JPH0331389A - After-foamable gel composition - Google Patents
After-foamable gel compositionInfo
- Publication number
- JPH0331389A JPH0331389A JP16366189A JP16366189A JPH0331389A JP H0331389 A JPH0331389 A JP H0331389A JP 16366189 A JP16366189 A JP 16366189A JP 16366189 A JP16366189 A JP 16366189A JP H0331389 A JPH0331389 A JP H0331389A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- foaming
- post
- composition
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 54
- 238000005187 foaming Methods 0.000 claims abstract description 32
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000004088 foaming agent Substances 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004094 surface-active agent Substances 0.000 claims abstract description 16
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims abstract description 14
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims abstract description 14
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims abstract description 10
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims abstract description 10
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000001282 iso-butane Substances 0.000 claims abstract description 7
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229920002125 Sokalan® Polymers 0.000 claims abstract description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000003349 gelling agent Substances 0.000 claims description 11
- 239000004480 active ingredient Substances 0.000 claims description 9
- 239000001294 propane Substances 0.000 claims description 7
- 239000004604 Blowing Agent Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 21
- 239000006260 foam Substances 0.000 abstract description 13
- 239000000344 soap Substances 0.000 abstract description 9
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 239000000499 gel Substances 0.000 description 33
- -1 ethanol is added Chemical compound 0.000 description 18
- 235000019441 ethanol Nutrition 0.000 description 16
- 239000000443 aerosol Substances 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 239000012459 cleaning agent Substances 0.000 description 7
- 239000006210 lotion Substances 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229940075894 denatured ethanol Drugs 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 4
- 238000005342 ion exchange Methods 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 3
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- RRKTZKIUPZVBMF-IBTVXLQLSA-N brucine Chemical compound O([C@@H]1[C@H]([C@H]2C3)[C@@H]4N(C(C1)=O)C=1C=C(C(=CC=11)OC)OC)CC=C2CN2[C@@H]3[C@]41CC2 RRKTZKIUPZVBMF-IBTVXLQLSA-N 0.000 description 3
- RRKTZKIUPZVBMF-UHFFFAOYSA-N brucine Natural products C1=2C=C(OC)C(OC)=CC=2N(C(C2)=O)C3C(C4C5)C2OCC=C4CN2C5C31CC2 RRKTZKIUPZVBMF-UHFFFAOYSA-N 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 2
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 208000003251 Pruritus Diseases 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000000118 hair dye Substances 0.000 description 2
- 150000008282 halocarbons Chemical class 0.000 description 2
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 2
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 2
- 239000000041 non-steroidal anti-inflammatory agent Substances 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- 229920001059 synthetic polymer Polymers 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 1
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- 241000416162 Astragalus gummifer Species 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 102000011632 Caseins Human genes 0.000 description 1
- 108010076119 Caseins Proteins 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 239000001879 Curdlan Substances 0.000 description 1
- 229920002558 Curdlan Polymers 0.000 description 1
- 235000017788 Cydonia oblonga Nutrition 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- CGBXSWXZXBQCMR-UHFFFAOYSA-N Glycerol 1-hexadecanoate Chemical compound OCC(O)CO.CCCCCCCCCCCCCCCC(O)=O CGBXSWXZXBQCMR-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- 229920000057 Mannan Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- HDSBZMRLPLPFLQ-UHFFFAOYSA-N Propylene glycol alginate Chemical compound OC1C(O)C(OC)OC(C(O)=O)C1OC1C(O)C(O)C(C)C(C(=O)OCC(C)O)O1 HDSBZMRLPLPFLQ-UHFFFAOYSA-N 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 230000003254 anti-foaming effect Effects 0.000 description 1
- 230000001166 anti-perspirative effect Effects 0.000 description 1
- 239000003213 antiperspirant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 235000019316 curdlan Nutrition 0.000 description 1
- 229940078035 curdlan Drugs 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 229940087091 dichlorotetrafluoroethane Drugs 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000010409 propane-1,2-diol alginate Nutrition 0.000 description 1
- 239000000770 propane-1,2-diol alginate Substances 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical class NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 235000010487 tragacanth Nutrition 0.000 description 1
- 239000000196 tragacanth Substances 0.000 description 1
- 229940116362 tragacanth Drugs 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野］ 本発明はエアゾール製品用の内容物に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to contents for aerosol products.
詳しくは４０％以上の水とゲル化剤、界面活性剤、後発
泡剤から作られるかあるいはさらに有効成分とアルコー
ル類を加えて作られるエアゾール製品用に用いる後発泡
性ゲル組成物に関する。Specifically, the present invention relates to a post-foaming gel composition for use in aerosol products, which is made from 40% or more of water, a gelling agent, a surfactant, and a post-foaming agent, or is made by further adding active ingredients and alcohols.
本発明によれば、組成中に石ケン（Ｆ！ｐち、高級脂肪
酸の水溶性塩類）を含まず、使用後のべとつき感が全く
無く、後発泡性を示す新規なゲル組成物が提供される。According to the present invention, there is provided a novel gel composition that does not contain soap (F!p, water-soluble salts of higher fatty acids) in its composition, has no sticky feeling after use, and exhibits post-foaming properties. Ru.
本発明による代表的製品としては、例えば、清拭剤、化
粧水、ヘアトリートメント剤、ヘアーセット剤、染毛剤
、パーマネントウェーブ剤等の化粧品、消炎鎮痛剤、か
ゆみ止め等の医薬品あるいは自動車や家具のつや出し剤
等が挙げられる。Typical products according to the present invention include, for example, cosmetics such as cleaning agents, lotions, hair treatment agents, hair setting agents, hair dyes, and permanent waving agents, pharmaceuticals such as anti-inflammatory analgesics, and anti-itch drugs, and products for automobiles and furniture. Examples include polishing agents.
