JPH0357008Y2 - - Google Patents
Info
- Publication number
- JPH0357008Y2 JPH0357008Y2 JP1984093243U JP9324384U JPH0357008Y2 JP H0357008 Y2 JPH0357008 Y2 JP H0357008Y2 JP 1984093243 U JP1984093243 U JP 1984093243U JP 9324384 U JP9324384 U JP 9324384U JP H0357008 Y2 JPH0357008 Y2 JP H0357008Y2
- Authority
- JP
- Japan
- Prior art keywords
- lead
- copper
- upper rib
- net
- rib
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 35
- 229910052802 copper Inorganic materials 0.000 claims description 35
- 239000010949 copper Substances 0.000 claims description 35
- 229910000978 Pb alloy Inorganic materials 0.000 claims description 17
- 239000002253 acid Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 description 5
- 239000013543 active substance Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000009826 distribution Methods 0.000 description 2
- 210000005069 ears Anatomy 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000005266 casting Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- Y02E60/12—
Landscapes
- Cell Electrode Carriers And Collectors (AREA)
Description
【考案の詳細な説明】
産業上の利用分野
本考案は放電性能を向上せしめるために、電極
の格子体材料として銅を用いた鉛蓄電池に関する
ものである。[Detailed Description of the Invention] Industrial Field of Application The present invention relates to a lead-acid battery using copper as the electrode grid material in order to improve discharge performance.
従来技術とその問題点
一般に鉛蓄電池用の銅格子体は、通常使用され
ている鉛合金格子体に比較して、電気抵抗が極め
て小さい。このため、放電時の集電電圧降下ロス
が小さく、かつ電極面各部における電流密度が均
一化して作用物質が効率良く利用される。従つて
銅格子体使用の鉛蓄電池は放電性能が非常に優れ
ており、特に高率放電や、電極が縦長となる背の
高い電池において、その効果が顕著であることが
判つている。Prior Art and Its Problems Copper grids for lead-acid batteries generally have extremely low electrical resistance compared to commonly used lead alloy grids. Therefore, the current collection voltage drop loss during discharge is small, the current density at each part of the electrode surface is made uniform, and the active substance is efficiently utilized. Therefore, it has been found that lead-acid batteries using a copper lattice have very excellent discharge performance, and this effect is particularly noticeable in high-rate discharge and tall batteries with vertically elongated electrodes.
鉛蓄電池において銅格子体を使用する場合に、
作用物質が充填される部分は通常銅板をエキスパ
ンド加工や、打抜き加工によりネツト状とする。
しかしながら電極の集電部は、最終的には鉛合金
製の端子ポールへ接続しなければならない。この
時ネツト部が端子ポールと異種金属である為に、
集電用上部親骨部の極群組立の作業性をいかに効
率良くするかが大きな問題である。 When using a copper grid in lead-acid batteries,
The part to be filled with the active substance is usually made into a net shape by expanding or punching a copper plate.
However, the current collector of the electrode must ultimately be connected to a lead alloy terminal pole. At this time, since the net part is made of a different metal than the terminal pole,
A major problem is how to improve the workability of assembling the pole group of the upper main rib for current collection.
従来この問題の解決策として、上部親骨を全て
鉛合金製とし、その一部に銅ネツト部の上端を埋
め込んだ形にして、鉛合金同志のバーニングによ
り組立てた構造や親骨を全て銅とし、従来の鉛格
子体使用電極と同様に、組立用のクシ歯に集電耳
部の銅をセツトした後、その周囲をバーニングに
より鉛合金で覆うと同時にボールと接続する構造
などを採用していた。 Conventionally, as a solution to this problem, the upper rib was made entirely of lead alloy, the upper end of the copper net part was embedded in a part of it, and the structure was assembled by burning the lead alloy together. Similar to the lead lattice electrode used in 1995, the copper for the collector ear was set on the comb teeth for assembly, and then the surrounding area was covered with lead alloy by burning, and at the same time it was connected to the ball.
しかしながら前記の如き構造では、生産性が悪
いのでコスト面で不利となり、性能面においても
未解決な問題が残されているのが現状である。 However, the structure described above is disadvantageous in terms of cost due to poor productivity, and there are still unresolved problems in terms of performance.
即ち、前者においては、上部親骨部の電気抵抗
が、従来の鉛格子体と変わらず大きいために、放
電時の電極巾方向における電流密度分布が均一化
しない。又上部親骨部の電圧降下ロスが大きいの
で、特に高率放電時において銅格子体本来の効果
を十分に発揮させられないという欠点があつた。 That is, in the former case, the electrical resistance of the upper rib portion is as large as that of the conventional lead grid body, so that the current density distribution in the electrode width direction during discharge is not uniform. Furthermore, since the voltage drop loss at the upper rib portion is large, there is a drawback that the original effect of the copper lattice body cannot be fully exhibited, especially during high rate discharge.
