn with a core-sheath structure, It is preferable that the difference in overfeed rate between the two is 3% to 5%.
また、第６図は、第３図で示したループやタルミを有す
る芯・鞘型複合糸条を製造するための概略工程図である
。第６図において、パーン８から引出された糸条Ｂは、
フィードローラ１３を経て仮撚域に送り込まれ、フィー
ドローラ１３とデリベリローラ１６との間で仮撚スピン
ドル１５により加熱されつつヒータ１４で熱固定され、
デリベリローラ１６を経て所定のオーバーフィード率で
流体撹乱処理ノズル１７へ供給される。Moreover, FIG. 6 is a schematic process diagram for manufacturing the core-sheath type composite yarn having the loops and sag shown in FIG. 3. In FIG. 6, the yarn B pulled out from the pirn 8 is
It is fed into the false twisting area via the feed roller 13, heated by the false twist spindle 15 between the feed roller 13 and the delivery roller 16, and heat-fixed by the heater 14.
The fluid is supplied to the fluid disturbance processing nozzle 17 via the delivery roller 16 at a predetermined overfeed rate.
一方、バーン４から引出されたセラミックス微粒子を含
有した糸条Ａは、フィードローラ１８を経て所定のオー
バーフィード率で流体撹乱処理ノズル１７へ供給され、
糸条Ｂの仮撚加工糸とともに流体撹乱処理された後、デ
リベリローラ１９によりループ毛羽を有する複合糸Ｙ、
として引取られる。On the other hand, the yarn A containing ceramic fine particles drawn out from the burn 4 is supplied to the fluid disturbance processing nozzle 17 at a predetermined overfeed rate via the feed roller 18.
After being subjected to fluid agitation treatment together with the false twisted textured yarn of yarn B, the composite yarn Y having loop fuzz is delivered by the delivery roller 19.
It will be taken over as.
上記の流体撹乱処理ノズルとしては１例えば特公昭３４
−８９６９号公報や特公昭３５−１６７３号公報等に記
載されているような、所謂タスランノズル等が使用され
る。As the above-mentioned fluid disturbance treatment nozzle, for example, 1
A so-called Taslan nozzle, etc., as described in Japanese Patent Publication No. 35-1673, etc., is used.
また９本発明でいうオーバーフィード率は。9. The overfeed rate in the present invention is as follows.
によって算出されるものである。（ａ：流体撹乱処理ノ
ズルに供給される糸の速度、ｂ二流体攪乱処理ノズルか
ら引取られる糸の速度）
ループやタルミを有する芯・鞘型複合糸条を製造するた
めには、上記において、フィードローラ１８及びデリベ
リローラー６の周速度をデリベリローラー９のそれより
速く設定し、かつ、フィードローラー８よりデリベリロ
ーラー６の周速度を速く設定すればよく、このように設
定することによって、糸条Ａが芯部、糸条Ｂが鞘部を形
成した芯・鞘構造を呈し、かつ、多数のループ毛羽を有
する複合糸となすことができる。また、流体撹乱処理を
施す際のオーバーフィード率は、糸条Ａより糸条Ｂが概
ね７％以上大きくなるように設定するのが好ましい。It is calculated by (a: speed of the yarn supplied to the fluid agitation treatment nozzle, b speed of the yarn taken off from the two-fluid agitation treatment nozzle) In order to manufacture a core-sheath type composite yarn having loops and sag, in the above, The circumferential speed of the feed roller 18 and the delivery roller 6 may be set faster than that of the delivery roller 9, and the circumferential speed of the delivery roller 6 may be set faster than that of the feed roller 8. , it can be made into a composite yarn exhibiting a core-sheath structure in which yarn A forms a core portion and yarn B forms a sheath portion, and has a large number of loop fuzz. Further, it is preferable that the overfeed rate when performing the fluid disturbance treatment is set so that yarn B is approximately 7% or more larger than yarn A.
（作 用）
本発明の芯・鞘型複合糸条は、芯部における吸熱作用と
鞘部における熱の放散防止作用を有している。(Function) The core-sheath type composite yarn of the present invention has a heat absorbing effect in the core portion and a heat dissipation preventing effect in the sheath portion.
