JPH0324196A - Composite resin sliding member - Google Patents
Composite resin sliding memberInfo
- Publication number
- JPH0324196A JPH0324196A JP1157548A JP15754889A JPH0324196A JP H0324196 A JPH0324196 A JP H0324196A JP 1157548 A JP1157548 A JP 1157548A JP 15754889 A JP15754889 A JP 15754889A JP H0324196 A JPH0324196 A JP H0324196A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- tetrafluoroethylene
- sliding member
- group
- volume
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000805 composite resin Substances 0.000 title claims description 7
- 229920005989 resin Polymers 0.000 claims abstract description 43
- 239000011347 resin Substances 0.000 claims abstract description 43
- 239000000203 mixture Substances 0.000 claims abstract description 15
- -1 perfluoroalkyl vinyl ether Chemical compound 0.000 claims abstract description 11
- 229920006026 co-polymeric resin Polymers 0.000 claims abstract description 10
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 8
- 239000004734 Polyphenylene sulfide Substances 0.000 claims abstract description 6
- 239000000945 filler Substances 0.000 claims abstract description 6
- 239000000314 lubricant Substances 0.000 claims abstract description 6
- 229920000069 polyphenylene sulfide Polymers 0.000 claims abstract description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 5
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 5
- 229920000728 polyester Polymers 0.000 claims abstract description 5
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract description 5
- 239000002657 fibrous material Substances 0.000 claims abstract description 4
- 239000000919 ceramic Substances 0.000 claims abstract description 3
- 229910052751 metal Inorganic materials 0.000 claims abstract description 3
- 239000002184 metal Substances 0.000 claims abstract description 3
- 229910052976 metal sulfide Inorganic materials 0.000 claims abstract description 3
- 239000007787 solid Substances 0.000 claims abstract description 3
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims abstract 3
- 230000002093 peripheral effect Effects 0.000 claims description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- 229910001512 metal fluoride Inorganic materials 0.000 claims description 2
- 238000005299 abrasion Methods 0.000 abstract 1
- 150000002222 fluorine compounds Chemical class 0.000 abstract 1
- 235000012054 meals Nutrition 0.000 abstract 1
- 238000000465 moulding Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 31
- 229920006324 polyoxymethylene Polymers 0.000 description 5
- 229930182556 Polyacetal Natural products 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 238000001994 activation Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- PEVRKKOYEFPFMN-UHFFFAOYSA-N 1,1,2,3,3,3-hexafluoroprop-1-ene;1,1,2,2-tetrafluoroethene Chemical group FC(F)=C(F)F.FC(F)=C(F)C(F)(F)F PEVRKKOYEFPFMN-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Landscapes
- Sliding-Contact Bearings (AREA)
- Laminated Bodies (AREA)
- Lubricants (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、自動車、電気機械、ＯＡ８！器、産業機械、
工作機械、一般産業機械等の摺動部材に好適な低摩擦性
、耐摩耗性、および強度にすぐれた複合樹脂摺動部材に
関する。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention is applicable to automobiles, electric machines, OA8! equipment, industrial machinery,
The present invention relates to a composite resin sliding member that has excellent low friction, wear resistance, and strength and is suitable for sliding members of machine tools, general industrial machinery, etc.
（従来の技術）
従来の技術としては、本出願の出願人の出願に係る発明
（特開昭６１ − ２６６４５１号公報）（以下、従来
技術１という）がある。(Prior Art) As a conventional technology, there is an invention (Japanese Unexamined Patent Publication No. 1983-266451) filed by the applicant of the present application (hereinafter referred to as "Prior Art 1").
従来技術１は摺動部材組成物に関するものであり、この
摺動部材組成物は、本願特許請求の範囲第１項（イ）ま
たは（ロ）の組成物（以下、ＤＦＡ（登録商標）という
）に相当する。このＤＦＡを単体樹脂摺動部材として使
用する場合、摩擦摩耗特性には優れているが、強度に劣
るなどの問題点があった。Prior art 1 relates to a sliding member composition, and this sliding member composition is a composition according to claim 1 (a) or (b) of the present application (hereinafter referred to as DFA (registered trademark)). corresponds to When this DFA is used as a single resin sliding member, it has excellent friction and wear characteristics, but has problems such as poor strength.
