JPH03161580A - Dyeing processing of cellulosic fiber cloth exhibiting shabby feeling - Google Patents
Dyeing processing of cellulosic fiber cloth exhibiting shabby feelingInfo
- Publication number
- JPH03161580A JPH03161580A JP1296897A JP29689789A JPH03161580A JP H03161580 A JPH03161580 A JP H03161580A JP 1296897 A JP1296897 A JP 1296897A JP 29689789 A JP29689789 A JP 29689789A JP H03161580 A JPH03161580 A JP H03161580A
- Authority
- JP
- Japan
- Prior art keywords
- dyeing
- feeling
- resin
- shabby
- fiber cloth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 28
- 238000004043 dyeing Methods 0.000 title claims abstract description 23
- 239000000835 fiber Substances 0.000 title claims abstract description 11
- 230000001747 exhibiting effect Effects 0.000 title 1
- 238000000034 method Methods 0.000 claims abstract description 30
- 229920005989 resin Polymers 0.000 claims abstract description 25
- 239000011347 resin Substances 0.000 claims abstract description 25
- 238000009991 scouring Methods 0.000 claims abstract description 7
- 206010016256 fatigue Diseases 0.000 claims description 20
- 229920002678 cellulose Polymers 0.000 claims description 7
- 239000001913 cellulose Substances 0.000 claims description 7
- 238000003672 processing method Methods 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 9
- 238000004061 bleaching Methods 0.000 abstract description 9
- 235000011121 sodium hydroxide Nutrition 0.000 abstract description 3
- USDJGQLNFPZEON-UHFFFAOYSA-N [[4,6-bis(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCNC1=NC(NCO)=NC(NCO)=N1 USDJGQLNFPZEON-UHFFFAOYSA-N 0.000 abstract description 2
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 abstract description 2
- 229960002218 sodium chlorite Drugs 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract 2
- 239000000839 emulsion Substances 0.000 description 12
- 239000000975 dye Substances 0.000 description 10
- 229920003043 Cellulose fiber Polymers 0.000 description 8
- -1 polyethylene Polymers 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000007844 bleaching agent Substances 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 4
- 229920005615 natural polymer Polymers 0.000 description 4
- 239000000984 vat dye Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 229920001281 polyalkylene Polymers 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- YGCOKJWKWLYHTG-UHFFFAOYSA-N [[4,6-bis[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol Chemical compound OCN(CO)C1=NC(N(CO)CO)=NC(N(CO)CO)=N1 YGCOKJWKWLYHTG-UHFFFAOYSA-N 0.000 description 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- YKCWQPZFAFZLBI-UHFFFAOYSA-N cibacron blue Chemical compound C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C(S(O)(=O)=O)C=C1NC(C=C1S(O)(=O)=O)=CC=C1NC(N=1)=NC(Cl)=NC=1NC1=CC=CC=C1S(O)(=O)=O YKCWQPZFAFZLBI-UHFFFAOYSA-N 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- COHYTHOBJLSHDF-BUHFOSPRSA-N indigo dye Chemical compound N\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-BUHFOSPRSA-N 0.000 description 2
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 229920005749 polyurethane resin Polymers 0.000 description 2
- 239000000985 reactive dye Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 229920001059 synthetic polymer Polymers 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- RTLULCVBFCRQKI-UHFFFAOYSA-N 1-amino-4-[3-[(4,6-dichloro-1,3,5-triazin-2-yl)amino]-4-sulfoanilino]-9,10-dioxoanthracene-2-sulfonic acid Chemical compound C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C(S(O)(=O)=O)C=C1NC(C=1)=CC=C(S(O)(=O)=O)C=1NC1=NC(Cl)=NC(Cl)=N1 RTLULCVBFCRQKI-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NJRHMGPRPPEGQL-UHFFFAOYSA-N 2-hydroxybutyl prop-2-enoate Chemical compound CCC(O)COC(=O)C=C NJRHMGPRPPEGQL-UHFFFAOYSA-N 0.000 description 1
