JPH03224951A - High weather proof metal ricin plate - Google Patents
High weather proof metal ricin plateInfo
- Publication number
- JPH03224951A JPH03224951A JP2099690A JP2099690A JPH03224951A JP H03224951 A JPH03224951 A JP H03224951A JP 2099690 A JP2099690 A JP 2099690A JP 2099690 A JP2099690 A JP 2099690A JP H03224951 A JPH03224951 A JP H03224951A
- Authority
- JP
- Japan
- Prior art keywords
- aggregate
- plate
- ricin
- adhesive layer
- pattern
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 13
- 239000002184 metal Substances 0.000 title claims abstract description 13
- 108010039491 Ricin Proteins 0.000 title claims description 12
- 239000012790 adhesive layer Substances 0.000 claims abstract description 12
- 239000003973 paint Substances 0.000 claims abstract description 11
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 5
- 239000011737 fluorine Substances 0.000 claims description 5
- 229910052731 fluorine Inorganic materials 0.000 claims description 5
- 239000000463 material Substances 0.000 abstract description 10
- 239000011248 coating agent Substances 0.000 abstract description 7
- 238000000576 coating method Methods 0.000 abstract description 7
- 229910000831 Steel Inorganic materials 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- 239000004925 Acrylic resin Substances 0.000 description 4
- 229920000178 Acrylic resin Polymers 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 4
- 239000004472 Lysine Substances 0.000 description 4
- 239000005002 finish coating Substances 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 229920005749 polyurethane resin Polymers 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical class FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- 239000004923 Acrylic lacquer Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007739 conversion coating Methods 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Finishing Walls (AREA)
- Laminated Bodies (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は金属薄板の少なくとも化粧面にリシン塗膜を形
成した屋根材、外壁材等の建材に有用な高耐候性金属リ
シン仮に関するものである。[Detailed Description of the Invention] [Field of Industrial Application] The present invention relates to a highly weather-resistant metallic lysine material useful for building materials such as roofing materials and exterior wall materials in which a lysine coating film is formed on at least the decorative surface of a thin metal sheet. be.
一般に金属板にリシンを形成する方法、またはその板材
として特開昭５０−１７４８８号公報、特開昭５２１４
１８４６号公報、および特開昭５４−１２７９３４号公
報等が知られている。Generally, a method of forming ricin on a metal plate or its plate material is disclosed in JP-A-50-17488 and JP-A-5214.
No. 1846, Japanese Patent Application Laid-Open No. 127934/1980, and the like are known.
しかしながら、この種リシン鋼板においては、■金属薄
板にポリエステル樹脂、アクリル樹脂、アルキッド樹脂
等を接着剤兼塗膜として使用していたため耐候性が約３
〜５年とあまり長くない。However, in this type of ricin steel sheet, the weather resistance is about 3.
~5 years is not that long.
■ポリウレタン樹脂、ポリエステル樹脂等のビヒクルは
色の劣化が速い。■ベースコートとオーバコートとの相
様性があり、樹脂の選択には容易となるが、耐候性に欠
ける。■リシン塗装では骨材がピンホールの一因ともな
るので塗膜の粘度を低くし、より濡れをよくする必要が
あり、その分、塗膜厚が薄く、下地、骨材の色彩により
化粧面の色彩が変わる。等の不利があった。■Vehicles such as polyurethane resin and polyester resin deteriorate quickly in color. ■The base coat and overcoat are compatible, making it easy to select the resin, but it lacks weather resistance. ■In ricin painting, the aggregate contributes to pinholes, so it is necessary to lower the viscosity of the coating film and improve wetting. The color of changes. There were disadvantages such as
本発明はこのような欠点を除去するため、金属板の凹部
模様にのみ骨材を接着剤で確実に固着し、全化粧面に対
しフッソ塗料を塗布してピンホールのない、かつ耐候性
、耐汚染性にすぐれ、しかも骨材の剥落の全くない高耐
候性金属リシン板を提案するものである。In order to eliminate these drawbacks, the present invention securely adheres the aggregate only to the concave pattern of the metal plate with adhesive, and coats the entire decorative surface with fluorine paint to create a pinhole-free, weather-resistant, The present invention proposes a highly weather-resistant metal ricin board that has excellent stain resistance and no aggregate flaking.
