JPH0348246A - Silver salt diffusion transfer method - Google Patents
Silver salt diffusion transfer methodInfo
- Publication number
- JPH0348246A JPH0348246A JP18404089A JP18404089A JPH0348246A JP H0348246 A JPH0348246 A JP H0348246A JP 18404089 A JP18404089 A JP 18404089A JP 18404089 A JP18404089 A JP 18404089A JP H0348246 A JPH0348246 A JP H0348246A
- Authority
- JP
- Japan
- Prior art keywords
- image
- receiving sheet
- silver
- diffusion transfer
- sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000012546 transfer Methods 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims description 28
- 238000009792 diffusion process Methods 0.000 title claims description 22
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 title claims description 15
- 229910052709 silver Inorganic materials 0.000 claims abstract description 41
- 239000004332 silver Substances 0.000 claims abstract description 41
- -1 silver halide Chemical class 0.000 claims abstract description 40
- 239000000839 emulsion Substances 0.000 claims abstract description 31
- 238000012545 processing Methods 0.000 claims abstract description 29
- 238000011161 development Methods 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920000642 polymer Polymers 0.000 claims abstract description 11
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 8
- 238000010521 absorption reaction Methods 0.000 claims abstract description 7
- 239000011780 sodium chloride Substances 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 20
- 230000004913 activation Effects 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 abstract description 12
- 239000007788 liquid Substances 0.000 abstract description 6
- 229920001567 vinyl ester resin Polymers 0.000 abstract description 6
- 229920002239 polyacrylonitrile Polymers 0.000 abstract description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract description 3
- 239000010410 layer Substances 0.000 description 38
- 239000000243 solution Substances 0.000 description 23
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 16
- 108010010803 Gelatin Proteins 0.000 description 14
- 229920000159 gelatin Polymers 0.000 description 14
- 239000008273 gelatin Substances 0.000 description 14
- 235000019322 gelatine Nutrition 0.000 description 14
- 235000011852 gelatine desserts Nutrition 0.000 description 14
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 11
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 8
- 239000000084 colloidal system Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 229920000247 superabsorbent polymer Polymers 0.000 description 8
- 238000000576 coating method Methods 0.000 description 7
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 6
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 6
- 239000001768 carboxy methyl cellulose Substances 0.000 description 6
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 6
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 5
- 238000003672 processing method Methods 0.000 description 5
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000007127 saponification reaction Methods 0.000 description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- NPERTKSDHFSDLC-UHFFFAOYSA-N ethenol;prop-2-enoic acid Chemical compound OC=C.OC(=O)C=C NPERTKSDHFSDLC-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000004848 polyfunctional curative Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 150000003346 selenoethers Chemical class 0.000 description 3
- 239000010802 sludge Substances 0.000 description 3
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 3
- 235000019345 sodium thiosulphate Nutrition 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical class C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 229910021607 Silver chloride Inorganic materials 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000001246 colloidal dispersion Methods 0.000 description 2
- FGRVOLIFQGXPCT-UHFFFAOYSA-L dipotassium;dioxido-oxo-sulfanylidene-$l^{6}-sulfane Chemical compound [K+].[K+].[O-]S([O-])(=O)=S FGRVOLIFQGXPCT-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229920000578 graft copolymer Polymers 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 2
- 229910001961 silver nitrate Inorganic materials 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- 239000001488 sodium phosphate Substances 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- XSOKHXFFCGXDJZ-UHFFFAOYSA-N telluride(2-) Chemical compound [Te-2] XSOKHXFFCGXDJZ-UHFFFAOYSA-N 0.000 description 2
- CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- DEWLEGDTCGBNGU-UHFFFAOYSA-N 1,3-dichloropropan-2-ol Chemical compound ClCC(O)CCl DEWLEGDTCGBNGU-UHFFFAOYSA-N 0.000 description 1
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- ZEQIWKHCJWRNTH-UHFFFAOYSA-N 1h-pyrimidine-2,4-dithione Chemical compound S=C1C=CNC(=S)N1 ZEQIWKHCJWRNTH-UHFFFAOYSA-N 0.000 description 1
- JAAIPIWKKXCNOC-UHFFFAOYSA-N 1h-tetrazol-1-ium-5-thiolate Chemical class SC1=NN=NN1 JAAIPIWKKXCNOC-UHFFFAOYSA-N 0.000 description 1
- LLCOQBODWBFTDD-UHFFFAOYSA-N 1h-triazol-1-ium-4-thiolate Chemical class SC1=CNN=N1 LLCOQBODWBFTDD-UHFFFAOYSA-N 0.000 description 1
- IVIDDMGBRCPGLJ-UHFFFAOYSA-N 2,3-bis(oxiran-2-ylmethoxy)propan-1-ol Chemical compound C1OC1COC(CO)COCC1CO1 IVIDDMGBRCPGLJ-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- CUGZWHZWSVUSBE-UHFFFAOYSA-N 2-(oxiran-2-ylmethoxy)ethanol Chemical compound OCCOCC1CO1 CUGZWHZWSVUSBE-UHFFFAOYSA-N 0.000 description 1
- HSDVRWZKEDRBAG-UHFFFAOYSA-N 2-[1-(oxiran-2-ylmethoxy)hexoxymethyl]oxirane Chemical compound C1OC1COC(CCCCC)OCC1CO1 HSDVRWZKEDRBAG-UHFFFAOYSA-N 0.000 description 1
- NNRAOBUKHNZQFX-UHFFFAOYSA-N 2H-benzotriazole-4-thiol Chemical compound SC1=CC=CC2=C1NN=N2 NNRAOBUKHNZQFX-UHFFFAOYSA-N 0.000 description 1