（問題を解決するための手段）
この発明は、前記従来の技術の問題点を解決した低摩擦
性、耐摩耗性及び強度をあわせもつ複合樹脂摺動部材を
提供することを目的とする。この目的を達成させるため
に、本願は次の（１）及び（２）の構造としている。す
なわち
（１）下記（イ）または（口）の摺動部材用組成物を内
周層とし、熱可塑性樹脂または充填材含有熱可塑性樹脂
を外周層とした構成の複合樹脂摺動部材。(Means for Solving the Problems) An object of the present invention is to provide a composite resin sliding member having low friction, wear resistance, and strength, which solves the problems of the conventional techniques. In order to achieve this objective, this application has the following structures (1) and (2). That is, (1) a composite resin sliding member having a structure in which the composition for a sliding member according to (a) or (x) below is used as an inner peripheral layer, and a thermoplastic resin or a filler-containing thermoplastic resin is used as an outer peripheral layer.
（イ）テトラフルオロエチレンーパーフ口オロアルキル
ビニルエーテル共重合樹脂、テトラフルオロエチレンー
へキサフルオロプロピレン共重合樹脂及びフルオロエチ
レンプロピレンエーテル樹脂よりなるＡ群から選ばれた
少なくとも１種の樹脂の０．１〜５０容量％、オキシベ
ンゾイルポリエステル、ボリフエニレンサルファイド及
び熱硬化性樹脂よりなるＢ群から選ばれた少なくとも１
種の樹脂の０．１〜５０容量％並びに残部が実質的にテ
トラフルオ口エチレン樹脂からなりこのテ１・ラフルオ
ロエチレン樹脂以外の各成分の合計が０．３〜７０容量
％である摺動部材用組成物。(a) 0.1 of at least one resin selected from Group A consisting of tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer resin, tetrafluoroethylene-hexafluoropropylene copolymer resin, and fluoroethylene propylene ether resin ~50% by volume, at least one selected from Group B consisting of oxybenzoyl polyester, polyphenylene sulfide, and thermosetting resin
A sliding member in which the seed resin is 0.1 to 50% by volume, and the remainder is substantially tetrafluoroethylene resin, and the total of each component other than the tetrafluoroethylene resin is 0.3 to 70% by volume. Composition for use.
（ロ）テトラフルオロエチレン−パーフロオロアルキル
ビニルエーテル共重合樹脂、テトラフルオロエチレンー
へキサフルオロブロビレン共重合樹脂及びフルオロエチ
レンプロピレンエーテル樹脂よりなるＡ群から選ばれた
少なくとも１種の樹脂の０．１〜５０容量％、オキシベ
ンゾイルポリエステル、ボリフエニレンサルファイド及
び熱硬化性樹脂よりなるＢ群から選ばれた少なくとも１
種の樹脂の０．１〜５０容量％、金属潤滑剤、金属酸化
物、複合金属酸化物、金属硫化物、金属弗化物、炭素系
固体潤滑剤、繊維材料及びセラミックスからなるＣ群の
少なくとも１種の０．１〜５０容量％、並びに残部が実
質的にテトラフルオ口エチレン４ｔｔ脂からなるテトラ
フルオロエチレン樹脂以外の各成分の合計が０．３〜７
０容量％である摺動部材用組成物。(b) 0.1 of at least one resin selected from Group A consisting of tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer resin, tetrafluoroethylene-hexafluorobrobylene copolymer resin, and fluoroethylene propylene ether resin ~50% by volume, at least one selected from Group B consisting of oxybenzoyl polyester, polyphenylene sulfide, and thermosetting resin
0.1 to 50% by volume of the seed resin, at least one member of Group C consisting of metal lubricants, metal oxides, composite metal oxides, metal sulfides, metal fluorides, carbon-based solid lubricants, fiber materials, and ceramics. The total amount of each component other than the tetrafluoroethylene resin is 0.1 to 50% by volume of seeds, and the remainder is essentially 4tt tetrafluoroethylene resin, which is 0.3 to 7% by volume.
A composition for a sliding member having a content of 0% by volume.
（２）前記内周層と外周層の両樹脂間の境界層が凹凸形
状である上記（１）記載の複合樹脂摺動部材。(2) The composite resin sliding member according to (1) above, wherein the boundary layer between the resins of the inner peripheral layer and the outer peripheral layer has an uneven shape.
