JPH03234877A - Mothproof textile and its production - Google Patents
Mothproof textile and its productionInfo
- Publication number
- JPH03234877A JPH03234877A JP14810890A JP14810890A JPH03234877A JP H03234877 A JPH03234877 A JP H03234877A JP 14810890 A JP14810890 A JP 14810890A JP 14810890 A JP14810890 A JP 14810890A JP H03234877 A JPH03234877 A JP H03234877A
- Authority
- JP
- Japan
- Prior art keywords
- insect repellent
- textile
- weight
- moth
- fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 239000004753 textile Substances 0.000 title abstract description 7
- 239000000839 emulsion Substances 0.000 claims abstract description 32
- 229920005989 resin Polymers 0.000 claims abstract description 24
- 239000011347 resin Substances 0.000 claims abstract description 24
- 238000009835 boiling Methods 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 239000003960 organic solvent Substances 0.000 claims abstract description 5
- 239000000077 insect repellent Substances 0.000 claims description 47
- 239000000835 fiber Substances 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 11
- 230000000694 effects Effects 0.000 abstract description 18
- -1 isobornyl thiocyanoacetic acid Chemical compound 0.000 abstract description 12
- 238000005406 washing Methods 0.000 abstract description 10
- 238000005108 dry cleaning Methods 0.000 abstract description 9
- 238000000576 coating method Methods 0.000 abstract description 8
- 239000011248 coating agent Substances 0.000 abstract description 6
- 239000004088 foaming agent Substances 0.000 abstract description 6
- 238000010438 heat treatment Methods 0.000 abstract description 6
- 238000001035 drying Methods 0.000 abstract description 2
- 239000004745 nonwoven fabric Substances 0.000 abstract description 2
- 239000002759 woven fabric Substances 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 239000004744 fabric Substances 0.000 description 43
- 229920001296 polysiloxane Polymers 0.000 description 20
- 229920002545 silicone oil Polymers 0.000 description 16
- 239000007787 solid Substances 0.000 description 13
- 239000003350 kerosene Substances 0.000 description 10
- 239000002562 thickening agent Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000006260 foam Substances 0.000 description 9
- 229920000742 Cotton Polymers 0.000 description 8
- 239000003995 emulsifying agent Substances 0.000 description 8
- 238000005187 foaming Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 230000035699 permeability Effects 0.000 description 7
- 239000003638 chemical reducing agent Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000000859 sublimation Methods 0.000 description 6
- 230000008022 sublimation Effects 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 239000012948 isocyanate Substances 0.000 description 5
- 150000002513 isocyanates Chemical class 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 3
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 3
- 241000238631 Hexapoda Species 0.000 description 3
- MMOXZBCLCQITDF-UHFFFAOYSA-N N,N-diethyl-m-toluamide Chemical compound CCN(CC)C(=O)C1=CC=CC(C)=C1 MMOXZBCLCQITDF-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 210000003746 feather Anatomy 0.000 description 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229940073665 octyldodecyl myristate Drugs 0.000 description 3
- 229960005235 piperonyl butoxide Drugs 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- WYAUHKUSKIIGEI-UHFFFAOYSA-N 2-thiocyanatoacetic acid Chemical compound OC(=O)CSC#N WYAUHKUSKIIGEI-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- ZDZSLKDRFBVUID-UHFFFAOYSA-M 1,2-dioctadecylpyridin-1-ium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCC1=CC=CC=[N+]1CCCCCCCCCCCCCCCCCC ZDZSLKDRFBVUID-UHFFFAOYSA-M 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 description 1
- VGUWZCUCNQXGBU-UHFFFAOYSA-N 3-[(4-methylpiperazin-1-yl)methyl]-5-nitro-1h-indole Chemical compound C1CN(C)CCN1CC1=CNC2=CC=C([N+]([O-])=O)C=C12 VGUWZCUCNQXGBU-UHFFFAOYSA-N 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 241000238713 Dermatophagoides farinae Species 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- WTEICVOERQQONI-UHFFFAOYSA-N [C].C1CO1 Chemical class [C].C1CO1 WTEICVOERQQONI-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000012874 anionic emulsifier Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000009990 desizing Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229960001673 diethyltoluamide Drugs 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000000384 rearing effect Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、防虫効果を有する繊維構造物に関するもので
ある。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a fiber structure having an insect repellent effect.
（従来の技術）
従来繊維の防虫加工は、天然又は合成繊維に防虫剤を塗
布、又はスプレーしたり、化合物溶液に繊維を含浸せし
める方法が知られている（特開昭６ｍ−２５９０３号公
報等）。また、特開昭６１２８４、２１０号公報には、
防虫剤を含有した合成樹脂をシート状に成形したカーテ
ンが、特開昭５９−２７８０１号公報には、ゴムに防虫
剤を添加してこれをカーペットの裏面に塗布することが
記載されている。(Prior Art) Conventional methods of insect repellent processing of fibers include coating or spraying insect repellents on natural or synthetic fibers, or impregnating the fibers with a compound solution (Japanese Patent Laid-Open No. 6M-25903, etc.). ). In addition, in Japanese Patent Application Laid-Open No. 61284/210,
Japanese Patent Laid-Open No. 59-27801 describes a curtain made of a synthetic resin containing an insect repellent formed into a sheet shape, in which the insect repellent is added to rubber and applied to the back side of the carpet.
（発明が解決しようとする課題） しかしながら、防虫剤を単に塗布、スプレー。(Problem to be solved by the invention) However, simply apply or spray insect repellent.
含浸したものではその効力に持続性がなくその後、洗濯
等によって容易に付着せしめた防虫剤が脱落してしまう
という欠点を有している。また、防虫物質は一般に高温
に弱く、前記従来技術の如く、通常の樹脂を用いた固着
では防虫効果が失なわれたり、有効成分が蒸散したりす
る。このため、防虫効果とその洗濯耐久性とを兼備えた
繊維構造物は、未だ完成していないのが現状である。Impregnated insect repellents have the disadvantage that their effectiveness is not sustainable and that the attached insect repellent easily falls off after washing or the like. In addition, insect repellent substances are generally sensitive to high temperatures, and when fixed using ordinary resins as in the prior art described above, the insect repellent effect is lost or the effective ingredients evaporate. For this reason, at present, a fiber structure that has both an insect repellent effect and washing durability has not yet been completed.