以下に、凹面を用いて本発明に係る高耐候性金属リシン
板（以下、単にリシン板という）の一実施例について詳
細に説明する。第１図は上記リシン板の断面の一部を示
す説明図であり、上はりシン板で基材２の化粧面５の凹
部模様２ａにのみ接着剤層３を塗布、被着し、その凹部
模様２ａにのみ骨材４が散在、高密度等の任意状態で固
定すると共に、骨材４を含む全化粧面５に仕上げ塗膜６
を塗布し、全化粧面５を被覆し、一体化したりシン板上
である。さらに説明すると、基材２はステンレス板、ア
ルミニウム板、亜鉛鉄板、カラー鋼板、チタン板等のエ
ンボス加工板からなるものであり、好ましくはカラー鋼
板がコスト、耐候性を総合すると最も望ましく、例えば
その断面を例示すると第２図に示す構成となり、第３図
に示すように形成したものである。すなわち、基材２は
芯材として鉄イ、亜鉛メツキロ、化成処理被膜ハ、下塗
り層二、上塗り層ホとしたものである。その際、上塗り
層ホは接着剤層３と相様性、密着性のよい塗膜とするこ
とが好ましい。勿論、この際、焼付が不完全（焼あま）
であれば接着剤層３、仕上げ塗膜６を焼付けするときと
同時に一体化してより密着度が向上するものである。接
着剤層３はアクリル樹脂、エポキシ樹脂、ポリウレタン
樹脂のように接着剤として有用な成分をビヒクルとする
塗料であり、かつ最終的には化粧面５の凹部模様２ａに
のみ存在し、未硬化のうちに骨材４を散布するものであ
る。勿論、骨材４を散布する際は化粧面５の凸部模様２
ｂには接着剤層３が存在しない状態である。骨材４は珪
砂、岩石、鉱物粉、ゼオライト、パーライト、バーミキ
ュライト、アルミナ、シラスバルーン、ガラス粉、金属
粉、セラミック粒の１種以上からなり、その大きさは約
１〜２５０メツシユ位である。なお、骨材４は仕上げ塗
膜６との関係で仕上げ塗膜６と相様性のよい成分でコー
テング、もしくは処理されていることがより好ましく、
例えばシランカップリング剤、活性剤で処理された直後
に散布すること等である。さらに、仕上げ塗膜６は全化
粧面５を被覆するものであり、その組成としては、例え
ばアクリル樹脂、アクリルラッカー、アクリルウレタン
、あるいはポリエステル樹脂とビスフェノールＡのエチ
レンオキサイド付加物、直鎮高分子ポリエステル樹脂、
ポリオレフィン類、エポキシ樹脂、フルオロオレフィン
ビニール系モノマー共重合体とアクリル（メタ）アクリ
レートを８５％以上を含むアクリル樹脂を２０〜６０重
量部、顔料、及び硬化剤を配合した塗料等の１種以上か
らなるものであり、約１０〜１００ミクロン（ウェット
）位の厚さである。フッソ樹脂としては（略称） ＰＴ
ＦＥ、 Ｆｌ！Ｐ 、、ＰＦ＾、ＥＰＥ 、 ＰＣＴＦ
Ｅ 。An embodiment of the highly weather resistant metal ricin plate (hereinafter simply referred to as ricin plate) according to the present invention will be described in detail below using a concave surface. FIG. 1 is an explanatory diagram showing a part of the cross section of the above-mentioned lysine board, in which the adhesive layer 3 is applied and adhered only to the concave pattern 2a of the decorative surface 5 of the base material 2 with the top lysine board. The aggregate 4 is scattered only on the pattern 2a, fixed in any desired state such as high density, etc., and a finishing coat 6 is applied to the entire decorative surface 5 including the aggregate 4.
is applied to cover the entire decorative surface 5 and integrated or on a thin board. To explain further, the base material 2 is made of an embossed plate such as a stainless steel plate, an aluminum plate, a galvanized iron plate, a colored steel plate, a titanium plate, etc. Preferably, a colored steel plate is the most desirable in terms of cost and weather resistance. An example of a cross section is the configuration shown in FIG. 2, which is formed as shown in FIG. 3. That is, the base material 2 has iron (a) as a core material, zinc metal (a), a chemical conversion coating (c), an undercoat layer (ii), and a topcoat layer (e). In this case, it is preferable that the top coat layer (E) be a coating film that has good compatibility and adhesion with the adhesive layer 3. Of course, at this time, the baking may be incomplete (baked).