- ZEYUSQVGRCPBPG-UHFFFAOYSA-N 4,5-dihydroxy-1,3-bis(hydroxymethyl)imidazolidin-2-one Chemical compound OCN1C(O)C(O)N(CO)C1=O ZEYUSQVGRCPBPG-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 239000004908 Emulsion polymer Substances 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229920001407 Modal (textile) Polymers 0.000 description 1
- PUPHKWFJRLCPPJ-UHFFFAOYSA-N NC(=O)N.C(O)C(=C(OC)CO)OC Chemical compound NC(=O)N.C(O)C(=C(OC)CO)OC PUPHKWFJRLCPPJ-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 241001062472 Stokellia anisodon Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 240000004584 Tamarindus indica Species 0.000 description 1
- 235000004298 Tamarindus indica Nutrition 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 238000010014 continuous dyeing Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000921 polyethylene adipate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000000988 sulfur dye Substances 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Coloring (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明はセルロース系瑚維布帛の染色方法に係わり、更
に詳細には樹脂を用いて前処理することにより洗いざら
し、あるいは着古した感じを現出さじ、かつ堅牢性にも
優れるセルロース系繊維布帛の染色加工法に関するもの
である。[Detailed Description of the Invention] (Industrial Application Field) The present invention relates to a method for dyeing cellulose-based gray fiber fabric, and more specifically, it relates to a method for dyeing cellulose-based fiber fabric, and more specifically, it pre-treats it with a resin to give it a washed-out or worn-out look. The present invention relates to a method for dyeing cellulose fiber fabrics that is easy to use and has excellent fastness.
（従来の技術〉
通常、染色物は繰り返し選ぶに対して変褪色が少ない事
、即ち洗いざらされない様に堅牢に染色されていること
が望まれている．しかしながら最近の若者によるファン
シッンの流行に於では例えばブルーデニムの如く、洗い
ざらした感じ、あるいは着古した感しか好まれている．
特にブリーチアウトデニムなどと呼称されているカジュ
アルパンツはインジゴ染料にて染色されたＢ”４Ｂ物あ
るいはその縫製品を漂白剤を使用した後で脱色されたも
のである．さらにインジゴ染料のブルーのみでなく種々
の色相のカラーデニムに対しても洗いざらした、即ちブ
リーチアウトした感しの商品が好まれるＩＩＪＩ向が大
となってきている。この様な要望に対して従来は反応性
染料で染色后、塩素晒をしたり、あるいはバット染料で
染色后、塩素晒をしたりしているが、それぞれ欠陥があ
る．即ち前者は一般に反応性染料の塩素堅牢度が不良の
ため、染色布の濃度コントロールが困難であり、後者は
塩素堅牢度が良好すぎてブリーチアウトした悪しが出に
くい．いずれの場合も凛白工程がウインス等のバッチ方
式であり長時間を要したり、漂白剤を使用して脱色する
ために漂白されずに残った染料さえも漂白剤により影響
を受け、堅牢度が低下する．又、漂白剤として次亜塩素
酸ソーダ等を使用するために臭気の問題で作業性が悪い
等の欠点がある．またその他の方法としてブリーチアウ
ト風仕上には布の組織の山部分のみ、即ち表面のみを染
色する方法あるいは染＃４施与後水通しを行って後に染
料を固着する方法などがあるが、これらは内部が淡く、
外部が濃いため本質的に自然に着古したような洗いざら
した感しを得ることはできない．
これらの問題点を解決するために特開昭５９−１６３４
９１号公報にはセルロース系織維の白布または染色布に
、水不溶性でかつ還元されリューコ化合物となって溶解
し染着する染料，アルカリ剤、スルフィン系還元剤およ
びアルカリ性で還元性を有する無機金属化合物を含む染
料液をパンドし、乾燥することなくスチーム処理するこ
とにより洗いざらし感を有する染色布を得る方法が提案
されているが、バット染料．硫化染料，硫化バット染料
等しか使用できないため色相が限定されることや、バッ
ト染料等が還元剤により分解されるために徐々に染ギ：
１濃度が降下し、テーリングが発生するという問題があ
った．
更にはセルロース系繊維布帛の原布を直接通常の方法に
て染色する事により洗いざらし感を有する染色布を得る
方法も検討されてはきたが、原布の油汚れの修正箇所が
そのまま加工不良として発現される為に歩留りが非常に
悪いという問題があった．
（発明が解決しようとするＡＩ題）
本発明は、セルロース系繊維布帛に対して自然な感しの
着古した洗いざらした外観を付与する場合における上記
のような問題を解決することを課題とするものである。(Prior art) Normally, it is desired that dyed products have little discoloration or fading even when repeatedly selected, that is, they should be dyed firmly so that they will not wash out. However, with the recent trend of fanshining among young people, For example, people only like blue denim that has a washed or worn look.