本発明の目的は、洗濯耐久性があり、かつ優れた防虫効
果を有する繊維構造物を供給することにある。An object of the present invention is to provide a fiber structure that is durable against washing and has an excellent insect repellent effect.
（課題を解決するための手段）
本発明は
（１１昇華性防虫剤を含有した有孔樹脂皮膜を表面に有
する防虫繊維構造物。(Means for Solving the Problems) The present invention provides (11) an insect repellent fiber structure having on its surface a perforated resin film containing a sublimable insect repellent.
（２） 沸点２００℃以上の昇華性防虫剤、低温反応
性樹脂、及び有機溶媒のエマルジョンを含有する処理液
を繊維構造物に施与した後、１５０℃以下の温度で熱処
理することを特徴とする防虫繊維構造物の製造方法。(2) A treatment liquid containing an emulsion of a sublimable insect repellent with a boiling point of 200°C or higher, a low-temperature reactive resin, and an organic solvent is applied to the fiber structure, and then heat-treated at a temperature of 150°C or lower. A method for manufacturing an insect-repellent fiber structure.
である。It is.
本発明に云う昇華性防虫剤とは、常温での昇華圧が大き
いもので、その気体により顕著な防虫効果を示すもので
ある。かかる昇華性防虫剤としては、ナフタリン、カン
ファー（樟脳）、ｐ−ジクロロベンゼン、Ｎ、Ｎ−ジエ
チル−ｍ−）ルアミドイソボルニル・チオシアノ酢酸、
１．２ベンゼンジカルボン酸ジエチルエステル等が挙げ
られるが、害虫忌避剤として効果、芳香の種類、更に後
に述べる製造法との関係からＮ、Ｎ−ジエチル−ｍトル
アミド及び／又はイソボルニル・チオシアノ酢酸が好ま
しく、特に両者を略々同量混合したものや、防虫物質１
００ｇ中に、１，２ベンゼンジカルボン酸ジエチルエス
テルを８１ｇ、 ピベロニルブトキサイドを５ｇ、
ミリスチン酸オクチルドデシルを５ｇおよび乳化剤を
９ｇ含むものが特に防虫効果が高く好ましい。The sublimation insect repellent referred to in the present invention is one that has a large sublimation pressure at room temperature and exhibits a remarkable insect repellent effect due to its gas. Such sublimation insect repellents include naphthalene, camphor, p-dichlorobenzene, N,N-diethyl-m-)ylamidoisobornyl thiocyanoacetic acid,
1.2 benzene dicarboxylic acid diethyl ester, etc., but N,N-diethyl-m-toluamide and/or isobornyl thiocyanoacetic acid are preferred from the viewpoint of effectiveness as a pest repellent, type of aroma, and relationship with the manufacturing method described later. , especially mixtures of both in approximately equal amounts, and insect repellent substances 1
In 00g, 81g of 1,2 benzenedicarboxylic acid diethyl ester, 5g of piveronyl butoxide,
One containing 5 g of octyldodecyl myristate and 9 g of an emulsifier is particularly preferred because of its high insect repellent effect.
次に、本発明に云う樹脂皮膜とはアクリル、ウレタン、
シリコン等の高分子重合体を架橋せしめたもので少なく
とも表面には多数の小孔を有するものである。かかる有
孔樹脂皮膜中には、前記昇華性防虫剤が全面に亘って略
々均一に分散しており、その含有量は、昇華初期（製造
時）において０．０１〜１０重量％（固形分として繊維
構造物重量に対して）程度が好ましい。繊維構造物は、
その表面に前記有孔樹脂皮膜を設けることができれば特
に限定されず、織物、＆ｌｌ物事不織布等種々ものが用
い得る。又、有孔樹脂皮膜と繊維構造物の接合も、コー
ティング、含浸、ラミネート等種々のものが用い得るが
、風合上コーティングにより一体化したものが好ましい
。Next, the resin film referred to in the present invention is acrylic, urethane,
It is made by crosslinking a high molecular weight polymer such as silicone, and has many small pores at least on the surface. In this porous resin film, the sublimable insect repellent is almost uniformly dispersed over the entire surface, and its content is 0.01 to 10% by weight (solid content) at the initial stage of sublimation (at the time of manufacture). (relative to the weight of the fibrous structure) is preferred. The fiber structure is
There is no particular limitation as long as the porous resin film can be provided on the surface, and various materials such as woven fabrics and non-woven fabrics can be used. In addition, various methods such as coating, impregnation, and lamination can be used to join the porous resin film and the fiber structure, but it is preferable to integrate the resin film by coating in terms of texture.
次に本発明方法について述べる。Next, the method of the present invention will be described.
昇華性防虫剤としては、熱処理により有効成分が蒸散・
変質しないよう沸点２００℃以上のものが必要である。As a sublimation insect repellent, the active ingredient transpires and
It is necessary to have a boiling point of 200°C or higher to avoid deterioration.
かかる物質としては前述のものが用い得、特に前記した
如きＮ、Ｎ−ジエチル−ｍ−トルアミド及びイソボルニ
ル・チオシアノ酢酸を略々同量と分散剤、乳化剤を添加
した薬剤や、防虫物質に対して１．２ヘンゼンジカルボ
ン酸ジエチルエステルを８１重量％、ピペロニルブトキ
サイドを５重量％、ミリスチン酸オクチルドデシルを５
重量％および乳化剤を９重量％含む薬剤が好ましい。As such substances, those mentioned above can be used, and in particular, for drugs and insect repellents containing approximately the same amount of N,N-diethyl-m-toluamide and isobornyl thiocyanoacetic acid as well as dispersants and emulsifiers. 1.2 81% by weight of Henzendicarboxylic acid diethyl ester, 5% by weight of piperonyl butoxide, 5% by weight of octyldodecyl myristate.
Preference is given to medicaments containing 9% by weight and emulsifier.