If so, the adhesive layer 3 and the finish coating film 6 are integrated at the same time as baking, thereby further improving the degree of adhesion. The adhesive layer 3 is a paint whose vehicle is a component useful as an adhesive, such as acrylic resin, epoxy resin, or polyurethane resin, and ultimately exists only in the concave pattern 2a of the decorative surface 5, and is an uncured paint. This is to scatter aggregate 4 inside the house. Of course, when dispersing the aggregate 4, the convex pattern 2 on the decorative surface 5
In b, the adhesive layer 3 is not present. The aggregate 4 is made of one or more of silica sand, rock, mineral powder, zeolite, perlite, vermiculite, alumina, shirasu balloon, glass powder, metal powder, and ceramic particles, and has a size of about 1 to 250 mesh. In addition, it is more preferable that the aggregate 4 is coated or treated with a component that is compatible with the finish coating film 6 in relation to the finish coating film 6.
For example, spraying may be performed immediately after treatment with a silane coupling agent or activator. Furthermore, the finishing coating film 6 covers the entire decorative surface 5, and its composition includes, for example, acrylic resin, acrylic lacquer, acrylic urethane, ethylene oxide adduct of polyester resin and bisphenol A, or straight-set polymeric polyester. resin,
One or more of polyolefins, epoxy resins, fluoroolefin vinyl monomer copolymers, and paints containing 20 to 60 parts by weight of acrylic resins containing 85% or more of acrylic (meth)acrylate, pigments, and curing agents. The thickness is about 10 to 100 microns (wet). Fluorine resin (abbreviation) PT
FE, Fl! P,,PF^,EPE,PCTF
E.
ＰＶＤＦ、 ＥＴＦＥ、 ＰＶＦ等をビヒクルの約１０
〜５０％位を含有するものである。具体的な一例を示せ
ば、■フルオロオレフィンービニル系モノマー共重合体
８０〜４０重量部と炭素数２〜５で分子量が１５，００
０〜４０．０００のアルキル（メタ）アクリレートを８
５％以上を含むアクリル樹脂を２０〜６０重量部、顔料
、及び硬化剤を配合した組成の塗料、アクリル変性フッ
化ビニリデン樹脂を主成分とし、これに紫外線吸収剤を
添加した塗料等であって、塗布時の粘度は３０〜５００
ＣＰＳ位である。ここで、エポキシ樹脂を接着剤層３と
してカラー鋼板よりなる基材２上の凹部模様２ａにのみ
形成し、この化粧面５に骨材４（２８〜３２メツシユ）
を平均に散布し、その上に前記した■の塗料を仕上げ塗
膜６として塗布し、約２００〜２５０°Ｃに焼成した試
験体（実施例）と、カラー鋼板と同じ塗料で接着剤層３
、仕上げ塗膜６を形成した試験体（比較例）とを準備し
、性能を比較すると下表のようになる。PVDF, ETFE, PVF etc. as vehicle
It contains about 50%. To give a specific example, (1) 80 to 40 parts by weight of a fluoroolefin-vinyl monomer copolymer, a carbon number of 2 to 5, and a molecular weight of 15,000.
0 to 40.000 alkyl (meth)acrylate 8
Paints with compositions containing 20 to 60 parts by weight of acrylic resin containing 5% or more, pigments, and curing agents, paints with acrylic-modified vinylidene fluoride resin as the main component and an ultraviolet absorber added thereto, etc. , the viscosity during application is 30-500
It is ranked CPS. Here, an epoxy resin is formed as an adhesive layer 3 only on the concave pattern 2a on the base material 2 made of a colored steel plate, and an aggregate 4 (28 to 32 meshes) is applied to this decorative surface 5.
A test piece (example) was prepared by spraying the above-mentioned paint (2) on it as a finishing coat 6 and baking it at about 200-250°C, and an adhesive layer 3 with the same paint as the colored steel plate.
, and a test specimen (comparative example) on which the finish coating film 6 was formed were prepared, and the performance was compared as shown in the table below.
◎ −〇 −Δ −不良
ただし、■は６０’鏡面反射率、■マジックインク除去
性、■焼付後の鉛筆硬度、■ゴバンの目セロテープ剥離
テスト （ただし、骨材４は別途）、０１０００時間、
■サンシャインウェザ−メーター照射３０００ ｈ ０
以上、説明したのは本発明の一実施例にすぎず、例えば
第４Ｅ（ａ）〜（ｕ）、および第５図（ａ）〜に）に示
す断面のサンドインチ板を形成することもできる。◎ -〇 -Δ -Poor However, ■ is 60' specular reflectance, ■ Magic ink removability, ■ Pencil hardness after baking, ■ Goban eye Cellotape peeling test (however, aggregate 4 is separate), 01000 hours,
■Sunshine weather meter irradiation 3000 h 0 What has been described above is only one embodiment of the present invention, and for example, the cross sections shown in Sections 4E(a) to (u) and FIGS. It is also possible to form a sandwich board.