すなわち、鞘部を構成する通常の糸条Ｂの熱伝導率が、
芯部を構成する遠赤外線放射能力を有するセラミックス
微粒子を含有した糸条Ａよりはるかに低く、シかも鞘部
のフィラメント群の空隙が緻密に形成されているため相
乗的に断熱作用を向上させることができる。In other words, the thermal conductivity of the normal thread B constituting the sheath part is
The heat insulating effect is much lower than that of the yarn A containing ceramic fine particles with far-infrared radiation ability, which constitutes the core, and synergistically improves the heat insulation effect because the voids between the filament groups in the sheath are densely formed. I can do it.
この作用は、特に晴天から曇天への移行の際に大いに発
揮される。一般に、晴天時には十分なエネルギーが与え
られるため、同時に熱の放散が行われていても温度低下
はほとんど生じないが、曇天時には熱エネルギーの吸収
量より放散量の方が大きくなり、温度低下は避けられな
い。この現象は、糸条全体がセラミックス微粒子を含ん
だマルチフィラメント糸のみで構成された場合により顕
著に現われる。ところが１本発明のような構成を有する
糸条によって製編織された布帛は、上記のごとき熱エネ
ルギーの低下時に熱の放散に伴う衣服内温度もしくは体
感温度の急激な低下を抑制することができる。This effect is particularly noticeable when the weather changes from clear to cloudy. In general, when it is sunny, sufficient energy is given, so even if heat is dissipated at the same time, there is almost no temperature drop, but on cloudy days, the amount of heat energy dissipated is greater than the amount absorbed, and a temperature drop is avoided. I can't. This phenomenon becomes more noticeable when the entire thread is composed only of multifilament threads containing ceramic fine particles. However, a fabric knitted and woven using yarn having the structure of the present invention can suppress a sudden drop in the internal temperature of the garment or the sensible temperature due to heat dissipation when the thermal energy decreases as described above.
特に、糸条にループやタルミ及び交絡が形成された芯・
鞘型複合糸条においては、ループ毛羽によってフィラメ
ント間に多数の微小空間が形成されているため、熱の対
流は糸条内で起こり、微小空間が吸収した熱を溜める蓄
熱作用を向上させることができる。In particular, cores and yarns with loops, sagging, and entanglements are
In the sheath-type composite yarn, many micro spaces are formed between the filaments by the loop fluff, so heat convection occurs within the yarn, improving the heat storage effect of storing the heat absorbed by the micro spaces. can.
（実施例） 次に９本発明を実施例により具体的に説明する。(Example) Next, the present invention will be specifically explained using examples.
なお、吸熱性と蓄熱性の評価は１次のような方法にて行
った。Note that the evaluation of heat absorption and heat storage properties was performed using the following method.
（１）吸熱性 室温２０℃、湿度６０％の恒温恒湿室内において。(1) Endothermic property In a constant temperature and humidity room with a room temperature of 20°C and a humidity of 60%.
エネルギー源として５００Ｗの松下電器社製ＲＥＦラン
プを用い、エネルギー源と布帛間距離を１ｍとし、ＲＥ
Ｆランプ照射後１０分経過したときの布帛表面温度を測
定した。A 500W REF lamp manufactured by Matsushita Electric Co., Ltd. was used as the energy source, and the distance between the energy source and the fabric was 1m.
The surface temperature of the fabric was measured 10 minutes after the F lamp irradiation.
（２）蓄熱性
上記で１０分照射後、ＲＥＦランプを１００Ｗのものに
切り替え、ＲＥＦランプを照射しながら、布帛表面温度
が３℃低下するのに要する時間を測定した。(2) Heat storage properties After 10 minutes of irradiation as described above, the REF lamp was switched to a 100 W one, and while irradiating with the REF lamp, the time required for the fabric surface temperature to decrease by 3° C. was measured.
実施例１，２．比較例１〜８
炭化ジルコニウム微粒子を０．５．０．７．２０及び２
５重量％含有したナイロン６又はポリエチレンテレフタ
レートマスターチップを溶融混合法で作製し。Examples 1 and 2. Comparative Examples 1 to 8 Zirconium carbide fine particles of 0.5.0.7.20 and 2
A nylon 6 or polyethylene terephthalate master chip containing 5% by weight was prepared by a melt mixing method.
次いで、このマスターチップとナイロン６又はポリエチ
レンテレフタレートとを１０ ： ９０の重量比で芯・
鞘複合糸を紡糸可能な溶融紡糸機で押し出すことにより
、炭化ジルコニウム微粒子を含有したポリマーが芯部に
配された。炭化ジルコニウム微粒子含有率０．０５．０
．０７．２．０及び２．５重量％のマルチフィラメント
糸を得た。Next, this master chip and nylon 6 or polyethylene terephthalate were mixed into a core at a weight ratio of 10:90.