低温反応型樹脂としては、例えば低温反応性のブロック
化イソシアネートプレポリマーのエマルジョン、低温反
応性のオルガノポリシロキサンプレポリマーのエマルジ
ョン等が挙げられ、低温反応性ブロック化イソシアネー
トプレポリマーのエマルジョンとは、重亜硫酸ソーダ、
アセチルアセトン、アセト酢酸エチル、ジルエチルマロ
ネート等、イソシアネート基に反応して一時的に安定化
合物を作り、後から熱処理することにより熱解離、７、
イソシアネート基を再生するブロック化イソシアネート
基を分子中に少なくとも１個以上含有する化合物であり
、アクリル又はメタクリル化合物及びシリコン変性、フ
ッ素変性等、変性アクリル又はメタクリル化合物を重合
して得られプロポリマーエマルジョン及びジイソシアネ
ートとポリオールからなるポリウレタンプレポリマーの
エマルジョン及び澱粉、セルロース等の天然多Ｉｌｉ類
のエマルション及ヒ天然タンパク質のエマルジョンであ
る。Examples of low-temperature-reactive resins include emulsions of low-temperature-reactive blocked isocyanate prepolymers and emulsions of low-temperature-reactive organopolysiloxane prepolymers. Sodium sulfite,
Acetylacetone, ethyl acetoacetate, diethyl malonate, etc., react with isocyanate groups to temporarily create stable compounds, which are then thermally dissociated by heat treatment.7.
It is a compound containing at least one blocked isocyanate group in the molecule to regenerate isocyanate groups, and is obtained by polymerizing an acrylic or methacrylic compound and a silicon-modified, fluorine-modified, etc., modified acrylic or methacrylic compound.Propolymer emulsion and These are emulsions of polyurethane prepolymers consisting of diisocyanates and polyols, emulsions of natural polyesters such as starch and cellulose, and emulsions of natural proteins.
また、低温反応性のオルガノボリシオキサンプレボリマ
ーのエマルジョンとは、１分子中にケイ素原子に結合す
るヒドロキシル基を少なくとも２個有するオルガノポリ
シロキサン及びその誘導体１００重量部及びアミノファ
ンクショナルシラン又は、その加水分解物と酸無水物と
の反応生成物０．１〜１０重量部とコリイダルシリコ１
〜５０重量部からなる均一分散液を該ポリシロキサンに
対して０．０１〜１０重量部及びアニオン系乳化剤が該
ポリシロキサンに対して０．３〜２０重量部及び水が該
ポリシロキサンに対して０．３〜２０重量部からなるシ
リコンの水性エマルジョンである。In addition, the emulsion of a low-temperature-reactive organoborisioxane prebolimer refers to 100 parts by weight of an organopolysiloxane and its derivatives having at least two hydroxyl groups bonded to a silicon atom in one molecule and an aminofunctional silane or its derivatives. 0.1 to 10 parts by weight of a reaction product of a hydrolyzate and an acid anhydride and 1 colloidal silico
0.01 to 10 parts by weight of a uniform dispersion of ~50 parts by weight based on the polysiloxane, an anionic emulsifier of 0.3 to 20 parts by weight based on the polysiloxane, and water based on the polysiloxane. It is an aqueous emulsion of silicone containing 0.3 to 20 parts by weight.
有機溶媒のエマルジョンとしては、ケロシンのような炭
化水素、各種のハロゲン炭化水素などの水と混和しない
ものを用いるとよく、取り扱い容易性及び出来る孔の状
態から、ケロシンが特に好ましく、水に適当な乳化剤と
ともに添加してエマルジョン化すればよい。As the emulsion of the organic solvent, it is preferable to use a hydrocarbon such as kerosene, various halogenated hydrocarbons, etc. that are immiscible with water. Kerosene is particularly preferred from the viewpoint of ease of handling and the state of the pores formed. It may be added together with an emulsifier to form an emulsion.
斯くの如き昇華性防虫剤、低温反応性樹脂、及び有機溶
媒のエマルジョンはこれを混合して処理液となすが、そ
の一実施例を述べると、繊維構造物重量に対して固形分
として０．２〜１５．０重量％の該低温反応性樹脂をケ
ロシン、水及び乳化剤を含有する増粘剤により粘度５０
００〜２００００センチボイズに調整して処理液を作る
。An emulsion of such a sublimable insect repellent, a low-temperature reactive resin, and an organic solvent is mixed to form a treatment liquid, and in one example, the solid content is 0.00% based on the weight of the fibrous structure. 2 to 15.0% by weight of the low temperature reactive resin is reduced to a viscosity of 50% by a thickener containing kerosene, water and an emulsifier.
Prepare a processing solution by adjusting the centivoise to 00 to 20,000 centivoise.
増粘剤としては、大日本インキ株式会社製品のりューダ
イーＷリイデューサーコンク４５０ （商標）などが挙
げられ、その使用量は溶液濃度で４０〜７０重量％であ
る。Examples of the thickener include Ryudai W Reducer Conc 450 (trademark) manufactured by Dainippon Ink Co., Ltd., and the amount used is 40 to 70% by weight in solution concentration.
これをコーティング加工法により繊維構造物に施与する
。又は、更に起泡剤と上記増粘剤を加えて、粘度を５０
００〜２００００センチポイズに調整して泡加工法によ
って繊維構造物に付与する。This is applied to the fiber structure by a coating method. Or, further add a foaming agent and the above thickener to reduce the viscosity to 50.
It is adjusted to 00 to 20,000 centipoise and applied to the fiber structure by a foam processing method.
コーティング加工法で使用される装置としてはナイフコ
ーター、エアドクタコーター、ブレードコーター、リバ
ースロールコータ−、グラビアコーター、キスコーター
などが挙げられる。コーテイング液の塗布量は、繊維構
造物の使用素材、目的等で異なるが概して１０〜８０ｇ
／ｍ” 、好ましくは、２０〜７０ｇ／ｍ２である。Examples of devices used in the coating process include a knife coater, an air doctor coater, a blade coater, a reverse roll coater, a gravure coater, and a kiss coater. The amount of coating liquid applied varies depending on the material used for the fiber structure, the purpose, etc., but is generally 10 to 80 g.