後発泡性ゲル組成物については、吐出後６０秒間ゲル状
態を保ち、かつ、剪断応力を加えると発泡するような組
成物が特公昭４９−３４９１２号公報に記載されている
。Regarding post-foamable gel compositions, Japanese Patent Publication No. 49-34912 describes a composition that maintains a gel state for 60 seconds after being discharged and foams when shear stress is applied.
この公知の後発泡性ゲル組成物は、水４０％以上と石ケ
ン（高級脂肪酸の水溶性塩）、水溶性ゲル化助剤及び後
発泡剤を必須成分としており、後発泡剤として、飽和脂
肪族炭化水素及びハロゲン化炭化水素を単独又は混合し
て利用している。This known post-foaming gel composition contains at least 40% water, soap (a water-soluble salt of higher fatty acid), a water-soluble gelling aid, and a post-foaming agent as essential components. Group hydrocarbons and halogenated hydrocarbons are used singly or in combination.
従来の後発泡性ゲル組成物は、ゲルの安定性が高く、吐
出後少なくとも６０秒間はゲル状態を保つが、石鹸を必
須成分として用いているために可能であり、一方ゲルで
吐出したものに剪断応力を加えると発泡するが発泡した
泡が石鹸成分を含んでいるために消えないとゆう欠点が
あることもわかった。Conventional post-foaming gel compositions have high gel stability and remain in a gel state for at least 60 seconds after dispensing, which is possible due to the use of soap as an essential ingredient; It was also found that when shear stress is applied, it foams, but the foamed foam does not disappear because it contains soap components.
特公昭４９−３４９１２号に示される実施例のものにつ
いて、手のひらに組成物を取り出し指でこすると発泡す
るこの泡を両手でこすり合わせているといつまでも泡は
消えず、細かな泡を含んだクリーム状で残ったまま消え
ず、また、簡単に拭き取ることができない。この現象は
使用後に洗い落すひげそり剤やシャンプー等にはなんら
問題はないが汚れをティッシュ等で拭きとる清拭剤や、
塗りっばなしで処理するトリートメント剤等には不向き
な組成物であることが判明した。Regarding the example shown in Japanese Patent Publication No. 49-34912, when you take out the composition in your palm and rub it with your fingers, it foams.If you rub your hands together, the foam will not disappear forever, and it will become a cream containing fine foam. It remains behind and cannot be easily wiped off. This phenomenon does not cause any problems with shaving agents, shampoos, etc. that are washed off after use, but cleaning agents that wipe off dirt with tissues, etc.
The composition was found to be unsuitable for treatment agents that require no application.
さらに、エタノール等のアルコールを添加すればゲル化
が困難となる欠点があると共に、石鹸に起因する組成物
がアルカリ性であるため商品設計にかなりの制約があっ
た。Furthermore, there is a drawback that gelation becomes difficult if alcohol such as ethanol is added, and the composition resulting from soap is alkaline, which imposes considerable restrictions on product design.
そこで本発明者等は、後発泡性ゲル組成物について種々
研究したところ、吐出されたゲルが保持する時間は、ゲ
ルを目的部位に塗り延ばして湿潤されるために必要な時
間は３０秒もあれば充分であることを見出した。Therefore, the present inventors conducted various studies on post-foaming gel compositions, and found that the time required for the expelled gel to remain is as long as 30 seconds, which is necessary for applying the gel to the target area and moistening it. I found that it is sufficient.
そこで鋭意研究を重ねた結果、吐出後３０秒間以上ゲル
状態を保ち、かつ、剪断応力を加えると発泡し、さらに
剪断応力を加え続けると、通常１０秒程度長くても３０
秒程度で簡単に消泡し、石鹸を含まず使用後に水で洗い
流したり濡れタオルで拭き取る必要のない新規な組成の
後発泡性ゲル組成物を見い出し本発明を完成するに至っ
た。As a result of extensive research, we found that if the gel state is maintained for 30 seconds or more after dispensing, and if shear stress is applied, foaming occurs.
The present inventors have discovered a post-foaming gel composition with a novel composition that defoams easily in about seconds, does not contain soap, and does not require rinsing with water or wiping with a wet towel after use, and has completed the present invention.
本発明は、
（１）ゲル化剤０．０１〜５重量％、界面活性剤０．０
１〜５重量％、水４０〜９８重量％、後発泡剤０．５〜
２０重量％からなる組成物及び／または前記組成物に有
効成分０．１〜１０ｉｔ量％、アルコール類５〜５０重
量％を加えてなる組成物であって、常温大気圧下少なく
とも３０秒間ゲル状を保ち、かつ、剪断応力を加えた場
合発泡し、さらに剪断応力をかけ続けた場合短時間で消
泡することを特徴とする後発泡性ゲル組成物。The present invention includes: (1) gelling agent 0.01 to 5% by weight, surfactant 0.0%;
1-5% by weight, water 40-98% by weight, post-foaming agent 0.5-5%
A composition comprising 20% by weight and/or a composition comprising 0.1 to 10 it weight% of an active ingredient and 5 to 50 weight% of an alcohol added to the above composition, wherein the gel-like composition is formed for at least 30 seconds at room temperature and atmospheric pressure. 1. A post-foamable gel composition which maintains the following properties, foams when shear stress is applied, and defoams in a short period of time when shear stress is continued to be applied.