In particular, casual pants called bleached-out denim are B"4B products dyed with indigo dye, or sewn products thereof, which are bleached after using bleach. Furthermore, they are made of only blue indigo dye. There is a growing trend towards IIJI, which prefers products with a washed-out, bleached-out feel to colored denim of various hues. , bleaching with chlorine, or bleaching with chlorine after dyeing with vat dye, but each has its own flaws.The former generally has poor chlorine fastness of reactive dyes, so it is difficult to control the concentration of the dyed fabric. In the latter case, the fastness to chlorine is so good that it is difficult to cause the problem of bleaching out.In both cases, the Rinpaku process is a batch method such as Winx, which takes a long time, and requires the use of bleach. Even the dye that remains unbleached is affected by the bleaching agent and its fastness decreases.Also, since sodium hypochlorite is used as the bleaching agent, workability is poor due to odor problems. Other methods include dyeing only the ridges of the texture of the fabric, that is, only the surface, or dyeing #4 and then passing water through it to fix the dye. etc., but these have a pale interior.
Because the exterior is dark, it is essentially impossible to obtain a washed-out, worn-in feel. In order to solve these problems,
Publication No. 91 describes dyes that are water-insoluble and can be reduced to dissolve and dye into leuco compounds, alkaline agents, sulfinic reducing agents, and inorganic metals that are alkaline and have reducing properties. A method has been proposed in which a dye solution containing a compound is pumped and steam-treated without drying to obtain a dyed cloth with a washed-out feel, but vat dyes. Because only sulfur dyes, sulfur vat dyes, etc. can be used, the hue is limited, and vat dyes are decomposed by reducing agents, so the dyeing process gradually increases.
There was a problem that the concentration decreased and tailing occurred. Furthermore, a method to obtain a dyed cloth with a washed-out appearance by directly dyeing the original cellulose fiber fabric using a conventional method has been considered, but the oil stains on the original fabric may be treated as a processing defect. There was a problem that the yield was very poor because of the (AI problem to be solved by the invention) An object of the present invention is to solve the above-mentioned problems when imparting a natural-looking, worn-out, washed-out appearance to cellulose-based fiber fabrics. It is.
