JPH03232804A - Poison bait composition for controlling insect pest - Google Patents
Poison bait composition for controlling insect pestInfo
- Publication number
- JPH03232804A JPH03232804A JP31935390A JP31935390A JPH03232804A JP H03232804 A JPH03232804 A JP H03232804A JP 31935390 A JP31935390 A JP 31935390A JP 31935390 A JP31935390 A JP 31935390A JP H03232804 A JPH03232804 A JP H03232804A
- Authority
- JP
- Japan
- Prior art keywords
- feeding
- poison bait
- bait composition
- pyridylpyridone
- ingredient
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- 230000003449 preventive effect Effects 0.000 description 1
- 239000000473 propyl gallate Substances 0.000 description 1
- 235000010388 propyl gallate Nutrition 0.000 description 1
- 229940075579 propyl gallate Drugs 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- FITIWKDOCAUBQD-UHFFFAOYSA-N prothiofos Chemical compound CCCSP(=S)(OCC)OC1=CC=C(Cl)C=C1Cl FITIWKDOCAUBQD-UHFFFAOYSA-N 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 239000011044 quartzite Substances 0.000 description 1
- 235000021067 refined food Nutrition 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- JZWFDVDETGFGFC-UHFFFAOYSA-N salacetamide Chemical group CC(=O)NC(=O)C1=CC=CC=C1O JZWFDVDETGFGFC-UHFFFAOYSA-N 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 235000020183 skimmed milk Nutrition 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 235000019259 sodium dehydroacetate Nutrition 0.000 description 1
- 229940079839 sodium dehydroacetate Drugs 0.000 description 1
- 235000010352 sodium erythorbate Nutrition 0.000 description 1
- 239000004320 sodium erythorbate Substances 0.000 description 1
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 description 1
- 235000010334 sodium propionate Nutrition 0.000 description 1
- 239000004324 sodium propionate Substances 0.000 description 1
- 229960003212 sodium propionate Drugs 0.000 description 1
- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 description 1
- RBWSWDPRDBEWCR-RKJRWTFHSA-N sodium;(2r)-2-[(2r)-3,4-dihydroxy-5-oxo-2h-furan-2-yl]-2-hydroxyethanolate Chemical compound [Na+].[O-]C[C@@H](O)[C@H]1OC(=O)C(O)=C1O RBWSWDPRDBEWCR-RKJRWTFHSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 235000012751 sunset yellow FCF Nutrition 0.000 description 1
- 239000004173 sunset yellow FCF Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- CJDWRQLODFKPEL-UHFFFAOYSA-N teflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC(Cl)=C(F)C(Cl)=C1F CJDWRQLODFKPEL-UHFFFAOYSA-N 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 1
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 1
- XAIPTRIXGHTTNT-UHFFFAOYSA-N triflumuron Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl XAIPTRIXGHTTNT-UHFFFAOYSA-N 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- WCJYTPVNMWIZCG-UHFFFAOYSA-N xylylcarb Chemical compound CNC(=O)OC1=CC=C(C)C(C)=C1 WCJYTPVNMWIZCG-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は、ピリジルピリドン誘導体を有効成分として含
有する害虫防除用毒餌組成物に関する。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a poison bait composition for pest control containing a pyridylpyridone derivative as an active ingredient.
〈従来の技術〉
従来、害虫防除用毒餌組成物はいくつが知られテオリ、
QB2,070.4BOA、特開昭5852205号公
報、USP4,564,681、特開昭61−1191
81号公報、特開昭68−218604号公報、特公昭
6B−26721号公報、EP272824A2 等に
記載されている。<Prior art> Several poison bait compositions for insect pest control have been known so far.
QB2,070.4BOA, JP-A-5852205, USP 4,564,681, JP-A-61-1191
81, Japanese Patent Application Laid-open No. 68-218604, Japanese Patent Publication No. 6B-26721, EP272824A2, etc.
〈発明が解決しようとする課題〉
しかしながら、従来知られている害虫防除用毒餌組成物
は、その殺虫有効成分として、ホウ酸、有機リン系殺虫
剤、カーバメート系殺虫剤、ピレスロイド系殺虫剤、ア
ミノヒドラゾン系殺虫剤等を含有するものが大半であり
、それぞれ以下のような欠点を有する。<Problems to be Solved by the Invention> However, conventionally known poison bait compositions for pest control contain boric acid, organophosphorus insecticides, carbamate insecticides, pyrethroid insecticides, amino acids, etc. as their insecticidal active ingredients. Most of them contain hydrazone insecticides, etc., and each has the following disadvantages.
0ホウ酸含有の毒餌組成物
害虫、特にゴキブリ等に対する基礎効力がさほど高くな
く、有効成1分としてのホウ酸含有量は、5〜50%と
かなり多い。ホウ酸自体の経口毒性には問題が多く、た
とえば第11日局解説書C−1475には、ホウ@5%
含有のてんか粉を使用した幼児の死亡例も認められる。Poison bait composition containing 0 boric acid The basic efficacy against pests, especially cockroaches, etc. is not very high, and the boric acid content as an active ingredient is quite high at 5 to 50%. There are many problems with the oral toxicity of boric acid itself.
There have also been cases of infant deaths caused by using the powder containing the ingredient.
また、ゴキブリ等に対するホウ酸の効力は、非常に遅効
的であり、喫食徒死に至るまでに1週間またはそれ以上
の時間を要する。しかも、その摂食過程において、下痢
症状を呈するため、ゴキブリ等の棲息場所周辺に軟***
物が多く付着し、非常に不衛斗であり、美観が損なわれ
るという事態も起こる。Furthermore, the effect of boric acid on cockroaches and the like is very slow-acting, and it takes one week or more for them to die from ingestion. Moreover, during the feeding process, they exhibit diarrheal symptoms, resulting in a large amount of soft excrement adhering to the areas where cockroaches and the like live, resulting in extremely unsanitary conditions and a loss of aesthetic appearance.
0 有機リン系殺虫剤またはカーバメート系殺虫剤含有
の毒餌組成物
それぞれの有効成分特有の臭いによって、害虫が毒餌を
忌避し、その結果、誘引喫食効果が悪くなり、殺虫効果
が著しく低下する。また、有効成分が系内の?lIm水
分で加水分解を受け、その分解から生じる臭いによって
、さらに忌避性が鳥味る上に、有効成分自体の含有率が
低下することもあって、殺虫効果がきわめて悪くなる場
合がある。0 The odor peculiar to the active ingredients of poison bait compositions containing organophosphorus insecticides or carbamate insecticides causes pests to avoid the poison baits, and as a result, the attracting feeding effect deteriorates and the insecticidal effect is significantly reduced. Also, is the active ingredient in the system? It undergoes hydrolysis with water, and the odor resulting from the decomposition further impairs its repellency, and the content of the active ingredient itself may decrease, resulting in extremely poor insecticidal effects.
Oピレスロイド系殺虫剤含有の組成物
有効成分特有の神経刺激性によって、害虫が毒餌を忌避
し、殺虫効果が著しく低下する。また、たとえ摂食され
たとしても、有効成分が、害虫体内で加水分解を受けや
すく、殺虫効果はきわめて悪くなる。O Due to the nerve stimulation characteristic of the active ingredient in compositions containing pyrethroid insecticides, pests avoid poisonous baits, and the insecticidal effect is significantly reduced. Moreover, even if the insect is ingested, the active ingredient is easily hydrolyzed within the body of the insect, and the insecticidal effect becomes extremely poor.