（２）ゲル化剤がカルボキシビニルポリマーであり、界
面活性剤がＨＬＢＩＯ以上の非イオン型であり、後発泡
剤がイソペンクン、ノルマルペンタン、イソブタン、ノ
ルマルブタン、プロパン及びジメチルエーテルから選ば
れる１種又は２種以上の混合物であり、アルコール類を
含む場合はアルコール類が１価のアルコールであること
を特徴とする上記（１）記載の後発泡性ゲル組成物。(2) The gelling agent is a carboxyvinyl polymer, the surfactant is a nonionic type of HLBIO or higher, and the post-foaming agent is one or two selected from isopencune, normal pentane, isobutane, normal butane, propane, and dimethyl ether. The post-foamable gel composition according to (1) above, which is a mixture of at least one kind of alcohol, and when it contains an alcohol, the alcohol is a monohydric alcohol.
（３）後発泡剤がイソペンタン及びノルマルペンタンか
ら選ばれる成分８０重量％以上とイソブタン、ノルマル
ブタン、プロパン及びジメチルエーテルから選ばれる成
分２０重量％以下からなることを特徴とする上記（１）
又は（２）記載の後発泡性ゲル組成物。(3) The above (1), wherein the post-foaming agent consists of 80% by weight or more of a component selected from isopentane and n-pentane and 20% by weight or less of a component selected from isobutane, n-butane, propane and dimethyl ether.
Or the post-foamable gel composition described in (2).
に関するものである。It is related to.
本発明に用いるゲル化剤は最終組成物をゲル状にするた
めの成分であり、たとえばカルボキシビニルポリマー、
ポリビニルアルコール、ポリアクリル酸ナトリウム、ポ
リエチレングリコール等の合成高分子、メチルセルロー
ス、エチルセルロース、ヒドロキシエチルセルロース、
ヒドロキシプロピルセルロース、カルボキシメチルセル
ロース、メチルヒドロキシプロピルセルロース、可溶性
デンプン、アルギン酸プロピレングリコール等の半合成
高分子、グアーガム、ローカストビーンガム、クインス
シード、カラギーナン、ガラクタン、アラビアゴム、ト
ラガント、ペクチン、マンナン、デンプン、キサンタン
ガム、デキストリン、サクシノグルカン、カードラン、
ゼラチン、カゼイン、アルブミン、コラーゲン等の天然
高分子などもあげられるが、水溶液のゲル化が可能なも
のであればこれらのみに限定されるものではない。The gelling agent used in the present invention is a component that makes the final composition gel-like, and includes, for example, carboxyvinyl polymer,
Synthetic polymers such as polyvinyl alcohol, sodium polyacrylate, polyethylene glycol, methylcellulose, ethylcellulose, hydroxyethylcellulose,
Hydroxypropyl cellulose, carboxymethyl cellulose, methyl hydroxypropyl cellulose, soluble starch, semi-synthetic polymers such as propylene glycol alginate, guar gum, locust bean gum, quince seed, carrageenan, galactan, gum arabic, tragacanth, pectin, mannan, starch, xanthan gum , dextrin, succinoglucan, curdlan,
Examples include natural polymers such as gelatin, casein, albumin, and collagen, but are not limited to these as long as they can gel an aqueous solution.
該ゲル化剤は組成物中０．０１〜５重量％、好ましくは
０．０５〜２重量％を用いる。該添加量は０．０１重量
％未満である場合充分なゲルが得られず、また、５重量
％をこえるとゲル化剤のべとつきによって不快感を与え
ることになるので好ましくない。The gelling agent is used in an amount of 0.01 to 5% by weight, preferably 0.05 to 2% by weight in the composition. If the amount added is less than 0.01% by weight, a sufficient gel cannot be obtained, and if it exceeds 5% by weight, the stickiness of the gelling agent will cause discomfort, which is not preferable.
本発明に用いる界面活性剤は、後発泡剤有効成分を可溶
化分散させるものであり、たとえばポリオキシンエチレ
ンアルキルエーテル、ポリオキシエチレンポリオキシプ
ロピレンアルキルエーテル、ポリオキシエチレンアルキ
ルフェニルエーテル、ポリオキシエチレンヒマシ油誘導
体等の非イオン型、アルキル硫酸塩、ポリオキシエチレ
ンアルキルエーテル硫酸塩、Ｎ−アシルアミノ酸塩、Ｎ
−アシルメチルタウリン塩、ポリオキシエチレンアルキ
ルエーテル酢酸塩、アルキルスルホカルボン酸塩、α−
オレフィンスルホン酸塩、アルキルリン酸塩、ポリオキ
シエチレンアルキルエーテルリン酸塩等の陰イオン型、
アルキルアンモニウム塩、アルキルベンジルアンモニウ
ム塩等の陽イオン型、酢酸ベタイン、イミダゾリウムベ
タイン、レシチン等の両性型等があげられるがこれらの
みに限定されるものではない。The surfactant used in the present invention is one that solubilizes and disperses the active ingredient of the post-foaming agent, and includes, for example, polyoxine ethylene alkyl ether, polyoxyethylene polyoxypropylene alkyl ether, polyoxyethylene alkylphenyl ether, and polyoxyethylene castor oil. Non-ionic derivatives, alkyl sulfates, polyoxyethylene alkyl ether sulfates, N-acylamino acid salts, N
-Acylmethyl taurine salt, polyoxyethylene alkyl ether acetate, alkyl sulfocarboxylate, α-
Anionic types such as olefin sulfonates, alkyl phosphates, polyoxyethylene alkyl ether phosphates,
Examples include, but are not limited to, cationic types such as alkyl ammonium salts and alkylbenzylammonium salts, and amphoteric types such as acetic acid betaine, imidazolium betaine, and lecithin.
