JPH0345792A - Ending of fiber reinforced plastic wire - Google Patents

Ending of fiber reinforced plastic wire

Info

Publication number
JPH0345792A
JPH0345792A JP17832489A JP17832489A JPH0345792A JP H0345792 A JPH0345792 A JP H0345792A JP 17832489 A JP17832489 A JP 17832489A JP 17832489 A JP17832489 A JP 17832489A JP H0345792 A JPH0345792 A JP H0345792A
Authority
JP
Japan
Prior art keywords
wire
fiber
resin
reinforced plastic
flattened
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP17832489A
Other languages
Japanese (ja)
Inventor
Shigeo Abiru
茂雄 阿比留
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyobo Co Ltd
Original Assignee
Toyobo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyobo Co Ltd filed Critical Toyobo Co Ltd
Priority to JP17832489A priority Critical patent/JPH0345792A/en
Publication of JPH0345792A publication Critical patent/JPH0345792A/en
Pending legal-status Critical Current

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  • Ropes Or Cables (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)

Abstract

PURPOSE:To simply end the title wire while improving bond strength and strength retention ratio of wire by flattening end of plastic wire, engaging the end part with a metallic ring, bonding under pressure, inserting an engaging member and covering with a resin. CONSTITUTION:End part of fiber-reinforced plastic wire 1 having >=40kg/mm<2> tensile strength comprising reinforcing fiber containing ultrahigh-molecular- weight polyethylene fiber and a synthetic polymer resin is flattened, the flattened part 1a is engaged with a metallic ring 2, bonded under pressure, the flattened part 2 bonded to the metallic ring 2 under pressure is inserted into a tubular engaging member 3 and the periphery of the part is fixed with a resin 4 to end the aimed plastic wire.

Description

【発明の詳細な説明】 (産業上の利用分野) この発明は、高強力、高弾性率を有する超高分子量ポリ
エチレン繊維を含む補強繊維と合成重合体樹脂とからな
る引張強度40 kg / rm ”以上の繊維強化プ
ラスチック線材の端部と端部、または上記端部と他の機
械構造体とを接合するための端止め方法に関するもので
あり、光フアイバーケーブルのテンションメンバ、ワイ
ヤロープ、ワイヤケーブル等として使用される繊維強化
プラスチック線材の端止めに好適な方法を提供するもの
である。
Detailed Description of the Invention (Field of Industrial Application) The present invention provides a reinforcing fiber having a tensile strength of 40 kg/rm, which is made of a synthetic polymer resin and reinforcing fibers including ultra-high molecular weight polyethylene fibers having high strength and high modulus of elasticity. The present invention relates to an end-stopping method for joining the ends of the above-mentioned fiber-reinforced plastic wires, or the above-mentioned ends and other mechanical structures, and is applicable to tension members of optical fiber cables, wire ropes, wire cables, etc. The present invention provides a method suitable for securing the ends of fiber-reinforced plastic wire used as a plastic wire rod.

(従来の技術) 光フアイバーケーブルのテンションメンバ、ワイヤロー
プ、ワイヤケーブル等の抗張材分野に軽量化、電磁誘導
障害対策、防錆化等を目的とし、ガラス繊維や芳香族ポ
リアミド繊維などを補強材とした強化プラスチック線材
やポリオキシメチレン線材等が使用されるようになって
きた。これらの線材を線材同士で接合する場合5または
線材を他の機械構造部材に接合する場合は、線材の端部
を180度折曲げてループを形成し、2本引揃えた部分
を括り、この部分を金属パイプに挿入してかしめる方法
、および上記線材の端部をそのままソケットに挿入し、
端部とソケット内面との間に樹脂を充填する方法などが
知られており、ガラス繊維や芳香族アラミド&l維を補
強材とするm維強化プラスチック線材の端止め方法とし
て一般に使用されている。また、ポリオキシメチレン線
材の場合は、線材の端部に複数個の金属パイプを嵌合し
、これをかしめた後この部分を樹脂中に埋設する方法が
知られている(特開昭62−48530号公報参照)。
(Conventional technology) Glass fibers, aromatic polyamide fibers, etc. are reinforced for the purpose of weight reduction, electromagnetic induction interference prevention, rust prevention, etc. in the field of tensile materials such as optical fiber cable tension members, wire ropes, and wire cables. Reinforced plastic wires and polyoxymethylene wires have come to be used as materials. When joining these wire rods to each other (5) or when joining the wire rods to other mechanical structural members, bend the ends of the wire rods 180 degrees to form a loop, tie the two wires together, and then A method of inserting the section into a metal pipe and caulking it, and inserting the end of the wire rod as it is into a socket,
A method of filling a resin between the end portion and the inner surface of the socket is known, and is generally used as an end-stopping method for m-fiber reinforced plastic wires using glass fibers or aromatic aramid &l fibers as reinforcing materials. In addition, in the case of polyoxymethylene wire, a method is known in which a plurality of metal pipes are fitted to the ends of the wire, the ends are caulked, and then this portion is buried in resin (Japanese Patent Application Laid-Open No. 1983-1999-1). (See Publication No. 48530).

