JPH0317033A - Fluorinated hydrocarbon-based solvent composition - Google Patents
Fluorinated hydrocarbon-based solvent compositionInfo
- Publication number
- JPH0317033A JPH0317033A JP1149503A JP14950389A JPH0317033A JP H0317033 A JPH0317033 A JP H0317033A JP 1149503 A JP1149503 A JP 1149503A JP 14950389 A JP14950389 A JP 14950389A JP H0317033 A JPH0317033 A JP H0317033A
- Authority
- JP
- Japan
- Prior art keywords
- fluorinated hydrocarbon
- composition
- weight
- present
- pentafluoropropanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 24
- 239000002904 solvent Substances 0.000 title claims abstract description 17
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 12
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 11
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 10
- UJIGKESMIPTWJH-UHFFFAOYSA-N 1,3-dichloro-1,1,2,2,3-pentafluoropropane Chemical compound FC(Cl)C(F)(F)C(F)(F)Cl UJIGKESMIPTWJH-UHFFFAOYSA-N 0.000 claims abstract description 5
- COAUHYBSXMIJDK-UHFFFAOYSA-N 3,3-dichloro-1,1,1,2,2-pentafluoropropane Chemical compound FC(F)(F)C(F)(F)C(Cl)Cl COAUHYBSXMIJDK-UHFFFAOYSA-N 0.000 claims abstract description 5
- PSQZJKGXDGNDFP-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropan-1-ol Chemical compound OCC(F)(F)C(F)(F)F PSQZJKGXDGNDFP-UHFFFAOYSA-N 0.000 claims abstract 5
- WMCLYSGSAJGCJY-UHFFFAOYSA-N 3-chloro-1,1,2,2-tetrafluoropropane Chemical compound FC(F)C(F)(F)CCl WMCLYSGSAJGCJY-UHFFFAOYSA-N 0.000 claims abstract 3
- VLHYAWNCTMZTSC-UHFFFAOYSA-N 1,1,3,3,3-pentafluoropropan-1-ol Chemical compound OC(F)(F)CC(F)(F)F VLHYAWNCTMZTSC-UHFFFAOYSA-N 0.000 claims description 3
- COWKRCCNQSQUGJ-UHFFFAOYSA-N 1,1,2,2,3-pentafluoropropan-1-ol Chemical compound OC(F)(F)C(F)(F)CF COWKRCCNQSQUGJ-UHFFFAOYSA-N 0.000 abstract 1
- 238000007796 conventional method Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- -1 chlorine radicals Chemical class 0.000 description 7
- 238000009835 boiling Methods 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 5
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 4
- 230000004907 flux Effects 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000004604 Blowing Agent Substances 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 3
- 239000010721 machine oil Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 3
- HNRMPXKDFBEGFZ-UHFFFAOYSA-N 2,2-dimethylbutane Chemical compound CCC(C)(C)C HNRMPXKDFBEGFZ-UHFFFAOYSA-N 0.000 description 2
- KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 239000003507 refrigerant Substances 0.000 description 2
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 1
- JHUUPUMBZGWODW-UHFFFAOYSA-N 3,6-dihydro-1,2-dioxine Chemical compound C1OOCC=C1 JHUUPUMBZGWODW-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000004971 nitroalkyl group Chemical group 0.000 description 1
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000013020 steam cleaning Methods 0.000 description 1
- 239000005437 stratosphere Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- KFUSEUYYWQURPO-OWOJBTEDSA-N trans-1,2-dichloroethene Chemical group Cl\C=C\Cl KFUSEUYYWQURPO-OWOJBTEDSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 239000005436 troposphere Substances 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Landscapes
- Extraction Or Liquid Replacement (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Manufacturing Of Printed Wiring (AREA)
- Cleaning Or Drying Semiconductors (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、代替フロンとして使用できるとともに溶剤等
として優れた特性を有する新規な弗素化炭化水素系溶剤
組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a novel fluorinated hydrocarbon solvent composition that can be used as a substitute for chlorofluorocarbons and has excellent properties as a solvent.