該界面活性剤は組成物中０．０１〜５重量％、好ましく
は０．１〜３重量％を用いる。該添加量は０．０１重量
％未満である場合、後発泡剤有効成分の可溶化分散が充
分でなく、また５重量％をこえると界面活性剤のべとつ
きによって不快感を与えることになるので好ましくない
。The surfactant is used in an amount of 0.01 to 5% by weight, preferably 0.1 to 3% by weight in the composition. If the amount added is less than 0.01% by weight, the solubilization and dispersion of the active ingredient of the post-foaming agent will not be sufficient, and if it exceeds 5% by weight, the stickiness of the surfactant will cause discomfort, so it is preferable. do not have.
本発明に用いる水は組成物の基剤となるものであり、通
常、水道水、蒸留水、イオン交換水等を用い、組成物中
４０〜９８重量％、好ましくは６０〜９５重量％を用い
る。該添加量は４０重量％未満である場合、充分な発泡
が得られないばかりでなく、経済的にも好ましくない。The water used in the present invention serves as the base of the composition, and is usually tap water, distilled water, ion-exchanged water, etc., and is used in an amount of 40 to 98% by weight, preferably 60 to 95% by weight of the composition. . If the amount added is less than 40% by weight, not only will sufficient foaming not be obtained, but it will also be economically unfavorable.
また９８重量％をこえると他の成分量に実質的に影響を
与え本発明の組成物となり得ない。Moreover, if it exceeds 98% by weight, the amounts of other components will be substantially affected and the composition of the present invention cannot be obtained.
本発明に用いる後発泡剤は、大気圧中に開放されたゲル
状の組成物を発泡状態にするものであり、たとえば、プ
ロパン、ブタン、ペンタン、ヘキサンなどの脂肪族炭化
水素、トリクロロトリフルオロエタン、ジクロロテトラ
フルオロエタンなどの部分的または全体的にハロゲン化
された炭化水素、ジメチルエーテルなどがあげられるが
、これらのみに限定されるものではない。The post-foaming agent used in the present invention foams a gel-like composition exposed to atmospheric pressure, and includes, for example, aliphatic hydrocarbons such as propane, butane, pentane, and hexane, and trichlorotrifluoroethane. , partially or fully halogenated hydrocarbons such as dichlorotetrafluoroethane, dimethyl ether, and the like, but are not limited to these.
該後発泡剤は組成物中０．５重量％〜２０重量％、好ま
しくは１重量％〜１０重量％を用いる。該添加量は０．
５重量％未満である場合、充分な発泡が得られなく、ま
た２０重量％をこえると大気圧中に開放された瞬間に発
泡してしまい好ましくない。The post-foaming agent is used in an amount of 0.5% to 20% by weight, preferably 1% to 10% by weight in the composition. The amount added is 0.
If it is less than 5% by weight, sufficient foaming cannot be obtained, and if it exceeds 20% by weight, foaming will occur the moment it is exposed to atmospheric pressure, which is not preferable.
液化ガスであるイソブタン、ノルマルブタン、プロパン
、ジメチルエーテルを２０重量％以下用いるのは発泡性
を良くするためである。The reason why liquefied gases such as isobutane, normal butane, propane, and dimethyl ether are used in an amount of 20% by weight or less is to improve foaming properties.
本発明に用いるアルコール類はエチルアルコール、イソ
プロピルアルコールなどの一部アルコールの外、エチレ
ングリコール、プロピレングリコール、ｌ、３−ブチレ
ングリコール、グリセリン、ソルビトールなどの多価ア
ルコールを組成物中１重量％〜５０重量％、好ましくは
、５重量％〜２０重量％用いることが出来る。The alcohols used in the present invention include some alcohols such as ethyl alcohol and isopropyl alcohol, as well as polyhydric alcohols such as ethylene glycol, propylene glycol, 1,3-butylene glycol, glycerin, and sorbitol, in an amount of 1% to 50% by weight in the composition. % by weight, preferably from 5% to 20% by weight can be used.
これらの−価アルコール、エチルアルコール、変性エチ
ルアルコール、イソプロピルアルコールは、生成ゲルの
透明性の向上および低温においての凍結防止に役立つ。These -hydric alcohols, ethyl alcohol, denatured ethyl alcohol, and isopropyl alcohol are useful for improving the transparency of the resulting gel and preventing freezing at low temperatures.
本発明による後発泡性ゲル組成物は化粧品として、化粧
水、体の一部または全部の清拭剤、ヘアトリートメント
剤、ヘアセット剤、染毛削、パーマネントウェーブ剤、
制汗剤、除毛剤等、医薬製剤として消炎鎮痛剤、かゆみ
止め、あるいは、自動車、家具等のつや出し剤、硬質面
クリーナー衣類の洗浄剤、消臭剤等の家庭用品等に用い
る有効成分を添加して調製することができる。The post-foaming gel composition according to the present invention can be used as a cosmetic product, such as a lotion, a part or whole body cleaning agent, a hair treatment agent, a hair setting agent, a hair dye shaver, a permanent waving agent,
Active ingredients used in pharmaceutical preparations such as antiperspirants and hair removers, anti-inflammatory analgesics, anti-itch agents, and household products such as polishing agents for automobiles and furniture, hard surface cleaners, cleaning agents for clothing, deodorants, etc. It can be prepared by adding
つぎに本発明を実施例に基づいてさらに詳細に説明する
が、本発明はかかる実施例のみに限定されるものではな
い。Next, the present invention will be explained in more detail based on Examples, but the present invention is not limited to these Examples.