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 1
- MECNWXGGNCJFQJ-UHFFFAOYSA-N 3-piperidin-1-ylpropane-1,2-diol Chemical compound OCC(O)CN1CCCCC1 MECNWXGGNCJFQJ-UHFFFAOYSA-N 0.000 description 1
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- ZZIHEYOZBRPWMB-UHFFFAOYSA-N 5-chloro-1,3-dihydrobenzimidazole-2-thione Chemical compound ClC1=CC=C2NC(S)=NC2=C1 ZZIHEYOZBRPWMB-UHFFFAOYSA-N 0.000 description 1
- KHCKAAVMRXTNOS-UHFFFAOYSA-N 6-sulfanyl-2-sulfanylidene-1h-pyrimidin-4-one Chemical compound SC1=CC(=O)NC(=S)N1 KHCKAAVMRXTNOS-UHFFFAOYSA-N 0.000 description 1
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- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
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- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
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- 239000010931 gold Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
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- NWVVVBRKAWDGAB-UHFFFAOYSA-N hydroquinone methyl ether Natural products COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
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- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
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- 229910052742 iron Inorganic materials 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
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- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000011824 nuclear material Substances 0.000 description 1
- 150000004010 onium ions Chemical class 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
- 235000019252 potassium sulphite Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- NDGRWYRVNANFNB-UHFFFAOYSA-N pyrazolidin-3-one Chemical class O=C1CCNN1 NDGRWYRVNANFNB-UHFFFAOYSA-N 0.000 description 1
- WHMDPDGBKYUEMW-UHFFFAOYSA-N pyridine-2-thiol Chemical compound SC1=CC=CC=N1 WHMDPDGBKYUEMW-UHFFFAOYSA-N 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- 229940047670 sodium acrylate Drugs 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical group [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 150000004772 tellurides Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000003536 tetrazoles Chemical class 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は銀塩拡散転写法に関するものであり、特に受偽
シートに高吸水性高分子化合物を用いて写真性能および
乾燥性を改良した銀塩拡散転写法に関するものである．
（発明の背景）
銀塩拡散転写法（ＤＴＲ法）は、米国特許第２３５２０
１４号に記載されているとおり周知である．ＤＴＲ法に
おいては、ＩＩ錯塩は拡散によってハロゲン化銀剤層か
ら受像層へ像に従って転写され、それらは多くの場合は
物理現像核の存在下に銀像に変換される．この目的のた
め、像に従って露光されたハロゲン化銀乳剤層は、現像
主薬およびハロゲン化銀錯化剤の存在下に受像層と接触
配置するか、接触するようにもたらされ、未露光ハロゲ
ン化銀を可溶性銀錯塩に変換させる．
ハロゲン化銀乳剤層の露光された部分において、ハロゲ
ン化銀は銀に現像され（化学現像）、従ってそれはそれ
以上溶解できず、従って拡散できない．
ハロゲン化銀乳剤層の未露光部分において、ハロゲン化
銀は可溶性銀塩に変換され、それが受倣層へ転写され、
そこでそれらが通常は現像核の存在下に銀像を形威する
．
直接ポジ用ハロゲン化銀乳剤では、露光、未露光部のハ
ロゲン化銀の作用は逆になる．ＤＴＲ法は、書類の再生
、平版印刷版の作製、版下材料の作製およびインスタン
ト写真などの広範囲の応用が可能である．
かような転写銀像を得るための最も一般的な拡散写真現
像方式は、ＤＴＲ用プロセッサー中の現像液中に受像シ
ートと露光済のネガシートとを受像層と感光層とが向い
合う形で挿入、浸漬し、スクイーズ・ローラーで絞って
両シートの間に必要量の現像処理液を残して余分の液を
除去し少時放置後両シートを剥すことによって受像シー
ト上に転写銀画像を得るものであった．
一方、受像シートのみを現像処理液に浸漬し、ついで現
像処理液系外で露光済のネガシートと密着してから分離
する方式も古くから提案されている（米国特許第３１７
９５１７号、特公昭６３６３８９３号等）．
しかしながら、後者の方式は、受像シートに含浸される
処理液の量が少なく、そのために転写濃度が低く（特に
受像シートがフィルム支持体の場合に転写濃度が低くな
る）コントラスト低いという問題があった．
（発明が解決すべきＬｌ題）
本発明の目的は、高い転写濃度とコントラストを得るこ
とができる銀塩拡散転写法を提供することにある．また
、本発明は上記目的に加えて、受像シートの乾燥付加が
少なく、また処理液の汚れが少ない銀塩拡散転写法を提
供することにある．（課題を解決するための手段）
本発明の目的は、現像処理液中に受像シートのみを浸漬
した後、該現像処理液系外で、ハロゲン化銀からなる乳
剤層を有するネガシートと密着しその後両シートを分離
する銀塩拡散転写法において、該受像シートに０．９％
塩化ナトリウム水溶液中での吸水倍率が４０ｇ／ｇ以上
の高吸水性高分子化合物を含有させることによって達或
された．本発明に於いて高吸水性高分子化合物の尺度で
ある吸水倍率は、０．９％ＮａＣｊ！水溶液（２５″）
中に被化合物を１０ｇ浸漬し１２０″Ｃの恒温恒湿器で
１時間加熱処理した後重量を測定し吸水量を出すことに
より容易に求めることが出来る．吸水倍率が４０ｇ／ｇ
以上の高分子化合物の例としては、アクリル酸ソーダ重
合体類、アクリル酸・ビニルアルコール共重合体類など
がある．ポリエチレンオキシド変戒物、ゼラチン、カル
ボキシメチルセルロースなどは吸水倍率が３０ｇ／ｇ以
下で有効でない．
かかる高吸水性高分子化合物の好ましい例としては、特
開昭５２−１４６８９号、同５３−５０２９０号、同５
１−１６０３８７号、同５３−６５５９７号、同５３−
８２６６６’号、同５３−１０４６５２号、同５３−１
０４６９１号、同５３−１０５５８９号、特公昭５３−
１３４９５号、同５３−１３６７８号等に記載された、
少なくともビニルエステルとエチレン系不飽和カルボン
酸又はその誘導体とからなる共重合体のケン化物、特開
昭５３−８０４９３号、同５ ３−６ ０ ９ ８ ５
号、同５ ３−６ ３ ４ ８ ６号等に記載されたア
クリロニトリル系重合体の加水分解物などがある．上記
において、ビニルエステルとしては、例えば酢酸ビニル
、プロピオン酸ビニル、ステアリン酸ビニルなど（好ま
しくは酢酸ビニル）がある．エチレン系不飽和カルボン
酸またはその誘導体としては、例えばアクリル酸、メタ
クリル酸、クロトン酸、イタコン酸、マレイン酸、フマ
ール酸、無水マレイン酸、無水イタコン酸及びこれらの
エステル類、アクリルアマイド、メタクリルアマイド、
好ましくはアクリル酸、メタクリル酸及びこれらのメチ
ルー、エチルー、ｎ−プロピルーイソプロピルー、ｎ−
プチルー、オーブチルーエステル類、アクリルアマイド
、メタクリルアマイドなどがある．
ビニルエステル威分（Ｘ）とエチレン系不飽和カルボン
酸威分（ｙ）とのモル比
ｘ：ｙ−２０：８０〜８０：２０
好ましくは ｘ：ｙ＝３０：７０〜７０：３０特に好ま
しくは ｘ ： ｙ−４ ０ 〜６ ０〜６ ０ ：
４Ｏである．
該共重合体中の他のエチレン性成分を１〜１０モル％、
好ましくは３〜７モル％の範囲で含有させてもよい．
ケン化度は、好ましくは上記共重合体中のビニルエステ
ル或分の３０モル％以上、エチレン系不飽和カルボン酸
エステルを共重合させた場合はその３０モル％以上（特
に７０モル％以上）である．具体的には、アクリル酸メ
チル含量が６２モル％の酢酸ビニルとアクリル酸メチル
の共重合体ケン化物（ケン化度９０モル％）、アクリル
酸メチル含量が２０モル％の酢酸ビニルとアクリル酸メ
チル共重合体のケン化物（ケン化度９８モル％〉、アク
リル酸メチル含量４８モル％の酢酸ビニルとアクリル酸
メチルの共重合体ケン化物（ケン化度９８．３モル％）
等があり、また市販品として住友化学■製のスミカゲル
（登録商標）Ｌ−５（Ｈ）．ＮＰ−１０２０などがある
．
次にアクリロニトリル系重合体の加水分解物について説
明する．
該アクリロニトリル系重合体とは、アクリロニトリルを
共重合戒分として含有する重合体の総称であり、具体的
には、アクリ口ニトリル単独重合体またはアクリロニト
リルと他の１種もしくは２種以上のエチレン系不飽和化
合物との共重合体、あるいはアクリロニトリルと他の重
合体、例えばでんぷん、ポリビニルアルコール等とのグ
ラフト重合体を挙げることができる．
該アクリロニトリルの含有率は３０重量％好ましくは５
０重量％以上が望ましい．
アクリロニトリル系重合体のケン化物はアクリロニトリ
ル部の加水分解によって生威したアクリル酸塩およびア
クリルアミドを含有する重合体である．
具体的にはアクリロニトリル含Ｍ９０％のアクリロニト
リルとアクリル酸メチルの共重合体のケン化物、でんぷ
んとアクリロニトリルのグラフト重合体のケン化物、８
５モル％のアクリロニトリル−６．２％のアクリル酸メ
チル−８．８％の塩化ビニリデンの共重合体のケン化物
などがある．本発明の高吸水性高分子化合物は、単独で
塗布膜を形威させて用いてもよく、またゼラチン等の他
の親水性コロイドと併用して塗布膜を形威させて用いて
もよい．
本発明の高吸水性高分子化合物を単独で塗布膜を形威さ
せて用いる場合は、架橋剤を用いるか、またはこれに代
えてもしくはこれと組合せて塗布後にキュアリングする
ことが望ましい．使用に適した架橋剤としてはグルタル
アルデヒド、グリオギザール、アジプアルデヒドなどの
アルデヒド類、エビクロルヒドリン、エチレングリコー
ルグリシジルエーテル、ポリエチレングリコールグリシ
ジルエーテル、グリセリンジグリシジルエーテル、トリ
メチロールプロパントリグリシジルエーテル、１．６−
ヘキサンジオールジグリシジルエーテルなどのエポキシ
化合物、ジクロルヒドリン、ジプロモヒドリンなどのビ
スハロゲン化物、２．４−トリレンジイソシアナート、
ヘキサメチレンジイソシアナートなどのイソシアナート
