JPH0350288A - Anti-fogging agent composition - Google Patents
Anti-fogging agent compositionInfo
- Publication number
- JPH0350288A JPH0350288A JP18506789A JP18506789A JPH0350288A JP H0350288 A JPH0350288 A JP H0350288A JP 18506789 A JP18506789 A JP 18506789A JP 18506789 A JP18506789 A JP 18506789A JP H0350288 A JPH0350288 A JP H0350288A
- Authority
- JP
- Japan
- Prior art keywords
- agent composition
- water
- antifogging agent
- sol
- antifogging
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 63
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 61
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 22
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000007787 solid Substances 0.000 claims abstract description 18
- 239000002245 particle Substances 0.000 claims abstract description 15
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000002736 nonionic surfactant Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 29
- 239000006185 dispersion Substances 0.000 abstract description 26
- 238000000576 coating method Methods 0.000 abstract description 17
- 239000011248 coating agent Substances 0.000 abstract description 16
- 238000009736 wetting Methods 0.000 abstract description 10
- 239000004094 surface-active agent Substances 0.000 abstract description 6
- 230000002688 persistence Effects 0.000 abstract 2
- 238000000034 method Methods 0.000 description 20
- 239000007788 liquid Substances 0.000 description 11
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- 239000002518 antifoaming agent Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- -1 various alums Chemical compound 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 3
- 229920001214 Polysorbate 60 Polymers 0.000 description 3
- 150000005215 alkyl ethers Chemical class 0.000 description 3
- 150000004687 hexahydrates Chemical class 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920001213 Polysorbate 20 Polymers 0.000 description 2
- JGDITNMASUZKPW-UHFFFAOYSA-K aluminium trichloride hexahydrate Chemical compound O.O.O.O.O.O.Cl[Al](Cl)Cl JGDITNMASUZKPW-UHFFFAOYSA-K 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000007970 homogeneous dispersion Substances 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 2
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- YLZOPXRUQYQQID-UHFFFAOYSA-N 3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]propan-1-one Chemical compound N1N=NC=2CN(CCC=21)CCC(=O)N1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F YLZOPXRUQYQQID-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 241000511343 Chondrostoma nasus Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- HDYRYUINDGQKMC-UHFFFAOYSA-M acetyloxyaluminum;dihydrate Chemical compound O.O.CC(=O)O[Al] HDYRYUINDGQKMC-UHFFFAOYSA-M 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 229940009827 aluminum acetate Drugs 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- 230000005661 hydrophobic surface Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 230000010415 tropism Effects 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Landscapes
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
Description
【発明の詳細な説明】
「産業上の利用分野１
本発明は、防曇剤組成物に関するものである６更に詳し
くは、保存安定性が良くガラス、今ｔ＆ ０４脂材料よ
りなる各種成形品の表面に防曇性を附与し、この防曇性
を長期間にわたって持続しうる高濃度に調製可能な防曇
剤組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION "Industrial Application Field 1 The present invention relates to an antifogging agent composition6. More specifically, it has good storage stability and is suitable for use in various molded articles made of glass and T&04 resin materials. The present invention relates to an antifogging agent composition that can be prepared at a high concentration that imparts antifogging properties to a surface and can maintain this antifogging property over a long period of time.
「従来の技術」
熱可塑性樹脂より製造された成形品の多くは、その表面
が疎水性であるため、成形品を使用する雰囲気の温度、
湿度等の条件によっては、成形品の表面に曇りを生じ、
種々の不都合をきたしている。例えば、合成樹脂製レン
ズを使用しているゴーグル、安全マスク等では、曇りの
ために視界がきかなかったり、食品包装用フィルムでは
、曇りのために内容物が見えにくくなる６また、温室に
用いられている農業用フィルムでは、曇りのために太陽
光線の透過が悪くなり、植物の生育を遅くしたり、水滴
が栽培植物に落下することにより、幼芽が害をうけたり
、病害の発生の原因となったり、温室内の作業者に不快
感を快える等、種々の不都合が生ずる。"Prior art" Many molded products made from thermoplastic resin have hydrophobic surfaces, so the temperature of the atmosphere in which the molded product is used,
Depending on conditions such as humidity, the surface of the molded product may become cloudy.
This has caused various inconveniences. For example, goggles, safety masks, etc. that use synthetic resin lenses may be cloudy, making it difficult to see, and food packaging films may be cloudy, making it difficult to see the contents6. With the agricultural film that is used, cloudy weather reduces the penetration of sunlight, slowing down plant growth, and causing water droplets to fall on cultivated plants, damaging young buds and causing diseases. This causes various inconveniences, such as causing discomfort to workers in the greenhouse.
このような不都合を解消するためには、熱可塑性０（脂
成形品表面に、防曇性を賦与すればよいことが知られて
いる。熱可塑性樹脂成形品の表面に防曇性を賦与するに
は、熱可塑性樹脂材料に、界面活性剤のような親水性物
質を練りこんで成形品を製造する方法、または成形品と
した後に、その表面に、親水性物質もしくは水溶性高分
子を塗布する方法が採用されている。後者の塗布方法に
用いる防曇剤の性質としては、塗布が容易であること、
塗膜の防暑効果が高く、効果が長期間持続すること等が
要求され、更に防曇剤自体の保存安定性のよいことも重
要なことである。It is known that in order to eliminate such inconveniences, it is sufficient to impart antifogging properties to the surface of thermoplastic resin molded products. In this method, a hydrophilic substance such as a surfactant is kneaded into a thermoplastic resin material to produce a molded product, or a hydrophilic substance or water-soluble polymer is applied to the surface of the molded product. The properties of the antifogging agent used in the latter application method are that it is easy to apply;
It is required that the coating film has a high heat protection effect and that the effect lasts for a long period of time, and it is also important that the antifogging agent itself has good storage stability.