［従来の技術］
弗素化炭化水素系化合物（以下単にフロンという）は、
毒性が少なく化学的に安定なものが多く、標準沸点の異
なる各種フロンが入手できることから、これらの特性を
活かして溶剤、発泡剤、プロペラントあるいは冷媒等と
じて１，１．２−トリクロロ−１．２．２− トリフル
オロエタン（ Ｒ １１３ ）が、発泡剤としてトリク
ロロモノフルオロメタン（Ｒｌｌ）が、プロペラントや
冷媒としてジクロロジフルオロメタン（ Ｒ １２ ）
が使われている。[Prior art] Fluorinated hydrocarbon compounds (hereinafter simply referred to as fluorocarbons) are
Many of them are less toxic and chemically stable, and various types of chlorofluorocarbons with different standard boiling points are available.Using these characteristics, 1,1,2-trichloro-1 can be used as a solvent, blowing agent, propellant, or refrigerant. .2.2- Trifluoroethane (R 113 ), trichloromonofluoromethane (Rll) as a blowing agent, and dichlorodifluoromethane (R 12 ) as a propellant or refrigerant.
is used.
［発明が解決しようとする課題１
化学的に特に安定なＲ １１， Ｒ １２、Ｒ １１３
は対流圏内での寿命が長く、拡散して戊層圏に達し、こ
こで太陽光線により分解して発生する塩素ラジカルがオ
ゾンと連鎖反応を起こし．オゾン層を破壊するとのこと
から、これら従来のフロンの使用規制が実施されること
となった。このため、これらの従来のフロンに代わり，
オゾン層を破壊しにくい代替フロンの探索が活発に行な
われている。[Problem to be solved by the invention 1 Chemically particularly stable R 11, R 12, R 113
It has a long lifetime in the troposphere and diffuses to the stratosphere, where the chlorine radicals generated by decomposition by sunlight cause a chain reaction with ozone. Conventional regulations on the use of these fluorocarbons have been implemented because they are said to destroy the ozone layer. Therefore, instead of these conventional CFCs,
The search for alternative CFCs that are less likely to deplete the ozone layer is being actively conducted.
本発明は、従来のフロンの使用量を低減し、且つ該フロ
ンが有している優れた特性を満足しながら代替フロンと
して使用できる新規なフロン組成物を提供することを目
的とするものである。An object of the present invention is to provide a new fluorocarbon composition that can be used as a fluorocarbon substitute while reducing the amount of conventional fluorocarbons used and satisfying the excellent properties of the fluorocarbons. .
［課題を解決するための手段］
本発明は、１．１−ジクロロ−２． ２， ３， ３．
３−ペンタフルオロプロパン（ Ｒ ２２５ｃａ ，
沸点５ｌ，１℃），１．３−ジクロロ−１． ２， ２
， ３． ３−ペンタフルオロプロパン（ Ｒ ２２５
ｃｂ ，沸点５６．１ ”Ｃ）．及び ｌ−クロロ−２
．２，３．３−テトラフルオロプロパン（ Ｒ ２４４
ｃａ，沸点 ５４℃）のいずれか１種と２． ２， ３
， ３． ３−ペンタフルオロプロパノール（ ５ＦＰ
，沸点８１℃）からなる弗素化炭化水素系溶剤組成物
に関するものである。[Means for Solving the Problems] The present invention provides 1,1-dichloro-2. 2, 3, 3.
3-pentafluoropropane (R225ca,
boiling point 5l, 1°C), 1.3-dichloro-1. 2, 2
, 3. 3-pentafluoropropane (R 225
cb, boiling point 56.1"C). and l-chloro-2
．． 2,3,3-tetrafluoropropane (R 244
ca, boiling point 54°C) and 2. 2, 3
, 3. 3-pentafluoropropanol (5FP
, a boiling point of 81° C.).
本発明の組成物は、特に洗浄溶剤として従来のＲ １１
３よりも洗浄力が大きいため、Ｒ１１３代替として極め
て有用なものである。The compositions of the present invention are particularly useful as cleaning solvents in conventional R 11
Since it has greater detergency than R113, it is extremely useful as a substitute for R113.