化合物（好ましくは、この中でもエポキシ化合物）など
がある．その使用量は通常高吸水性高分子化合物に対し
て０．００５〜２０重量％、特に０．０１〜２重量％で
ある．キエアリングの条件は任意であるが、通常４０゜
Ｃ〜１８０″Ｃで３０秒〜２時間、好ましくは５０℃〜
１２０℃で３０秒〜３０分で充分である．もちろん高温
であるほどキエアリングにようする時間は短縮できる．
なお、ゼラチン等の他の架橋性親水性コロイドと併用し
て塗布膜を形威させる態様で使用する場合には高吸水性
高分子化合物のための架橋剤の添加とキエアリングは実
施しなくてもよい．本発明においては、高吸水性高分子
化合物は好ましくは支持体１ｙｒｆ当たり０．００５〜
２０ｇ，特に０．１〜５ｇの範囲で使用される．本発明
に用いる受像層には物理現像核を必らず含むが、通常そ
れ以外に親水性コロイド物質、色調剤を含み、さらに蛍
光増白剤のような増白剤、硼酸のようなステイン防止剤
、塗布用界面活性剤、硬膜剤等を含有しうる．
物理現像核としては、亜鉛、水銀、鉛、カドミウム、鉄
、クロム、ニッケル、錫、コバルト、銅などの重金属、
パラジウム、白金、銀、金などの貴金属、あるいはこれ
らの諸金属の硫化物、セレン化物、テルル化物など、従
来、物理現像槙として公知のものをすべて使用すること
ができる．これらの物理現像核物質は、対応する金属イ
オンを還元して、金属コロイド分散物をつくるか、ある
いは、金属イオン溶液と、可溶性硫化物、セレン化物ま
たはテルル化物溶液を混合して、水不溶性金属硫化物、
金属セレン化物または金属テルル化物のコロイド分散物
をつくることによってえられる．
銀塩拡散転写法において物理現像核物質の働き２につい
ては、たとえば米国特許２，７７４，６６７号に記載さ
れている．高いコントラストの画像を与える受像要素を
うるには、これらの物理現像核は、受像層上に、通常、
ＩＱ−１＠〜１０−’ｇ／ｄ，好ましくはｌＯ−●〜１
０−’ｇ／ｄ含ませる．本発明に用いる受倣シ一トにお
いて、物理現像核を含む受像層には必要に応じて色調剤
を含有させる事が好ましい．
本発明の受像材料はまたチオ硫酸カリウム、チオ硫酸ナ
トリウムの如きハロゲン化恨溶剤も含有しうる。Detailed Description of the Invention (Field of Industrial Application) The present invention relates to a silver salt diffusion transfer method, and in particular to a silver salt diffusion transfer method, in which a highly water-absorbing polymer compound is used in a fake receiving sheet to improve photographic performance and drying properties. It concerns the salt diffusion transfer method. (Background of the invention) The silver salt diffusion transfer method (DTR method) is disclosed in U.S. Patent No. 23520.
It is well known as described in No. 14. In the DTR process, II complex salts are imagewise transferred by diffusion from a silver halide agent layer to an image-receiving layer, and they are converted into a silver image, often in the presence of physical development nuclei. For this purpose, an imagewise exposed silver halide emulsion layer is placed in contact with, or brought into contact with, an image-receiving layer in the presence of a developing agent and a silver halide complexing agent, and the unexposed halides are Converts silver to soluble silver complex salt. In the exposed parts of the silver halide emulsion layer, the silver halide is developed to silver (chemical development), so that it cannot be dissolved any further and therefore cannot be diffused. In the unexposed parts of the silver halide emulsion layer, the silver halide is converted to soluble silver salt, which is transferred to the receiver layer,
Therefore, they usually form a silver image in the presence of development nuclei. In direct positive silver halide emulsions, the effects of silver halide in exposed and unexposed areas are reversed. The DTR method has a wide range of applications, including document reproduction, lithographic printing plate production, block material production, and instant photography. The most common diffusion photographic development method for obtaining such transferred silver images involves inserting an image-receiving sheet and an exposed negative sheet into a developer solution in a DTR processor, with the image-receiving layer and photosensitive layer facing each other. A transfer silver image is obtained on an image-receiving sheet by dipping it, squeezing it with a squeeze roller, leaving the required amount of developing solution between both sheets, removing the excess solution, leaving it for a while, and then peeling off both sheets. Met. On the other hand, a method has long been proposed in which only the image-receiving sheet is immersed in a developing solution, and then brought into close contact with an exposed negative sheet outside the developing solution system before being separated (U.S. Pat. No. 317
No. 9517, Special Publication No. 6363893, etc.). However, the latter method had the problem that the amount of processing liquid impregnated into the image receiving sheet was small, resulting in low transfer density (particularly when the image receiving sheet was a film support, the transfer density was low) and low contrast. ．． (Problems to be Solved by the Invention) An object of the present invention is to provide a silver salt diffusion transfer method that can obtain high transfer density and contrast. In addition to the above-mentioned objects, the present invention also provides a silver salt diffusion transfer method in which drying of the image-receiving sheet is reduced and staining of the processing solution is reduced. (Means for Solving the Problems) An object of the present invention is to immerse only an image-receiving sheet in a development processing solution, and then, outside the development processing solution system, contact the image-receiving sheet with a negative sheet having an emulsion layer made of silver halide. In the silver salt diffusion transfer method that separates both sheets, 0.9%
This was achieved by containing a super absorbent polymer compound with a water absorption capacity of 40 g/g or more in an aqueous sodium chloride solution. In the present invention, the water absorption capacity, which is a measure of the superabsorbent polymer compound, is 0.9% NaCj! Aqueous solution (25″)
It can be easily determined by immersing 10g of the compound in the liquid and heating it in a constant temperature and humidity chamber at 120''C for 1 hour, then measuring the weight and calculating the amount of water absorbed.The water absorption capacity is 40g/g.
Examples of the above polymer compounds include sodium acrylate polymers and acrylic acid/vinyl alcohol copolymers. Polyethylene oxide derivatives, gelatin, carboxymethyl cellulose, etc. are not effective if their water absorption capacity is less than 30g/g. Preferred examples of such super absorbent polymer compounds include JP-A-52-14689, JP-A-53-50290, and JP-A-5.