実施例１ （化粧水）
９５％ブルシン変性エタノール１０．０部、イオン交換
水７６．５５部、グリセリン５．０部、界面活性剤とし
てＮＰ−２０（日光ケミカルズ■製、 ＨＬＢ ２０．
０）１．０部、ゲル化剤としてカーボボール９４０ （
Ｂ、Ｆ。Example 1 (Lotion) 10.0 parts of 95% brucine-denatured ethanol, 76.55 parts of ion-exchanged water, 5.0 parts of glycerin, and NP-20 as a surfactant (manufactured by Nikko Chemicals ■, HLB 20.0 parts).
0) 1.0 part, Carboball 940 (
B, F.
Ｇｏｏｄｒｉｃｈ Ｃｈｅｍｉｃａｌ Ｃｏｍｐａｎｙ
） ０．２部、香料としてＢｏｕｑｕｅｔ ８４５１／
ＳＡ （山本番料ＩＩ） ０．０５部、トリエタノール
アミン０．２部、後発泡剤としてインペンタン７．０部
をエアゾール用ポリエチレンテレフタレート製透明耐圧
容器（滴注量７９０１ｄ）に充填し、エアゾール用バル
ブを取りつけた後、よく振盪し窒素ガスにて約２ ｋｇ
／ｃｍ”（ゲージ圧）に加圧し、後発泡性ゲル組成物（
６０ｇ ）の清拭剤を作製した。Goodrich Chemical Company
) 0.2 parts as fragrance Bouquet 8451/
0.05 parts of SA (Yamamoto Banryo II), 0.2 parts of triethanolamine, and 7.0 parts of impentane as a post-foaming agent were filled into a transparent pressure-resistant container made of polyethylene terephthalate for aerosols (dropping amount 7901d), and the aerosol After attaching the valve, shake well and remove about 2 kg with nitrogen gas.
/cm" (gauge pressure), and the post-foamable gel composition (
60g) of cleaning agent was prepared.
組成物を変えたほかは実施例１と同様にして、清拭剤（
実施例２）、ヘアセット剤（実施例３）、ヘアトリート
メント剤（実施例４）及び殺菌剤（実施例５）を調製し
た。A cleaning agent (
Example 2), a hair setting agent (Example 3), a hair treatment agent (Example 4), and a bactericide (Example 5) were prepared.
実施例２ （清拭剤）
イオン交換水
界面活性剤 ＮＰ−２０
一へ％
９１．８１９
０．８
染 料 青色１号
トリエタノールアミン
後発泡剤 イソベンクン
実施例３
（ヘアセット剤）
９５％ブルシン変性エタノール
イオン交換水
グリセリン
界面活性剤 ＢＣ−４０７Ｘ
ビニル共Ｎ合体
０．００１
０．２
７．０
一／−％
１０．０
？３．０９９
５．０
１．０
香料
染料
後発泡剤
Ｊａｓｍｉｎ ＢＡＴ−２８６２（高砂香料ｍ＞赤色１
０２号
トリエタノールアミン
イソペンクン
ｎ−ブタン
０゜１
０．００１
０．４
６．３
０．７
実施例５ （殺菌剤）
９５％ゲラニオール変性エタノール
イオン交換水
界面活性剤 ＰＢＣ−４４（日光ケルカルズ■）有効成
分 ＣＡ−１０１（日光ケルカルズ■）ゲル化剤
ヒドロキシエチルセルロース後発泡剤 イソベンク
ン
賀／−％
１０．０
８２．９
１．０
０．１
１．０
５．０
実施例４
界面活性剤
有効成分
香料
染料
ゲル化剤
（ヘアトリートメント剤）
９５％ブルシン変性エタノール
イオン交換水
グリセリン
ＡＭ−３０１（日光ケルカルズ■）
ＣＡ−２４６５（日光ケルカルズ■）
ブロモイス−３２（成和化成）
Ｊａｓｍｉｎ ＢＡＴ−２８６２（高砂香料■）黄色５
号
ヒドロキシエチルセルロース
ｗ／賀％
１０．０
？３．５９９
５．０
３．０
０．３
１．０
０．１
０．００１
１．０
１００．０
実施例６ （化粧水）
イオン交換水９１．８１９重量部に界面活性剤ＮＰ−２
０（実施例１に同じ）０．８重量部とゲル他剤カーボポ
ール９４０ （Ｂ、Ｆ、Ｇｏｏｄｒｉｃｈ Ｃｈｅｍｉ
ｃａｌ Ｃｏａ＋ｐａｎｙ）０．１８重量部とトリエタ
ノールアミン０．２重量部と染料青色１号、０．００１
重量部とを溶解させたものを第１原液とし、後発泡剤イ
ンペンクンを第２原液として、第１原液、９３重量部と
第２原液、７重量部とを２つのシリンダーで１ケのパイ
プラインホモミキサーに送り込み、撹拌し均一に混合し
たゲル組成物を取り出し内袋を持ったエアゾール用耐圧
容器の内袋側に１００重量部充填し、バルブを取りつけ
て後発泡性ゲル組成物の化粧水を作成した。尚、内袋の
外側とエアゾール耐圧容器内で形成する空間にエアゾー
ル耐圧容器底部に設けたガス注入パルプより２５℃で４
、０ ｋｇ ／ ｃ−のゲージ圧をもつ液化石油ガス
（プロパン、イソブタンよりなる）を５重量部充填し、
エアゾール用バルブにスパウトを付けて原液とガス隔離
式の化粧水エアゾール製品を作成した。Example 2 (cleaning agent) Ion-exchanged water surfactant NP-20 % 91.819 0.8 Dye Blue No. 1 triethanolamine post-foaming agent Isobencune Example 3 (hair setting agent) 95% brucine denatured ethanol Ion exchange water glycerin surfactant BC-407X Vinyl co-N combination 0.001 0.2 7.0 1/-% 10.0 ? 3.099 5.0 1.0 Perfume dye post-foaming agent Jasmin BAT-2862 (Takasago perfume m>red 1
No. 02 triethanolamine isopencune n-butane 0°1 0.001 0.4 6.3 0.7 Example 5 (Bactericide) 95% geraniol-denatured ethanol ion exchange water surfactant PBC-44 (Nikko Kelcals) ■) Active ingredient CA-101 (Nikko Kelcals ■) Gelling agent
Hydroxyethyl cellulose post-foaming agent Isobenkune Ka/-% 10.0 82.9 1.0 0.1 1.0 5.0 Example 4 Surfactant active ingredient Fragrance dye Gelling agent (hair treatment agent) 95% brucine modification Ethanol ion exchange water Glycerin AM-301 (Nikko Kelcals ■) CA-2465 (Nikko Kelcals ■) Bromois-32 (Seiwa Kasei) Jasmin BAT-2862 (Takasago Fragrance ■) Yellow 5
No. Hydroxyethylcellulose w/Ka% 10.0? 3.599 5.0 3.0 0.3 1.0 0.1 0.001 1.0 100.0 Example 6 (Lotion) Surfactant NP-2 in 91.819 parts by weight of ion exchange water