すなわら、本発明においては、セルロース系繊維布帛に
対して簡単かつ均一に自然な感しの着古した洗いざらし
感を付与でき、また連続方式で種々の色相を可能にする
染色加工方法を提供するものである．
（課題を解決するための手段）
上述の目的は、セルロース系繊維布帛の原市に対して拐
脂を施与した後に通常の方法にて猜練晒し、しかる後通
常の方法にて染色することを特徴とするセルロース系繊
維布帛の洗いざらし感を有する染色加工法により達成さ
れる．
更に本発明方法について詳細に述べる。本発明方ｌｂで
いうセルロース糸織維布帛とは、綿，ポリノジック．麻
等単独、またはそれ等繊維の混紡あるいは交織、更には
綿，ポリノジソク，麻等とボリエ．ステル繊維等との混
紡あるいは交織による織物及び編物が挙げられ、これら
の布帛を構戊する経糸，緯糸の番手，密度は特に限定さ
れない．本発明方法に使用し得る樹脂としては、繊維素
反応型樹脂，縮台型樹脂，合成高分子のエマルジョン．
天然高分子とその架橋剤，熱反応型水溶性ウレタン等が
挙げられ、−４１又は二種以上組合わセて、使用される
．
織維素反応型樹脂としては、ジメチロールジヒドロキシ
エチレン尿素，ジメチロールジメトキシエチレン尿素．
ジメチロールブロビレン尿素、ミ縮合型樹脂としては、
トリメチロールメラξン．ヘキサメチロールメラミン等
が例示される．
又合或高分子のエマルジョンとしては、１個以上のビニ
ル基を含有するモノマーを単独又は２昔以上乳化重合し
て得られるアクリル又はメタクリル化合物のエマルジョ
ン、例えばアクリル酸．メタクリル酸，メチルアクリレ
ート，メチルメタアクリレート，エチルアクリレート，
エチルメタクリレート，プチルアクリレート．プチルメ
タクリレート，アクリロニトリル．アクリルアミド．メ
チロールアクリルアミド．２−ヒドロキンエチルアクリ
レート，２−ヒドロキシブチルアクリレート等の乳化重
合物のエマルジョンや、ポリアルキレン単独又は２者以
上からなるボリマーのエマルジッン、例えばポリエチレ
ン，ポリプロピレン樹脂のエマルジａンや、多価アルコ
ールと多塩基酸からなるポリエチレン樹脂のエマルジョ
ン、例えば多価アルコールとしてエチレングリコール，
１，４−プタンジオール．ｌ，６−ヘキサンジオールジ
エチレングリコール．トリメチロールプロパンと多塩基
酸としてフタル酸．アジピン酸，マレイン酸，トリメリ
ット酸．テレフタル酸からなるポリエステル樹脂のエマ
ルジョンや、ジイソシアネ−トとボリオールからなるポ
リウレタン樹脂のエマルジョン、例えば、ジイソシアネ
ートとしてヘキサメチレンジイソシアネート，キシレン
ジイソシアネート，トリレンジイソシアネート．４．４
’一ジフェニルメタンジイソノアネート，ｌ，５−ナフ
タレンジイソシア不一トとボリオールとしてポリエチレ
ンアジベート，ボリプロビレンアジペート．ポリブチレ
ンアジペート．ポリエチレンフクレート，ボリエチレン
グリコール，ボリブロビレングリコール，ポリエチレン
プロピレングリコールからなるポリウレタン樹脂のエマ
ルジａン等の合成高分子のエマルジョン等が例示される
．天然高分子とその架橋剤としては、例えば天然高分子
としてｒｊ＄５） ． カルボキシメチル化殿扮．カル
ボキシエチル化殿粉．ヒドロキシエチル化殿粉，天然高
分子ゴムであるグアガム．タマリンドガム等の水溶性ゴ
ム、その架橋剤としてイソシアネート基をブロンクした
水溶性熱反応型ウレタン、市販商品名としては第一工業
製薬一のエラストロンＭＦ−９，エラストロンＷ−１１
及びバイエルＧ場のシンクープレントＢＡＰ等や、アル
キレングリコールジクリシジルエーテル及びポリアルキ
レングリコールジクリシジルエーテル等の水溶性ジクリ
シジルエーテル誘導体、市販商品名としては共栄社由脂
化学工業一のエポライト２ ０ ０ Ｅ，エボライト４
０ ０ Ｅ． エボライト４００Ｐやアミノプラス
ト樹脂例えばトリメチロールメラミン．ヘキサメチロー
ルメラミン等が例示される．熱反応型水溶性ウレタンと
しては重亜硫酸ソーダ．アセチルアセトン５アセト酢酸
エチル．ジエチルマ口不一ト等インシア不一ト基に反応
して一時的に安定な化合物を作り、後から熱処理するこ
とにより熱解離し、イソシア不−ト基を再生するブロッ
ク化イソシアネート基を分子中に少くとも１個以上含有
する化合物等が例示される．次に本発明の実施態様につ
いて詳述する．まず、セルロース系繊維布帛の原布に前
記の如き樹脂を施与するが、この場合、樹脂を水に熔解