本発明の熱可塑性樹脂とは単体あるいは充填材含有ＡＢ
Ｓ樹脂、ボリブロピレン樹脂、ポリアセタール樹脂、ポ
リカーボネート樹脂、ポリエチレンフタレート樹脂、ポ
リブチレンフタレート樹脂、芳香族ポリエステル樹脂、
ボリアミド樹脂、ポリフェニレンサルファイド樹脂、ボ
リスルフオン系樹脂、ポリエーテル系樹脂等である。The thermoplastic resin of the present invention is AB alone or containing a filler.
S resin, polypropylene resin, polyacetal resin, polycarbonate resin, polyethylene phthalate resin, polybutylene phthalate resin, aromatic polyester resin,
These include polyamide resin, polyphenylene sulfide resin, borisulfon resin, polyether resin, and the like.
充填材は、ガラス繊維やカーボン繊維等の繊維材料、炭
酸カルシウムやガラスビーズなどの無機充填材、着色剤
等をいう。Fillers include fiber materials such as glass fibers and carbon fibers, inorganic fillers such as calcium carbonate and glass beads, colorants, and the like.
本発明で使用される内周層用摺動部材の形態としては、
フイルム、シート、チューブまたはパイプその他の任意
の形態のもので、戒形品の所要の表面を被覆可能にされ
たものを使用することができる。（そして、内周層用摺
動部材は、戒形品の形状に合わせて或形されたものでも
、通常のフイルムやシートの形態のままで使用すること
も可能である。）
（実施例）
第１実施例（本発明品）
内径１０ｍｍ肉厚１ｍｍ長さ１０ｍｍに予め機械加工等
で戒形加工され外周層と接する側に活性化処理された従
来技術ｌにかかる摺動部材（ＤＦＡ（登録商標））の内
周層用円筒部材を射出戒形用金型内のコアピンに装着す
る。The form of the inner peripheral layer sliding member used in the present invention is as follows:
Any other form of film, sheet, tube, pipe, etc. that can cover the required surface of the precept article can be used. (The sliding member for the inner peripheral layer may be shaped to match the shape of the pre-shaped article, or it may be used as it is in the form of a normal film or sheet.) (Example) First Example (Product of the Present Invention) A sliding member (DFA (registered)) according to the prior art l, which was pre-shaped by machining etc. to an inner diameter of 10 mm, wall thickness of 1 mm, and length of 10 mm, and activated on the side in contact with the outer peripheral layer. The cylindrical member for the inner circumferential layer (Trademark) is attached to the core pin in the injection mold.
次に１８５〜２２０°Ｃに溶融したポリアセタール（Ｐ
ＯＭ）を圧力８００ ｋｇ ／ ｃｍ２で、金型温度８
０°Ｃの条件で射出或形し、内周に摺動部材用組成物の
層を有し、外周には、ＰＯＭの層を有する外径１５ｍｍ
内径１０ｍｍ長さ１．０ｍｍの円筒状の戒形品を得た。Next, polyacetal (P
OM) at a pressure of 800 kg/cm2 and a mold temperature of 8
Injected or shaped at 0°C, with a layer of sliding member composition on the inner periphery and a POM layer on the outer periphery, with an outer diameter of 15 mm.
A cylindrical article with an inner diameter of 10 mm and a length of 1.0 mm was obtained.
この戒形品内周層の摩擦摩耗特性及び強度は表１に示し
、試験条件は表２に示す。The friction and wear characteristics and strength of the inner circumferential layer of this pre-shaped article are shown in Table 1, and the test conditions are shown in Table 2.
第２実施例（本発明品）
第１実施例において内周層用円筒部材の外周用層と接す
る側に、活性化処理をする前に（活性化処理をした後で
もよい）結合強度を増加させる目的で、深さ０．３ ｍ
ｍ幅０．２ｍｍの凹型溝を２本形威した。Second Example (product of the present invention) In the first example, the bonding strength is increased before (or after the activation process) is applied to the side of the inner layer cylindrical member in contact with the outer layer. 0.3 m deep for the purpose of
Two concave grooves with a width of 0.2 mm were formed.