Oアミノヒドラゾン系殺虫剤含有の組成物害虫、特にゴ
キブリ等に対する効力が非常に遅効的であり、喫食徒死
に散るまでに1週間またはそれ以上の時間を有する。し
かも、その摂食過程において、害虫が長期間、痙拳や麻
痺を起こすため、ゴキブリ等が棲息場所周辺で、牢死状
態のまま数日間にわたって横たわることになり、美観上
好ましくなく、非常に気味悪がられることがある。Compositions containing O-aminohydrazone insecticides have very slow-acting effects against pests, especially cockroaches, and take a week or more to die of ingestion. Moreover, during the feeding process, the pests suffer from convulsions and paralysis for a long period of time, so cockroaches lie in a prison state for several days near their habitat, making them aesthetically undesirable and extremely creepy. Sometimes people hate me.
く課題を順法するための手段〉
本発明者らは、殺虫活性化合物を含有する毒餌組成物が
無数に考えられる中から、前述の組成物(5)
群が有する欠点をカバーしうる害虫防除用毒餌組成物に
ついて、鋭意検討を行なった結果、−1式C式中、Xは
フッ素紗子才たは論集原子を表わし、2は論集原子また
はシアノ基を誌、ゎす。)で示されるピリジルビリドシ
銹琴5体と、少なくとも一抽以上の摂食ル引剤または喫
食成分を食台する害虫防除用毒餌組成物C以下、本発明
組成物と記す)が、その有効成分の特性より、非常に優
れた害虫防除効果を有することを見出し、本発明に至っ
た。Means for Complying with the Problems Among the countless possible poison bait compositions containing insecticidal active compounds, the present inventors have developed a method for controlling pests that can overcome the shortcomings of compositions (5) described above. As a result of intensive studies on the poison bait composition, we found that in the formula -1, X represents a fluorine atom or a cyano atom, and 2 represents a cyano atom or a cyano group. ) is a poison bait composition for controlling pests containing five pyridyl pyridoshiseikin shown in Based on its characteristics, it was discovered that it has an extremely excellent pest control effect, leading to the present invention.
特開昭61−72754号公報で、−1式[11で示さ
れる化合物を含むピリジルピリドン誘導体が、きわ必で
良好な殺虫活性を有することは公知である。It is known from JP-A-61-72754 that pyridylpyridone derivatives containing the compound represented by formula -1 [11] have extremely good insecticidal activity.
本発明者らは、新しい害FIi防除用毒llI4組成物
を(6)
探索するなかで、該ピリジルピリドン誘導体の殺虫活性
についてさらに鋭意検討を重ねた結果、該誘導体のうち
、一般式CI〕で示されるピリジルピリドン誘導体に、
特に顕著な毒餌活性が認められることを確認した。While searching for a new poison III4 composition (6) for controlling harmful FIi, the present inventors further intensively investigated the insecticidal activity of the pyridylpyridone derivatives, and found that among the derivatives, the general formula CI] In the pyridylpyridone derivative shown,
It was confirmed that particularly remarkable poison bait activity was observed.
すなわち、本発明名らは、本発明組成物が、前述した既
存の害虫防除用毒餌組成物か有する種々の欠点をすべて
カバーし、
1、芭生類に対し、きわめて高い食缶活性をモする。That is, the composition of the present invention covers all of the various drawbacks of the existing poison bait compositions for controlling insect pests as described above, and: 1. It exhibits extremely high canning activity against Basin.
2、■生類に対し、食毒効果が速効的に発珈し、速やか
に死に至らせる。2. ■ The food poisoning effect takes effect quickly on living organisms, causing immediate death.
8 害虫類に対し、臭いや神経刺激性による摂食忌避活
性を示さない。8 Does not exhibit feeding repellent activity against pests due to odor or nerve stimulation.
4、摂食された組成物中の有効成分が害虫体内で解毒さ
れにくい。4. The active ingredients in the ingested composition are difficult to detoxify within the insect body.
5、摂食された後、害虫か下絢舵状を呈しない。5. After being ingested, the insects do not exhibit a pest-like appearance.
6、摂食された後、害虫が長期間にわたって、痙拳や麻
痺を続け、生死状態を持続することがない。6. After being ingested, the pest does not remain alive or dead for a long period of time due to convulsions or paralysis.
7、有機リン剤、カーバメート剤、ピレスロイド剤等に
低感受性な害虫に対しても、卓効を示す。7. It is highly effective against pests that are less sensitive to organic phosphorus agents, carbamates, pyrethroid agents, etc.
8、溢血動物に対する経口毒性か非常に低い。8. Oral toxicity to bleeding animals is very low.
9、紅、酸物中の有効成分が、経時良化しにくい。9. Red: The active ingredients in the acid are difficult to improve over time.
等の優れた性漬を有することを確鼾・した。It was confirmed that it has excellent sex pickles.
一般式〔すで示されるピリジルピリドン誘導体のうち、
本発明組成物の有効成分として特に奸才しいものは、X
が塩素原子を表わす化合物であり、さらに最も好ましい
ものは、Xおよび2が、ともに塩素原子を表わす化合物
である。Among the pyridylpyridone derivatives represented by the general formula [
Particularly clever active ingredients of the composition of the present invention are X
is a compound in which X represents a chlorine atom, and most preferred is a compound in which both X and 2 represent a chlorine atom.
本発明組成物は、少なくとも1枠以上の摂食訊引剤才た
は喫食成分を含有する。含有可能な摂食誘引剤としては
、このような目的に使用され1全ての物質かあげられる
が、喫食成分を兼ねることも多い。The composition of the present invention contains at least one or more feeding stimulant or edible ingredient. Food attractants that can be included include all substances used for such purposes, but they often also serve as edible ingredients.
摂食誘引剤または喫食成分の具体例としては、たとえは
以下のものがあげられる。Specific examples of feeding inducers or edible ingredients include the following.