これらの諸点にすぐれた防曇剤としては例えば特開昭６
Ｏ−９６（３８２号公報に記載されている、特定のアル
ミナゾルとシリカゾルの混合コロイドゾルと非イオン性
界面活性剤を併用した防曇剤がある。An example of an antifogging agent that is excellent in these respects is JP-A No. 6
There is an antifogging agent that uses a specific mixed colloidal sol of alumina sol and silica sol together with a nonionic surfactant, which is described in O-96 (No. 382).
しかし、この防曇剤にも環境条件によってより一層の防
曇効果の持続性等特性の向上を要求される場合があり、
改善が望まれている。However, depending on the environmental conditions, even this antifogging agent may be required to further improve its properties such as the sustainability of its antifogging effect.
Improvement is desired.
［発明が解決しようとする課題」
本発明者らは、かかる状況にあって、保存安定性に優れ
成形品表面への塗布が容易で、塗布面の耐水性に優れ、
成形品表面へ塗布した直後の初期防曇性に優れ、さらに
防曇効果の持続性も良好な、高濃度に調製可能な防曇剤
組成物を提供することを目的として、鋭意検討した結果
、本発明を完成するに至ったものである。[Problems to be Solved by the Invention] In view of this situation, the present inventors have developed a product that has excellent storage stability, is easy to apply to the surface of a molded product, and has excellent water resistance on the coated surface.
As a result of intensive studies, we aimed to provide an antifogging agent composition that has excellent initial antifogging properties immediately after being applied to the surface of a molded product, has a long-lasting antifogging effect, and can be prepared at a high concentration. This has led to the completion of the present invention.
「課題を解決するための手段」
しかして、本発明の要旨とするところは、平均粒子径が
１００ミリミクロン以下の（Ａ）アルミナゾルと（Ｂ）
シリカゾルとが、固形分の重量比で９５％５１５％９５
（全体で１００とする）の割合で混合されている無機質
コロイドゾルを、固形分として１〜４０重量％（Ｃ）水
溶性アルミニウム塩を０．０５〜２０重量％（Ｄ）非イ
オンＰＳｌｉＩｉＬ面活性剤を０．０５〜１５重量％含
有することを特徴とする防曇剤組成物に存する。"Means for Solving the Problems" Therefore, the gist of the present invention is that (A) an alumina sol having an average particle diameter of 100 millimicrons or less;
Silica sol is 95% 515% 95% by weight of solid content.
(Total: 100%) of inorganic colloidal sol mixed at a solid content of 1 to 40% by weight (C) Water-soluble aluminum salt of 0.05 to 20% by weight (D) Nonionic PSliIiL surfactant An antifogging agent composition characterized by containing 0.05 to 15% by weight of.
以下、本発明の詳細な説明する。The present invention will be explained in detail below.
本発明に係る防曇剤組成物は、第−成分及び第二成分と
して、平均粒子径が１００ミリミクロン以下のアルミナ
ゾルとシリカゾルとが、重量比で９５へ−５１５へ−９
５（全体で１００とする）の割合で混合されている無機
質コロイドゾルを、固形分として１′５４０重量％（防
曇剤組成物全体として１００重量％とする）含有する。In the antifogging agent composition according to the present invention, as the first component and the second component, alumina sol and silica sol having an average particle size of 100 millimicrons or less are included in a weight ratio of 95 to 515 to -9.
The solid content of the inorganic colloidal sol is 1'540% by weight (the entire antifogging agent composition is 100% by weight).
防曇剤組成物の第−成分及び第二成分である無機質コロ
イドゾルは、成形品表面に塗布された後に成形品表面に
残り、成形品の防曇性向上、防曇持続性向上の機能を果
す。The inorganic colloidal sol, which is the first component and the second component of the antifogging agent composition, remains on the surface of the molded product after being applied to the surface of the molded product, and functions to improve the antifogging property and durability of the molded product. .
無機質コロイドの平均粒子径は、１００ミリミクロン以
下のむのとする。The average particle size of the inorganic colloid is 100 millimicrons or less.
平均粒子径が１００ミリミクロンより大であると、これ
を含む防曇剤組成物を成形品表面に塗布した際に、成形
品の透明性を低下させるので、好ましくない。If the average particle diameter is larger than 100 millimicrons, the transparency of the molded product will be reduced when an antifogging agent composition containing this is applied to the surface of the molded product, which is not preferable.
無機質コロイドゾルは、アルミナゾルとシリカゾルとを
固形分の重量比で９５・）、 ５ ／ ５〜９５（全体
で１００とする）の割合で混合されたものとする。アル
ミナゾルは、塗布後の成形品表面の水分による濡れを向
上させるのに有効であるが、この成分割合が多くなると
、防曇持続性が悪くなるとともに、最終的に得られる防
曇剤組成物の流動性も悪くなるので好ましくない。シリ
カゾルは、塗布後の成形品表面の防曇持続性を向上させ
るのに有効であるが、この成分割合が多くなると、成形
品表面の水分による濡れが悪くなるので、好ましくない
。塗布後の成形品表面の水分の濡れを向上させ、かつ、
防暑効果を持続させるには、アルミナゾルとシリカゾル
との混合割合を、上記範囲とするのが好ましい。The inorganic colloidal sol is a mixture of alumina sol and silica sol at a solid content weight ratio of 95.), 5/5 to 95 (total 100). Alumina sol is effective in improving the moisture wetting of the surface of the molded product after application, but when the proportion of this component increases, the antifogging durability deteriorates and the final antifogging agent composition This is not preferable because the fluidity also deteriorates. Silica sol is effective in improving the anti-fog durability of the surface of a molded product after application, but if the proportion of this component increases, the wetting of the surface of the molded product by moisture becomes poor, which is not preferable. Improves moisture wetting on the surface of the molded product after application, and
In order to maintain the heat protection effect, the mixing ratio of alumina sol and silica sol is preferably within the above range.
