JPH03184320A - Surface treating method - Google Patents

Surface treating method

Info

Publication number
JPH03184320A
JPH03184320A JP32321489A JP32321489A JPH03184320A JP H03184320 A JPH03184320 A JP H03184320A JP 32321489 A JP32321489 A JP 32321489A JP 32321489 A JP32321489 A JP 32321489A JP H03184320 A JPH03184320 A JP H03184320A
Authority
JP
Japan
Prior art keywords
gas
hmds
treated
mixed
concentration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP32321489A
Other languages
Japanese (ja)
Other versions
JP3011728B2 (en
Inventor
Kimiharu Matsumura
松村 公治
Hiroyuki Sakai
宏之 境
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tokyo Electron Ltd
Tokyo Electron Kyushu Ltd
Original Assignee
Tokyo Electron Ltd
Tokyo Electron Kyushu Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokyo Electron Ltd, Tokyo Electron Kyushu Ltd filed Critical Tokyo Electron Ltd
Priority to JP1323214A priority Critical patent/JP3011728B2/en
Publication of JPH03184320A publication Critical patent/JPH03184320A/en
Application granted granted Critical
Publication of JP3011728B2 publication Critical patent/JP3011728B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

PURPOSE:To supply the upper section of a body to be treated with the gas in proper concentration of a vaporized treating liquid in proper quantities when the surface of a semiconductor wafer is treated by a method wherein the treating liquid is vaporized, a carrier gas is mixed with the vaporized gas, the flow rate and concentration of the gas are adjusted by the quantity of the carrier gas mixed, and the body to be treated is treated. CONSTITUTION:A treating liquid is vaporized, a carrier gas C is mixed with the gas of the treating liquid, the flow rate and concentration of said gas are adjusted by the quantity of the carrier gas C mixed and a body to be treated 30 is treated. A vaporizing vessel 10 is supplied with a fixed quantity of liquefied HMDS from an HMDS supply system 11, and the vaporization of liquefied HMDS is promoted. Vaporized HMDS is passed through a piping 12 while the feed of N2 gas is controlled so as to be brought to the desired concentration of HMDS from a carrier-gas supply system 14 by operating a valve V, N2 gas is flowed into the piping 12 from an inflow port 15 and mixed, and the mixed gas is fed to a treating section 13. The gas is spread over the whole surface of the semiconductor wafer 30 in proper quantities by a diffusing plate 18 adjusted at a desired temperature in the treating section 13, and HMDS is atomized onto the semiconductor wafer 30.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は半導体ウェハの製造工程に関し、特に半導体ウ
ェハ表面処理方法に係る。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a semiconductor wafer manufacturing process, and particularly to a semiconductor wafer surface treatment method.

[従来の技術] 半導体ウェハ製造におけるホトレジスト処理工程は、ウ
ェハ上に積層されたSiO2等の薄膜上にレジスト塗布
し、所望のパターンに露光、現像して薄膜上にパターン
を形成している。通常、レジスト塗布前の半導体ウェハ
上の薄膜は大気中の水気を吸収し、表面に○H基が吸着
して親水性となっている。親水性表面に対してポジレジ
ストを塗布した場合、レジストの接着性が弱いため現像
処理中にレジストの剥離が生じることがある。
[Prior Art] In a photoresist processing step in the manufacture of semiconductor wafers, a resist is applied onto a thin film of SiO2 or the like stacked on a wafer, exposed to light in a desired pattern, and developed to form a pattern on the thin film. Normally, a thin film on a semiconductor wafer before resist coating absorbs moisture from the atmosphere and becomes hydrophilic due to adsorption of ○H groups on the surface. When a positive resist is applied to a hydrophilic surface, the resist may peel off during the development process because the adhesiveness of the resist is weak.

このためレジストの接着性強化のためにHMDS(ヘキ
サメチルジシラザン(CH,)、5iNH8i(CH3
)3) )を用いてウェハ表面で以下の反応式に示す処
理により疎水性化処理(アトヒユージョン処理)が行わ
れている。
Therefore, to strengthen the adhesion of the resist, HMDS (hexamethyldisilazane (CH,), 5iNH8i (CH3)
)3)) Hydrophobic treatment (atfusion treatment) is performed on the wafer surface by the treatment shown in the following reaction formula.