(発明が解決しようとする課題) 上記の従来方法は、ガラス繊維や芳香族アラミド繊維を
用いた繊維強化プラスチック線材およびポリオキシメチ
レン線材の端止め方法としては有効であるが、高強力、
高弾性率を有する分子量50万以上の超高分子量ポリエ
チレン繊維を補強材とする繊維強化プラスチック線材を
これらの方法で端止め加工した場合は、上記超高分子量
ポリエチレン繊維の引張強力特性が十分に発揮されない
という問題があった。すなわち、線材の端部をループに
形成した場合は、上記線材が圧壊変形を受けて強力低下
を招き、かしめ部分で上記の線材が素抜けして線材本来
の強力を利用することができず、またソケットに挿入し
たり金属パイプを嵌合したりして樹脂で固める方法は、
線材と樹脂との接着性が弱く、比較的低応力で線材端部
が樹脂埋設部から素抜けして上記線材の高度の引張り強
力特性を発揮することができなかった。
(Problem to be Solved by the Invention) The above conventional method is effective as a method for end-stopping fiber-reinforced plastic wire rods and polyoxymethylene wire rods using glass fibers or aromatic aramid fibers;
When fiber-reinforced plastic wires made of ultra-high molecular weight polyethylene fibers with a molecular weight of 500,000 or more and a high modulus of elasticity are end-stopped using these methods, the tensile strength properties of the ultra-high molecular weight polyethylene fibers are fully exhibited. There was a problem that it was not done. In other words, when the end of the wire is formed into a loop, the wire undergoes crushing deformation, resulting in a decrease in strength, and the wire becomes hollow at the caulked portion, making it impossible to utilize the original strength of the wire. Also, the method of inserting it into a socket or fitting a metal pipe and hardening it with resin is
The adhesion between the wire and the resin was weak, and the end of the wire could be easily pulled out of the resin-embedded part under relatively low stress, making it impossible to exhibit the high tensile strength properties of the wire.

この発明は、超高分子量ポリエチレン繊維を含む補強繊
維の強い引張り強力特性を十分に発揮することができ、
樹脂埋設部から素抜けを生じることがなく、しかも使用
現場で容易に実施可能な端止め方法を提供するものであ
る。
This invention can fully exhibit the strong tensile strength properties of reinforcing fibers containing ultra-high molecular weight polyethylene fibers,
To provide an end-stopping method that does not cause the resin-embedded part to come off and can be easily implemented at the site of use.

(課題を解決するための手段) 超高分子量ポリエチレン繊維を含む補強繊維と合成重合
体樹脂とからなる引張強度40 kg / m ”以上
の繊維強化プラスチック線材の端部を偏平化し、この偏
平化部分に金属製リングを嵌合、圧着し、この金属製リ
ングが圧着された偏平化部分を管状の係合用部材に挿入
し樹脂で包埋固定する。
(Means for Solving the Problem) The ends of a fiber-reinforced plastic wire with a tensile strength of 40 kg/m or more, which is made of reinforcing fibers containing ultra-high molecular weight polyethylene fibers and synthetic polymer resin, are flattened, and the flattened portions are A metal ring is fitted and crimped thereon, and the flattened portion to which the metal ring is crimped is inserted into a tubular engagement member and embedded and fixed in resin.