/m", preferably 20 to 70 g/m2.
泡加工に用いられる好適な起泡剤としては、分子中に約
１０ないし５０個、好ましくは、約１２ないし２０個の
エチレノキシド単位を有する混合ＣＩｌ〜Ｃ１５の線形
第２アルコールのエチレノキシド付加物、炭素数１０な
いし１６個の線形第１アルコールのエチレノキシド付加
物、炭素数８ないし１２個のアルキルフェノールのエチ
レノキシド５ないし約５０個、好ましくはフないし２０
個を有するもの、ココナツト脂肪酸モノエタノールアミ
ドのような脂肪酸アルカノールアミド、ジナトリウムＮ
−オクタデシルスルホサクシネート。Suitable blowing agents used in foam processing include ethyleneoxide adducts of mixed CII-C15 linear secondary alcohols having about 10 to 50 ethyleneoxide units in the molecule, preferably about 12 to 20 ethyleneoxide units, carbon Ethylenoxide adducts of several 10 to 16 linear primary alcohols, 5 to about 50 ethyleneoxides, preferably F to 20 ethyleneoxides of alkylphenols having 8 to 12 carbon atoms
fatty acid alkanolamides such as coconut fatty acid monoethanolamide, disodium N
-Octadecyl sulfosuccinate.
テトラナトリウムＮ−（１，２−ジカルボキシエチル）
−Ｎ−オクタデシルスルホサクシネート、ナトリウムス
ルホコハク酸のシアミルエステル、ナトリウムスルホコ
ハク酸のジオクチルエステル。Tetrasodium N-(1,2-dicarboxyethyl)
-N-octadecyl sulfosuccinate, cyamyl ester of sodium sulfosuccinate, dioctyl ester of sodium sulfosuccinate.
ナトリウムスルホコハク酸のジオクチルエステルなどの
ようなスルホサクシネートエステル塩、等の非イオン活
性剤及びアニオン界面活性剤のほかに、ジステアリルピ
リジニウムクロライド、Ｎココ−アミノプロピオン酸（
Ｎ−タロー又はＮラウリル誘導体）もしくはナトリウム
塩、ステアリルジメチルヘンシルアンモニウムクロライ
ド。In addition to nonionic and anionic surfactants such as sulfosuccinate ester salts, such as dioctyl ester of sodium sulfosuccinate, distearylpyridinium chloride, N-coco-aminopropionic acid (
N-tallow or N-lauryl derivatives) or the sodium salt, stearyldimethylhensylammonium chloride.
ベタインのようなカチオン界面活性剤または両性界面活
性剤も使用することが出来る。Cationic or amphoteric surfactants such as betaine can also be used.
これらの起泡剤は、繊維構造物重量に対して０．０５〜
５重量％、好ましくは０．１〜３重景％を用いる。These foaming agents are added in an amount of 0.05 to 0.05 to the weight of the fiber structure.
5% by weight, preferably 0.1-3% by weight is used.
繊維構造物に泡加工を行なうには通常公知の方法２機械
例えばガストンカランティ社のＦＦＴフオームアプリケ
ーター、ストークル社のスケーグ。For foaming textile structures, there are generally known methods 2 machines, such as the FFT foam applicator from Gaston Calanti, the skeg from Stokl.
東伸工業株式会社のユニバーサルクォーター、キュース
ター社のキュースターアプリケーター、ファプコン社の
ファブコンＦＦＴシステンム等の泡加工機や東伸工業株
式会社のロータリースクリーン、キスコーター、グラビ
アコーター、捺染機等を用いればよい。発泡液の塗布量
としては繊維構造物の使用素材、目付等で異なるが概し
て１０〜８０ｇ／ｍ２である。Foam processing machines such as Toshin Kogyo Co., Ltd.'s Universal Quarter, Custar Co., Ltd.'s Custar Applicator, Fapcon's Fabcon FFT System, and Toshin Kogyo Co., Ltd.'s rotary screen, kiss coater, gravure coater, textile printing machine, etc. may be used. . The amount of foaming liquid applied varies depending on the material used for the fiber structure, the basis weight, etc., but is generally 10 to 80 g/m2.
この外、繊維構造物の風合調整をかねて必要に応じて、
エポキシ変性シリコンオイルエマルジョン例えば、大日
本インキ株式会社製品のディソクシリコンソフナーＡ−
９００（商標）、アミノ変性シリコンオイルエマルジョ
ン例えば、大日本インキ株式会社製品のディックシリコ
ンソフナー２００ （商標）をそれぞれ繊維構造物重量
に対して固形分として０．２〜０．８重量％更に付与し
てもよい。In addition to this, we also adjust the texture of the fiber structure as necessary.
Epoxy-modified silicone oil emulsion, for example, Disoc Silicone Softener A- manufactured by Dainippon Ink Co., Ltd.
900 (trademark), an amino-modified silicone oil emulsion, for example, Dick Silicone Softener 200 (trademark) manufactured by Dainippon Ink Co., Ltd., are further added in an amount of 0.2 to 0.8% by weight as a solid content based on the weight of the fiber structure. It's okay.
以上の如く、処理液を付与した後は、１００〜１３０℃
程度で乾燥後、温度８０〜１５０℃好ましくは１００〜
１３０℃にて１０秒〜１０分好ましくは３０秒〜５分間
の熱処理を行うことにより、０−
多数の小孔を持つ樹脂皮膜が繊維構造物に固着される。As mentioned above, after applying the treatment liquid, the temperature is 100-130℃.
After drying at a temperature of 80~150℃, preferably 100~
By performing a heat treatment at 130° C. for 10 seconds to 10 minutes, preferably 30 seconds to 5 minutes, a resin film having 0 to a large number of small pores is fixed to the fibrous structure.