植物粉:ジャガイモ粉、サツマイモ粉、トウモロコシ粉
、小麦粉、米粉、サトイモ粉、デンプン粉、繊維素粉、
米粉、樹皮粉、センキュウ粉末等
植物油二大豆油、菜種油、ゴマ油、小麦胚芽油、トウモ
ロコシ油、ヒマシ油、ビーナツツ油、綿実油、やし油、
オリーブ油、パーム油、トール油等
植物体:ジャガイモ、サツマイモ、サトイモ、ニンニク
、タマネギ、麦芽、米ヌカ、フスマ等植物加工品:(結
晶)セルロース、デキストリン、乾燥酵母(粉末)、動
物用固型飼料(粉末)等
動物体:鶏卵等
動物加工品:魚粉、サナギ粉、オキアミ粉、エビ粉、卵
粉、食肉エキス等
加工食品:粉乳、牛乳、ビスケット粉、酒等タンパク類
:アルブミン、グロブリン、カゼイン、各種アミノ酸等
糖類ニジw @s ブドウ糖、果糖、黒砂糖、乳糖、赤
砂糖、三泡糖、麦芽糖、孕≠→−4隋サトウキヒ果汁、
廃糖蓋、ハチミツ等
脂肪Mニオレイン際、リノール酸、リルン酸、(9)
ステアリン酸等
香料:チーズ香料、バター香料、ビーナツツ香料、ビー
チ香料、ストロベリー香料、ミルク香料、タマネギ香料
等
化学誘引剤:α−オキシ酸、α−オキシエステル、α−
ケトール、ar−α−テトラロール、ar −β−テト
ラロール、aC−α−テトラロール、α−ナフトール、
β−ナフトール、フラネオール(4−ヒドロキシ−2,
5−ジメチル−81(2H)フラノン)、4,5−ジヒ
ドロキシ−2,5−ジメチル−4−オキソ−8−フラニ
ルメチルエステル、4.5−ジヒドロキシ−2,5−ジ
メチル−4−オキソ−8−フラニルエチルエステル、2
−シクロヘキシル−5−メチル−8,F(2H)フラノ
ン、4−アセチル−5−メチル−8汐(2H)フラノン
、2.5−ジメチル−8ガ(2H)フラノン等
集合フェロモン:1−ジメチルアミノ−2−メチル−2
−プロパツールおよびその塩酸塩、ギ(10)
戯・塩、酢酸塩、シュウ酸塩またはステアリン!塩、1
−アミノ−2−メチル−2−プロパツール、1−ジエチ
ルアミノ−2−メチル−2−プロパツール、1−メチル
アミノ−2メチル−2−プロパツール、その他アミン系
化合物等
道しるベフェロモン:(8S、4R,6E、10Z)−
8,4,7,11−テトラメチル−トリデカ−6,10
−ジェナール、(Z)−9へキサデセナール、2.5−
ジメチルピラジン、8−メチル−2,5−ジメチルピラ
ジン、Z、E−α−フラネセン、E、E−α−フラネセ
ン等
また、本発明組成物においては、必要に応じて、製剤用
助剤、すなわち吸着担体、増量剤、結合剤、酸化防止剤
、保存剤、誤食防止剤、着色剤等を配合することができ
る。これらの製剤用助剤の具体例を以下に示す。Plant flour: potato flour, sweet potato flour, corn flour, wheat flour, rice flour, taro flour, starch flour, cellulose flour,
Rice flour, bark powder, nebula powder, etc. vegetable oils, soybean oil, rapeseed oil, sesame oil, wheat germ oil, corn oil, castor oil, bean oil, cottonseed oil, coconut oil,
Olive oil, palm oil, tall oil, etc. Plants: potatoes, sweet potatoes, taro, garlic, onions, malt, rice bran, bran, etc. Plant processed products: (crystalline) cellulose, dextrin, dried yeast (powder), solid animal feed (powder), etc.Animal bodies: Eggs, etc.Animal processed products: Fish meal, pupa meal, krill meal, shrimp meal, egg meal, meat extract, etc.Processed foods: Milk powder, milk, biscuit flour, alcohol, etc.Proteins: Albumin, globulin, casein , Various amino acids and other sugars w @s Glucose, fructose, brown sugar, lactose, brown sugar, trifoam sugar, maltose, fertilization≠→-4 Sui sugar cane juice,
Fats such as waste sugar cap, honey, M niolein, linoleic acid, lylunic acid, (9) stearic acid, etc. Flavoring agents: Cheese flavoring, butter flavoring, peanut flavoring, beach flavoring, strawberry flavoring, milk flavoring, onion flavoring, etc. Chemical attractants: α-oxyacid, α-oxyester, α-
Ketol, ar-α-tetralol, ar-β-tetralol, aC-α-tetralol, α-naphthol,
β-naphthol, furaneol (4-hydroxy-2,
5-dimethyl-81(2H) furanone), 4,5-dihydroxy-2,5-dimethyl-4-oxo-8-furanylmethyl ester, 4,5-dihydroxy-2,5-dimethyl-4-oxo- 8-Furanyl ethyl ester, 2
-Cyclohexyl-5-methyl-8,F(2H) furanone, 4-acetyl-5-methyl-8-(2H) furanone, 2,5-dimethyl-8(2H) furanone, etc. Aggregation pheromone: 1-dimethylamino -2-methyl-2
-Propertool and its hydrochloride, Gi(10) salt, acetate, oxalate or stearin! salt, 1
- Amino-2-methyl-2-propatol, 1-diethylamino-2-methyl-2-propatol, 1-methylamino-2methyl-2-propatol, and other amine compounds, etc. Bepheromone: ( 8S, 4R, 6E, 10Z)-
8,4,7,11-tetramethyl-trideca-6,10
-genal, (Z)-9 hexadecenal, 2.5-
Dimethylpyrazine, 8-methyl-2,5-dimethylpyrazine, Z, E-α-furanesene, E, E-α-furanesene, etc. In addition, in the composition of the present invention, formulation auxiliaries, i.e. Adsorption carriers, fillers, binders, antioxidants, preservatives, ingestion prevention agents, coloring agents, and the like can be added. Specific examples of these formulation aids are shown below.
吸着担体二マット用基材(コツトンリンターとパルプと
の混合物のフィブリルを板状に固めたもの)等
増量剤ニジリカゲル、珪酸、珪礫土、カオリン、タルク
、クレー、高分散ケイ酸、ホワイトカーボン、ベントナ
イト、ゼオライト、セピオライト、アタパルジャイト等
結合剤:アイリッシモス、トラガントガム、カラヤガム
、カルボキシメチルセルロースナトリウム、メチルセル
ロース、ヒドロキシプロピルセルロース、タブ粉等
酸化防止剤:エリソルビン酸、エリソルビン酸ナトリウ
ム、ジブチルヒドロキシトルエン、dl−α−トコフェ
ロール、ノルジヒドログアイアレチン酩、メチルヒドロ
キシアニソール、没食子酸プロピル、グアヤク脂、L−
システィン塩酩塩、ブチルヒドロキシアニソール等保存
例二安息香酸、安息香酸ナトリウム、サリチル酩、ジフ
ェニル、ソルビンし、ソルビン除カリウム、デヒドロ酢
酸、デヒドロ酢酸ナトリウム、パラオキシ安息香酸イソ
ブチル、パラオキシ安息香酸イソプロピル、パラオキシ
安息香酸エチル、パラオキシ安素香酸ブチル、パラオキ
シ安息香酸プロピル、プロピオン酸カルシウム、プロピ
オン飯ナトリウム、2ヒドロキシジフエニル等
誤食防止剤:トウガラシ末、アマランス、アマランスア
ルミニウムレーキ、エリスロシン、エリスロシンアルミ
ニウムレーキ、ニューコクシン、フロキシン、ローズベ
ンガル、アシドレッド、タートラジン、タートラジンア
ルミニウムレーキ、サンセットイエローFCF。Substrate for adsorption carrier 2-mat (fibrils of a mixture of cotton linters and pulp solidified into a plate shape), etc.Extending agents Nijiri gel, silicic acid, quartzite earth, kaolin, talc, clay, highly dispersed silicic acid, white carbon, Bentonite, zeolite, sepiolite, attapulgite, etc. Binders: irissimus, gum tragacanth, gum karaya, sodium carboxymethylcellulose, methylcellulose, hydroxypropylcellulose, tab powder, etc. Antioxidants: erythorbic acid, sodium erythorbate, dibutylhydroxytoluene, dl-α-tocopherol , nordihydroguaiaretin, methylhydroxyanisole, propyl gallate, guaiac butter, L-
Cysteine salt, butylhydroxyanisole, etc. Preservation examples Dibenzoic acid, sodium benzoate, salicyl, diphenyl, sorbin, potassium sorbin removal, dehydroacetic acid, sodium dehydroacetate, isobutyl paraoxybenzoate, isopropyl paraoxybenzoate, paraoxybenzoate Ethyl acid, butyl paraoxybenzoate, propyl paraoxybenzoate, calcium propionate, sodium propionate, 2-hydroxydiphenyl, etc. Preventive agents: Capsicum powder, amaranth, amaranth aluminum lake, erythrosin, erythrosine aluminum lake, Newkoku Shin, Phloxin, Rose Bengal, Acid Red, Tartrazine, Tartrazine Aluminum Lake, Sunset Yellow FCF.