上記の繊維強化プラスチック線材は、特開昭61−15
36]、1号公報に開示された可撓性抗張力線が好まし
い、使用する補強繊維は、少なくとも20g/デニール
、好ましくは30g/デニール以上、特に40g/デニ
ール以上の引張強度と少なくとも500 g/デニール
、好ましくは800 g /デニール以上、特に100
0 g /デニール以上の引張弾性率とを有する粘度平
均分子量50万以上、好ましくは100万以上の超高分
子量ポリエチレン繊維を主体とするものであり、この超
高分子量ポリエチレン繊維100%のものでもよく、こ
の超高分子量ポリエチレン繊維と芳香族ポリアミド繊維
、芳香族ポリエステル繊維、カーボン繊維およびガラス
繊維のいずれかとの複合体であってもよい、ただし、そ
の混合割合は、マトリックス材としての合成重合体樹脂
を含浸して繊維強化プラスチック線材としたときの引張
強度が40kg八−以へとなる割合であり、超高分子量
ポリエチレン繊維を全補強繊維の50%以上とすること
が好ましい。上記線材の引張強度が40 kg / m
 ”未満の場合は、テンションメンバ、ワイヤロープ、
ワイヤケーブル等の抗張力分野では強力不足となって使
用できない、マトリックス材としての合成重合体樹脂は
、不飽和ポリエステル樹脂、ビニールエステル樹脂、エ
ポキシ樹脂、ウレタンアクリレート樹脂等の熱硬化性樹
脂であり、これらが単独で、または2種以上を配合して
使用される。そして、上記の熱硬化性樹脂の液槽に前記
の補強繊維を通して含浸処理を施し、次に任意の断面形
状を有する加熱ダイを通して所望の断面形状に成形硬化
させることにより、この発明の繊維強化プラスチック線
材が製造される。
The above-mentioned fiber-reinforced plastic wire rod is
36], the flexible tensile strength wires disclosed in Publication No. 1 are preferred; the reinforcing fibers used have a tensile strength of at least 20 g/denier, preferably 30 g/denier or more, especially 40 g/denier or more and at least 500 g/denier. , preferably 800 g/denier or more, especially 100 g/denier
It is mainly composed of ultra-high molecular weight polyethylene fibers having a tensile modulus of 0 g/denier or more and a viscosity average molecular weight of 500,000 or more, preferably 1,000,000 or more, and may be made of 100% ultra-high molecular weight polyethylene fibers. It may be a composite of this ultra-high molecular weight polyethylene fiber and any one of aromatic polyamide fiber, aromatic polyester fiber, carbon fiber, and glass fiber, but the mixing ratio thereof may be determined by the synthetic polymer resin as the matrix material. It is preferable that the tensile strength of the fiber-reinforced plastic wire rod obtained by impregnating the reinforcing fibers is 40 kg or more, and that the ultra-high molecular weight polyethylene fibers should account for 50% or more of the total reinforcing fibers. The tensile strength of the above wire is 40 kg/m
” If the tension member, wire rope,
Synthetic polymer resins as matrix materials that cannot be used in the tensile strength field of wire cables and other products due to insufficient strength are thermosetting resins such as unsaturated polyester resins, vinyl ester resins, epoxy resins, and urethane acrylate resins. are used alone or in combination of two or more. Then, the reinforcing fibers are passed through a liquid bath of the thermosetting resin to undergo an impregnation treatment, and then the fiber-reinforced plastic of the present invention is molded and hardened into a desired cross-sectional shape through a heating die having an arbitrary cross-sectional shape. Wire rods are manufactured.

なお、マトリックス材としての合成重合体樹脂は、熱硬
化性樹脂に限定されるものではなく、紫外線硬化性樹脂
や熱可塑性樹脂を使用してもよい。
Note that the synthetic polymer resin as the matrix material is not limited to thermosetting resins, and ultraviolet curable resins and thermoplastic resins may also be used.

上記線材の端部を偏平化する手段は任意であるが、偏平
化に伴う補強繊維の損傷が少なく、線材に割れの生じる
ことがなく、かつ周囲に凹凸のない断面だ円形ないしは
小判形の棒状、板状または薄いリボン状に形成され、強
力保持率の上昇することが望まし7い0例えば、線材の
一部を表面平滑な治具で両側から挟み、これをプレスで
加圧する方法が例示される。なお、偏平化後の線材の断
面形状は、長径と短径との比が2〜15、特に5〜10
であることが好ましい。また、偏平化する部分の長さは
5〜50備が好ましい。
Although the means for flattening the end of the wire rod is arbitrary, the reinforcing fibers are less damaged due to flattening, the wire rod does not crack, and the cross section is oval or oval with no unevenness around the rod. It is desirable that the wire be formed into a plate shape or a thin ribbon shape to increase the strength retention rate.70 For example, a method of sandwiching a part of the wire from both sides with a jig with a smooth surface and pressurizing it with a press is exemplified. be done. Note that the cross-sectional shape of the wire after flattening has a ratio of the major axis to the minor axis of 2 to 15, particularly 5 to 10.
It is preferable that Moreover, the length of the part to be flattened is preferably 5 to 50 mm.