本発明の組成物のＲ ２２５ｃａと５ＦＰの混合比はＲ
２２５ｃａが６０〜９９重量％．及び５ＦＰが１〜４
０重量％であり、好ましくはＲ ２２５ｃａが７０〜９
０重量％，及び５ＦＰがｌＯ〜３０重量％である。The mixing ratio of R 225ca and 5FP in the composition of the present invention is R
225ca is 60-99% by weight. and 5FP is 1-4
0% by weight, preferably R225ca is 70-9
0% by weight, and 5FP is 10 to 30% by weight.
本発明の組成物のＲ ２２５ｃｂと ５ＦＰの混合比は
Ｒ ２２５ｃｂが６０〜９９重量％，及び５ＦＰが １
〜４０重量％であり、好ましくはＲ ２２５ｃｂが７０
〜９０重量％，及び５ＦＰがｌＯ〜３０重量％である。The mixing ratio of R 225cb and 5FP in the composition of the present invention is 60 to 99% by weight of R 225cb and 1% by weight of 5FP.
~40% by weight, preferably R225cb is 70
~90% by weight, and 5FP ~30% by weight.
本発明の組成物のＲ ２４４ｃａと５ＦＰの混合比はＲ
２４４ｃａが６０〜９９重量％，及び５ＦＰが１〜４
０重量％であり、好ましくはＲ ２４４ｃａが７０〜９
０重量％，及び５ＦＰがｌＯ〜３０重゛量％である．本
発明の組成物には、用途に応じてその他の成分を更に添
加混合することができる。例えば、溶剤としての用途に
おいては、ベンタン，イソペンタン，ヘキサン．イソヘ
キサン，ネオヘキサン，ヘブタン，イソへブタン．２．
３−ジメチルブタン，シクロペンタン等の炭化水素類、
ニトロメタン，ニトロエタン，ニトロブロバン等のニト
ロアルカン類、ジエチルアミン，トリエチルアミン．イ
ソブロビルアミン，プチルアミン，イソブチルアミン等
のアミン類、メタノール，エタノール，ｎ−プロビルア
ルコール，ｉ−プロビルアルコール，ｎ−ブチルアルコ
ール，ｉ−ブチルアルコール，Ｓ−ブチルアルコール．
ｔ−ブチルアルコール等のアルコール類、メチルセロソ
ルブ，テトラヒドロフラン，ｌ，４−ジオキサン等のエ
ーテル類、アセトン，メチルエチルケトン，メチルブチ
ルケトン等のケトン類、酢酸エチル，酢酸プロビル，酢
酸ブチル等のエステル類、ジクロロメタン，ｔｒａｎｓ
ｅ−１．２−ジクロロエチレン， ｃＬｓ−１．２−ジ
クロロエチレン．２−ブロモブロバン等のハロゲン化炭
化水素類、その他、１．１−ジクロロ−１−フルオロエ
タン等の本発明以外のフロン類等を適宜添加することが
できる。The mixing ratio of R 244ca and 5FP in the composition of the present invention is R
244ca is 60-99% by weight, and 5FP is 1-4
0% by weight, preferably R244ca is 70-9
0% by weight, and 5FP is 10~30% by weight. Other components may be further added to the composition of the present invention depending on the intended use. For example, when used as a solvent, bentane, isopentane, hexane. Isohexane, neohexane, hebutane, isohexane. 2.
Hydrocarbons such as 3-dimethylbutane and cyclopentane,
Nitroalkanes such as nitromethane, nitroethane, nitrobroban, diethylamine, triethylamine. Amines such as isobrobylamine, butylamine, isobutylamine, methanol, ethanol, n-propyl alcohol, i-propyl alcohol, n-butyl alcohol, i-butyl alcohol, S-butyl alcohol.
Alcohols such as t-butyl alcohol, ethers such as methyl cellosolve, tetrahydrofuran, l,4-dioxane, ketones such as acetone, methyl ethyl ketone, methyl butyl ketone, esters such as ethyl acetate, probyl acetate, butyl acetate, dichloromethane ,trans
e-1,2-dichloroethylene, cLs-1,2-dichloroethylene. Halogenated hydrocarbons such as 2-bromobrovane, fluorocarbons other than those of the present invention such as 1,1-dichloro-1-fluoroethane, etc. can be added as appropriate.