HMDSの処理方法は通常薬液使用量の少ないHMDS
ベーパにより、アトヒユージョン処理が施されている。
HMDS treatment method usually uses HMDS with a small amount of chemical solution.
Atherosclerosis treatment is performed using vapor.

[発明が解決すべき課題] ベーパ処理のHMDS処理装置は第5図に示すように液
状のHMDSの収納容器1にN2ガスを供給し、N2ガ
スのバブルにより、液状HMDSを気化させ密閉状の処
理装置2内に配置された半導体ウェハ3上に供給してい
る。しかし、この種の処理装置2では、HMDSの供給
量、濃度等はN2ガスの供給量によりコントロールをし
ていたが十分広い濃度範囲でHMDS発生濃度コントロ
ールができず、原理的に低濃度域に限定されていた。そ
のためウェハの薄膜上に供給されるHMDSは濃度が希
薄でしかも設定しうる濃度の範囲が狭く、半導体ウェハ
3の疎水処理条件が適正でないため、レジスト剥離が生
じたり、あるいは過剰のHMDSを供給して無駄になる
という欠点があった。
[Problems to be Solved by the Invention] As shown in FIG. 5, the HMDS processing apparatus for vapor treatment supplies N2 gas to a storage container 1 for liquid HMDS, and vaporizes the liquid HMDS by bubbles of the N2 gas to form a sealed container. It is supplied onto a semiconductor wafer 3 placed in a processing apparatus 2. However, in this type of treatment equipment 2, although the supply amount and concentration of HMDS are controlled by the supply amount of N2 gas, it is not possible to control the HMDS generation concentration over a sufficiently wide concentration range, and in principle, it is not possible to control the HMDS generation concentration in a sufficiently wide concentration range. It was limited. Therefore, the concentration of HMDS supplied onto the thin film of the wafer is dilute and the range of concentrations that can be set is narrow, and the hydrophobic treatment conditions of the semiconductor wafer 3 are not appropriate, resulting in resist peeling or excessive HMDS being supplied. The disadvantage was that it was wasted.

本発明は上記の欠点を解消するためになされたものであ
って、半導体ウェハの表面処理を行うにあたり気化され
た処理液の適正濃度の気体を過不足なく被処理体上に供
給可能な表面処理方法を提供することを目的とする。
The present invention has been made in order to eliminate the above-mentioned drawbacks, and is a surface treatment that can supply gas at an appropriate concentration of a vaporized processing liquid onto an object to be processed in the process of surface processing a semiconductor wafer. The purpose is to provide a method.

[課題を解決するための手段] 上記の目的を達成するため本発明の表面処理方法は、処
理液を気化し、該処理液の気体にキャリアガスを混合し
、該キャリアガス混合量により前記気体の流量及び濃度
を調整して被処理体を処理する。
[Means for Solving the Problems] In order to achieve the above object, the surface treatment method of the present invention vaporizes a treatment liquid, mixes a carrier gas with the gas of the treatment liquid, and adjusts the amount of the gas by the mixed amount of the carrier gas. The object to be treated is treated by adjusting the flow rate and concentration of the substance.

さらに前記処理液の気化容器を加温して、前記気体の発
生速度を調整するものである。
Furthermore, the vaporization container for the processing liquid is heated to adjust the generation rate of the gas.

[作用] 本発明の表面処理方法は、気化容器に処理液である液体
のHMDSを定量供給して発生させたHMDSペーパー
に流量をコントロールしたキャリアガスを流入し、これ
によりウェハの表面上に供給するHMDSの流量、濃度
をコントロールして表面処理を行う。さらに、液体のH
MDSの気化流量とキャリアガスの流量をコントロール
すると供にHMDSのキャリアガスの気化容器に加温手
段を設け、HNDSの気化流量を精密にコントロールす
ることにより処理液の供給量、濃度の微調整を行うこと
が可能になる。
[Operation] In the surface treatment method of the present invention, a carrier gas with a controlled flow rate is flowed into the HMDS paper generated by supplying a fixed amount of liquid HMDS as a treatment liquid to a vaporization container, thereby supplying it onto the surface of the wafer. Surface treatment is performed by controlling the flow rate and concentration of HMDS. Furthermore, liquid H
In addition to controlling the MDS vaporization flow rate and the carrier gas flow rate, a heating means is installed in the HMDS carrier gas vaporization container, and by precisely controlling the HNDS vaporization flow rate, the supply amount and concentration of the processing liquid can be finely adjusted. It becomes possible to do so.