（実施例）
実施例中の
（１） 防虫効果については内径６ｃｍのガラス性シ
ャーレの底面に飼料（径６ｃｍ）を敷きその上に供試虫
を飼育培地とともに約２００匹（培地として１５０ｍｇ
）を放ち、２５℃、７５％ＲＨ条件下にて経時的な死亡
率を求めた。生死の判別は、実体顕微鏡下で微針を用い
刺激を与え、反応しないものを死生とした。尚、供試虫
には、コナヒョウヒダ、−（Ｄｅｒｍａｔｏｐｈａｇｏ
ｉｄｅｓｆａｒｉｎａｅ）、飼育培地には、エビオス（
酵母）と昆虫飼育飼料を等量ずつ配合したものを使用し
た。(Example) Regarding the insect repellent effect (1) in the example, feed (6 cm in diameter) was spread on the bottom of a glass petri dish with an inner diameter of 6 cm, and about 200 test insects were placed on it together with a breeding medium (150 mg as the medium).
), and the mortality rate over time was determined under conditions of 25° C. and 75% RH. To determine whether the animals were alive or dead, stimulation was applied using a microneedle under a stereoscopic microscope, and those that did not respond were classified as dead or alive. In addition, the test insects include Dermatophaga, -(Dermatophago
idesfarinae), and Ebios (
A mixture of equal amounts of yeast) and insect rearing feed was used.
（２） 洗濯品は、ＪＩＳ−Ｌ−０２１７−１０３法
で洗濯５回後、及び１０回後、上記試験を行なった。(2) The above-mentioned test was conducted on the washed products after washing them 5 times and 10 times according to the JIS-L-0217-103 method.
（３） ドライクリーニング品は、Ｊ Ｔ ５−Ｌ０
２１７−４０１法でドライクリーニング３凹稜上記試験
を行なった。(3) For dry cleaning products, JT 5-L0
The above test for dry cleaning 3 concave edges was conducted using the 217-401 method.
（４） 通気度はＪＩＳ−Ｌ−］、］０９６−Ａによ
り測定した。(4) Air permeability was measured according to JIS-L-], ]096-A.
実施例１
通常公知の方法で、糊抜、精練、漂白、シルケット、染
色した綿１００％、４０番手の目付１３０ｇ／ｍ”のサ
テン地に次の処理液をコーティングした。即ち、防虫物
質としてイソボルニル・チオシアノ酢酸ＣＣ＋３Ｈ＋ｑ
ＮＯ□５）２０重量％（沸点２１２℃、融点２０４“Ｃ
）、ジエチル・トルアミド（ＣＩ２Ｈ１７ＯＮ）２０重
量％（沸点１６６℃）及び若干の分散剤・乳化剤と水か
らなるものを５０ ｇ／ｆｆ、低温反応性樹脂として第
−工業製薬株式会社製のブロック化イソシアネートエマ
ルジョン、エラストロンＭ−２０７６５０ｇ／ｎ及び第
−工業製薬株式会社製のキャタリスト３２５ｇ／ｌ大日
本インキ株式会社製のアミン変性シリコンオイルエマル
ジョン、ディソクシリコンソフナー２００ （商標、固
形分４０％含有）１０ｇ／ｉ大日本インキ株式会社製の
エポキシ変性シリコンオイルエマルジョン、デイソクシ
リコンソフナー９００ （商標、固形分４０％含有）１
０ｇ／ｌ、ケロシンを含む増粘剤として大日本インキ株
式会社製のりュウダイＷ、リイデューサーコンク４５０
（商標）４００ｇ／！、及び残部が水よりなる粘度７
０００センチポイズの処理液である。該処理液を５０ｇ
／ｍ２サテン地に塗布した後、１００°Ｃて乾燥し、１
３０℃で３分間熱処理し、繊維構造物に対して、防虫物
質０．７５重量％アミノ変性シリコンオイル０．１５重
量％、エポキシ変性シリコンオイル０．１５重量％が付
与された防虫サテン織物を得た。Example 1 A desizing, scouring, bleaching, mercerizing, and dyed 100% cotton, 40-count satin fabric with a basis weight of 130 g/m'' was coated with the following treatment solution using a commonly known method.・Thiocyanoacetic acid CC+3H+q
NO□5) 20% by weight (boiling point 212℃, melting point 204"C
), 20% by weight of diethyl toluamide (CI2H17ON) (boiling point 166°C) and 50 g/ff of something consisting of some dispersant/emulsifier and water, blocked isocyanate manufactured by Dai-Kogyo Seiyaku Co., Ltd. as a low temperature reactive resin. Emulsion, Elastron M-207650 g/n and Catalyst 325 g/l manufactured by Dai-Kogyo Seiyaku Co., Ltd. Amine-modified silicone oil emulsion manufactured by Dainippon Ink Co., Ltd., Disoku Silicone Softener 200 (trademark, containing 40% solids) 10 g /i Epoxy-modified silicone oil emulsion manufactured by Dainippon Ink Co., Ltd., Daisoku Silicone Softner 900 (trademark, solid content 40%) 1
0 g/l, Ryudai W manufactured by Dainippon Ink Co., Ltd. and Reducer Conc 450 as thickeners containing kerosene.
(Trademark) 400g/! , and the remainder is water, and the viscosity is 7.
000 centipoise processing solution. 50g of the treatment liquid
/m2 After applying to satin fabric, dry at 100°C,
Heat treatment was performed at 30° C. for 3 minutes to obtain an insect repellent satin fabric to which 0.75% by weight of insect repellent, 0.15% by weight of amino-modified silicone oil, and 0.15% by weight of epoxy-modified silicone oil were applied to the fiber structure. Ta.
得られた加工上りの生地、洗濯１０回後の生地及びドラ
イクリーニング１０回後の生地による防虫効果、加工上
り生地の通気度を第１表に示した。Table 1 shows the insect repellent effects of the resulting processed fabrics, the fabrics after 10 washes, and the fabrics after 10 dry cleanings, and the air permeability of the processed fabrics.
又、該防虫サテン地を羽根布団の側地として用いたとこ
ろ、詰物の噴出もなく、更に適当な芳香が得られ好適で
あった。Furthermore, when the insect-repellent satin material was used as a side material for a feather comforter, no filler material was ejected and a suitable fragrance was obtained.