一方、後者においては、バーニングによる銅耳
部と鉛合金との接合の信頼性が低く、接合部分の
電圧降下ロスが大きく、又電池使用中の振動や衝
撃により極板が集電用の鉛合金部から離脱すると
いう大きな欠点があつた。 On the other hand, in the latter case, the reliability of the bond between the copper ear and the lead alloy due to burning is low, the voltage drop loss at the bond is large, and the electrode plate is damaged by the lead alloy for current collection due to vibration and impact during battery use. There was a major drawback in that he had to leave the club.
考案の目的
本考案は、鉛蓄電池における高率放電特性を大
巾に改良すると共に、生産性の良好な耐振動、耐
衝撃性に優れた鉛蓄電池用格子体を提供すること
を目的としたものである。Purpose of the invention The purpose of the invention is to significantly improve the high-rate discharge characteristics of lead-acid batteries, and to provide a grid for lead-acid batteries with good productivity and excellent vibration and shock resistance. It is.
考案の構成
すなわち、本考案は上記の目的を達成するため
に、上部親骨1と銅ネツト2とを有する鉛蓄電池
用格子体であつて、前記上部親骨1と前記銅ネツ
ト2とは銅からなり、前記上部親骨1は、集電耳
部5を有し、その先端に鉛または鉛合金からなる
集電接続用鉛体4が接合されていることを特徴と
するものである。Structure of the invention That is, in order to achieve the above object, the present invention provides a lattice body for a lead-acid battery having an upper rib 1 and a copper net 2, wherein the upper rib 1 and the copper net 2 are made of copper. The upper main rib 1 is characterized in that it has a current collecting ear part 5, and a current collecting connecting lead body 4 made of lead or a lead alloy is joined to the tip thereof.
実施例の説明
以下に本考案の詳細につき、実施例により説明
する。DESCRIPTION OF EMBODIMENTS The details of the present invention will be explained below using examples.
第1図のAは本考案による銅格子体の平面図で
あり、Bはその上部親骨と銅ネツトの腰部断面拡
大図である。 FIG. 1A is a plan view of the copper lattice according to the present invention, and B is an enlarged sectional view of the upper rib and the waist of the copper net.
1は上部親骨、2は作用物質が充填される銅ネ
ツト、3は下部親骨、4は鉛合金からなる集電接
続用鉛体、5は集電耳部であり、上部親骨1は銅
で作られており、その下端に銅ネツト2が接続さ
れている。又上部親骨1に設けられた集電耳部5
の先端には、集電接続用鉛体4が集電耳部5の銅
を一部覆う形で接合されている。 1 is an upper rib, 2 is a copper net filled with an active substance, 3 is a lower rib, 4 is a lead body made of a lead alloy for connecting a current collector, 5 is a current collector ear, and the upper rib 1 is made of copper. A copper net 2 is connected to the lower end. In addition, a current collecting ear portion 5 provided on the upper rib 1
A lead body 4 for current collecting connection is joined to the tip of the current collecting ear portion 5 so as to partially cover the copper of the current collecting ear portion 5 .
このように、本考案による銅格子体において
は、電極の集電部である格子体の上部親骨耳部の
端部のみを鉛合金としているので、従来の上部親
骨の全てを鉛とした銅格子体と比べて、上部親骨
の電気抵抗が極めて小さくなる。従つて銅格子体
の持つ、集電部の電圧降下ロスの減少と、放電時
の電極各部における電流密度分布の均一化の効果
を低下させることがないので、高率放電において
優れた性能が得られる。 In this way, in the copper lattice body according to the present invention, only the ends of the upper rib ears of the lattice body, which are the current collecting parts of the electrodes, are made of lead alloy. The electrical resistance of the upper rib is extremely small compared to the body. Therefore, the effectiveness of the copper grid in reducing voltage drop loss at the current collecting section and making the current density distribution uniform in each part of the electrode during discharge is not reduced, so excellent performance can be achieved in high rate discharge. It will be done.
又端子ポールと極板との接続が、従来の鉛格子
体と全く同じ鉛合金同志のバーニングとして行な
うことができる。このため従来の上部親骨を全て
銅とした銅格子体使用電池の最大の欠点であつ
た、端子ポールの集電用鉛合金部と集電耳部の接
続不良による電気抵抗の増大や、機械的な接続強
度不足の問題が解消でき、しかも生産性が極めて
良好となる。 In addition, the connection between the terminal pole and the electrode plate can be made by burning lead alloys together, just like the conventional lead grid. For this reason, the biggest drawback of conventional batteries that use copper grids, where the upper rib is entirely copper, is that electrical resistance increases due to poor connection between the current collecting lead alloy part of the terminal pole and the current collecting ear, and mechanical This solves the problem of insufficient connection strength, and also improves productivity.
本考案における上部親骨1の銅と集電接続用鉛
体4の鉛合金との接合は、集電耳部5を予め鋳型
にセツトしておき、そこへ鉛合金湯を流し込む、
いわゆる鋳造方式や、予め鋳型に鉛合金湯を満た
しておき、そこへ銅格子体の集電耳部5を没入さ
せる、いわゆるキヤストオン方式などにより容易
に接合できる。 In the present invention, the copper of the upper rib 1 and the lead alloy of the lead body 4 for current collector connection are joined by setting the current collecting ear part 5 in a mold in advance, and pouring lead alloy hot water into it.