その後は第１実施例と同じ方法で威形品を得た。After that, a prestigious product was obtained in the same manner as in the first example.
この戒形品内周層の摩擦摩耗特性及び強度は表１に示し
、試験条件は表２に示す。The friction and wear characteristics and strength of the inner circumferential layer of this pre-shaped article are shown in Table 1, and the test conditions are shown in Table 2.
第３実施例（本発明品）
内径１０ｍｍ肉厚１ｍｍ長さ１０ｍｍに予め機械加工等
で或形加工され外周層と接する側に活性化処理された従
来技術１にかかる摺動部材（ＤＦＡ（登録商標））の内
周層用円筒部材を射出戒形用金型内のコアビンに装着す
る。Third Example (Product of the Present Invention) A sliding member (DFA (registered)) according to Prior Art 1 was pre-processed into a certain shape by machining or the like to have an inner diameter of 10 mm, a wall thickness of 1 mm, and a length of 10 mm, and the side in contact with the outer peripheral layer was activated. The cylindrical member for the inner circumferential layer (Trademark) is attached to the core bin in the injection mold.
次に２３０〜２４５６Ｃに溶融したグラスファイバー２
５％含有ポリブチレンフタレート樹脂（ＰＢＴ）を圧力
６００ ｋｇ ／ ｃｍ２で、金型温度７０°Ｃの条件
で射出戒形し、内周に摺動部材用組成物の層を有し、外
周には、ＰＢＴの層を有する外径１５ｍｍ内径１０ｍｍ
長さ１０ｍｍの円筒状の戒形品を得た。Next, glass fiber 2 fused to 230-2456C
Polybutylene phthalate resin (PBT) containing 5% is injected at a pressure of 600 kg/cm2 and a mold temperature of 70°C, with a layer of a composition for sliding parts on the inner periphery and a layer on the outer periphery. , outer diameter 15mm inner diameter 10mm with a layer of PBT
A cylindrical article with a length of 10 mm was obtained.
この戒形品内周層の摩擦摩耗特性及び強度は表１に示し
、試験条件は表２に示す。The friction and wear characteristics and strength of the inner circumferential layer of this pre-shaped article are shown in Table 1, and the test conditions are shown in Table 2.
第４実施例（本発明品）
第３実施例において内周層用円筒部材の外周用層と接す
る側に、活性化処理をする前に（活性化処理をした後で
もよい）結合強度を増加させる目的で、深さ０．３ ｍ
ｍ ｌｌｉ ０．２ ｍｍの凹型溝を２本形威した。Fourth Example (product of the present invention) In the third example, the bonding strength is increased before (or after the activation process) is applied to the side of the cylindrical member for the inner peripheral layer that is in contact with the outer peripheral layer. 0.3 m deep for the purpose of
Two concave grooves with a diameter of 0.2 mm were formed.
その後は第３実施例と同じ方法で戒形品を得た。Thereafter, a precept was obtained in the same manner as in the third example.
この或形品内周層の摩擦摩耗特性及び強度は表１に示し
、試験条件は表２に示す。The friction and wear characteristics and strength of the inner circumferential layer of this certain shaped article are shown in Table 1, and the test conditions are shown in Table 2.
第５実施例（比較品）
内径１０ｍｍ肉厚１ｍｍ長さ１０ｍｍに予め機械加工等
で或形加工され外周層と接する側に活性化処理された１
５％グラファイト含有ポリテトラフルオロエチレンの内
周層用円筒部材を射出戊形用金型内のコアビンに装着す
る。5th Example (comparative product) 1 which was previously machined into a certain shape with an inner diameter of 10 mm, a wall thickness of 1 mm, and a length of 10 mm, and activated on the side in contact with the outer peripheral layer.
A cylindrical member for the inner peripheral layer of polytetrafluoroethylene containing 5% graphite is attached to a core bin in an injection mold.
次に１８５〜２２０°Ｃに溶融したポリアセタール（Ｐ
ＯＭ）を圧力８００ ｋｇ ／ ａｍ２で、金型温度８
０ ’Ｃの条件で射出或形し、内周に摺動部材用組成物
の層を有し、外周には、ＰＯＭの層を有する外径１５ｍ
ｍ内径１０ｍｍ長さ１０ｍｍの円筒状の成形品を得た。Next, polyacetal (P
OM) at a pressure of 800 kg/am2 and a mold temperature of 8
Injected or shaped at 0'C, with a layer of sliding member composition on the inner periphery and a layer of POM on the outer periphery, with an outer diameter of 15 m.