本発明に係る防曇剤組成物に占める第一成分（Ａ）及び
第二成分（Ｂ）の合計の割合は、１へ７４０重皺％（組
成物全体として１００重量％とする）とする。無８！１
質コロイドゾルの割合２が１重量％に満たないときは、
防曇剤組成物は有効成分が少なすぎて好ましくない。一
方４０重量％を超えるときは、防曇剤組成物の粘度が高
くなりすぎ、取り扱い難くなるので好ましくない。上記
範囲の中で特に好ましいのは、１５・９３０重量％の範
囲である。The total proportion of the first component (A) and the second component (B) in the antifogging agent composition according to the present invention is 1 to 740% by weight (the entire composition is 100% by weight). No 8!1
When the proportion 2 of the colloidal sol is less than 1% by weight,
Antifogging agent compositions are undesirable because they contain too little active ingredient. On the other hand, when it exceeds 40% by weight, the viscosity of the antifogging agent composition becomes too high, making it difficult to handle, which is not preferable. Particularly preferred within the above range is 15.930% by weight.
アルミナゾルは、通常市販されている製品そのもの、ま
たは通常市販さ紅ているアルミナ粉末を水に分散させて
水性ゾルとしたもの、いずれであってもよい。アルミナ
ゾルは、高濃度で水に分散させようとすると、分散液の
粘度が急激に高まるといういわゆるチキントロピー性を
示し、均質な分散液が得にくいが、コロイドミルの様な
媒質剪断内ｉ撹拌機を用いると、均質な分散液を得るこ
とができる。また、この分散液にシリカゾルを混合する
と、分散液の粘度を降下させることができる。The alumina sol may be a commercially available product itself, or an aqueous sol obtained by dispersing commonly available alumina powder in water. When alumina sol is dispersed in water at a high concentration, it exhibits so-called chicken tropism, in which the viscosity of the dispersion increases rapidly, making it difficult to obtain a homogeneous dispersion. Using this method, a homogeneous dispersion can be obtained. Furthermore, when silica sol is mixed into this dispersion, the viscosity of the dispersion can be lowered.
他方のシリカゾルは、多くの場合粒子表面は陰電荷に帯
電しているが、本発明においては、陰電荷に帯電してい
るものを用いるのは好ましくない。On the other hand, in most cases, the particle surface of the silica sol is negatively charged, but in the present invention, it is not preferable to use a silica sol that is negatively charged.
これは、上述のアルミナゾルは、粒子表面が陽電荷に帯
電しているために、陰電荷に帯電したシリカゾルと陽電
荷に帯電しているアルミナゾルとを混合すると、混合分
散液は急激に凝集し、デル化し、分散不良を生起する。This is because the above-mentioned alumina sol has a positively charged particle surface, so when a negatively charged silica sol and a positively charged alumina sol are mixed, the mixed dispersion rapidly aggregates. del, causing poor dispersion.
従って、シリカゾルは、粒子表面に陽電荷に帯電したも
のとするのがよい。Therefore, it is preferable that the silica sol has a positively charged particle surface.
本発明に係る防曇剤組成物は、第三成分（Ｃ）として、
水溶性アルミニウム塩を０．０５へ、２０重量％（防曇
剤組成物全体として１００重景％とする）含有する。The antifogging agent composition according to the present invention includes, as the third component (C),
It contains 0.05 to 20% by weight of a water-soluble aluminum salt (the entire antifogging agent composition is 100% by weight).
第主成分である水溶性アルミニウム塩は、塗布後の成形
品表面の水分による濡れの向上及び防曇持続性の向上を
はかるのに寄与する。The water-soluble aluminum salt, which is the first main component, contributes to improving the wetting of the surface of the molded product by moisture and improving the anti-fogging durability after application.
防曇剤組成物中の水溶性アルミニウム塩の量が、０．０
５重量％に満たないときは、成形品表面の水分による濡
れの向上及び防曇持続性の向上がはかれないので、好ま
しくない、一方、２０重量％を超えるときは、防曇持続
性が悪くなるので、好ましくない。上記範囲の中で特に
好ましいのは、０ 、１ ”、１５重電％の範囲である
。The amount of water-soluble aluminum salt in the antifogging agent composition is 0.0
If it is less than 5% by weight, it is not preferable because it will not improve wetting of the surface of the molded product with water and the durability of the anti-fogging property.On the other hand, if it exceeds 20% by weight, the durability of the anti-fogging property will be poor. Therefore, it is not desirable. Among the above ranges, particularly preferred are the ranges of 0, 1'' and 15% heavy electric charge.
第三成分となしうる水溶性アルミニウム塩は、水溶性の
ものであればその種類を問わないが、例えば硫酸アルミ
ニウム、硝酸アルミニウム、塩化アルミニウム、各種明
ばん、酢酸アルミニウムなどがあげられるが、これらの
中で特に好ましいのは塩化アルミニウムである。The water-soluble aluminum salt that can be used as the third component is not limited to any type as long as it is water-soluble, and examples include aluminum sulfate, aluminum nitrate, aluminum chloride, various alums, and aluminum acetate. Among them, aluminum chloride is particularly preferred.
本発明に係る防曇剤組成物は、第四成分（Ｄ）として、
非イオン系界面活性剤を０．０５へ・１５爪量％（防曇
剤組成物全体として１００重量％とする）含有する。The antifogging agent composition according to the present invention includes, as the fourth component (D),
Contains a nonionic surfactant in an amount of 0.05 to 15% (assuming the entire antifogging agent composition is 100% by weight).