[実施例コ 本発明の表面処理方法を半導体ウェハ製造のホトレジス
ト処理工程におけるレジスト接着強化処理装置に適用し
た一実施例を図面を参照して説明する。
[Example 1] An example in which the surface treatment method of the present invention is applied to a resist adhesion strengthening treatment apparatus in a photoresist treatment process for manufacturing semiconductor wafers will be described with reference to the drawings.

第1図に図示のレジスト接着強化処理装置の表面処理装
置20において、処理液である液体のHMDSの気化容
器10に接続されたHMDS供給系11から液状のHM
DSが定量供給される。上気気化容器10の加熱により
気化容器lo中の液体HMDSの気化が促され配管工2
を通って処理部13に導入される。配管12にはキャリ
アガスCの供給量を調整するバルブVの開閉をコントロ
ールする調整手段を有するキャリアガス供給体14から
キャリアガスCが流入する流入口15が設けられる。
In the surface treatment apparatus 20 of the resist adhesion strengthening treatment apparatus shown in FIG.
A fixed amount of DS is supplied. The heating of the upper air vaporization container 10 promotes vaporization of the liquid HMDS in the vaporization container lo, and the plumber 2
It is introduced into the processing section 13 through the. The pipe 12 is provided with an inlet 15 through which the carrier gas C flows from a carrier gas supply body 14 having an adjusting means for controlling the opening and closing of a valve V that adjusts the amount of carrier gas C supplied.

さらに、配管12に接続された処理部13にはキャリア
ガスCが混合された気体のHMDSが供給される。載置
台16上には被処理体である半導体ウェハ30が搬入載
置されており、この半導体ウェハ30の表面全域上に気
体状HMDSが均一に噴出されるよう半導体ウェハ30
に対面して多数の孔17が穿孔され、温度調節機構を備
えた拡散板18が設けられる。また処理部13は必要で
あれば減圧装置に接続される。
Further, gaseous HMDS mixed with carrier gas C is supplied to the processing section 13 connected to the pipe 12. A semiconductor wafer 30, which is an object to be processed, is carried and placed on the mounting table 16, and the semiconductor wafer 30 is placed so that gaseous HMDS is uniformly ejected over the entire surface of the semiconductor wafer 30.
A large number of holes 17 are bored facing each other, and a diffusion plate 18 equipped with a temperature adjustment mechanism is provided. Further, the processing section 13 is connected to a pressure reducing device if necessary.

さらに、HMDS液の収納容器10には、HMDS温度
を調整するようヒーター等の加温手段19が具備される
Further, the HMDS liquid storage container 10 is equipped with a heating means 19 such as a heater to adjust the HMDS temperature.

以上のような構成の表面処理袋W20の作用を説明する
The operation of the surface-treated bag W20 configured as above will be explained.