A cylindrical molded product with an inner diameter of 10 mm and a length of 10 mm was obtained.
この成形品内周層の摩擦摩耗特性及び強度は表１に示し
、試験条件は表２に示す。The friction and wear characteristics and strength of the inner peripheral layer of this molded article are shown in Table 1, and the test conditions are shown in Table 2.
第６実施例（比較品）
従来技術１にかかる摺動部材（商標ＤＦＡ）用粉末を金
型に充填し、戒形圧力５００ ｋｇ ／ ａｍ２で圧粉
或形した後、３４０ 〜３７０°Ｃで焼威し外径２０ｍ
ｍ高さ５０ｍｍの丸棒を得た。その丸棒を機械加工にて
外径１５ｍｍ内径１０ｍｍ長さ１０ｍｍの円筒状或形品
を得た。Sixth Example (comparative product) The powder for sliding members (trademark DFA) according to Prior Art 1 was filled into a mold, compacted at a pressure of 500 kg/am2, and then heated at 340 to 370°C. Burning outer diameter 20m
A round bar with a height of 50 mm was obtained. The round bar was machined to obtain a cylindrical product with an outer diameter of 15 mm, an inner diameter of 10 mm, and a length of 10 mm.
この戒形品の摩擦摩耗特性は表１に示し、試験条件は表
２に示す。The friction and wear characteristics of this shaped article are shown in Table 1, and the test conditions are shown in Table 2.
表１ 表２ （発明の効果） 本発明品は、以下のようなすぐれた効果を奏する。Table 1 Table 2 (Effect of the invention) The product of the present invention has the following excellent effects.
（Ａ） 従来技術ｌとして説明した低摩擦性、耐摩耗
性を有する単体樹脂摺動部材を内周層とし、新たに熱可
塑性樹脂外周層を設けたことから、強度を向上させるこ
とができる。(A) Since the single resin sliding member having low friction and wear resistance described as Prior Art 1 is used as the inner peripheral layer, and a new thermoplastic resin outer peripheral layer is provided, the strength can be improved.
（Ｂ） 本発明品は、両樹脂間に凹凸形状を備えたこ
とにより、実質上、表面層の面積が増えたことから、ア
ンカー効果により、さらに強固な結合（接着）強度が得
られている。(B) The product of the present invention has an uneven shape between both resins, which substantially increases the area of the surface layer, resulting in stronger bonding (adhesion) strength due to the anchor effect. .
Claims (2)
周層とし、熱可塑性樹脂または充填材含有熱可塑性樹脂
を外周層とした構成の複合樹脂摺動部材。 （イ）テトラフルオロエチレン−パーフロオロアルキル
ビニルエーテル共重合樹脂、テトラフルオロエチレン−
ヘキサフルオロプロピレン共重合樹脂及びフルオロエチ
レンプロピレンエーテル樹脂よりなるＡ群から選ばれた
少なくとも１種の樹脂の０．１〜５０容量％、オキシベ
ンゾイルポリエステル、ポリフェニレンサルファイド及
び熱硬化性樹脂よりなるＢ群から選ばれた少なくとも１
種の樹脂の０．１〜５０容量％並びに残部が実質的にテ
トラフルオロエチレン樹脂からなりこのテトラフルオロ
エチレン樹脂以外の各成分の合計が０．３〜７０容量％
である摺動部材用組成物。 （ロ）テトラフルオロエチレン−パーフロオロアルキル
ビニルエーテル共重合樹脂、テトラフルオロエチレン−
ヘキサフルオロプロピレン共重合樹脂及びフルオロエチ
レンプロピレンエーテル樹脂よりなるＡ群から選ばれた
少なくとも１種の樹脂の０．１〜５０容量％、オキシベ
ンゾイルポリエステル、ポリフェニレンサルファイド及
び熱硬化性樹脂よりなるＢ群から選ばれた少なくとも１
種の樹脂の０．１〜５０容量％、金属潤滑剤、金属酸化
物、複合金属酸化物、金属硫化物、金属弗化物、炭素系
固体潤滑剤、繊維材料及びセラミックスからなるＣ群の
少なくとも１種の０．１〜５０容量％、並びに残部が実
質的にテトラフルオロエチレン樹脂からなるテトラフル
オロエチレン樹脂以外の各成分の合計が０．３〜７０容
量％である摺動部材用組成物。(1) A composite resin sliding member having an inner peripheral layer made of the sliding member composition of (a) or (b) below and an outer peripheral layer made of a thermoplastic resin or a filler-containing thermoplastic resin. (a) Tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer resin, tetrafluoroethylene-
0.1 to 50% by volume of at least one resin selected from Group A consisting of hexafluoropropylene copolymer resin and fluoroethylene propylene ether resin; Group B consisting of oxybenzoyl polyester, polyphenylene sulfide, and thermosetting resin; At least one selected
0.1 to 50% by volume of the seed resin, and the remainder substantially consists of tetrafluoroethylene resin, and the total of each component other than this tetrafluoroethylene resin is 0.3 to 70% by volume.