No. 1-160387, No. 53-65597, No. 53-
No. 82666', No. 53-104652, No. 53-1
No. 04691, No. 53-105589, Special Publication No. 1973-
Described in No. 13495, No. 53-13678, etc.
Saponified product of copolymer consisting of at least vinyl ester and ethylenically unsaturated carboxylic acid or derivative thereof, JP-A-53-80493, JP-A-53-6 0985
There are hydrolysates of acrylonitrile polymers described in No. 53-63486 and the like. In the above, vinyl esters include, for example, vinyl acetate, vinyl propionate, vinyl stearate, etc. (preferably vinyl acetate). Examples of ethylenically unsaturated carboxylic acids or derivatives thereof include acrylic acid, methacrylic acid, crotonic acid, itaconic acid, maleic acid, fumaric acid, maleic anhydride, itaconic anhydride and esters thereof, acrylamide, methacrylamide,
Preferably acrylic acid, methacrylic acid, and methyl, ethyl, n-propyl, isopropyl, n-
These include petitroux, orbutyroux esters, acrylamide, and methacrylamide. Molar ratio of vinyl ester component (X) to ethylenically unsaturated carboxylic acid component (y) x:y-20:80 to 80:20, preferably x:y=30:70 to 70:30, particularly preferably x:y-40~60~60:
It is 4O. 1 to 10 mol% of other ethylenic components in the copolymer,
Preferably, it may be contained in a range of 3 to 7 mol%. The degree of saponification is preferably 30 mol% or more of the vinyl ester in the above copolymer, or 30 mol% or more (especially 70 mol% or more) of the vinyl ester in the copolymerized ethylenically unsaturated carboxylic acid ester. be. Specifically, saponified copolymers of vinyl acetate and methyl acrylate with a methyl acrylate content of 62 mol% (saponification degree of 90 mol%), vinyl acetate and methyl acrylate with a methyl acrylate content of 20 mol% Saponified copolymer (saponification degree 98 mol%), saponified copolymer of vinyl acetate and methyl acrylate with methyl acrylate content 48 mol% (saponification degree 98.3 mol%)
There are also commercially available products such as Sumikagel (registered trademark) L-5 (H). manufactured by Sumitomo Chemical ■. Examples include NP-1020. Next, we will explain the hydrolyzate of acrylonitrile polymer. The acrylonitrile-based polymer is a general term for polymers containing acrylonitrile as a copolymer component, and specifically, it includes an acrylonitrile homopolymer or acrylonitrile and one or more other ethylene-based polymers. Examples include copolymers with saturated compounds, and graft polymers of acrylonitrile with other polymers such as starch, polyvinyl alcohol, etc. The content of acrylonitrile is 30% by weight, preferably 5% by weight.
0% by weight or more is desirable. Saponified acrylonitrile polymers are polymers containing acrylate and acrylamide produced by hydrolysis of the acrylonitrile moiety. Specifically, a saponified product of a copolymer of acrylonitrile and methyl acrylate containing M90% of acrylonitrile, a saponified product of a graft polymer of starch and acrylonitrile, 8
Examples include saponified copolymers of 5 mol% acrylonitrile, 6.2% methyl acrylate, and 8.8% vinylidene chloride. The superabsorbent polymer compound of the present invention may be used alone to form a coating film, or may be used in combination with other hydrophilic colloids such as gelatin to form a coating film. When the superabsorbent polymer compound of the present invention is used alone to form a coating film, it is desirable to use a crosslinking agent, or instead of or in combination with this, to perform curing after application. Crosslinking agents suitable for use include aldehydes such as glutaraldehyde, glyogyzal, adipaldehyde, shrimp chlorohydrin, ethylene glycol glycidyl ether, polyethylene glycol glycidyl ether, glycerin diglycidyl ether, trimethylolpropane triglycidyl ether, 1 .6-
Epoxy compounds such as hexanediol diglycidyl ether, bishalides such as dichlorohydrin and dipromohydrin, 2,4-tolylene diisocyanate,
Examples include isocyanate compounds such as hexamethylene diisocyanate (preferably epoxy compounds among these). The amount used is usually 0.005 to 20% by weight, particularly 0.01 to 2% by weight, based on the superabsorbent polymer compound. The conditions for the air ring are arbitrary, but usually at 40°C to 180″C for 30 seconds to 2 hours, preferably at 50°C to
30 seconds to 30 minutes at 120°C is sufficient. Of course, the higher the temperature, the shorter the time required for the air ring. Note that when used in combination with other crosslinkable hydrophilic colloids such as gelatin to form a coated film, the addition of a crosslinking agent and the drying for the super absorbent polymer compound are not necessary. good. In the present invention, the superabsorbent polymer compound is preferably 0.005 to 1 yrf of the support.
It is used in an amount of 20g, especially in the range of 0.1 to 5g. The image-receiving layer used in the present invention necessarily contains physical development nuclei, but usually also contains a hydrophilic colloid substance, a color toning agent, and a brightening agent such as a fluorescent whitening agent, and a stain preventive material such as boric acid. It may contain a coating agent, a coating surfactant, a hardening agent, etc. Physical development nuclei include heavy metals such as zinc, mercury, lead, cadmium, iron, chromium, nickel, tin, cobalt, and copper;
All conventionally known physical development tools can be used, including noble metals such as palladium, platinum, silver, and gold, as well as sulfides, selenides, and tellurides of these metals. These physically developable nuclear materials can be prepared by reducing the corresponding metal ions to form metal colloidal dispersions or by mixing metal ion solutions with soluble sulfide, selenide or telluride solutions to form water-insoluble metals. sulfide,
It is obtained by making a colloidal dispersion of metal selenide or metal telluride. The function 2 of the physical development nucleus material in the silver salt diffusion transfer method is described, for example, in US Pat. No. 2,774,667. To obtain a receiver element that gives a high contrast image, these physical development nuclei are usually applied onto the receiver layer.
IQ-1@~10-'g/d, preferably lO-●~1
Include 0-'g/d. In the receiving sheet used in the present invention, it is preferable that the image-receiving layer containing physical development nuclei contain a toning agent as necessary. The image-receiving materials of the invention may also contain halogenated solvents such as potassium thiosulfate and sodium thiosulfate.