第四成分である非イオン系界面活性剤は、防曇剤組成物
の分散安定性向上、更に成形品表面に塗布する際の塗布
作業能率向上、塗布した後の防曇性向上、等をはかるの
に寄与する。The nonionic surfactant, which is the fourth component, improves the dispersion stability of the antifogging agent composition, improves the efficiency of coating when applied to the surface of the molded product, and improves the antifogging property after coating. Contribute to.
防曇剤組成物中の非イオン系界面活性剤の量が、０．０
５重量％に満たないときは、防曇剤組成物の分散安定性
が悪く、成形品表面への塗布作業能率が悪く、かつ、塗
布した後の防曇性も向上しないので、好ましくない。一
方１５重量％を超えるときは、防曇剤組成物の分散性は
悪く、流動性も悪く（粘度が高くなる）、防曇持続性が
悪くなるので、好ましくない。上記範囲の中で特に好ま
しいのは、０．１へ一８重景％の範囲である。The amount of nonionic surfactant in the antifogging agent composition is 0.0
When the amount is less than 5% by weight, the dispersion stability of the antifogging agent composition is poor, the efficiency of coating on the surface of the molded article is poor, and the antifogging property after coating is not improved, which is not preferable. On the other hand, when it exceeds 15% by weight, the antifogging agent composition has poor dispersibility, poor fluidity (high viscosity), and poor antifogging durability, which is not preferable. Particularly preferred within the above range is a range of 0.1 to 18%.
第四成分となしうる非イオン系界面活性剤の具体例とし
ては、ポリオキシエチレンアルキルエーテル類、ポリオ
キシエチレンアルキル７エ／−ルエーテル類、ポリオキ
シエチレンアルキルエステル類、ソルビタンアルキルエ
ステル類、ポリオキシエチレンソルビタンアルキルエス
テル類、脂肪酸７／ｌロールアマイド類、セルロースエ
ーテル類などがあげられる。Specific examples of nonionic surfactants that can be used as the fourth component include polyoxyethylene alkyl ethers, polyoxyethylene alkyl ethers, polyoxyethylene alkyl esters, sorbitan alkyl esters, and polyoxyethylene alkyl ethers. Examples include ethylene sorbitan alkyl esters, fatty acid 7/l rollamides, and cellulose ethers.
防曇剤組成物は、水あるいはアルコールのような水性な
いし親水性の媒体中に分散さ＃ｔた状態で塗布に供され
る。通常適当な媒体は水である。The antifogging agent composition is applied after being dispersed in an aqueous or hydrophilic medium such as water or alcohol. Usually a suitable medium is water.
本発明に係る防曇剤組成物は、以上のとおり四成分より
なるが、第一成分の分散性を助ける、分散液の流動性を
調節する等の目的で、さらに少量の他の成分を含んでい
てもよい。例えば−価の無機酸または有機酸があげられ
る。The antifogging agent composition according to the present invention is composed of the four components as described above, but may further contain small amounts of other components for the purpose of aiding the dispersibility of the first component and adjusting the fluidity of the dispersion. It's okay to stay. Examples include -valent inorganic acids or organic acids.
本発明に係る防曇剤組成物は、そのまま、または水で希
釈して、防曇性を賦与したい成形品の表面に塗布し、水
を揮散させると、成形品表面に無機室コロイドゾル粒子
と非イオン系界面活性剤とよりなる被膜が形成される。The antifogging agent composition according to the present invention is applied as it is or diluted with water to the surface of a molded article to which it is desired to impart antifogging properties, and when the water is evaporated, inorganic colloidal sol particles and non-fog particles are formed on the surface of the molded article. A film made of ionic surfactant is formed.
この被膜が、優れた防曇性を発揮し、かつ、これを長期
間持続するという効果を発揮する。This coating exhibits excellent antifogging properties and maintains this for a long period of time.
本発明に係る防曇剤組成物を水で希釈する場合は、その
使用目的、使用方法（塗布方法）、使用場所等に応じて
、３００倍まで希釈することができる。When diluting the antifogging agent composition according to the present invention with water, it can be diluted up to 300 times depending on the purpose of use, method of use (coating method), location of use, etc.
本発明に係る防曇剤組成物を塗布することができる成形
品としては、本発明の特性を損なわないものであれば、
格別に制限はない。−船釣にその特徴が顕著に認められ
る成形品としては、プラスチック、無機プラス、透明セ
ラミック、金属、鏡面材料などがある。これらの中で待
に実用価値の高い例として、プラスチック成形品、プラ
スチックフィルム、無機がラスレンズ、浴室の窓、自動
車または電車等の窓がある。Molded articles to which the antifogging agent composition according to the present invention can be applied include those that do not impair the characteristics of the present invention.
There are no particular restrictions. - Molded products that have distinctive characteristics for boat fishing include plastics, inorganic plastics, transparent ceramics, metals, and mirror-finish materials. Among these, examples of high practical value include plastic molded products, plastic films, inorganic lath lenses, bathroom windows, and windows for automobiles or trains.
本発明に係る防曇剤組成物を、そのまま、または水で希
釈して成形品表面に塗布するには、ロールコート法、デ
イツプコート法、ハケ塗り法、スプレーコート法、バー
コード法、ナイフコート法等、それ自体公知の方法によ
ることができる６成形品の表面に塗布した防曇剤組成物
を乾燥させるには、自然乾燥法、強制乾燥法によればよ
い。The antifogging agent composition according to the present invention can be applied to the surface of a molded article as it is or after being diluted with water by a roll coating method, a dip coating method, a brush coating method, a spray coating method, a barcoding method, or a knife coating method. 6. The antifogging agent composition applied to the surface of the molded article may be dried by a natural drying method or a forced drying method.
強制乾燥するときは、熱風乾燥法、赤外線照射法などが
採用できる。For forced drying, hot air drying method, infrared irradiation method, etc. can be used.