上記の偏平化部分に嵌合、圧着する金属製リングは、ア
ルミニウム、銅、しんちゅう等の金属からなるリングで
ある。その形状は、上記偏平化部分に緩く嵌合するもの
であれば任意であり、その肉厚は偏平化部分の厚さの2
〜20倍、また長さは偏平化部分の長さの173〜1/
10がそれぞれ好ましい、そして、上記金属製リングの
使用個数は、線材の長さ10(1)当り2〜4個が好ま
しい。
The metal ring that is fitted and crimped onto the flattened portion is a ring made of metal such as aluminum, copper, or brass. Its shape is arbitrary as long as it fits loosely into the flattened part, and its wall thickness is 2 times the thickness of the flattened part.
~20 times, and the length is 173~1/ of the length of the flattened part
The number of metal rings used is preferably 2 to 4 per 10(1) of the length of the wire.

上記の偏平化部分を包埋する樹脂は、常温硬化性の樹脂
、特にエポキシ系樹脂が好ましく、アラルダイトスタン
ダード(チバガイギー社製、商品名)、ソケットストロ
ング(杉田産業社製、商品名)などが例示される。
The resin for embedding the flattened portion is preferably a resin that hardens at room temperature, especially an epoxy resin, examples of which include Araldite Standard (manufactured by Ciba Geigy, trade name) and Socket Strong (manufactured by Sugita Sangyo, trade name). be done.

(作用) 繊維強化プラスチック線材の端部を偏平化し、金ftL
製リングを圧着することにより、線材と包埋用樹脂との
接着面積が増大し、線材の端部に包埋用樹脂が強固に接
着し、線材の引張強度未満の引張り応力では素抜けが生
じなくなる。特に、偏平化部分にあらかじめ包埋用樹脂
液をなじませた後、テーバを有する円筒状、直方体の型
枠、いわゆるソケットに挿入し、このソケット内に包埋
用樹脂を充填固化した場合は、接着が一層強固に行なわ
れる。
(Function) The end of the fiber reinforced plastic wire is flattened and gold ftL
By crimping the ring, the bonding area between the wire and the embedding resin increases, the embedding resin firmly adheres to the end of the wire, and tensile stress below the tensile strength of the wire will cause it to break through. It disappears. In particular, when the embedding resin liquid is applied to the flattened part in advance, it is inserted into a cylindrical or rectangular parallelepiped mold with a taper, so-called a socket, and the embedding resin is filled and solidified into this socket. Adhesion is even stronger.

(実施例) 引張強度32g/デニール、引張弾性率1150 g 
/デニール、合計繊度1600デニールの超高分子量ポ
リエチレン繊維糸条を6本引揃え、ウレタンアクリレー
ト系マトリックス樹脂液に浸漬し、引抜き成形法によっ
て第1図の直径1.4mm、li維体積含有率(vf)
 72%の繊維強化プラスチック線材1を製造した。こ
の線材1の引張強力は、キャプスタングリップ把持法を
用いテンシロン引張試験機で1lllJ定したところ2
83kgf(184kgf/ma”)を示した。
(Example) Tensile strength: 32 g/denier, tensile modulus: 1150 g
/denier, with a total fineness of 1600 denier, six ultra-high molecular weight polyethylene fiber threads were aligned, immersed in a urethane acrylate matrix resin solution, and then pultruded into a material with a diameter of 1.4 mm and a li fiber volume content (as shown in Figure 1). vf)
A 72% fiber-reinforced plastic wire rod 1 was manufactured. The tensile strength of this wire 1 was determined as 1llllJ using a Tensilon tensile tester using the capstan grip gripping method.
83 kgf (184 kgf/ma").