銀塩拡散転写法ネガシートは、支持体上に設吠られた少
なくとも１つのハロゲン化恨乳剤層から構威され、一般
に硝酸銀に換算したハロゲン化銀は０．５ｇ〜３．５ｇ
／ｒｒｒの範囲で塗布される．このハロゲン化銀乳剤層
以外に必要るより下塗層、中間層、保護層、剥離層など
の補助層が設けられる．例えば、本発明に使用される感
光材料は、特公昭３Ｂ−１８１３４号、同昭３８−１８
１３５号等に記載のような水透過性結合剤、例えばメチ
ルセルロース、カルボキシメチルセルロースのナトリウ
ム塩、アルギン酸ナトリウム等をハロゲン化銀乳剤層の
被覆層とし、転写の均一化を計ることができ、この層は
拡散を実質的に阻止または抑制しないように薄層とする
．ネガシートにおけるハロゲン化銀乳剤層、及び受像シ
ートの受像層などには、いずれも親水性コロイド物質、
例えばゼラチン、フタル化ゼラチンの如きゼラチン誘導
体、カルボキシメチルセルローズ、ヒドロキシメチルセ
ルローズの如きセルローズ誘導体、デキストリン、可溶
性澱粉、ポリビニルアルコール等の親水性高分子コロイ
ド物質を一種以上含んでいる．ハロゲン化銀乳剤は、上
記の親水性コロイド中に分散されたハロゲン化銀、例え
ば塩化銀、臭化銀、塩臭化銀及びこれらに沃化物を含ん
だものからなる．
本発明では一般のネガ型ハロゲン化銀写真乳剤も用いら
れるが、直接ポジ型ハロゲン化銀写真乳剤でもよい．直
接ポジ型のもののうち、電子受容体またはハロゲン受容
体を含むものが特に好ましい．
本発明において用いられるハロゲン化銀乳剤は、酸性法
、中性法、アンモニア法等、いづれの方法によって調製
されてもよい．
特に、米国特許３，５３１．２９０号明細書に記載され
た如き、塩化物が５０モル％以上のカブらされたハロゲ
ン化銀乳剤に、電子受容体もしくはハロゲン受容体と、
感度増大に必要な量の水溶性臭化物もしくは臭化物と沃
化物を添加した高感光度の直接ポジ用ハロゲン化銀乳剤
も好ましい．ハロゲン化銀乳剤層および／または受像層
などには銀錯塩拡散転写法を実施するために通常使用さ
れている任意の化合物を含有しうる．これら化合物には
例えばテトラザインデンやメルヵプトテトラゾール類な
どのカブリ抑制剤、サポニンやポリアルキレンオキサイ
ド類などの塗布助剤、ホルマリンやクロム明ばんなとの
硬膜剤、可塑剤などを含むことができる．
本発明のハロゲン化銀感光材料（ネガシート）には公知
の写真用添加剤を加えることができる．以下にその一例
を述べる．
添加剤種類
ＲＤ１７６４３
ＲＤ１８７１６
１
化学増感剤
２３頁
６４８頁右欄
２
感度上昇剤
同上
４
増白剤
２４頁
７
ステイン防止剤
２５頁右欄
６５０頁左〜右欄
８
硬膜剤
２６頁
６５１頁左欄
９
ハイングー
２６頁
同上
１０
可塑剤、潤滑剤
２７頁
６５０頁右欄
１２
スタチック防止
剤
２７頁
同上
前記のとおり本発明の写真乳剤は分光増感されていても
よい．分光増感される波長域はオルソでもパンクロでも
よい．また、赤外域に分光増感されてもよい．赤外域の
分光増感は特開昭５９−１９２２４２号、同５９−１９
１０３２号、同６０−８０８４１号、同６２−１９２７
３６号、同６２−２９９８３９号、同６２−２９９８３
８号、同６２−１２３４５４号、同６２−３２５０号、
同６３−３１６８５３号、同６２−２３１４８号等の記
載を適用することによって達戒できる．感光材料あるい
は受像材料に使用する支持体は通常使用される任意の支
持体であるそれには紙、フィルム例えばセルロースアセ
テートフイルム、ポリエチレンテレフタレートフィルム
等、紙で両側を被覆した金属支持体、片側または両側を
α一オレフィン重合体例えばポリエチレン被覆した紙支
持体も使用できる．
本発明においては支持体上にカーボンブラック分散物及
び／又は染料からなるアンチハレーション層を設け、そ
の上にハロゲン化銀乳剤層を塗布することが好ましい．
とくに、アンチハレーション層の塗布＆］Ｉ戒物中に現
像主薬を添加することが出来る．
本発明に用いられる現像主薬はハイドロキノン類例えば
ハイドロキノン、ｔ−プチルハイドロキノン、メチルヒ
ドロキノンなど、３−ピラゾリジノン類例えば１−フエ
ニルー３−ビラゾリジノン、４．４−ジメチル−１−フ
エニルー３−ビラゾリジノン、４−ヒドロキシメチノレ
−４−メチル−１−フエニルー３−ビラゾリジノン、４
．４−ジメチル−１−ｐ−｝リルー３−ビラゾリジノン
、４−ヒドロキシメチル−４−メチル−１−ｐ−トリル
−３−ビラゾリジノン、１−ｐ−ヒドロキシエチルフェ
ニルー３−ビラゾリトン、１．４−ジメチル−３−ビラ
ゾリドンなどが用いられる．アクチベーターで処理する
現像主薬を含有するネガシートの場合には前記現像主薬
はハロゲン化銀乳剤層及び／又はその隣接層に添加する
ことが好ましいが＋ａ層及び／又はその隣接層に添加し
てもよい．
本発明に用いられる処理組威物には、前述したｍ或物以
外に保恒剤、例えば亜硫酸カリウム、亜硫酸ナトリウム
；カブリ防止剤例えば臭化カリウム、臭化ナトリウム、
転写促進剤例えばアルカノールアミン類、粘調剤、例え
ばヒドロキシエチルセルロース、カルボキシメチルセル
ロース；界面活性剤例えばポリオキシアルキレン化合物
、オニウム化合物；硬水軟化剤例えばＥＤＴＡのＮａ塩
などが含有される．又処理組威物のｐＨは現像活性を維
持するに要するｐＨはｌＯ〜１４であり１０．５〜１２
．８が好ましい．
本発明に用いるハロゲン化銀溶剤はアルカリ金属のチオ
硫酸塩、例えば、チオ硫酸ナトリウム、チオ硫酸カリウ
ムが用いられ、好ましくはチオ硫酸ナトリウム画像用い
らる．
ハロゲン化溶剤は通常約０．０６モル／ｌ〜約０．１９
モル／ｌである．
色調剤として、たとえばイミダゾリジン−２一チオン、
パーヒドロジアジン−２−チオン、メルカプトベンツイ
ミダゾール類（たとえば２−メルカブトベンツイξダゾ
ール、２−メルカブト−５一メチルベンツイミダゾール
、２−メルカプトー５−クロルベンツイミダゾールなど
）、メルカブトイミダゾール類（たとえば２−メルカブ
トイミダゾール、２−メルカブト−４−フエニルイミダ
ゾール、ｌ−メチル−２−メルカブト−５−フエニルイ
ミダゾール、ｌ−ベンジル−２−メルカプトイミダゾー
ル、２−メルカブト−１−フエニルイミダゾールなど）
、メルカプトトリアゾール類（たとえば、３−メルカブ
ト−４．５−ジメチルトリアゾール、４−ｐ−｝ルイル
ー４Ｈ−１．２．４−トリアゾールー３−チオールなど
）、メルカブトベンゾトリアゾール［（たとえば、ペン
ゾトリアゾール−２−チオールなど）、テトラゾール５
−チオール類（たとえばｌ−フエニルー５メルカプトテ
トラゾール、ｌ一エチル−５−メルカブト−ＬＨ−テト
ラゾールなど）、メルカプトビリミジン類（たとえば、
２−メルカプトピリξジン、２．４−ジメルカプトピリ
ミジン、４−ヒドロキシ−２．６−ジメルカブトピリミ
ジン、など）、テトラザペンタレンＭ（たとえば、１．
４一ジメルカブト−３Ｈ，６Ｈ−２．３ａ，５，６
ａ−テトラザペンタレン、３，６−ジフエニルー１．４
−ジメルカプト−３Ｈ，６Ｈ ３２．３ａ，５．６ａ
−テトラザペンタレンなど）を使用することができる．
色調剤として処理液１２当たり約１．５Ｘ１０−’〜約
２Ｘ１０−３モルが好ましく、０．ＩＸＩＯ−３〜Ｉ
Ｘ １ ０−３が特に好ましい．銀塩拡散転写法はハロ
ゲン化銀乳剤層を含むネガシートと物理現像核含有の受
像シートを現像主薬とハロゲン化ｔＲｔｌｊ剤を含む処
理液で処理する方法が一般的であるが、現像主薬を含む
ネガシートと物理現像核を含む受像シートを実質的に現
像剤を含まない、ハロゲン化銀溶剤含有処理液（アクチ
ベーター）で処理する方法にも本発明は有効である．
処理組威物は迅速な現像を行なうためにＰＨが約１０〜
１４という高アルカリに設定されるのが通常である．そ
のためのアルカリ物質としてアルカリ性物質例えば水酸
化カリウム、水酸化ナトリウム、リン酸塩（リン酸ミナ
トリウムなど）などが用いられる．
受像シートは、任意の温度の現像処理液中に任意の時間
、例えば数秒間から数十秒間浸漬すれば十分であり、受
像シート上に均一な転写画像を得るためには少なくとも
約１秒間の浸漬をすることが好ましい．
又受像シートに現像処理液を塗付けてもよい．又系外で
ネガシートと現像処理液を含有する受像シートを重ね合
わる際、単なる加圧ローラ一対でも良いが熱ローラ一対
を用いることにより処理液温度依存性をなくし処理時間
を著しく短縮することが可能となる、さらに受像シート
の乾燥性を高めることも出来る．
受像シートの浸漬は、現像処理液中で化学現像も物理現
像も起さないから必然的にハイドロキノンやビラゾリド
ンの如き現像主薬の酸化物による液着色も銀スラツジの
生戒も、さらには液組或の変化も起さないで多数枚処理
、所謂ランニング処理による現像処理液の疲労が極めて
少ない利点がある．
（実施例）
以下に本発明に用いられる好ましい態様について詳しく
説明する．
実施例１
ポリエチレンで両側を被覆した１１０ｇ／ｎ｛の紙支持
体側に金属パラジウム核を含むゼラチンとカルボキシメ
チルセルロース（４１）からなる受像層を親水性コロイ
ドが乾燥重量３ｇ／ｎＴになるように設けて受像シ一ト
■（ペーパー）を作製した．
次に受像層形戒時にカルボキシメチルセルロースの代り
にスミカゲルＬ−５ （Ｈ）を用いて受像シ一ト■を作
製した．
一方、受像シートと同じ紙支持体上に、ハレーシッン防
止用として０．２５ｇ／ｒｒｒのカーボンプランク及び
０．８ｇｌｒｄのハイドロキノンと０．２ｇ／ｒｒｆの
４−ヒドロキシメチル−４−メチル−１−フエニルー３
−ビラゾリジノンを含むゼラチン層（ゼラチン２ｇ／ｎ
ｆ）を設け、その上に０．３μの平均粒径の塩臭化銀（
臭化１１２モル％）を硝酸銀に換算して２．０ｇ／ｒｄ
で含むオルソ増感されたゼラチン塩臭化銀乳剤層を設け
てネガシートを作製した．
この感光材料の乳剤面にセンシトメトリー露光を与えた
後受像シートの受像面を接触させ、第１表のような処理