0 (same as Example 1) and gel agent Carbopol 940 (B, F, Goodrich Chemi
cal Coa+pany) 0.18 parts by weight, 0.2 parts by weight of triethanolamine, and Dye Blue No. 1, 0.001
Parts by weight were dissolved as the first stock solution, and the post-foaming agent Impengkun was used as the second stock solution. The gel composition was fed into a homomixer, stirred and mixed uniformly, and then 100 parts by weight was filled into the inner bag side of an aerosol pressure-resistant container with an inner bag, and a valve was attached to apply the post-foaming gel composition lotion. Created. In addition, the space formed between the outside of the inner bag and the inside of the aerosol pressure-resistant container is filled with gas injected pulp provided at the bottom of the aerosol pressure-resistant container at 25°C.
, filled with 5 parts by weight of liquefied petroleum gas (consisting of propane and isobutane) with a gauge pressure of 0 kg/c-,
A spout was attached to the aerosol valve to create a lotion aerosol product that separates the undiluted solution from the gas.
〔発明の効果〕
本発明の後発泡性ゲル組成物は、石ケンを使用せず、使
用後に水で洗い流したり濡れタオルで拭き取らなくても
べたつき感のない良好なものであり、また簡単に拭き取
ることができる。また、剪断応力をかけつづけると一度
発泡した泡が簡単に消える性質を有する。したがって、
本発明の後発泡性ゲル組成物は、化粧水とかティッシュ
等で拭きとりたいものに非常に有用である。又リートメ
ント剤のように塗りっばなしのものにおいては、発泡す
るから塗布した個所を知ることができるのみでなく、簡
単に消泡するので外観的にも全く問題がなく、このよう
な用途にも極めて有用である。[Effects of the Invention] The post-foaming gel composition of the present invention does not use soap, does not have a sticky feeling even if it is not washed away with water or wiped with a wet towel after use, and is easily applied. Can be wiped off. In addition, if shear stress is continued, once foamed, the foam easily disappears. therefore,
The post-foaming gel composition of the present invention is very useful for things that need to be wiped off with a lotion, tissue, or the like. In addition, when using a treatment agent that does not require a coating, it not only foams so you can see where it has been applied, but also defoams easily so there is no problem with the appearance, making it suitable for such applications. is also extremely useful.
また、アルコールの添加が容易であり、各種有効成分の
配合、使用感の向上が期待出来るものである。In addition, it is easy to add alcohol, and it can be expected to improve the combination of various active ingredients and the feeling of use.
以下、本発明の効果を具体的に説明するため、本発明の
後発泡性ゲル組成物の分散性、発泡性、消泡性、ゲル状
態及びべたつき感についての試験例を示す。In order to specifically explain the effects of the present invention, test examples will be shown below regarding the dispersibility, foamability, antifoaming properties, gel state, and sticky feeling of the post-foaming gel composition of the present invention.
試験例
（イ）試験方法
（分散性）
透明耐圧容器中の組成物を観察し、後発泡剤の他の成分
への分散性を以下の判、定基準によって評価した。Test Example (a) Test Method (Dispersibility) The composition in a transparent pressure-resistant container was observed, and the dispersibility of the post-foaming agent in other components was evaluated using the following criteria.
（判定基準）
Ｏ：均一に分散しているもの
×：不連続相を認め、均一に分散していないもの
（発泡性）
後発泡性ゲル組成物を常温の状態でガラス板上に約１ｇ
吐出し、３０秒間放置した後、指で直径的５ＣＩｌに塗
り延ばし、発泡状態を以下の判定基準によって評価した
。(Judgment criteria) O: Uniformly dispersed ×: Discontinuous phase observed and not uniformly dispersed (foaming property) Approximately 1 g of the post-foamable gel composition was placed on a glass plate at room temperature.
After discharging and leaving for 30 seconds, it was spread with fingers to a diameter of 5 CIl, and the foaming state was evaluated according to the following criteria.