実施例２
実施例１と同じサテン地、防虫物質を用いて、更に防虫
物質としてイソボルニル・チオシアノ酢酸５０ｇ／β、
低温反応性樹脂としてオルガノポリシロキサンプレポリ
マーエマルジョンの信越化学工業株式会社製のＫＭ２０
０２Ｌ−１を５０ｇ／β、大日本インキ株式会社製のア
ミノ変性シリコンオイルエマルジョン、ディソクシリコ
ンソフナー２００（商標、固形分４０％含有）Ｌｏｇ／
ｐ、大日本インキ株式会社製のエポキシ変性シリコンオ
イルエマルジョン、ディソクシリコンソフナー９００（
商標、固形分４０％含有）１０ｇ／β、ケロシンを含む
増粘剤として大日本インキ株式会社製のりュウダイＷ、
リイデューサーコンク４５０ （商標）４００ｇ／βと
気泡剤として明成化成株式会社のメーホーマーＦ２１８
Ｌｏｇ／ｐ、及び残部が水よりなる混合液を発泡機
にかけ、発泡倍率２０倍、粘度８０００センチボイズの
泡を作り、東伸工業株式会社製のロータリースタリンを
使用して、７０ｇ／ｍ” の泡を綿１００％のサテン地
に付与した。これを１００℃で乾燥し、１５０℃で３分
間熱処理して防虫サテン織物を得３
４
た。得られた加工上りの生地、洗濯１０回後の生地、及
びドライクリーニング１０回後の生地による防虫効果、
加工上り生地の通気度を第１表に示した。Example 2 Using the same satin fabric and insect repellent as in Example 1, 50 g/β of isobornyl thiocyanoacetic acid was added as an insect repellent.
Organopolysiloxane prepolymer emulsion KM20 manufactured by Shin-Etsu Chemical Co., Ltd. as a low-temperature reactive resin
02L-1 at 50g/β, amino-modified silicone oil emulsion manufactured by Dainippon Ink Co., Ltd., Disoku Silicone Softener 200 (trademark, containing 40% solids) Log/
p, epoxy-modified silicone oil emulsion manufactured by Dainippon Ink Co., Ltd., Disoku Silicone Softener 900 (
Ryudai W manufactured by Dainippon Ink Co., Ltd. as a thickener containing kerosene (Trademark, solid content 40%) 10g/β,
Reducer Conc 450 (trademark) 400g/β and Meihomer F218 from Meisei Kasei Co., Ltd. as a foaming agent
A mixture of Log/p and the balance of water was applied to a foaming machine to produce foam with a foaming ratio of 20 times and a viscosity of 8,000 centibois, and then a foam of 70 g/m" was produced using a rotary stalin manufactured by Toshin Kogyo Co., Ltd. was applied to a 100% cotton satin fabric.This was dried at 100°C and heat-treated at 150°C for 3 minutes to obtain an insect-proof satin fabric34.The obtained fabric after processing and the fabric after washing 10 times , and the insect repellent effect of the fabric after 10 times of dry cleaning.
Table 1 shows the air permeability of the processed fabric.
比較例１
実施例１で使用したと同一の綿１００％サテン地につい
て未処理生地、洗濯１０回後の生地、及びドライクリー
ニング１０回後の生地による防虫効果、加工上り生地の
通気度を第１表及び第２表に示した。Comparative Example 1 Regarding the same 100% cotton sateen fabric used in Example 1, the insect repellent effect of the untreated fabric, the fabric after 10 washes, and the fabric after 10 dry cleanings, and the air permeability of the processed fabric were evaluated as follows: It is shown in Table and Table 2.
比較例２
実施例１で使用したと同一の綿１００％サテン地に低温
反応性樹脂として第−工業製薬製のブロック化イソシア
ネートエマルジョン、エラストロンＭ−２０７６を５０
ｇ ／ Ｉｌ及び第−工業製薬株式会社製のキャタリ
スト３２を５ ｇ ／ ＩＬ、大日本インキ化学工業株
式会社製のアミン変性シリコンオイルエマルジョン、デ
ィックシリコンソフナー２００ （商標、固形分４０％
含有）Ｌｏｇ／ｌ大日本インキ化学工業株式会社製のエ
ポキシ変性シリコンオイルエマルジョン、ディックシリ
コンソフナー９００（商標、固形分４０％含有）１０ｇ
／Ｉ２、ケロシンを含む増粘剤として大日本インキ株式
会社製のリュウダイＷ、リイデューサーコンク４５０
（商標）４００ｇ／βと気泡剤として明成化成株式会社
のメーホーマーＦ２１８ １０ｇ／β、及び残部が水よ
りなる混合液を発泡機にかけ、発泡倍率２０倍、粘度８
０００センチボイズの泡を作り、東伸工業株式会社製の
ロータリースクリーンを使用して、７０ｇ’／ｍ”の泡
を綿１００％のサテン地に付与した。これを１００℃で
乾燥し、１５０℃で３分間熱処理して防虫サテン織物を
得た。得られた加工上りの生地、洗濯１０回後の生地、
及びドライクリーニング１０回後の生地による防虫効果
、加工上り生地の通気度を第１表に示した。Comparative Example 2 50% of Elastron M-2076, a blocked isocyanate emulsion manufactured by Dai-Kogyo Seiyaku, was applied as a low-temperature reactive resin to the same 100% cotton satin fabric used in Example 1.
g/IL and Catalyst 32 manufactured by Dai-Kogyo Seiyaku Co., Ltd. at 5 g/IL, amine-modified silicone oil emulsion manufactured by Dainippon Ink & Chemicals Co., Ltd., Dick Silicone Softener 200 (trademark, solid content 40%)
Contains) Log/l Epoxy-modified silicone oil emulsion manufactured by Dainippon Ink & Chemicals Co., Ltd., Dick Silicone Softener 900 (trademark, solid content 40%) 10g
/I2, Ryudai W manufactured by Dainippon Ink Co., Ltd., Reducer Conc 450 as a thickener containing kerosene
(Trademark) 400g/β, Meisei Kasei Co., Ltd.'s Mehomer F218 10g/β as a foaming agent, and the balance water was applied to a foaming machine, with a foaming ratio of 20 times and a viscosity of 8.