組威物を有する図１の通常の現像機を通し、スクイズロ
ーラーを出て、２０秒後に両材料を引き剥がした．処理
温度は２５℃である（処理法−１）。A silver salt diffusion transfer negative sheet consists of at least one halide emulsion layer disposed on a support, and generally contains 0.5 to 3.5 g of silver halide in terms of silver nitrate.
/rrr. In addition to this silver halide emulsion layer, necessary auxiliary layers such as an undercoat layer, intermediate layer, protective layer, and release layer are provided. For example, the photosensitive material used in the present invention is disclosed in Japanese Patent Publication No. 3B-18134,
135, etc., such as methyl cellulose, sodium salt of carboxymethyl cellulose, sodium alginate, etc., can be used as a coating layer for the silver halide emulsion layer to ensure uniform transfer. The layer should be thin so as not to substantially prevent or inhibit diffusion. The silver halide emulsion layer of the negative sheet and the image receiving layer of the image receiving sheet both contain hydrophilic colloid substances,
For example, it contains one or more hydrophilic polymer colloid substances such as gelatin, gelatin derivatives such as phthalated gelatin, cellulose derivatives such as carboxymethyl cellulose and hydroxymethyl cellulose, dextrin, soluble starch, and polyvinyl alcohol. Silver halide emulsions consist of silver halides, such as silver chloride, silver bromide, silver chlorobromide, and iodide-containing compounds thereof, dispersed in the above-mentioned hydrophilic colloids. Although general negative-working silver halide photographic emulsions are used in the present invention, direct positive-working silver halide photographic emulsions may also be used. Among direct positive types, those containing an electron acceptor or a halogen acceptor are particularly preferred. The silver halide emulsion used in the present invention may be prepared by any method such as an acid method, a neutral method, or an ammonia method. In particular, a fogged silver halide emulsion containing 50 mole % or more of chloride, as described in U.S. Pat.
Highly sensitive direct positive silver halide emulsions containing water-soluble bromide or bromide and iodide in amounts necessary to increase sensitivity are also preferred. The silver halide emulsion layer and/or the image-receiving layer may contain any compound commonly used for carrying out the silver complex diffusion transfer method. These compounds may include, for example, fog suppressants such as tetrazaindene and mercaptotetrazoles, coating aids such as saponin and polyalkylene oxides, hardeners such as formalin and chromium alum, and plasticizers. Can be done. Known photographic additives can be added to the silver halide photosensitive material (negative sheet) of the present invention. An example is described below. Additive type RD17643 RD18716 1 Chemical sensitizer page 23, page 648, right column 2 Sensitivity enhancer, same as above 4 Brightener, page 24 7 Stain inhibitor, page 25, right column, page 650, left to right column 8 Hardener, page 26, page 651, left Column 9 Hingu, page 26 Same as above 10 Plasticizers, lubricants Page 27 Page 650 Right column 12 Static inhibitors Page 27 Same as above As mentioned above, the photographic emulsion of the present invention may be spectrally sensitized. The wavelength range to be spectrally sensitized may be ortho or panchromatic. It may also be spectrally sensitized to the infrared region. Spectral sensitization in the infrared region is described in JP-A-59-192242 and JP-A-59-19.
No. 1032, No. 60-80841, No. 62-1927
No. 36, No. 62-299839, No. 62-29983
No. 8, No. 62-123454, No. 62-3250,
The precepts can be attained by applying the descriptions in Nos. 63-316853 and 62-23148, etc. The support used for the light-sensitive or image-receiving material is any commonly used support, including paper, film such as cellulose acetate film, polyethylene terephthalate film, etc., a metal support coated on both sides with paper, or a metal support coated on one or both sides with paper. Paper supports coated with alpha-olefin polymers such as polyethylene can also be used. In the present invention, it is preferable to provide an antihalation layer consisting of a carbon black dispersion and/or a dye on the support, and coat the silver halide emulsion layer thereon.