By extruding the sheath composite yarn using a melt spinning machine capable of spinning, a polymer containing fine zirconium carbide particles was placed in the core. Zirconium carbide fine particle content 0.05.0
．． 07.2.0 and 2.5% by weight multifilament yarns were obtained.
上記で得た未延伸糸を延伸して得られた各種マルチフィ
ラメント糸（糸条Ａ）と、セラミックス微粒子を含有し
ていないナイロン６及びポリエステルマルチフィラメン
ト糸（糸条Ｂ）を使用して。Using various multifilament yarns (Yarn A) obtained by drawing the undrawn yarn obtained above, and nylon 6 and polyester multifilament yarns (Yarn B) that do not contain ceramic fine particles.
実施例１及び比較例２〜４は第４図、実施例２及び比較
例５〜８は第５図に示した加工工程にしたがい、第１表
及び第２表に示した条件で加工して第３表及び第４表に
示した槽底の複合糸条を得た。Example 1 and Comparative Examples 2 to 4 were processed according to the processing steps shown in Figure 4, and Example 2 and Comparative Examples 5 to 8 were processed under the conditions shown in Tables 1 and 2 according to the processing steps shown in Figure 5. Composite yarns with tank bottoms shown in Tables 3 and 4 were obtained.
なお、比較例１は、スピンドル回転数２００Ｏｒｐｍ、
撚数３００Ｔ／Ｍで合撚することによって得た。In addition, in Comparative Example 1, the spindle rotation speed was 200 Orpm,
It was obtained by combining and twisting at a twist number of 300 T/M.
次いで、実施例１及び比較例１〜４で得られた糸条を各
々単独で経糸、緯糸の両方に用いて、経糸密度１２０本
／ ２．５４ｃｍ、緯糸密度６６本／ ２．５４ｃｍの
平織物を作成した。Next, each of the yarns obtained in Example 1 and Comparative Examples 1 to 4 was used alone as both the warp and the weft to produce a plain woven fabric with a warp density of 120 threads/2.54 cm and a weft thread density of 66 threads/2.54 cm. It was created.
また、実施例２及び比較例５〜８の糸条を各々単独で経
糸、緯糸の両方に用いて、経糸密度１３６本／ ２．５
４ｃｍ、緯糸密度７５本／ ２．５４ｃｍの平織物を作
成した。In addition, each of the yarns of Example 2 and Comparative Examples 5 to 8 was used alone as both the warp and weft, and the warp density was 136/2.5.
A plain woven fabric with a length of 4 cm and a weft density of 75 threads/2.54 cm was produced.
上記の各実施例及び比較例で得られた織物の評価を第３
表及び第４表に示す。The evaluation of the fabrics obtained in each of the above examples and comparative examples was
It is shown in Table and Table 4.
第
！
表
第
表
第３．４表から明らかなように、実施例１．２で得られ
た芯・鞘型複合糸条を用いた布帛は、光のエネルギー吸
収が良好で、かつ、吸収した熱の保持が各比較例に比べ
て大きく改善されていた。No.! As is clear from Table 3.4, the fabric using the core-sheath composite yarn obtained in Example 1.2 has good light energy absorption and absorbs heat. Retention was greatly improved compared to each comparative example.
また、実施例１，２で得られた布帛を用いてジャンパー
ジャケットを試作し、試着実験を行ったところ、晴天か
ら曇天に移行した後でも、衣服内温度の急激な低下がな
く、優れた蓄熱性を示していた。In addition, when we prototyped a jumper jacket using the fabrics obtained in Examples 1 and 2 and tried it on, we found that even after the weather changed from sunny to cloudy, there was no sudden drop in the temperature inside the garment, and it had excellent heat storage. It showed sexuality.
一方１本発明の構成要件のうち、いずれか一つを満足し
ない比較例１〜８からの布帛は、吸熱性もしくは蓄熱性
のいずれかの点で劣るものであった。On the other hand, the fabrics from Comparative Examples 1 to 8 that did not satisfy any one of the constituent requirements of the present invention were inferior in either heat absorption or heat storage.