本発明の弗素化炭化水素系溶剤組成物は、従来のフロン
と同様、熱媒体や発泡剤等の各種用途に使用でき、特に
溶剤として用いた場合、従来のＲ１１３より高い溶解力
を有するため好適である。The fluorinated hydrocarbon solvent composition of the present invention can be used for various purposes such as a heat medium and a blowing agent like conventional fluorocarbons, and is particularly suitable when used as a solvent because it has a higher dissolving power than conventional R113. It is.
溶剤の具体的な用途としては、フラックス，グリース，
油，ワックス．インキ等の除去剤，塗料用溶剤，抽出剤
、ガラス，セラミックス，プラスチック．ゴム，金属製
各種物品，特にＩＣ部品，電気機器，精密機械，光学レ
ンズ等の洗浄剤や水切り剤等を挙げることができる。洗
浄方法としては、手拭き，浸漬，スプレー，揺動，超音
波洗浄，蒸気洗浄等を採用すれぱよい。Specific uses of solvents include flux, grease,
Oil, wax. Ink removers, paint solvents, extractants, glass, ceramics, plastics. Examples include cleaning agents and draining agents for various rubber and metal articles, particularly IC parts, electrical equipment, precision instruments, optical lenses, etc. As a cleaning method, hand wiping, dipping, spraying, shaking, ultrasonic cleaning, steam cleaning, etc. may be used.
［実施例］ 以下に本発明の実施例を示す。[Example] Examples of the present invention are shown below.
実施例１〜３
本発明の組戒物を用いてフラツクスの洗浄試験を行なっ
た。プリント基板全面にブラックス（タムラＡＬ−４，
タムラ製作所！！）を塗布し、２００ ’Ｃの電気炉で
２分間焼成後、本発明の組成物中に５分間浸漬した。比
較例としてＲ１１３についても同様の試験を行なった。Examples 1 to 3 Flux cleaning tests were conducted using the composite materials of the present invention. Blacks (Tamura AL-4,
Tamura Manufacturing! ! ) was applied, baked in an electric furnace at 200'C for 2 minutes, and then immersed in the composition of the present invention for 5 minutes. A similar test was also conducted for R113 as a comparative example.
本発明の組成物の混合比及びフラツクスの除去の度合い
を第１表に示す。Table 1 shows the mixing ratio and degree of flux removal of the composition of the present invention.
第１表
０：良好に除去できる ○：ほぼ良好Δ：微量残存
×：かなり残存実施例４〜６
本発明の組成物を用いて機械油の洗浄試験を行なった。Table 1 0: Can be removed well ○: Almost good Δ: Trace amount remaining
×: Significant residual Examples 4 to 6 A machine oil cleaning test was conducted using the composition of the present invention.
ＳＵＳ−３０４のテストビース（ ２５ｍｍＸ ３０ｍ
ｍＸ ２ｍｍ厚）を機械油（ＣＱ−３０日本石油（ＩＩ
！）′＃Ｉ）中に浸漬した後、本発明の組成物中に５分
間浸漬した。SUS-304 test bead (25mm x 30m
mX 2mm thick) using machine oil (CQ-30 Nippon Oil (II)
! )'#I) and then immersed in the composition of the present invention for 5 minutes.
比較例としてＲ １１３についても同様の試験を行なっ
た。A similar test was conducted on R 113 as a comparative example.
本発明の組成物の混合比及び機械油の除去の度合いを第
２表に示す。The mixing ratio of the composition of the present invention and the degree of removal of machine oil are shown in Table 2.
第２表
［発明の効果］
本発明の弗素化炭化水素系溶剤組成物は、従来のフロン
が有している優れた特性を満足しながら、代替フロンと
して使用できるとともに、従来のフロンと同様の使い方
ができるため、従来技術の大幅な変更を要しない等の利
点がある。又、溶剤としてよく使われているＲ １１３
よりもフラックスや油等の溶解除去性に優れるためＲ
１１３に代わる洗浄溶剤として最適である。Table 2 [Effects of the Invention] The fluorinated hydrocarbon solvent composition of the present invention can be used as a substitute for fluorocarbons while satisfying the excellent properties of conventional fluorocarbons, and has the same properties as conventional fluorocarbons. Since it is easy to use, it has advantages such as not requiring major changes in conventional technology. Also, R 113, which is often used as a solvent,
Because it is better in dissolving and removing flux and oil than
It is most suitable as a cleaning solvent in place of 113.