In particular, a developing agent can be added to the coating of the antihalation layer and to the precepts. The developing agents used in the present invention are hydroquinones such as hydroquinone, t-butylhydroquinone, methylhydroquinone, etc., 3-pyrazolidinones such as 1-phenyl-3-virazolidinone, 4,4-dimethyl-1-phenyl-3-virazolidinone, 4-hydroxy Methynole-4-methyl-1-phenyl-3-virazolidinone, 4
．． 4-dimethyl-1-p-}lyru-3-virazolidinone, 4-hydroxymethyl-4-methyl-1-p-tolyl-3-virazolidinone, 1-p-hydroxyethylphenyl-3-virazolitone, 1,4-dimethyl -3-Vyrazolidone etc. are used. In the case of a negative sheet containing a developing agent to be treated with an activator, the developing agent is preferably added to the silver halide emulsion layer and/or its adjacent layer, but it may also be added to the +a layer and/or its adjacent layer. good. In addition to the above-mentioned substances, the processing agents used in the present invention include preservatives such as potassium sulfite and sodium sulfite; antifoggants such as potassium bromide and sodium bromide;
Transfer accelerators such as alkanolamines, viscosity agents such as hydroxyethyl cellulose and carboxymethyl cellulose; surfactants such as polyoxyalkylene compounds and onium compounds; water softeners such as Na salt of EDTA are contained. In addition, the pH of the treated composition is 10.5 to 12, which is 10 to 14, which is required to maintain development activity.
．． 8 is preferred. The silver halide solvent used in the present invention is an alkali metal thiosulfate, such as sodium thiosulfate or potassium thiosulfate, preferably sodium thiosulfate. The halogenated solvent usually ranges from about 0.06 mol/l to about 0.19 mol/l.
It is mole/l. As a color toning agent, for example, imidazolidine-2-thione,
perhydrodiazine-2-thione, mercaptobenzimidazoles (e.g. 2-mercabutobenziξdazole, 2-mercabuto-5-methylbenzimidazole, 2-mercapto-5-chlorobenzimidazole, etc.), mercaptobenzimidazoles ( For example, 2-mercabutoimidazole, 2-mercabuto-4-phenylimidazole, l-methyl-2-mercabuto-5-phenylimidazole, l-benzyl-2-mercaptoimidazole, 2-mercabuto-1-phenylimidazole, etc. )
, mercaptotriazoles (e.g., 3-mercabuto-4.5-dimethyltriazole, 4-p-}ruyl-4H-1.2.4-triazole-3-thiol, etc.), mercaptobenzotriazole [(e.g., penzotriazole) -2-thiol, etc.), tetrazole 5
-thiols (e.g., l-phenyl-5-mercaptotetrazole, l-ethyl-5-mercapto-LH-tetrazole, etc.), mercaptovirimidines (e.g.,
2-mercaptopyridine, 2,4-dimercaptopyrimidine, 4-hydroxy-2,6-dimercaptopyrimidine, etc.), tetrazapentalene M (for example, 1.
4-dimerkabuto-3H,6H-2.3a,5,6
a-tetrazapentalene, 3,6-diphenyl-1.4
-dimercapto-3H, 6H 32.3a, 5.6a
-tetrazapentalene, etc.) can be used. The color toning agent is preferably about 1.5 x 10-' to about 2 x 10-3 mol per 12 of the processing solution, and 0. IXIO-3~I
X 1 0-3 is particularly preferred. In the silver salt diffusion transfer method, a negative sheet containing a silver halide emulsion layer and an image receiving sheet containing physical development nuclei are generally processed with a processing solution containing a developing agent and a halogenated tRtlj agent. The present invention is also effective in a method in which an image-receiving sheet containing physical development nuclei is processed with a processing solution (activator) containing a silver halide solvent and substantially free of developer. The processing composition has a pH of approximately 10 to 10 for rapid development.
It is usually set at a high alkalinity of 14. For this purpose, alkaline substances such as potassium hydroxide, sodium hydroxide, and phosphates (such as monosodium phosphate) are used. It is sufficient to immerse the image-receiving sheet in a developing treatment solution at an arbitrary temperature for an arbitrary period of time, for example, from several seconds to several tens of seconds.In order to obtain a uniform transferred image on the image-receiving sheet, immersion for at least about 1 second is sufficient. It is preferable to do so. Alternatively, a developing solution may be applied to the image-receiving sheet. Furthermore, when overlapping a negative sheet and an image-receiving sheet containing a developing processing solution outside the system, it is possible to use a simple pair of pressure rollers, but by using a pair of heat rollers, it is possible to eliminate the dependence on processing solution temperature and significantly shorten processing time. Furthermore, it is possible to improve the drying properties of the image-receiving sheet. Since immersion of the image-receiving sheet does not cause any chemical or physical development in the developing solution, it inevitably affects the coloring of the silver sludge by oxides of developing agents such as hydroquinone and virazolidone, as well as the liquid composition. This has the advantage that there is no change in the processing temperature, and the fatigue of the developing solution caused by processing a large number of sheets, or so-called running processing, is extremely low. (Example) Preferred embodiments used in the present invention will be described in detail below. Example 1 An image-receiving layer consisting of gelatin containing metal palladium cores and carboxymethyl cellulose (41) was provided on the side of a 110 g/n paper support coated on both sides with polyethylene so that the dry weight of the hydrophilic colloid was 3 g/nT. An image receiving sheet ■ (paper) was prepared. Next, when forming an image receiving layer, Sumikagel L-5 (H) was used in place of carboxymethyl cellulose to prepare an image receiving sheet ■. On the other hand, on the same paper support as the image-receiving sheet, 0.25 g/rrr of carbon plank, 0.8 glrd of hydroquinone, and 0.2 g/rrf of 4-hydroxymethyl-4-methyl-1-phenyl-3 were added to prevent Halley thinning.
- Gelatin layer containing virazolidinone (gelatin 2g/n)
f), and silver chlorobromide (
bromide (112 mol%) converted to silver nitrate is 2.0 g/rd
A negative sheet was prepared with an ortho-sensitized gelatin silver chlorobromide emulsion layer containing . After sensitometric exposure is applied to the emulsion surface of this light-sensitive material, the image-receiving surface of the image-receiving sheet is brought into contact with the emulsion surface, and the material is passed through a conventional developing machine shown in FIG. After 20 seconds, both materials were peeled off. The treatment temperature is 25°C (treatment method-1).