サンセットイエロー1i” CFアルミニウムレーキ、
ファストグリーンFCF、ファストグリーンFCFアル
ミニウムレーキ、ブリリアントブルーFCF、ブリリア
ントブルーFCFアルミニウムレーキ、インジゴカルミ
ン、インジゴカルミンアルミニウムレーキ、β−カロチ
ン、銅クロロフィル等
着色剤:リソールル♂ン、レーキレッド、リソールレッ
ド、ロータ重ン、テトラクロロテトラブロモフルオレセ
イン、ブリリアントレーキ(13)
レッド、ディープマルーン、トルイジンレッド、ヘリン
ドンピンク、ファストアシツドマゲン、パーマトンレッ
ド、エオシン、ビオラミン、ブリリアントファストスカ
ーレット、パーマネントレッド、オイルレッド、ファス
トレッド、アゾ染料、フタロシアニン染料、赤色1号等
さらに、本発明組成物においては、殺虫成分であるピリ
ジルピリドン誘導体をマイクロカプセル化して、毒餌中
に含有させることも可能である。Sunset Yellow 1i” CF Aluminum Lake,
Fast Green FCF, Fast Green FCF Aluminum Lake, Brilliant Blue FCF, Brilliant Blue FCF Aluminum Lake, Indigo Carmine, Indigo Carmine Aluminum Lake, β-Carotene, Copper Chlorophyll, etc. Colorants: Lysol Lune, Lake Red, Lysol Red, Rotor Heavy Tetrachlorotetrabromofluorescein, Brilliant Lake (13) Red, Deep Maroon, Toluidine Red, Herringdon Pink, Fast Acid Magen, Permaton Red, Eosin, Violamine, Brilliant Fast Scarlet, Permanent Red, Oil Red, Fast Red , azo dye, phthalocyanine dye, Red No. 1, etc.Furthermore, in the composition of the present invention, it is also possible to microcapsule the insecticidal component, pyridylpyridone derivative, and include it in the poisoned bait.
このようなマイクロカプセルの膜物質としては、たとえ
ばポリウレア、ポリウレタン、ボリア主ド、ポリエステ
ル、ポリカーボネート、ポリスルホネート、ポリスルホ
ンアミド、エポキシ樹脂等をあげることができる。また
マイクロカプセルの製造方法としては、界面重合法が好
ましい。また、マイクロカプセルの形態としては、平均
粒径が1〜1000Eクロン、(粒子径/膜厚)比が1
0〜140である場合が好ましい。Examples of membrane materials for such microcapsules include polyurea, polyurethane, boria-based resin, polyester, polycarbonate, polysulfonate, polysulfonamide, and epoxy resin. Moreover, as a method for producing microcapsules, an interfacial polymerization method is preferable. In addition, the morphology of the microcapsules is such that the average particle size is 1 to 1000 E croms and the (particle size/film thickness) ratio is 1.
It is preferably 0 to 140.
本発明組成物である毒餌中に含有させる諸成分(14) の構成比率はある範囲で変えることができる。Various components to be contained in the poison bait that is the composition of the present invention (14) The composition ratio of can be varied within a certain range.
1式[I]で示されるピリジルピリドン誘導体(殺虫成
分)の星は、001〜10重垣%の間、好ましくは0,
1〜5重丹%の間である。摂食誘引剤または喫食成分は
、10〜99.99重u%の間、好ましくは20〜99
.9重量%の間である。製剤用助剤(マイクロカプセル
膜物質を含む)lこついては、トータルでθ〜89.9
9%、好ましくは0〜79.9重に%である。1 The star of the pyridylpyridone derivative (insecticidal ingredient) represented by formula [I] is between 001 and 10%, preferably 0,
It is between 1% and 5%. The feeding attractant or edible ingredient is between 10 and 99.99% by weight, preferably between 20 and 99% by weight.
.. Between 9% and 9% by weight. Formulation auxiliaries (including microcapsule membrane materials) have a total of θ ~ 89.9
9%, preferably 0 to 79.9% by weight.
また、本発明組成物は、−1式[I]で示されるピリジ
ルピリドン誘導体以外にも、1種以上の殺虫剤または昆
虫成長調節剤等を配合することもできる。これらの殺虫
活性化合物の具体例としては、有機リン系殺虫剤:カル
ビンホス、クロルピリホス、クロルピリホスメチル、シ
アノフェンホス、シアノホス、ダイアジノン、ジクロル
ボス、フェニトロチオン、フェンチオン、マラチオン、
ナレド、ビリミホスメチル、プロチオホス、ピリダフェ
ンチオン、サリチオン、テトラクロルビ次ホス、トリク
ロルホン、ブロモホス、プロペタンホス、アザメチホス
等カーバメート系殺虫剤: B PMC,カルバリル、
CPMC,エチオフェンカーブ、MPMC。In addition to the pyridylpyridone derivative represented by Formula -1 [I], the composition of the present invention may also contain one or more insecticides or insect growth regulators. Specific examples of these insecticidal active compounds include organophosphorus insecticides: carbynphos, chlorpyrifos, chlorpyrifos-methyl, cyanofenphos, cyanophos, diazinon, dichlorvos, fenitrothion, fenthion, malathion,
Carbamate insecticides such as naled, virimiphos-methyl, prothiophos, pyridafenthione, salithion, tetrachlorbiphos, trichlorfon, bromophos, propetanphos, azamethyphos, etc.: B PMC, carbaryl,
CPMC, ethiophene carb, MPMC.