They can be easily joined by a so-called casting method, or a so-called cast-on method, in which a mold is filled with lead alloy hot water and the current collecting ears 5 of the copper grid are immersed therein.
上記の方式によれば接合部の電気抵抗及び接合
強度が、バーニングによる従来の方法に比べて、
はるかに信頼性の高いものが得られる。 According to the above method, the electrical resistance and bond strength of the joint are improved compared to the conventional method using burning.
You get something much more reliable.
尚、集電接続用鉛体4を純鉛にしても良く、前
記と同じ接合方法が可能である。 Note that the lead body 4 for current collector connection may be made of pure lead, and the same joining method as described above is possible.
又、上部親骨1と銅ネツト2との接続は、一枚
の銅板の一部をネツト状に加工し、その後ネツト
に加工されていない部分を親骨部として、所定の
形に切断する方法や、上部親骨1と銅ネツト2を
別々に作つておき、上部親骨1の下端にネツト部
2の上端をスポツト溶接する等により容易に接続
できる。いずれの方法においても、本考案の構造
を採用することが可能である。 In addition, the connection between the upper main rib 1 and the copper net 2 can be achieved by processing a part of one copper plate into a net shape, and then cutting the part that is not processed into a net into a predetermined shape as the main rib. The upper rib 1 and the copper net 2 are made separately and can be easily connected by spot welding the upper end of the net portion 2 to the lower end of the upper rib 1. In either method, it is possible to employ the structure of the present invention.
更に完成格子体として、銅ネツト2の下端に下
部親骨3を設けることや、電池性能に悪影響を及
ぼす電解液中への銅の溶出を防止するため、銅が
露出しない様に格子体に鉛メツキ等を施こすこと
等が考えられるが、本考案はこれらの工程に対し
ても何等の障害となるものではない。 Furthermore, in the completed lattice body, a lower rib 3 is provided at the lower end of the copper net 2, and in order to prevent copper from leaching into the electrolyte, which has a negative effect on battery performance, the lattice body is plated with lead to prevent copper from being exposed. However, the present invention does not pose any hindrance to these steps.
考案の効果
上述した如く、本考案は作用物質の充填される
部分に銅ネツトを集電体として用いた格子体にお
いて、上部の親骨を銅とし該親骨に設けられた集
電耳の端部に鉛又は鉛合金を接合した格子体とす
ることにより、高率放電特性が大巾に改良され、
かつ生産性の良い、安価なしかも耐振動、耐衝撃
性に優れた鉛蓄電池用格子体を提供することがで
きるものであり、その工業的価値は極めて大であ
る。Effects of the Invention As mentioned above, the present invention is a lattice body in which a copper net is used as a current collector in the part filled with an active substance. By using a grid made of lead or lead alloy, the high rate discharge characteristics are greatly improved.
Moreover, it is possible to provide a grid for lead-acid batteries that is highly productive, inexpensive, and has excellent vibration resistance and impact resistance, and its industrial value is extremely large.
第1図は本考案の一実施例を示す図でありAは
その平面図、Bは要部断面の拡大図である。
1……上部親骨、2……銅ネツト、3……下部
親骨、4……集電接続用鉛体、5……集電耳部。
FIG. 1 is a diagram showing an embodiment of the present invention, in which A is a plan view thereof and B is an enlarged cross-sectional view of a main part. DESCRIPTION OF SYMBOLS 1... Upper rib, 2... Copper net, 3... Lower rib, 4... Lead body for current collection connection, 5... Current collector ear.
Claims (1)
格子体であつて、 前記上部親骨1と前記銅ネツト2とは銅からな
り、 前記上部親骨1は、集電耳部5を有し、その先
端に鉛または鉛合金からなる集電接続用鉛体4が
接合されていることを特徴とする、 鉛蓄電池用格子体。[Claims for Utility Model Registration] A lattice body for a lead-acid battery having an upper rib 1 and a copper net 2, wherein the upper rib 1 and the copper net 2 are made of copper, and the upper rib 1 is used for collecting current. A lattice body for a lead-acid battery, characterized in that it has an ear part 5, and a lead body 4 for current collection connection made of lead or a lead alloy is joined to the tip of the ear part 5.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1984093243U JPS618945U (en) | 1984-06-21 | 1984-06-21 | Grid for lead-acid batteries |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1984093243U JPS618945U (en) | 1984-06-21 | 1984-06-21 | Grid for lead-acid batteries |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS618945U JPS618945U (en) | 1986-01-20 |
JPH0357008Y2 true JPH0357008Y2 (en) | 1991-12-25 |
Family
ID=30650745
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1984093243U Granted JPS618945U (en) | 1984-06-21 | 1984-06-21 | Grid for lead-acid batteries |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS618945U (en) |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55117774U (en) * | 1979-02-15 | 1980-08-20 |
-
1984
- 1984-06-21 JP JP1984093243U patent/JPS618945U/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS618945U (en) | 1986-01-20 |
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