成形品の表面に防曇剤組成物を塗布し、分散媒である水
を乾燥、揮散させた後の固形物の付着風は、成形品の防
曇性を表面全体を、均一に無機質コロイドゾルで被覆す
る最少量でよい。その量としては、ｏ、ｏ ｏ ｉ−・
−、１、５ｇ／翰２程度で、この中でも０．００５”−
０，７５ｇ／＋ａ２の範囲が好適である。After applying the antifogging agent composition to the surface of the molded product and drying and volatilizing the water as a dispersion medium, the air adhering to the solid particles will improve the antifogging properties of the molded product evenly over the entire surface with the inorganic colloidal sol. The minimum amount to cover is sufficient. The amount is o, o o i-・
-, about 1.5g/Kan 2, among which 0.005"-
A range of 0.75 g/+a2 is preferred.
成形品表面と、本発明に係る防曇剤組成物に由来する塗
膜との、接着性が充分でない場合には、防曇剤組成物を
塗布する前に、成形品表面に改質処理を施すのが好まし
い。表面改質処理法としては、アンダーコート処理を施
す方法（例えば、特公昭５０ ５７３３号公報に記載さ
れているように、アクリル系樹脂を主成分とした被覆剤
を塗布する方法）、成形品表面に、本発明に係る無８！
質コロイドゾルとは反対の陰電荷を有する成分を塗布す
る方法、成形品表面にプラスチックを施して表面を改質
する方法、成形品表面にコロナ放電処理を施して表面を
改質する方法等があげられる。If the adhesion between the surface of the molded product and the coating film derived from the antifog composition according to the present invention is insufficient, the surface of the molded product may be subjected to a modification treatment before applying the antifog composition. It is preferable to apply Surface modification treatment methods include a method of applying an undercoat treatment (for example, a method of applying a coating agent mainly composed of acrylic resin, as described in Japanese Patent Publication No. 50 5733), a method of applying a coating agent mainly composed of acrylic resin, No. 8 according to the present invention!
Examples include a method of applying a component with a negative charge opposite to that of the colloidal sol, a method of applying plastic to the surface of the molded product to modify the surface, and a method of modifying the surface of the molded product by subjecting it to corona discharge treatment. It will be done.
「発明の効果ｊ
本発明に係る防曇剤組成物は、以上説明したとおりであ
り、次のように特別に顕著な効果を奏し、その産業上の
利用価値は極めて大である。``Effects of the Invention j'' The antifogging agent composition according to the present invention is as explained above, and exhibits particularly remarkable effects as described below, and its industrial utility value is extremely large.
（１）本発明に係る防曇剤組成物は、特定の粒径のアル
ミナゾルとシリカゾルとが、特定の割合で混合されてお
り、かつ、水溶性アルミニウム塩及び非イオン系界面活
性剤で分散されているので、組成物の粘度は低く取り扱
いが容易であり、分散状態も安定で、長期間の保存が可
能である。(1) The antifogging agent composition according to the present invention includes alumina sol and silica sol of a specific particle size mixed in a specific ratio, and is dispersed with a water-soluble aluminum salt and a nonionic surfactant. Therefore, the viscosity of the composition is low and easy to handle, the dispersion state is stable, and it can be stored for a long period of time.
（２）本発明に係る防曇剤組成物は、特定の粒径のアル
ミナゾルとシリカゾルとが、特定の割合で混合されてお
り、かつ、水溶性アルミニウム塩を含んでいるので、成
形品表面に塗布し塗布膜を形成したときに、成形品の透
明性は低下されず、成形品表面の濡れ性（防曇性）、防
曇効果の持続性においても優れた効果を示す。(2) The antifogging agent composition according to the present invention is a mixture of alumina sol and silica sol with a specific particle size in a specific ratio, and also contains a water-soluble aluminum salt, so that it does not coat the surface of the molded product. When applied to form a coating film, the transparency of the molded product is not reduced, and it exhibits excellent wettability (antifogging properties) on the surface of the molded product and durability of the antifogging effect.
「実施例Ｊ
以下、本発明を実施例にもとづいて詳細に説明するが、
本発明はその要旨を超えない限り、以下の例に限定され
るものではない６
実施例１
（１）アルミナゾルの調製
容器にいれた水を撹拌しながら、アルミニウムオキサイ
ドＣ（日本アエロジル（株）社製、平均粒子径２０ミリ
ミクロン）を添加し、固形分２５重量％の分散液をｇ９
１ Ｌだ。この分散液を調製する過程で、粘度が上昇し
たので、分散液を攪拌しながら硝酸を添加し、液のｐＨ
を４．３にｆ１４ｆｆ１５した。“Example J The present invention will be explained in detail based on Examples below.
The present invention is not limited to the following examples unless it exceeds the gist of the invention.6 Example 1 (1) Preparation of alumina sol While stirring water in a container, aluminum oxide C (Nippon Aerosil Co., Ltd.) was used. 25% solids by weight, and 9 g of a dispersion with a solid content of 25% by weight
It's 1 L. During the process of preparing this dispersion, the viscosity increased, so nitric acid was added while stirring the dispersion to adjust the pH of the liquid.
I changed it to 4.3 f14ff15.
（２）消泡剤液の７！４製
容器にいれた水を撹拌しながら、シリコーンエマルノタ
ン（東しシリコーン（株）社製、Ｓ Ｍ ５５１２、固
形分４５重量％）を添加し、固形分１０重量％のシリコ
ーンエマルジョン（消泡剤液）を調製した。(2) Add silicone emalnotane (manufactured by Toshi Silicone Co., Ltd., SM 5512, solid content 45% by weight) while stirring the water placed in a 7!4 container of antifoaming agent liquid, A silicone emulsion (defoaming agent liquid) having a solid content of 10% by weight was prepared.