MTMC,プロメカルブ、スエップ、プロポキサ−等
ピレスロイド系殺虫剤ニジペルメトリン、シフエツトリ
ン、デルタメスリン、フェンプロパスリン、フェンバレ
レート、カブスリン、ペルメトリン、フエノトリン、フ
ラメスリン、レスメスリン、シフルスリン、トラロメス
リン、フルサイスリネート、サイハロスリン、テフルス
リン、ビンェンスリン、ペンフルスワン、エトフェンブ
ロックス等
幼若ホルモン型昆虫成長調節剤
メトプレン、ハイドロプレン、ビリプロキシフェン、フ
ェノキシカーブ等
キチン合成阻害型昆虫成長調節剤
ジンルベンズロン、トリフルムロン、テフルベンズロン
、クロルフルアズロン、フルフェノクスロン、ヘキサフ
ルロン、N−2,6−シフルオロペンゾイルーN−[2
−フルオロ−4−(1,1,2,2−テトラフルオロエ
トキシ)フェニル]泳素、N−2,6−シフルオロベン
ゾイルーN−2−フルオロ−4−トリフルオロメチルフ
ェニル尿素、シロマシン等
その他の殺虫剤
ホウ酸、ヒドラメチルノン、スルフルラ多ド、メトキサ
シアシン、エバーメスチン等
等があげられる。これらの殺虫活性化合物の毒餌中の構
成比率は0〜2重量%の間が好ましい。MTMC, promecarb, SWEP, propoxa, etc. Pyrethroid insecticides Nidipermethrin, sifuetthrin, deltamethrin, fenpropathrin, fenvalerate, cabsurin, permethrin, phenotrin, flamethrin, resmethrin, cyfluthrin, tralomethrin, flucythrinate, cyhalosthrin, tefluthrin, Juvenile hormone-type insect growth regulators such as Bingenthrin, Penfluswan, and Etofenbrox Methoprene, hydroprene, biriproxyfen, and phenoxycarb Insect growth regulators that inhibit chitin synthesis Zinlubenzuron, Triflumuron, Teflubenzuron, Chlorfluazuron, Flufenoxuron , hexafluron, N-2,6-cyfluoropenzoyl N-[2
-Fluoro-4-(1,1,2,2-tetrafluoroethoxy)phenyl] fluorine, N-2,6-cyfluorobenzoyl-N-2-fluoro-4-trifluoromethylphenylurea, cyromassin, etc. Insecticides such as boric acid, hydramethylnon, sulfurad, methoxacyacin, and evermestin are listed. The composition ratio of these insecticidal compounds in the poison bait is preferably between 0 and 2% by weight.
本発明組成物である毒餌の製法としては、大きく分けて
、含浸法と練り込み法の2通りある。There are two main methods for producing the poison bait that is the composition of the present invention: an impregnation method and a kneading method.
含浸法は、摂食誘引剤または喫食成分が固体であるとき
に限られる。このW1合、−1式CI]で示されるピリ
ジルピリドン誘導体は、あらかじめ有機溶剤に溶解する
かまたは乳剤、水和剤、フロアブル等に製剤されたもの
を水で希釈するかして、液状にしておく必要がある。こ
うしてできた殺虫液を、摂食誘引剤または摂食基剤に直
接含浸処理し、(17)
溶媒または水を蒸発させることにより、製剤ができる。Impregnation methods are limited to cases where the feeding attractant or edible ingredient is a solid. The pyridylpyridone derivative represented by the formula W1, -1 CI] can be made into a liquid by dissolving it in an organic solvent in advance or by diluting it with water after it has been formulated into an emulsion, wettable powder, flowable, etc. It is necessary to keep it. A preparation can be prepared by directly impregnating the insecticidal liquid thus produced into a feeding attractant or feeding base, and (17) evaporating the solvent or water.
練り込み法の場合は、−1式[I)で示されるピリジル
ピリドン肪導体才たはマイクロカプセル等に製剤された
ものを、少なくとも1種以上の摂食誘引剤または喫食成
分および適切ならば、化の製剤用助剤と攪拌しながら混
合し、必要ならばこの混合物を磨砕する。諸成分の混合
順序には特に制限はなく、混合には、ミキサー等を用い
ることかできる。混合物は、その昧ままき餌として使用
することもできるが、打錠成形し、任意の大きさの錠剤
とすることもできる。打錠成型の際の圧力は、通常、1
0〜2,000Kf/cIn の範囲である。また、
水と混合し、塗布剤の形にすることもできる。In the case of the kneading method, the pyridylpyridone fatty acid derivative represented by formula [I] or microcapsules or the like is mixed with at least one or more feeding inducer or edible ingredient and, if appropriate, Mix with agitating formulation aids and mill the mixture if necessary. There is no particular restriction on the order of mixing the various components, and a mixer or the like may be used for mixing. The mixture can be used as a raw bait, but it can also be compressed into tablets of any size. The pressure during tablet molding is usually 1
It is in the range of 0 to 2,000 Kf/cIn. Also,
It can also be mixed with water and made into a liniment.
このようにして出来上った本発明組成物は、そのまま毒
餌として、供試することもできるが、プラスチックや樹
脂製の容器内に封入し、容器に小さな出入口を設け、防
除対象となる害虫だけに摂食させることも可能である。The composition of the present invention thus obtained can be used as is as a poisonous bait, but it can be sealed in a container made of plastic or resin, with a small entrance and exit in the container, and only the pests to be controlled can be used. It is also possible to feed them.
本発明組成物は、害虫防除用毒餌として、卓越(18)
した摂食毒性を各種害虫に対し示すが、優れた効力を発
揮する防除対象虫の具体例としては、たとえば以下のも
のがあげられる。The composition of the present invention, as a poisonous bait for controlling pests, exhibits excellent (18) feeding toxicity against various pests. Specific examples of insects to be controlled that exhibit excellent efficacy include, for example, the following: .
網翅目害虫:チャバネゴキブリ、ヤマトゴキブリ、クロ
ゴキブリ、ワモンゴキブリ、トビイロゴキブリ、コバネ
ゴキブリ等のゴキブリ類等膜翅目害虫:ヒメアリ、クロ
ヤマアリ、トビイロシワアリ、オオズアカアリ、トビイ
ロケアリ、サムライアリ、イエシロアリ等のアリ類、オ
オハリアリ、並に胆匣ハ属等のハリアリ類、スズメバチ
類、アシナガバチ類等
等翅目害虫ニヤマドシロアリ、イエシロアリ等のシロア
リ類等
鞘翅目害虫:タバコシバンムシ、ジンサンシバンムシ等
のシバンムシ類、コクヌストモドキ、ヒラタコクヌスト
モドキ等のゴミムシダマシ類、ノコギリヒラタムシ、カ
クムネヒラタムシ等のヒラタムシ類等
双翅目害虫:イエバエ類、ショウシロバエ類等中でも、
本発明組成物が、害虫防除用毒餌組成物として、特に優
れた効力を発揮する防除対象虫は、各種ゴキブリ類、す
なわち網翅目害虫である。Hymenoptera pests: Cockroaches such as the German cockroach, Japanese cockroach, black cockroach, American cockroach, Japanese cockroach, Japanese cockroach, etc.Hymenoptera pests: Ants such as the Japanese cockroach, black wood ant, Japanese brown ant, Japanese black ant, Japanese black ant, Japanese black ant, samurai ant, Japanese termite, etc. , as well as Isoptera pests such as ants such as the genus Ilva, wasps, and paper wasps. Among Diptera pests, such as mealworms such as the white-spotted beetle;
The target insects to be controlled by the composition of the present invention, as a poison bait composition for controlling insect pests, are various cockroaches, that is, insects of the order Recipitate.
次に、−1式CI)で示されるピリジルピリドン誘導体
のいくつかを第1表に示す。Next, some of the pyridylpyridone derivatives represented by the formula -1 CI) are shown in Table 1.