A composition for a sliding member. (b) Tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer resin, tetrafluoroethylene-
0.1 to 50% by volume of at least one resin selected from Group A consisting of hexafluoropropylene copolymer resin and fluoroethylene propylene ether resin; Group B consisting of oxybenzoyl polyester, polyphenylene sulfide, and thermosetting resin; At least one selected
0.1 to 50% by volume of the seed resin, at least one member of Group C consisting of metal lubricants, metal oxides, composite metal oxides, metal sulfides, metal fluorides, carbon-based solid lubricants, fiber materials, and ceramics. A composition for a sliding member, wherein the total amount of each component other than the tetrafluoroethylene resin is 0.1 to 50% by volume, and the remainder is substantially tetrafluoroethylene resin, from 0.3 to 70% by volume.
形状である特許請求の範囲第１項記載の複合樹脂摺動部
材。(2) The composite resin sliding member according to claim 1, wherein the boundary layer between the resins of the inner peripheral layer and the outer peripheral layer has an uneven shape.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1157548A JPH0324196A (en) | 1989-06-20 | 1989-06-20 | Composite resin sliding member |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1157548A JPH0324196A (en) | 1989-06-20 | 1989-06-20 | Composite resin sliding member |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0324196A true JPH0324196A (en) | 1991-02-01 |
Family
ID=15652089
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1157548A Pending JPH0324196A (en) | 1989-06-20 | 1989-06-20 | Composite resin sliding member |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0324196A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998050229A1 (en) * | 1997-05-01 | 1998-11-12 | Daikin Industries, Ltd. | Adhesive composite material for office automation machines |
| KR20180117547A (en) * | 2017-04-19 | 2018-10-29 | 세이코 인스트루 가부시키가이샤 | Sliding bearing having a coating layer and drive module |
| JP2018179286A (en) * | 2017-04-19 | 2018-11-15 | セイコーインスツル株式会社 | Sliding bearing with coating layer and drive module |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5397075A (en) * | 1977-02-07 | 1978-08-24 | Taiho Kogyo Co Ltd | Sliding friction material |
| JPS61266451A (en) * | 1985-05-21 | 1986-11-26 | Daido Metal Kogyo Kk | Composition for sliding member |
-
1989
- 1989-06-20 JP JP1157548A patent/JPH0324196A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5397075A (en) * | 1977-02-07 | 1978-08-24 | Taiho Kogyo Co Ltd | Sliding friction material |
| JPS61266451A (en) * | 1985-05-21 | 1986-11-26 | Daido Metal Kogyo Kk | Composition for sliding member |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998050229A1 (en) * | 1997-05-01 | 1998-11-12 | Daikin Industries, Ltd. | Adhesive composite material for office automation machines |
| US6500537B1 (en) | 1997-05-01 | 2002-12-31 | Daikin Industries, Ltd. | Non-sticking composite materials for office automation equipment |
| KR20180117547A (en) * | 2017-04-19 | 2018-10-29 | 세이코 인스트루 가부시키가이샤 | Sliding bearing having a coating layer and drive module |
| JP2018179286A (en) * | 2017-04-19 | 2018-11-15 | セイコーインスツル株式会社 | Sliding bearing with coating layer and drive module |
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