実施例３．比較例９〜１２
炭化ジルコニウム微粒子を０．０７重量％及び２．０重
量％含有した２種のナイロン６チップをそれぞれ溶融紡
糸し９次いで延伸して得たマルチフィラメント糸（糸条
Ａ）と、セラミックス微粒子を含有していないナイロン
６延伸マルチフィラメント糸（糸条Ｂ）とを使用して、
第６図に示した加工工程にしたがい、第５表の条件で加
工して第６表に示した構成のループ毛羽を有する芯・鞘
型複合糸条を得た。なお、糸条（Ｂ）の仮撚数（Ｔ／Ｍ
）は。Example 3. Comparative Examples 9 to 12 Multifilament yarn (yarn A) obtained by melt-spinning two types of nylon 6 chips containing 0.07% by weight and 2.0% by weight of zirconium carbide fine particles and then drawing 9 times, Using nylon 6 drawn multifilament yarn (yarn B) that does not contain ceramic fine particles,
According to the processing steps shown in FIG. 6, processing was performed under the conditions shown in Table 5 to obtain a core-sheath type composite yarn having loop fuzz having the structure shown in Table 6. In addition, the number of false twists (T/M
)teeth.
実施例３と比較例９．１０が３０００．比較例１１が２
３００゜比較例１２が４３００に設定した。Example 3 and Comparative Example 9.10 were 3000. Comparative example 11 is 2
300° Comparative Example 12 was set to 4300°.
次いで、実施例３及び比較例９〜１２で得られた糸条を
各々単独で経糸、緯糸の双方に用いて、経糸密度１２０
本／ ２．５４ｃｍ、緯糸密度６６本／ ２．５４ｃｍ
の平織物を作成した。Next, each of the yarns obtained in Example 3 and Comparative Examples 9 to 12 was used alone as both the warp and weft, and the warp density was 120.
Book/2.54cm, weft density 66/2.54cm
A plain woven fabric was created.
得られた織物の評価結果を第７表に示す。Table 7 shows the evaluation results of the obtained fabrics.
第
表
第
７
表
第７表から明らかなように、実施例３で得られたループ
毛羽を有する芯・鞘型複合糸条を用いた布帛は、光のエ
ネルギーをよく吸収し、しかも吸収した熱を長時間持続
した。また、上記実施例の布帛を用いてジャンパージャ
ケットを試作し、試着実験を行った結果、晴天から曇天
に移行した後でも、衣服内温度は急激に減少せず、優れ
た蓄熱性を示した。Table 7 As is clear from Table 7, the fabric using the core-sheath composite yarn with loop fluff obtained in Example 3 can absorb light energy well and absorb the absorbed heat. lasted for a long time. In addition, a jumper jacket was prototyped using the fabric of the above example, and as a result of a try-on experiment, the temperature inside the garment did not decrease rapidly even after the weather changed from sunny to cloudy, showing excellent heat storage properties.
一方、比較例９〜１２で得られた布帛には、吸熱性と蓄
熱性の両方を同時に満足するものがなかった。On the other hand, none of the fabrics obtained in Comparative Examples 9 to 12 satisfied both heat absorption and heat storage properties at the same time.
（発明の効果）
本発明の芯・鞘型複合糸条は、芯部が遠赤外線放射能力
を有するセラミックス微粒子を含有したマルチフィラメ
ント糸で形成されているため吸熱性が優れており、また
、鞘部が熱伝導率の低い繊維で構成されているため断熱
性にも優れている。(Effects of the Invention) The core/sheath type composite yarn of the present invention has excellent heat absorbing properties because the core portion is formed of a multifilament yarn containing ceramic fine particles that have far-infrared radiation ability. It also has excellent heat insulation properties because it is made of fibers with low thermal conductivity.
このように、熱エネルギーの効果的な吸収性と。Thus, with effective absorption of thermal energy.
熱エネルギー低下時の優れた保温蓄熱性を兼ね備えた糸
条であるから、この糸条を用いた布帛は。Fabrics using this yarn have excellent heat retention and heat storage properties when thermal energy is low.
極めて暖かな衣服とすることができる。It can be a very warm garment.
また、芯・鞘型複合糸条にループやタルミを形成させた
ものには、ループやタルミによる微小空間が多数存在し
ており、このため、断熱性が一層向上し、従来の保温素
材よりも外部への熱の放散防止性が著しく向上する。In addition, in core-sheath type composite yarns with loops and sag formed, there are many microscopic spaces due to the loops and sagging, which further improves the insulation properties and improves it compared to conventional heat-retaining materials. The ability to prevent heat dissipation to the outside is significantly improved.