Claims (6)
フルオロプロパン及び２，２，３，３，３−ペンタフル
オロプロパノールとからなる弗素化炭化水素系溶剤組成
物。(1) A fluorinated hydrocarbon solvent composition comprising 1,1-dichloro-2,2,3,3,3-pentafluoropropane and 2,2,3,3,3-pentafluoropropanol.
フルオロプロパン６０〜９９重量％，及び２，２，３，
３，３−ペンタフルオロプロパノール１〜４０重量％か
らなる請求項１に記載の組成物。(2) 1,1-dichloro-2,2,3,3,3-pentafluoropropane 60 to 99% by weight, and 2,2,3,
2. A composition according to claim 1, comprising 1 to 40% by weight of 3,3-pentafluoropropanol.
フルオロプロパン及び２，２，３，３，３−ペンタフル
オロプロパノールとからなる弗素化炭化水素系溶剤組成
物。(3) A fluorinated hydrocarbon solvent composition comprising 1,3-dichloro-1,2,2,3,3-pentafluoropropane and 2,2,3,3,3-pentafluoropropanol.
フルオロプロパン６０〜９９重量％，及び２，２，３，
３，３−ペンタフルオロプロパノール１〜４０重量％か
らなる請求項３に記載の組成物。(4) 1,3-dichloro-1,2,2,3,3-pentafluoropropane 60 to 99% by weight, and 2,2,3,
4. A composition according to claim 3, comprising 1 to 40% by weight of 3,3-pentafluoropropanol.
ロパン及び２，２，３，３，３−ペンタフルオロプロパ
ノールとからなる弗素化炭化水素系溶剤組成物。(5) A fluorinated hydrocarbon solvent composition comprising 1-chloro-2,2,3,3-tetrafluoropropane and 2,2,3,3,3-pentafluoropropanol.
ロパン６０〜９９重量％，及び２，２，３，３，３−ペ
ンタフルオロプロパノール１〜４０重量％からなる請求
項５に記載の組成物。(6) 60 to 99% by weight of 1-chloro-2,2,3,3-tetrafluoropropane and 1 to 40% by weight of 2,2,3,3,3-pentafluoropropanol according to claim 5. Composition of.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1149503A JPH0317033A (en) | 1989-06-14 | 1989-06-14 | Fluorinated hydrocarbon-based solvent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1149503A JPH0317033A (en) | 1989-06-14 | 1989-06-14 | Fluorinated hydrocarbon-based solvent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0317033A true JPH0317033A (en) | 1991-01-25 |
Family
ID=15476578
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1149503A Pending JPH0317033A (en) | 1989-06-14 | 1989-06-14 | Fluorinated hydrocarbon-based solvent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0317033A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5304321A (en) * | 1989-11-06 | 1994-04-19 | Kali-Chemie Ag | Cleaning compositions, formed of hydrogen-containing fluorochlorohydrocarbons and partially fluorinated alkanols |
| JP2009513451A (en) * | 2005-10-28 | 2009-04-02 | グラフィック パッケージング インターナショナル インコーポレイテッド | Carton with resealable opening function |
-
1989
- 1989-06-14 JP JP1149503A patent/JPH0317033A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5304321A (en) * | 1989-11-06 | 1994-04-19 | Kali-Chemie Ag | Cleaning compositions, formed of hydrogen-containing fluorochlorohydrocarbons and partially fluorinated alkanols |
| JP2009513451A (en) * | 2005-10-28 | 2009-04-02 | グラフィック パッケージング インターナショナル インコーポレイテッド | Carton with resealable opening function |
| JP4850255B2 (en) * | 2005-10-28 | 2012-01-11 | グラフィック パッケージング インターナショナル インコーポレイテッド | Carton with resealable opening function |
| US8672214B2 (en) | 2005-10-28 | 2014-03-18 | Graphic Packaging International, Inc. | Cartons with reclosable opening features |
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