（３） 防曇剤組成物の調製
」１記（１）で調製したアルミナゾル分散液７２グラム
に、水１５グラムを加えたにの液を撹拌しながら、陽電
荷に帯電したシリカゾル（８産化学（株）社製、商品名
スノーテックスＡＫ、固形分３０重量％、平均粒子径２
０ミリミクロン）を７グラム、塩化アルミニウム（６水
塩）（和光紬薬工業（株）社製、試薬特級）を１グラム
、非イオン系界面活性剤としてポリオキシエチレンソル
ビタンモノラウレート（日本油脂（株）社製、商品名Ｌ
Ｔ−２２１）を４グラム、前記（２）においてｙ！４！
１た消泡剤液１グラムを添加し、目的とする防曇剤組成
物を得た。(3) Preparation of antifogging agent composition" 15 grams of water was added to 72 grams of the alumina sol dispersion prepared in 1. Co., Ltd., product name Snowtex AK, solid content 30% by weight, average particle size 2
0 millimicrons), 7 grams of aluminum chloride (hexahydrate) (manufactured by Wako Tsumugi Pharmaceutical Co., Ltd., special reagent grade), and polyoxyethylene sorbitan monolaurate (NOF) as a nonionic surfactant. Manufactured by Co., Ltd., product name L
4 grams of T-221), y! in (2) above. 4!
1 gram of antifoaming agent liquid was added to obtain the desired antifoaming agent composition.
（４）防曇剤組成物の評価
上記（３）で得られた防曇剤組成物について、以下に記
載した方法で、分散安定性お上Ｖ流動性を評価した。結
果を第１表に示す。(4) Evaluation of antifogging agent composition The antifogging agent composition obtained in the above (3) was evaluated for dispersion stability and fluidity using the methods described below. The results are shown in Table 1.
■ 分散安定性
得られた防曇剤組成物を、常温で６力月間放置したのち
、外観を内服で観察し、評価した。評価結果の表示は、
次のようにした。(2) Dispersion Stability The obtained antifogging agent composition was allowed to stand at room temperature for 6 months, and then the appearance was observed and evaluated by oral administration. To display the evaluation results,
I did it like this:
ｒＯＪ・・・・・・６力月以上放置しても、外観は変わ
らない。rOJ... Even if left for more than 6 months, the appearance will not change.
「Δ」・・・・・・放置後６力月未満で、わずかに固形
分の分離、沈降が生ずるが、強く振盪す
ると、再分散する。"Δ": Slight separation and sedimentation of solids occurs after standing for less than 6 months, but when shaken vigorously, they are redispersed.
「×」・・・・・・放置開始直後に固形物は凝集し、デ
ル化する。"×": Immediately after the start of standing, the solid matter aggregates and becomes a delta.
■ 流動性
得られた防曇剤組成物を、常温″ｃ６カ月間放置したの
ち、２５℃における粘度をＢ型帖度計で測定した。(2) Fluidity After the obtained antifogging agent composition was left at room temperature for 6 months, the viscosity at 25°C was measured using a B-type meter.
評価結果の表示は、次のようにした。The evaluation results were displayed as follows.
「１」・・・・・・防曇削調製後６カ月経過後の粘度が
、２００ （１ｃｐｓ未満のもの。"1": Viscosity 6 months after anti-fogging preparation is less than 200 cps (less than 1 cps).
１°２１・・・・・・防曇削調製後６カ月経過後の粘度
が、２００ （１ｃｐｓ以上のもの。1°21... Viscosity 6 months after anti-fogging preparation is 200 (1 cps or more).
実施例２
（１）非イオン系界面活性剤分散液の調製容器にいれた
水を撹拌しながら、メチルセルローズ（信越化学工業（
株）社製、商品名メトローズ５Ｍ−１５）を添加し、１
０重景％濃度の分散液を調製した６
（２）防曇剤組成物の調製
実施例１（１）において調製したアルミナゾル分散液７
２グラムに水９グラムを加えた。この液を撹拌しながら
、シリカゾル（スフ−テックスＡＫ）を７グラム、塩化
アルミニウム（６水塩）を１グラム、上記（１）におい
て調製した分散液１０グラム、および実施例１（２）に
おいて調製したｊｉ’ｆ泡剤液全剤液ラム添加し、目的
とする防曇剤組成物を得た。Example 2 (1) Preparation of nonionic surfactant dispersion While stirring water in a container, add methylcellulose (Shin-Etsu Chemical Co., Ltd.).
Co., Ltd., trade name Metrose 5M-15) was added, and 1
A dispersion with a concentration of 0% concentration was prepared 6 (2) Preparation of antifogging agent composition Alumina sol dispersion prepared in Example 1 (1) 7
9 grams of water was added to the 2 grams. While stirring this liquid, add 7 grams of silica sol (Suf-Tex AK), 1 gram of aluminum chloride (hexahydrate), 10 grams of the dispersion prepared in (1) above, and the dispersion prepared in Example 1 (2). The entire JI'F foaming agent solution was added to the ram to obtain the desired antifogging agent composition.
（３） 防曇剤組成物の評価
実施例１（４）に記載の方法で特性を評価し、その結果
を、第１表に示す。(3) Evaluation of antifogging agent composition Characteristics were evaluated by the method described in Example 1 (4), and the results are shown in Table 1.
実施例３
実施例１（１）において調製したアルミナゾル分散液８
．４グラムに、水を２５．６グラム加えた。Example 3 Alumina sol dispersion 8 prepared in Example 1 (1)
．． To 4 grams, 25.6 grams of water was added.