第１図、第２図及び第３図は１本発明の芯・鞘型複合糸
条の実施態様を示す模式図であり、第４図、第５図及び
第６図は、それぞれ第１図、第２図及び第３図の複合糸
条を製造するための概略工程図である。
Ａ：遠赤外線放射能力を有するセラミックス微粒子を含
有した合成繊維マルチフィラメント糸Ｂ：通常の熱可塑
性合成繊維マルチフィラメント糸
ｌ：開繊被覆部
２：交絡部
３：微小空間Figures 1, 2 and 3 are schematic diagrams showing embodiments of the core-sheath type composite yarn of the present invention, and Figures 4, 5 and 6 are diagrams of Figure 1, respectively. , FIG. 3 is a schematic process diagram for manufacturing the composite yarn of FIGS. 2 and 3. A: Synthetic fiber multifilament yarn containing ceramic fine particles having far-infrared radiation ability B: Ordinary thermoplastic synthetic fiber multifilament yarn 1: Spread coating portion 2: Intertwined portion 3: Microspace
Claims (2)
０．１〜２０重量％含有した合成繊維マルチフィラメン
ト糸（糸条Ａ）が主として芯部を形成し、通常の熱可塑
性合成繊維マルチフィラメント糸（糸条Ｂ）が主として
鞘部を形成した芯・鞘型複合糸であって、糸条Ａと糸条
Ｂの重量比が２０：８０〜７０：３０であることを特徴
とする芯・鞘型複合糸条。(1) Synthetic fiber multifilament yarn (yarn A) containing 0.1 to 20% by weight of ceramic fine particles having far-infrared radiation ability mainly forms the core, and ordinary thermoplastic synthetic fiber multifilament yarn (yarn A core-sheath type composite yarn in which the thread B) mainly forms a sheath part, and the weight ratio of the thread A and the thread B is 20:80 to 70:30. Yarn.
び交絡が形成されていることを特徴とする芯・鞘型複合
糸条。(2) A core-sheath type composite yarn, characterized in that the yarn according to claim 1 is formed with loops, sagging, and entanglements.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19484389A JPH0359134A (en) | 1989-07-26 | 1989-07-26 | Core-sheath type composite yarn |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19484389A JPH0359134A (en) | 1989-07-26 | 1989-07-26 | Core-sheath type composite yarn |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0359134A true JPH0359134A (en) | 1991-03-14 |
Family
ID=16331199
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19484389A Pending JPH0359134A (en) | 1989-07-26 | 1989-07-26 | Core-sheath type composite yarn |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0359134A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997042363A1 (en) * | 1996-05-07 | 1997-11-13 | Chavanoz Industrie | Composite yarn |
| KR100460002B1 (en) * | 1998-01-03 | 2005-01-17 | 주식회사 새 한 | Woolen type polyester different shrinkage mixed yarn having excellent dryness, repulsive property and bulkiness |
| JP2010223408A (en) * | 2009-03-25 | 2010-10-07 | Hitachi Appliances Inc | Vacuum heat insulating material, and heat insulating box and equipment using the same |
| CN102517738A (en) * | 2011-12-19 | 2012-06-27 | 中国人民解放军总后勤部军需装备研究所 | Cellulose fiber/synthetic fiber sheath core type composite modified continuous filament yarn and preparation method thereof |
| CN102677238A (en) * | 2012-05-17 | 2012-09-19 | 绍兴文理学院 | Production process of environment-friendly heather grey effect composite textured filament for knitting |
| CN102677240A (en) * | 2012-05-17 | 2012-09-19 | 绍兴文理学院 | Environment-friendly dyeable heather grey effect composite mixing fiber filament yarn production process. |
| CN103132206A (en) * | 2011-11-29 | 2013-06-05 | 东丽纤维研究所（中国）有限公司 | Composite yarn textile capable of absorbing moisture and sensing cold and application thereof |
| US9920455B2 (en) | 2001-09-21 | 2018-03-20 | Outlast Technologies, LLC | Cellulosic fibers having enhanced reversible thermal properties and methods of forming thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63182434A (en) * | 1987-01-23 | 1988-07-27 | ミネソタ マイニング アンド マニユフアクチユアリング カンパニー | Elastic composite yarn equipped with fragile ceramic yarn |
-
1989