あるいは分叶させた処理液を用い、コーティング，スプ
レー法あるいは浸漬してマングルにより絞る方法などが
（ｉｉｌれも用いられる．そして、樹脂を施与後乾燥を
行い、必要に応してキュアリングを実施する．なお、本
発明において、洗いざらし感の優れた染色物を得るには
、樹脂の付着盟は繊維重量に対して０．５〜１０重星％
が好ましい．即ち１１４度が高すぎると防染効果が大と
なりすぎて、洗いざらしの感しか得られにくい上、得ら
れたものの風合が硬すぎる欠点を生してしまい、一方余
りに低濃度では、全体が均一に染色されて洗いざらし感
の発現効果が小さい．
樹脂を施与した布帛は次いで精練晒されるが、その精練
晒は通常行なわれるセルロース系繊維に対する精練晒法
がすべて可能である．
梢独晒された布帛は次いで染色されるが、その染色は通
常行なわれているセルロース系繊維に対する染色法がす
べて可能である．但し染法としては、バッチ方弐による
吸尽染色法などの場合あまりに長時間であると樹脂が脱
落して表面への防染効果が小さくなることがあり、連続
染色法の方が好ましい。In other words, the present invention provides a dyeing method that can easily and uniformly impart a natural, worn-out, washed-out feel to a cellulose fiber fabric, and that can produce various hues in a continuous manner. It is something. (Means for Solving the Problems) The above purpose is to apply fat removal to a raw material of cellulose fiber fabric, smelt it by a normal method, and then dye it by a normal method. This is achieved through a dyeing process that gives the cellulose fiber fabric a characteristic washed-out feel. Further, the method of the present invention will be described in detail. The cellulose yarn woven fabric mentioned in method 1b of the present invention refers to cotton, polynosic, etc. Linen, etc. alone, or blended or woven with these fibers, as well as cotton, polyester, hemp, etc. and bolier. Examples include woven and knitted fabrics made by blending or interweaving with stell fibers, etc., and the counts and densities of the warps and wefts that make up these fabrics are not particularly limited. Examples of resins that can be used in the method of the present invention include cellulose-reactive resins, reduced table resins, and emulsions of synthetic polymers.
Examples include natural polymers, their crosslinking agents, heat-reactive water-soluble urethanes, etc. -41 or a combination of two or more are used. Examples of woven fiber-reactive resins include dimethylol dihydroxyethylene urea and dimethylol dimethoxyethylene urea.