この液を撹拌しながら、シリカゾル（スフ−テックスＡ
Ｋ）を６０グラム、硝酸アルミニウム（９水塩）（和光
紬薬工業（株）社製、試薬特級）を２グラム、非イオン
Ｍ％面活性剤としてポリオキシエチレンソルビタンモノ
ラウレート（ＬＴ−２２１）を４グラム、および実施例
１（２）において調製した消泡剤液を１グラム添加し、
目的とする防曇剤組成物を得た。While stirring this liquid, add silica sol (Suf-Tex A).
60 grams of aluminum nitrate (9 hydrate) (manufactured by Wako Tsumugi Kogyo Co., Ltd., special grade reagent), and polyoxyethylene sorbitan monolaurate (LT-221) as a nonionic M% surfactant. ) and 1 g of the antifoam solution prepared in Example 1 (2),
The desired antifogging agent composition was obtained.
得られた防曇剤組成物の特性を、実施例１（４）に記載
の方法で評価し、その結果を第１表に示す。The properties of the obtained antifogging agent composition were evaluated by the method described in Example 1 (4), and the results are shown in Table 1.
比較例１
実施例１（１）において調製したアルミナゾル分散液８
０グラムに水１４グラムを加えた。この液を攪拌しなが
ら、塩化アルミニウム（６水塩）を１グラム、ポリオキ
シエチレンソルビタンモ／ラウレー）（ＬＴ−２２１）
を４グラムおよび実施例１（２）において調製した消泡
剤液を１グラム添加し、防曇剤組成物を得た。Comparative Example 1 Alumina sol dispersion 8 prepared in Example 1 (1)
14 grams of water was added to 0 grams. While stirring this solution, add 1 gram of aluminum chloride (hexahydrate) and polyoxyethylene sorbitan mo/lauray) (LT-221).
and 1 g of the antifoaming agent liquid prepared in Example 1 (2) were added to obtain an antifogging agent composition.
比較例２
シリカゾル（スノーテックスＡＫ）８０グラムに、水を
２グラム加えた。この液を撹拌しながら、塩化アルミニ
ウム（６水塩）を１グラム、ポリオキシエチレンソルビ
タンモ／ラウレー）（ＬＴ−２２１）を１６グラムおよ
び実施例１（２）において調製した消泡剤液を１グラム
添加し、防曇剤組成物を得た。Comparative Example 2 2 grams of water was added to 80 grams of silica sol (Snowtex AK). While stirring this solution, add 1 gram of aluminum chloride (hexahydrate), 16 grams of polyoxyethylene sorbitan mo/laure (LT-221), and 1 gram of the antifoaming agent solution prepared in Example 1 (2). gram was added to obtain an antifogging agent composition.
得られた防曇剤組成物の特性を、上と同様に評価し、結
果を第１表に示す。The properties of the obtained antifogging agent composition were evaluated in the same manner as above, and the results are shown in Table 1.
比較例３
陰電荷に帯電したシリカゾル（口述化学（株）社製、ス
フ−テックス３０、固形分３０重景％）６６．７グラム
に、水を２７．３グラム加えた。この液を撹拌しながら
、硝酸アルミニウム（９水塩）を２グラム、ポリオキシ
ェチレンソルビタンモノラウレー）（ＬＴ−２２１＞を
４グラム、および実施例１（２）において調製した消泡
剤液を１グラム添加し、防曇剤組成物を得た。Comparative Example 3 27.3 grams of water was added to 66.7 grams of negatively charged silica sol (manufactured by Kuchikagaku Co., Ltd., Suf-Tex 30, solid content 30%). While stirring this solution, add 2 grams of aluminum nitrate (nase hydrate), 4 grams of polyoxyethylene sorbitan monolaure (LT-221), and the antifoaming agent solution prepared in Example 1 (2). 1 gram of was added to obtain an antifogging agent composition.
得られた防曇剤組成物の特性を、実施例におけると同様
に評価し、その結果を第１表に示す。The properties of the obtained antifogging agent composition were evaluated in the same manner as in the examples, and the results are shown in Table 1.
比較例４
実施例（１）において調製したアルミナゾル分散液５４
グラムに、水１１グラムを加えた。この液を撹拌しなが
ら、シリカゾル（スノーテックスＡＫ）を５グラム、塩
化アルミニウム（６水塩）を２５グラム、ポリオキシエ
チレンソルビクンモノラウレー）（ＬＴ−２２１）を４
グラムおよび実施例１（２）において調製した消泡剤液
を１グラム添加し、防曇剤組成物を得た。Comparative Example 4 Alumina sol dispersion 54 prepared in Example (1)
11 grams of water were added to the grams. While stirring this liquid, add 5 grams of silica sol (Snowtex AK), 25 grams of aluminum chloride (hexahydrate), and 4 grams of polyoxyethylene sorbicun monolaure) (LT-221).
gram and 1 gram of the antifoaming agent liquid prepared in Example 1 (2) were added to obtain an antifogging agent composition.
得られた防曇剤組成物の特性を、実施例におけると同様
に評価し、その結果を第１表に示す。The properties of the obtained antifogging agent composition were evaluated in the same manner as in the examples, and the results are shown in Table 1.
参考例１〜１１
実施例Ｌ〜３、比較例１〜４に示した各防曇剤組成物の
各々を、水で１５０倍に希釈して、Ｂ１ｌ１類の塗布液
を準備した。Reference Examples 1 to 11 Each of the antifogging agent compositions shown in Examples L to 3 and Comparative Examples 1 to 4 was diluted 150 times with water to prepare a B111 type coating liquid.
これら塗布液をそれぞれ、ポリエチレンテレフタレート
フィルム表面にスプレーフート法で塗布し、乾燥後の固
形分の訊を０．２５グラム／１１２ とした。塗布液を
フィルムに塗布する際に、次の事項をｍ察した。結果を
、＠２表に示す。Each of these coating solutions was applied to the surface of a polyethylene terephthalate film by a spray foot method, and the solid content after drying was adjusted to 0.25 g/112. When applying the coating liquid to the film, the following points were observed. The results are shown in Table @2.