上記の線材1を50国mの長さに切断し、その両端15
a*の部分を治具に挟み、プレス機を用い200kgf
の荷重を加えて偏平化し、第2図および第3図に示すよ
うに、厚さ0.3m、幅5.1mの偏平化部分1aを形
成した。この偏平化部分1aにアルミニウム製の内径4
閣、肉厚1.5+amのパイプを3備の長さに切断し上
記線材の偏平化部分が挿入し易いように予備圧縮して得
られた偏平な金属製リング2を等間隔に嵌合しく第4図
および第5図参照)、シかるのちこの金属製リング2を
圧縮して線材工の偏平化部分1aに圧着しく第6図参照
)、試験片を得た0次いで、両端の偏平化部分を杉田産
業社製エポキシ系2液接着剤混合液(ソケットロング)
で充分になじませ、しかるのち第7図のソケット3に挿
入し、このソケット3に上記の樹脂液4(第8図参照)
を充填し、埋設長を15C!11として常温で一昼夜放
置し、上記の樹脂液4を固化した。この試験片の両端を
端止めした上記両ソケット3をテンシロン引張試験機に
ピンで取付け。
Cut the above wire rod 1 into a length of 50 mm, and
Place the part a* in a jig and use a press machine to press 200 kgf.
The flattened portion 1a having a thickness of 0.3 m and a width of 5.1 m was formed as shown in FIGS. 2 and 3. This flattened portion 1a has an aluminum inner diameter 4
First, cut a pipe with a wall thickness of 1.5+ am into three lengths, and fit the flat metal rings 2 obtained by pre-compressing them at equal intervals so that the flattened part of the wire rod can be easily inserted. (See Figures 4 and 5), and then compress the metal ring 2 and press it onto the flattened part 1a of the wire rod (see Figure 6) to obtain a test piece.Then, both ends were flattened. Use Sugita Sangyo Co., Ltd.'s 2-component epoxy adhesive mixture (socket long) for the part.
After that, insert it into the socket 3 shown in Fig. 7, and pour the above resin liquid 4 into this socket 3 (see Fig. 8).
Fill it with 15C burial length! As No. 11, the above resin liquid 4 was solidified by standing at room temperature for a day and night. Both sockets 3 with both ends of this test piece fixed were attached to the Tensilon tensile testing machine with pins.

引張り強力を測定したところ、225kgfの最高応力
で偏平化部の根元部分が破断した。また、強力保持率(
埋設線材強力/線材強力)は80%であった。
When the tensile strength was measured, the root portion of the flattened portion broke at a maximum stress of 225 kgf. In addition, strong retention rate (
Buried wire strength/wire strength) was 80%.

(比較例) 上記実施例の繊維強化プラスチック線材を50国の長さ
に切断し、その両端をそのままソケット3に挿入し、実
施例と同様に埋設長さが15L:Mになるように樹脂埋
設により固定し、比較例1の試験片を得た。この比較例
1の試験片の引張強力は、85kgの最高応力で引き抜
けが生じた。また、強力保持率は30%であった。
(Comparative example) The fiber-reinforced plastic wire rod of the above example was cut to a length of 50 mm, both ends of which were inserted into the socket 3 as they were, and the resin was buried in the same manner as in the example so that the buried length was 15L:M. was fixed to obtain a test piece of Comparative Example 1. Regarding the tensile strength of the test piece of Comparative Example 1, pull-out occurred at a maximum stress of 85 kg. Moreover, the strength retention rate was 30%.

(発明の効果) この発明は、超高分子量ポリエチレン繊維を含む繊維強
化プラスチック線材の端部を偏平化し、腋部に金属製リ
ングを嵌合して樹脂で包埋固定するという簡便な方法で
あるから、従来方法に比べて包埋固定用樹脂との接触面
積が著しく増大して接着力および線材の強力保持率が向
上し、従来生じていた素抜けおよび煩雑な作業が解消し
、超高分子量ポリエチレン繊維を含む繊維強化プラスチ
ック線材の優れた引張強力を充分に活かすことができ、
光フアイバーケーブルのテンションメンバ、ワイヤロー
プおよびワイヤケーブル等の抗張力材として使用した場
合の性能が著しく向上する。
(Effect of the invention) This invention is a simple method of flattening the end of a fiber-reinforced plastic wire containing ultra-high molecular weight polyethylene fiber, fitting a metal ring to the armpit, and embedding and fixing it in resin. Compared to the conventional method, the contact area with the embedding and fixing resin is significantly increased, improving adhesive strength and strong retention of the wire, eliminating the conventional process of slip-through and complicated work, and improving ultra-high molecular weight The excellent tensile strength of fiber-reinforced plastic wire containing polyethylene fibers can be fully utilized.
When used as a tension member for optical fiber cables, a tensile strength material for wire ropes, wire cables, etc., the performance is significantly improved.