処理部13の載置台16上に図示しない搬送装置により
半導体ウェハ30を搬入載置したのち、処理部13を密
閉する。必要であれば減圧をかける。この減圧をかける
ことにより、低温で気化速度を増大させることができる
。すなわち、低温化をはかることができる。その後HM
DS供給系11から所定量の液状のHMDSを気化容器
1oに供給し、液状HMDSの気化を促す。HMDSの
気化を促すためには加温手段19を作動させて液状HM
DSの気化温度に昇温させ、この温度によリHMDSの
気化速度を調整する。気化されたHMDSは例えば1分
間0.1−10Q量となって配管12を通り、一方キャ
リアガス供給系14からバルブVを操作して所望のHM
DSの濃度になるようキャリアガス例えばN2ガスの供
給量をコントロールする。キャリアガスC例えば1分間
にIOQの窒素N2ガスを流入口15より配管12に流
入させて、HMDSの気体にHMDS濃度調整のために
供給されたN2ガスを混合させ、この混合気体を処理部
13に供給する。キャリアガスCとしてはHMDSと反
応しないものならば何れのものでも使用でき、不活性ガ
スのN2ガス等が好適である。処理部13において温度
調節機構により所望の温度(例えば20℃)に調整され
た拡散板18により載置台16上の半導体ウェハ30の
全面に気体が過不足なく行き亘り、HMDSがベーパも
しくはミスト状液状となって半導体ウェハ30上に噴霧
される。H’MDSの濃度及び流量はHMDSの気化流
量とキャリアガスCの流量で微妙に調節することができ
、キャリアガスCを多くするかまたはHMDSの気化流
量を小さくすることにより半導体ウェハ30上に形成さ
れるHMDS膜厚は薄くなり、キャリアガスCを少くす
るかまたはHMDSの気化流量を大きくするとHMDS
膜は厚くなる。従って、後工程のレジスト塗布された時
に第2図に示すように形成される水滴と半導体ウェハ3
0とのなす接触角θにより、表面処理状況が判断できる
。即ち、θが十分大きければ完全な疎水処理がなされて
いることが確認でき、レジスト膜と半導体ウェハとの接
着力のコントロールも可能となる。
After the semiconductor wafer 30 is carried in and placed on the mounting table 16 of the processing section 13 by a transport device (not shown), the processing section 13 is sealed. Apply vacuum if necessary. By applying this reduced pressure, the rate of vaporization can be increased at low temperatures. In other words, the temperature can be lowered. Then H.M.
A predetermined amount of liquid HMDS is supplied from the DS supply system 11 to the vaporization container 1o to promote vaporization of the liquid HMDS. In order to promote the vaporization of HMDS, the heating means 19 is operated to heat the liquid HMDS.
The temperature is raised to the vaporization temperature of DS, and the vaporization rate of HMDS is adjusted by this temperature. The vaporized HMDS passes through the pipe 12 in an amount of, for example, 0.1-10Q per minute, while the desired HMDS is supplied by operating the valve V from the carrier gas supply system 14.
The supply amount of carrier gas, such as N2 gas, is controlled so that the concentration of DS is achieved. Carrier gas C For example, nitrogen N2 gas of IOQ per minute is flowed into the pipe 12 from the inlet 15 to mix the HMDS gas with the N2 gas supplied for adjusting the HMDS concentration, and this mixed gas is passed to the processing section 13. supply to. As the carrier gas C, any gas can be used as long as it does not react with HMDS, and an inert gas such as N2 gas is suitable. In the processing section 13, the diffusion plate 18, which is adjusted to a desired temperature (for example, 20° C.) by the temperature control mechanism, spreads the gas over the entire surface of the semiconductor wafer 30 on the mounting table 16 in just the right amount. and is sprayed onto the semiconductor wafer 30. The concentration and flow rate of H'MDS can be delicately adjusted by the vaporization flow rate of HMDS and the flow rate of carrier gas C, and by increasing the carrier gas C or decreasing the vaporization flow rate of HMDS, H'MDS can be formed on the semiconductor wafer 30. The thickness of the HMDS film becomes thinner, and if the carrier gas C is reduced or the HMDS vaporization flow rate is increased, the HMDS film becomes thinner.
The membrane becomes thicker. Therefore, water droplets and the semiconductor wafer 3 formed as shown in FIG. 2 when the resist is applied in the subsequent process.
The surface treatment status can be determined based on the contact angle θ with respect to 0. That is, if θ is sufficiently large, it can be confirmed that the hydrophobic treatment is complete, and it is also possible to control the adhesive force between the resist film and the semiconductor wafer.

また、第3図に示すHMDSの濃度とアトヒユージョン
処理所要時間の関係からHMDSベーパの濃度が高いほ
ど処理時間を短縮することができるため、必要最小限の
処理時間でアトヒユージョン処理を終了することができ
る。
Furthermore, from the relationship between the concentration of HMDS and the time required for atfusion processing shown in Figure 3, the higher the concentration of HMDS vapor, the shorter the processing time, so the atfusion processing can be completed in the minimum necessary processing time. can do.

次に、本発明の他の一実施例について説明する。Next, another embodiment of the present invention will be described.

第4図に示すように、HMDSの気化容器10Aに接続
されたHMDS供給系11から液状のHMDSが定量供
給され上記気化容器で気化するように構成されている。
As shown in FIG. 4, a fixed amount of liquid HMDS is supplied from an HMDS supply system 11 connected to an HMDS vaporization container 10A and vaporized in the vaporization container.

