JPH03212500A - Detergent composition for metal surface - Google Patents
Detergent composition for metal surfaceInfo
- Publication number
- JPH03212500A JPH03212500A JP710990A JP710990A JPH03212500A JP H03212500 A JPH03212500 A JP H03212500A JP 710990 A JP710990 A JP 710990A JP 710990 A JP710990 A JP 710990A JP H03212500 A JPH03212500 A JP H03212500A
- Authority
- JP
- Japan
- Prior art keywords
- limonene
- metal surfaces
- cleaning composition
- terpenic
- cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 23
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 20
- 239000002184 metal Substances 0.000 title claims abstract description 20
- 239000003599 detergent Substances 0.000 title 1
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims abstract description 14
- -1 alkyl succinate compounds Chemical class 0.000 claims abstract description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 230000001804 emulsifying effect Effects 0.000 claims abstract description 3
- 150000002148 esters Chemical class 0.000 claims abstract description 3
- 229950008882 polysorbate Drugs 0.000 claims abstract description 3
- 229920000136 polysorbate Polymers 0.000 claims abstract description 3
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 claims abstract 4
- XMGQYMWWDOXHJM-SNVBAGLBSA-N (-)-α-limonene Chemical compound CC(=C)[C@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-SNVBAGLBSA-N 0.000 claims abstract 2
- 238000004140 cleaning Methods 0.000 claims description 16
- 235000007586 terpenes Nutrition 0.000 claims description 13
- 150000003505 terpenes Chemical class 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- UZABCLFSICXBCM-UHFFFAOYSA-N ethoxy hydrogen sulfate Chemical class CCOOS(O)(=O)=O UZABCLFSICXBCM-UHFFFAOYSA-N 0.000 claims description 2
- 150000003890 succinate salts Chemical class 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract description 6
- 150000001875 compounds Chemical class 0.000 abstract description 4
- 229910052736 halogen Inorganic materials 0.000 abstract description 4
- 150000002367 halogens Chemical class 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000002845 discoloration Methods 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract 1
- 229940087305 limonene Drugs 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 235000001510 limonene Nutrition 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000005979 Citrus limon Nutrition 0.000 description 2
- 244000131522 Citrus pyriformis Species 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- BQOFWKZOCNGFEC-UHFFFAOYSA-N carene Chemical compound C1C(C)=CCC2C(C)(C)C12 BQOFWKZOCNGFEC-UHFFFAOYSA-N 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- YKFLAYDHMOASIY-UHFFFAOYSA-N γ-terpinene Chemical compound CC(C)C1=CCC(C)=CC1 YKFLAYDHMOASIY-UHFFFAOYSA-N 0.000 description 2
- 240000000662 Anethum graveolens Species 0.000 description 1
- 240000000467 Carum carvi Species 0.000 description 1
- 235000005747 Carum carvi Nutrition 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910001315 Tool steel Inorganic materials 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
Landscapes
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【発明の詳細な説明】 〈産業上の利用分野〉 この発明は金属表面用洗浄組成物に関する。[Detailed description of the invention] <Industrial application field> This invention relates to cleaning compositions for metal surfaces.
〈従来の技術及びその課題〉
各種加工工具やモールド金型の金属（ステンレスやダイ
ス鋼、工具鋼或いは超硬合金等）の表面に付着している
油脂やイオン性物質の洗浄は、−殻内にハロゲン物質を
含んだ溶剤や、希硫酸或いは硝酸等の無機酸や、カルボ
ン酸等の有機酸を主成分とした洗浄剤を使用していた。<Conventional technology and its problems> Cleaning of oils and ionic substances adhering to the surface of various processing tools and metals (stainless steel, die steel, tool steel, cemented carbide, etc.) of metal molds - inside the shell For this purpose, solvents containing halogen substances, inorganic acids such as dilute sulfuric acid or nitric acid, and cleaning agents mainly composed of organic acids such as carboxylic acids were used.
しかしながら、このような従来の技術にあっては、溶剤
に含まれているハロゲン物質や洗浄剤の低ｐｈにより、
金属表面が変色或いは腐食したりする場合があった。However, in such conventional technology, due to the halogen substances contained in the solvent and the low pH of the cleaning agent,
There were cases where the metal surface became discolored or corroded.
この発明はこのような従来の技術に着目してなされたも
のであり、ハロゲン物質を含まず且つｐｈがあまり低く
ない金属表面用洗浄組成物を提供せんとするものである
。The present invention has been made with attention to such conventional techniques, and it is an object of the present invention to provide a cleaning composition for metal surfaces that does not contain halogen substances and has a pH that is not too low.
く課題を解決するための手段〉
上記の目的を達成するため、この発明に係る金属表面用
洗浄組成物はテルペン化合物と、必要により４０ｗｔ％
以下の界面活性剤とを含む構成とした。Means for Solving the Problems> In order to achieve the above object, the cleaning composition for metal surfaces according to the present invention contains a terpene compound and, if necessary, 40 wt%.