（判定基準）
Ａ：吐出後から３０秒間は発泡が認められず、塗り延ば
し後に発泡を認めたちの
Ｂ：吐出直後またはそれから３０秒間に発泡を認めたも
の
Ｃ：吐出後から３０秒間に発泡が認められず、塗り延ば
し後にも発泡が認められないもの
（消泡性）
後発泡性ゲル組成物を常温の状態でガラス板上に約１ｇ
吐出し、指で直径５Ｃ１１位に塗り延ばし、発泡した状
態で静置し泡の消える時間を測定し判定基準により評価
した。(Judgment criteria) A: No foaming was observed for 30 seconds after dispensing, but foaming was observed after spreading. B: Foaming was observed immediately after dispensing or 30 seconds thereafter. C: Foaming was observed within 30 seconds after dispensing. Approximately 1 g of the post-foaming gel composition is placed on a glass plate at room temperature.
The product was discharged, spread with a finger to a diameter of about 5C11, allowed to stand in a foamed state, and the time for the foam to disappear was measured and evaluated based on criteria.
（判定基準）
Ａ：発泡させて２時間以内で泡がほぼ消えるもの
Ｂ：発泡させて１２時間以内で泡がほぼ消えるもの
Ｃ：発泡させて１２時間以上泡が消えないもの（ゲル状
態）
常温の状態にて一昼夜、正立状態で放置された透明耐圧
容器中の組成物を容器ごと倒立状態にし、組成物の約８
０％が下方へ移動するまでの時間を計測し、ゲル状態を
以下の判定基準によって評価した。(Judgment criteria) A: Bubbles almost disappear within 2 hours after foaming B: Bubbles almost disappear within 12 hours after foaming C: Bubbles do not disappear for more than 12 hours after foaming (gel state) Room temperature The composition in a transparent pressure-resistant container that had been left in an upright position for a day and a night was turned upside down, and about 8
The time until 0% moved downward was measured, and the gel state was evaluated according to the following criteria.
（判定基準）
Ａ：６０秒以上のもの
Ｂ：３０秒以上６０秒未満のもの
Ｃ：３０秒未満のもの
（べたつき惑）
後発泡性ゲル組成物を手の甲に約０．５ｇ吐出後、指で
直径的３ｃｍに塗り延ばし、約１秒間放置後、ティッシ
ュベーパーで拭き取った後のべたつき感を以下の判定基
準によって評価した。(Judgment criteria) A: 60 seconds or more B: 30 seconds or more but less than 60 seconds C: Less than 30 seconds (sticky) After dispensing about 0.5g of the post-foaming gel composition on the back of the hand, use your fingers to It was spread to a diameter of 3 cm, left for about 1 second, and then wiped off with tissue vapor. The sticky feeling was evaluated according to the following criteria.
（判定基準） Ａ：べたつき感がない Ｂ：ややべたつき惑がある Ｃ：べたつき感がある （口）試験結果 本試験の結果は第１表に示す通りである。(Judgment criteria) A: No sticky feeling B: Slightly sticky C: There is a feeling of stickiness. (mouth) test results The results of this test are shown in Table 1.
第１表
表中の比較例１は下記のように石ケンを含む組成とする
ほかは、実施例１と同様にして調製したひげ剃り剤であ
る。Comparative Example 1 in Table 1 is a shaving agent prepared in the same manner as Example 1, except that the composition contains soap as shown below.
比較例１
（ひげ剃り剤）
９５％ブルシン変性エタノール
イオン交換水
グリセリン
パルミチン酸
スラアリン酸
トリエタノールアミン
ＮＰ−２０（日光ケミカルズ■）
カーポボール９４０
Ｂｏｕｑｕｅｔ ８４５１／ＳＡ（白木香料■）イソペ
ンタン
彎／−％
１０．０
６４．７５
５．０
５．８
２．０
４．２
１．０
０．２
０．０５
７．０
比較例２は、
ものを示す。Comparative example 1 (shaving agent) 95% brucine denatured ethanol ion-exchanged water glycerin palmitic acid suralic acid triethanolamine NP-20 (Nikko Chemicals ■) Carpoball 940 Bouquet 8451/SA (Shiraki Kaori ■) Isopentane curvature/-% 10 .0 64.75 5.0 5.8 2.0 4.2 1.0 0.2 0.05 7.0 Comparative Example 2 shows the following.
比較例３は、 のを示す。Comparative example 3 is It shows.
実施例１から界面活性剤を除いた 実施例１からゲル化剤を除いたもThe surfactant was removed from Example 1. Example 1 with the gelling agent removed
Claims (1)
〜５重量％、水４０〜９８重量％、後発泡剤０．５〜２
０重量％からなる組成物及び／または前記組成物に有効
成分０．１〜１０重量％、アルコール類５〜５０重量％
を加えてなる組成物であって、常温大気圧下少なくとも
３０秒間ゲル状を保ち、かつ、剪断応力を加えた場合発
泡し、さらに剪断応力をかけ続けた場合短時間で消泡す
ることを特徴とする後発泡性ゲル組成物。 ２、ゲル化剤がカルボキシビニルポリマーであり、界面
活性剤がＨＬＢ１０以上の非イオン型であり、後発泡剤
がイソペンタン、ノルマルペンタン、イソブタン、ノル
マルブタン、プロパン及びジメチルエーテルから選ばれ
る１種又は２種以上の混合物であり、アルコール類を含
む場合はアルコール類が１価のアルコールであることを
特徴とする請求項１記載の後発泡性ゲル組成物。 ３、後発泡剤がイソペンタン及びノルマルペンタンから
選ばれる成分８０重量％以上とイソブタン、ノルマルブ
タン、プロパン及びジメチルエーテルから選ばれる成分
２０重量％以下からなることを特徴とする請求項１又は
２記載の後発泡性ゲル組成物。[Claims] 1. Gelling agent 0.01 to 5% by weight, surfactant 0.01
~5% by weight, water 40-98% by weight, post-foaming agent 0.5-2
0% by weight of the composition and/or 0.1 to 10% by weight of the active ingredient and 5 to 50% by weight of the alcohol to the above composition.