第
表
〈実施例〉
以下、本発明を製剤例および試験例によりさらに詳しく
説明するが、本発明はこれらの例のみに限定されるもの
ではない。Table 1: Examples The present invention will be explained in more detail below using formulation examples and test examples, but the present invention is not limited to these examples.
まず、製剤例を示す。以下の例において、本発明組成物
の有効成分となる化合物は、第1表の化合物番号で示し
、部は重量部を示す。First, a formulation example will be shown. In the following examples, compounds serving as active ingredients of the compositions of the present invention are indicated by compound numbers in Table 1, and parts indicate parts by weight.
製剤例1
化合物(1)〜(8)の各々801ayをアセトン06
−中に俗解し、この溶液を、動物用固型飼料(飼育繁殖
用固型飼料CE−2、日本クレア株式会社商品名) −
片c8f)に均一に処理する。ついでアセトンを風乾し
、各々の1%毒餌を得る。Formulation Example 1 Each of compounds (1) to (8) 801ay was dissolved in acetone 06
- In general, this solution is added to solid feed for animals (solid feed for captive breeding CE-2, trade name of CLEA Japan Co., Ltd.) -
Process evenly on piece c8f). The acetone was then air-dried to obtain each 1% poisoned bait.
製剤例2
化合物(1)〜(8)の各々251vをアセトン0.5
−中に溶解し、この溶液を、動物用固型飼料粉末(飼育
繁殖用固型飼料粉末CE−2、日本夕レア株式会社商品
名)5fに処理し、均一に混合する。ついでアセトンを
風乾し、各々の05%毒餌を得る。Formulation Example 2 251v of each of compounds (1) to (8) was added to 0.5v of acetone.
- This solution is treated with solid feed powder for animals (solid feed powder for captive breeding CE-2, trade name of Nippon Yura Co., Ltd.) 5f and mixed uniformly. The acetone was then air-dried to obtain each 05% poisoned bait.
製剤例8
化合物(1)60部と高分散ケイ酸40部とを攪拌桶中
で撹拌混合する。この予備混合物0.84部をメチルセ
ルロース0.75部およびシ旨軸98.41部と室温で
混合し、ついでこの混合物を磨砕する(21)
ことにより、0.5%水分散性毒餌を得る。Formulation Example 8 60 parts of compound (1) and 40 parts of highly dispersed silicic acid are stirred and mixed in a stirring tank. A 0.5% water-dispersible poison bait is obtained by mixing 0.84 parts of this premix with 0.75 parts of methylcellulose and 98.41 parts of cornstarch at room temperature and then grinding the mixture (21). .
製剤例4
化合物(2)10部とリノール酸10部(純度65%)
との混合物を、透明溶液が得られるまで60℃で加熱す
る。この混合液に、大豆油80部を加え攪拌した後、室
温で冷却し、10%液状毒餌を得る。Formulation example 4 10 parts of compound (2) and 10 parts of linoleic acid (purity 65%)
The mixture is heated at 60° C. until a clear solution is obtained. 80 parts of soybean oil is added to this mixture, stirred, and then cooled to room temperature to obtain a 10% liquid poison bait.
製剤例5
化合物(8) 10 !とオレイン#h15部との混合
物を、透明溶液が得られるまで80℃で加熱する。Formulation Example 5 Compound (8) 10! and 15 parts of olein #h are heated at 80° C. until a clear solution is obtained.
この混合液に大豆油75部を加え、攪拌した後、室温で
冷却し、10%液状物餌を得る。75 parts of soybean oil is added to this mixed solution, stirred, and then cooled to room temperature to obtain a 10% liquid bait.
製剤例6
化合物(1)1部、シw 糖70部、サナギ粉27部お
よびヒドロキシメチルセルロース2部に、適おの水を加
え、均一に攪拌混合する。この混合物を造粒機で平均粒
径1.0■1に造粒した後、水分を乾燥し、1%粒状毒
餌を得る。Formulation Example 6 Add an appropriate amount of water to 1 part of compound (1), 70 parts of sugar, 27 parts of pupa flour, and 2 parts of hydroxymethyl cellulose, and stir and mix uniformly. This mixture is granulated using a granulator to an average particle size of 1.0 1, and then the moisture is dried to obtain a 1% granular poison bait.
製剤例7
化合物(8)1剖、ハチ疋ツ70部、オキアミ粒27(
22)
部およびヒドロキシメチルセルロース2部を均一に攪拌
混合する。この混合物を、造粒機で平均粒径1.5−に
造粒した後乾燥し、1%粒状毒餌を得る。Formulation Example 7 Compound (8) 1 dissection, 70 parts of honey, 27 krill grains (
22) and 2 parts of hydroxymethyl cellulose are uniformly mixed by stirring. This mixture is granulated using a granulator to an average particle size of 1.5 and then dried to obtain a 1% granular poison bait.
製剤例8
化合物(1) 0.5部とゴマ油8部とを混合し、これ
に黒砂11?5部、結晶セルロース80部、ジャガイモ
テンフン61.87部、ブチルヒドロキシアニソ径80
■)に打鍵成形し、05%毒餌を得る。Formulation Example 8 Mix 0.5 parts of compound (1) and 8 parts of sesame oil, add 11-5 parts of black sand, 80 parts of crystalline cellulose, 61.87 parts of potato starch, and butyl hydroxyaniso diameter 80
■) Press the key to obtain 05% poison bait.
製剤例9
化合物(8) 0.8部とコーン油5部とを混合し、こ
れに三温糖22部、結晶セルロース85部、トウモロコ
シデンプン81.58部、ノルジヒドログアイアレチン
酸0.02部、デヒドロ酢酸0.1部、フラネオール(
4−ヒドロキシ−2,5−ジメチル毒餌を得る。Formulation Example 9 Mix 0.8 parts of compound (8) and 5 parts of corn oil, and add 22 parts of brown sugar, 85 parts of crystalline cellulose, 81.58 parts of corn starch, and 0.02 parts of nordihydroguaiaretic acid. part, dehydroacetic acid 0.1 part, furaneol (
Obtain 4-hydroxy-2,5-dimethyl poison bait.
製剤例10
化合物(1)〜(8)の各々80ダをアセトン0.84
中に溶解し、この溶液を、脱脂粉乳22とグラニユー糖
IPとの混合物に処理し、各−に混合する。Formulation Example 10 80 da each of compounds (1) to (8) was added to 0.84 dah of acetone.
This solution is processed into a mixture of skimmed milk powder 22 and granulated sugar IP and mixed into each.
ついでアセトンを風乾し、1%毒餌を得る。Then air dry the acetone to obtain 1% poisoned bait.
製剤例11
化合物(1)〜(8)の各々101vをアセトン1−中
に溶解し、この溶液をグラニユー糖10Fに処理し、均
一に混合する。ついでアセトンを風乾し、01%毒餌を
得る。Formulation Example 11 101v of each of compounds (1) to (8) is dissolved in acetone 1-1, and this solution is treated with granulated sugar 10F and mixed uniformly. Then, air dry the acetone to obtain 01% poison bait.
製剤例12
化合物(1)〜(8)の各々2部、デキストリン94.