次に受像シートのみを図１の現像機を用いて第１表の活
性化処理液に浸漬後ネガシートの乳剤面に接触させて、
スクイーズ・ローラーを通し２０秒後に両シートを引き
剥がした（処理法２）．さらに６０℃の熱ローラーを用
いたテストもおこなった．
処理結果を下表に示す．
比較ｌ
比較ｌ
比 較２
本発明２
スクリーン）
Ａ １．４５ 劣る
８ １．４３ 劣る
Ａ ０． １５ 劣る
８ １．４２ 優れる
ｉ艮スラフジ発生
霊艮スラツジ発生
透明
透明
本発明の化合物を含有した受像シートを使用する事によ
り、処理性能が良い、かつ処理液劣化がない処理法２で
も十分な濃度が得られる事がわかる．
実施例２
ダブルジェット法により、立方体で平均粒径０．３ミク
ロンの塩臭化銀（塩化銀９５モル％）ゼラチン乳剤を調
製し、凝固沈澱した後、水洗した．この乳剤を再溶解し
てゼラチンを加えた後に、銀１モル当たり４■の塩化金
酸カリウムを加え、さらに６０分間熟威する．温度を約
４０℃に下げ、ｐＡｇ ７． ８に調整しｐＨ５．０
に下げた上記乳剤に銀１モノレ当たり、ピナクリブトー
ル・イエロー４００■および下記の色素３００１１ｇＣ
＊Ｈｓ Ｃｔｌｌｓ ＳＣＮ−を加えた
．
次いでナトリウムへプチルーα−スルホラウレ−トを加
え、硬膜剤を添加して仕上り乳剤とし、コロナ放電処理
したポリエチレン被覆紙支持体上にｉｍ２．５ｇ／ｎｆ
となるように保護層用塗布液（ゼラチン１． ０ｇ／
ｒｒｆ）と共に塗布し乾燥した．一方、ＰＥＴ支持体の
片側に硫化ニッケル核を含むゼラチンとカルボキシメチ
ルセルロース（重量比１：１）からなる受像層を親水性
コロイドの乾燥重量３ｇ／ｎｆになるように設けて受像
フィルム０を作製した．
次に、カルボキシエチルセルロースの代りに、スミカゲ
ルＮＰ−１０２０を用いた受像シ一ト０を作製した．
上記ネガシートにセンシトメトリー露光を与えた後、受
像シートと重ね合わせ、下記の拡散転写現像液を含む図
１の現像機を通し、絞りローラーを出て６０秒後に両シ
ートを剥離した（処理法１）処理温度は２５℃である．
次に受像シートのみを図１の現像機を用いて第２表の拡
散転写現像液に浸漬後、ネガシートの乳剤面に接触させ
て、９０゜Ｃのヒーター・ローラーを通し、６０秒後に
両シートを引き剥がした（処理法２）．
処理結果を下表に示す．
セ
啼
呻
四
０
ロ
０
ロ
本発明の化合物を含有した受像シートを使用する事によ
り、処理性能や取り扱い性が良く、かつ処理液劣化がな
い処理法２でも充分な濃度が得られる事がわかる．
また同上の現像液を受像シートの表面に塗り付けて処理
しても同様な結果が得られた．第２表
〈拡散転写現像液〉Next, only the image-receiving sheet was immersed in the activation processing solution shown in Table 1 using the developing machine shown in FIG. 1, and then brought into contact with the emulsion surface of the negative sheet.
After passing through a squeeze roller for 20 seconds, both sheets were peeled off (processing method 2). We also conducted a test using a heated roller at 60°C. The processing results are shown in the table below. Comparison l Comparison l Comparison 2 Invention 2 Screen) A 1.45 Inferior 8 1.43 Inferior A 0. 15 Poor 8 1.42 Excellent sludge generation Sludge generation Transparent By using the image-receiving sheet containing the compound of the present invention, the processing performance is good and the processing solution does not deteriorate and the concentration is sufficient even in processing method 2. It can be seen that this can be obtained. Example 2 A cubic silver chlorobromide (silver chloride 95 mol %) gelatin emulsion having an average particle size of 0.3 microns was prepared by the double jet method, coagulated and precipitated, and then washed with water. After redissolving the emulsion and adding gelatin, 4 μl of potassium chloroaurate per mole of silver was added and allowed to ripen for an additional 60 minutes. Reduce temperature to approximately 40°C and reduce pAg 7. Adjust to pH 8 and pH 5.0
To the above emulsion reduced to
*Added Hs Ctlls SCN-. Sodium heptyl-alpha-sulfolaurate was then added and a hardener was added to form the finished emulsion, im 2.5 g/nf on a corona discharge treated polyethylene coated paper support.
Coating liquid for protective layer (gelatin 1.0g/
rrf) and dried. On the other hand, an image-receiving layer made of gelatin containing nickel sulfide cores and carboxymethyl cellulose (weight ratio 1:1) was provided on one side of the PET support so that the dry weight of hydrophilic colloid was 3 g/nf to prepare image-receiving film 0. ．． Next, image receiving sheet 0 was prepared using Sumikagel NP-1020 instead of carboxyethyl cellulose. After the negative sheet was subjected to sensitometric exposure, it was superimposed on the image-receiving sheet, passed through the developing machine shown in Fig. 1 containing the following diffusion transfer developer, and both sheets were peeled off after 60 seconds after exiting the aperture roller (processing method 1) The processing temperature is 25°C. Next, only the image-receiving sheet was immersed in the diffusion transfer developer shown in Table 2 using the developing machine shown in Figure 1, brought into contact with the emulsion side of the negative sheet, passed through a heater roller at 90°C, and after 60 seconds both sheets were immersed. was peeled off (processing method 2). The processing results are shown in the table below. It can be seen that by using the image-receiving sheet containing the compound of the present invention, sufficient density can be obtained even in Processing Method 2, which has good processing performance and ease of handling, and does not cause deterioration of the processing solution. ．． Similar results were also obtained when the above developer was applied to the surface of the image-receiving sheet. Table 2 <Diffusion transfer developer>
図面は、ＤＲＴ法に従来から使用されている現像プロセ
ッサーの断面略図である．The drawing is a schematic cross-sectional view of a development processor conventionally used in the DRT method.
Claims (3)
現像処理液系外でハロゲン化銀からなる乳剤層を有する
ネガシートと密着しその後両シートを分離する銀塩拡散
転写法において、該受像シートが０．９％塩化ナトリウ
ム水溶液中での吸水倍率が４０ｇ／ｇ以上の高吸水性高
分子化合物を含有するものであることを特徴とする銀塩
拡散転写法。(1) In the silver salt diffusion transfer method, in which only the image-receiving sheet is immersed in a development processing solution, the image-receiving sheet is brought into close contact with a negative sheet having an emulsion layer made of silver halide outside the development processing solution system, and then both sheets are separated. A silver salt diffusion transfer method, characterized in that the image-receiving sheet contains a highly water-absorbing polymer compound having a water absorption capacity of 40 g/g or more in a 0.9% aqueous sodium chloride solution.
現像液であることを特徴とする請求項１記載の銀塩拡散
転写法。(2) The silver salt diffusion transfer method according to claim 1, wherein the developing solution is an alkaline developer containing an effective amount of a developing agent.
リ性活性化処理液であり、かつネガシートが有効量の現
像主薬を含むことを特徴とする請求項１記載の銀塩拡散
転写法。(3) The silver salt diffusion transfer method according to claim 1, wherein the processing solution is an alkaline activation processing solution that does not contain an effective amount of a developing agent, and the negative sheet contains an effective amount of a developing agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18404089A JPH0348246A (en) | 1989-07-17 | 1989-07-17 | Silver salt diffusion transfer method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18404089A JPH0348246A (en) | 1989-07-17 | 1989-07-17 | Silver salt diffusion transfer method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0348246A true JPH0348246A (en) | 1991-03-01 |
Family
ID=16146309
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18404089A Pending JPH0348246A (en) | 1989-07-17 | 1989-07-17 | Silver salt diffusion transfer method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0348246A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5772142A (en) * | 1980-10-22 | 1982-05-06 | Mitsubishi Paper Mills Ltd | Diffusion transferring method for silver complex salt |
| JPS6147956A (en) * | 1984-08-15 | 1986-03-08 | Fuji Photo Film Co Ltd | Photographic product for color diffusion transfer process |
| JPS61132952A (en) * | 1984-11-30 | 1986-06-20 | Fuji Photo Film Co Ltd | Transfer method of coloring matter |
-
1989
- 1989-07-17 JP JP18404089A patent/JPH0348246A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5772142A (en) * | 1980-10-22 | 1982-05-06 | Mitsubishi Paper Mills Ltd | Diffusion transferring method for silver complex salt |
| JPS6147956A (en) * | 1984-08-15 | 1986-03-08 | Fuji Photo Film Co Ltd | Photographic product for color diffusion transfer process |
| JPS61132952A (en) * | 1984-11-30 | 1986-06-20 | Fuji Photo Film Co Ltd | Transfer method of coloring matter |
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