- 1989-07-26 JP JP19484389A patent/JPH0359134A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63182434A (en) * | 1987-01-23 | 1988-07-27 | ミネソタ マイニング アンド マニユフアクチユアリング カンパニー | Elastic composite yarn equipped with fragile ceramic yarn |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997042363A1 (en) * | 1996-05-07 | 1997-11-13 | Chavanoz Industrie | Composite yarn |
| FR2748496A1 (en) * | 1996-05-07 | 1997-11-14 | Chavanoz Ind | COMPOSITE WIRE |
| US6032454A (en) * | 1996-05-07 | 2000-03-07 | Chavanoz Industrie | Composite yarn |
| KR100460002B1 (en) * | 1998-01-03 | 2005-01-17 | 주식회사 새 한 | Woolen type polyester different shrinkage mixed yarn having excellent dryness, repulsive property and bulkiness |
| US9920455B2 (en) | 2001-09-21 | 2018-03-20 | Outlast Technologies, LLC | Cellulosic fibers having enhanced reversible thermal properties and methods of forming thereof |
| US10208403B2 (en) | 2001-09-21 | 2019-02-19 | Outlast Technologies, LLC | Cellulosic fibers having enhanced reversible thermal properties and methods of forming thereof |
| JP2010223408A (en) * | 2009-03-25 | 2010-10-07 | Hitachi Appliances Inc | Vacuum heat insulating material, and heat insulating box and equipment using the same |
| CN103132206A (en) * | 2011-11-29 | 2013-06-05 | 东丽纤维研究所（中国）有限公司 | Composite yarn textile capable of absorbing moisture and sensing cold and application thereof |
| CN102517738A (en) * | 2011-12-19 | 2012-06-27 | 中国人民解放军总后勤部军需装备研究所 | Cellulose fiber/synthetic fiber sheath core type composite modified continuous filament yarn and preparation method thereof |
| CN102677238A (en) * | 2012-05-17 | 2012-09-19 | 绍兴文理学院 | Production process of environment-friendly heather grey effect composite textured filament for knitting |
| CN102677240A (en) * | 2012-05-17 | 2012-09-19 | 绍兴文理学院 | Environment-friendly dyeable heather grey effect composite mixing fiber filament yarn production process. |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3664585B2 (en) | Fiber with excellent heat radiation | |
| JPH0359134A (en) | Core-sheath type composite yarn | |
| JPH01314716A (en) | White fabric having heat insulating property | |
| JP5297331B2 (en) | Core-sheath type composite fiber | |
| US3914929A (en) | Process and apparatus for continuously producing slub yarn | |
| JPH01314715A (en) | Fiber and fabric having heat insulating property | |
| JPH01132816A (en) | Selectively absorptive fiber for solar heat and warmth-retentive fiber therefrom | |
| JPH03104949A (en) | Core-sheath conjugate yarn | |
| JPS6055614B2 (en) | Mixed fiber crimped yarn and its manufacturing method | |
| JPH01174625A (en) | Flat spun yarn and production thereof | |
| JP3059203B2 (en) | Method for producing heat insulating composite structural yarn | |
| JPS6221884B2 (en) | ||
| JPH0351312A (en) | Heat-accumulating and heat retaining fiber having improved whiteness | |
| JP3242552U (en) | Elastic composite fiber filament with UV resistance | |
| JPH108345A (en) | Lightweight heat insulating fabric | |
| JPH0491238A (en) | Thermally insulating multi-layered structural yarn | |
| JPH08120534A (en) | Production of heat insulating composite bulking textured yarn | |
| JPS5855260Y2 (en) | Bulky processed yarn | |
| JP3103095B2 (en) | Warm polyester crimped yarn | |
| JPS5939532B2 (en) | Silk spun processed yarn and its manufacturing method | |
| JPH0299626A (en) | Production method for crimped yarn with a multilayer structure | |
| JPH101835A (en) | Textured yarn having heat-accumulating conjugate structure and cloth produced by using the yarn | |
| JPH1121720A (en) | Polyester-based self-elongating yarn having heat retaining property, its combined filament yarn and fabric | |
| JP3831076B2 (en) | Solar selective absorption heat storage lightweight fabric | |
| JPH03167333A (en) | False twisted conjugated yarn and production thereof |