9部、デヒドロ酢酸0.1部およびフラネオール(4−
ヒドロキシ−2,5−ジメチル−8(2H)フラノン)
8部を均一に混合する。この混合物に、1511/cn
4の圧力をかけ、1錠約4f(直径8゜寵)に打錠成型
し、各々の2%毒餌を得る。Formulation Example 12 2 parts each of compounds (1) to (8), 94% dextrin.
9 parts, 0.1 part of dehydroacetic acid and furaneol (4-
hydroxy-2,5-dimethyl-8(2H) furanone)
Mix 8 parts evenly. To this mixture, add 1511/cn
A pressure of 4 degrees is applied, and each tablet is compressed into approximately 4 f (diameter: 8 degrees) to obtain 2% poison bait of each type.
製剤例1B
ポリウレタンを膜物質に用いてマイクロカプセル化した
化合物(1)〜(8)の各々5部、デキストリン94.
9部およびデヒドロ酢酸0,1部を均一に混合する。こ
の混合物に15Kf/m”の圧力をかけ、1錠約4f(
直径80−)に打錠成型し、各々の5%毒餌を得る。Formulation Example 1B 5 parts each of Compounds (1) to (8) microencapsulated using polyurethane as a membrane material, 94 parts of dextrin.
9 parts and 0.1 part of dehydroacetic acid are mixed uniformly. A pressure of 15 Kf/m was applied to this mixture, and each tablet was approximately 4 f/m (
The pellets were compressed into tablets with a diameter of 80 mm to obtain 5% poisoned bait.
製剤例14
化合物(1)〜(8)の各々1部、ゴマ油8部、デキス
トリン66部および乾燥酵母(エビオス)粉末80部を
均一に混合する。この混合物に% I 、 000h/
all’の圧力をかけ、1flE約52C泊径80m)
に打錠成形し、各々の1%毒餌を得る。Formulation Example 14 1 part of each of compounds (1) to (8), 8 parts of sesame oil, 66 parts of dextrin, and 80 parts of dried yeast (Ebios) powder are uniformly mixed. This mixture contains %I, 000h/
Apply pressure of all', 1flE approx. 52C, diameter 80m)
The mixture was compressed into tablets to obtain 1% poison bait.
製剤例15
ショ糖50Mgおよび粉ミルク50w9を水1−に溶解
し、2.5鋼×1.5副、厚さ0.28傷、重さ0.7
5Fのマット用基材(コツトンリンターとバルブとの混
合物のフィブリルを板状に固めたもの)に含浸し、風乾
させる。化合物(1)〜(8)の各々10■をアセトン
1艷に溶解し、これを上記のマットに均一に含浸させた
後風乾し、各々の毒餌を得る。Formulation Example 15 50 Mg of sucrose and 50 w9 of powdered milk were dissolved in 1-1 of water, 2.5 steel x 1.5 parts, thickness 0.28 scratches, weight 0.7
A 5F mat base material (fibrils of a mixture of cotton linters and bulbs solidified into a plate shape) is impregnated and air-dried. 10 μm of each of Compounds (1) to (8) was dissolved in one bottle of acetone, and the above mat was uniformly impregnated with this solution, and then air-dried to obtain each poison bait.
製剤例16
(25)
オキアミ粉40部、ショ糖40部、デキストリン10部
およびビーナツツ油10部を均一に攪拌混合し、この混
合物を造粒機で平均粒径0.7■に造粒する。化合物(
1)〜(8)の各々80qをアセトン0、1 rnlに
溶解し、これを上記の粒状餌0.8fに均一に処理した
後脚乾し、各々の1%毒餌を得る。Formulation Example 16 (25) 40 parts of krill powder, 40 parts of sucrose, 10 parts of dextrin, and 10 parts of peanut oil are uniformly stirred and mixed, and this mixture is granulated using a granulator to an average particle size of 0.7 square meters. Compound(
Dissolve 80q of each of 1) to (8) in 0.1 rnl of acetone, apply this uniformly to 0.8f of the above granular bait, and dry the hind legs to obtain 1% poisoned bait for each.
次に、試験例を示す。以下の例において、化合物は第1
表の化合物番号で示し、比較対照に用いた化合物は第2
表の化合物記号で示す。Next, a test example will be shown. In the examples below, the compound is the first
The compound number shown in the table is the compound used for comparison.
Indicated by compound symbol in the table.
(26)
第
2
表
化合物記号
構
造
式
()
製剤例2に準じて得られた毒餌(ただし、有効成分濃度
は、0.1%)および比較対照化合物の同一処方0.1
%毒餌を用いて、以下の試験を行なった。(26) Table 2 Compound symbol Structural formula () Poison bait obtained according to Formulation Example 2 (however, the active ingredient concentration is 0.1%) and the same formulation of the comparative compound 0.1
The following test was conducted using % poison bait.
ポリエチレンカップ(凶径12!、 高さ7(7))の
中に、殺虫剤低感受性系統のチャバネゴキブリ成虫20
頭(雄雌各10頭)を放飼し、上記の毒ID41fおよ
び同一処方の無処理111419を、それぞれ別のプラ
スチック製キャップ(直径3 cm 1高さ2cnI)
に入れて与え、P紙製シェルタ−(3cm X4、5
crn、高さl cm )および給水源を置き、25℃
で保持した。放@2週間後および8週間後に、供第
表
試験例2
製剤例11によって得られた0、1%毒餌および比較対
照化合物の同一処方0.1%毒餌を用1.1で、以下の
試験を行なった。In a polyethylene cup (diameter 12!, height 7 (7)), there were 20 adult German cockroaches of a insecticide-insensitive strain.
The heads (10 males and 10 females) were released, and the above poison ID 41f and the same prescription untreated 111419 were added to each with separate plastic caps (diameter 3 cm 1 height 2 cnI).
Put it in a P paper shelter (3cm x 4, 5
crn, height l cm) and a water source at 25 °C.
It was held at After 2 weeks and 8 weeks of release, the following test was carried out using 0.1% poisoned bait obtained from Test Example 2 Formulation Example 11 and 0.1% poisoned bait with the same formulation of the comparative control compound in Table 1.1. I did this.
ポリエチレンカップ(直径9.5m、高さ4.5 cI
n)の中に、クロヤマアリ成虫10頭を放飼し、プラス
チック製キャップ(直径26n、高さ1釧)に入(29
)
れた上記毒餌0.8fおよび給水源を置いた。放飼2日
後に生死を調査し、死出率を求めた(2反復)。Polyethylene cup (diameter 9.5 m, height 4.5 cI
10 adult black wood ants were released in a plastic cap (diameter 26n, height 1) (29mm).
0.8f of the above poisoned bait and a water source were placed. Two days after release, the animals were examined for survival and death, and the mortality rate was determined (2 repetitions).
結果を第4表に示す。The results are shown in Table 4.
第 4 表
試験例8
製剤例10によって得られた1%毒餌および比較対照化
合物の同一処方1%毒餌を用いて、以下の試験を行なっ
た。Table 4 Test Example 8 The following test was conducted using the 1% poisoned bait obtained in Formulation Example 10 and the 1% poisoned bait with the same formulation of the comparative compound.