Dimethylol brobylene urea, mi-condensation type resin, trimethylol melane. Examples include hexamethylolmelamine. Examples of emulsions of polymers include emulsions of acrylic or methacrylic compounds obtained by emulsion polymerization of monomers containing one or more vinyl groups, such as acrylic acid. Methacrylic acid, methyl acrylate, methyl methacrylate, ethyl acrylate,
Ethyl methacrylate, butyl acrylate. Butyl methacrylate, acrylonitrile. Acrylamide. Methyloacrylamide. Emulsions of emulsion polymers such as 2-hydroquine ethyl acrylate and 2-hydroxybutyl acrylate, emulsions of polymers consisting of polyalkylene alone or two or more, such as emulsions of polyethylene and polypropylene resins, and emulsions of polyalkylene and polyalkylene. Emulsion of polyethylene resin consisting of basic acid, e.g. ethylene glycol as polyhydric alcohol,
1,4-butanediol. l,6-hexanediol diethylene glycol. Trimethylolpropane and phthalic acid as a polybasic acid. Adipic acid, maleic acid, trimellitic acid. Emulsions of polyester resins made of terephthalic acid, emulsions of polyurethane resins made of diisocyanates and polyols, for example, hexamethylene diisocyanate, xylene diisocyanate, tolylene diisocyanate as diisocyanates. 4.4
'-diphenylmethane diisonoanate, l,5-naphthalene diisocyanate and polyol as polyethylene adipate, polypropylene adipate. Polybutylene adipate. Examples include emulsions of synthetic polymers such as emulsion a of polyurethane resins consisting of polyethylene fucrate, polyethylene glycol, polybrobylene glycol, and polyethylene propylene glycol. As a natural polymer and its crosslinking agent, for example, as a natural polymer, rj$5). Carboxymethylation star. Carboxyethylated starch. Hydroxyethylated starch, guar gum, a natural polymer rubber. Water-soluble rubber such as tamarind gum, water-soluble heat-reactive urethane with isocyanate groups as a crosslinking agent, commercially available product names are Daiichi Kogyo Seiyaku Ichi's Elastron MF-9 and Elastron W-11.
and Bayer G field's Shincouplent BAP, etc., water-soluble dicrycidyl ether derivatives such as alkylene glycol dicrycidyl ether and polyalkylene glycol dicrycidyl ether, commercially available product names include Kyoeisha Yuki Kagaku Kogyo Ichi's Epolite 200 E, evolite 4
0 0 E. Evolite 400P and aminoplast resins such as trimethylolmelamine. Examples include hexamethylolmelamine. Sodium bisulfite is a heat-reactive water-soluble urethane. Acetylacetone 5 Ethyl acetoacetate. Blocked isocyanate groups such as diethyl machinate react with the isocyanate group to create a temporarily stable compound, which is then thermally dissociated by heat treatment to regenerate the isocyanate group. Examples include compounds containing at least one. Next, embodiments of the present invention will be described in detail. First, the above-mentioned resin is applied to the original cellulose fiber fabric. In this case, a treatment solution in which the resin is dissolved or decomposed in water is used, and a coating, spraying method, or dipping and squeezing with a mangle is used. etc. (ii) are also used.Then, after applying the resin, drying is performed, and curing is performed if necessary.In addition, in the present invention, in order to obtain a dyed product with an excellent washed-out feel, the resin The adhesion is 0.5 to 10% based on the weight of the fiber.
is preferable. That is, if the concentration of 114 degrees is too high, the resisting effect will be too strong and it will be difficult to obtain a washed-out feeling, and the texture of the obtained product will be too hard.On the other hand, if the concentration is too low, the dye will be uniform throughout. The effect of creating a washed-out feeling is small. The resin-applied fabric is then subjected to scouring and bleaching, which can be done by any of the usual scouring and bleaching methods for cellulose fibers. The exposed fabric is then dyed using any of the commonly used dyeing methods for cellulose fibers. However, if the dyeing method is an exhaustive dyeing method using a batch method or the like, if the dyeing time is too long, the resin may fall off and the resist dyeing effect on the surface may be reduced, so a continuous dyeing method is preferable.