また、上記気化容器内10Aには配管31が接続されて
おり、キャリアガスCの供給量を調整するバルブVの開
閉をコントロールするtA整平手段有するキャリアガス
供給体14からキャリアガスCが上記気化容器10A内
に導入される。さらに、上記気化容器10Aの周囲には
加温手段19が設けられている。そして、HMDSの気
体とキャリアガスC例えば窒素N2ガスの混合気体が配
管32を通って処理部(図示せず)に供給される。
Further, a pipe 31 is connected to the inside of the vaporization container 10A, and the carrier gas C is supplied from the carrier gas supply body 14 having a flattening means for controlling the opening and closing of a valve V for adjusting the supply amount of the carrier gas C to the vaporization container. It is introduced into the container 10A. Further, a heating means 19 is provided around the vaporization container 10A. Then, a mixed gas of HMDS gas and a carrier gas C, for example, nitrogen N2 gas, is supplied to a processing section (not shown) through the pipe 32.

なお、この実施例の動作作用・効果等については第1図
に示す一実施例と同等であるためその説明は省略する。
It should be noted that the operation, effects, etc. of this embodiment are the same as those of the embodiment shown in FIG. 1, so a description thereof will be omitted.

上記実施例では液状HMDSの気化手段として蒸気圧温
度に設定した例について説明したが、超音波手段により
霧状化させてもよい。上記実施例では、HMDSによる
アトヒユージョン処理工程に適用した例について説明し
たが、表面被処理体に気体状処理物による処理であれば
何れにも適用できる。
In the above embodiment, an example was explained in which the vapor pressure temperature was set as the means for vaporizing liquid HMDS, but it may also be atomized by ultrasonic means. In the above embodiment, an example in which the present invention is applied to an atfusion treatment process using HMDS has been described, but the present invention can be applied to any treatment as long as the surface of the object to be treated is treated with a gaseous treatment substance.

[発明の効果] 以上の説明からも明らかなように、本発明の表面処理方
法によれば、HMDSの気化流量とキャリアガスの流量
を調整することによりHMDS濃度の濃度の調整が可能
となる。従って、広範囲の濃度で均一なHMDS処理を
行い、半導体ウェハ上に形成されるHMDS膜厚をコン
トロールして半導体ウェハとレジストの接着力を調整す
ることができる。しかもアトヒユージョンに要する処理
時間も適正値に短縮することができるので時間的にも必
要最少限で処理を行うことができるため。
[Effects of the Invention] As is clear from the above description, according to the surface treatment method of the present invention, the HMDS concentration can be adjusted by adjusting the vaporization flow rate of HMDS and the flow rate of the carrier gas. Therefore, it is possible to perform uniform HMDS treatment over a wide range of concentrations, control the thickness of the HMDS film formed on the semiconductor wafer, and adjust the adhesive force between the semiconductor wafer and the resist. Moreover, since the processing time required for atfusion can be shortened to an appropriate value, the processing can be performed in the minimum amount of time required.

半導体ウェハの高精度なパターン形成を短時間で行うこ
とができる。
Highly accurate pattern formation on semiconductor wafers can be performed in a short time.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の表面処理方法に係る一実施例を示す構
成図、第2図及び第3図は表面処理方法を説明する図、
第4図は本発明の他の一実施例の要部を示す構成図、第
5図は従来の表面処理方法に係る装置を示す図である。 10・・・・・気化容器 20・・・・・表面処理装置 30・・・・・半導体ウェハ(被処理体)工4・・・・
・キャリアガス供給体 上9・・・・・加温手段 HMDS・・・・・・処理液
FIG. 1 is a block diagram showing an embodiment of the surface treatment method of the present invention, FIGS. 2 and 3 are diagrams explaining the surface treatment method,
FIG. 4 is a block diagram showing a main part of another embodiment of the present invention, and FIG. 5 is a diagram showing an apparatus related to a conventional surface treatment method. 10... Vaporization container 20... Surface treatment device 30... Semiconductor wafer (object to be processed) processing 4...
・On carrier gas supply body 9... Heating means HMDS... Processing liquid

Claims (1)