ポリエチレンカップ(直径12crn、高さ7備)(8
0)
の中に、ピレスロイド低感受性イエバエ桶20頭、ポリ
エチレン製カップ(直径8.5cfR1高さ2.56n
)に入れた上記毒餌12および給水源を置き、25℃で
保持した。羽化2日後にイエバエの生死を調査し、死出
率を求めた(2反復)。Polyethylene cup (diameter 12 crn, height 7) (8
0) Contains 20 pyrethroid-insensitive housefly buckets and a polyethylene cup (diameter 8.5cfR1 height 2.56n).
) and the above-mentioned poison bait 12 and a water source were placed in the container and maintained at 25°C. Two days after emergence, the house flies were examined for survival and death rate was determined (two repetitions).
結果を第5表に示す。The results are shown in Table 5.
第5表
試験例4
製剤例14に準じて得られた1%毒餌および比較対照化
合物の同一処方1%毒餌を用いて、以下の試験を行なっ
た。Table 5 Test Example 4 The following test was conducted using a 1% poisoned bait obtained according to Formulation Example 14 and a 1% poisoned bait with the same formulation of a comparative control compound.
ポリスチレン製コンテナ(61(7)×40ctn1高
さ14.l)m)の中に、クロゴキブリ雄成虫20頭を
放飼し、上舵の毒餌1におよび同一処方の無処理濯餌1
錠(各52)を、それぞれ別のアルミ皿(直径4.5
cm X高さ1crn)に入れ、コンテナの2隅に対角
に誼いて与えた。そして木製シェルタ−8後に、供試虫
の生死を調査し、死出率を求めた。Twenty male black cockroaches were released in a polystyrene container (61 (7) x 40 ctn, height 14.1 m), and 1 poisonous bait for the upper rudder and 1 untreated rinse bait of the same formulation were placed.
Locks (52 each) were placed in separate aluminum plates (diameter 4.5
cm x height 1 crn) and diagonally diagonally placed in two corners of the container. After 8 hours in the wooden shelter, the test insects were examined to see if they were alive or dead, and the mortality rate was determined.
結果を第6表鉦ζ示す。The results are shown in Table 6.
第 6 表
〈発明の効果〉 、う本発明
の害虫防除用毒餌組成物は、網翅目栽虫、膜翅目害虫、
双翅目害虫をはじめ、各種の害虫に対して有効であり、
その中でも特に網翅目害虫に対して有効である。Table 6 <Effects of the Invention> The poison bait composition for pest control of the present invention can be used to control insect pests of the order Apiptera, pests of the order Hymenoptera,
Effective against various pests including Diptera pests,
Among them, it is particularly effective against insect pests of the order Apiptera.
(83完)(83 completed)
Claims (11)
塩素原子またはシアノ基を表わす。)で示されるピリジ
ルピリドン誘導体を有効成分として含有することを特徴
とする害虫防除用毒餌組成物。(1) General formula ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (In the formula, X represents a fluorine atom or a chlorine atom, and Z represents a chlorine atom or a cyano group.) The pyridylpyridone derivative represented by the following is used as an active ingredient. A poisonous bait composition for controlling pests, characterized by comprising:
ある請求項1記載の害虫防除用毒餌組成物。(2) The poison bait composition for pest control according to claim 1, wherein in the general formula according to claim 1, X is a chlorine atom.
もに塩素原子である請求項1記載の害虫防除用毒餌組成
物。(3) The poison bait composition for pest control according to claim 1, wherein in the general formula according to claim 1, both X and Z are chlorine atoms.
が、0.01〜10重量%の範囲にある請求項1記載の
害虫防除用毒餌組成物。(4) The poison bait composition for pest control according to claim 1, wherein the content of the pyridylpyridone derivative according to claim 1 is in the range of 0.01 to 10% by weight.
が、0.1〜5重量%の範囲にある請求項1記載の害虫
防除用毒餌組成物。(5) The poison bait composition for pest control according to claim 1, wherein the content of the pyridylpyridone derivative according to claim 1 is in the range of 0.1 to 5% by weight.
を含有する請求項1記載の害虫防除用毒餌組成物。(6) The poison bait composition for pest control according to claim 1, which contains at least one kind of feeding attractant or edible ingredient.
が0.01〜10重量%、摂食誘引剤または喫食成分の
含有量が、10〜99.99重量%の範囲にある請求項
1記載の害虫防除用毒餌組成物。(7) The content of the pyridylpyridone derivative according to claim 1 is in the range of 0.01 to 10% by weight, and the content of the feeding attractant or the edible ingredient is in the range of 10 to 99.99% by weight. Poison bait composition for pest control.
が0.1〜5重量%、摂食誘引剤または喫食成分の含有
量が、20〜99.9重量%の範囲にある請求項1記載
の害虫防除用毒餌組成物。(8) Claim 1, wherein the content of the pyridylpyridone derivative according to Claim 1 is in the range of 0.1 to 5% by weight, and the content of the feeding attractant or edible ingredient is in the range of 20 to 99.9% by weight. Poison bait composition for pest control.
分として含有することを特徴とするゴキブリ防除用毒餌
組成物。(9) A poison bait composition for controlling cockroaches, comprising the pyridylpyridone derivative according to claim 1 as an active ingredient.
害虫防除方法。(10) A method for controlling pests using the poison bait composition for controlling pests according to claim 1.
ゴキブリ防除方法。(11) A method for controlling cockroaches using the poison bait composition for controlling pests according to claim 1.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP31935390A JPH03232804A (en) | 1989-12-01 | 1990-11-21 | Poison bait composition for controlling insect pest |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP31373889 | 1989-12-01 | ||
JP1-313738 | 1989-12-01 | ||
JP31935390A JPH03232804A (en) | 1989-12-01 | 1990-11-21 | Poison bait composition for controlling insect pest |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH03232804A true JPH03232804A (en) | 1991-10-16 |
Family
ID=26567687
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP31935390A Pending JPH03232804A (en) | 1989-12-01 | 1990-11-21 | Poison bait composition for controlling insect pest |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH03232804A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5582721A (en) * | 1993-02-26 | 1996-12-10 | Mitsubishi Chemical Corporation | Apparatus for separating a liquid mixture |
JP2007500159A (en) * | 2003-07-29 | 2007-01-11 | ノバルティス アクチエンゲゼルシャフト | Organic mixture |
WO2009116594A1 (en) * | 2008-03-19 | 2009-09-24 | ライオン株式会社 | Bait for mosquito |
JP2020111517A (en) * | 2019-01-08 | 2020-07-27 | 昭和産業株式会社 | Insect attractant and its production method |
-
1990
- 1990-11-21 JP JP31935390A patent/JPH03232804A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5582721A (en) * | 1993-02-26 | 1996-12-10 | Mitsubishi Chemical Corporation | Apparatus for separating a liquid mixture |
JP2007500159A (en) * | 2003-07-29 | 2007-01-11 | ノバルティス アクチエンゲゼルシャフト | Organic mixture |
WO2009116594A1 (en) * | 2008-03-19 | 2009-09-24 | ライオン株式会社 | Bait for mosquito |
JP5422551B2 (en) * | 2008-03-19 | 2014-02-19 | ライオン株式会社 | Mosquito bait and mosquito control equipment |
JP2020111517A (en) * | 2019-01-08 | 2020-07-27 | 昭和産業株式会社 | Insect attractant and its production method |
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