【図面の簡単な説明】[Brief explanation of drawings]

図面はこの発明の実施態様を例示し、第1図は繊維強化
プラスチック線材の正面図、第2図は上配線材の偏平化
部分の正面図、第3図は第2図の■−m線断面図、第4
図は金属製リングを嵌合した線材の正面図、第5図は第
4図の■−■線断面図、第6図は金属製リングを圧縮し
た状態の断面図、第7図はソケットを被着した状態の一
部破砕正面図、第8図は樹脂を充填した状態のソケット
の一部破砕正面図である。 1:繊維強化プラスチック線材、la:偏平化部分、2
:金属製リング、3:ソケット(管状の係合用部材)、
4:樹脂。
The drawings illustrate embodiments of the present invention; FIG. 1 is a front view of a fiber-reinforced plastic wire, FIG. 2 is a front view of a flattened portion of the upper wiring material, and FIG. 3 is a view taken along the ■-m line in FIG. 2. Cross section, 4th
The figure is a front view of the wire fitted with a metal ring, Figure 5 is a sectional view taken along the line ■-■ in Figure 4, Figure 6 is a sectional view of the metal ring in a compressed state, and Figure 7 is a socket. FIG. 8 is a partially exploded front view of the socket filled with resin. 1: Fiber-reinforced plastic wire, la: flattened part, 2
: Metal ring, 3: Socket (tubular engagement member),
4: Resin.

Claims (1)

【特許請求の範囲】 〔1〕超高分子量ポリエチレン繊維を含む補強繊維と合
成重合体樹脂とからなる引張強度40kg/mm^2以
上の繊維強化プラスチック線材の端部を偏平化し、この
偏平化部分に金属製リングを嵌合、圧着し、この金属製
リングの圧着された偏平化部分を管状の係合用部材に挿
入し樹脂で包埋固定することを特徴とする繊維強化プラ
スチック線材の端止め方法。
[Scope of Claims] [1] An end portion of a fiber-reinforced plastic wire material having a tensile strength of 40 kg/mm^2 or more made of reinforcing fibers containing ultra-high molecular weight polyethylene fibers and a synthetic polymer resin is flattened, and the flattened portion A method for end-fixing a fiber-reinforced plastic wire, which comprises fitting and crimping a metal ring to the metal ring, inserting the crimped flattened portion of the metal ring into a tubular engagement member, and embedding and fixing it in resin. .
JP17832489A 1989-07-10 1989-07-10 Ending of fiber reinforced plastic wire Pending JPH0345792A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP17832489A JPH0345792A (en) 1989-07-10 1989-07-10 Ending of fiber reinforced plastic wire

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP17832489A JPH0345792A (en) 1989-07-10 1989-07-10 Ending of fiber reinforced plastic wire

Publications (1)

Publication Number Publication Date
JPH0345792A true JPH0345792A (en) 1991-02-27

Family

ID=16046493

Family Applications (1)

Application Number Title Priority Date Filing Date
JP17832489A Pending JPH0345792A (en) 1989-07-10 1989-07-10 Ending of fiber reinforced plastic wire

Country Status (1)

Country Link
JP (1) JPH0345792A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010097060A (en) * 2008-10-17 2010-04-30 Unitika Ltd Tension member for optical cable
WO2019093137A1 (en) 2017-11-07 2019-05-16 ヒュービットジェノミクス株式会社 Method for inhibiting allergic predisposition acquisition in infant stage through effect of suppressing ige class-specific immunoreaction

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010097060A (en) * 2008-10-17 2010-04-30 Unitika Ltd Tension member for optical cable
WO2019093137A1 (en) 2017-11-07 2019-05-16 ヒュービットジェノミクス株式会社 Method for inhibiting allergic predisposition acquisition in infant stage through effect of suppressing ige class-specific immunoreaction

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