000 centibois foam was made, and using a rotary screen manufactured by Toshin Kogyo Co., Ltd., 70 g'/m'' of foam was applied to a 100% cotton satin fabric. This was dried at 100°C and then heated at 150°C. The insect-proof satin fabric was obtained by heat treatment for 3 minutes.The obtained fabric after processing, the fabric after washing 10 times,
Table 1 shows the insect repellent effect of the fabric after 10 dry cleanings and the air permeability of the processed fabric.
実施例３
実施例１において、防虫物質としてイソボルニル・チオ
シアノ酢酸２０重量％及び若干の分散剤・乳化剤と水か
らなるものを用いた他は全く同様に処理を行ない防虫サ
テン織物を得た。Example 3 An insect-proof satin fabric was obtained by carrying out the same treatment as in Example 1, except that 20% by weight of isobornyl thiocyanoacetic acid, some dispersants/emulsifiers, and water were used as the insect-proof substance.
比較例３
実施例１において、低温反応性樹脂に代えて通常のウレ
タンエマルジョン樹脂（大日本インキ製ボンデイック１
６１ＯＮＳ）９０ｇ／ｌを用い、１００℃で乾燥し、１
５０℃で３分間熱処理した他は全く同様に処理を行った
。Comparative Example 3 In Example 1, ordinary urethane emulsion resin (Bondic 1 manufactured by Dainippon Ink) was used instead of the low temperature reactive resin.
61ONS) 90g/l, dried at 100℃,
The treatment was carried out in exactly the same manner except that the heat treatment was performed at 50° C. for 3 minutes.
比較例４
実施例１において、増粘剤としてケロシンを含有しない
ものを用いた他は、全く同様に処理を行った。得られた
布帛表面を顕微鏡で観察したとこ７
８
実施例４
実施例１で使用したと同一の綿１００％サテン地に次の
処理液をコーティングした。即ち、防虫物質として１，
２ベンゼンジカルボン酸ジエチルエステル（沸点２９５
°Ｃ）８１重量％、ピペロニルブトキサイド５重量％、
ミリスチン酸オクチルドデシル５重量％、及び乳化剤９
重量％からなるものを５０ｇ／ρ、低温反応性樹脂とし
て第−工業製薬株式会社製のブロック化イソシアネート
エマルジョン エラストロンＭ−２０７６５０ｇ／β及
び第−工業製薬株式会社製のキャタリスト３２ ５ｇ／
り、大日本インキ株式会社製のアミノ変性シリコンオイ
ルエマルジョン、デイックシリコンソフナー２００（商
標、固形分４０％含有）１０ ｇ／ｊ！、大日本インキ
株式会社製のエポキシ変性シリコンオイルエマルジョン
、ディソクシリコンソフナー９００ （商標、固形分４
０％含有）１０ ｇ／ｊ！、ケロシンを含む増粘剤とし
て大日本インキ株式会社製のリュウダイＷ、リイデュー
サーコンク４５０ （商標）４００ｇ／７！、及び残部
が水よりなる粘度７０００センチポイズの処理液である
。該処理液を５０ｇ／ｍ”サテン地に塗布した後、１０
０℃で乾燥し、１３０℃で３分間熱処理し、繊維構造物
に対して、防虫物質０．７５重量％、アミノ変性シリコ
ンオイル０．１５重量％。Comparative Example 4 The same process as in Example 1 was carried out except that a thickener that did not contain kerosene was used. The surface of the obtained fabric was observed under a microscope.7 8 Example 4 The same 100% cotton satin fabric used in Example 1 was coated with the following treatment solution. That is, as an insect repellent substance, 1,
2-benzenedicarboxylic acid diethyl ester (boiling point 295
°C) 81% by weight, piperonyl butoxide 5% by weight,
Octyldodecyl myristate 5% by weight and emulsifier 9
50 g/ρ by weight%, blocked isocyanate emulsion Elastron M-207650 g/β manufactured by Dai-Kogyo Seiyaku Co., Ltd. and Catalyst 32 5 g/β manufactured by Dai-Kogyo Seiyaku Co., Ltd. as low-temperature reactive resins.
Amino-modified silicone oil emulsion manufactured by Dainippon Ink Co., Ltd., DIC Silicone Softener 200 (trademark, containing 40% solids) 10 g/j! , epoxy-modified silicone oil emulsion manufactured by Dainippon Ink Co., Ltd., Disoku Silicone Softener 900 (trademark, solid content 4
0% content) 10 g/j! , Ryudai W manufactured by Dainippon Ink Co., Ltd., Reducer Conc 450 (trademark) 400g/7! as a thickener containing kerosene. , and the balance is water, and has a viscosity of 7000 centipoise. After applying the treatment solution to 50 g/m" satin fabric,
Dry at 0°C and heat treat at 130°C for 3 minutes to obtain 0.75% by weight of insect repellent and 0.15% by weight of amino-modified silicone oil based on the fiber structure.
エポキシ変性シリコンオイル０．１５重量％が付与され
た防虫サテン織物を得た。An insect-proof satin fabric to which 0.15% by weight of epoxy-modified silicone oil was applied was obtained.
得られた加工上りの生地、洗濯１０回後の生地及びドラ
イクリーニング１０回後の生地による防虫効果、加工上
り生地の通気度を第２表に示した。Table 2 shows the insect repellent effects of the finished fabrics, the fabrics after washing 10 times, and the fabrics after dry cleaning 10 times, and the air permeability of the fabrics after processing.
又、該防虫サテン地を羽根布団の側地として用いたとこ
ろ、詰物の噴出もなく、好適であった。Furthermore, when the insect-proof satin fabric was used as a side fabric for a feather comforter, no filler material spewed out and it was suitable.