【特許請求の範囲】 1、処理液を気化し、該処理液の気体にキャリアガスを
混合し、該キャリアガス混合量により前記気体の流量及
び濃度を調整して被処理体を処理することを特徴とする
表面処理方法。 2、前記処理液の気化容器を加温して、前記気体の発生
を調整することを特徴とする第1項記載の表面処理方法
[Claims] 1. Processing the object by vaporizing the processing liquid, mixing a carrier gas with the gas of the processing liquid, and adjusting the flow rate and concentration of the gas according to the amount of the carrier gas mixed. Characteristic surface treatment method. 2. The surface treatment method according to item 1, characterized in that the vaporization container for the treatment liquid is heated to adjust the generation of the gas.
JP1323214A 1989-12-13 1989-12-13 Surface treatment equipment Expired - Fee Related JP3011728B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1323214A JP3011728B2 (en) 1989-12-13 1989-12-13 Surface treatment equipment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1323214A JP3011728B2 (en) 1989-12-13 1989-12-13 Surface treatment equipment

Publications (2)

Publication Number Publication Date
JPH03184320A true JPH03184320A (en) 1991-08-12
JP3011728B2 JP3011728B2 (en) 2000-02-21

Family

ID=18152311

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1323214A Expired - Fee Related JP3011728B2 (en) 1989-12-13 1989-12-13 Surface treatment equipment

Country Status (1)

Country Link
JP (1) JP3011728B2 (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5525551A (en) * 1993-09-20 1996-06-11 Fujitsu Limited Method for forming insulating film in semiconductor device using a TEOS or HMDS pre-treatment
JP2005226048A (en) * 2004-02-16 2005-08-25 Hitachi Chem Co Ltd Adhesive composition, film-formed adhesive and circuit-joining material by using the same, and joining structure of circuit member and method for producing the same
JP2009194246A (en) * 2008-02-15 2009-08-27 Tokyo Electron Ltd Vaporizer, substrate processing apparatus, substrate processing method, and storage medium
JP2010258068A (en) * 2009-04-22 2010-11-11 Tokyo Electron Ltd Liquid processing apparatus, and liquid processing method
JP2011044671A (en) * 2009-08-24 2011-03-03 Tokyo Electron Ltd Hydrophobization treatment apparatus, hydrophobization treatment method, and storage medium
JP2012038868A (en) * 2010-08-05 2012-02-23 Tokyo Electron Ltd Vaporizer, substrate processing apparatus, coating development apparatus and substrate processing method
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US5525551A (en) * 1993-09-20 1996-06-11 Fujitsu Limited Method for forming insulating film in semiconductor device using a TEOS or HMDS pre-treatment
JP2005226048A (en) * 2004-02-16 2005-08-25 Hitachi Chem Co Ltd Adhesive composition, film-formed adhesive and circuit-joining material by using the same, and joining structure of circuit member and method for producing the same
JP4655487B2 (en) * 2004-02-16 2011-03-23 日立化成工業株式会社 Adhesive composition, film-like adhesive and circuit connecting material using the same, circuit member connecting structure, and manufacturing method thereof
JP2009194246A (en) * 2008-02-15 2009-08-27 Tokyo Electron Ltd Vaporizer, substrate processing apparatus, substrate processing method, and storage medium
JP2016066811A (en) * 2008-06-16 2016-04-28 株式会社東芝 Substrate processing apparatus
JP2010258068A (en) * 2009-04-22 2010-11-11 Tokyo Electron Ltd Liquid processing apparatus, and liquid processing method
JP2011044671A (en) * 2009-08-24 2011-03-03 Tokyo Electron Ltd Hydrophobization treatment apparatus, hydrophobization treatment method, and storage medium
KR20110020731A (en) * 2009-08-24 2011-03-03 도쿄엘렉트론가부시키가이샤 Hydrophobicizing apparatus, hydrophobicizing method and storage medium
US8430967B2 (en) 2009-08-24 2013-04-30 Tokyo Electron Limited Hydrophobicizing apparatus, hydrophobicizing method and storage medium
TWI479536B (en) * 2009-08-24 2015-04-01 Tokyo Electron Ltd Hydrophobic treatment device and hydrophobic treatment method
JP2012038868A (en) * 2010-08-05 2012-02-23 Tokyo Electron Ltd Vaporizer, substrate processing apparatus, coating development apparatus and substrate processing method

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