（作用）
本発明は、染色前に樹脂を施与しその後精練晒を行なっ
ているので、樹脂が精練晒により斑落ちし、樹脂が残在
している部分においては樹脂が防染層として働き、染料
が浸透しに＜＜、一方樹脂が脱落している部分において
は染料が浸透しやすいので全体として斑染となり、洗い
ざらし感を有する染色物となる．
（実ＦＪｆｆｉ例）
次に実施例に基づき本発明の方法を具体的に説明する．
実施例ｌ
この実施例においては、セルロース糸織維布帛として経
糸２０番単糸．緯糸２０番単糸からなる経密度１０８本
／インチ５緯密度５８本／インチの純綿絞！Ｑｌｉ物組
織のものを用いた．このｗ！織物原布をユーラミンＴ−
８０（三井東圧Ｉ１社製、モノメチロールアクリルアξ
ド系樹脂、固形分５０％）＋５！４．キャタリストＧ（
大日本インキ■社製、金属塩系触媒、固形分５０％）３
％．ダイアサーバー（三菱化或０粉社製、浸透剤）０．
５％からなる樹脂液に浸清し、マングルにより７０％
に絞った後熱風乾燥機１２０℃にて乾燥し、しかる後１
５０℃×３分キュアリングを施した．この樹脂を施与し
た綾織物を苛性ソーダ５％，トライボン（一方社油脂社
製、非イオン界面活性剤）０． ４％からなる精練液に
浸漬し、マングルにより＋００９Ａに絞った後９８℃×
３０分スチーミングしソーピングし、引き続き亜塩素酸
ソーダ０． ７％醋酸０． ２％からなる晒液に浸漬し
、マングルにより１００％に絞った後日５℃×３０分ス
チーξングし、脱塩及びソーピングした後乾燥した．次
いで、このｔｌｌ練晒をした綾織物を苛性ソーダ１８％
．４０℃でシルケフト加工後、次いで反応性染料にて染
色した．染色は次の組成、即ちシバクロン・ブルーＢＲ
（チバガイギー社製）０．０９％．シバクロン・ブルー
３Ｒ（チバガイギー社５！）０．１４％，プロシオン・
ブラウンＢＲＤ （ＩＣ１社製） ０． １ ３％２尿
素１５％，ソーダ灰ｌ％からなる染液をパッドし、７０
％に絞って乾燥した後、１５０℃で３分間のベーキング
を行ない固着し、次いで常法により未固着染料除去のた
めに、オーブンソーパーでソーピングを行なった．以上
の如くして得られた染色布は洗いざらし感を有するもの
であった．
また実施例１のユーラミンＴ−８０の濃度を１０％，キ
ャタリストＧの濃度を２％にした他は実施例Ｉと同様の
方法で製造したもの及び実施例ｌのユーラミンＴ−８０
の濃度を５％，キャクゾス｝Ｃの濃度を１％にした他は
実施例ｌと同様の方法で製造した染色布は、実施例１に
比較してやや洗いざらし感は不足するものの同様の効果
が得られた．
（発明の効果）
以上の如く、本発明方法によれば、従来のように染色濃
度コントロールの難かしいこともなくまた工程時間を短
かく、臭気の問題もなく、再現性に優れた堅牢なるプリ
ーチアウトの感し．洗いざらしの感しのある加工が連続
的に達成できるものであり、その工業的利用価値は大で
ある．また、得られる製品はあらゆる色相が可能であり
、今までにない洗いざらしの感じがあり、カジュアル用
途としては頗る有用である．(Function) In the present invention, since the resin is applied before dyeing and then scouring and bleaching is performed, the resin will fade in spots due to scouring and bleaching, and in the areas where the resin remains, the resin will act as a resist dyeing layer. On the other hand, in areas where the resin has fallen off, the dye easily penetrates, resulting in mottled dyeing as a whole, resulting in a dyed product with a washed-out feel. (Actual FJffi Example) Next, the method of the present invention will be specifically explained based on an example. Example 1 In this example, the warp #20 single yarn was used as the cellulose yarn woven fabric. Pure cotton with a warp density of 108 threads/inch and a weft density of 58 threads/inch, consisting of weft #20 single yarn! Qli tissue was used. This lol! Yulamin T- for raw fabric
80 (manufactured by Mitsui Toatsu I1, monomethylol acrylic ξ
solid resin, solid content 50%) +5!4. Catalyst G (
Manufactured by Dainippon Ink ■, metal salt catalyst, solid content 50%) 3
%. Diaserver (manufactured by Mitsubishi Kaoru Kogyo Co., Ltd., penetrating agent) 0.
Immerse in a resin solution consisting of 5% and reduce to 70% with a mangle.