■ 表面濡れ状況
水をいれた水槽の上部に、フィルムの塗布膜を形成した
表面を水槽内部に向けて配置し、外気温度をＯ°±２℃
に、水温を１５℃に保持し、温度を上のようにセットし
てから６０分経過後に、フィルム表面の濡れ状況を肉眼
で観察判定する。評価結果の表示は、次のようにした。■Surface wetness condition: Place the film-coated surface on the top of a water tank facing the inside of the tank, and set the outside temperature to 0°±2°C.
First, the water temperature was maintained at 15° C., and after 60 minutes had elapsed since the temperature was set as above, the wetting state of the film surface was observed and judged with the naked eye. The evaluation results were displayed as follows.
「○」・・・・・・表面の濡れが速い。"○"...The surface gets wet quickly.
「Δ」・・・・・・表面の濡れが若干遅い。"Δ"...Wetting of the surface is a little slow.
ｒＸＪ・・・・・・表面の濡れが遅い。rXJ... Surface wetting is slow.
■ 防備効果持続性
上と同じ水槽上に、フィルムを同様に配置し、水温４５
°±２℃に、外気温度を常温に保持し、試験開始直後、
１力月経過後、６力月経過後、１２力月経過後の各時点
における、フィルム表面の防曇性を肉眼で評価した。評
価結果の表示は、次のとおりとした。■ Durability of protective effect Place the film in the same way as above on the same water tank, and set the water temperature to 45%.
Immediately after the start of the test, the outside temperature was kept at room temperature at °±2 °C.
The antifogging properties of the film surface were visually evaluated at each time point after 1 month, 6 months, and 12 months. The evaluation results were displayed as follows.
［１，１・・・・・・防曇性良好
「２」・・・・・・防曇性やや不良
「３」・・・・・・防曇性不良
「４」・・・・・・防曇性者しく不良
第 ２ 表
第１表および＠２表より、次のことが明らかとなる６
（１）本発明に係る防曇剤組成物は、分散安定性、流動
性ともに優れている。[1,1... Good anti-fog property "2"... Somewhat poor anti-fog property "3"... Poor anti-fog property "4"... From Tables 1 and 2, the following is clear: (1) The antifogging agent composition according to the present invention has excellent dispersion stability and fluidity. .
（２）本発明に係る防曇剤組成物を塗布した成形品表面
は、表面が濡れ易く水滴がつがず、がっ、防曇効果の持
続性に優れている。(2) The surface of a molded article coated with the antifogging agent composition according to the present invention is easily wettable, does not attract water droplets, and has an excellent long-lasting antifogging effect.
（３）これに対して比較例のものは、分散安定性、流動
性、成形品に塗布したあとの表面の濡れ易さ、防曇効果
持続性の全てにおいて優れた性質を示すものはない。(3) On the other hand, none of the comparative examples exhibit excellent properties in terms of dispersion stability, fluidity, ease of wetting the surface after being applied to a molded article, and durability of the antifogging effect.
Claims (1)
ミナゾルと（Ｂ）シリカゾルとが、固形分の重量比で９
５〜５／５〜９５全体で１００とする）の無機質コロイ
ドゾルを、固形分として１〜４０重量％（Ｃ）水溶性ア
ルミニウム塩を０．０５〜２０重量％（Ｄ）非イオン系
界面活性剤を０．０５〜１５重量％含有することを特徴
とする防曇剤組成物。1) (A) alumina sol and (B) silica sol with an average particle diameter of 100 millimicrons or less have a solid content weight ratio of 9
5-5/5-95) inorganic colloidal sol, 1-40% by weight as solid content (C) 0.05-20% by weight of water-soluble aluminum salt (D) Nonionic surfactant An antifogging agent composition containing 0.05 to 15% by weight of
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18506789A JPH0350288A (en) | 1989-07-18 | 1989-07-18 | Anti-fogging agent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18506789A JPH0350288A (en) | 1989-07-18 | 1989-07-18 | Anti-fogging agent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0350288A true JPH0350288A (en) | 1991-03-04 |
Family
ID=16164229
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18506789A Pending JPH0350288A (en) | 1989-07-18 | 1989-07-18 | Anti-fogging agent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0350288A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0748835A1 (en) * | 1995-06-17 | 1996-12-18 | Degussa Aktiengesellschaft | Use of a water spreading coating on a hollow plastic panel |
| US5820978A (en) * | 1995-11-09 | 1998-10-13 | Minnesota Mining And Manufacturing Company | Durability improved colloidal silica coating |
| WO1998055573A1 (en) * | 1997-06-04 | 1998-12-10 | Toto Ltd. | Method for surface pretreatment before formation of photocatalytic hydrophilic film, and detergent and undercoat composition for use in the same |
| JP2012188565A (en) * | 2011-03-11 | 2012-10-04 | Mitsubishi Electric Corp | Coating composition, method of producing the same, and water-repellent member |
-
1989
- 1989-07-18 JP JP18506789A patent/JPH0350288A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0748835A1 (en) * | 1995-06-17 | 1996-12-18 | Degussa Aktiengesellschaft | Use of a water spreading coating on a hollow plastic panel |
| US5820978A (en) * | 1995-11-09 | 1998-10-13 | Minnesota Mining And Manufacturing Company | Durability improved colloidal silica coating |
| WO1998055573A1 (en) * | 1997-06-04 | 1998-12-10 | Toto Ltd. | Method for surface pretreatment before formation of photocatalytic hydrophilic film, and detergent and undercoat composition for use in the same |
| JP2012188565A (en) * | 2011-03-11 | 2012-10-04 | Mitsubishi Electric Corp | Coating composition, method of producing the same, and water-repellent member |
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