The composition is characterized by maintaining a gel-like state for at least 30 seconds at room temperature and atmospheric pressure, foaming when shear stress is applied, and defoaming in a short period of time when shear stress is continued to be applied. A post-foaming gel composition. 2. The gelling agent is a carboxyvinyl polymer, the surfactant is a nonionic type with an HLB of 10 or more, and the post-foaming agent is one or two selected from isopentane, normal pentane, isobutane, normal butane, propane, and dimethyl ether. 2. The post-foaming gel composition according to claim 1, which is a mixture of the above, and when alcohol is contained, the alcohol is a monohydric alcohol. 3. The post blowing agent according to claim 1 or 2, characterized in that the post-foaming agent consists of 80% by weight or more of a component selected from isopentane and normal pentane and 20% by weight or less of a component selected from isobutane, normal butane, propane and dimethyl ether. Foaming gel composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1163661A JP2799362B2 (en) | 1989-06-28 | 1989-06-28 | Post-foamable gel composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1163661A JP2799362B2 (en) | 1989-06-28 | 1989-06-28 | Post-foamable gel composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0331389A true JPH0331389A (en) | 1991-02-12 |
| JP2799362B2 JP2799362B2 (en) | 1998-09-17 |
Family
ID=15778183
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1163661A Expired - Lifetime JP2799362B2 (en) | 1989-06-28 | 1989-06-28 | Post-foamable gel composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2799362B2 (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0725725A (en) * | 1993-07-09 | 1995-01-27 | Koike Kagaku Kk | Expanding aerosol product for human body |
| JP2002037362A (en) * | 2000-07-28 | 2002-02-06 | Daizo:Kk | Pressurized product |
| JP2002255741A (en) * | 2001-03-05 | 2002-09-11 | Pola Chem Ind Inc | Gel-like aerosol cosmetic |
| JP2004509833A (en) * | 1999-09-03 | 2004-04-02 | サラ リー／デーエーエヌ ファウ | Cosmetic composition |
| JP2006182664A (en) * | 2004-12-27 | 2006-07-13 | Koike Kagaku Kk | Post-foaming gel form hair dressing |
| JP2006298772A (en) * | 2005-04-15 | 2006-11-02 | Koike Kagaku Kk | Post-foamable cosmetic |
| US7837984B2 (en) | 2002-12-27 | 2010-11-23 | Avon Products, Inc. | Post-foaming cosmetic composition and method employing same |
| US8668916B2 (en) | 2010-09-24 | 2014-03-11 | Conopco, Inc. | HIPE-gelation process for making highly concentrated, spherical biopolymer gel particle suspensions |
| JP2019501905A (en) * | 2015-12-21 | 2019-01-24 | ザ プロクター アンド ギャンブル カンパニー | Package for dispensing foamed composition |
| JP2019210302A (en) * | 2018-05-31 | 2019-12-12 | エステー株式会社 | Aerosol composition and aerosol product using the same |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01153624A (en) * | 1987-12-01 | 1989-06-15 | Colgate Palmolive Co | Post-foamable gel shower product |
-
1989
- 1989-06-28 JP JP1163661A patent/JP2799362B2/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01153624A (en) * | 1987-12-01 | 1989-06-15 | Colgate Palmolive Co | Post-foamable gel shower product |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0725725A (en) * | 1993-07-09 | 1995-01-27 | Koike Kagaku Kk | Expanding aerosol product for human body |
| JP2004509833A (en) * | 1999-09-03 | 2004-04-02 | サラ リー／デーエーエヌ ファウ | Cosmetic composition |
| JP2002037362A (en) * | 2000-07-28 | 2002-02-06 | Daizo:Kk | Pressurized product |
| JP2002255741A (en) * | 2001-03-05 | 2002-09-11 | Pola Chem Ind Inc | Gel-like aerosol cosmetic |
| US7837984B2 (en) | 2002-12-27 | 2010-11-23 | Avon Products, Inc. | Post-foaming cosmetic composition and method employing same |
| US7837985B2 (en) | 2002-12-27 | 2010-11-23 | Avon Products, Inc | Post application expanding cosmetic composition and method employing same |
| US7846424B2 (en) | 2002-12-27 | 2010-12-07 | Avon Products, Inc | Non-pressurized post-application expanding composition |
| JP2006182664A (en) * | 2004-12-27 | 2006-07-13 | Koike Kagaku Kk | Post-foaming gel form hair dressing |
| JP2006298772A (en) * | 2005-04-15 | 2006-11-02 | Koike Kagaku Kk | Post-foamable cosmetic |
| US8668916B2 (en) | 2010-09-24 | 2014-03-11 | Conopco, Inc. | HIPE-gelation process for making highly concentrated, spherical biopolymer gel particle suspensions |
| JP2019501905A (en) * | 2015-12-21 | 2019-01-24 | ザ プロクター アンド ギャンブル カンパニー | Package for dispensing foamed composition |
| JP2019210302A (en) * | 2018-05-31 | 2019-12-12 | エステー株式会社 | Aerosol composition and aerosol product using the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2799362B2 (en) | 1998-09-17 |
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