After squeezing it, dry it in a hot air dryer at 120℃, and then
Curing was performed at 50°C for 3 minutes. The twill fabric coated with this resin was treated with 5% caustic soda and 0% Tribon (manufactured by Ipposha Yushi Co., Ltd., a nonionic surfactant). Immersed in a scouring solution consisting of 4%, squeezed to +009A with a mangle, and then heated to 98℃
Steam and soap for 30 minutes, then apply 0.0% sodium chlorite. 7% acetic acid 0. It was immersed in a 2% bleaching solution, squeezed to 100% with a mangle, and then steamed at 5°C for 30 minutes, desalted and soaped, and then dried. Next, this tll kneaded twill fabric was soaked in 18% caustic soda.
．． After Silkeft processing at 40°C, it was then dyed with a reactive dye. The staining had the following composition: Cibacron Blue BR
(manufactured by Ciba Geigy) 0.09%. Cibacron Blue 3R (Ciba Geigy 5!) 0.14%, Procion
Brown BRD (manufactured by IC1) 0. 1. Pad with a dye solution consisting of 3% 2 urea 15% and soda ash 1%, and
After drying, it was baked at 150°C for 3 minutes to fix it, and then soaped with an oven soaper in a conventional manner to remove unfixed dye. The dyed fabric thus obtained had a washed-out feel. In addition, Euramin T-80 of Example 1 and Euramin T-80 of Example 1 were produced in the same manner as in Example I except that the concentration of Euramin T-80 in Example 1 was 10% and the concentration of Catalyst G was 2%.
A dyed cloth produced in the same manner as in Example 1 except that the concentration of C was 5% and the concentration of Kyaczos}C was 1% had the same effect as Example 1, although the washed-out feeling was slightly lacking. It was done. (Effects of the Invention) As described above, according to the method of the present invention, there is no difficulty in controlling the dyeing density as in the conventional method, the process time is short, there is no odor problem, and the method provides a durable pleat with excellent reproducibility. Feeling out. Processing with a washed-out feel can be achieved continuously, and its industrial utility value is great. Additionally, the resulting product is available in all hues and has an unprecedented washed-out feel, making it extremely useful for casual use.
Claims (1)
した後に通常の方法にて精練晒し、しかる後通常の方法
にて染色することを特徴とするセルロース系繊維布帛の
洗いざらし感を有する染色加工法。(1) A cellulose-based fiber fabric has a washed-out feel, which is obtained by applying a resin to the original cellulose-based fiber fabric, scouring and exposing it using a normal method, and then dyeing it using a normal method. Dyeing processing method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1296897A JPH03161580A (en) | 1989-11-15 | 1989-11-15 | Dyeing processing of cellulosic fiber cloth exhibiting shabby feeling |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1296897A JPH03161580A (en) | 1989-11-15 | 1989-11-15 | Dyeing processing of cellulosic fiber cloth exhibiting shabby feeling |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03161580A true JPH03161580A (en) | 1991-07-11 |
Family
ID=17839580
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1296897A Pending JPH03161580A (en) | 1989-11-15 | 1989-11-15 | Dyeing processing of cellulosic fiber cloth exhibiting shabby feeling |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03161580A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5350423A (en) * | 1992-09-23 | 1994-09-27 | Burlington Industries Inc. | Fabric finishing procedure |
| US5474577A (en) * | 1993-06-09 | 1995-12-12 | Central Trading Enterprises, Inc. | Methods and compositions for treating denim fabric and the fabric produced thereby |
-
1989
- 1989-11-15 JP JP1296897A patent/JPH03161580A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5350423A (en) * | 1992-09-23 | 1994-09-27 | Burlington Industries Inc. | Fabric finishing procedure |
| US5474577A (en) * | 1993-06-09 | 1995-12-12 | Central Trading Enterprises, Inc. | Methods and compositions for treating denim fabric and the fabric produced thereby |
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