比較例５
実施例１で使用したと同一の綿１００％サテン地に、低
温反応性樹脂として第−工業製薬株式会社製のブロック
化イソシアネートエマルジョンエラストロンＭ−２０７
６５０ｇ／β及び第−工業製薬株式会社製のキャタリス
）３２ ５ｇ／ｐ、大日本インキ化学工業株式会社製の
アミノ変性シリコンオイルエマルジョン、ディソクシリ
コンソフナー２００ （商標、固形分４０％含有）Ｌｏ
ｇ／ｊ！、大日本インキ化学工業株式会社製のエポキシ
変性シリコンオイルエマルジョン、ディソクシリコンソ
フナー９００（商標、固形分４０％含有）Ｌｏｇ／β、
ケロシンを含む増粘剤として大日本インキ株式会社製の
リュウダイＷ、リイデューサーコンク４５０ （商標）
４ｏｏｇ／ｌと気泡剤として明成化成株式会社のメ
ーホーマーＦｚｌａ １０．ｇ／Ａ、及び残部が水よ
りなる混合液を発泡機にかけ、発泡倍率２０倍、粘度８
０００センチボイズの泡を作り、東伸工業株式会社製の
ロータリースクリーンを使用して、７０ｇ ／ ｍ ２
の泡を綿１００％のサテン地に付与した。Comparative Example 5 The same 100% cotton satin fabric used in Example 1 was coated with blocked isocyanate emulsion Elastron M-207 manufactured by Dai-Kogyo Seiyaku Co., Ltd. as a low-temperature reactive resin.
650g/β and Catalys manufactured by Dai-Kogyo Seiyaku Co., Ltd.) 32 5g/p, amino-modified silicone oil emulsion manufactured by Dainippon Ink & Chemicals Co., Ltd., Disoku Silicone Softener 200 (trademark, containing 40% solids) Lo
g/j! , epoxy-modified silicone oil emulsion manufactured by Dainippon Ink and Chemicals Co., Ltd., Disoku Silicone Softener 900 (trademark, containing 40% solids) Log/β,
Ryudai W and Reducer Conc 450 (trademark) manufactured by Dainippon Ink Co., Ltd. are used as thickeners containing kerosene.
4oog/l and Meihomer Fzla from Meisei Kasei Co., Ltd. as a foaming agent 10. g/A, and the balance is water, is applied to a foaming machine to obtain a foaming ratio of 20 times and a viscosity of 8.
000 centibois bubbles were made, using a rotary screen made by Toshin Kogyo Co., Ltd., 70 g/m 2
foam was applied to 100% cotton satin fabric.
これを１００℃で乾燥し、１５０℃で３分間熱処理して
防虫サテン織物を得た。得られた加工上りの生地、洗濯
１０回後の生地、及びドライクリーニング１０回後の生
地による防虫効果、加工上り生地の通気度を第２表に示
した。This was dried at 100°C and heat treated at 150°C for 3 minutes to obtain an insect-proof satin fabric. Table 2 shows the insect repellent effect and air permeability of the finished fabric, the fabric after washing 10 times, and the fabric after dry cleaning 10 times.
比較例６
実施例４において、増粘剤としてケロシンを含有しない
ものを用いた他は、全く同様に処理を行った。得られた
布帛表面を顕微鏡で観察したとこ１
２
（発明の効果）
本防虫繊維構造物は、昇華性防虫剤が耐久性よ（繊維構
造物に付与されたもので安全性・防虫効果に優れたもの
である。又、本発明方法は該防虫繊維構造物を工業的に
製造可能とするものである。Comparative Example 6 The same process as in Example 4 was carried out except that a thickener that did not contain kerosene was used. Observation of the surface of the obtained fabric with a microscope 1 2 (Effects of the invention) This insect repellent fiber structure has a sublimation insect repellent that is durable (it is added to the fiber structure and has excellent safety and insect repellent effects). Furthermore, the method of the present invention enables industrial production of the insect repellent fiber structure.
尚、本発明は、布団の裏地や側地として用いると有用で
あり、特にコーテイング品は羽根布団に用いれば目つぶ
し効果と相俟って有効である。The present invention is useful when used as a lining or side material for a futon, and in particular, a coated product is effective when used for a feather futon together with the eye closing effect.
Claims (2)
する防虫繊維構造物。(1) An insect repellent fiber structure having a perforated resin film containing a sublimable insect repellent on its surface.
脂、及び有機溶媒のエマルジョンを含有する処理液を繊
維構造物に施与した後、 １５０℃以下の温度で熱処理することを特徴とする防虫
繊維構造物の製造方法。(2) A treatment liquid containing an emulsion of a sublimable insect repellent with a boiling point of 200°C or higher, a low-temperature reactive resin, and an organic solvent is applied to the fiber structure, and then heat-treated at a temperature of 150°C or lower. A method for manufacturing an insect-repellent fiber structure.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14810890A JPH03234877A (en) | 1989-12-18 | 1990-06-05 | Mothproof textile and its production |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP32877289 | 1989-12-18 | ||
| JP1-328772 | 1989-12-18 | ||
| JP14810890A JPH03234877A (en) | 1989-12-18 | 1990-06-05 | Mothproof textile and its production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03234877A true JPH03234877A (en) | 1991-10-18 |
Family
ID=26478436
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14810890A Pending JPH03234877A (en) | 1989-12-18 | 1990-06-05 | Mothproof textile and its production |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03234877A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012061699A3 (en) * | 2010-11-05 | 2012-08-16 | Momentive Performance Materials Inc. | Durable non-fluorine water repellent agent and process for preparing same |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62250281A (en) * | 1986-04-23 | 1987-10-31 | カネボウ株式会社 | Durable deodorizing and antibacterial fiber structure havingperforated film |
-
1990
- 1990-06-05 JP JP14810890A patent/JPH03234877A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62250281A (en) * | 1986-04-23 | 1987-10-31 | カネボウ株式会社 | Durable deodorizing and antibacterial fiber structure havingperforated film |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012061699A3 (en) * | 2010-11-05 | 2012-08-16 | Momentive Performance Materials Inc. | Durable non-fluorine water repellent agent and process for preparing same |
| US8329255B2 (en) | 2010-11-05 | 2012-12-11 | Momentive Performance Materials Inc. | Durable non-fluorine water repellent agent and process for preparing same |
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