上述したように、本発明に係るリシン板によれば、■凸
部模様と凹部模様の乱反射面とのコントラストにより立
体感が助長される。■骨材の剥落がない。■耐候性、耐
汚染性がよい。■フッソの接水性により防カビ性にすぐ
れる。■フッソ塗膜と骨材の一体化が図れる。等の特徴
、効果がある。As described above, according to the ricin board according to the present invention, the three-dimensional effect is enhanced by the contrast between the diffused reflection surface of the convex pattern and the concave pattern. ■No flaking of aggregate. ■Good weather resistance and stain resistance. ■Excellent anti-mold properties due to the water contact properties of fluorine. ■The fluorine coating film and aggregate can be integrated. It has the following characteristics and effects.
第１図は本発明に係る高耐候性金属リシン板の一部を拡
大して示す説明図、第２図は上記板体をさらに抽出拡大
して示す説明図、第３図、第４図（ａ）〜（１１）、お
よび第５図（ａ）〜に）は上記リシン板を使用した建材
の一例を示す断面図である。
■・・・高耐候性金属リシン板、２・・・基材、３・・
・接着剤層、４・・・骨材、６・・・仕上げ塗膜。
第
Ｓ
図
（α）
パ′ う゛
クーーーー＝−−−コ
第
図
＜９ｒFIG. 1 is an explanatory diagram showing an enlarged part of the highly weather-resistant metal ricin plate according to the present invention, FIG. 2 is an explanatory diagram showing a further enlarged extraction of the plate, FIGS. a) to (11) and FIGS. 5(a) to 5) are cross-sectional views showing an example of a building material using the above-mentioned ricin board. ■... Highly weather resistant metal ricin plate, 2... Base material, 3...
・Adhesive layer, 4... aggregate, 6... finishing coating film. FIG.
Claims (1)
の凹部模様にのみ接着剤層を介在して骨材を固着し、該
全化粧面をフッソ塗料からなる仕上げ塗膜で被覆し一体
化したことを特徴とする高耐候性金属リシン板。(1) A random pattern of unevenness is added to the decorative surface. Aggregate is fixed with an adhesive layer interposed only in the concave pattern of the decorative surface, and the entire decorative surface is covered with a finishing film made of fluorine paint and integrated. Highly weather resistant metal ricin plate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2099690A JPH03224951A (en) | 1990-01-30 | 1990-01-30 | High weather proof metal ricin plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2099690A JPH03224951A (en) | 1990-01-30 | 1990-01-30 | High weather proof metal ricin plate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03224951A true JPH03224951A (en) | 1991-10-03 |
Family
ID=12042729
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2099690A Pending JPH03224951A (en) | 1990-01-30 | 1990-01-30 | High weather proof metal ricin plate |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03224951A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06108606A (en) * | 1992-09-30 | 1994-04-19 | Natl House Ind Co Ltd | Finishing structure for external facing |
| WO2015063274A1 (en) * | 2013-10-31 | 2015-05-07 | Umicore Building Products France | Patterned rolled zinc alloy sheet |
| JP2017177683A (en) * | 2016-03-31 | 2017-10-05 | 日揮触媒化成株式会社 | Base material with water-repellent coating film and method for producing the same |
-
1990
- 1990-01-30 JP JP2099690A patent/JPH03224951A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06108606A (en) * | 1992-09-30 | 1994-04-19 | Natl House Ind Co Ltd | Finishing structure for external facing |
| WO2015063274A1 (en) * | 2013-10-31 | 2015-05-07 | Umicore Building Products France | Patterned rolled zinc alloy sheet |
| KR20160082532A (en) * | 2013-10-31 | 2016-07-08 | 유미코르 빌딩 프로덕츠 프랑스 쏘시에떼 파르 액티온스 심플리피에 | Patterned rolled zinc alloy sheet |
| US10494812B2 (en) | 2013-10-31 | 2019-12-03 | Umicore Building Products France | Patterned rolled zinc alloy sheet |
| JP2017177683A (en) * | 2016-03-31 | 2017-10-05 | 日揮触媒化成株式会社 | Base material with water-repellent coating film and method for producing the same |
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