It was configured to include the following surfactants.
ここで、テルペン化合物としては、ピネンに限定される
ものではないが、α、β異性体の両者、γ−テルピネン
、δ−３−カレン、リモネンおよびジペンテン（光学活
性リモネンの異性体のラセミ混合物）を含み、中でもｄ
−リモネン、！−リモネン、ジペンテン等が好ましい。Here, the terpene compound is not limited to pinene, but includes both α and β isomers, γ-terpinene, δ-3-carene, limonene, and dipentene (racemic mixture of optically active limonene isomers). including, among others, d
-Limonene! -Limonene, dipentene, etc. are preferred.
これらテルペン化合物は、単独でも使用することができ
、金属表面の汚れ（油脂）と複合体を形成し、除去後に
、過剰テルペンでフラッシュすることにより、または紙
あるいは布に付着することにより除去される。しかしな
がら、テルペン類はほぼ完全に非水溶性のために、水で
直接フラッシュされない。あるいはまた好ましくは、テ
ルペン化合物は１種またはそれ以上のテルペン乳化界面
活性剤と結合している。かかる界面活性剤を添加すると
、水ですすぐことによりテルペン類は水中油滴エマルジ
ョンを形成するため、金属表面からのテルペン類の除去
を促進する。このテルペン化合物は、従来使用されてい
た有機溶媒とは異なり、非毒性で環境に対し生分解性を
有する。リモネンは、快いレモン臭を有するレモン、オ
レンジ、カラウェー、イノンドおよびベルガモ・ソトの
油のような各種エーテル性油中の天然産品である。These terpene compounds, which can be used alone, form complexes with dirt (oils and fats) on metal surfaces and are removed after removal by flushing with excess terpene or by adhering to paper or cloth. . However, terpenes are not flushed directly with water because they are almost completely water-insoluble. Alternatively and preferably, the terpene compound is combined with one or more terpene emulsifying surfactants. The addition of such surfactants facilitates the removal of terpenes from the metal surface because upon rinsing with water, the terpenes form an oil-in-water emulsion. This terpene compound is non-toxic and biodegradable to the environment, unlike conventionally used organic solvents. Limonene is a natural product found in various ethereal oils such as lemon, orange, caraway, dill and bergamo soto oils, which have a pleasant lemon odor.
界面活性剤としては、非イオン系、アニオン系、カチオ
ン系、両性のいずれでも良い。特に、直鎖アルキルベン
センスルホネート類に限定されず、直鎖または枝分れ鎖
アルコールエトキシレート類およびエトキシスルフェー
ト類、ポリソルベートエステル類、エトキシレート化ア
ルキルフェノール類およびアルキルおよびジアルキルス
クシネート化合物等の、テルペン類を乳化可能なものも
使用できる。化合物の後者の１例として、ナトリウムジ
オクチルスルホスクシネートがある。エトキシレート化
アルキルフェノール類は、各種アルキル側鎖および多数
のリンクされたエチレンオキシド単位を含む。この類の
有効な化合物は、約５〜２０、好ましくは７または８の
エチレンオキシド基を含む。The surfactant may be nonionic, anionic, cationic, or amphoteric. In particular, such as, but not limited to, linear alkyl benzene sulfonates, linear or branched alcohol ethoxylates and ethoxy sulfates, polysorbate esters, ethoxylated alkyl phenols, and alkyl and dialkyl succinate compounds, Those that can emulsify terpenes can also be used. One example of the latter compound is sodium dioctyl sulfosuccinate. Ethoxylated alkylphenols contain various alkyl side chains and multiple linked ethylene oxide units. Useful compounds of this class contain about 5 to 20, preferably 7 or 8 ethylene oxide groups.
そして、この洗浄組成物のｐｈは４．５〜６であり、金
属表面を変色させたり或いは腐食させたりする程の低ｐ
ｈではない。The pH of this cleaning composition is 4.5 to 6, which is low enough to discolor or corrode metal surfaces.
Not h.
更に、この洗浄組成物は加温する必要がなく、常温（１
５〜２５°Ｃ）で使用することができる。Furthermore, this cleaning composition does not need to be heated and can be kept at room temperature (1
5-25°C).
く実 施 例〉
本発明に係る以下の組成Ａ−Ｆの如き洗浄組成物をつく
り、これを用いて超硬合金製のモールド金型の清浄実験
を行った。EXAMPLE Cleaning compositions according to the present invention having the following compositions A to F were prepared, and a cleaning experiment of a cemented carbide mold was conducted using these compositions.
実験方法としては、まず上記組成の洗浄組成物を浸漬タ
ンク内に溜め、その洗浄タンク内にモールド金型を浸漬
したり、浸漬したままブラシで洗浄したり、或いはシャ
ワー洗浄した。そして純水で洗浄し、乾燥させた。そし
て、浸漬タンクから取り出して純水で洗浄し、乾燥させ
た。結果は、洗浄後の金属表面に変色や腐食は全くなく
、しかも油脂等の汚れは完全に除去されていた。As an experimental method, a cleaning composition having the above composition was first stored in a dipping tank, and the mold was immersed in the cleaning tank, cleaned with a brush while being immersed, or washed with a shower. Then, it was washed with pure water and dried. Then, it was taken out from the immersion tank, washed with pure water, and dried. The results showed that there was no discoloration or corrosion on the metal surface after cleaning, and dirt such as oil and fat was completely removed.
組成Ａ
（非イオン系＋陰イオン系）
組成り
（非イオン系）
組成Ｃ
（非イオン系十両性）
組成り
（非イオン系十両性）
金属表面（超硬合金）
更に、残留イオン物をアルファメタルズ社製オメガメー
タにより測定したところ、全て低い値であった。Composition A (Non-ionic + Anionic) Composition (Non-ionic) Composition C (Non-ionic and de-amphodic) Composition (Non-ionic and de-amphodic) Metal surface (Cemented carbide) Furthermore, residual ionic substances are alpha When measured using an omega meter manufactured by Metals, all values were low.
〈発明の効果〉
この発明に係る金属表面用洗浄組成物は、以上説明して
きた如き内容のものであって、金属表面に対して高い洗
浄効果を示すものでありながら、金属表面に変色や腐食
を起こさせることがない。<Effects of the Invention> The cleaning composition for metal surfaces according to the present invention has the content as explained above, and although it shows a high cleaning effect on metal surfaces, it does not cause discoloration or corrosion on the metal surfaces. I never let it happen.
しかも、この洗浄組成物自体が、非毒性で環境に対し生
分解性を有するので、安全衛生上或いは安全管理上好適
である。Moreover, this cleaning composition itself is non-toxic and biodegradable to the environment, so it is suitable from the viewpoint of safety and hygiene or safety management.
Claims (3)
界面活性剤とを含む金属表面用洗浄組成物。(1) A cleaning composition for metal surfaces containing a terpene compound and, if necessary, 40 wt% or less of a surfactant.
、ジペンテンから成る群から選ばれる請求項１記載の金
属表面用洗浄組成物。2. The cleaning composition for metal surfaces according to claim 1, wherein the terpene compound is selected from the group consisting of d-limonene, l-limonene, and dipentene.
ト類、直鎖または枝分れ鎖アルコールエトキシレート類
およびエトキシスルフェート類、ポリソルベートエステ
ル類、アルキルおよびジアルキルスクシネート化合物類
、および約５〜２０のエチレンオキシド基を有するエト
キシレート化アルキルフェノール類から成る群から選ば
れるテルペン乳化界面活性剤である請求項１又は２記載
の金属表面用洗浄組成物。(3) the surfactant comprises linear alkylbenzene sulfonates, linear or branched alcohol ethoxylates and ethoxy sulfates, polysorbate esters, alkyl and dialkyl succinate compounds, and about 5 to 20 The cleaning composition for metal surfaces according to claim 1 or 2, which is a terpene emulsifying surfactant selected from the group consisting of ethoxylated alkylphenols having ethylene oxide groups.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP710990A JPH03212500A (en) | 1990-01-18 | 1990-01-18 | Detergent composition for metal surface |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP710990A JPH03212500A (en) | 1990-01-18 | 1990-01-18 | Detergent composition for metal surface |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03212500A true JPH03212500A (en) | 1991-09-18 |
Family
ID=11656924
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP710990A Pending JPH03212500A (en) | 1990-01-18 | 1990-01-18 | Detergent composition for metal surface |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03212500A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0697471A1 (en) * | 1994-07-18 | 1996-02-21 | Halliburton Company | Solvent compositions and their use |
| US9138393B2 (en) | 2013-02-08 | 2015-09-22 | The Procter & Gamble Company | Cosmetic compositions containing substituted azole and methods for improving the appearance of aging skin |
| US9144538B2 (en) | 2013-02-08 | 2015-09-29 | The Procter & Gamble Company | Cosmetic compositions containing substituted azole and methods for alleviating the signs of photoaged skin |
-
1990
- 1990-01-18 JP JP710990A patent/JPH03212500A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0697471A1 (en) * | 1994-07-18 | 1996-02-21 | Halliburton Company | Solvent compositions and their use |
| US9138393B2 (en) | 2013-02-08 | 2015-09-22 | The Procter & Gamble Company | Cosmetic compositions containing substituted azole and methods for improving the appearance of aging skin |
| US9144538B2 (en) | 2013-02-08 | 2015-09-29 | The Procter & Gamble Company | Cosmetic compositions containing substituted azole and methods for alleviating the signs of photoaged skin |
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